CA2979995C - System and method for preparing a treatment fluid - Google Patents
System and method for preparing a treatment fluid Download PDFInfo
- Publication number
- CA2979995C CA2979995C CA2979995A CA2979995A CA2979995C CA 2979995 C CA2979995 C CA 2979995C CA 2979995 A CA2979995 A CA 2979995A CA 2979995 A CA2979995 A CA 2979995A CA 2979995 C CA2979995 C CA 2979995C
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- container
- packet
- proppant
- storage area
- mixer
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/267—Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/20—Adding fluid, other than for crushing or disintegrating by fluid energy after crushing or disintegrating
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B21/00—Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
- E21B21/06—Arrangements for treating drilling fluids outside the borehole
- E21B21/062—Arrangements for treating drilling fluids outside the borehole by mixing components
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/2607—Surface equipment specially adapted for fracturing operations
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- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Filling Or Emptying Of Bunkers, Hoppers, And Tanks (AREA)
- Processing Of Solid Wastes (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
Description
PREPARING A TREATMENT FLUID
FIELD
[0001] The disclosure generally relates to the preparation of subterranean formation treatment fluids, and more particularly, but not by way of limitation, systems and methods for introducing additives into a treatment fluid using additive packets.
BACKGROUND
Such fluids may be used as fracturing fluids, acidizing fluids, and high-density completion fluids. In an operation known as well fracturing, such fluids are used to initiate and propagate underground fractures for increasing petroleum productivity.
SUMMARY
passing the packets from the first container packet storage area to a packet shredder positioned below the first container; at least partially breaching the liners of the packets to expose the additive, thereby forming exposed additive; passing the exposed additive to a first mixer inlet of a mixer; passing an aqueous solution to a second mixer inlet of the mixer; and mixing the exposed additive with the aqueous solution in the mixer to form a treatment fluid.
[0011a] In accordance with another embodiment, there is provided a method for preparing a treatment fluid comprising: disposing a plurality of individual packets in a first container packet storage area of a first container, each of the plurality of packets comprising an additive encased within a liner; passing the plurality of individual packets from the first container packet storage area to a packet shredder positioned below the first container; metering the individual packets while passing the packets from the first container packet storage area to the packet shredder; utilizing the packet shredder to at least partially breach the liners of the packets to expose the additive, thereby forming exposed additive; passing the exposed additive through a first mixer inlet of a mixer;
storing proppant separate from the additive; delivering the proppant into the mixer;
passing an aqueous solution through a second mixer inlet of the mixer and thus exposing the additive and the proppant to the aqueous solution; and mixing the exposed additive, the proppant, and the aqueous solution in the mixer to form the treatment fluid.
2a Date Recue/Date Received 2022-07-19 BRIEF DESCRIPTION OF THE DRAWINGS
DETAILED DESCRIPTION
The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily referring to the same embodiment.
and a second container 122 comprising an aqueous solution and having an aqueous solution outlet 124 in fluid flow communication with the second mixer inlet 118. The first container 102 can be a hopper or can be a silo.
In accordance with some embodiments, with reference to Figures 1 and 3, the metering device 134 can be positioned between the packet delivering opening 106 and the chute 132 to meter the packets prior to conveying the packets to the chute 132. The metering device can be selected from the group consisting of a metering auger, an optical counter device, or a rotary valve that selectively allows a given number of pouches per revolution, or combinations thereof.
and the proppant delivery opening 210 can be positioned above a second area of first mixer inlet 220.
Figure 8 is a top plan view of silo 252 and first container 202. With reference to Figures 7 and 8, silo 252 comprises a partition 254 dividing the silo 252 into a silo packet storage area 256 having a silo packet outlet 258 and a silo proppant storage area 260 having a silo proppant outlet 262, wherein the silo packet outlet 258 is positioned above the first container packet storage area 204 and the silo proppant outlet 262 is positioned above the first container proppant storage area 208.
and the silo proppant outlet 362 can be positioned above a second area 376 of first mixer inlet 320.
[0069] In accordance with some embodiments, as shown in Figure 16, system 300 can further comprise an auger 368 having an auger inlet 370 and an auger outlet 372; and wherein the shredder outlet 316 is connected in fluid flow communication with the auger inlet 370 and the auger outlet 372 is positioned in fluid flow communication with the first mixer inlet 320. In accordance with some embodiments, as shown in Figure 16, the auger outlet 372 can be positioned above a first area 374 of first mixer inlet 320; and wherein the silo proppant outlet 362 can be positioned above a second area 376 of first mixer inlet 320.
[0060] In accordance with some embodiments, the additive can be a solid material selected from the group consisting of fluid loss additives, breakers, and fiber. In accordance with some embodiments, the liners of the packets can be water soluble, and the packets on average can contain less than about 1728 or less than 216, or less than 27 cubic inches of additive.
[0061] In accordance with some embodiments, and with reference to Figure 1, a method for preparing a treatment fluid comprises providing the packets described above to first container packet storage area 104 of first container 102;
passing the packets from the first container packet storage area 104 to the packet shredder 108 positioned below the first container 102; at least partially breaching the liners of the packets in packet shredder 108 to expose the additive, thereby forming exposed additive; passing the exposed additive to first mixer inlet 116 of mixer 114;
passing an aqueous solution to the second mixer inlet 118 of the mixer 114; and mixing the exposed additive with the aqueous solution in the mixer 114 to form the treatment fluid. In accordance with some embodiments, with reference to Figure 1, the treatment fluid can be charged from mixer outlet 120 to wellbore 126 penetrating the subterranean formation. The wellbore can be connected to the mixer outlet 120 by pump 128 and mixer outlet conduit 130, as shown in Figure 1.
[0062] In accordance with some embodiments, with reference to Figure 2, chute 132 is positioned between packet delivery opening 106 and packet shredder 108, and the packets can be charged from the first container packet storage area 104 to the chute 132 prior to passing to the packet shredder 108. In accordance with some embodiments, and with reference to Figure 2, metering device 134 can be positioned between the chute 132 and the packet shredder 108; and the packets can be metered prior to conveyance to the packet shredder 108. Such metering allows greater control of the rate of additive addition to the mixture, and the meter data can be used in controlling the rate of introduction of packets to the packet shredder by, among other things, controlling the size of the packet delivery opening. The first container 102 can further comprise a gate valve 178 (shown in Figure 2) in slidable arrangement with the packet delivery opening 106 to allow control of the size of the packet delivery opening 106. As shown in Figure 3, the metering device 134 can be positioned between the packet delivery opening 106 and the chute 132, and the packets can be metered prior to conveyance to the chute 132, and then to packet shredder 108, for the reasons stated above.
[0063] In accordance with some embodiments, as shown in Figure 4, auger 136 can be positioned between the packet shredder 108 and the first mixer inlet 116, and the exposed additive from the packet shredder 108 can be passed to the auger inlet 138. The exposed additive can be passed from the auger outlet 140 to the first mixer inlet 116 of the mixer 114.
[0064] In accordance with some embodiments, and with reference to Figure 5, a method for preparing a treatment fluid comprises providing the packets described above to first container packet storage area 204 of first container 202;
passing the packets from the first container packet storage area 204 to the packet shredder 212 positioned below packet delivery opening 206 of first container 202; at least partially breaching the liners of the packets in packet shredder 212 to expose the additive, thereby forming exposed additive; passing the exposed additive to first mixer inlet 220 of mixer 218; passing an aqueous solution to the second mixer inlet 222 of the mixer 218; and mixing the exposed additive with the aqueous solution in the mixer 218 to form the treatment fluid. In accordance with some embodiments, and with reference to Figure 5, proppant is charged to the first container proppant storage area 208 and the proppant can be passed to the first mixer inlet 220 of the mixer 218 to become a part of the treatment fluid. In accordance with some embodiments, the proppant can be first combined with the exposed additive prior to passing to the mixer (not shown). In accordance with some embodiments, with reference to Figure 5, the treatment fluid can be charged from mixer outlet 224 to wellbore 238 penetrating the subterranean formation. The wellbore can be connected to the mixer outlet 224 by pump 240 and mixer outlet conduit 242, as shown in Figure 5. The system useful for carrying out the method(s) as described herein can be any of the above described embodiments or equivalents thereof.
[0065] In accordance with some embodiments, as described above with reference to Figures 7 - 9, at least one silo 252 can be positioned above the first container 202. The proppant can be passed from the silo proppant storage area to the first container proppant storage area 208, and the packets can be passed from the silo packet storage area 256 to the first container packet storage area 204.
[0066] In accordance with some embodiments, with reference to Figure 10, chute 264 is positioned between packet delivery opening 206 and packet shredder 212, and the packets can be charged from the first container packet storage area 204 to the chute 264 prior to passing to the packet shredder 212. In accordance with some embodiments, and with reference to Figure 10, metering device 266 can be positioned between the chute 264 and the packet shredder 212; and the packets can be metered prior to conveyance to the packet shredder 212. Such metering allows greater control of the rate of additive addition to the mixture, and the meter data can be used in controlling the rate of introduction of packets to the packet shredder by, among other things, controlling the size of the packet delivery opening.
The first container 202 can further comprise a gate valve 278 (shown in Figure 10) in slidable arrangement with the packet delivery opening 206 to allow control of the size of the packet delivery opening 206. As shown in Figure 11, the metering device can be positioned between the packet delivery opening 206 and the chute 264, and the packets can be metered prior to conveyance to the chute 264, and then to packet shredder 212, for the reasons stated above.
[0067] In accordance with some embodiments, as shown in Figure 12, auger 268 can be positioned between the packet shredder 212 and the first mixer inlet 220, and the exposed additive from the packet shredder 212 can be passed to the auger inlet 270. The exposed additive can be passed from the auger outlet 272 to the first mixer inlet 220 of the mixer 218. As shown in Figure 12, the auger outlet 272 can be positioned above first area 274 of the first mixer inlet 220 and the exposed additive can be passed to the first area 274 of the first mixer inlet 220, and the proppant can be passed from proppant delivery opening 210 to second area 276 of the first mixer inlet 220.
[0068] In accordance with some embodiments, and with reference to Figures 13 and 13A, a method for preparing a treatment fluid comprises providing the packets described above to silo packet storage area 356 of silo 352 (the first container); passing the packets from the silo packet storage area 356 to the packet shredder 312 positioned below silo packet outlet 358 of silo 352; at least partially breaching the liners of the packets in packet shredder 312 to expose the additive, thereby forming exposed additive; passing the exposed additive to first mixer inlet 320 of mixer 318; passing an aqueous solution to the second mixer inlet 322 of the mixer 318; and mixing the exposed additive with the aqueous solution in the mixer 318 to form the treatment fluid. In accordance with some embodiments, and with reference to Figures 13 and 13A, proppant is charged to the silo proppant storage area 360 and the proppant can be passed to the first mixer inlet 320 of the mixer 318 to become a part of the treatment fluid. In accordance with some embodiments, the proppant can be first combined with the exposed additive prior to passing to the mixer (not shown). In accordance with some embodiments, with reference to Figures 13 and 13A, the treatment fluid can be charged from mixer outlet 324 to wellbore 338 penetrating the subterranean formation. The wellbore can be connected to the mixer outlet 324 by pump 340 and mixer outlet conduit 342, as shown in Figure 13. The system useful for carrying out the method(s) as described herein can be any of the above described embodiments or equivalents thereof.
[0069] In accordance with some embodiments, with reference to Figure 14, chute 364 is positioned between silo packet outlet 358 and packet shredder 312, and the packets can be charged from the silo packet storage area 356 to the chute prior to passing to the packet shredder 312. In accordance with some embodiments, and with reference to Figure 14, metering device 366 can be positioned between the chute 364 and the packet shredder 312; and the packets can be metered prior to conveyance to the packet shredder 312. Such metering allows greater control of the rate of additive addition to the mixture, and the meter data can be used in controlling the rate of introduction of packets to the packet shredder by, among other things, controlling the size of the silo packet outlet 358. The silo 352 can further comprise a gate valve 378 (shown in Figure 14) in slidable arrangement with the silo packet outlet 358 to allow control of the size of the silo packet outlet 358. As shown in Figure 15, the metering device 366 can be positioned between the silo packet outlet 358 and the chute 364, and the packets can be metered prior to conveyance to the chute 364, and then to packet shredder 312, for the reasons stated above.
[0070] In accordance with some embodiments, as shown in Figure 16, auger 368 can be positioned between the packet shredder 312 and the first mixer inlet 320, and the exposed additive from the packet shredder 312 can be passed to the auger inlet 370. The exposed additive can be passed from the auger outlet 372 to the first mixer inlet 320 of the mixer 318. As shown in Figure 16, the auger outlet 372 can be positioned above first area 374 of the first mixer inlet 320 and the exposed additive can be passed to the first area 374 of the first mixer inlet 320, and the proppant can be passed from silo proppant outlet 362 to second area 376 of the first mixer inlet 320.
[0071] In accordance with some embodiments, the aqueous solution described above can comprise components selected from the group consisting of gelling agents, friction reducers, surfactants, biocides, cross-linkers, acids, fluid-loss additives, breakers, fibers in aqueous suspension, and combinations thereof.
[0072] In accordance with some embodiments, the packet shredder depicted as reference number 108 in Figures 1 ¨4, and depicted as reference number 212 in Figures 5,7, and 10-12, and depicted as reference number 312 in Figures 13-16 can be any shredder or other device capable of breaching the liner of a packet.
The shredder or device can comprise a sharp blade, such as a stationary knife, a handheld knife, cutting wheels, or augers. The packet shredder can be selected from the group consisting of a cheese-grater type shredder as shown in Figure 17A, a shredder employing multiple fingers on two counter rotating shafts as shown in Figure 17B, a sliding block shredder as shown in Figure 170, a rotary disc shredder as shown in Figure 17D, or any combination thereof.
[0073] In accordance with some embodiments, the mixer depicted as reference number 114 in Figures 1-4, and depicted as reference number 218 in Figures 5,7 and 10-12, and depicted as reference number 318 in Figures 13-16 can be any mixer capable of mixing the additive and/or proppant with the aqueous solution for preparation of a treatment fluid. The mixer can be a pod mixer including an upwardly facing slinger disc coupled to a downwardly facing impeller. In operation, the mixer can create an open eye within the slurry circulating above the slinger disc. The open eye can have a diameter from about 0.25 to about 8 feet, or from about 0.5 to about 3 feet, or from about 1 foot to about 2 feet. With reference to Figures 12 and 16, the first area (274 in Figure 12 and 374 in Figure 16) is positioned above one side of the slurry ring forming the eye and the second area (276 in Figure 12 and 376 in Figure 16) is positioned above the other side of the slurry ring forming the eye. In accordance with an embodiment, the mixer can also be a mix tank that can be rectangular or square or round, can be up to the size of a road legal trailer (8 feet wide), and the top can be open for directly dumping the additives/packets into the fluid.
[0074] In accordance with some embodiments, Figure 18 shows a perspective view of the system 200 as positioned on a process trailer at a wellsite.
Figure 19 shows an enlarged perspective view of system 200 from that shown in Figure 18, and Figure 20 is an enlarged side view of system 200 from that shown in Figure 18.
The reference numbers in Figures 19 and 20 are the same as those used in describing system 200 with reference to Figures 5-12 as described herein.
[0076] As used herein, the term "fluid flow communication" shall include connection of devices by pipes or other conduits, and shall also include fluid flow communication by gravity. For example, such as when a component passes from a first device to a second device positioned below the first device, even if the inlet of the second device is not physically connected to the outlet of the first device by a pipe or other conduit.
[0076] The foregoing description of the embodiments has been provided for purposes of illustration and description. Example embodiments are provided so that this disclosure will be thorough, and will fully convey the scope to those who are skilled in the art. Numerous specific details are set forth such as examples of specific components, devices, and methods, to provide a thorough understanding of embodiments of the disclosure, but are not intended to be exhaustive or to limit the disclosure. Individual elements or features of a particular embodiment are generally not limited to that particular embodiment, but, where applicable, are interchangeable and can be used in a selected embodiment, even if not specifically shown or described. The same may also be varied in many ways. Such variations are not to be regarded as a departure from the disclosure, and all such modifications are intended to be included within the scope of the disclosure.
[0077] It will be apparent to those skilled in the art that specific details need not be employed, that example embodiments may be embodied in many different forms and that neither should be construed to limit the scope of the disclosure. In some example embodiments, well-known processes, well-known device structures, and well-known technologies are not described in detail. Further, it will be readily apparent to those of skill in the art that in the design, manufacture, and operation of apparatus to achieve that described in the disclosure, variations in apparatus design, construction, condition, erosion of components, gaps between components may be present, for example.
[0078] Although the terms first, second, third, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms may be only used to distinguish one element, component, region, layer or section from another region, layer or section. Terms such as "first,"
"second," and other numerical terms when used herein do not imply a sequence or order unless clearly indicated by the context. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the example embodiments.
[0079] Spatially relative terms, such as "inner," "outer," "beneath,"
"below,"
"lower," "above," "upper," and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. Spatially relative terms may be intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as "below" or "beneath" other elements or features would then be oriented "above" the other elements or features. Thus, the example term "below"
can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
[0080] Although various embodiments have been described with respect to enabling disclosures, it is to be understood the invention is not limited to the disclosed embodiments. Variations and modifications that would occur to one of skill in the art upon reading the specification are also within the scope of the invention, which is defined in the appended claims.
Claims (12)
disposing a plurality of individual packets in a first container packet storage area of a first container, each of the plurality of packets comprising an additive encased within a liner;
passing the plurality of individual packets from the first container packet storage area to a packet shredder positioned below the first container;
metering the individual packets while passing the packets from the first container packet storage area to the packet shredder;
utilizing the packet shredder to at least partially breach the liners of the packets to expose the additive, thereby forming exposed additive;
passing the exposed additive through a first mixer inlet of a mixer;
storing proppant separate from the additive;
delivering the proppant into the mixer;
passing an aqueous solution through a second mixer inlet of the mixer and thus exposing the additive and the proppant to the aqueous solution; and mixing the exposed additive, the proppant, and the aqueous solution in the mixer to form the treatment fluid.
providing proppant to the first container proppant storage area; and passing the proppant to the first mixer inlet of the mixer to become a part of the treatment fluid.
utilizing a silo positioned above the first container and comprising a partition dividing the silo into a silo packet storage area comprising the packets and a silo proppant storage area comprising the proppant;
passing the proppant from the silo proppant storage area to the first container proppant storage area; and passing the packets from the silo packet storage area to the first container packet storage area.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/661,709 | 2015-03-18 | ||
| US14/661,709 US10464071B2 (en) | 2013-09-18 | 2015-03-18 | System and method for preparing a treatment fluid |
| PCT/US2016/019707 WO2016148868A1 (en) | 2015-03-18 | 2016-02-26 | System and method for preparing a treatment fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2979995A1 CA2979995A1 (en) | 2016-09-22 |
| CA2979995C true CA2979995C (en) | 2023-08-29 |
Family
ID=56919274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2979995A Active CA2979995C (en) | 2015-03-18 | 2016-02-26 | System and method for preparing a treatment fluid |
Country Status (4)
| Country | Link |
|---|---|
| AR (1) | AR102845A1 (en) |
| CA (1) | CA2979995C (en) |
| RU (1) | RU2669413C1 (en) |
| WO (1) | WO2016148868A1 (en) |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5190374A (en) * | 1991-04-29 | 1993-03-02 | Halliburton Company | Method and apparatus for continuously mixing well treatment fluids |
| RU2228842C2 (en) * | 2002-08-01 | 2004-05-20 | Ооо "Нтф Унисон" | Mixing device |
| EP1508417A1 (en) * | 2003-07-24 | 2005-02-23 | Services Petroliers Schlumberger | Blending system |
| EP1660231B1 (en) * | 2004-02-13 | 2007-04-18 | Total Petrochemicals Research Feluy | Method and apparatus for preparing and supplying catalyst slurry to a polymerisation reactor |
| US20070201305A1 (en) * | 2006-02-27 | 2007-08-30 | Halliburton Energy Services, Inc. | Method and apparatus for centralized proppant storage and metering |
| US7730966B2 (en) * | 2007-01-31 | 2010-06-08 | M-I L.L.C. | High density slurry |
| NO333673B1 (en) * | 2007-04-16 | 2013-08-05 | Matheus Christensen | Integrated unit and method for processing cuttings and use of the integrated unit |
| US8834012B2 (en) * | 2009-09-11 | 2014-09-16 | Halliburton Energy Services, Inc. | Electric or natural gas fired small footprint fracturing fluid blending and pumping equipment |
| US8672029B2 (en) * | 2009-12-30 | 2014-03-18 | Schlumberger Technology Corporation | System for reducing foam in mixing operations |
-
2015
- 2015-11-26 AR ARP150103895A patent/AR102845A1/en unknown
-
2016
- 2016-02-26 CA CA2979995A patent/CA2979995C/en active Active
- 2016-02-26 WO PCT/US2016/019707 patent/WO2016148868A1/en not_active Ceased
- 2016-02-26 RU RU2017134370A patent/RU2669413C1/en active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2669413C1 (en) | 2018-10-11 |
| AR102845A1 (en) | 2017-03-29 |
| WO2016148868A1 (en) | 2016-09-22 |
| CA2979995A1 (en) | 2016-09-22 |
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