CA2969363A1 - Procede et appareil pour le traitement d'hydrocarbures - Google Patents
Procede et appareil pour le traitement d'hydrocarbures Download PDFInfo
- Publication number
- CA2969363A1 CA2969363A1 CA2969363A CA2969363A CA2969363A1 CA 2969363 A1 CA2969363 A1 CA 2969363A1 CA 2969363 A CA2969363 A CA 2969363A CA 2969363 A CA2969363 A CA 2969363A CA 2969363 A1 CA2969363 A1 CA 2969363A1
- Authority
- CA
- Canada
- Prior art keywords
- section
- voltage
- hydrocarbons
- current value
- electrodes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 210
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 208
- 238000000034 method Methods 0.000 title claims abstract description 121
- 238000012545 processing Methods 0.000 title claims abstract description 48
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000005864 Sulphur Substances 0.000 claims abstract description 32
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 29
- 230000009467 reduction Effects 0.000 claims abstract description 27
- 238000003860 storage Methods 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000001737 promoting effect Effects 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 71
- 239000004215 Carbon black (E152) Substances 0.000 claims description 61
- 239000011159 matrix material Substances 0.000 claims description 50
- 241000894007 species Species 0.000 claims description 35
- 239000008186 active pharmaceutical agent Substances 0.000 claims description 34
- 230000002441 reversible effect Effects 0.000 claims description 24
- 230000000694 effects Effects 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 24
- 238000011065 in-situ storage Methods 0.000 abstract description 10
- 238000007254 oxidation reaction Methods 0.000 abstract description 10
- 230000003647 oxidation Effects 0.000 abstract description 8
- 239000003921 oil Substances 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- 230000008569 process Effects 0.000 description 29
- 239000010779 crude oil Substances 0.000 description 26
- 238000000605 extraction Methods 0.000 description 25
- 150000003254 radicals Chemical class 0.000 description 16
- 238000011282 treatment Methods 0.000 description 16
- 230000007423 decrease Effects 0.000 description 11
- 239000000295 fuel oil Substances 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 238000013459 approach Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- -1 light oils Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000003027 oil sand Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000001960 triggered effect Effects 0.000 description 2
- 238000010794 Cyclic Steam Stimulation Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010796 Steam-assisted gravity drainage Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- PLZFHNWCKKPCMI-UHFFFAOYSA-N cadmium copper Chemical compound [Cu].[Cd] PLZFHNWCKKPCMI-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005370 electroosmosis Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G15/00—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
- C10G15/08—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs by electric means or by electromagnetic or mechanical vibrations
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
- C10G32/02—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/2401—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection by means of electricity
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electromagnetism (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fluid Mechanics (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Microbiology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Plasma Technology (AREA)
Abstract
La présente invention concerne un procédé et un appareil qui décomposent des composés, en particulier des hydrocarbures, par oxydation. Les composés peuvent encore être in situ ou se trouver dans un emplacement fabriqué par l'homme comme un réservoir de stockage ou une conduite. Le procédé pour le traitement d'hydrocarbures au sein d'un lieu consiste à : a) introduire deux électrodes dans le lieu contenant les hydrocarbures ; b) fournir des connexions entre une source de tension et les électrodes ; c) appliquer une tension d'une première polarité aux connexions pendant une première période de temps, sous le contrôle d'un régulateur de tension ; d) appliquer une tension d'une seconde polarité inversée aux connexions pendant une seconde période de temps, sous le contrôle du régulateur de tension ; e) répéter les étapes c) et d) ; les étapes c), d) et e) favorisant la production de radicaux libres, ce qui favorise une réduction de la longueur de la chaîne de carbone et/ou une réduction de la teneur en soufre et/ou une réduction de la teneur en métaux lourds des hydrocarbures.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1421261.7 | 2014-12-01 | ||
| GBGB1421261.7A GB201421261D0 (en) | 2014-12-01 | 2014-12-01 | Improvements in and relating to the processing of matrices and/or the contents of matrices |
| PCT/EP2015/078242 WO2016087459A1 (fr) | 2014-12-01 | 2015-12-01 | Procédé et appareil pour le traitement d'hydrocarbures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2969363A1 true CA2969363A1 (fr) | 2016-06-09 |
Family
ID=52349698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2969363A Abandoned CA2969363A1 (fr) | 2014-12-01 | 2015-12-01 | Procede et appareil pour le traitement d'hydrocarbures |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20170306245A1 (fr) |
| EP (1) | EP3227410A1 (fr) |
| CA (1) | CA2969363A1 (fr) |
| GB (1) | GB201421261D0 (fr) |
| RU (1) | RU2017123062A (fr) |
| WO (1) | WO2016087459A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11084992B2 (en) * | 2016-06-02 | 2021-08-10 | Saudi Arabian Oil Company | Systems and methods for upgrading heavy oils |
| WO2019018225A1 (fr) | 2017-07-17 | 2019-01-24 | Saudi Arabian Oil Company | Systèmes et procédés pour le traitement d'huiles lourdes |
| GB2570922B (en) * | 2018-02-12 | 2021-07-14 | A Taylor John | Purification of hydrocarbons |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1779402A (en) * | 1923-11-21 | 1930-10-21 | C & C Developing Company | Art of manufacturing useful products from hydrocarbons |
| US5012868A (en) * | 1989-03-14 | 1991-05-07 | Uentech Corporation | Corrosion inhibition method and apparatus for downhole electrical heating in mineral fluid wells |
| GB2336602B (en) * | 1995-06-27 | 2000-01-12 | Harden Technolgies Ltd | Method of effecting flow in porous ground |
| US6199634B1 (en) * | 1998-08-27 | 2001-03-13 | Viatchelav Ivanovich Selyakov | Method and apparatus for controlling the permeability of mineral bearing earth formations |
| US7004251B2 (en) * | 2001-04-24 | 2006-02-28 | Shell Oil Company | In situ thermal processing and remediation of an oil shale formation |
| GB2434800B (en) * | 2004-12-15 | 2009-07-29 | Univ Temple | Method for reduction of crude oil viscosity |
| US9447657B2 (en) * | 2010-03-30 | 2016-09-20 | The Lubrizol Corporation | System and method for scale inhibition |
-
2014
- 2014-12-01 GB GBGB1421261.7A patent/GB201421261D0/en not_active Ceased
-
2015
- 2015-12-01 US US15/532,014 patent/US20170306245A1/en not_active Abandoned
- 2015-12-01 RU RU2017123062A patent/RU2017123062A/ru not_active Application Discontinuation
- 2015-12-01 CA CA2969363A patent/CA2969363A1/fr not_active Abandoned
- 2015-12-01 EP EP15805139.1A patent/EP3227410A1/fr not_active Withdrawn
- 2015-12-01 WO PCT/EP2015/078242 patent/WO2016087459A1/fr active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| GB201421261D0 (en) | 2015-01-14 |
| US20170306245A1 (en) | 2017-10-26 |
| WO2016087459A1 (fr) | 2016-06-09 |
| RU2017123062A (ru) | 2019-01-10 |
| RU2017123062A3 (fr) | 2019-03-05 |
| EP3227410A1 (fr) | 2017-10-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20210831 |
|
| FZDE | Discontinued |
Effective date: 20210831 |