CA2911345C - Biological load for bioreactor - Google Patents
Biological load for bioreactor Download PDFInfo
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- CA2911345C CA2911345C CA2911345A CA2911345A CA2911345C CA 2911345 C CA2911345 C CA 2911345C CA 2911345 A CA2911345 A CA 2911345A CA 2911345 A CA2911345 A CA 2911345A CA 2911345 C CA2911345 C CA 2911345C
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- Prior art keywords
- biological load
- bioreactor
- layer
- wastewater
- treatment
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- 229920000642 polymer Polymers 0.000 claims abstract description 8
- 230000007704 transition Effects 0.000 claims abstract description 8
- 239000004743 Polypropylene Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 5
- -1 polypropylene Polymers 0.000 claims abstract description 5
- 229920001155 polypropylene Polymers 0.000 claims abstract description 5
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 4
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 4
- 239000002351 wastewater Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 6
- 238000004065 wastewater treatment Methods 0.000 abstract description 8
- 239000010840 domestic wastewater Substances 0.000 abstract description 2
- 241001481828 Glyptocephalus cynoglossus Species 0.000 abstract 1
- 239000002028 Biomass Substances 0.000 description 10
- 244000005700 microbiome Species 0.000 description 9
- 238000005273 aeration Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 238000005276 aerator Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 150000002826 nitrites Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 229920006051 CapronĀ® Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 208000018747 cerebellar ataxia with neuropathy and bilateral vestibular areflexia syndrome Diseases 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Biological Treatment Of Waste Water (AREA)
Abstract
The present invention relates to the field of wastewater treatment witch deals with the biological load for bioreactors. The biological load for the bioreactor having a cylindrical shaped housing with an inner surface and an outer surface, said housing comprises of an inner layer having a diameter placed at said inner surface made of a low-density polyethylene with a polymorphic structure; a middle layer to form a supporting frame of the biological load having a gradient porous transition into an outer layer; said outer layer formed by a canvas of polymer filaments made of polypropylene fiber, said canvas formed as a plurality of rowlock arch shaped distributed over said outer surface. The canvas can be used as a component of deep biochemical and biological treatment for domestic wastewater.
Description
TITLE: BIOLOGICAL LOAD FOR BIOREACTOR
INVENTOR: Mikhail PUKEMO
FIELD OF THE INVENTION:
[01] The present invention in general relates to the field of wastewater treatment, and in particular, it deals with the biological load for bioreactors which contain polymer filaments formed into a canvas with many uniformly distributed loops over its surroundings.
BACKGROUND OF THE INVENTION:
INVENTOR: Mikhail PUKEMO
FIELD OF THE INVENTION:
[01] The present invention in general relates to the field of wastewater treatment, and in particular, it deals with the biological load for bioreactors which contain polymer filaments formed into a canvas with many uniformly distributed loops over its surroundings.
BACKGROUND OF THE INVENTION:
[02] The prior art discloses the biological load for bioreactors which contains polymer filaments with Capron (trade-mark) line and stainless steel wire as a base.
The prior arts have too many drawbacks such as short service life. Corrosion which happens in bioload construction and the design of the bioload construction are the main reasons for the short service life in the prior arts.
The prior arts have too many drawbacks such as short service life. Corrosion which happens in bioload construction and the design of the bioload construction are the main reasons for the short service life in the prior arts.
[03] In prior arts problem caused by low quality biological load and additionally with the absence of a rigid frame which leads handling biological load with difficulty.
[04] There is a need for a rigid biological load for bioreactors which has a specific construction that is corrosion resistance and can handle biological load.
SUMMARY OF THE INVENTION
SUMMARY OF THE INVENTION
[05] The present invention is a biological load for biological filter for wastewater treatment. The invention is a type of bioload, which contains uniformly distributed loops of polymer filaments formed over the entire surface of a canvas. The canvas is adapted to be placed inside a cylindrical space with the loops appearing on the outside of the cylinder. This special canvas is used in biochemical and biological treatment of domestic wastewater and it is similar in composition to them.
[06] The biological load - the base for the biological filter, which is a part of the bioreactor, in which wastewater is filtered through the biological load, is coated by biological film (biofilm) formed by colonies of microorganisms.
[07] The main purpose of the present invention is to propose a biological load for bioreactors which will at minimum offset, to solve the prior arts drawbacks and also it provides an improvement on the technical specifications of the biological load, namely: an improvement in the ratio between the surface area and the volume of the biological load, an increase in the corrosion resistance, an increase in the structural integrity of the frame of the biological load, and an improvement in the practicability of the assembly and maintenance of the biological load.
[08] For such an achievement, the biological load for bioreactors has an additional inner layer made of low-density polyethylene with a porous structure.
[09] Due to these advantageous characteristics, it is possible to aerate the bulk biomass to the layers both from inside and outside with aeration nozzles or hydro-aerators ejecting pressurized air into the water. Hydro-aerators enable airlifting with additional bubble grinding through the porous walls of the base (the middle layer) and removal of biomass from the biological load. Additionally, with these characteristics, the inner layer promotes the formation and retention of a multilayer biofilm and the development of aerobic and anaerobic biological forms within the space of this layer.
[10] The biological load for bioreactors also have a middle layer which forms the supporting frame and has a gradient porous transition into an outer layer formed from a canvas of polymeric filaments.
[11] It is possible to achieve the desired strength in the structure of the present invention by increasing the density of the layer and by decreasing, to a certain extent, the permeability of the flow after passing the outer layer, to disperse large amount of air bubbles and to create a base for the formation of the next layer.
[12] The outer layer of the bioload is formed from a canvas of polymeric filaments, made from polypropylene fiber.
[13] This bioload allows for an increase in the apparent viscosity of the water flow, which helps to capture more of suspended nutrients.
[14] In the preferred embodiment of the present invention, the inner layer of the bioload has a porosity of up to 71%. This provides an optimal condition for the aeration of the main biomass.
[15] In the preferred embodiment of the present invention, the pores of the inner layer are uniform in size, and preferably are 1.5 mm is size. This size provides an optimum condition for the aeration of the main biomass.
[16] In the preferred embodiment of the present invention, the surface area of the space between the inner and outer layers is not less than 750 m2/m3. This provides an optimal condition for the aeration of the main biomass.
[17] In another embodiment of the present invention, the middle layer possesses a diagonal thickness ranging from 0.5 to 2% of the exterior diameter of the inner layer to provide certain rigidity to the frame.
[18] In another embodiment of the present invention, the middle layer has a varying porous layer, having a smooth transition into the third outer layer. This provides an optimal condition for the dispersion of large air bubbles.
[19] In another embodiment of the present invention, the middle layer is created possessing a ratio between the sizes of the pore channels of the inner and outer boundary equal to two. This allows for having different types of middle layer.
[20] In another embodiment of the present invention, the outer layer has a specific surface area of no less than 1220 m2/m3. This makes it possible to build a multilayer biofilm with a large amount of biomass bridges and to capture a greater amount of suspended nutrients.
[21] In another embodiment of the present invention, the outer layer possesses a density no less than 95%. This provides an optimal condition for biomass growth.
[22] Other objects, features, and advantages of the present invention will be readily appreciated from the following description. The description makes reference to the accompanying drawings, which are provided for illustration of the preferred embodiment. However, such embodiments do not represent the full scope of the invention.
BRIEF DESCRIPTION OF THE DRAWINGS:
BRIEF DESCRIPTION OF THE DRAWINGS:
[23] Embodiments herein will hereinafter be described in conjunction with the appended drawings provided to illustrate and not to limit the scope of the claims, wherein like designations denote like elements, and in which:
FIG. 1 shows a two dimensional view of the biological load for bioreactors according to the present invention FIG. 2 shows a schematic cut-away view through the line A-A in FIG. 1;
FIG. 3 shows microscopic view of the polymeric filament used in the outer layer of the present invention;
FIG. 4 shows a typical wastewater treatment with the biological load of the present invention;
FIG. 5 shows a schematic diagram of a wastewater treatment plant with the present invention; and FIG. 6 shows the operational workflow of the present invention in a treatment plant.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS:
FIG. 1 shows a two dimensional view of the biological load for bioreactors according to the present invention FIG. 2 shows a schematic cut-away view through the line A-A in FIG. 1;
FIG. 3 shows microscopic view of the polymeric filament used in the outer layer of the present invention;
FIG. 4 shows a typical wastewater treatment with the biological load of the present invention;
FIG. 5 shows a schematic diagram of a wastewater treatment plant with the present invention; and FIG. 6 shows the operational workflow of the present invention in a treatment plant.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS:
[24] FIGs. 1 and 2 schematically show the appearance of the biological load 10 for bioreactors according to the present invention. As shown in FIGs. 1 and 2, the biological load 10 for bioreactors includes three layers: inner layer 1, middle layer 2 and outer layer 3.
[25] Again as shown in FIGs. 1 and 2, a biological load 10 for a bioreactor having a cylindrical shaped housing with an inner surface 21 and an outer surface 22, the housing comprises of an inner layer 1 having a diameter and it placed at the inner surface 21 made of a low-density polyethylene with a polymorphic structure; a middle layer 2 to form a supporting frame of the biological load 10 having a gradient porous transition into an outer layer 3; and the outer layer 3 formed by a canvas of polymer filaments 40 made of polypropylene fiber, the canvas formed as a plurality of rowlock arch shaped 40 distributed over the outer surface 22.
[26] The inner layer 1 promotes the formation and retention of a multilayer biofilm and the development of aerobic and anaerobic biological forms within the space of the layer.
[27] The inner layer 1 is made of high-density polyethylene and has a porous polymorphic structure. The middle layer 2 forms the supporting frame of the structure and has a gradient porous transition into the outer layer.
[28] The outer layer 3 is formed from a canvas of polymer filaments as shown in FIGs.
1-3. The polymer filaments are formed into a canvas of pluralities of uniformly distributed loops 40 over its surrounding. The canvass is adapted for placement inside a cylindrical space with the loops 40 appearing on the outside of the cylinder. The outer layer 3 is made of polypropylene fiber. The design and construction of the outer layer 3 helps to capture more of suspended nutrients in the waste water treatment.
1-3. The polymer filaments are formed into a canvas of pluralities of uniformly distributed loops 40 over its surrounding. The canvass is adapted for placement inside a cylindrical space with the loops 40 appearing on the outside of the cylinder. The outer layer 3 is made of polypropylene fiber. The design and construction of the outer layer 3 helps to capture more of suspended nutrients in the waste water treatment.
[29] In one embodiment of the present invention, the inner layer 1 is formed with a porosity of up to 71%, with linear values for the size of the pores up to 1.5 mm, and with the surface area of the space between the inner 1 and outer layers 3 is at least 750 m2/m3.
[30] The middle layer 2 is formed with a diagonal thickness ranging from 0.5 to 2% of the exterior diameter of the inner layer, with a gradient porous transition into a third outer layer 3, and having a ratio between the sizes of the pore channels of the inner and outer boundary equal to two.
[31] The outer layer 3 has a specific surface area of at least 1220 m2/m3 and a density of at least 95%.
IMPLEMENTATION OF THE PRESENT INVENTION
IMPLEMENTATION OF THE PRESENT INVENTION
[32] The implementation of biological load for bioreactors as an example is shown which is describe one embodiment of the present invention and does not limit the application of the present invention. The usage of bio-filter in an Alta Air Master treatment plant is provided as an example of the utility model.
[33] FIG. 4 shows a typical wastewater treatment with the biological load of the present invention. As shown in FIG. 4, the biological load 10 is located in the tank which an aerator mixes air with water. The mixture of air and water contact with inner and outer surface of the biological load during the circulation. The loops designed in the outer surface of the biological load 10 helps to capture more of suspended nutrients in the waste water treatment. Because of the design of the outer surface of the biological load 10, the colonies of microorganisms, which are the basis of the bio-filter, begin to multiply and colonize the space formed by the loops and canvas of the biological load 10.
[34] During the circulation, because of the specific design of the biological load, the maximum contact between the biological load and air-water mixture happens. By the time, the colonies of microorganisms grow in the spaces between the loops in the outer surface and by circulation connect to each other. The heavy colonies fall down the tank.
[35] As shown in FIG. 5, the plant has a Primary Sludge Settling Tank 5, a Aerotank Bio-filter 6, a Secondary Sludge Settling Tank 7 and a Pure Water Chamber 8 that are connected in-line.
[36] FIG. 6 shows the operational steps of the present invention in a treatment plant.
Step Al. The biological load for bioreactors of the present invention are placed in the Aerotank Bio-filter [[6]], specifically in the biological filter of the bioreactor.
Step Al. The biological load for bioreactors of the present invention are placed in the Aerotank Bio-filter [[6]], specifically in the biological filter of the bioreactor.
[37] Step A2. Colonies of microorganisms, which are the basis of the bio-filter, begin to multiply and colonize the space formed by the loops and canvas of the biological load for bioreactors.
[38] Step A3. Wastewater is fed into the first chamber which acts as a primary sludge settling tank and a receiver-accumulator operating as a system recycling activated sludge and nitrified substances in the chamber. Nitrates and nitrites received from the wastewater chamber by the recirculation system are anaerobically biodegraded by microorganisms into oxygen, which they need for life, and nitrogen, which is released as a gas.
[39] Step A4. Next, the wastewater flows for purification into bioreactor, which in this case, is both an aeration tank and a bio-filter. In this tank, microorganism biocenoses successfully exist in several states:
- immobilized on submerged loading material biomass, - detached free-floating microorganisms.
- immobilized on submerged loading material biomass, - detached free-floating microorganisms.
[40] Step A5. The bioreactor is supplied with air, and the microorganisms begin to oxidize organic substances in the wastewater, thereby producing the energy they need to continue their lifecycle and also synthesizing their biomass. When all the organics are digested by the microorganisms, autotrophs start working instead of the heterotrophs, nitrifying the wastewater ammonia nitrogen to nitrites and nitrates in the aerobic conditions of the bioreactor.
[41] Step A6. If repair, diagnostics, or replacement of bioreactor elements with the biological load for bioreactors is necessary, it is sufficient to pull out the desired element of the biological load out of the bioreactor.
INDUSTRIAL APPLICABILITY
INDUSTRIAL APPLICABILITY
[42] The presented biological load for bioreactors has a clear purpose, can be implemented by a specialist in practice, and the implementation ensures realization of the claimed purpose.
[43] The prototype biological load for bioreactors was manufactured by an automated rotary thermoforming and mechanical shuttle hook-spoke-binding.
[44] The biological load for bioreactors is a composite resin pipe with specified functional three-layer structure made by an optimized process of thermoforming and knitting, with geometric, physical and mechanical characteristics listed in the below table.
No. Characteristics Value 1 Overall outer diameter, mm 123 3 2 Overall inner diameter, mm 80 2 3 Length, mm 1000 10 4 Active surface area of biological load, 6.42 no less than, m2 Specific surface area of biological load, 1925 no less than, m2/m3 6 Bend strength, kg/cm2 127 20 7 Tensile strength, kg/cm2 115 20 8 Weight of biological load, g 730.8 20.5 9 Weight of first and second layers, g 552.2 20.0 Weight of third layer, g 177.6 0.5 11 Mean theoretical density of first and second layers, % 71 1.5 12 Mean theoretical density of third layer, % 97 1.5
No. Characteristics Value 1 Overall outer diameter, mm 123 3 2 Overall inner diameter, mm 80 2 3 Length, mm 1000 10 4 Active surface area of biological load, 6.42 no less than, m2 Specific surface area of biological load, 1925 no less than, m2/m3 6 Bend strength, kg/cm2 127 20 7 Tensile strength, kg/cm2 115 20 8 Weight of biological load, g 730.8 20.5 9 Weight of first and second layers, g 552.2 20.0 Weight of third layer, g 177.6 0.5 11 Mean theoretical density of first and second layers, % 71 1.5 12 Mean theoretical density of third layer, % 97 1.5
[45] Trial operation of the utility model has shown that the design of the biological load for bioreactors provides:
- improved efficiency of the biofilter due to rapid biomass growth, - reduced overall dimensions of treatment facilities.
- improved efficiency of the biofilter due to rapid biomass growth, - reduced overall dimensions of treatment facilities.
[46] Thus, by making the biological load for bioreactors consisting of three layers with the above parameters, the technical result is achieved, namely the improved technical specifications of the biological load.
- improved ratio between the surface area and the occupied volume of the biological load, - increased corrosion resistance, - increased structural integrity of the frame of the biological load, - improved practicability of the assembly and maintenance of the biological load.
- improved ratio between the surface area and the occupied volume of the biological load, - increased corrosion resistance, - increased structural integrity of the frame of the biological load, - improved practicability of the assembly and maintenance of the biological load.
[47] Thus, it is recommended to use the proposed biological load for bioreactors for installation, both in flow aeration tanks and in aeration tanks of variable action, in stations for deep biochemical and biological treatment of wastewater from residential complexes, hotels, guesthouses, resorts, building complexes, cottage communities, neighborhoods, towns, etc.
[48] The foregoing is considered as illustrative only of the principles of the invention.
Further, since numerous modifications and changes will readily occur to those skilled in the art, it is not desired to limit the invention to the exact construction and operation shown and described, and accordingly, all suitable modifications and equivalents may be resorted to, falling within the scope of the invention.
Further, since numerous modifications and changes will readily occur to those skilled in the art, it is not desired to limit the invention to the exact construction and operation shown and described, and accordingly, all suitable modifications and equivalents may be resorted to, falling within the scope of the invention.
[49] With respect to the above description, it is to be realized that the optimum relationships for the parts of the invention in regard to size, shape, form, materials, function and manner of operation, assembly and use are deemed readily apparent and obvious to those skilled in the art, and all equivalent relationships to those illustrated in the drawings and described in the specification are intended to be encompassed by the present invention.
Claims (8)
1. A biological load for a bioreactor for the treatment of wastewater having a cylindrical shaped housing with an inner surface and an outer surface, said housing comprising of, a. an inner layer having a diameter, made of a low-density polyethylene and placed at said inner surface with a polymorphic structure, wherein said inner layer is porous and has a plurality of pore channels;
b. a middle layer to form a supporting frame of the biological load having a gradient porous transition into an outer layer;
c. said outer layer formed by a canvas of polymer filaments made of polypropylene fiber, said canvas formed as a plurality of rowlock arch shapes distributed over said outer surface.
b. a middle layer to form a supporting frame of the biological load having a gradient porous transition into an outer layer;
c. said outer layer formed by a canvas of polymer filaments made of polypropylene fiber, said canvas formed as a plurality of rowlock arch shapes distributed over said outer surface.
2. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein said inner layer has a porosity of up to 71%.
3. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein said inner layer further has a linear value for the size of the pore channels up to 1.5 mm.
4. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein the middle layer has a surface area of at least 750 m2/m3.
5. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein said middle layer has a diagonal thickness ranging from 0.5 to 2% of the diameter of the inner layer.
6. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein the gradient porous transition of said middle layer between its inner boundary and its outer boundary is equal to two.
7. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein said outer layer has a specific surface area of at least 1220 m2/m3.
8. The biological load for a bioreactor for the treatment of wastewater of claim 1, wherein said outer layer has a density of at least 95%.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2014144740 | 2014-11-07 | ||
RU2014144740 | 2014-11-07 | ||
US14/933,284 US20160130545A1 (en) | 2014-11-07 | 2015-11-05 | Biological load for bioreactor |
US14933284 | 2015-11-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2911345A1 CA2911345A1 (en) | 2016-05-07 |
CA2911345C true CA2911345C (en) | 2018-09-18 |
Family
ID=55867704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2911345A Active CA2911345C (en) | 2014-11-07 | 2015-11-06 | Biological load for bioreactor |
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Country | Link |
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CA (1) | CA2911345C (en) |
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- 2015-11-06 CA CA2911345A patent/CA2911345C/en active Active
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