CA2897408C - Barrier layer for corrosion protection in electrochemical devices - Google Patents

Abstract

The invention is directed to a barrier layer for corrosion protection in electrochemical devices, e.g. carbon based gas diffusion layers (GDLs) in electrochemical devices, comprising electrically conductive ceramic material and a non-ionomeric polymer binder. The electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm, preferably > 1 S/cm in air atmosphere (as detected by the powder method) and is selected from the group of precious metal and/or base metal containing oxides, carbides, nitrides, borides and mixtures and combinations thereof. Membrane-electrode assemblies (MEAs), catalyst-coated membranes (CCMs), gas diffusion electrodes (GDEs) and gas diffusion layers (GDLs) comprising the barrier layer of the invention show improved corrosion resistance, preferably against carbon corrosion; particularly in start-up/shutdown cycles and fuel starvation situations of PEM fuel cells.

Description

Barrier layer for corrosion protection in electrochemical devices Field of invention The present invention is directed to the field of electrochemistry and fuel cells. This invention provides a barrier layer for corrosion protection in electrochemical devices, e.g. for carbon-based gas diffusion layers (GDLs) or current collectors, in electrochemical devices such as polymer electrolyte fuel cells ("PEMFC") or PEM electrolyzer cells. The barrier layer of the pre-sent invention finds use in PEMFC components such as membrane electrode assemblies ("MEAs"), catalyst-coated membranes ("CCMs"), gas diffusion electrodes ("GDEs") and gas diffusion layers ("GDLs"). More specifically, the barrier layer disclosed in the present invention provides improved resistance to carbon corrosion of carbon-based GDLs and leads to a better stability in start-up/shut down cycles and fuel starvation situations in PEMFC.
Background of the invention Fuel cells (FCs) are power generating electrochemical devices used or commercially foreseen to be used for a wide range of different applications including, for instance, automotive drive trains, stationary units for residen-tial heating, embarked auxiliary power units, portable electronic equipments and remote or portable back-up units. In principle, a fuel cell converts the chemical energy of hydrogen (H2 gas) or another fuel into electrical current and heat; water is produced as by-product in this electrochemical reaction.
During operation of the PEM fuel cell, reduction of oxygen takes place at the cathode and oxidation of hydrogen (or other fuel) takes place at the anode of the fuel cell. Finally, water, electric power and heat are produced.
A PEM fuel cell (PEMFC) is, more particularly, a fuel cell comprising a solid polymer-electrolyte membrane, sometimes also called proton-exchange membrane (hereafter referred to as "membrane" for sake of con-venience) such as a proton-conducting perfluorosulfonic acid membrane (commercially available under the name Nafion ) or a hydrocarbon acid membrane.

2 Examples of PEMFCs are hydrogen PEMFCs, reformed-hydrogen PEM-FCs and direct methanol PEMFCs (frequently abbreviated as "DMFC").
A PEMFC is built up as a stack of so-called membrane-electrode-assemblies (MEAs) and bipolar flowfield plates. The membrane electrode assembly (MEA) in turn is a key component of the PEMFC stack and has a significant influence on its end-use characteristics. A general, simplified structure of a MEA is shown in Figure 1. A membrane-electrode assembly is based on a multilayer structure and typically comprises 5 layers. An ion-omer membrane (6) in the center, a cathode gas diffusion layer (1) (here-inafter called "cathode-GDL"), an cathode catalyst layer (5), an anode cata-lyst layer (5') and a anode gas diffusion layer (1') (hereinafter called "an-ode-GDL").
A "catalyst-coated membrane" (hereinafter abbreviated "CCM") com-prises an ionomer membrane (6) that is provided on both sides with the catalytically active layers, i.e. the cathode catalyst layer (5) and the anode catalyst layer (5'). Because the CCM comprises basically three layers (anode catalyst layer, ionomer membrane and cathode catalyst layer), it is often referred to as a "three-layer MEA."
"Gas diffusion layers" ("GDLs"), sometimes referred to as gas diffu-sion substrates or backings, are placed onto the anode and cathode layers of the CCM in order to bring the gaseous reaction media (e.g., hydrogen and air) to the catalytically active layers and, at the same time, to establish an electrical contact. GDLs may be coated with a micro-porous layer in order to improve the contact to the electrode.
"Gas diffusion electrodes" (GDEs") are GDLs coated with a catalyst layer on the side facing the ionomer membrane. GDEs are often referred to as catalyst-coated GDLs or "catalyst-coated backings" (abbreviated "CCBs").
Generally, a MEA can be manufactured by combining a CCM with two GDLs (on the anode and the cathode side) or, alternatively, by combining an ionomer membrane with two gas diffusion electrodes (GDEs) at the an-

3 ode and the cathode sides. In both cases, a five-layer MEA product is ob-tained.
PEM electrolysers generally have a similar structure to a PEM fuel cell, but they operate in a different way. Compared to a regular PEM fuel cell, the flow of current and the electrodes are reversed in a PEM electrolyser, so that decomposition of water takes place. The liberation of oxygen occurs at the anode ("oxygen evolution reaction" or "OER" for short) and the reduc-tion of protons (H ), which pass through the polymer electrolyte membrane, takes place at the cathode ("hydrogen evolution reaction" or "HER" for short). The result is that water is decomposed into hydrogen and oxygen with the aid of electric current.
A membrane-electrode-assembly ("MEA") for a PEM water electrolys-er (hereinafter also referred to as "electrolysis MEA") generally contains a polymer electrolyte membrane (for example NafionC) from DuPont) which is arranged in a sandwich construction between two electrodes and two po-rous gas diffusion layers (GDLs) which are each mounted on the two sides of the electrodes. Generally, due to corrosion effects, carbon-based GDL
materials cannot be used on the anode side of electrolysis MEAs.
In the following the technology of regular PEM fuel cells is further de-scribed. In the anode layer, an appropriate electrocatalyst, generally a plat-inum or a platinum alloy electrocatalyst, causes the oxidation of the fuel (for instance hydrogen or methanol) generating, notably, positive hydrogen ions (protons) and negatively charged electrons. The membrane allows only the positively charged hydrogen ions to pass through it in order to reach the cathode layer, whereas the negatively charged electrons travel along an external circuit connecting the anode with the cathode, thus creating an electrical current.
The gas diffusion layers (GDLs) usually comprise relatively thick po-rous layers and are located between the electrode layers and the flow field .. plates. Primary purpose of a GDL is to assure a better access of the reactant gases to the electrode layers and an efficient removal of water (in either liquid or vapor form) from the fuel cell, to enhance the electrical conductivi-

4 ty of the fuel cell assuring a better electrical contact between the electrode layers and the flow-field plates and last but not least to provide the me-chanical strength necessary to preserve the structural integrity of the elec-trode layers.
The GDL usually comprises carbon paper or carbon woven cloth, possibly treated with variable amounts of per- or partly-fluorinated poly-mers in order to properly control its electrical conductivity, mechanical strength, hydrophobicity, porosity and mass-transport properties.
It is known that during operation of electrochemical cells such as fuel cells, the cells of the stack and the membrane-electrode-assembly (MEA) incorporated therein can be exposed to high potentials (>1.2 V), both on the cathode and the anode side.
High potentials on the cathode typically occur upon restart of the fuel cell after the cell has been shut down for a prolonged period of time and hydrogen is introduced at the anode side while air is present on both sides of the MEA (referred to as "air/air starts"). The mechanism leading to high potentials in this case is commonly known as "current reverse mechanism".
High potentials on the anode side may occur if fuel is delivered insuf-ficiently to the electrode while demanding a certain power to the cell, which drives the cell into reverse voltage. This case is commonly known as "fuel starvation" or "cell reversal".
The oxygen side of the cell can also be exposed to high potentials for prolonged periods when the fuel cell is used in the so-called "reversible mode". Hereby, hydrogen and oxygen are generated by supplying water to the cell while at the same time applying a voltage difference through an external load, which is sufficiently high to cause water electrolysis.
Under such high potential events or conditions, carbon-containing electrodes (e.g. carbon-supported electrocatalysts) of the fuel cell undergo degradation due to corrosion of the carbon support material.
To reduce such degradation phenomena, electrocatalysts based on graphitized carbon black may be employed and/or catalysts able to facilitate water oxidation are added to the electrodes so that the reaction current is sustained by water oxidation rather than by carbon corrosion (e.g. ref. to US2009/0162725 Al and US2009/0068541 Al). However, this strategy mitigates the problem but does not completely prevent carbon corrosion.

5 W02007/119134A1 discloses a PEMFC, in which two separate layers are implemented on the anode and the cathode side, which contain a water-electrolysis catalyst as so-called "fuel deficiency countermeasure". Prefera-bly such water electrolysis catalysts are based on iridium and/or ruthenium oxides. The two separate layers comprise ionomeric binder materials.
EP 2475034 discloses improved MEAs for PEMFC, which are based on electrodes containing a mixture of Pt-based electrocatalysts with electrocat-alysts comprising an iridium oxide component and ionomeric binder.
The use of Jr-based catalyst materials is further reported in US6,936,370 and W02011/021034.
An alternative approach to reduce the problem of carbon corrosion is to substitute carbon-based electrocatalysts in the catalyst layer with car-bon-free electrocatalysts. These materials generally comprise catalyst parti-cles (usually platinum or platinum alloys) finely dispersed on corrosion-stable electrically conductive support materials. Typically, conductive ce-ramic materials such as metal oxides, nitrides or carbides are used as cata-lyst support materials.
In the patent literature a broad number of electrically conductive ce-ramic materials have been disclosed for use as conductive additives in cata-lyst layers (e.g. ref to US7,767,330 B2).
It was found that, even when such corrosion stable catalysts are used, still the MEA performance is deteriorated by exposure to high voltag-es. This occurs as the gas diffusion layers (GDL), which are generally part of a 5-layer MEA, are typically also carbon-based, and thus subject to corro-sion. In simple words, if the electrocatalyst layer is stable enough, the GDL
becomes the "weak part" of the MEA in terms of corrosion.

6 Such corrosion of the GDL was detected by the presence of carbon dioxide (CO2) in the outlet gas of the cell, which obviously cannot originate from the electrodes in case carbon-free electrocatalysts are employed.
Further, GDL corrosion was reported and demonstrated also by atom-ic force microscopy, Hg-intrusion porosimetry, electron microscopy and performance deterioration. Thus, corrosion-stable electrodes (i.e. catalyst layers) mitigate but do not solve the problem of MEA deterioration under high potential events as long as carbon-based GDLs are employed in said M EAs.
Various proposals are made to overcome this problem. US patent U57,909,969 discloses coating of gas diffusion layers (GDLs) with a micro-protective layer to increase corrosion stability when the cell is operated in the water electrolysis mode. The micro-protective layer is tightly adhered to the GDL and consists essentially of catalysts for catalyzing active oxygen species to become non-active oxygen gas and corrosion-resistant metallic powders for assisting said catalysts. US7,909,969 is silent in regard to the chemical nature of the active catalysts employed; Ti and Ti alloys are re-ported as corrosion-resistant metallic powders.
US 2003/0190517 discloses cathode electrodes for fuel cells, com-prising a non-electrolytic layer acting to reduce the degradation of the ion-omer membrane. The non-electrolytic layers typically contain a catalyst for catalyzing the reaction of peroxide into water; they do not contain conduc-tive ceramic oxides.
W02011/076396 Al discloses introducing a selectively conducting component on the anode side of a PEMFC to mitigate cathode degradation (i.e. carbon corrosion and platinum dissolution) during start-up and shut-down events. The selectively conductive component contains a selectively conducting material, typically a metal oxide, exhibiting a low resistance when exposed to hydrogen and a high resistance (i.e. low electrical conduc-tivity) when exposed to air. However, it is shown in the examples that MEAs containing a GDL coated with a selectively conductive layer on the cathode

7 side show extremely poor voltage versus current characteristics. This is related to the high resistance of the selectively conductive component in air.
In summary, there is a need for improved corrosion protection in electrochemical devices. Further, there is a need for MEAs for PEMFCs which provide an improved stability against high cell potentials and which exhibit less deterioration of the polarization (U/I) characteristics after exposure to high voltages. More precisely, there is a need for MEAs with high corrosion resistance and improved stability, particularly in start-up/shut down cycles and fuel starvation situations.
One objective of the present invention is to provide means for improved corrosion protection in electrochemical devices. A further objective of the present invention is to provide barrier layers for corrosion protection in electrochemical devices. Finally, a further objective is to provide MEAs, CCMs, GDEs and GDLs comprising such barrier layers and showing improved stability against carbon corrosion.
Summary of the invention This invention provides a barrier layer for corrosion protection in electrochemical devices, e.g. for carbon-based gas diffusion layers (GDLs) in electrochemical devices. The barrier layer finds use in PEMFC components such as membrane electrode assemblies ("MEAs"), catalyst-coated membranes ("CCMs"), gas diffusion electrodes ("GDEs") and gas diffusion layers ("GDLs"). More specifically, the barrier layer provides improved resistance to carbon corrosion of carbon-based GDLs.
According to the present invention, the barrier layer (BL) comprises electrically conductive ceramic material and a non-ionomeric polymer binder.
Date Recue/Date Received 2020-06-10

8 PCT/EP2014/053315 Typically, the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm, preferably >1 S/cm and particularly preferred >10 S/cm in air atmosphere (as detected by the powder method).
Further, the electrically conductive ceramic material has a high acid .. stability showing a solubility of <10-3 mo1/1, preferably a solubility of <10-4 mo1/1 and particularly preferred a solubility of <10-5 mo1/1 upon acidic treat-ment in 1 M H2504 at 90 C.
In general, the electrically conductive ceramic material is selected from the group of precious metal and/or base metal containing oxides, car-.. bides, nitrides, borides and mixtures and combinations thereof.
In the broadest aspect, the polymeric binder used in barrier layer of this invention is a non-ionomeric, non-conductive polymeric material, pref-erably a fluorine-containing polymer which may be partly or fully fluorinat-ed.
By means of the present invention, MEAs for PEMFC showing im-proved stability against high cell potential events are obtained. Such im-proved stability and simultaneous high performance is achieved by introduc-ing an additional layer (hereinafter called "barrier layer", BL) between the catalyst layer and the gas diffusion layer (GDL), comprising an electrically .. conductive oxidation-resistant ceramic material in combination with a non-ionomeric polymer binder.
It has been surprisingly found that when the MEA of the invention is operated at high cell voltages on the side where the barrier layer (BL) is present, degradation of the polarization characteristics is far less severe compared to the case where the BL is omitted. It has also been surprisingly found that the introduction of the BL does not detrimentally affect the per-formance (i.e. the polarization characteristics) of the MEA.
The BL may be introduced on the cathode side, the anode side or on both sides of the MEA, depending on which side of the electrochemical de-vice components, e.g. the gas diffusion layers (GDLs) need to be protected against exposure to high potentials during operation.

8a According to an aspect of the present invention there is provided membrane-electrode assembly comprising at least one barrier layer, wherein the at least one barrier layer is positioned between a catalyst layer and a gas diffusion layer; or catalyst-coated membrane, comprising a ionomer membrane, two catalyst layers and at least one barrier layer, wherein the at least one barrier layer is positioned on at least one of the catalyst layers; or gas diffusion electrode, comprising a carbon-based gas diffusion layer, and a barrier layer, wherein a catalyst layer is coated on the barrier layer; or carbon-based gas diffusion layer comprising a barrier layer, wherein said barrier layer comprises electrically conductive ceramic material and a non-ionomeric polymer binder, wherein the electrically conductive ceramic material comprises ruthenium oxides (RuO2, Ru203), iridium oxides (1r203, Ir02), mixed ruthenium-iridium oxides (Rux1r1_x02), iridium-tantalum oxides (IrxTai_x02), ruthenium-titanium oxides (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxNi_x), tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titanium oxynitride (TiON), niobium doped titanium oxides (NbxTi1_x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSn1_x02) or any combination thereof, and wherein the non-ionomeric polymer binder is polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoroethylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoroeth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR), glassy amorphous fluoropolymers or any combination thereof.
In some embodiments, the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm in air atmosphere as detected by the powder method.
Date Recue/Date Received 2020-06-10 8b In some embodiments, the electrically conductive ceramic material has a high acid stability showing a solubility of < 10-3 mo1/1 upon acidic treatment in 1 M H2SO4 at 90 C.
In some embodiments, the electrically conductive ceramic material comprises iridium oxides (1r203, Ir02), mixed ruthenium-iridium oxides (Rux1r1,02), iridium-tantalum oxide (IrxTa1_x02), ruthenium-titanium oxide (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) or tantalum carbonitride (TaCxNy).
In some embodiments, the electrically conductive ceramic material is a conductive oxide supported on a non-conductive oxide.
In some embodiments, the electrically conductive material supported on a non-conductive oxide is lrO /sin fro Frio fro /AI n or Irn Urn 2. 2, 2. . 2, .. ¨2. ¨.2 ¨ 3 ¨ . 2. ¨ 2.
In some embodiments, the electrically conductive material is conductive iridium oxide supported on titanium oxide (1r02/Ti02).
In some embodiments, the weight ratio between the conductive material and the polymer binder is in the range of 0.5 to 50 wt.-% based on the total weight of the dry layer composition.
In some embodiments, having a layer thickness after drying in the range of 0.1 to 100 microns.
In some embodiments, the gas diffusion electrode comprises a micro-porous layer.
In some embodiments, the carbon-based gas diffusion layer comprises a micro-porous layer.
According to another aspect of the present invention there is provided electrochemical device, comprising a membrane-electrode assembly as described herein or a catalyst-coated membrane as described herein, wherein the at least one barrier layer is positioned on the cathode side, on the anode side or both sides of said electrochemical device.
According to a further aspect of the present invention there is provided use of the membrane electrode assembly, catalyst-coated membrane, gas diffusion electrode and carbon-based gas diffusion layer as described herein in PEM fuel cells, PEM electrolysers, regenerative PEM fuel cells, or batteries.
Date Recue/Date Received 2020-06-10

9 Description of specific prior art For the sake of clarification, the major differences between the barri-er layer of the present invention and the selectively conducting component containing layer disclosed in W02011/076396 (cited above) are outlined in more detail in the following section.
While W02011/076396 refers to materials which are selectively con-ductive, i.e. conduct electrical current in hydrogen and insulate in oxygen or air, and are applied to the anode to protect the cathode from corrosion; the present invention refers to materials that are permanently electrically con-ductive, i.e. they conduct electrical current in hydrogen as well as in oxygen or air and under low and high potentials. The technical advantage is that (1) the barrier layer of the present invention can be applied to the cathode side (in order to protect the cathode side of the MEA) and (2) when applied to the anode, the barrier layer provides for dissipation of reversal currents and effectively protects the anode side of the MEA.
It should be noted that the material/layer of W02011/076396 does not provide for dissipation of current under a cell reversal event, which potentially makes the event even more damaging for the anode side of the MEA. In order to solve this issue, W02011/076396 proposes to make the layer patterned, providing some regions where the layer is absent.
Instead, the barrier layer of the present invention generally extends over the whole active area of the MEA, even when placed on the anode side, to provide effective and complete protection of the MEA. By active area it is meant the area being covered by the catalyst layer and being accessible to the reaction gases. Therefore the electrochemical reactions take place in the active area.
The material/layer of W02011/076396 may be placed not only be-tween the GDL and the anode layer, but anywhere in the electrical series of the cell, e.g. also between the bipolar plate and the GDL. This would not apply for the barrier layer according to the present invention, which aims to separate parts, which are subject to corrosion, e.g. the GDL from the cata-lyst layer and does not prevent electrical conductivity in the presence of

10 oxygen or air. Due to this conceptual difference, the barrier layer of the present invention requires materials with different properties.
W02011/076396 teaches to keep the layer containing selectively conducting material advantageously separated from the anode in order to avoid degradation of the layer, e.g. by incorporating a carbon sub-layer in between. This teaching again underlines the conceptual difference compared to the barrier layer of the present invention.
W02011/076396 does not intend to protect the anode side from carbon corrosion;

instead, it proposes to introduce a carbon sublayer against the anode. Under a cell reversal tolerance event, such carbon sublayer would be subject to corrosion and the cell would not work any more.
Brief Description of the Drawings The invention is described in detail below with reference to the drawings, in which:
Figure 1 shows a general, simplified structure of a MEA;
Figure 2 schematically represents a MEA according to an embodiment of the present invention;
Figure 3 shows the MEA layer structure of another embodiment of the present invention;
Figure 4 shows a 4-layer MEA comprising a barrier layer on the cathode side;
and Figure 5 shows a gas diffusion electrode for the cathode side, containing a barrier layer coated with a cathode catalyst layer.
Detailed description of the invention The following shall describe the various embodiments of the present invention in more detail. These embodiments may be used as products in various electrochemical devices.
As already outlined in the section above, the general simplified structure of a state-of-the art 5-layer MEA is shown in Figure 1. The MEA comprises an ionomer membrane (6) in the center, a cathode gas diffusion layer (1), an cathode catalyst layer (5), an anode catalyst layer (5') and a anode gas diffusion layer (1').
Figure 2 schematically represents a MEA according to the first embodiment (embodiment 1) of the present invention. In this embodiment 1, the barrier layer (BL) is introduced on both sides of the MEA, i.e. on the cathode and on the anode side. Further, the Date Recue/Date Received 2020-06-10 10a gas diffusion layers (GDLs) with numerals 1 and 1' comprise two layers, namely a macro-porous carbon-based backing layer (numerals 2, 2') and an additional micro-porous layer (numerals 3, 3'). These micro-porous layers (3, 3') are frequently called "compensating layers" as they often have the function to smoothen the GDL surfaces which come in contact with the catalyst layer in the MEA.
Date Recue/Date Received 2020-06-10

11 The layers of numerals 1 to 5 represent the cathode side and the lay-ers from numerals 1' to 5' represent the anode side, while numeral 6 repre-sents the ionomer membrane in the center. Numeral 5 represents the cath-ode catalyst layer and numeral 5' the anode catalyst layer, respectively.
.. Numeral 4 indicates the barrier layer (BL) on the cathode side; numeral 4' identifies the barrier layer on the anode side.
More precisely, embodiment 1 comprises a MEA layer structure show-ing the sequence 2 - 3 - 4 - 5 - 6 - 5' - 4' - 3' - 2' (i.e. cathode GDL with microlayer and barrier layer, anode GDL with microlayer and barrier layer).
Additionally, embodiment 1 encloses the two variations in which either the cathode GDL or the anode GDL comprises a microlayer while the opposite GDL is without it.
Thus, embodiment 1A comprises a MEA layer structure showing the sequence 2 - 3 - 4 - 5 - 6 - 5' - 4' - 2' (i.e. cathode GDL with microlayer and barrier layer, anode GDL without microlayer but with barrier layer).
Likewise, embodiment 1B comprises a MEA layer structure showing the sequence 2 - 4 - 5 - 6 - 5' - 4' - 3' - 2' (i.e. cathode GDL without microlayer but with barrier layer, anode GDL with microlayer and barrier layer).
In the second embodiment (embodiment 2) of the present invention, the barrier layer (BL) is again introduced on the cathode and on the anode side of the MEA. However, the gas diffusion layers (GDLs) 1 and 1' comprise only one layer, namely a macro-porous carbon-based backing layer (2, 2') and a micro-porous layer is omitted. In such a case, the barrier layer (BL) can be seen as replacing the micro-porous layer. In this case, the barrier layers 4 and 4' are in direct contact with the macro-porous layers of the GDLs, which need to be protected against corrosion due to their carbona-ceous nature. BLs 4 and 4' separate the electrodes from the GDLs and pre-vent deterioration of the MEA performance when the cathode side of the MEA (layers 1 to 5) and the anode side of the MEA (layers 1' to 5') are ex-posed to high cell potentials.

12 Various variations and combinations of the two embodiments de-scribed above are feasible. For example, in case only one side of the MEA
needs to be protected, only one barrier layer (4 or 4') may be employed, either on the anode or on the cathode side of the MEA.
Thus, the third embodiment (embodiment 3) of the present invention is directed to a MEA structure, wherein the barrier layer (4') is applied only to the anode side. Hereby, the third embodiment includes all 4 variations generated by the use of GDLs with or without micro-layer on cathode and/or anode side.
More precisely, embodiment 3A comprises the MEA layer structure 2 - 3 - 5 - 6 - 5' - 4' - 3' - 2' (i.e. cathode GDL with microlayer, anode GDL
with microlayer and barrier layer).
Embodiment 3B comprises the MEA layer structure 2 - 5 - 6 - 5' - 4' - 3' - 2' (i.e. cathode GDL without microlayer, anode GDL with microlayer and barrier layer).
Embodiment 3C comprises the MEA layer structure 2 - 3 - 5 - 6 - 5' - 4' - 2' (i.e. cathode GDL with microlayer, anode GDL without microlayer but with barrier layer).
And finally, embodiment 3D comprises the MEA layer structure 2 - 5 - 6 - 5' - 4' - 2' (i.e. cathode GDL without microlayer, anode GDL without microlayer but with barrier layer).
Corresponding to these combinations, the fourth embodiment (em-bodiment 4) of the present invention is directed to a MEA structure, wherein the barrier layer (4) is applied only to the cathode side. Here again, the fourth embodiment includes all variations generated by the use of GDLs with or without micro-layer on cathode and/or anode side.
In more detail, embodiment 4A comprises the MEA layer structure 2 -3 - 4 - 5 - 6 - 5' - 3' - 2' (i.e. cathode GDL with microlayer and barrier layer, anode GDL with microlayer). Embodiment 4A is shown in Figure 3.

13 Embodiment 4B comprises the MEA layer structure 2 - 4 - 5 - 6 - 5' - 3' - 2' (i.e. cathode GDL without microlayer but with barrier layer, anode GDL with microlayer).
Embodiment 4C comprises the MEA layer structure 2 - 3 - 4 - 5 - 6 -5' - 2' (i.e. cathode GDL with microlayer and barrier layer, anode GDL with-out microlayer).
Finally, embodiment 4D comprises the MEA layer structure 2 - 4 - 5 - 6 - 5' - 2' (i.e. cathode GDL without microlayer but with barrier layer, anode GDL without microlayer).
In a further embodiment (embodiment 5), the barrier layer (BL) may be applied directly to the catalyst-coated membrane (CCM) instead applying it to the gas diffusion layers (GDL). This embodiment 5 encompasses cata-lyst-coated membranes (CCMs) which contain barrier layers either on the cathode or the anode side or on both sides. After the assembly of such 4-layer or 5-layer CCMs with appropriate GDLs on anode and cathode side (either with or without micro-porous layer), essentially the MEA layer struc-tures of embodiments 1A to 4D will result (see above). Figure 4 shows an example of Embodiment 5. A 4-layer MEA comprising a barrier layer on the cathode side (4) is shown. This barrier layer (4) is directly applied on the surface of the cathode catalyst layer (5).
In a further alternative embodiment (embodiment 6), gas diffusion electrodes (abbreviated GDEs) are employed. Such GDEs are obtained by coating standard gas diffusion layers GDLs (with or without microlayer) with a suitable anode or cathode electrocatalyst. Thus GDEs are often referred to as "catalysed" GDLs or "catalyst-coated gas diffusion layers". Embodiment 6 encompasses gas diffusion electrodes (GDE) comprising a barrier layer.
Hereby, starting from a GDL with a barrier layer (BL), electrocatalyst layers may be coated on top of the BL, using suitable electrocatalyst inks. After drying, the GDL with barrier layer and catalyst layer (i.e. a GDE with barrier layer) can be applied to an ionomer membrane by heat and pressure to obtain a final MEA according to the present invention. As an example of

14 embodiment 6, Figure 5 shows a gas diffusion electrode for the cathode side, containing a barrier layer (4) coated with a cathode catalyst layer (5).
In a still further embodiment (embodiment 7), the present invention encompasses gas diffusion layers (GDLs) coated with the barrier layer (4) of the present invention. The GDL may comprise a microlayer (3) (i.e. layer structure 2 - 3 - 4) or may be without microlayer. In the latter case, the barrier layer (4) is coated directly on the surface of the gas diffusion layer macro-porous backing (2), i.e. the layer structure is 2 - 4.
As a basic feature, the corrosion-resistant MEAs of the present inven-tion comprise at least one barrier layer (BL). As described above, this barri-er layer (BL) may be present on both sides or only on one side of the MEA
(cathode or anode side only) thus representing the various embodiments described. However, various additional combinations may be applied.
In embodiments 1 and 2, the barrier layer is applied to both MEA
sides. Combinations, in which a catalyst layer is coated with the BL on one side and the GDL is coated with the BL on the other side are also possible.
In embodiments 3 and 4, where only one side of the MEA contains a barrier layer, various combined techniques are feasible provided that only one GDL or one side of the CCM may be coated.
It is clear to the person skilled in the art that different orders and combinations in the manufacturing and assembly of the successive layers of the MEA can be conceived, without departing from the scope of the present invention.
In general, the present invention refers to any electrochemical de-vice, comprising at least one barrier layer (4, 4') of the present invention either on the cathode side, on the anode side or on the cathode and on the anode side.
In more detail, the present invention refers to a membrane-electrode assembly comprising at least one barrier layer (4, 4'), wherein the at least one barrier layer (4, 4') is positioned between the catalyst layer (5, 5') and the gas diffusion layer (1, 1') In further detail, the present invention refers to a catalyst-coated membrane, comprising an ionomer membrane (6), two catalyst layers (5, 5') and at least one barrier layer (4), wherein the at least one barrier layer (4) is positioned on at least one of the catalyst layers (5, 5') on the side not 5 facing the membrane.
Further, the present invention refers to a gas diffusion electrode, comprising a carbon-based gas diffusion layer (1), optionally comprising a micro-porous layer (3), and comprising a barrier layer (4); wherein a cata-lyst layer (5) is coated on the barrier layer (4).
10 Still further, the present invention refers to a carbon-based gas diffu-sion layer (GDL, 1), optionally comprising a micro-porous layer (3), and comprising a barrier layer (4).
Finally, the barrier layer according to the present invention may be used in electrochemical devices selected from the group of PEM fuel cells,

15 PEM electrolysers, regenerative PEM fuel cells, redox-flow batteries and batteries.
Additionally, the membrane electrode assemblies (MEAs), catalyst-coated membranes (CCMs), gas diffusion electrodes (GDEs) and gas diffu-sion layers according to the present invention find use in PEM fuel cells, PEM
electrolysers, regenerative PEM fuel cells, redox-flow batteries or batteries.
Materials selection Typically, backing layers 2 and 2' are sheets of woven carbon fabric, carbon paper, non-woven or felt carbon-based materials, often advanta-geously made hydrophobic by treatment with a hydrophobic material, e.g.
polytetra-fluoroethylene (PTFE).
Micro-porous layers ("microlayers") 3 and 3' normally comprise mix-tures of carbon particles and a hydrophobic binder, typically also PTFE or other fluorinated polymers. The presence of micro-porous layers on the GDL
surface is optional, i.e. on one or both sides of the MEA, the micro-porous layer 3 and/or 3' may not be present.

16 Generally, GDLs with or without micro-porous layers are well known in the prior art. Commercially available GDLs comprising micro-porous layer are for example: SigracetC) 10BC, 24BC, 25BC, 24BCH, 25BCH and 34BC
from SGL Group, Meitingen (Germany); H2315 12 C6 and H2315 12 C8 from Freudenberg FCCT KG, Weinheim (Germany); AvCarb GD53215, GD52230, GDS2120 and GDS1120 from Ballard Power Systems Inc., Burn-aby Canada; N1S1007 and W1S1005 from CeTech Co., Ltd., Taichung County, Taiwan.
Commercial GDL types without micro-porous layer are e.g.:
SigracetC) 10BA, 24BA, 25BA and 34BA from SGL Group; H2315 12 from Freudenberg FCCT KG; TGP-H-60 and TGP-H-120 from Toray Industries, Inc., JP; NOS1005 and WOS1002 from CeTech Co., Ltd.
The catalyst layers 5 and 5' typically contain finely divided precious metals selected from the group of platinum (Pt), palladium (Pd), ruthenium (Ru) or rhodium (Rh), optionally mixed or alloyed with base metals such as Co, Ni, Mn, Cr or Cu. The electrocatalyst materials are mixed with an iono-mer component. The precious metals are typically supported on a carbon black based support. Suitable support materials are typically carbon black (preferably graphitized types with improved corrosion resistance) or con-ductive ceramic materials (e.g. metal oxides). The electrocatalyst may also be present without a support (e.g. platinum black). The composition of cathode catalyst layer 5 and anode catalyst layer 5' may differ or may be the same, but typically they differ in type and amount of electrocatalyst(s) employed. The catalyst layers 5 and 5' may additionally comprise, together with the electrocatalyst material and the ionomer, a second electrocatalyst material facilitating the oxygen evolution reaction (water splitting) at high electrode potentials, such as iridium or ruthenium oxides.
Vacuum deposition processes may also be used to fabricate the cata-lyst layers 5 and 5', particularly the anode catalyst layer 5'. Such processes include physical vapor deposition (PVD), chemical vapor deposition (CVD) and sputtering processes.
Catalyst layers as described herein are well known in the art.

17 As a basic feature, the MEA of the present invention comprises at least one barrier layer (BL) for corrosion protection. This barrier layer (BL) acts as an electrically conductive separator layer between the carbon-containing GDL materials and the catalyst layers of the MEA. As a specific feature, the barrier layer does not comprise any proton-conducting compo-nents or ionomer materials.
In more detail, the barrier layer (BL) comprises an electrically con-ductive ceramic material (such as, for example, a conductive metal oxide) stable to oxidation at high cell potentials, i.e. at cell potentials >1.2 V.
By the term "electrically conductive" it is meant that the ceramic material is able to transport electrons with an electrical conductivity of >0.1 S/cm, preferably >1 S/cm and particularly preferred 10 S/cm in air atmosphere.
The value of electrical conductivity is detected according to the powder method described in the Experimental section. It should be mentionened that all measurements of electrical conductivity are determined under air atmosphere.
It was found that materials with lower electrical conductivity (i.e. <
0.1 S/cm) lead to high resistance in the barrier layer and thus cause high performance losses in the resulting PEM fuel cell.
By the term "stable to oxidation" it is meant that the conductive ce-ramic material does not dissolve or lose its electrical conductivity when exposed to the high potentials in acidic media while admitting that, in the case of a conductive ceramic, the metal constituent may change its oxida-tion state. The electrically conductive ceramic material in the BL should be generally stable to acids, preferably under potential control. By this term, it is meant that the conductive ceramic material should exhibit a high acid stability, i.e. the solubility of the material should be < 10-3 mo1/1, preferably < 10-4 mo1/1, more preferably < 10-5 mo1/1 upon acidic treatment in 1 M
F12504 at 90 C. Details of this testing method are given in the Experimental section.
Additionally, the barrier layer (BL) comprises a polymeric binder, which keeps the metal or ceramic particles together and confers good me-

18 chanical properties to the layer. The polymeric binder may be an organic polymer, preferably a fluorinated polymer.
In general, the electrically conductive ceramic material is selected from the group of precious metal and/or base metal containing oxides, car-bides, nitrides, borides and mixtures and combinations thereof.
More than one metal or conductive ceramic material may be present in the barrier layer. These can be mixed or may be present in distinct sub-layers to form the BL. In the latter case, it is advantageous that a conduc-tive ceramic stable to acids is present in the sub-layer in contact with the catalyst layer, while the feature of acid stability is not so important for the conductive ceramic opposite to the catalyst layer, i.e. on the side of the GDL, since a non-ionomeric binder is employed in the BL sub-layers. Multi-ple layers for barrier layer construction may be advantageous when e.g.
employing a more expensive material at lower loading for one sub-layer and a less expensive material at higher loading for another sub-layer. As an example, a highly acid-stable expensive material such as iridium oxide can be used in a very thin sub-layer on the catalyst layer side, while a cheaper conductive metal oxide with lower acid stability can be used, if applicable, in a thicker second sub-layer on the GDL side. The polymeric binder may be the same or different in the different sub-layers.
As already mentioned, the conductive ceramic material should have an electrical conductivity of >0.1 S/cm, preferably >1 S/cm and particularly preferred >10 S/cm in air atmosphere (as detected by the powder method).
Suitable examples are ceramic materials selected from the group of ruthenium oxides (RuO2, Ru203), iridium oxides (Ir203, Ir02), mixed ruthe-nium-iridium oxides (RuxIr1-x02), iridium-tantalum oxide (IrxTa1-x02), ruthe-nium-titanium oxide (RuxTi1-x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxN1-x), tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titani-um oxynitride (TiON), niobium doped titanium oxide (NbxTii-x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSnl-x02) and mixtures and combinations thereof.

19 Preferably, the ceramic material is selected from the group of iridium oxides (Ir203, Ir02), mixed ruthenium-iridium oxides (RuxIri-x02), iridium-tantalum oxide (IrxTa1-x02), ruthenium-titanium oxide (RuxTi1-x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) and tantalum carbonitride (TaCxNy).
In a particularly preferred embodiment, the electrically conductive ce-ramic material may be supported on a non-conductive, inert refractory ox-ide such as SiO2, T102, A1203 or ZrO2 or mixtures thereof. Examples for such supported conductive oxides are Ir02/Ti02, Ir02/A1203, Ir02/Si02 and Ir02/Zr02 as disclosed in EP 1701790B1.
Generally, the thickness of the barrier layer (BL) after the drying pro-cess is in the range of 0.01 to 300 microns, preferably in the range of 0.1 microns to 100 microns. When no micro-porous layer is present on the GDL, a thickness after drying in the range of 1 to 100 microns is particularly pre-ferred. Thicknesses of around 2 to 50 microns are most preferred in this case. In this case, the barrier layer of the present invention may simultane-ously take the function of a micro-porous layer on the GDL substrate.
The barrier layer may partially penetrate the GDL. For example, when the BL is fabricated from a liquid dispersion and applied directly on the mac-ro-porous layer of a GDL without micro-porous layer, it is easily understood that part of the materials of the BL may penetrate the pores of the GDL. In this case the thickness of the BL may be identified as the thickness of the layer which is external to the GDL backing porosity.
The metal or conductive ceramic material is present in the BL in the .. form of particles with shapes ranging from spherical to aggregates of spher-ical primary particles or "fibrillar", i.e. tube like appearance and eventually partially agglomerated (agglomerates are bundles of aggregates). The par-ticle size of such BL material (particles, agglomerates or aggregates) as defined above can range from 0.01 microns to 5 microns, preferably from 0.02 microns to 1 micron. For fibrous materials the length of the tube can be as long as tens of microns and the diameter should be lower than 0.3 microns.

The metal or conductive ceramic material is typically provided in form of fine micron-sized powders but aqueous or solvent based suspensions may also be an option.
Typical porosity of the barrier layer is in the range of > 0.4 void vol-5 ume calculated from the film weight and thickness (e.g. by SEM) and the density of the constituent materials. An alternative way of investigating the void volume is mercury intrusion and void should be >0.3. Secondary pore sizes (pathway of reactants) of the BL determined by Hg intrusion should be in the range of 0.01 to 10 pm. Preferred range of pore sizes is in the range 10 of 0.04 to 1 pm. A preferred range is from 0.08 to 0.4 pm.
The polymeric binder may be selected in order to provide the desired hydrophilic / hydrophobic properties to the BL. Fluorinated polymers are preferred, perfluorinated ones even more preferred. By fluorinated polymer it is meant a polymer where a substantial amount of hydrogen atoms at-15 tached to carbon atoms in the macromolecular chain have been substituted by fluorine atoms. By perfluorinated (or fully fluorinated) polymer it is meant a polymer in which all the hydrogen atoms attached to carbon atoms in the macromolecular chain have been replaced by fluorine atoms, or even-tually, in smaller amounts, by heteroatoms like chlorine, iodine and bro-

20 mine. Oxygen atoms and other heteroatoms like nitrogen, sulfur and phos-phorus can also be incorporated in (per)fluorinated polymers.
The polymer binder is a non-ionomeric polymer, i.e., the polymer chains do not contain any ionic moieties, which could provide proton con-ductivity.
The non-ionomeric polymer binder is selected from the group of poly-tetrafluorethylene (PTFE), ethylene/tetrafluorethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoreth-ylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoreth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR) and mixtures and combinations thereof.

21 Polytetrafluoroethylene (PTFE) is preferred, especially when the BL is prepared on the GDL which allows high-temperature sintering (T >330-340 C) of the PTFE after BL fabrication. PTFE is typically provided in the form of a water-based dispersion, with particle size ranging from a few tens of nanometers to a few microns.
When the BL is prepared directly on the electrode of a catalyst-coated-membrane (CCM) according to embodiment 5, materials allowing low-temperature sintering or requiring no sintering are advantageously used. This is due to the impossibility of high-temperature sintering which would damage the temperature-sensitive CCM.
Fluorinated semi-crystalline polymers with a melting point Tm <
250 C may be employed in this case, e.g. polyvinylidene-fluoride (PVDF) and semi crystalline copolymers of vinylidene-fluoride.
Further, amorphous glassy polymers with a glass transition point Tg <
200 C may be employed. Examples are Teflon AF from DuPont, Hyflon AD from Solvay or Cytop from Asahi Glass.
Further, rubbery fluoropolymers may be employed, such as perfluoro rubbers (PFR) or vinylidene fluoride/hexafluoropropylene (VDF/HFP) rubbery copolymers.
The materials above are typically provided in the form of water-based dispersions or emulsion polymerization latexes. Normally, a sintering step is required after application of the BL containing such dispersions.
However, soluble fluorinated polymers may also be employed which require no sintering. Solutions of PVDF or VDF/HFP copolymers or amor-phous glassy polymers such as Teflon AF, Hyflon AD or Cytop may be provided in non-fluorinated polar solvents (e.g. for the case of PVDF or VDF/HFP copolymers) or fluorinated solvents (e.g. for the case of amor-phous glassy perfluorinated polymers).
As with the conductive ceramic materials, more than one polymer .. may be used as binder in the barrier layer of the present invention. These

22 different polymer materials may be mixed in one layer or may be present separately in distinct sub-layers.
When a micro-porous layer is present on the GDL, the polymer binder in the BL may be chosen so that it confers hydrophobic properties similar to those of the micro-porous layer, i.e. the same or a similar binder in chemi-cal nature may be employed.
The weight ratio between the conductive ceramic material and the polymeric binder in the barrier layer can vary in accordance with the desired porosity and hydrophobic/hydrophilic properties of the layer. This can be expressed as the weight percent (wt.-%) of the polymeric binder in the dry layer, i.e. binder/(binder + inorganic material) x 100 and is typically in the range of 0.5 to 50 wt.-%, preferably in the range of 1 to 25 wt.-% based on the total weight of the dry layer composition.
The barrier layer of the present invention can be prepared by differ-ent fabrication routes. Typically, a liquid ink is first prepared comprising the metal or conductive ceramic materials and the polymeric binder materials in a liquid medium. Depending on the polymeric binder(s), the liquid medium may be D.I. water or a mixture of water and one or more polar solvents.
Further, the liquid medium can be a polar solvent or a mixture of polar solvents or it can be a non-polar solvent or a mixture of non-polar solvents, eventually fluorinated or perfluorinated.
Further, dispersants, surfactants and other agents, such as thickening agents, may be added to the barrier layer ink. Pore formers may also be added to aid porosity formation during drying of the layer.
Generally, the barrier layer inks of the present invention may be pre-pared in the same way as conventional catalyst inks. Typically, various dispersing equipments (e.g. high-speed stirrers, roll mills, vertical or hori-zontal bead mills, asymmetric centrifuges, magnetic mixers, mechanical mixers, ultrasonic mixers, etc.) are used. The preparation of catalyst inks is well known to the person skilled in the art.
The liquid dispersion ("barrier layer ink") is then coated or printed on the GDL or the CCM in a thin layer by techniques known to the person

23 skilled in the art. Coating techniques that can be employed are for instance spraying, brushing, screen printing, offset printing, gravure printing, stencil printing, ink-jet printing, doctor-blade coating, bar coating, slot die coating, curtain coating, cascade coating, etc.
After application of the barrier layer ink, a drying step is applied to remove the solvent(s) of the ink deposits. Drying is typically performed in conventional or IR heated box ovens or belt furnaces at temperatures in the range of 50 to 200 C, preferably in the range of 50 to 150 C. Optionally, such heat treatment may be performed under protective atmosphere (nitro-gen, argon).
Following the drying step, a high temperature step can be optionally performed e.g. to sinter the polymer binder if required and remove any high-boiling additives from the deposited layer. Optionally the drying step may be combined with a subsequent high temperature sintering step in a continuous heating treatment process. Optionally, such heat treatment may be performed under protective atmosphere (e.g. nitrogen, argon).
In such a manner, a GDL or a CCM with a barrier layer is obtained.
GDLs with BLs can be applied to a CCM by a lamination process (em-ploying heat and pressure) to obtain a final MEA according to the present invention (ref to embodiments 1 to 4).
GDLs with BLs may also be applied to the CCM when assembling the MEAs, i.e. stacking them into the fuel cell stack alternated to the other components, i.e. bipolar plates, gaskets and CCMs. This case is often re-ferred to as MEAs with "loose GDLs." In this case, the GDLs most often become tightly bonded to the catalyst layers during operation of the PEMFC, due to pressure and local heat dissipation.
In an alternative process (ref. to embodiment 5), the barrier layer can be coated on top of the catalyst layers of a regular catalyst-coated membrane (CCM), and standard GDLs can then be applied to the BL-coated CCM, for example by lamination, to obtain a final MEA according to the invention. The standard GDLs may also be mounted "loose" on the two

24 sides of the BL-coated CCM when assembling the MEA in the formation of the PEMFC stack.
In a further alternative (ref to embodiment 6), gas diffusion elec-trodes (GDEs) comprising barrier layers (BL) are provided. Hereby, starting from a GDL with a barrier layer (BL), electrocatalyst layers may be coated on top of the BL, using suitable electrocatalyst inks as previously outlined.
The final MEA according to the present invention is obtained in by laminat-ing anode and cathode GDEs onto the front and back side of an ionomer membrane.
Other processes to obtain a corrosion-resistant MEA according to the present invention are also possible. For example, starting from a carrier substrate, e.g. a polymer film, a first barrier layer, a first electrocatalyst layer, a polymer electrolyte membrane, a second catalyst layer and a sec-ond barrier layer are coated in succession, with or without intermediate drying steps, according to what is generally called an "integral" CCM fabri-cation method. The CCM comprising one or more barrier layers obtained in this manner may then be combined with GDLs to obtain a final MEA accord-ing to the invention. Successive coating of layers, including the barrier lay-ers, with or without intermediate drying steps, can also be accomplished starting from a GDL, according to what can be named an "integral" MEA
fabrication method.
The introduction of at least one additional layer (herein called "barrier layer", BL) results in MEAs showing improved stability against high cell potential events. Such improved stability and simultaneous high perfor-mance is achieved by introducing an additional layer (hereinafter called "barrier layer", BL) between the catalyst layer and the gas diffusion layer (GDL), comprising an oxidation-resistant metal or conductive ceramic mate-rial in combination with a polymeric binder. The MEAs based on the various embodiments of the present invention are tested and evaluated in PEMFCs in the course of various electrochemical testing procedures (ref to experi-mental section).

Further, surprising benefits have been found. When a GDL with barri-er layer is applied to a CCM, e.g. by hot pressing, or a GDL is applied to a CCM with barrier layer, the BL may provide the additional advantageous feature of improving the adhesion of the CCM to the GDL, which in turn 5 improves the performance and durability of the MEA. In general, and inde-pendent of the MEA manufacturing method, the barrier layer can act as a "tie layer" between the electrocatalyst layers and the GDLs thus improving the performance and durability of the MEAs In a specific embodiment, the present invention may also be applied 10 to the manufacture of corrosion resistant MEAs for electrolysis. For such electrolysis-MEAs, which are operated in a reversed way compared to regu-lar PEMFC MEAs (ref to introductory part), the introduction of at least one additional layer ("barrier layer", BL) results in MEAs with improved corrosion resistance. In this case, the BL is advantageously introduced between the 15 anode layer, which is operated at high potentials in the electrolysis mode, and the gas diffusion layer, carbon- or metal-based, or the "current collec-tor" (in electrolysis technology, metal-based GDLs or gas diffusion media, such as metal nets or metal porous substrates, are often referred to as "current collectors"). This eventually allows the use of cheap and easy-to-20 handle carbon-based GDLs as diffusion media instead of expensive GDL
substrates ("current collectors") such as e.g. titanium nets or porous metal substrates (often further treated with precious metal coatings) which are typically used on the anode side of an electrolyser when in direct contact with the catalyst layer. This also eventually allows avoiding precious metal

25 coatings of the metal-based current collectors, which are protected against corrosion by the presence of the barrier layer.
Membrane-electrode assemblies (MEAs), catalyst-coated membranes (CCMs), gas diffusion electrodes (GDEs) and gas diffusion layers (GDLs) comprising the barrier layer of the invention show improved corrosion re-sistance, preferably against carbon corrosion; particularly in start-up/shut-down cycles and fuel starvation situations of PEM fuel cells.

26 Although the specific examples are described herein for illustrative purposes, various equivalent modifications may be made without departing from the spirit and scope of the disclosure, as will be recognized by those skilled in the relevant art. The teachings of the various examples provided herein may be applied to all types of MEAs, not necessarily the exemplary MEAs described in the following section.
In general, in the following examples should not be construed to limit the claims to the specific embodiments disclosed.
Experimental Section Measurement of electrical conductivity (powder method) A 4-point powder conductivity unit provided by Mitsubishi Chemical (Loresta PA system, MCP-PD51) is employed for the method. The ceramic powder is filled into a measurement compartment and then the sample is compacted by a pressure piston. The conductivity is measured under differ-ent compaction pressures by the four point method, i.e. a current is passed through two electrodes and the difference in potential is measured between two other electrodes. The conductivity measurement results are reported for a pressure of 63 MPa at room temperature (T 23 C).
The electrical conductivity of Elyst Ir75 0480 is typically ¨ 100 Sicm.
Measurement of acid resistance Dissolution in acid is detected by soaking the ceramic powder in 1 molar (1 M) sulphuric acid at 90 C for 24 h. The ratio of powder weight to the quantity of sulfuric acid is 1 g to 100 ml acid. Approximately 10 g of ceramic powder are employed for testing. After acid soaking for 24 hours at 90 C, the residual suspension is filtered and the non-dissolved material is removed. The remaining solution is analyzed by Inductive Coupled Plasma analysis (ICP-OES) to determine the quantity of dissolved metals/elements leached out from the ceramic material.

27 For Elyst Ir75 0480 typical values of ¨ 2 x 10-6 mo1/1 Jr and ¨ 1 x 10-4 mo1/1 Ti is found. This indicates a loss of 0.009 wt.-% of Jr and a loss of 0.55 wt.-% Ti (in both cases based on the metals employed). Thus, a very low acid solubility of < 10-3 mo1/1 is found.
For comparison, a commercially available In203-SnO2 material (ITO, Inframat Nano-powder) is tested. The ITO material dissolves during the described test and a quantity of 6 x 10-2 mol In/1 is found in the remaining solution by ICP, thus indicating a high acid solubility of ITO (i.e. loss of wt.-% of In employed).
.. Electrochemical testing Electrochemical testing is performed in a 50 cm2 PEM single cell fitted with graphitic serpentine flow field plates. The single cell is thermally con-trolled by K-type thermocouples, resistive heating pads for heating and a ventilator for air cooling. Gases are humidified using bubblers. The cell is operated in counter flow. All MEA samples are sealed with incompressible glass-reinforced PTFE gaskets resulting in a 20% compression of the GDL.
Prior to performance and accelerated degradation testing of MEA
samples, the cell is conditioned under hydrogen/air for 8 hours at 1 A/crn2 at a pressure of 1.5 bar abs, Tcell of 80 C, humidifier temperatures of 80 C
.. (anode) and 64 C (cathode).
Hydrogen/air IV-polarization measurements are performed at begin-ning of life (BOL) and at end of test (EOT), under the following condition:
Tceli =60 C, humidifier temperatures =60 C (both sides), pressure = 1.5 bar abs, anode stoichionnetry = 1.5, cathode stoichionnetry = 2.
.. High potential "corrosion" testing To simulate degradation induced by high cell potentials in air/air start up/shut down (current reverse) and fuel starvation (cell reversal) conditions in PEMFC, a potentiostatic holding experiment is used.
For this experiment the working electrode ("cathode") is purged with nitrogen at 40 nl h-1 and then set to a high potential of 1.4 V versus the reference/counter electrode ("anode") which is supplied with hydrogen at 30

28 nl h-1-. The cell is operated at 80 C, ambient pressure and at full humidifica-tion of both gases. In intervals of every two hours a short polarization ex-periment at 0.2, 0.8 and 1.2 A/cm2 is made under the conditions reported above for the IV-polarization measurements. This is repeated for a total of 10 hours at high cell potential (5 cycles).
Examples Example 1 Preparation of catalyst-coated membranes (CCM) A catalyst-coated membrane ("CCM") is provided having an anode catalyst loading of 0.1 mg Pt/cm2 (based on Pt/C-catalyst Elyst 20Pt 0350 from Umicore AG & Co KG, Hanau, Germany) and a cathode platinum load-ing of 0.5 mg Pt/cm2 , based on Pt black (Umicore AG & Co KG, Hanau, Germany) mixed with Ir02/TiO2 catalyst Elyst Ir75 0480 (Umicore AG & Co KG) in a ratio of 30:70 applied on both sides of an ionomer membrane Nafi-on 212C5 (thickness 50.8 pm, DuPont, USA). The catalyst layers are ap-plied by standard decal methods. The active area of both catalyst layers is 71 mm x 71 mm and the overall membrane size is 110 mm x 110 mm.
Example 2 Preparation of a GDL with barrier layer (BL) To a water-based PTFE dispersion TF 5032Z (Dyneon GmbH, Burgkir-chen, Germany), containing 55.2 wt.-% PTFE with average particle size of 160 nm and 3.8 wt.-% emulsifier, solvent dipropylene glycol (Merck Cat.
No. 803265) is added to obtain a dispersion with the following composition (wt.-%):

29 PTFE (solid polymer) 9.0 wt.-%
DI Water: 6.7 wt.-%
Emulsifier: 0.6 wt.-%
Dipropylene glycol: 83.7 wt.-%
Total 100.0 wt.-%
The dispersion is then stirred for 30 minutes. Thereafter, 30.0 grams of a supported conductive metal oxide 1r02/TiO2 (Elyst Ir75 0480; Umicore AG & Co KG) is then added to 70.0 grams of the PTFE dispersion prepared above and the mixture is thoroughly dispersed in a bead mill (grinding me-dia zirconia, ca. 1 mm diameter, milling time 30 minutes at about 2.000 rpm). The resulting barrier layer ink contains 30.0 wt.-% Ir02/TiO2 oxide material and 6.3 wt.-% PTFE. This results in a ratio of Jr oxide materi-al/PTFE = 4.76:1, i.e. a binder content of 17.4%.
The barrier layer ink is screen-printed on a gas diffusion layer (GDL) Sigracet 24BC (SGL-Carbon, Meitingen Germany) on the side coated with a micro-porous layer and dried in a belt oven for 8 minutes at a peak drying temperature of 95 C. A loading of ca. 0.55 mg Ir/cm2 is obtained on the GDL, corresponding to a barrier layer (BL) thickness of about 2.5 to 3 mi-crons after drying.
After drying, the coated GDL is further annealed by heat treatment in a box oven at a peak temperature of 340 C for about 10 minutes under nitrogen atmosphere.
The BL-coated GDL thus obtained is assembled with the CCMs de-scribed in Example 1. In such case it is placed loose against the cathode catalyst layer of the CCM within the flow field plates of a test cell to assem-ble a MEA according to the embodiment 4A of the present invention, which is shown in Figure 3.
Results of electrochemical testing CCM samples prepared as described in Example 1 are mounted in the single cell and GDLs (either coated or non-coated) are applied on two sides.

First group (MEAs 1 and 2): On the anode side, a standard SigracetC) 24BC (SGL) is applied. On the cathode side, a GDL with a barrier layer as prepared in Example 2 (according to the invention) is applied.
Second group (MEAs REF 1 and REF 2): On the anode and on the 5 cathode side both a standard Sigracet0 24BC (SGL) is applied.
The results are shown in Table 1. As can be seen in this table, the MEAs containing GDLs with the barrier layer (BL) according to the present invention (MEAs 1 and 2) reveal a very good performance in the accelerated corrosion testing. They show a high resistance to the high potential treat-10 ment demonstrated by a low voltage loss in the range of less than 7%
based on BOL performance. Contrary to that, the voltage loss of MEAs with-out barrier layer (REF 1 and REF 2) reveal a high voltage loss in the range of 50% based on the BOL performance.
15 Table 1: Results of High cell potential corrosion testing Cathode BOL (1) EOT (2) Voltage loss Sample GDL performance (V) Performance (V) (%) + Barrier layer 0.735 0.702 - 4 + Barrier layer 0.733 0.679 - 7 24BC 0.733 0.370 - 49 24BC 0.737 0.433 - 41 Ref 2 (1) cell voltage detected at 0.2 A/cm2 (2) end of test measurement after 10 h at 1.4 V

Claims (46)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A membrane-electrode assembly comprising at least one barrier layer, wherein the at least one barrier layer is positioned between a catalyst layer and a gas diffusion layer, wherein said barrier layer comprises electrically conductive ceramic material and a non-ionomeric polymer binder, wherein the electrically conductive ceramic material comprises iridium-tantalum oxides (lrxTai_x02), ruthenium-titanium oxides (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxNi_x), tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titanium oxynitride (TiON), niobium doped titanium oxides (NbxTii_x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSni_x02) or any combination thereof, and wherein the non-ionomeric polymer binder is polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoroethylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoroeth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR), glassy amorphous fluoropolymers or any combination thereof.

2. The membrane-electrode assembly according to claim 1, wherein the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm in air atmosphere as detected by a powder method.

3. The membrane-electrode assembly according to claim 1 or 2, wherein the electrically conductive ceramic material has a high acid stability showing a solubility of < 10-3 mol/l upon acidic treatment in 1 M H2504at 90 C.

4. The membrane-electrode assembly according to any one of claims 1 to 3, wherein Date Recue/Date Received 2021-01-22 the electrically conductive ceramic material comprises iridium-tantalum oxide (IrxTai_x02), ruthenium-titanium oxide (RuxTi1_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) or tantalum carbonitride (TaCxNy).

5. The membrane-electrode assembly according to any one of claims 1 to 4, wherein the electrically conductive ceramic material is a conductive oxide supported on a non-conductive oxide.

6. The membrane-electrode assembly according to claim 5, wherein the electrically conductive material supported on a non-conductive oxide is 1r02/Si02, 1r02/Ti02, 1r02/A1203 or Ir02/Zr02.

7. The membrane-electrode assembly according to claim 6, wherein the electrically conductive material is conductive iridium oxide supported on titanium oxide (1r02/Ti02).

8. The membrane-electrode assembly according to any one of claims 1 to 7, wherein the weight ratio between the conductive material and the polymer binder is in the range of 0.5 to 50 wt.-% based on the total weight of the dry layer composition.

9. The membrane-electrode assembly according to any one of claims 1 to 8, having a layer thickness after drying in the range of 0.1 to 100 microns.

10. The membrane-electrode assembly according to any one of claims 1 to 9, wherein the gas diffusion electrode comprises a micro-porous layer.

11. The membrane-electrode assembly according to any one of claims 1 to 9, wherein the carbon-based gas diffusion layer comprises a micro-porous layer.

12. A catalyst-coated membrane, comprising a ionomer membrane, two catalyst layers and at least one barrier layer, wherein the at least one barrier layer is positioned on at least one of the catalyst layers, Date Recue/Date Received 2021-01-22 wherein said barrier layer comprises electrically conductive ceramic material and a non-ionomeric polymer binder, wherein the electrically conductive ceramic material comprises iridium-tantalum oxides (lrxTai_x02), ruthenium-titanium oxides (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxNi_x), tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titanium oxynitride (TiON), niobium doped titanium oxides (NbxTii_x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSni_x02) or any combination thereof, and wherein the non-ionomeric polymer binder is polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoroethylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoroeth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR), glassy amorphous fluoropolymers or any combination thereof.

13. The catalyst-coated membrane according to claim 12, wherein the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm in air atmosphere as detected by a powder method.

14. The catalyst-coated membrane according to claim 12 or 13, wherein the electrically conductive ceramic material has a high acid stability showing a solubility of < 10-3 mol/l upon acidic treatment in 1 M H2SO4at 90 C.

15. The catalyst-coated membrane according to any one of claims 12 to 14, wherein the electrically conductive ceramic material comprises iridium-tantalum oxide (lrxTai_x02), ruthenium-titanium oxide (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) or tantalum carbonitride (TaCxNy).

16. The catalyst-coated membrane according to any one of claims 12 to 15, wherein the electrically conductive ceramic material is a conductive oxide supported on a non-Date Recue/Date Received 2021-01-22 conductive oxide.

17. The catalyst-coated membrane according to claim 16, wherein the electrically conductive material supported on a non-conductive oxide is Ir02/Si02, Ir02/Ti02, Ir02/A1203 or Ir02/Zr02.

18. The catalyst-coated membrane according to claim 17, wherein the electrically conductive material is conductive iridium oxide supported on titanium oxide (I
r02/Ti02).

19. The catalyst-coated membrane according to any one of claims 12 to 18, wherein the weight ratio between the conductive material and the polymer binder is in the range of 0.5 to 50 wt.-% based on the total weight of the dry layer composition.

20. The catalyst-coated membrane according to any one of claims 12 to 19, having a layer thickness after drying in the range of 0.1 to 100 microns.

21. The catalyst-coated membrane according to any one of claims 12 to 20, wherein the gas diffusion electrode comprises a micro-porous layer.

22. The catalyst-coated membrane according to any one of claims 12 to 21, wherein the carbon-based gas diffusion layer comprises a micro-porous layer.

23. A gas diffusion electrode, comprising a carbon-based gas diffusion layer, optionally a micro-porous layer, and a barrier layer, wherein a catalyst layer is coated on the barrier layer, wherein said barrier layer comprises electrically conductive ceramic material and a non-ionomeric polymer binder, wherein the electrically conductive ceramic material comprises iridium-tantalum oxides (lrxTai_x02), ruthenium-titanium oxides (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxNi_x), Date Recue/Date Received 2021-01-22 tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titanium oxynitride (TiON), niobium doped titanium oxides (NbxTii_x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSni_x02) or any combination thereof, and wherein the non-ionomeric polymer binder is polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoroethylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoroeth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR), glassy amorphous fluoropolymers or any combination thereof.

24. The gas diffusion electrode according to claim 23, wherein the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm in air atmosphere as detected by a powder method.

25. The gas diffusion electrode according to claim 23 or 24, wherein the electrically conductive ceramic material has a high acid stability showing a solubility of < 10-3 mo1/1 upon acidic treatment in 1 M H2504 at 90 C.

26. The gas diffusion electrode according to any one of claims 23 to 25, wherein the electrically conductive ceramic material comprises iridium-tantalum oxide (IrxTai_x02), ruthenium-titanium oxide (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) or tantalum carbonitride (TaCxNy).

27. The gas diffusion electrode according to any one of claims 23 to 26, wherein the electrically conductive ceramic material is a conductive oxide supported on a non-conductive oxide.

28. The gas diffusion electrode according to claim 27, wherein the electrically conductive material supported on a non-conductive oxide is 1r02/Si02, 1r02/Ti02, 1r02/A1203 or 1r02/Zr02.
Date Recue/Date Received 2021-01-22

29. The gas diffusion electrode according to claim 28, wherein the electrically conductive material is conductive iridium oxide supported on titanium oxide (1r02/Ti02).

30. The gas diffusion electrode according to any one of claims 23 to 29, wherein the weight ratio between the conductive material and the polymer binder is in the range of 0.5 to 50 wt.-% based on the total weight of the dry layer composition.

31. The gas diffusion electrode according to any one of claims 23 to 30, having a layer thickness after drying in the range of 0.1 to 100 microns.

32. The gas diffusion electrode according to any one of claims 23 to 31, wherein the gas diffusion electrode comprises a micro-porous layer.

33. The gas diffusion electrode according to any one of claims 23 to 32, wherein the carbon-based gas diffusion layer comprises a micro-porous layer.

34. A carbon-based gas diffusion layer comprising a barrier layer and optionally a micro-porous layer, wherein said barrier layer comprises electrically conductive ceramic material and a non-ionomeric polymer binder, wherein the electrically conductive ceramic material comprises iridium-tantalum oxides (lrxTai_x02), ruthenium-titanium oxides (RuJii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx), tantalum carbonitride (TaCxN1-x), tungsten carbide (WC), titanium carbide (TiC), titanium nitride (TiN), titanium oxynitride (TiON), niobium doped titanium oxides (Nbx-iii_x02), nickel tantalum carbide (NixTayCz), niobium doped tin dioxide (NbxSni_x02) or any combination thereof, and wherein the non-ionomeric polymer binder is polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene copolymers (ETFE), fluorinated ethylene/propylene copolymers (FEP), tetrafluoroethylene/perfluoroalkoxyvinyl copolymers (PFA), polyvinylidene fluoride Date Recue/Date Received 2021-01-22 (PVDF), vinylidene fluoride (VDF) copolymers, tetrafluoroeth-ylene/hexafluoropropylene/vinylidene fluoride terpolymers (THV), perfluoro rubbers (PFR), glassy amorphous fluoropolymers or any combination thereof.

35. The carbon-based gas diffusion layer according to claim 34, wherein the electrically conductive ceramic material has an electrical conductivity of >0.1 S/cm in air atmosphere as detected by a powder method.

36. The carbon-based gas diffusion layer according to claim 34 or 35, wherein the electrically conductive ceramic material has a high acid stability showing a solubility of < 10-3 mol/l upon acidic treatment in 1 M H2SO4 at 90 C.

37. The carbon-based gas diffusion layer according to any one of claims 34 to 36, wherein the electrically conductive ceramic material comprises iridium-tantalum oxide (lrxTai_x02), ruthenium-titanium oxide (RuxTii_x02), titanium diboride (TiB2), molybdenum nitride (Mo2N), tantalum carbide (TaCx) or tantalum carbonitride (TaCxNy).

38. The carbon-based gas diffusion layer according to any one of claims 34 to 37, wherein the electrically conductive ceramic material is a conductive oxide supported on a non-conductive oxide.

39. The carbon-based gas diffusion layer according to claim 38, wherein the electrically conductive material supported on a non-conductive oxide is Ir02/Si02, Ir02/Ti02, Ir02/A1203 or Ir02/Zr02.

40. The carbon-based gas diffusion layer according to claim 39, wherein the electrically conductive material is conductive iridium oxide supported on titanium oxide (I
r02/Ti02).

41. The carbon-based gas diffusion layer according to any one of claims 34 to 40, wherein the weight ratio between the conductive material and the polymer binder is in the range of 0.5 to 50 wt.-% based on the total weight of the dry layer composition.
Date Recue/Date Received 2021-01-22

42. The carbon-based gas diffusion layer according to any one of claims 34 to 41, having a layer thickness after drying in the range of 0.1 to 100 microns.

43. The carbon-based gas diffusion layer according to any one of claims 34 to 42, wherein the gas diffusion electrode comprises a micro-porous layer.

44. The carbon-based gas diffusion layer according to any one of claims 34 to 43, wherein the carbon-based gas diffusion layer comprises a micro-porous layer.

45. An electrochemical device, comprising the membrane-electrode assembly as defined in any one of claims 1 to 11 or the catalyst-coated membrane as defined in any one of claims 12 to 22, wherein the at least one barrier layer is positioned on the cathode side, on the anode side or both sides of said electrochemical device.

46. Use of the membrane electrode assembly as defined in any one of claims 1 to 11, the catalyst-coated membrane as defined in any one of claims 12 to 22, the gas diffusion electrode as defined in any one of claims 23 to 33, or the carbon-based gas diffusion layer as defined in any one of claims 34 to 44 in PEM fuel cells, PEM electrolysers, regenerative PEM fuel cells, or batteries.
Date Recue/Date Received 2021-01-22