CA2803030C - Use of sugars in a stabilization matrix and solid compositions - Google Patents
Use of sugars in a stabilization matrix and solid compositions Download PDFInfo
- Publication number
- CA2803030C CA2803030C CA2803030A CA2803030A CA2803030C CA 2803030 C CA2803030 C CA 2803030C CA 2803030 A CA2803030 A CA 2803030A CA 2803030 A CA2803030 A CA 2803030A CA 2803030 C CA2803030 C CA 2803030C
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- CA
- Canada
- Prior art keywords
- composition
- sugar
- water
- carbonate
- solidification matrix
- Prior art date
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- 239000011159 matrix material Substances 0.000 title claims abstract description 68
- 235000000346 sugar Nutrition 0.000 title claims abstract description 64
- 150000008163 sugars Chemical class 0.000 title abstract description 11
- 230000006641 stabilisation Effects 0.000 title abstract description 4
- 238000011105 stabilization Methods 0.000 title abstract description 4
- 239000008247 solid mixture Substances 0.000 title description 17
- 239000000203 mixture Substances 0.000 claims abstract description 206
- 239000013042 solid detergent Substances 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000007711 solidification Methods 0.000 claims description 75
- 230000008023 solidification Effects 0.000 claims description 75
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 59
- -1 optical brighteners Substances 0.000 claims description 50
- 239000000463 material Substances 0.000 claims description 42
- 239000004094 surface-active agent Substances 0.000 claims description 32
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 238000005260 corrosion Methods 0.000 claims description 20
- 230000007797 corrosion Effects 0.000 claims description 20
- 150000005846 sugar alcohols Chemical class 0.000 claims description 18
- 239000002562 thickening agent Substances 0.000 claims description 16
- 239000003112 inhibitor Substances 0.000 claims description 15
- 239000008204 material by function Substances 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 229930006000 Sucrose Natural products 0.000 claims description 12
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 12
- 239000005720 sucrose Substances 0.000 claims description 12
- 239000007844 bleaching agent Substances 0.000 claims description 10
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
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- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 7
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- HVTHJRMZXBWFNE-UHFFFAOYSA-J sodium zincate Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Zn+2] HVTHJRMZXBWFNE-UHFFFAOYSA-J 0.000 description 1
- CCGZTJIIHNUAQA-UHFFFAOYSA-M sodium;2-[2-hydroxyethyl-(octadecanoylamino)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)NN(CCO)CC([O-])=O CCGZTJIIHNUAQA-UHFFFAOYSA-M 0.000 description 1
- DHKNRPIHFUTNOW-UHFFFAOYSA-M sodium;3-[(dodecanoylamino)-(2-hydroxyethyl)amino]propanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)NN(CCO)CCC([O-])=O DHKNRPIHFUTNOW-UHFFFAOYSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- PZDOWFGHCNHPQD-VNNZMYODSA-N sophorose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](C=O)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PZDOWFGHCNHPQD-VNNZMYODSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- VXYADVIJALMOEQ-UHFFFAOYSA-K tris(lactato)aluminium Chemical compound CC(O)C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O VXYADVIJALMOEQ-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- GTQFPPIXGLYKCZ-UHFFFAOYSA-L zinc chlorate Chemical compound [Zn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O GTQFPPIXGLYKCZ-UHFFFAOYSA-L 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- 239000011670 zinc gluconate Substances 0.000 description 1
- 235000011478 zinc gluconate Nutrition 0.000 description 1
- 229960000306 zinc gluconate Drugs 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- TUDPEWOTGHYZBQ-UHFFFAOYSA-L zinc;dibromate Chemical compound [Zn+2].[O-]Br(=O)=O.[O-]Br(=O)=O TUDPEWOTGHYZBQ-UHFFFAOYSA-L 0.000 description 1
- MLVWCBYTEFCFSG-UHFFFAOYSA-L zinc;dithiocyanate Chemical compound [Zn+2].[S-]C#N.[S-]C#N MLVWCBYTEFCFSG-UHFFFAOYSA-L 0.000 description 1
- KHADWTWCQJVOQO-UHFFFAOYSA-N zinc;oxido-(oxido(dioxo)chromio)oxy-dioxochromium Chemical compound [Zn+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KHADWTWCQJVOQO-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/268—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0052—Cast detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/870,588 | 2010-08-27 | ||
| US12/870,588 US8975221B2 (en) | 2010-08-27 | 2010-08-27 | Use of sugars in a stabilization matrix and solid compositions |
| PCT/IB2011/053739 WO2012025902A2 (en) | 2010-08-27 | 2011-08-25 | Use of sugars in a stabilization matrix and solid compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2803030A1 CA2803030A1 (en) | 2012-03-01 |
| CA2803030C true CA2803030C (en) | 2020-01-21 |
Family
ID=45698034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2803030A Active CA2803030C (en) | 2010-08-27 | 2011-08-25 | Use of sugars in a stabilization matrix and solid compositions |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US8975221B2 (enExample) |
| EP (1) | EP2609187B1 (enExample) |
| JP (2) | JP5856168B2 (enExample) |
| CN (1) | CN103038329B (enExample) |
| AU (1) | AU2011294721B2 (enExample) |
| BR (1) | BR112013003965A2 (enExample) |
| CA (1) | CA2803030C (enExample) |
| ES (1) | ES2759018T3 (enExample) |
| MX (1) | MX356178B (enExample) |
| WO (1) | WO2012025902A2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
| CA2876338C (en) * | 2012-08-03 | 2019-04-09 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
| US9133420B2 (en) | 2013-01-08 | 2015-09-15 | Ecolab Usa Inc. | Methods of using enzyme compositions |
| CN104419544A (zh) * | 2013-08-22 | 2015-03-18 | 南通丝乡丝绸有限公司 | 一种丝绸凉席擦洗剂 |
| JP2017503061A (ja) | 2013-11-11 | 2017-01-26 | エコラボ ユーエスエー インコーポレイティド | 多目的酵素洗剤及び使用溶液を安定化する方法 |
| US9624119B2 (en) | 2014-06-13 | 2017-04-18 | Ecolab Usa Inc. | Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations |
| WO2018200927A1 (en) * | 2017-04-27 | 2018-11-01 | Ecolab Usa Inc. | Solid controlled release carbonate detergent compositions |
| WO2019099059A1 (en) | 2017-11-14 | 2019-05-23 | Ecolab Usa Inc. | Solid controlled release caustic detergent compositions |
| DE102018123920A1 (de) * | 2018-09-27 | 2020-04-02 | Buck Service Gmbh | Mittel zur Reinigung von Wäsche |
| EP3786267A1 (en) * | 2019-08-29 | 2021-03-03 | Dr. Schnell GmbH & Co KGaA | Cleaning composition |
| CA3151823A1 (en) | 2019-09-27 | 2021-04-01 | Ecolab Usa Inc. | Concentrated 2 in 1 dishmachine detergent and rinse aid |
| EP3835400A1 (en) * | 2019-12-10 | 2021-06-16 | Kevin Orchard Co., Ltd. | Solid detergent |
| CN120897986A (zh) * | 2023-04-05 | 2025-11-04 | 埃科莱布美国股份有限公司 | 用于柜台下机器器皿洗涤的固体2合1洗涤剂漂洗配方 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| BE617684A (enExample) | 1961-05-15 | |||
| US3701735A (en) * | 1971-04-12 | 1972-10-31 | Colgate Palmolive Co | Automatic dishwashing compositions |
| US4102799A (en) * | 1974-08-29 | 1978-07-25 | Colgate-Palmolive Company | Automatic dishwasher detergent with improved effects on overglaze |
| USRE32763E (en) * | 1978-02-07 | 1988-10-11 | Ecolab Inc. | Cast detergent-containing article and method of making and using |
| JPS60189108A (ja) | 1984-03-08 | 1985-09-26 | 日本石油化学株式会社 | 電気絶縁油 |
| DE3417820A1 (de) | 1984-05-14 | 1985-11-14 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung eines waschzusatzes in tablettenform |
| GB2174712B (en) * | 1985-05-10 | 1988-10-19 | Unilever Plc | Detergent granules |
| GB8626691D0 (en) * | 1986-11-07 | 1986-12-10 | Unilever Plc | Detergent composition |
| US4782901A (en) | 1986-12-12 | 1988-11-08 | Mobil Oil Corporation | Minimizing gravity override of carbon dioxide with a gel |
| US4830773A (en) | 1987-07-10 | 1989-05-16 | Ecolab Inc. | Encapsulated bleaches |
| GB8716899D0 (en) * | 1987-07-17 | 1987-08-26 | Unilever Plc | Detergent compositions |
| US5264144A (en) * | 1991-05-30 | 1993-11-23 | The Procter & Gamble Company | Freezer personal cleansing bar with selected fatty acid soaps for improved mildness and good lather |
| US5152911A (en) | 1991-10-11 | 1992-10-06 | Church & Dwight Co., Inc. | Non-phosphate machine dishwashing detergents |
| US5279756A (en) | 1992-08-27 | 1994-01-18 | Church & Dwight Co., Inc. | Non-phosphate machine dishwashing detergents |
| CA2160342A1 (en) * | 1993-04-23 | 1994-11-10 | Thomas Edward Huetter | Method of making a tartar control baking soda dentrifice |
| US5545348A (en) | 1994-11-02 | 1996-08-13 | Church & Dwight Co., Inc. | Non-Phosphate high carbonate machine dishwashing detergents containing maleic acid homopolymer |
| US5786320A (en) | 1996-02-01 | 1998-07-28 | Henkel Corporation | Process for preparing solid cast detergent products |
| US6017864A (en) * | 1997-12-30 | 2000-01-25 | Ecolab Inc. | Alkaline solid block composition |
| EP1071738A1 (en) * | 1998-03-18 | 2001-01-31 | Ecolab Inc. | Solid block enzymatic cleaning with electrolytic control for clean-in-place systems |
| US6770616B1 (en) * | 1999-03-04 | 2004-08-03 | The Procter & Gamble Company | Detergent tablet |
| FR2791973B1 (fr) | 1999-04-08 | 2001-07-27 | Roquette Freres | Adjuvants pour liants mineraux, a base d'un produit de deshydratation interne d'un sucre hydrogene, liants mineraux adjuvantes et leur procede de preparation |
| JP3352977B2 (ja) | 1999-06-15 | 2002-12-03 | 花王株式会社 | 固形状洗剤 |
| DE10015661A1 (de) | 2000-03-29 | 2001-10-31 | Henkel Kgaa | Wasch- und Reinigungsmittelformkörper mit speziellem Tensidgranulat |
| DE60123263D1 (de) | 2000-10-25 | 2006-11-02 | Unilever Nv | Geschirrspuelmittelzusammensetzungen |
| EP1216783A1 (fr) | 2000-12-08 | 2002-06-26 | L'air Liquide, S.A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude | Procédé et système pour résoudre un problème se posant lors d'une opération de soudage ou analogue |
| JP2002348594A (ja) | 2001-05-25 | 2002-12-04 | Asahi Denka Kogyo Kk | 固形ブロック洗浄剤組成物およびその製造方法 |
| US20030162685A1 (en) * | 2001-06-05 | 2003-08-28 | Man Victor Fuk-Pong | Solid cleaning composition including stabilized active oxygen component |
| US20050148488A1 (en) * | 2002-05-15 | 2005-07-07 | Maren Jekel | Detergent tablets with active phase |
| US20060172059A1 (en) | 2002-12-19 | 2006-08-03 | Kanou Takeuchi | Method of inhibiting water content variation of composition and use thereof |
| US7423005B2 (en) * | 2003-11-20 | 2008-09-09 | Ecolab Inc. | Binding agent for solidification matrix |
| FR2871155B1 (fr) | 2004-06-02 | 2007-04-27 | Roquette Freres | Utilisation de polysaccharides particuliers pour l'adjuvantation de matieres minerales |
| JP5002580B2 (ja) * | 2005-03-18 | 2012-08-15 | スリーエム イノベイティブ プロパティズ カンパニー | 加熱食品調理面用の固形クリーナー |
| US7964544B2 (en) | 2005-10-31 | 2011-06-21 | Ecolab Usa Inc. | Cleaning composition and method for preparing a cleaning composition |
| US7828905B2 (en) * | 2007-05-04 | 2010-11-09 | Ecolab Inc. | Cleaning compositions containing water soluble magnesium compounds and methods of using them |
| US7888303B2 (en) * | 2007-05-04 | 2011-02-15 | Ecolab Inc. | Solidification matrix |
| US7893012B2 (en) * | 2007-05-04 | 2011-02-22 | Ecolab Inc. | Solidification matrix |
| US7763576B2 (en) * | 2008-01-04 | 2010-07-27 | Ecolab Inc. | Solidification matrix using a polycarboxylic acid polymer |
| US7759300B2 (en) | 2007-07-02 | 2010-07-20 | Ecolab Inc. | Solidification matrix including a salt of a straight chain saturated mono-, di-, or tri- carboxylic acid |
| US8759269B2 (en) * | 2007-07-02 | 2014-06-24 | Ecolab Usa Inc. | Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid |
| US8889048B2 (en) * | 2007-10-18 | 2014-11-18 | Ecolab Inc. | Pressed, self-solidifying, solid cleaning compositions and methods of making them |
| US8198228B2 (en) * | 2008-01-04 | 2012-06-12 | Ecolab Usa Inc. | Solidification matrix using an aminocarboxylate |
| US8138138B2 (en) * | 2008-01-04 | 2012-03-20 | Ecolab Usa Inc. | Solidification matrix using a polycarboxylic acid polymer |
| US8216989B2 (en) * | 2009-08-26 | 2012-07-10 | Ecolab Usa Inc. | Cleaning composition for removing/preventing redeposition of protein soils |
| US8822403B2 (en) * | 2011-01-20 | 2014-09-02 | Ecolab Usa Inc. | Detergent composition including a saccharide or sugar alcohol |
-
2010
- 2010-08-27 US US12/870,588 patent/US8975221B2/en active Active
-
2011
- 2011-08-25 WO PCT/IB2011/053739 patent/WO2012025902A2/en not_active Ceased
- 2011-08-25 BR BR112013003965A patent/BR112013003965A2/pt not_active Application Discontinuation
- 2011-08-25 EP EP11819510.6A patent/EP2609187B1/en active Active
- 2011-08-25 AU AU2011294721A patent/AU2011294721B2/en active Active
- 2011-08-25 JP JP2013525411A patent/JP5856168B2/ja active Active
- 2011-08-25 MX MX2013001467A patent/MX356178B/es active IP Right Grant
- 2011-08-25 CN CN201180037697.4A patent/CN103038329B/zh active Active
- 2011-08-25 CA CA2803030A patent/CA2803030C/en active Active
- 2011-08-25 ES ES11819510T patent/ES2759018T3/es active Active
-
2015
- 2015-01-29 US US14/608,616 patent/US9902924B2/en active Active
- 2015-12-10 JP JP2015241042A patent/JP6404809B2/ja active Active
-
2018
- 2018-01-10 US US15/867,392 patent/US20180134996A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP6404809B2 (ja) | 2018-10-17 |
| WO2012025902A2 (en) | 2012-03-01 |
| ES2759018T3 (es) | 2020-05-07 |
| US20180134996A1 (en) | 2018-05-17 |
| BR112013003965A2 (pt) | 2016-07-12 |
| JP2016033231A (ja) | 2016-03-10 |
| US20150141318A1 (en) | 2015-05-21 |
| EP2609187A2 (en) | 2013-07-03 |
| MX356178B (es) | 2018-05-17 |
| US8975221B2 (en) | 2015-03-10 |
| AU2011294721A1 (en) | 2013-01-24 |
| AU2011294721B2 (en) | 2015-07-02 |
| EP2609187A4 (en) | 2017-04-26 |
| JP2013538269A (ja) | 2013-10-10 |
| CN103038329A (zh) | 2013-04-10 |
| WO2012025902A3 (en) | 2012-07-19 |
| US20120053110A1 (en) | 2012-03-01 |
| JP5856168B2 (ja) | 2016-02-09 |
| EP2609187B1 (en) | 2019-09-25 |
| CA2803030A1 (en) | 2012-03-01 |
| US9902924B2 (en) | 2018-02-27 |
| CN103038329B (zh) | 2015-08-12 |
| MX2013001467A (es) | 2013-05-14 |
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