CA2795834A1 - Fibrous composition for paper and card production - Google Patents

Fibrous composition for paper and card production Download PDF

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Publication number
CA2795834A1
CA2795834A1 CA2795834A CA2795834A CA2795834A1 CA 2795834 A1 CA2795834 A1 CA 2795834A1 CA 2795834 A CA2795834 A CA 2795834A CA 2795834 A CA2795834 A CA 2795834A CA 2795834 A1 CA2795834 A1 CA 2795834A1
Authority
CA
Canada
Prior art keywords
pulp
oxidized
paper
composition according
mmol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2795834A
Other languages
French (fr)
Inventor
Christian Jehn-Rendu
Hans-Georg Lemaire
Oliver Koch
Tilo Habicher
Sylke Haremza
Markus Hoffmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2795834A1 publication Critical patent/CA2795834A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/005Treatment of cellulose-containing material with microorganisms or enzymes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/20Chemically or biochemically modified fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/10Retention agents or drainage improvers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents

Abstract

The present invention relates to a novel fibrous composition for paper or card production, which contains an oxidized wastepaper stuff and/or an oxidized mechanical stuff into which 1 to 500 mmol of carboxyl groups per kg and 1 to 200 mmol of aldehyde groups per kg were introduced by oxidation. The invention also relates to paper and card based on such a fibrous composition and also to a process for producing such a paper or card. The invention also relates to the use of oxidized wastepaper stuff and/or oxidized mechanical stuff to improve the retention and drainage properties of a stuff suitable for the production of paper or card. The invention further relates to the use of oxidized wastepaper stuff and/or oxidized mechanical stuff to improve, i.e. enhance, the dry strength of paper and card.

Claims (22)

1. A pulp composition for paper or solid board production, comprising a) at least one chemical pulp A, and b) at least one oxidized pulp B in which, by oxidation of at least one conventional pulp selected from the group consisting of recovered paper pulp, mechanical pulp and mixtures thereof, from 1 to 500 mmol of carboxyl groups and from 1 to 200 mmol of aldehyde groups per kg of conventional pulp have been introduced, and c) at least one further conventional pulp C other than A and B;
wherein the total amount of the constituents A and B accounts for from 30% to 80% by weight of the entire pulp mass in the pulp composition, and the constituents A, B and C account for at least 70%, more particularly at least 80%, of the entire pulp mass in the pulp composition, each reckoned as oven dry material.
2. The pulp composition according to claim 1 wherein the molar ratio in the oxidized pulp of the aldehyde groups introduced to the carboxyl groups introduced is not more than 1:1.
3. The pulp composition according to either of the preceding claims, comprising the oxidized pulp B and the pulp C in a total amount of 70% to 98% by weight, based on the total weight of the pulp mass in the pulp composition.
4. The pulp composition according to any preceding claim wherein the oxidized pulp accounts for at least 50% by weight, based on the total amount of oxidized pulp B
and chemical pulp A.
5. The pulp composition according to any preceding claim wherein the oxidized pulp is selected from an oxidized recovered paper pulp.
6. The pulp composition according to any preceding claim wherein the pulp C is selected from conventional mechanical and thermomechanical pulp and conventional recovered paper pulp.
7. The pulp composition according to any preceding claim wherein the oxidized pulp is obtainable by oxidation of a conventional pulp with oxygen in the presence of a laccase.
8. The pulp composition according to claim 7 wherein the oxidation is carried in the additional presence of a redox mediator.
9. The pulp composition according to claim 8 wherein the redox mediator is a sterically hindered amine oxide compound.
10. A paper stock wherein the fiber constituents are a pulp composition according to any one of claims 1 to 9.
11. A paper or solid board based on a pulp composition according to any one of claims 1 to 9.
12. A process for producing a paper or solid board, comprising i) producing an aqueous fiber suspension comprising a) at least one chemical pulp A, and b) at least one oxidized pulp B in which, by oxidation of at least one conventional pulp selected from the group consisting of recovered paper pulp, mechanical pulp and mixtures thereof, from 1 to 500 mmol of carboxyl groups and from 1 to 200 mmol of aldehyde groups per kg of conventional pulp have been introduced, and c) at least one further conventional pulp C other than A and B, comprising suspending the pulps in water and optionally adding customary additives and fillers, and ii) draining the fiber suspension in a paper machine to form paper or solid board, wherein the relative amount of the pulps are chosen such that the total amount of the constituents A and B accounts for from 30% to 80% by weight of the entire pulp mass in the fiber suspension, and the total amount of the constituents A, B
and C accounts for at least 70% of the entire pulp mass in the pulp composition, each reckoned as oven dry material.
13. The process according to claim 12 wherein the molar ratio in the oxidized pulp of the aldehyde groups introduced to the carboxyl groups introduced is not more than 1:1.
14. The process according to claim 12 or 13 wherein the oxidized pulp B and the pulp C account for from 70% to 98% by weight of the total pulp mass in the fiber suspension, each reckoned as oven dry material.
15. The process according to claim 12, claim 13 or claim 14 wherein the oxidized pulp accounts for at least 50% by weight, based on the total amount of oxidized pulp B and chemical pulp A in the fiber suspension.
16. The process according to any one of claims 12 to 15 wherein the oxidized pulp is selected from oxidized recovered paper pulp.
17. The process according to any one of claims 12 to 16 wherein the pulp C is selected from conventional mechanical and thermomechanical pulp and conventional recovered paper pulp.
18. The process according to any one of claims 12 to 17 wherein the paper is writing or printing paper.
19. The process according to any one of claims 12 to 17 wherein the paper is packaging paper.
20. The process according to any one of claims 12 to 17 wherein solid board is concerned.
21. The use of an oxidized pulp B in which, by oxidation of at least one conventional pulp selected from the group consisting of recovered paper pulp, mechanical pulp and mixtures thereof, from 1 to 500 mmol of carboxyl groups and from 1 to 200 mmol of aldehyde groups per kg of conventional pulp have been introduced, for improving the retention properties of pulp compositions for paper or solid board production which comprise at least one chemical pulp and at least one further pulp selected from mechanical, chemomechanical and conventional recovered paper pulp.
22. The use according to claim 21 wherein the oxidized pulp is selected from oxidized recovered paper pulp.
CA2795834A 2010-05-05 2011-05-04 Fibrous composition for paper and card production Abandoned CA2795834A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10162028 2010-05-05
EP10162028.4 2010-05-05
PCT/EP2011/057134 WO2011138366A1 (en) 2010-05-05 2011-05-04 Fibrous composition for paper and card production

Publications (1)

Publication Number Publication Date
CA2795834A1 true CA2795834A1 (en) 2011-11-10

Family

ID=44318338

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2795834A Abandoned CA2795834A1 (en) 2010-05-05 2011-05-04 Fibrous composition for paper and card production

Country Status (5)

Country Link
EP (1) EP2567024A1 (en)
CN (1) CN102869830A (en)
BR (1) BR112012027210A2 (en)
CA (1) CA2795834A1 (en)
WO (1) WO2011138366A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103556517A (en) * 2013-10-31 2014-02-05 昆明理工大学 Method for improving oxygen-alkali pulping effect through laccase pretreatment

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102677496B (en) * 2012-05-29 2015-07-01 宜宾丝丽雅集团有限公司 Material preparation process for preparing dissolving pulp by modifying bleached bamboo-wood composite pulp
CN104213448A (en) * 2014-08-28 2014-12-17 华南理工大学 Laccase/glutamic acid-based biological treatment method for inhibiting strength degradation of regenerated fibers
CN105064133B (en) * 2015-07-07 2017-04-19 浙江华川实业集团有限公司 High-toughness wear resistant cardboard and making method thereof

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Publication number Priority date Publication date Assignee Title
JPH02238885A (en) 1989-03-13 1990-09-21 Oji Paper Co Ltd Phenol oxidase gene recombination dna, microorganism transformed with same recombinant dna, culture mixture thereof and production of phenol oxidase
US5167766A (en) 1990-06-18 1992-12-01 American Cyanamid Company Charged organic polymer microbeads in paper making process
FI903443A (en) 1990-07-06 1992-01-07 Valtion Teknillinen FRAMSTAELLNING AV LACKAS GENOM REKOMBINANTORGANISMER.
DK77393D0 (en) 1993-06-29 1993-06-29 Novo Nordisk As ENZYMER ACTIVATION
US5912405A (en) 1994-09-27 1999-06-15 Novo Nordisk A/S Enhancers such as acetosyringone
US20030192664A1 (en) 1995-01-30 2003-10-16 Kulick Russell J. Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-making
FI974139A (en) 1997-11-04 1999-05-05 Valtion Teknillinen A method for modifying cellulose
ATE324384T1 (en) * 1999-02-24 2006-05-15 Sca Hygiene Prod Gmbh OXIDIZED CELLULOSE-CONTAINING FIBER MATERIALS AND PRODUCTS MADE THEREFROM
US6379494B1 (en) 1999-03-19 2002-04-30 Weyerhaeuser Company Method of making carboxylated cellulose fibers and products of the method
DE60023563T2 (en) * 1999-05-06 2006-07-27 Novozymes A/S Process for the production of paper materials with improved wet strength
US6368456B1 (en) 1999-08-17 2002-04-09 National Starch And Chemical Investment Holding Corporation Method of making paper from aldehyde modified cellulose pulp with selected additives
US6695950B1 (en) * 1999-08-17 2004-02-24 National Starch And Chemical Investment Holding Corporation Aldehyde modified cellulose pulp for the preparation of high strength paper products
US6228126B1 (en) 1999-08-17 2001-05-08 National Starch And Chemical Investment Holding Corporation Paper prepared from aldehyde modified cellulose pulp and the method of making the pulp
TW550325B (en) 1999-11-08 2003-09-01 Ciba Spec Chem Water Treat Ltd Manufacture of paper and paperboard
TW483970B (en) 1999-11-08 2002-04-21 Ciba Spec Chem Water Treat Ltd A process for making paper and paperboard
MY140287A (en) 2000-10-16 2009-12-31 Ciba Spec Chem Water Treat Ltd Manufacture of paper and paperboard
US20050028956A1 (en) * 2003-08-05 2005-02-10 Weyerhaeuser Company Method for making tissue product containing carboxylated cellulosic fibers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103556517A (en) * 2013-10-31 2014-02-05 昆明理工大学 Method for improving oxygen-alkali pulping effect through laccase pretreatment
CN103556517B (en) * 2013-10-31 2016-11-23 昆明理工大学 A kind of laccase pretreatment improves the method for oxygen alkali pulping effect

Also Published As

Publication number Publication date
CN102869830A (en) 2013-01-09
EP2567024A1 (en) 2013-03-13
BR112012027210A2 (en) 2016-07-26
WO2011138366A1 (en) 2011-11-10

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Effective date: 20150505