CA2698904C - Procede de preparation de polymeres fonctionnalises par catalyse enzymatique - Google Patents

Procede de preparation de polymeres fonctionnalises par catalyse enzymatique Download PDF

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Publication number
CA2698904C
CA2698904C CA2698904A CA2698904A CA2698904C CA 2698904 C CA2698904 C CA 2698904C CA 2698904 A CA2698904 A CA 2698904A CA 2698904 A CA2698904 A CA 2698904A CA 2698904 C CA2698904 C CA 2698904C
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Prior art keywords
peg
ppm
functionalized
vinyl
poly
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Expired - Fee Related
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CA2698904A
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CA2698904A1 (fr
Inventor
Judit E. Puskas
Mustafa Yasin Sen
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University of Akron
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University of Akron
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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/001—Amines; Imines
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
    • C12P17/10—Nitrogen as only ring hetero atom
    • C12P17/12—Nitrogen as only ring hetero atom containing a six-membered hetero ring
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P9/00—Preparation of organic compounds containing a metal or atom other than H, N, C, O, S or halogen

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention concerne des polymères fonctionnalisés, téléchéliques synthétisés par une catalyse et des procédés enzymatiques, et la fonctionnalisation de polymères par lintermédiaire dune addition de Michael avec un catalyseur lipase, et la réticulation de polymères mono- ou difonctionnels (téléchéliques) fabriqués par catalyse enzymatique, comme par lutilisation des agents de couplage multifonctionnels et des catalyseurs enzymatiques. Une transestérification quantitative du méthacrylate de vinyle avec le poly(éthylène glycol), le poly(isobutylène) et le poly(diméthylsiloxane) a été obtenue en utilisant la lipase B de Catadida matarctica. En outre, léther monométhylique du poly(éthylène glycol) fonctionnalisé par des méthacrylates a été couplé avec succès à léther monométhylique de laminoéthoxy poly(éthylène glycol) par lintermédiaire dune addition de Michael en utilisant la lipase B de Candida antarctica. Les poly(éthylène glycols) fonctionnalisés par des amines ont également été utilisés pour la préparation de dendrimères et de gels à base de poly(éthylène glycol) par le biais dune addition de Michael du polymère sur la triacryloyl hexahydro-triazine en utilisant la même enzyme. Les spectroscopies RMN 1H et 13C ont permis de vérifier la structure des polymères fonctionnalisés.
CA2698904A 2010-04-01 2010-04-01 Procede de preparation de polymeres fonctionnalises par catalyse enzymatique Expired - Fee Related CA2698904C (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2698904A CA2698904C (fr) 2010-04-01 2010-04-01 Procede de preparation de polymeres fonctionnalises par catalyse enzymatique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA2698904A CA2698904C (fr) 2010-04-01 2010-04-01 Procede de preparation de polymeres fonctionnalises par catalyse enzymatique

Publications (2)

Publication Number Publication Date
CA2698904A1 CA2698904A1 (fr) 2011-10-01
CA2698904C true CA2698904C (fr) 2019-01-08

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CA2698904A Expired - Fee Related CA2698904C (fr) 2010-04-01 2010-04-01 Procede de preparation de polymeres fonctionnalises par catalyse enzymatique

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CA (1) CA2698904C (fr)

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Publication number Publication date
CA2698904A1 (fr) 2011-10-01

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