CA2673175A1 - Process for producing tissue paper - Google Patents
Process for producing tissue paper Download PDFInfo
- Publication number
- CA2673175A1 CA2673175A1 CA002673175A CA2673175A CA2673175A1 CA 2673175 A1 CA2673175 A1 CA 2673175A1 CA 002673175 A CA002673175 A CA 002673175A CA 2673175 A CA2673175 A CA 2673175A CA 2673175 A1 CA2673175 A1 CA 2673175A1
- Authority
- CA
- Canada
- Prior art keywords
- wood
- fibrous material
- digestion
- chemicals
- oven
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 80
- 230000008569 process Effects 0.000 title claims description 76
- 239000002023 wood Substances 0.000 claims abstract description 110
- 229920005610 lignin Polymers 0.000 claims abstract description 53
- 239000000835 fiber Substances 0.000 claims abstract description 29
- 239000000725 suspension Substances 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims description 124
- 230000029087 digestion Effects 0.000 claims description 114
- 239000002657 fibrous material Substances 0.000 claims description 94
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 14
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 13
- 238000007670 refining Methods 0.000 claims description 13
- 239000007791 liquid phase Substances 0.000 claims description 11
- 229920002522 Wood fibre Polymers 0.000 claims description 10
- 239000012808 vapor phase Substances 0.000 claims description 10
- 239000002025 wood fiber Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 239000011121 hardwood Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 43
- 241000196324 Embryophyta Species 0.000 description 31
- 235000019641 whiteness Nutrition 0.000 description 12
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 11
- 150000004056 anthraquinones Chemical class 0.000 description 11
- 239000000123 paper Substances 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 6
- 238000003825 pressing Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011368 organic material Substances 0.000 description 5
- 235000018185 Betula X alpestris Nutrition 0.000 description 4
- 235000018212 Betula X uliginosa Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000012978 lignocellulosic material Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 235000010265 sodium sulphite Nutrition 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 235000014633 carbohydrates Nutrition 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 241001263092 Alchornea latifolia Species 0.000 description 2
- 244000166124 Eucalyptus globulus Species 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 235000014466 Douglas bleu Nutrition 0.000 description 1
- 240000003433 Miscanthus floridulus Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 240000001416 Pseudotsuga menziesii Species 0.000 description 1
- 235000005386 Pseudotsuga menziesii var menziesii Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 210000003484 anatomy Anatomy 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- LPHFLPKXBKBHRW-UHFFFAOYSA-L magnesium;hydrogen sulfite Chemical compound [Mg+2].OS([O-])=O.OS([O-])=O LPHFLPKXBKBHRW-UHFFFAOYSA-L 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
- D21C3/06—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
- D21F11/145—Making cellulose wadding, filter or blotting paper including a through-drying process
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/06—Sulfite or bisulfite pulp
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
Abstract
The invention relates to a method for the production of a tissue web (1) produced from a material suspension comprising fibers. To this end, the volume and the tear length is to be improved, with minimized freeness degree, such that the material suspension comprises lignocellulosic pulp of wood or annuals, which has a tear length of more than 6.5 km at 12 °SR, or a tear length of more than 8.0 km at 15°SR, and a lignin content of at least 15% in relation to the otro pulp for coniferous wood in an unbleached state, or a tear length of more than 4.5 km at 20 °SR, and a lignin content of at least 12% in relation to the otro pulp for hardwood in an unbleached state, or a tear length of more than 3.5 km at 20 °SR, and a lignin content of at least 10% in relation to the otro pulp for annuals in an unbleached state.
Description
Process for producing tissue paper The invention relates to a process for producing a tissue web, which is produced from a stock suspension comprising fibers.
The invention also relates to a process for producing a stock suspension for use in particular for the production of tissue webs.
Tissue products are currently mainly produced from fully cellulosic materials, in particular kraft pulps.
Mechanically produced fibrous materials find only limited use, since here the tendency to yellowing and the poor strength properties of the stocks prevent widespread use.
Common mixture ratios between long fiber and short fiber stocks lie in the region of 50:50.
The porosity and the permeability of the tissue paper are determined critically by the freeness of the fibers in the stock suspension from which the tissue paper is produced.
Here, a high freeness necessitates a high content of fines in the suspension, which leads to lower porosity and permeability.
Furthermore, a high freeness causes a high water retention value for the fibers of the stock suspension, which means that the tissue paper is difficult to dewater during its production.
At high machine speeds, the poor dewatering ability often results in too low a dryness during production.
The invention also relates to a process for producing a stock suspension for use in particular for the production of tissue webs.
Tissue products are currently mainly produced from fully cellulosic materials, in particular kraft pulps.
Mechanically produced fibrous materials find only limited use, since here the tendency to yellowing and the poor strength properties of the stocks prevent widespread use.
Common mixture ratios between long fiber and short fiber stocks lie in the region of 50:50.
The porosity and the permeability of the tissue paper are determined critically by the freeness of the fibers in the stock suspension from which the tissue paper is produced.
Here, a high freeness necessitates a high content of fines in the suspension, which leads to lower porosity and permeability.
Furthermore, a high freeness causes a high water retention value for the fibers of the stock suspension, which means that the tissue paper is difficult to dewater during its production.
At high machine speeds, the poor dewatering ability often results in too low a dryness during production.
For instance, before the Yankee drying cylinder a certain dryness is needed in order to prevent lifting of the tissue paper web as a result of its contact with the hot circumferential surface of the tissue drying cylinder.
In addition, the tissue must be tear-resistant.
The tearing strength is determined both by the production process and by the freeness of the fibers.
In order to increase the tearing strength, the tissue paper must be consolidated during its production. In order to obtain a high tearing strength, the proportion of fines must also be high.
The requirements on the tearing strength thus contradict the requirements on the water absorption capacity, the absorbency and the dewatering ability.
The object of the invention is therefore the production of tissue paper with a high specific volume, as high a tearing length as possible, with the lowest possible freeness.
According to the invention, the object is achieved in that the stock suspension contains lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 6. 0 km at 12 SR or a tearing length of more than 7.5 km at 15 SR and a lignin content of at least 15%, based on the oven-dry fibrous material, for coniferous wood in the unbleached state, or a tearing length of more than 4.5 km at 20 SR
and a lignin content of at least 12%, based on the oven-dry fibrous material, for deciduous wood in the unbleached state, or a tearing length of more than 3.5 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the unbleached state.
In addition, the tissue must be tear-resistant.
The tearing strength is determined both by the production process and by the freeness of the fibers.
In order to increase the tearing strength, the tissue paper must be consolidated during its production. In order to obtain a high tearing strength, the proportion of fines must also be high.
The requirements on the tearing strength thus contradict the requirements on the water absorption capacity, the absorbency and the dewatering ability.
The object of the invention is therefore the production of tissue paper with a high specific volume, as high a tearing length as possible, with the lowest possible freeness.
According to the invention, the object is achieved in that the stock suspension contains lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 6. 0 km at 12 SR or a tearing length of more than 7.5 km at 15 SR and a lignin content of at least 15%, based on the oven-dry fibrous material, for coniferous wood in the unbleached state, or a tearing length of more than 4.5 km at 20 SR
and a lignin content of at least 12%, based on the oven-dry fibrous material, for deciduous wood in the unbleached state, or a tearing length of more than 3.5 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the unbleached state.
The fibers already exhibit high strength values at a freeness which is far lower as compared with fibers used hitherto. The fibrous material according to the invention is already capable of forming good bonds with neighboring fibers at a lower freeness and therefore also with a lower expenditure of refining energy.
The lignin content of the unbleached fibrous material in the case of coniferous wood can advantageously comprise at least 15%, preferably at least 18%, in particular at least 21%, of the oven-dry fibrous material, in the case of deciduous wood at least 12%, preferably at least 14%, in particular at least 16%, of the oven-dry fibrous material and, in the case of annual plants, at least 10%, preferably at least 12 %
and in particular at least 19%, of the oven-dry fibrous material.
The higher the lignin content of the fibrous material, the lower are the losses of woody substance during production of the fibrous material.
In this case, it is entirely possible to achieve even higher strength values. Therefore, the tearing length for coniferous wood fiber stock at 12 SR should be greater than 7 km, preferably greater than 7.5 km and in particular greater than 8 km. The tearing length for coniferous wood fiber stock at 15 SR should be greater than 9 km, preferably greater than 9.5 km and in particular greater than 10 km.
The tearing length for deciduous wood fiber stock at a lignin content of at least 12% and a freeness of 20 SR
should be greater than 6 km, preferably greater than 7 km and in particular greater than 7.5 km.
The tearing length for annual plant fiber stock at 20 SR should be greater than 3.5 km, preferably greater than 4 km and in particular greater than 4.5 km.
The lignin content of the unbleached fibrous material in the case of coniferous wood can advantageously comprise at least 15%, preferably at least 18%, in particular at least 21%, of the oven-dry fibrous material, in the case of deciduous wood at least 12%, preferably at least 14%, in particular at least 16%, of the oven-dry fibrous material and, in the case of annual plants, at least 10%, preferably at least 12 %
and in particular at least 19%, of the oven-dry fibrous material.
The higher the lignin content of the fibrous material, the lower are the losses of woody substance during production of the fibrous material.
In this case, it is entirely possible to achieve even higher strength values. Therefore, the tearing length for coniferous wood fiber stock at 12 SR should be greater than 7 km, preferably greater than 7.5 km and in particular greater than 8 km. The tearing length for coniferous wood fiber stock at 15 SR should be greater than 9 km, preferably greater than 9.5 km and in particular greater than 10 km.
The tearing length for deciduous wood fiber stock at a lignin content of at least 12% and a freeness of 20 SR
should be greater than 6 km, preferably greater than 7 km and in particular greater than 7.5 km.
The tearing length for annual plant fiber stock at 20 SR should be greater than 3.5 km, preferably greater than 4 km and in particular greater than 4.5 km.
However, the fibrous material according to the invention is not just distinguished by high tearing lengths. Instead, the strength level overall is high.
If the fibrous material according to the invention is subjected to a bleaching treatment, the fiber properties are enhanced considerably. The bleaching treatment is required for many applications with higher requirements on the whiteness. However, it is also aimed at the setting and improvement of the fiber properties. With the bleaching treatment, the tearing lengths increase.
Thus, the stock suspension should contain lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 7.5 km at 15 SR and a lignin content of at least 13%, based on the oven-dry fibrous material, for coniferous wood in the bleached state, or a tearing length of more than 5.0 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for deciduous wood in the bleached state, or a tearing length of more than 5.5 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the bleached state.
Here, too, higher tearing lengths are advantageous.
Thus, the tearing length for coniferous wood fiber stock at 15 SR should be greater than 9 km, preferably greater than 10 km.
The tearing length for deciduous wood fiber stock at 20 SR should be greater than 5.5 and the tearing length for annual plant fiber stock at 25 SR should be greater than 5 km, preferably greater than 5.5 km and in particular greater than 6 km.
r T CA 02673175 2009-06-18 In order to be able to make optimal use of the advantages with respect to a high specific volume and high strength at the lowest possible freeness, the stock suspension should exclusively contain lignocellolosic fibrous material according to the above description.
For many applications, however, it is sufficient if the stock suspension is only partly formed from such lignocellulosic fibrous material. In this case it is advantageous if between 20 and 80%, preferably between 30 and 50%, of the fibrous material of the stock suspension is formed from lignocellulosic fibrous material according to the above description.
Following the formation of a tissue web, this is preferably led between an upper structured and permeable belt and a lower permeable belt in a dewatering step, pressure being exerted on the upper belt, the tissue web and the lower belt along a dewatering section.
The pressure exerted on the arrangement comprising the upper belt, tissue web and lower belt can be effected by a gas flow and/or by a mechanical pressing force.
Preferably, during a dewatering step, a gas flows firstly through the upper belt, then the tissue web and then the lower belt. In this case, the dewatering takes place in the direction of the lower belt.
Additionally or alternatively to the through flow of gas, it may be advantageous if, during the dewatering step, the arrangement comprising the upper belt, tissue web and lower belt is led in at least some sections between a press belt under tension and a smooth surface, the press belt acting on the upper belt and the lower belt being supported on the smooth surface.
If the fibrous material according to the invention is subjected to a bleaching treatment, the fiber properties are enhanced considerably. The bleaching treatment is required for many applications with higher requirements on the whiteness. However, it is also aimed at the setting and improvement of the fiber properties. With the bleaching treatment, the tearing lengths increase.
Thus, the stock suspension should contain lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 7.5 km at 15 SR and a lignin content of at least 13%, based on the oven-dry fibrous material, for coniferous wood in the bleached state, or a tearing length of more than 5.0 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for deciduous wood in the bleached state, or a tearing length of more than 5.5 km at 20 SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the bleached state.
Here, too, higher tearing lengths are advantageous.
Thus, the tearing length for coniferous wood fiber stock at 15 SR should be greater than 9 km, preferably greater than 10 km.
The tearing length for deciduous wood fiber stock at 20 SR should be greater than 5.5 and the tearing length for annual plant fiber stock at 25 SR should be greater than 5 km, preferably greater than 5.5 km and in particular greater than 6 km.
r T CA 02673175 2009-06-18 In order to be able to make optimal use of the advantages with respect to a high specific volume and high strength at the lowest possible freeness, the stock suspension should exclusively contain lignocellolosic fibrous material according to the above description.
For many applications, however, it is sufficient if the stock suspension is only partly formed from such lignocellulosic fibrous material. In this case it is advantageous if between 20 and 80%, preferably between 30 and 50%, of the fibrous material of the stock suspension is formed from lignocellulosic fibrous material according to the above description.
Following the formation of a tissue web, this is preferably led between an upper structured and permeable belt and a lower permeable belt in a dewatering step, pressure being exerted on the upper belt, the tissue web and the lower belt along a dewatering section.
The pressure exerted on the arrangement comprising the upper belt, tissue web and lower belt can be effected by a gas flow and/or by a mechanical pressing force.
Preferably, during a dewatering step, a gas flows firstly through the upper belt, then the tissue web and then the lower belt. In this case, the dewatering takes place in the direction of the lower belt.
Additionally or alternatively to the through flow of gas, it may be advantageous if, during the dewatering step, the arrangement comprising the upper belt, tissue web and lower belt is led in at least some sections between a press belt under tension and a smooth surface, the press belt acting on the upper belt and the lower belt being supported on the smooth surface.
Preferably, the gas flow flows through the arrangement comprising the upper belt, tissue web and lower belt, at least in some sections in the region of the dewatering section, so that the dewatering is carried out simultaneously by the pressing force of the press belt and the through flow of the gas.
Trials have shown that the gas flow through the tissue web should amount to about 150 m3 per minute and meter length along the dewatering section.
In the interests of adequate dewatering of the tissue web, the press belt should be under a tension of at least 30 kN/m, preferably at least 60 kN/m and in particular 80 kN/m.
In order to be able to achieve good dewatering of the tissue web by means of the mechanical tension of the press belt and also on account of the gas flow through the press belt, the press belt should have an open area of more than 50% and a contact area of at least 15%.
The smooth surface is preferably formed by the circumferential surface of a roll. The gas flow can advantageously be produced via a suction zone in the roll and/or a positive pressure hood arranged above the upper belt.
During the production of the lignocellulosic fibrous material according to the invention, it is important that at least a proportion of the stock suspension is produced from wood or annual plants having a lignin content of at least 15% for coniferous wood and 12% for deciduous wood and 10% for annual plants, in each case based on the oven-dry fiber mass, by the following steps:
- producing a chemical solution with more than 5% of chemicals (calculated as NaOH) for coniferous wood or with more than 3.5% of chemicals (calculated as NaOH) for deciduous wood or with more than 2.5% of chemicals (calculated as NaOH), in each case based on the oven-dry quantity of the wood used, - mixing the chemical solution with the wood or annual plants in a prescribed liquor ratio, - heating the chemical solution and the wood or annual plants to a temperature above room temperature and then either (lst alternative) - removing free-flowing chemical solution and - digesting the wood or annual plants in the vapor phase or (2nd alternative) - digesting the wood or annual plants in the presence of the chemical solution in liquid phase and - separating the free-flowing chemical solution and the wood or annual plants.
The process according to the invention is based on the fact that, in order to produce high-yield fibrous materials, higher quantities of chemicals are used than were previously usual. More than 5% of chemicals for coniferous wood is considerably above the quantities of chemicals previously usual for industrial fibrous material production, likewise more than 3.5% of chemicals for deciduous wood and 2.5% for annual plants. This high use of chemicals produces fibrous materials with good yield and excellent strength properties. Thus, for coniferous wood at freenesses of only 12 SR to 15 SR, tearing lengths of more than 8 km but also tearing lengths of more than 9 km and more than 10 km are measured. For deciduous woods at only 20 SR, values of more than 5 km but also tearing lengths of more than 6 km and more than 7 km are measured. The desired high strength level is therefore achieved.
It is to be viewed as an extraordinary advantage of the orocess accordinq to the invention that the strength values are already achieved at extremely low freenesses, such as were not available hitherto for high-yield fibrous materials. Fibrous materials according to the prior art do not exhibit an acceptable strength level at freenesses of 12 SR to 15 SR for coniferous wood fibrous materials or of 20 SR for deciduous wood. Known fibrous materials at these low freenesses have until now resulted in fibers which have not demonstrated adequate strength properties for economic use of such fibers.
Suitable annual plants are in particular bamboo, hemp, rice straw, bagasse, wheat, miscanthus and the like.
On the other hand, at freenesses in the range from 12 SR to 15 SR, the fibrous materials produced by the process of the invention already have tearing lengths of more than 8 km up to 11 km and tear propagation resistances of more than 70 cN up to more than 110 cN, based on a sheet weight of 100 g/m2. These low freenesses are moreover achieved with a low specific requirement for refining energy, which is less than 500 kWh/t of fibrous material for coniferous wood; in the case of deciduous wood the need for refining energy can even be less than 300 kWh/t of fibrous material.
The finding that the high strength level is already reached at low freenesses of 12 SR to 15 SR for coniferous wood and at 20 SR for deciduous wood and less is a substantial part of the invention.
These high strength values in combination with low freenesses for fibrous materials with a lignin content of more than 15% for coniferous wood fibrous materials, of more than 12% for deciduous wood fibrous materials or of more than 10% for annual plants, have hitherto not been known. The high strength level can, however, also be maintained for fibrous materials having an even higher lignin content. The process according to the invention is even suitable for producing coniferous wood fibrous materials having a lignin content of more than 18%, preferably more than 21%, advantageously more than 24%, based on the oven-dry fiber mass. Deciduous wood fibrous materials having a lignin content of more than 14%, preferably more than 16%, particularly preferably more than 18%, and also annual plants having a lignin content of more than 10%, preferably more than 12%, in particular more than 19%, can likewise be produced with the process according to the invention and exhibit a high strength level.
The composition of the chemical solution used for the digestion can be defined in accordance with the wood or annual plants used for the digestion and the desired fibrous material properties. As a rule, only a sulfite component is used. Alternatively or as a supplement, a sulfide component can also be added. Digestion with a sulfite component is not disrupted by the presence of sulfide components. Industrially, sodium sulfite is normally used but the use of ammonium or potassium sulfite or of magnesium bisulfite is also possible. In particular if high quantities of sulfite are used, it is possible to dispense with the use of an alkaline component since a high pH, which encourages digestion, is established even without the addition of alkaline components.
In order to adjust the pH and to assist the delignification, an acid and/or an alkaline component can also be metered in. Industrially, the alkaline component used is normally sodium hydroxide (NaOH).
However, the use of carbonates is also possible, in particular sodium carbonate. All statements relating to quantities of chemicals in the digestion process in this document, for example to total chemical used or to the subdivision of the sulfite component and the alkaline component are, if not otherwise specified, in each case calculated and stated as sodium hydroxide (NaOH).
Trials have shown that the gas flow through the tissue web should amount to about 150 m3 per minute and meter length along the dewatering section.
In the interests of adequate dewatering of the tissue web, the press belt should be under a tension of at least 30 kN/m, preferably at least 60 kN/m and in particular 80 kN/m.
In order to be able to achieve good dewatering of the tissue web by means of the mechanical tension of the press belt and also on account of the gas flow through the press belt, the press belt should have an open area of more than 50% and a contact area of at least 15%.
The smooth surface is preferably formed by the circumferential surface of a roll. The gas flow can advantageously be produced via a suction zone in the roll and/or a positive pressure hood arranged above the upper belt.
During the production of the lignocellulosic fibrous material according to the invention, it is important that at least a proportion of the stock suspension is produced from wood or annual plants having a lignin content of at least 15% for coniferous wood and 12% for deciduous wood and 10% for annual plants, in each case based on the oven-dry fiber mass, by the following steps:
- producing a chemical solution with more than 5% of chemicals (calculated as NaOH) for coniferous wood or with more than 3.5% of chemicals (calculated as NaOH) for deciduous wood or with more than 2.5% of chemicals (calculated as NaOH), in each case based on the oven-dry quantity of the wood used, - mixing the chemical solution with the wood or annual plants in a prescribed liquor ratio, - heating the chemical solution and the wood or annual plants to a temperature above room temperature and then either (lst alternative) - removing free-flowing chemical solution and - digesting the wood or annual plants in the vapor phase or (2nd alternative) - digesting the wood or annual plants in the presence of the chemical solution in liquid phase and - separating the free-flowing chemical solution and the wood or annual plants.
The process according to the invention is based on the fact that, in order to produce high-yield fibrous materials, higher quantities of chemicals are used than were previously usual. More than 5% of chemicals for coniferous wood is considerably above the quantities of chemicals previously usual for industrial fibrous material production, likewise more than 3.5% of chemicals for deciduous wood and 2.5% for annual plants. This high use of chemicals produces fibrous materials with good yield and excellent strength properties. Thus, for coniferous wood at freenesses of only 12 SR to 15 SR, tearing lengths of more than 8 km but also tearing lengths of more than 9 km and more than 10 km are measured. For deciduous woods at only 20 SR, values of more than 5 km but also tearing lengths of more than 6 km and more than 7 km are measured. The desired high strength level is therefore achieved.
It is to be viewed as an extraordinary advantage of the orocess accordinq to the invention that the strength values are already achieved at extremely low freenesses, such as were not available hitherto for high-yield fibrous materials. Fibrous materials according to the prior art do not exhibit an acceptable strength level at freenesses of 12 SR to 15 SR for coniferous wood fibrous materials or of 20 SR for deciduous wood. Known fibrous materials at these low freenesses have until now resulted in fibers which have not demonstrated adequate strength properties for economic use of such fibers.
Suitable annual plants are in particular bamboo, hemp, rice straw, bagasse, wheat, miscanthus and the like.
On the other hand, at freenesses in the range from 12 SR to 15 SR, the fibrous materials produced by the process of the invention already have tearing lengths of more than 8 km up to 11 km and tear propagation resistances of more than 70 cN up to more than 110 cN, based on a sheet weight of 100 g/m2. These low freenesses are moreover achieved with a low specific requirement for refining energy, which is less than 500 kWh/t of fibrous material for coniferous wood; in the case of deciduous wood the need for refining energy can even be less than 300 kWh/t of fibrous material.
The finding that the high strength level is already reached at low freenesses of 12 SR to 15 SR for coniferous wood and at 20 SR for deciduous wood and less is a substantial part of the invention.
These high strength values in combination with low freenesses for fibrous materials with a lignin content of more than 15% for coniferous wood fibrous materials, of more than 12% for deciduous wood fibrous materials or of more than 10% for annual plants, have hitherto not been known. The high strength level can, however, also be maintained for fibrous materials having an even higher lignin content. The process according to the invention is even suitable for producing coniferous wood fibrous materials having a lignin content of more than 18%, preferably more than 21%, advantageously more than 24%, based on the oven-dry fiber mass. Deciduous wood fibrous materials having a lignin content of more than 14%, preferably more than 16%, particularly preferably more than 18%, and also annual plants having a lignin content of more than 10%, preferably more than 12%, in particular more than 19%, can likewise be produced with the process according to the invention and exhibit a high strength level.
The composition of the chemical solution used for the digestion can be defined in accordance with the wood or annual plants used for the digestion and the desired fibrous material properties. As a rule, only a sulfite component is used. Alternatively or as a supplement, a sulfide component can also be added. Digestion with a sulfite component is not disrupted by the presence of sulfide components. Industrially, sodium sulfite is normally used but the use of ammonium or potassium sulfite or of magnesium bisulfite is also possible. In particular if high quantities of sulfite are used, it is possible to dispense with the use of an alkaline component since a high pH, which encourages digestion, is established even without the addition of alkaline components.
In order to adjust the pH and to assist the delignification, an acid and/or an alkaline component can also be metered in. Industrially, the alkaline component used is normally sodium hydroxide (NaOH).
However, the use of carbonates is also possible, in particular sodium carbonate. All statements relating to quantities of chemicals in the digestion process in this document, for example to total chemical used or to the subdivision of the sulfite component and the alkaline component are, if not otherwise specified, in each case calculated and stated as sodium hydroxide (NaOH).
Acids can be metered in as acid components in order to set the desired pH. However, preference is given to the addition of SO2r if appropriate in aqueous solution.
It is inexpensive and easily available, in particular when the used chemical solution, for example based on sodium sulfite, is conditioned for further use following the digestion.
It is seen as an independent achievement of the invention to have recognized the advantages of the use of a quinone component for the high-yield digestion according to the invention. Quinone components, in particular anthraquinone, have until now been used in the production of pulps with a minimal lignin content, in order to prevent undesired action on the carbohydrate towards the end of the digestion. By adding quinone components it becomes possible to continue the digestion of wood further until the approximately complete breakdown of the lignin. It has emerged as a previously unknown, unexpected property of quinone components that these raise the rate of the lignin breakdown significantly during the production of high-yield pulps. The duration of the digestion, for example during the production of coniferous wood fibrous materials, can be shortened by more than a half, depending on the digestion conditions by more than three-quarters. This noticeable effect is achieved with minimal use of quinone, for example. A
use of, for example, anthraquinone which is between 0.005% and 0.5% is optimal. A use of anthraquinone of up to 1% also produces the desired effect. A use of more than 3% anthraquinone is normally uneconomic.
A chemical solution is produced from an individual chemical or a plurality of the aforementioned chemicals. An aqueous solution is normally added. As an option, the use or the addition of organic solvents can also be provided. Alcohol, in particular methanol - il -and ethanol, in a mixture with water gives particularly effective chemical solutions for the production of high-quality high-yield fibrous materials. The mixture ratio of water and alcohol can be optimized for the respective raw material in a few trials.
The quantity of chemicals to be used according to the invention for producing a fibrous material with a yield of at least 70% is at least 5% for coniferous wood, at least 3.5% for deciduous wood and at least 2.5% for annual plants, in each case based on the oven-dry wood or annual plant mass to be digested. The quality of the fibrous material produced exhibits the best results with a chemical usage of up to 15% for coniferous wood, of up to 10% for deciduous wood and up to 10% for annual plants. Preferably, between 9% and 11% of chemicals, based on the oven-dry wood used, is added in the case of coniferous wood. For deciduous wood, the use of the chemicals is somewhat lower, preferably between 4% and 10%, particularly preferably between 6%
and 9%, and between 3% and 10o in the case of annual plants.
As already explained above, the setting of a specific pH is in no way required. Only when, for example, particular properties of the pulp (particularly high whiteness, a specific ratio of tearing length and tear propagation resistance) are to be achieved with the digestion may it be expedient to add acid or an alkaline component before or during the digestion.
According to an advantageous refinement of the invention, irrespective of the chosen use of chemicals overall, a ratio between an alkaline component and sulfur dioxide (SiO2) can be set over a wide range.
Here, SOZ is named as representing the acid component mentioned above. It is therefore also possible to use an acid instead of SO2. Since the quinone component possibly added is used only in minimal quantities, normally considerably below 1%, it can be disregarded in setting this ratio. A ratio of alkaline component:S02 in a range from 5:1 to 1.6:1 is well suited to carrying out the process of the invention and to achieving fibrous materials with high strength properties. A usual, particularly suitable range is lies between 2:1 and 1.6:1. The proportional components are coordinated on the basis of the raw material to be digested and the respectively chosen process management (digestion temperature, digestion time, impregnation).
The process according to the invention can be carried out in a wide pH range. The ratio of alkaline component to acid component and the use of an acid or alkaline component can be set in such a way that at the start of the process a pH between 6 and 11, preferably between 7 and 11, particularly preferably between 7.5 and 10, is set. The rather alkaline pH values between 8 and 11, which are advantageous for the process according to the invention, also encourage the action of the quinone component. The process according to the invention is tolerant with respect to the pH; few chemicals are needed for pH adjustment. This has a beneficial effect on the costs for chemicals.
Without any further addition of acid or alkaline component, a pH between 5 and 9, normally between 6.5 and 9, for example for coniferous wood, is established in the free-flowing chemical solution at the end of the digestion and also in the organic components dissolved therein, which are liquefied by the digestion. The dissolved organic substances primarily include lignosulfates.
The liquor ratio, i.e. ratio of the quantity of oven-dry wood or annual plants to the chemical solution, is set between 1:1.5 and 1:6. A liquor ratio of 1:2 to 1:4 is preferred. In this range, good and simple mixinq and impregnation of the material to be digested is ensured. For coniferous wood, a liquor ratio of 1:3.5 is preferred. For wood chips with a large surface, the liquor ratio can also be considerably higher, in order to permit rapid wetting and impregnation. At the same time, the concentration of the chemical solution can be kept so high that the quantities of liquid to be circulated do not become too large.
The mixing or impregnation of the wood or annual plant material to be digested is preferably carried out at elevated temperatures. Heating the chips and the chemical solution to up to 110 C, preferably to up to 120 C, particularly preferably to up to 130 C, leads to rapid and uniform digestion of the wood. For the mixing or impregnation of the chips, a time period of up to 30 minutes, preferably of up to 60 minutes, particularly preferably of up to 90 minutes; is advantageous. The respectively optimal time period depends, amongst other things, on the quantity of chemicals, the liquor ratio, the chosen temperature and the type of digestion (liquid or vapor phase).
The digestion of the lignocellulosic material mixed or impregnated with the chemical solution is preferably carried out at temperatures between 120 C and 190 C, preferably between 140 C and 180 C. For most woods, digestion temperatures between 150 C and 170 C are set.
Higher or lower temperatures can be set but in this temperature range the expenditure of energy for the heating and the acceleration of the digestion are in an economic relationship with each other. Higher temperatures can additionally have a detrimental effect on the strengths and the whiteness of the fibrous materials. The pressure generated by the high temperatures can readily be absorbed by appropriate design of the digester. The duration of the heating is normally only a few minutes, normally up to 30 minutes, advantaqeously up to 10 minutes, in particular when steam heating is used. The duration of the heating can be up to 120 minutes, preferably up to 60 minutes, for example when digestion in the liquid phase is carried out and the chemical solution has to be heated together with the chips.
The duration of the digestion is primarily chosen on the basis of the desired fibrous material properties.
The duration of the digestion can be shortened to up to 2 minutes, for example for the case of vapor-phase digestion of deciduous wood having a low lignin content. However, it can also be up to 180 minutes, if for example the digestion temperature is low and the natural lignin content of the wood to be digested is high. Even if the initial pH of the digestion is in the neutral range, a long digestion time can be necessary. In particular, the digestion time is up to 90 minutes, particularly in the case of coniferous wood. The digestion time is particularly preferably up to 60 minutes, advantageously up to 30 minutes. A
digestion time of 60 minutes is suitable in particular in the case of deciduous woods.
In the case of annual plants, the digestion time is up to 90 minutes. The use of a quinone component, in particular anthraquinone, permits a reduction in the digestion time of up to 25% of the time required without the addition of anthraquinone. If the use of quinone components is omitted, the digestion time for comparable digestion results is lengthened by more than an hour, for example from 45 minutes to 180 minutes.
According to an advantageous embodiment of the process according to the invention, the duration of the digestion is set as a function of the chosen liquor ratio. The lower the liquor ratio, the shorter the process duration can be set.
The production of high-yield fibrous material with high chemical use of more than 5% for coniferous wood, of more than 3.5% for deciduous wood and at least 2.5% for annual plants initially appears uneconomic. However, trials have shown that only part of the chemicals is consumed during the partial digestion of the lignocellulosic material. The predominant part of the chemicals is removed unused, either before the digestion (vapor-phase digestion) or after the digestion (digestion in the liquid phase). The actual consumption of chemicals is below the quantities used in the digestion solution.
The chemical consumption is registered as the quantity of chemicals which - based on the quantity of chemicals originally used - is measured after the removal or separation of the chemical solution and, if appropriate, the capture of chemical solution which is measured after the difibering or in conjunction with capture of the chemical solution. The chemical consumption depends on the absolute quantity of chemicals used for the digestion, based on the oven-dry mass of wood to be digested. The higher the use of digestion chemicals, the lower the direct conversion of chemicals. Given a use of 27.5% of chemicals, based on oven-dry mass of wood, for example only about 30% of the chemicals used are consumed. Given the use of 15%
of chemicals, based on oven-dry mass of wood, 60% of the chemicals used are consumed, however, as could be verified in laboratory trials. The chemical consumption of the process according to the invention according to a preferred embodiment of the process during the digestion is up to 80%, preferably up to 60%, particularly preferably up to 40%, advantageously up to 20%, particularly advantageously up to 10%, of the chemical input at the start of the digestion.
The chemical consumption for producing a tonne of fibrous material is around 6% to 14% sulfite and/or sulfide component and also alkaline and/or acid component and also, if appropriate, quinone component, based on oven-dry fibrous material (deciduous and coniferous wood or annual plants) . According to the invention, this quantity of chemicals is enough to produce a fibrous material having the prescribed properties. In order however to ensure a uniform process result and possibly to obtain particular, desired fiber properties, it may prove to be expedient to use higher quantities of chemicals for the digestion, for example the aforementioned up to 30% of chemicals based on oven-dry wood or annual plant mass.
The use of these quantities of chemicals at the start of the digestion exhibits an advantageous effect, since the fibrous materials obtained in this way have previously unavailable properties, in particular high strength properties and high whitenesses. In particular, no digestion process which produces fibrous materials with high strength values over a wide pH
range from neutral as far as the alkaline range has hitherto been available. It has been shown to be economically particularly attractive that the fibrous materials produced in accordance with the invention can be refined to prescribed freenesses with an energy demand far lower than known fibrous materials. In addition, they already develop the high strengths at unusually low freenesses of 12 SR to 15 SR for coniferous wood and of 20 SR for deciduous wood.
After the mixing and impregnation of the wood with the chemical solution or after the digestion, there is an excess of chemicals in the free-flowing liquid. This excess is drawn off before the digestion (lst alternative) or after the digestion (2nd alternative).
According to an advantageous development of the process, the composition of the chemical solution removed is captured and subsequently adjusted to a prescribed composition for renewed use for the i production of fibers. The chemical solution which is removed before or after the digestion of the wood or the annual plants no longer has the composition set at the beginning. At least part of the chemicals used for the digestion has - as described above - penetrated into the material to be digested and/or has been consumed in the digestion. The unused chemicals can readily be used again for the next digestion. However, the invention proposes firstly determining the composition of the chemicals removed and then supplementing the used proportions of, for example, sulfite, alkaline component, quinone component or else water or alcohol, in order once more to produce the prescribed composition of the next digestion. This supplementation step is also designated strengthening.
It is to be viewed as a considerable advantage of this measure that the chemical solution, in the case of removal before the digestion but also in the case of removal after the digestion, really contains no substances at all or very few substances which prove to be disruptive during renewed use of the strengthened chemical solution for the next digestion. The process according to the invention, which is based on making a surplus of digestion chemicals available during the impregnation, is also able to operate extremely economically, despite the procedure of the high chemical use, initially appearing uneconomic, for the removal or the separation and the strengthening of the chemical solution can be carried out simply and cost-effectively.
The process according to the invention is controlled specifically in such a way that only as little as possible of the starting material used is broken down or dissolved. The aim is to produce a fibrous material which, for coniferous wood, has a lignin content of at least 15%, based on the oven-dry fiber mass, preferably a lignin content of at least 180, particularly preferably of 21%, advantageously of at least 24%. For deciduous wood, the aim is to achieve a lignin content of at least 12%, based on the oven-dry fiber mass, preferably of at least 14%, particularly preferably of at least 16%, advantageously of at least 18%. In the case of annual plants, the preferred lignin content is between 10 and 28%, in particular between 12 and 26%.
The yield of the process according to the invention is at least 70%, preferably more than 75%, advantageously more than 80%, in each case based on the wood used.
This yield correlates with the lignin content of the fibrous material specified above. The original lignin content of wood is specific to the type. The loss of yield in the present process is predominantly represented as a loss of lignin. In the case of non-specific digestion processes, the proportion of hydrocarbons is increased considerably, for example because digestion chemicals also put cellulose or hemicelluloses into solution in a manner that is undesired per se.
A further, advantageous measure, after the defibering and possibly the refining of the lignocellulosic material, is to remove the chemical solution still remaining and to supply it to further use. In a preferred refinement, this further use can comprise two aspects. Firstly, the organic material broken down or put into solution during the partial digestion, predominantly lignin, can be used further. For example, it is burned in order to obtain process energy. Or it is prepared in order to be used in a different manner. Secondly, the used and unused chemicals are reconditioned, so that they can the used for a renewed partial digestion of lignocellulosic material. This includes the preparation of consumed chemicals.
According to a particularly preferred variant of the process according to the invention, the chemical solution employed is used extraordinarily efficiently.
After the defibering and possibly the refining, the fibrous material is washed, in order to displace the chemical solution as far as possible my means of water.
The filtrate arising during this washing and displacement operation contains considerable quantities of chemical solution and organic material. According to the invention, this filtrate is supplied to 'the removed or separated chemical solution before the chemical solution is strengthened and fed to the next digestion. The chemicals contained in the filtrate and organic constituents do not disrupt the digestion. To the extent that they make a contribution to the delignification during the next digestion, their content of chemicals is registered and taken into account during the determination of the quantity of chemicals needed for this digestion. The chemicals further contained in the filtrate behave inertly during the impending digestion; they do not interfere. The organic constituents contained in the filtrate likewise behave inertly. They are used further during the conditioning of the chemical solution after the next digestion, either to produce process energy or in another way.
It is viewed as particularly advantageous that, as a result of this management of the filtrate, less fresh water and fewer chemicals are used for the digestion.
At the same time, a maximum of dissolved organic material is captured. This improved utilization of the organic materials that have gone into solution also improves the economy of, the process according to the invention.
In the following text, the invention is to be explained in more detail in a number of exemplary embodiments.
In the appended drawinq:
Figure 1 shows an apparatus for carrying out the inventive method; and figure 2 shows a second apparatus.
Firstly, however, the details of the method according to the invention for producing the stock suspension will be explained in more detail below in exemplary embodiments.
The following trials were evaluated in accordance with the following instructions:
- The yield was calculated by weighing the raw material put in and the pulp obtained after the digestion, in each case dried to constant weight at 105 C (absolutely dry).
- The lignin content was determined as Klason lignin in accordance with TAPPT T 222 om-98.
The acid-soluble lignin was determined in accordance with TAPPI UM 250.
- The paper technological properties were determined on test sheets which were produced in accordance with Zellcheming Note Sheet V/8/76.
- The freeness was registered as per Zellcheming Note Sheet V/3/62.
- The bulk was determined as per Zellcheming Instruction V/11/57.
- The tearing length was determined as per Zellcheming Instruction V/12/57.
- The tear propagation resistance was determined as per DIN 53 128 Elmendorf.
- The determination of tensile, tear and burst index was carried out in accordance with TAPPI 220 sp-96.
- The whiteness was determined by producing the test sheets as per Zellcheming Note Sheet V/19/63, measured as per SCAN C 11:75 with a Datacolor elrepho 450 x photometer; the whiteness is specified in percent as per ISO Standard 2470.
- The viscosity was determined as per Note Sheet IV/36/61 of the German Association of Pulp and Paper Chemists and Engineers (Zelicheming).
- All the % statements in this document are to be read as percent by weight if not otherwise individually indicated.
- The statement "o.d." in this document refers to "oven-dry" material, which has been dried to constant weight at 105 C.
- The chemicals for the digestion are specified in percent by weight as sodium hydroxide if not otherwise explained.
Example 1 - Coniferous wood digestion in the liquid phase A mixture of birch wood and Douglas fir chips, after steaming (30 minutes in saturated steam at 105 C), was dosed with a sodium sulfite digestion solution with a liquor ratio of wood:digestion solution of 1:3. The total use of chemicals was less than 15%, based on o.d.
wood. The pH at the start of the digestion was adjusted to pH 8.5 - 9 by adding SOZ.
The birch wood/chips mixture impregnated with chemical solution was heated to 170 C over a time period of 90 minutes and digested at this maximum temperature over 60 minutes.
The free-flowing liquid was then removed by centrifuging, collected and analyzed and strengthened in an arrangement for feeding back unused liquid and in this way conditioned for the next digestion.
The digested chips were defibered. Partial quantities of the fibrous material produced in this way were refined for different times in order to determine the strenath at different freenesses. The expenditure of energy for defibering the partly digested chips was less than 300 kWh/t of fibrous material.
The yield in this trial was around 77%, based on the wood mass used.
This corresponds to a fibrous material having a lignin content of far above 20%. The average lignin content for birch wood is given as 28%, based on the o.d. wood mass (Wagenfuhr, Anatomie des Holzes [Anatomy of Wood], VEB Fachbuchverlag, Leipzig, 1980). The actual lignin content of the fibrous material is higher than 20%
since, during the digestion, it is predominantly but not exclusively lignin which is broken down.
Carbohydrates (cellulose and hemicelluloses) are also dissolved in small quantities. The values specified show that the digestion exhibits good selectivity with regard to the breakdown of lignin and carbohydrates.
The whiteness is unexpectedly high with values over 55%
ISO and thus offers a good starting basis for possible subsequent bleaching, in which whitenesses of 75% ISO
can be achieved.
With an initial freeness of 12 SR, these materials already have a 6 km tearing length at a specific weight of 1.87 cm3/g.
In order to refine the fibrous materials to a freeness of 15 SR, a refining time of 20 to 30 minutes is needed. Up to a refining time of 20 minutes (freeness 12 SR - 15 SR), the freeness develops within a narrow range irrespective of the pH at the start of the digestion (pH 6 to pH 9.4).
Likewise irrespective of the initial pH of the digestion and the refining time needed to reach the freeness, a high strength level is reached at a freeness of 15 SR.
Example 2 The fibrous material was produced from birch chips, the pH at the start of the digestion being 9.4.
In addition to the 15% total chemicals (sulfite and NaOH in the prescribed ratio), 0.1 anthraquinone, based on the quantity of wood used, was added.
The digestion time was 60 minutes.
The following values resulted:
Yield (o): 81.1 Lignin content: 22.7 Whiteness (% ISO): 53.7 Tearing length (km): 9.6 Tear propagation resistance (cN; 100 g/m2): 75.0 As a result of the addition of 0.1% anthraquinone, the digestion time can be reduced from about 180 minutes to 60 minutes under otherwise unchanged digestion conditions. This time gain is valuable, above all because the fibrous material production plants can be dimensioned smaller. Further potential savings reside in the fact that the temperature needed for the digestion has to be maintained over only a very much shorter time period.
Furthermore, it was determined that, with a decreasing use of overall chemicals to values between 5 and 15% in the case of coniferous wood, fibrous material with largely equally good properties is produced. The results do not depend on the use of the anthraquinone.
The anthraquinone has the effect of accelerating the digestion but the desired fibrous material can also be digested without the addition of anthraquinone.
Example 3: Deciduous wood digestion in the liquid phase Eucalyptus chips, after steaming, have a sodium sulfite digestion solution added at a liquor ratio of wood:digestion solution of 1:3. The use of chemicals was 10.5% here (as NaOH) on o.d. chips.
Over a time period of 90 minutes, the material to be digested was impregnated and the digestion material was heated to the maximum digestion temperature of 170 C.
The digestion time was 50 minutes.
Digestions with eucalyptus wood show that these materials cam be produced with a specific energy input for defibering of less than 250 kWh/t.
The yield in these trials was around 77%, based on the wood mass used. Given an initial freeness of 14 SR, these materials already have a 3.5 km tearing length with a specific ... of 2.05 cm3/g. In the subsequent bleaching these materials could be bleached to whitenesses of 79.9% ISO.
Trials have shown that the digestions in the vapor phase exhibit a lower overall time requirement. As compared with digestion in the liquid phase, the heating to the maximum digestion temperature is carried out very much faster. The actual digestion then needs the same amount of time as a digestion in the liquid phase. During the vapor phase digestion there is no free-flowing chemical solution; this is drawn off after the impregnation and before the digestion. It therefore has less organic material added than the chemical solution which is drawn off after the digestion in the liquid phase. However, this has no significant influence on the quality of the fibrous material produced.
Whereas in the case of vapor phase digestions similar values in terms of yield can be achieved, the whiteness of the fibrous materials produced in vapor-phase digestion are considerably lower, however. A
significant effect is achieved by reducing the maximum digestion temperature from 170 C to 150 C; the whiteness rises.
The fibrous materials produced in the vapor phase exhibit excellent strengths. The tearing length was measured as 10 km, for example, and as 11 km at 15 SR.
The tear propagation resistance was measured as 82.8 cN
and 91.0 cN, for example. These values correspond to the best values for fibrous materials with a high lignin content which have been achieved for digestions in the liquid phase, or are even higher. Comparable strength values are not known from the prior art for fibrous materials with a high lignin content.
From the examples it can be gathered particularly clearly that the fibrous materials according to the invention need only little expenditure of energy during refining in order to build up high tearing lengths, without the tear propagation resistance being reduced.
A freeness of 12 SR was in each case reached in 0-10 minutes; a freeness of 13 SR in 5-30 minutes, normally 10-20 minutes. In order to reach a freeness of 14 SR, the Jokro mill had to operate for 30-40 minutes and for a freeness of 15 SR between 35 and 40 minutes were needed. It is obvious that refining to freenesses around 40 SR would require enormous expenditure on refining energy. A particular advantage of the process according to the invention is therefore to be seen in the fact that fibrous materials with high strengths can be refined with little expenditure of energy.
The apparatus for providing a stock suspension which is used below in the process according to the invention for producing a tissue web, comprises a pulper, in which the dry raw and semifinished materials and waste paper are slushed in water and transformed into a state that can be pumped. The stock formed in this way is then fed to a mixing chest.
During the subsequent refining operation, the stock suspension is refined to a freeness of 12 SR or more.
After the machine chest, the stock suspension is diluted very highly with white water and fed to a headbox 13.
Irrespective of how the stock suspension is obtained, it is important for the production of tissue paper that the stock suspension emerging from the headbox 13 has a freeness of less than 20 SR and a tearing length of more than 4.5 km.
A stock suspension 1 having the abovementioned properties emerges from the headbox 13 in such a way that this is injected into the ingoing gap between a forming fabric 14 and a structured, in particular 3-dimensionally structured, belt 3, by which means a tissue web 1 is formed.
The forming fabric 14 has a side oriented toward the tissue web 1 which is smooth relative to that of the structured belt 3.
Here, the side of the structured belt 3 pointing toward the tissue web 1 has deepened regions and regions elevated with respect to the deepened regions, so that the tissue web 1 is formed in the deepened regions and the elevated regions of the structured belt 3. The difference in height between the deepened regions and the elevated regions is preferably 0.07 mm and 0.6 mm.
The area formed by the elevated regions is preferably 10% or more, particularly preferably 20% or more and particularly preferably 25% to 30%.
In the exemplary embodiments illustrated, the arrangement comprising upper belt 3, tissue web 1 and forming fabric 14 is deflected around a forming roll 15 and the tissue web 1 is dewatered substantially by the forming fabric 14, before the forming fabric 14 is taken off the tissue web 1 and the tissue web 1 is transported onward on the belt 4.
The voluminous sections of the tissue web 1 formed in the deepened regions of the belt 3 have a higher volume and a higher grammage than the sections of the tissue web 1 formed in the elevated regions of the belt 3.
Consequently, on account of its formation on the structured belt 3, the tissue web 1 already has a 3-dimensional structure.
However, the sheet formation can also take place between two smooth forming fabrics 14, so that a substantially smooth tissue web 1 without a 3-dimensional structure is formed.
During a dewatering step following the formation of the tissue web 1, the tissue web 1 is led between the structured belt 3, which is arranged on the top, and a lower, permeable belt 2 formed as a felt, pressure being exerted on the structured belt 3, the tissue web 1 and the belt 2 along a dewatering section during the dewatering step, in such a way that the tissue web 1 is dewatered in the direction of the belt 2, as indicated by the arrows in the two figures.
During the dewatering, the tissue web 1, together with the belts 2, 3, wraps around a roll 5.
Because the tissue web 1 is dewatered in the direction of the belt 2 during this dewatering step and because the tissue web 1 is dewatered on the structured belt 3 on which it has already been formed, the voluminous sections are compressed less intensely than the other sections, so that as a result the voluminous structure of these sections is maintained.
The pressure for dewatering the tissue web 1 during the dewatering step according to figure 1 is produced simultaneously, at least in some sections, by a gas flow and by a mechanical pressing force.
In this case, the gas flow flows first through the structured belt 3, then the tissue web 1 and then the lower belt 2 formed as a felt. The gas flow through the tissue web 1 is about 150 m3 per minute and meter web length.
In the present case, the gas flow is produced by a suction zone 10 in the roll 5, the suction zone 10 having a length in the range between 200 mm and 2500 mm, preferably between 800 mm and 1800 mm, particularly preferably between 1200 mm and 1600 mm.
The vacuum in the suction zone 10 is between -0.2 bar and -0.8 bar, preferably between -0.4 bar and -0.6 bar.
With regard to the performance of the dewatering step carried out by means of mechanical pressing force and optionally or additionally by means of a gas flow, and also to the various configurations of apparatuses for carrying out such a dewatering step, the entire extent of PCT/EP2005/050198 is also to be incorporated into the disclosure content of the present application.
According to figure 1, the mechanical pressing force is produced in that, during the dewatering step, the arrangement comprising structured belt 3, tissue web 1 and belt 2 is guided ... a dewatering section 11 between a press belt 4 under tension and a smooth surface, the press belt 4 acting on the structured belt 3 and the belt 2 being supported on the smooth surface.
. = CA 02673175 2009-06-18 Here, the smooth surface is formed by the circumferential surface of the roll 5.
The dewatering section 11 is defined substantially by the wrap region of the press belt 4 around the circumferential surface of the roll 5, the wrap region being defined by the spacing of the two deflection rollers 12.
The press belt 4 is under a tension of at least 30 kN/m, preferably at least 60 kN/m or 80 kN/m, and has an open area of at least 25% and a contact area of at least 10% of its total area pointing toward the upper belt 3.
In a specific case the press belt 4, embodied as a spiral link fabric, has an open area of between 51% and 62% and a contact area of between 38% and 49% of its total area pointing toward the upper belt 3.
With regard to the structure of the press belt, the entire extent of PCT/EP2005/050198 is to be incorporated into the disclosure content of the present application.
The tissue web 1 leaves the dewatering section 11 with a dryness of between 25% and 55%.
In a further dewatering step following the dewatering step, the tissue web 1, together with the structured belt 3, is then led through a press nip, the tissue web 1 in the press nip being arranged between the structured belt 3 and a smooth roll surface of a Yankee drying cylinder 7. Here, the press nip is an extended press nip formed by the Yankee drying cylinder 7 and a shoe press roll 8.
= CA 02673175 2009-06-18 The tissue web 1 rests on one side with a relatively great area on the circumferential surface of the Yankee drying cylinder 7, the tissue web 1 resting on the structured belt 3 on the other side.
The deepened regions and the regions elevated relative thereto of the structured belt 3 are here formed and arranged in relation to one another in such a way that the voluminous sections are substantially not pressed in the press nip. On the other hand, the other sections are pressed, by which means the strength of the tissue web 1 is increased further.
Between the two dewatering steps described, a further dewatering step can be provided, which can be carried out by means of an apparatus 9.
Optionally, provision can be made for the tissue web 1, before it runs through the press nip, to be led together with the structured belt 3 around an evacuated deflection roll, the structured belt 3 being arranged between the tissue web 1 and the evacuated deflection roll (not illustrated).
From figure 2 it can be seen that the gas flow can additionally be produced by a positive pressure hood 6 arranged above the structured belt 3, the dewatering step in this case being carried out without any mechanical pressing force, i.e., as opposed to figure 1, no press belt 4 which wraps around some section of the roll 5 being provided.
It is inexpensive and easily available, in particular when the used chemical solution, for example based on sodium sulfite, is conditioned for further use following the digestion.
It is seen as an independent achievement of the invention to have recognized the advantages of the use of a quinone component for the high-yield digestion according to the invention. Quinone components, in particular anthraquinone, have until now been used in the production of pulps with a minimal lignin content, in order to prevent undesired action on the carbohydrate towards the end of the digestion. By adding quinone components it becomes possible to continue the digestion of wood further until the approximately complete breakdown of the lignin. It has emerged as a previously unknown, unexpected property of quinone components that these raise the rate of the lignin breakdown significantly during the production of high-yield pulps. The duration of the digestion, for example during the production of coniferous wood fibrous materials, can be shortened by more than a half, depending on the digestion conditions by more than three-quarters. This noticeable effect is achieved with minimal use of quinone, for example. A
use of, for example, anthraquinone which is between 0.005% and 0.5% is optimal. A use of anthraquinone of up to 1% also produces the desired effect. A use of more than 3% anthraquinone is normally uneconomic.
A chemical solution is produced from an individual chemical or a plurality of the aforementioned chemicals. An aqueous solution is normally added. As an option, the use or the addition of organic solvents can also be provided. Alcohol, in particular methanol - il -and ethanol, in a mixture with water gives particularly effective chemical solutions for the production of high-quality high-yield fibrous materials. The mixture ratio of water and alcohol can be optimized for the respective raw material in a few trials.
The quantity of chemicals to be used according to the invention for producing a fibrous material with a yield of at least 70% is at least 5% for coniferous wood, at least 3.5% for deciduous wood and at least 2.5% for annual plants, in each case based on the oven-dry wood or annual plant mass to be digested. The quality of the fibrous material produced exhibits the best results with a chemical usage of up to 15% for coniferous wood, of up to 10% for deciduous wood and up to 10% for annual plants. Preferably, between 9% and 11% of chemicals, based on the oven-dry wood used, is added in the case of coniferous wood. For deciduous wood, the use of the chemicals is somewhat lower, preferably between 4% and 10%, particularly preferably between 6%
and 9%, and between 3% and 10o in the case of annual plants.
As already explained above, the setting of a specific pH is in no way required. Only when, for example, particular properties of the pulp (particularly high whiteness, a specific ratio of tearing length and tear propagation resistance) are to be achieved with the digestion may it be expedient to add acid or an alkaline component before or during the digestion.
According to an advantageous refinement of the invention, irrespective of the chosen use of chemicals overall, a ratio between an alkaline component and sulfur dioxide (SiO2) can be set over a wide range.
Here, SOZ is named as representing the acid component mentioned above. It is therefore also possible to use an acid instead of SO2. Since the quinone component possibly added is used only in minimal quantities, normally considerably below 1%, it can be disregarded in setting this ratio. A ratio of alkaline component:S02 in a range from 5:1 to 1.6:1 is well suited to carrying out the process of the invention and to achieving fibrous materials with high strength properties. A usual, particularly suitable range is lies between 2:1 and 1.6:1. The proportional components are coordinated on the basis of the raw material to be digested and the respectively chosen process management (digestion temperature, digestion time, impregnation).
The process according to the invention can be carried out in a wide pH range. The ratio of alkaline component to acid component and the use of an acid or alkaline component can be set in such a way that at the start of the process a pH between 6 and 11, preferably between 7 and 11, particularly preferably between 7.5 and 10, is set. The rather alkaline pH values between 8 and 11, which are advantageous for the process according to the invention, also encourage the action of the quinone component. The process according to the invention is tolerant with respect to the pH; few chemicals are needed for pH adjustment. This has a beneficial effect on the costs for chemicals.
Without any further addition of acid or alkaline component, a pH between 5 and 9, normally between 6.5 and 9, for example for coniferous wood, is established in the free-flowing chemical solution at the end of the digestion and also in the organic components dissolved therein, which are liquefied by the digestion. The dissolved organic substances primarily include lignosulfates.
The liquor ratio, i.e. ratio of the quantity of oven-dry wood or annual plants to the chemical solution, is set between 1:1.5 and 1:6. A liquor ratio of 1:2 to 1:4 is preferred. In this range, good and simple mixinq and impregnation of the material to be digested is ensured. For coniferous wood, a liquor ratio of 1:3.5 is preferred. For wood chips with a large surface, the liquor ratio can also be considerably higher, in order to permit rapid wetting and impregnation. At the same time, the concentration of the chemical solution can be kept so high that the quantities of liquid to be circulated do not become too large.
The mixing or impregnation of the wood or annual plant material to be digested is preferably carried out at elevated temperatures. Heating the chips and the chemical solution to up to 110 C, preferably to up to 120 C, particularly preferably to up to 130 C, leads to rapid and uniform digestion of the wood. For the mixing or impregnation of the chips, a time period of up to 30 minutes, preferably of up to 60 minutes, particularly preferably of up to 90 minutes; is advantageous. The respectively optimal time period depends, amongst other things, on the quantity of chemicals, the liquor ratio, the chosen temperature and the type of digestion (liquid or vapor phase).
The digestion of the lignocellulosic material mixed or impregnated with the chemical solution is preferably carried out at temperatures between 120 C and 190 C, preferably between 140 C and 180 C. For most woods, digestion temperatures between 150 C and 170 C are set.
Higher or lower temperatures can be set but in this temperature range the expenditure of energy for the heating and the acceleration of the digestion are in an economic relationship with each other. Higher temperatures can additionally have a detrimental effect on the strengths and the whiteness of the fibrous materials. The pressure generated by the high temperatures can readily be absorbed by appropriate design of the digester. The duration of the heating is normally only a few minutes, normally up to 30 minutes, advantaqeously up to 10 minutes, in particular when steam heating is used. The duration of the heating can be up to 120 minutes, preferably up to 60 minutes, for example when digestion in the liquid phase is carried out and the chemical solution has to be heated together with the chips.
The duration of the digestion is primarily chosen on the basis of the desired fibrous material properties.
The duration of the digestion can be shortened to up to 2 minutes, for example for the case of vapor-phase digestion of deciduous wood having a low lignin content. However, it can also be up to 180 minutes, if for example the digestion temperature is low and the natural lignin content of the wood to be digested is high. Even if the initial pH of the digestion is in the neutral range, a long digestion time can be necessary. In particular, the digestion time is up to 90 minutes, particularly in the case of coniferous wood. The digestion time is particularly preferably up to 60 minutes, advantageously up to 30 minutes. A
digestion time of 60 minutes is suitable in particular in the case of deciduous woods.
In the case of annual plants, the digestion time is up to 90 minutes. The use of a quinone component, in particular anthraquinone, permits a reduction in the digestion time of up to 25% of the time required without the addition of anthraquinone. If the use of quinone components is omitted, the digestion time for comparable digestion results is lengthened by more than an hour, for example from 45 minutes to 180 minutes.
According to an advantageous embodiment of the process according to the invention, the duration of the digestion is set as a function of the chosen liquor ratio. The lower the liquor ratio, the shorter the process duration can be set.
The production of high-yield fibrous material with high chemical use of more than 5% for coniferous wood, of more than 3.5% for deciduous wood and at least 2.5% for annual plants initially appears uneconomic. However, trials have shown that only part of the chemicals is consumed during the partial digestion of the lignocellulosic material. The predominant part of the chemicals is removed unused, either before the digestion (vapor-phase digestion) or after the digestion (digestion in the liquid phase). The actual consumption of chemicals is below the quantities used in the digestion solution.
The chemical consumption is registered as the quantity of chemicals which - based on the quantity of chemicals originally used - is measured after the removal or separation of the chemical solution and, if appropriate, the capture of chemical solution which is measured after the difibering or in conjunction with capture of the chemical solution. The chemical consumption depends on the absolute quantity of chemicals used for the digestion, based on the oven-dry mass of wood to be digested. The higher the use of digestion chemicals, the lower the direct conversion of chemicals. Given a use of 27.5% of chemicals, based on oven-dry mass of wood, for example only about 30% of the chemicals used are consumed. Given the use of 15%
of chemicals, based on oven-dry mass of wood, 60% of the chemicals used are consumed, however, as could be verified in laboratory trials. The chemical consumption of the process according to the invention according to a preferred embodiment of the process during the digestion is up to 80%, preferably up to 60%, particularly preferably up to 40%, advantageously up to 20%, particularly advantageously up to 10%, of the chemical input at the start of the digestion.
The chemical consumption for producing a tonne of fibrous material is around 6% to 14% sulfite and/or sulfide component and also alkaline and/or acid component and also, if appropriate, quinone component, based on oven-dry fibrous material (deciduous and coniferous wood or annual plants) . According to the invention, this quantity of chemicals is enough to produce a fibrous material having the prescribed properties. In order however to ensure a uniform process result and possibly to obtain particular, desired fiber properties, it may prove to be expedient to use higher quantities of chemicals for the digestion, for example the aforementioned up to 30% of chemicals based on oven-dry wood or annual plant mass.
The use of these quantities of chemicals at the start of the digestion exhibits an advantageous effect, since the fibrous materials obtained in this way have previously unavailable properties, in particular high strength properties and high whitenesses. In particular, no digestion process which produces fibrous materials with high strength values over a wide pH
range from neutral as far as the alkaline range has hitherto been available. It has been shown to be economically particularly attractive that the fibrous materials produced in accordance with the invention can be refined to prescribed freenesses with an energy demand far lower than known fibrous materials. In addition, they already develop the high strengths at unusually low freenesses of 12 SR to 15 SR for coniferous wood and of 20 SR for deciduous wood.
After the mixing and impregnation of the wood with the chemical solution or after the digestion, there is an excess of chemicals in the free-flowing liquid. This excess is drawn off before the digestion (lst alternative) or after the digestion (2nd alternative).
According to an advantageous development of the process, the composition of the chemical solution removed is captured and subsequently adjusted to a prescribed composition for renewed use for the i production of fibers. The chemical solution which is removed before or after the digestion of the wood or the annual plants no longer has the composition set at the beginning. At least part of the chemicals used for the digestion has - as described above - penetrated into the material to be digested and/or has been consumed in the digestion. The unused chemicals can readily be used again for the next digestion. However, the invention proposes firstly determining the composition of the chemicals removed and then supplementing the used proportions of, for example, sulfite, alkaline component, quinone component or else water or alcohol, in order once more to produce the prescribed composition of the next digestion. This supplementation step is also designated strengthening.
It is to be viewed as a considerable advantage of this measure that the chemical solution, in the case of removal before the digestion but also in the case of removal after the digestion, really contains no substances at all or very few substances which prove to be disruptive during renewed use of the strengthened chemical solution for the next digestion. The process according to the invention, which is based on making a surplus of digestion chemicals available during the impregnation, is also able to operate extremely economically, despite the procedure of the high chemical use, initially appearing uneconomic, for the removal or the separation and the strengthening of the chemical solution can be carried out simply and cost-effectively.
The process according to the invention is controlled specifically in such a way that only as little as possible of the starting material used is broken down or dissolved. The aim is to produce a fibrous material which, for coniferous wood, has a lignin content of at least 15%, based on the oven-dry fiber mass, preferably a lignin content of at least 180, particularly preferably of 21%, advantageously of at least 24%. For deciduous wood, the aim is to achieve a lignin content of at least 12%, based on the oven-dry fiber mass, preferably of at least 14%, particularly preferably of at least 16%, advantageously of at least 18%. In the case of annual plants, the preferred lignin content is between 10 and 28%, in particular between 12 and 26%.
The yield of the process according to the invention is at least 70%, preferably more than 75%, advantageously more than 80%, in each case based on the wood used.
This yield correlates with the lignin content of the fibrous material specified above. The original lignin content of wood is specific to the type. The loss of yield in the present process is predominantly represented as a loss of lignin. In the case of non-specific digestion processes, the proportion of hydrocarbons is increased considerably, for example because digestion chemicals also put cellulose or hemicelluloses into solution in a manner that is undesired per se.
A further, advantageous measure, after the defibering and possibly the refining of the lignocellulosic material, is to remove the chemical solution still remaining and to supply it to further use. In a preferred refinement, this further use can comprise two aspects. Firstly, the organic material broken down or put into solution during the partial digestion, predominantly lignin, can be used further. For example, it is burned in order to obtain process energy. Or it is prepared in order to be used in a different manner. Secondly, the used and unused chemicals are reconditioned, so that they can the used for a renewed partial digestion of lignocellulosic material. This includes the preparation of consumed chemicals.
According to a particularly preferred variant of the process according to the invention, the chemical solution employed is used extraordinarily efficiently.
After the defibering and possibly the refining, the fibrous material is washed, in order to displace the chemical solution as far as possible my means of water.
The filtrate arising during this washing and displacement operation contains considerable quantities of chemical solution and organic material. According to the invention, this filtrate is supplied to 'the removed or separated chemical solution before the chemical solution is strengthened and fed to the next digestion. The chemicals contained in the filtrate and organic constituents do not disrupt the digestion. To the extent that they make a contribution to the delignification during the next digestion, their content of chemicals is registered and taken into account during the determination of the quantity of chemicals needed for this digestion. The chemicals further contained in the filtrate behave inertly during the impending digestion; they do not interfere. The organic constituents contained in the filtrate likewise behave inertly. They are used further during the conditioning of the chemical solution after the next digestion, either to produce process energy or in another way.
It is viewed as particularly advantageous that, as a result of this management of the filtrate, less fresh water and fewer chemicals are used for the digestion.
At the same time, a maximum of dissolved organic material is captured. This improved utilization of the organic materials that have gone into solution also improves the economy of, the process according to the invention.
In the following text, the invention is to be explained in more detail in a number of exemplary embodiments.
In the appended drawinq:
Figure 1 shows an apparatus for carrying out the inventive method; and figure 2 shows a second apparatus.
Firstly, however, the details of the method according to the invention for producing the stock suspension will be explained in more detail below in exemplary embodiments.
The following trials were evaluated in accordance with the following instructions:
- The yield was calculated by weighing the raw material put in and the pulp obtained after the digestion, in each case dried to constant weight at 105 C (absolutely dry).
- The lignin content was determined as Klason lignin in accordance with TAPPT T 222 om-98.
The acid-soluble lignin was determined in accordance with TAPPI UM 250.
- The paper technological properties were determined on test sheets which were produced in accordance with Zellcheming Note Sheet V/8/76.
- The freeness was registered as per Zellcheming Note Sheet V/3/62.
- The bulk was determined as per Zellcheming Instruction V/11/57.
- The tearing length was determined as per Zellcheming Instruction V/12/57.
- The tear propagation resistance was determined as per DIN 53 128 Elmendorf.
- The determination of tensile, tear and burst index was carried out in accordance with TAPPI 220 sp-96.
- The whiteness was determined by producing the test sheets as per Zellcheming Note Sheet V/19/63, measured as per SCAN C 11:75 with a Datacolor elrepho 450 x photometer; the whiteness is specified in percent as per ISO Standard 2470.
- The viscosity was determined as per Note Sheet IV/36/61 of the German Association of Pulp and Paper Chemists and Engineers (Zelicheming).
- All the % statements in this document are to be read as percent by weight if not otherwise individually indicated.
- The statement "o.d." in this document refers to "oven-dry" material, which has been dried to constant weight at 105 C.
- The chemicals for the digestion are specified in percent by weight as sodium hydroxide if not otherwise explained.
Example 1 - Coniferous wood digestion in the liquid phase A mixture of birch wood and Douglas fir chips, after steaming (30 minutes in saturated steam at 105 C), was dosed with a sodium sulfite digestion solution with a liquor ratio of wood:digestion solution of 1:3. The total use of chemicals was less than 15%, based on o.d.
wood. The pH at the start of the digestion was adjusted to pH 8.5 - 9 by adding SOZ.
The birch wood/chips mixture impregnated with chemical solution was heated to 170 C over a time period of 90 minutes and digested at this maximum temperature over 60 minutes.
The free-flowing liquid was then removed by centrifuging, collected and analyzed and strengthened in an arrangement for feeding back unused liquid and in this way conditioned for the next digestion.
The digested chips were defibered. Partial quantities of the fibrous material produced in this way were refined for different times in order to determine the strenath at different freenesses. The expenditure of energy for defibering the partly digested chips was less than 300 kWh/t of fibrous material.
The yield in this trial was around 77%, based on the wood mass used.
This corresponds to a fibrous material having a lignin content of far above 20%. The average lignin content for birch wood is given as 28%, based on the o.d. wood mass (Wagenfuhr, Anatomie des Holzes [Anatomy of Wood], VEB Fachbuchverlag, Leipzig, 1980). The actual lignin content of the fibrous material is higher than 20%
since, during the digestion, it is predominantly but not exclusively lignin which is broken down.
Carbohydrates (cellulose and hemicelluloses) are also dissolved in small quantities. The values specified show that the digestion exhibits good selectivity with regard to the breakdown of lignin and carbohydrates.
The whiteness is unexpectedly high with values over 55%
ISO and thus offers a good starting basis for possible subsequent bleaching, in which whitenesses of 75% ISO
can be achieved.
With an initial freeness of 12 SR, these materials already have a 6 km tearing length at a specific weight of 1.87 cm3/g.
In order to refine the fibrous materials to a freeness of 15 SR, a refining time of 20 to 30 minutes is needed. Up to a refining time of 20 minutes (freeness 12 SR - 15 SR), the freeness develops within a narrow range irrespective of the pH at the start of the digestion (pH 6 to pH 9.4).
Likewise irrespective of the initial pH of the digestion and the refining time needed to reach the freeness, a high strength level is reached at a freeness of 15 SR.
Example 2 The fibrous material was produced from birch chips, the pH at the start of the digestion being 9.4.
In addition to the 15% total chemicals (sulfite and NaOH in the prescribed ratio), 0.1 anthraquinone, based on the quantity of wood used, was added.
The digestion time was 60 minutes.
The following values resulted:
Yield (o): 81.1 Lignin content: 22.7 Whiteness (% ISO): 53.7 Tearing length (km): 9.6 Tear propagation resistance (cN; 100 g/m2): 75.0 As a result of the addition of 0.1% anthraquinone, the digestion time can be reduced from about 180 minutes to 60 minutes under otherwise unchanged digestion conditions. This time gain is valuable, above all because the fibrous material production plants can be dimensioned smaller. Further potential savings reside in the fact that the temperature needed for the digestion has to be maintained over only a very much shorter time period.
Furthermore, it was determined that, with a decreasing use of overall chemicals to values between 5 and 15% in the case of coniferous wood, fibrous material with largely equally good properties is produced. The results do not depend on the use of the anthraquinone.
The anthraquinone has the effect of accelerating the digestion but the desired fibrous material can also be digested without the addition of anthraquinone.
Example 3: Deciduous wood digestion in the liquid phase Eucalyptus chips, after steaming, have a sodium sulfite digestion solution added at a liquor ratio of wood:digestion solution of 1:3. The use of chemicals was 10.5% here (as NaOH) on o.d. chips.
Over a time period of 90 minutes, the material to be digested was impregnated and the digestion material was heated to the maximum digestion temperature of 170 C.
The digestion time was 50 minutes.
Digestions with eucalyptus wood show that these materials cam be produced with a specific energy input for defibering of less than 250 kWh/t.
The yield in these trials was around 77%, based on the wood mass used. Given an initial freeness of 14 SR, these materials already have a 3.5 km tearing length with a specific ... of 2.05 cm3/g. In the subsequent bleaching these materials could be bleached to whitenesses of 79.9% ISO.
Trials have shown that the digestions in the vapor phase exhibit a lower overall time requirement. As compared with digestion in the liquid phase, the heating to the maximum digestion temperature is carried out very much faster. The actual digestion then needs the same amount of time as a digestion in the liquid phase. During the vapor phase digestion there is no free-flowing chemical solution; this is drawn off after the impregnation and before the digestion. It therefore has less organic material added than the chemical solution which is drawn off after the digestion in the liquid phase. However, this has no significant influence on the quality of the fibrous material produced.
Whereas in the case of vapor phase digestions similar values in terms of yield can be achieved, the whiteness of the fibrous materials produced in vapor-phase digestion are considerably lower, however. A
significant effect is achieved by reducing the maximum digestion temperature from 170 C to 150 C; the whiteness rises.
The fibrous materials produced in the vapor phase exhibit excellent strengths. The tearing length was measured as 10 km, for example, and as 11 km at 15 SR.
The tear propagation resistance was measured as 82.8 cN
and 91.0 cN, for example. These values correspond to the best values for fibrous materials with a high lignin content which have been achieved for digestions in the liquid phase, or are even higher. Comparable strength values are not known from the prior art for fibrous materials with a high lignin content.
From the examples it can be gathered particularly clearly that the fibrous materials according to the invention need only little expenditure of energy during refining in order to build up high tearing lengths, without the tear propagation resistance being reduced.
A freeness of 12 SR was in each case reached in 0-10 minutes; a freeness of 13 SR in 5-30 minutes, normally 10-20 minutes. In order to reach a freeness of 14 SR, the Jokro mill had to operate for 30-40 minutes and for a freeness of 15 SR between 35 and 40 minutes were needed. It is obvious that refining to freenesses around 40 SR would require enormous expenditure on refining energy. A particular advantage of the process according to the invention is therefore to be seen in the fact that fibrous materials with high strengths can be refined with little expenditure of energy.
The apparatus for providing a stock suspension which is used below in the process according to the invention for producing a tissue web, comprises a pulper, in which the dry raw and semifinished materials and waste paper are slushed in water and transformed into a state that can be pumped. The stock formed in this way is then fed to a mixing chest.
During the subsequent refining operation, the stock suspension is refined to a freeness of 12 SR or more.
After the machine chest, the stock suspension is diluted very highly with white water and fed to a headbox 13.
Irrespective of how the stock suspension is obtained, it is important for the production of tissue paper that the stock suspension emerging from the headbox 13 has a freeness of less than 20 SR and a tearing length of more than 4.5 km.
A stock suspension 1 having the abovementioned properties emerges from the headbox 13 in such a way that this is injected into the ingoing gap between a forming fabric 14 and a structured, in particular 3-dimensionally structured, belt 3, by which means a tissue web 1 is formed.
The forming fabric 14 has a side oriented toward the tissue web 1 which is smooth relative to that of the structured belt 3.
Here, the side of the structured belt 3 pointing toward the tissue web 1 has deepened regions and regions elevated with respect to the deepened regions, so that the tissue web 1 is formed in the deepened regions and the elevated regions of the structured belt 3. The difference in height between the deepened regions and the elevated regions is preferably 0.07 mm and 0.6 mm.
The area formed by the elevated regions is preferably 10% or more, particularly preferably 20% or more and particularly preferably 25% to 30%.
In the exemplary embodiments illustrated, the arrangement comprising upper belt 3, tissue web 1 and forming fabric 14 is deflected around a forming roll 15 and the tissue web 1 is dewatered substantially by the forming fabric 14, before the forming fabric 14 is taken off the tissue web 1 and the tissue web 1 is transported onward on the belt 4.
The voluminous sections of the tissue web 1 formed in the deepened regions of the belt 3 have a higher volume and a higher grammage than the sections of the tissue web 1 formed in the elevated regions of the belt 3.
Consequently, on account of its formation on the structured belt 3, the tissue web 1 already has a 3-dimensional structure.
However, the sheet formation can also take place between two smooth forming fabrics 14, so that a substantially smooth tissue web 1 without a 3-dimensional structure is formed.
During a dewatering step following the formation of the tissue web 1, the tissue web 1 is led between the structured belt 3, which is arranged on the top, and a lower, permeable belt 2 formed as a felt, pressure being exerted on the structured belt 3, the tissue web 1 and the belt 2 along a dewatering section during the dewatering step, in such a way that the tissue web 1 is dewatered in the direction of the belt 2, as indicated by the arrows in the two figures.
During the dewatering, the tissue web 1, together with the belts 2, 3, wraps around a roll 5.
Because the tissue web 1 is dewatered in the direction of the belt 2 during this dewatering step and because the tissue web 1 is dewatered on the structured belt 3 on which it has already been formed, the voluminous sections are compressed less intensely than the other sections, so that as a result the voluminous structure of these sections is maintained.
The pressure for dewatering the tissue web 1 during the dewatering step according to figure 1 is produced simultaneously, at least in some sections, by a gas flow and by a mechanical pressing force.
In this case, the gas flow flows first through the structured belt 3, then the tissue web 1 and then the lower belt 2 formed as a felt. The gas flow through the tissue web 1 is about 150 m3 per minute and meter web length.
In the present case, the gas flow is produced by a suction zone 10 in the roll 5, the suction zone 10 having a length in the range between 200 mm and 2500 mm, preferably between 800 mm and 1800 mm, particularly preferably between 1200 mm and 1600 mm.
The vacuum in the suction zone 10 is between -0.2 bar and -0.8 bar, preferably between -0.4 bar and -0.6 bar.
With regard to the performance of the dewatering step carried out by means of mechanical pressing force and optionally or additionally by means of a gas flow, and also to the various configurations of apparatuses for carrying out such a dewatering step, the entire extent of PCT/EP2005/050198 is also to be incorporated into the disclosure content of the present application.
According to figure 1, the mechanical pressing force is produced in that, during the dewatering step, the arrangement comprising structured belt 3, tissue web 1 and belt 2 is guided ... a dewatering section 11 between a press belt 4 under tension and a smooth surface, the press belt 4 acting on the structured belt 3 and the belt 2 being supported on the smooth surface.
. = CA 02673175 2009-06-18 Here, the smooth surface is formed by the circumferential surface of the roll 5.
The dewatering section 11 is defined substantially by the wrap region of the press belt 4 around the circumferential surface of the roll 5, the wrap region being defined by the spacing of the two deflection rollers 12.
The press belt 4 is under a tension of at least 30 kN/m, preferably at least 60 kN/m or 80 kN/m, and has an open area of at least 25% and a contact area of at least 10% of its total area pointing toward the upper belt 3.
In a specific case the press belt 4, embodied as a spiral link fabric, has an open area of between 51% and 62% and a contact area of between 38% and 49% of its total area pointing toward the upper belt 3.
With regard to the structure of the press belt, the entire extent of PCT/EP2005/050198 is to be incorporated into the disclosure content of the present application.
The tissue web 1 leaves the dewatering section 11 with a dryness of between 25% and 55%.
In a further dewatering step following the dewatering step, the tissue web 1, together with the structured belt 3, is then led through a press nip, the tissue web 1 in the press nip being arranged between the structured belt 3 and a smooth roll surface of a Yankee drying cylinder 7. Here, the press nip is an extended press nip formed by the Yankee drying cylinder 7 and a shoe press roll 8.
= CA 02673175 2009-06-18 The tissue web 1 rests on one side with a relatively great area on the circumferential surface of the Yankee drying cylinder 7, the tissue web 1 resting on the structured belt 3 on the other side.
The deepened regions and the regions elevated relative thereto of the structured belt 3 are here formed and arranged in relation to one another in such a way that the voluminous sections are substantially not pressed in the press nip. On the other hand, the other sections are pressed, by which means the strength of the tissue web 1 is increased further.
Between the two dewatering steps described, a further dewatering step can be provided, which can be carried out by means of an apparatus 9.
Optionally, provision can be made for the tissue web 1, before it runs through the press nip, to be led together with the structured belt 3 around an evacuated deflection roll, the structured belt 3 being arranged between the tissue web 1 and the evacuated deflection roll (not illustrated).
From figure 2 it can be seen that the gas flow can additionally be produced by a positive pressure hood 6 arranged above the structured belt 3, the dewatering step in this case being carried out without any mechanical pressing force, i.e., as opposed to figure 1, no press belt 4 which wraps around some section of the roll 5 being provided.
Claims (42)
1. A process for producing a tissue web (1), which is produced from a stock suspension comprising fibers, characterized in that the stock suspension contains lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 6.0 km at 12°SR or a tearing length of more than 7.5 km at 15°SR and a lignin content of at least 15%, based on the oven-dry fibrous material, for coniferous wood in the unbleached state, or a tearing length of more than 4.5 km at 20°SR and a lignin content of at least 12%, based on the oven-dry fibrous material, for deciduous wood in the unbleached state, or a tearing length of more than 3.5 km at 20°SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the unbleached state.
2. The process as claimed in claim 1, characterized in that the lignin content of the unbleached fibrous material in the case of coniferous wood is at least 15%, preferably at least 18%, in particular at least 21%, of the oven-dry fibrous material, in the case of deciduous wood at least 12%, preferably at least 14%, in particular at least 16%, of the oven-dry fibrous material and, in the case of annual plants, at least 10%, preferably at least 12% and in particular at least 19%, of the oven-dry fibrous material.
3. The process as claimed in claim 1 or 2, characterized in that the tearing length for coniferous wood fiber stock at 12°SR is greater than 7 km, preferably greater than 7.5 km and in particular greater than 8 km.
4. The process as claimed in one of the preceding claims, characterized in that the tearing length for coniferous wood fiber stock at 15°SR is greater than 9 km, preferably greater than 9.5 km and in particular greater than 10 km.
5. The process as claimed in one of the preceding claims, characterized in that the tearing length for deciduous wood fiber stock at a freeness of 20°SR is greater than 6 km, preferably greater than 7 km and in particular greater than 7.5 km.
6. The process as claimed in one of the preceding claims, characterized in that the tearing length for annual plant fiber stock at 20°SR is greater than 3.5 km, preferably greater than 4 km and in particular greater than 4.5 km.
7. A process for producing a tissue web (1), which is produced from a stock suspension comprising fibers, characterized in that the stock suspension contains lignocellulosic fibrous material made of wood or annual plants which has a tearing length of more than 7. 5 km at 15 ° SR and a lignin content of at least 13%, based on the oven-dry fibrous material, for coniferous wood in the bleached state, or a tearing length of more than 5.0 km at 20°SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for deciduous wood in the bleached state, or a tearing length of more than 5.5 km at 20 ° SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the bleached state.
8. The process as claimed in claim 7, characterized in that the tearing length for coniferous wood fiber stock at 15°SR is greater than 9 km, preferably greater than 10 km.
9. The process as claimed in claim 7 or 8, characterized in that the tearing length for deciduous wood fiber stock at 20°SR is greater than 5.5.
10. The process as claimed in one of claims 7 to 9, characterized in that the tearing length for annual plant fiber stock at 20°SR is greater than 4 km, preferably greater than 4.5 km and in particular greater than 5 km.
11. The process for producing a tissue web (1), characterized in that the stock suspension contains only lignocellolosic fibrous material as claimed in one of the preceding claims.
12. The process for producing a tissue web (1), characterized in that the stock suspension is only partly formed from lignocellolosic fibrous material as claimed in one of claims 1 to 11.
13. The process as claimed in claim 12, characterized in that between 20 and 80%, preferably between 30 and 50%, of the fibrous material of the stock suspension is formed from lignocellolosic fibrous material as claimed in one of claims 1 to 11.
14. The process as claimed in one of the preceding claims, characterized in that, during a dewatering step, the tissue web (1) is led between an upper structured and permeable belt (3) and between a lower permeable belt (2), pressure being exerted on the upper belt (3), the tissue web (1) and the lower belt (2) along a dewatering section (11).
15. The process as claimed in claim 14, characterized in that, during a dewatering step (11), a gas flows firstly through the upper belt (3), then the tissue web (1) and then the lower belt (2).
16. The process as claimed in claim 14 or 15, characterized in that, during the dewatering step, the arrangement comprising the upper belt (3), tissue web (1) and lower belt (2) is led, at least in some sections, between a press belt (4) under tension and a smooth surface, the press belt (4) acting on the upper belt (3) and the lower belt (2) being supported on the smooth surface.
17. The process as claimed in claim 15 or 16, characterized in that the gas flow flows through the arrangement comprising the upper belt (3), tissue web (1) and lower belt (2), at least in some sections in the region of the dewatering section (11).
18. The process as claimed in one of claims 15 to 17, characterized in that the gas flow through the tissue web (1) is about 150 m3 per minute and meter length along the dewatering section (11).
19. The process as claimed in one of claims 16 to 18, characterized in that the press belt (4) is under a tension of at least 30 kN/m, preferably at least 60 kN/m and in particular 80 kN/m.
20. The process as claimed in one of claims 16 to 18, characterized in that the press belt (4) has an open area of more than 50% and a contact area of at least 15%.
21. The process as claimed in one of claims 16 to 20, characterized in that the smooth surface is formed by the circumferential surface of a roll (5).
22. The process as claimed in claim 21, characterized in that the gas flow is formed by a suction zone (10) in the roll (5).
23. The process as claimed in one of claims 15 to 22, characterized in that the gas flow is produced by a positive pressure hood (6) arranged above the upper belt (3).
24. A process for producing a stock suspension comprising fibers, in particular for use for the production of a tissue web (1), in which at least a proportion of wood or annual plants having a lignin content of at least 15% for coniferous wood, of at least 12% for deciduous wood and of at least 10% for annual plants, in each case based on the oven-dry fiber stock, is produced by the following steps:
- producing a chemical solution with more than 5%
of chemicals (calculated as NaOH) for coniferous wood or with more than 3.5% of chemicals (calculated as NaOH) for deciduous wood or with more than 2.5% of chemicals (calculated as NaOH) for annual plants, in each case based on the oven-dry quantity of the wood, - mixing the chemical solution with wood or annual plants in a predefined liquor ratio, - heating the chemical solution and the wood or annual plants to a temperature above room temperature and then - either (1st alternative) removing free-flowing chemical solution and digesting the wood or the annual plants in the vapor phase - or (2nd alternative) digesting the wood or the annual plants in the liquid phase and separating the flee-flowing chemical solution and the wood or the annual plants.
- producing a chemical solution with more than 5%
of chemicals (calculated as NaOH) for coniferous wood or with more than 3.5% of chemicals (calculated as NaOH) for deciduous wood or with more than 2.5% of chemicals (calculated as NaOH) for annual plants, in each case based on the oven-dry quantity of the wood, - mixing the chemical solution with wood or annual plants in a predefined liquor ratio, - heating the chemical solution and the wood or annual plants to a temperature above room temperature and then - either (1st alternative) removing free-flowing chemical solution and digesting the wood or the annual plants in the vapor phase - or (2nd alternative) digesting the wood or the annual plants in the liquid phase and separating the flee-flowing chemical solution and the wood or the annual plants.
25. The process as claimed in claim 24, characterized in that a fibrous material is produced which has a lignin content of at least 15%, preferably at least 18%, advantageously at least 21%, in particular at least 24%, based on oven-dry fibrous material, for coniferous wood, or which has a lignin content of at least 14%, preferably at least 16%, particularly preferably at least 18%, based on oven-dry fibrous material, for deciduous wood, or which has a lignin content of at least 10%, preferably at least 12%, in particular at least 19%, based on oven-dry fibrous material, for annual plants.
26. The process as claimed in claim 24 or 25, characterized in that a quinone component is used to produce the chemical solution.
27. The process as claimed in one of claims 24 to 26, characterized in that, in order to digest coniferous wood, at most 15% of chemicals, preferably between 9 and 11% of chemicals, are used.
28. The process as claimed in one of claims 24 to 27, characterized in that, in order to digest deciduous wood, at most 10% of chemicals, preferably between 4 and 10% of chemicals, in particular between 6 and 9% of chemicals, are used.
29. The process as claimed in one of claims 24 to 28, characterized in that, in order to digest annual plants, at most 10%, preferably between 3 and 10%, of chemicals are used.
30. The process as claimed in one of claims 24 to 29, characterized in that, in order to produce the chemical solution, sulfites and sulfides are used, individually or in a mixture.
31. The process as claimed in claim 30, characterized in that, in order to produce the chemical solution, an acid and/or an alkaline component is used, in particular an acid, sulfur dioxide, sodium hydroxide and/or a carbonate.
32. The process as claimed in one of claims 24 to 31, characterized in that, for the purposes of digestion, an alkaline component and an acid component, in particular SO2, are used, the ratio of alkaline component:SO2 being set in a range from 5:1 to 1.6:1, preferably at 2:1.
33. The process as claimed in one of claims 24 to 32, characterized in that the process is carried out at a pH of between 6 and 11, preferably between 7 and 11, particularly preferably between 7.5 and 10.
34. The process as claimed in one of claims 24 to 33, characterized in that a liquor ratio of wood:chemical solution of between 1:1.5 and 1:6, preferably of between 1:2 and 1:4, is set.
35. The process as claimed in one of claims 24 to 34, characterized in that the chemical solution and the wood or the annual plants are heated to up to 130°C, preferably to up to 120°C, advantageously to up to 110°C.
36. The process as claimed in one of claims 24 to 35, characterized in that the wood or the annual plants and possibly the chemical solution are heated for up to 120 minutes, preferably for up to 60 minutes, advantageously for up to 30 minutes, particularly advantageously for up to 10 minutes.
37. The process as claimed in one of claims 24 to 36, characterized in that the wood or the annual plants are digested at temperatures between 120°C
and 190°C, preferably at temperatures between 150°C and 180°C, particularly preferably at temperatures between 160°C and 170°C.
and 190°C, preferably at temperatures between 150°C and 180°C, particularly preferably at temperatures between 160°C and 170°C.
38. The process as claimed in one of claims 24 to 37, characterized in that the digestion of the wood or the annual plants lasts for up to 180 minutes, preferably up to 90 minutes, particularly preferably up to 60 minutes, advantageously up to 30 minutes, particularly advantageously up to 2 minutes.
39. The process as claimed in claim 38, characterized in that the digestion time is chosen as a function of the liquor ratio.
40. The process as claimed in one of claims 24 to 39, characterized in that the consumption of chemicals during the digestion is up to 80%, preferably up to 60%, particularly preferably up to 40%, advantageously up to 20%, particularly advantageously up to 10%, of the chemicals put in at the start of the digestion.
41. The process as claimed in one of claims 24 to 40, characterized in that the composition of the chemical solution that is removed or separated is registered and subsequently adjusted to a prescribed composition for renewed use for the production of fibers.
42. The process as claimed in one of claims 24 to 41, characterized in that chemical solution liberated after the defibering and possible refining of the digested lignocellolosic material is removed and supplied to further use.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006061480.1 | 2006-12-23 | ||
DE200610061480 DE102006061480A1 (en) | 2006-12-23 | 2006-12-23 | Producing fibrous material comprises producing a chemical solution, mixing the chemical solution with wood and/or annual plant; heating the chemical solution and pulping and then separating the woods and the chemical solution |
DE102007017061.2 | 2007-04-11 | ||
DE200710017061 DE102007017061A1 (en) | 2007-04-11 | 2007-04-11 | Pulp, for tissue paper production, is of wood or annual plant fibers with structured lignin contents and shear lengths |
PCT/EP2007/010165 WO2008077450A1 (en) | 2006-12-23 | 2007-11-23 | Method for the production of tissue paper |
Publications (1)
Publication Number | Publication Date |
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CA2673175A1 true CA2673175A1 (en) | 2008-07-03 |
Family
ID=38983930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002673175A Abandoned CA2673175A1 (en) | 2006-12-23 | 2007-11-23 | Process for producing tissue paper |
Country Status (7)
Country | Link |
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US (1) | US20090266500A1 (en) |
EP (1) | EP2126195A1 (en) |
JP (1) | JP2010514946A (en) |
BR (1) | BRPI0718883A2 (en) |
CA (1) | CA2673175A1 (en) |
RU (1) | RU2009128370A (en) |
WO (1) | WO2008077450A1 (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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DE102007036382A1 (en) * | 2007-07-31 | 2009-02-05 | Voith Patent Gmbh | Lignocellulosic pulp from annual plants |
CN102154899B (en) * | 2011-04-28 | 2012-05-23 | 永州湘江纸业有限责任公司 | Base paper of sandpaper and production method thereof |
US8524374B2 (en) | 2011-09-21 | 2013-09-03 | Kimberly-Clark Worldwide, Inc. | Tissue Product comprising bamboo |
SG11201708100WA (en) | 2015-04-29 | 2017-11-29 | Sca Hygiene Prod Ab | Tissue paper comprising pulp fibers originating from miscanthus and method for manufacturing the same |
CN105297526B (en) * | 2015-11-03 | 2017-05-24 | 山东鲁南新材料股份有限公司 | Water-resistant abrasive base paper and production method thereof |
WO2018026804A1 (en) | 2016-08-01 | 2018-02-08 | Domtar Paper Company, Llc | Surface enhanced pulp fibers at a substrate surface |
CA3041057A1 (en) | 2016-10-18 | 2018-04-26 | Domtar Paper Company, Llc | Method for production of filler loaded surface enhanced pulp fibers |
WO2018156109A1 (en) | 2017-02-22 | 2018-08-30 | Kimberly-Clark Worldwide, Inc. | Layered tissue comprising non-wood fibers |
CA3088962A1 (en) * | 2018-02-05 | 2019-08-08 | Harshad PANDE | Paper products and pulps with surface enhanced pulp fibers and increased absorbency, and methods of making same |
WO2020198516A1 (en) | 2019-03-26 | 2020-10-01 | Domtar Paper Company, Llc | Paper products subjected to a surface treatment comprising enzyme-treated surface enhanced pulp fibers and methods of making the same |
WO2020229737A1 (en) * | 2019-05-15 | 2020-11-19 | Kemira Oyj | Fiber formulation, its use and method for making it |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB478943A (en) * | 1935-04-24 | 1938-01-24 | Cellulose Res Corp | System of obtaining and treating cellulose and product thereof |
GB885605A (en) * | 1958-09-11 | 1961-12-28 | Stora Kopparbergs Bergslags Ab | Improved method for the production of neutral sulfite pulp |
JPH0931880A (en) * | 1995-07-17 | 1997-02-04 | Mitsubishi Paper Mills Ltd | Bleaching and modification of chemical pulp |
GB2382592A (en) * | 2001-11-30 | 2003-06-04 | Sca Hygiene Prod Gmbh | Use of ozone to enhance the wet strength of fibrous cellulosic material |
CN1177101C (en) * | 2002-07-05 | 2004-11-24 | 岳阳纸业股份有限公司 | Chemical treatment and hot pulping process of wood pulp and dreg pulp with mechanical mill and stone mill |
CN1208519C (en) * | 2003-01-15 | 2005-06-29 | 岳阳纸业股份有限公司 | Surface glued newsprinting paper and manufacturing method thereof |
JP2007519834A (en) * | 2004-01-30 | 2007-07-19 | ボイス ペ−パ− パテント ゲ−エムベ−ハ− | State-of-the-art dehydration system |
DE102005036075A1 (en) * | 2005-08-01 | 2007-02-15 | Voith Patent Gmbh | Process for the production of tissue paper |
KR100694840B1 (en) * | 2005-06-09 | 2007-03-14 | 유해일 | Manufacturing method of mechanical pulp from cornstalk |
DE102005049502A1 (en) * | 2005-10-13 | 2007-04-19 | Voith Patent Gmbh | Process for the production of tissue paper |
-
2007
- 2007-11-23 BR BRPI0718883-8A2A patent/BRPI0718883A2/en not_active Application Discontinuation
- 2007-11-23 WO PCT/EP2007/010165 patent/WO2008077450A1/en active Application Filing
- 2007-11-23 JP JP2009541802A patent/JP2010514946A/en active Pending
- 2007-11-23 CA CA002673175A patent/CA2673175A1/en not_active Abandoned
- 2007-11-23 RU RU2009128370/12A patent/RU2009128370A/en unknown
- 2007-11-23 EP EP07846766A patent/EP2126195A1/en not_active Withdrawn
-
2009
- 2009-04-30 US US12/432,919 patent/US20090266500A1/en not_active Abandoned
Also Published As
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RU2009128370A (en) | 2011-01-27 |
JP2010514946A (en) | 2010-05-06 |
US20090266500A1 (en) | 2009-10-29 |
WO2008077450A1 (en) | 2008-07-03 |
BRPI0718883A2 (en) | 2014-02-18 |
EP2126195A1 (en) | 2009-12-02 |
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