CA2668473C - Use of a binary salt flux of nacl and mgcl2 for the purification of aluminum or aluminum alloys, and method thereof - Google Patents
Use of a binary salt flux of nacl and mgcl2 for the purification of aluminum or aluminum alloys, and method thereof Download PDFInfo
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- CA2668473C CA2668473C CA2668473A CA2668473A CA2668473C CA 2668473 C CA2668473 C CA 2668473C CA 2668473 A CA2668473 A CA 2668473A CA 2668473 A CA2668473 A CA 2668473A CA 2668473 C CA2668473 C CA 2668473C
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/10—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals with refining or fluxing agents; Use of materials therefor, e.g. slagging or scorifying agents
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/062—Obtaining aluminium refining using salt or fluxing agents
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Abstract
A use and a method for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, wherein said metal is in a liquid phase and is contacted with a salt flux consisting of a binary mixture of NaCl and MgCl2. Preferably, more than 22 % by weight of the binary mixture consists of NaCl.
Description
, USE OF A BINARY SALT FLUX OF NaCI and MgC12 FOR THE PURIFICATION
OF ALUMINUM OR ALUMINUM ALLOYS, AND METHOD THEREOF
Field of the invention [0001] The invention relates to the use of a binary salt flux comprising NaCI
and MgCl2 for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, more particularly for the removal of alkali and alkaline-earth metals. The invention also relates to a method for the purification of said metal with said binary salt flux.
Prior art [0002] The use of fluxes is well known in the field of metallurgy and these fluxes fulfill various functions.
OF ALUMINUM OR ALUMINUM ALLOYS, AND METHOD THEREOF
Field of the invention [0001] The invention relates to the use of a binary salt flux comprising NaCI
and MgCl2 for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, more particularly for the removal of alkali and alkaline-earth metals. The invention also relates to a method for the purification of said metal with said binary salt flux.
Prior art [0002] The use of fluxes is well known in the field of metallurgy and these fluxes fulfill various functions.
[0003] Fluxes can be used to form a protecting layer at the surface of an alloy to prevent oxidation. When fluxes contain chemical active agents, they can be used to clean furnace walls by softening accumulated layers of corundum. Some exothermic fluxes are also used for cleaning dross and removing aluminum trapped in oxide layers.
[0004] Fluxes that are based on alkali chlorides and alkaline-earth chlorides are also used for the refining of alloys. Those skilled in the art generally define refining as the removal of alkali and alkaline-earth metals, non metallic inclusions and hydrogen from the alloys.
[0005] Sodium and calcium are always present as impurities in aluminum obtained from the Hall-Fleroult process. Lithium fluoride is often added to the electrolytic bath to improve the efficiency of cells. However, a small amount in the metallic state is found dissolved in the aluminum. These impurities entail quality issues. For example, in an alloy containing magnesium, the presence of sodium may interfere during the hot rolling processes. The presence of sodium in aluminum and silicon alloys neutralize the effect of phosphorus used for the refining of grains. For the above-mentioned reasons, the use of fluxes containing sodium is not recommended for aluminum and its alloys, more particularly for aluminum alloys comprising a magnesium content higher than 3 % by weight or a silicon content higher than 10 `)/0 by weight.
[0006] Also, the presence of hydrogen in too high concentration may lead to a too high porosity of the aluminum during its solidification. During the recycling of aluminum, the presence of non metallic inclusions is important.
[0007] Reactional kinetics for the withdrawal of calcium and sodium in an aluminum alloy have been well studied. Naturally, in these alloys, both impurities disappear according to a kinetic of order 1 for small concentrations and order 0 for high concentrations. Because of its high vapor tension, sodium oxidizes itself more rapidly than calcium, that is why calcium is used during cleaning tests. The addition of fluxes involves an increase of reactional constants and thereby a faster reduction of the content in impurities. Mixing also has a non negligible effect on the reduction of impurities. Mixing accelerates the withdrawal of impurities by increasing the contact between impurities and the salt flux.
[0008] MgCl2 is one of the chemical active agents used for the withdrawal of impurities in alloys. Its concentration has a direct effect on the kinetic of withdrawal of calcium and sodium. Its melting point is 714 C, but in common fluxes, it is mixed with other salts to obtain a melting point between 400 and 550 C. However, MgC12 is hygroscopic and can not be exposed for a long period of time to the surrounding air.
Fluxes obtained by fusion of salts comprising magnesium chloride have hygroscopic properties. Consequently, the packaging is an important factor in limiting the absorption of humidity during the manufacturing of such fluxes.
Fluxes obtained by fusion of salts comprising magnesium chloride have hygroscopic properties. Consequently, the packaging is an important factor in limiting the absorption of humidity during the manufacturing of such fluxes.
[0009] There are examples of fluxes that are based on magnesium chloride. US
patent no. 1,377,374 relates to the use of a flux having an equimolar composition of sodium chloride and magnesium chloride for the production of manganese or magnesium alloys. US patent no. 1,754,788 relates to the use of this same flux in a process for the cleaning of magnesium. US patent no. 1,519,128 relates to the addition of calcium chloride to this composition and US patent no. 2,262,105 relates to the addition of potassium chloride and magnesium oxide in addition to the calcium chloride. US patent no. 5,405,427 mentions a flux based on sodium chloride, magnesium chloride, potassium chloride and carbon for the treatment of metal.
patent no. 1,377,374 relates to the use of a flux having an equimolar composition of sodium chloride and magnesium chloride for the production of manganese or magnesium alloys. US patent no. 1,754,788 relates to the use of this same flux in a process for the cleaning of magnesium. US patent no. 1,519,128 relates to the addition of calcium chloride to this composition and US patent no. 2,262,105 relates to the addition of potassium chloride and magnesium oxide in addition to the calcium chloride. US patent no. 5,405,427 mentions a flux based on sodium chloride, magnesium chloride, potassium chloride and carbon for the treatment of metal.
[0010] The article entitled "Salt Fluxes for Alkali and Alkali and Alkaline Earth Element Removal from Molten Aluminum" by David H. DeYoung (7th Australian Asian Pacific Conference Aluminum Cast House Technology, pp: 99-113 (2001)) shows the use of a ternary salt based on magnesium chloride, sodium chloride and potassium chloride for the removal of sodium, calcium and lithium from aluminum alloys. However, the article entitled "The Treatment of Liquid Aluminum-Silicon Alloys" by Gruzleski et al., (American Foundrymen's Society, Inc. pp. 204-205, 1990) indicates that it is important to those skilled in the art, not to use fluxes containing sodium salts. Therefore, even if a ternary flux salts having low content in sodium salts may be tolerated, those skilled in the art are expressly invited to avoid using sodium salts.
[0011] Initially, the refining of aluminum was carried out by bubbling of chlorine and argon in the liquid metal. However, this created environmental problems due to emissions of chlorine, chlorhydric acid and particles in suspension. The use of salt fluxes was later adopted as a more ecologically-friendly solution.
, , [0012] The refining fluxes are usually composed of alkali chlorides or alkaline-earth chlorides, which are mixed to obtain melting points that are lower than the operating temperature of alloys -- the melting point of pure compounds being usually quite high.
, , [0012] The refining fluxes are usually composed of alkali chlorides or alkaline-earth chlorides, which are mixed to obtain melting points that are lower than the operating temperature of alloys -- the melting point of pure compounds being usually quite high.
[0013] Several methods can be used to incorporate salt fluxes in an alloy. US
patent no. 4,099,965 relates to a method where a flux of KCI and MgC12 is added in solid form in the bottom of a preheated container before the addition of aluminum.
More currently, fluxes are added by an inert gas in a pipe under the surface of the metal (lance fluxing). Recently, a method was developed where a hollow shaft brings the salt flux in the alloy with a gas carrier, and the salt flux is dispersed by an agitator (rotary flux injection). This method reduces the amount of salt flux required for carrying out the purification while increasing the dispersion of this salt flux in the alloy. Following the addition of a salt flux to the metal, impurities and salts float on the surface of the liquid metal and can be easily removed.
patent no. 4,099,965 relates to a method where a flux of KCI and MgC12 is added in solid form in the bottom of a preheated container before the addition of aluminum.
More currently, fluxes are added by an inert gas in a pipe under the surface of the metal (lance fluxing). Recently, a method was developed where a hollow shaft brings the salt flux in the alloy with a gas carrier, and the salt flux is dispersed by an agitator (rotary flux injection). This method reduces the amount of salt flux required for carrying out the purification while increasing the dispersion of this salt flux in the alloy. Following the addition of a salt flux to the metal, impurities and salts float on the surface of the liquid metal and can be easily removed.
[0014] Advantageously, the use of solid compounds obtained by melting of salts controls the granulometry. Particles may be used in batch processes or in continuous processes.
[0015] However, costs related to salt fluxes such as binary mixtures of magnesium chloride and potassium chloride, are high. Furthermore, the use of salt fluxes having a substantial content in sodium chloride is not recommended by those skilled in the art due to perceived negative effects of sodium content in the resulting aluminum or aluminum alloys. In fact, when sodium chloride is present in fluxes for the purification of aluminum or aluminum alloys, those skilled in the art currently will avoid or limit the use of sodium chloride. More particularly, in the case of certain kinds of alloys such as, for example, aluminum alloys having silicon content higher than 10%
by , weight and more particularly aluminum alloys having magnesium content higher than 3% by weight, those skilled in the art currently recommend not using sodium chloride in salt flux.
by , weight and more particularly aluminum alloys having magnesium content higher than 3% by weight, those skilled in the art currently recommend not using sodium chloride in salt flux.
[0016] During Applicant's search for a more effective solution to the purification problem, it was surprisingly noted that contrary to current apprehensions and beliefs of those skilled in the art, it is possible in a salt flux containing MgC12, to replace expensive KCI by inexpensive NaCI. Consequently, the present invention offers an economical solution for the treatment of aluminum or aluminum alloys with an efficiency of purification that is equivalent to methods presently used.
Indeed, contrary to apprehensions of those skilled in the art, there is no significant amount of sodium in the resulting aluminum or aluminum alloys when using the inventive purification method described herein.
Indeed, contrary to apprehensions of those skilled in the art, there is no significant amount of sodium in the resulting aluminum or aluminum alloys when using the inventive purification method described herein.
[0017] Embodiments of the present invention show the following advantages:
- Economical advantages o Lower production costs because the melting point of the flux is lower.
o Lower costs of raw material.
-Efficiency equivalent to the purification methods using an existing well known salt flux sold under the trademark Promag (40 wt % KCI ¨ 60 wt % MgCl2).
- Economical alternative to existing product sold under the trademark Promag without creating any significant accumulation of sodium within aluminum or aluminum alloys.
, Summary of the Invention [0018] A first preferred aspect of the invention relates to the use of a salt flux for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, said metal being in liquid phase and said salt flux being a binary mixture of NaCI and MgCl2.
- Economical advantages o Lower production costs because the melting point of the flux is lower.
o Lower costs of raw material.
-Efficiency equivalent to the purification methods using an existing well known salt flux sold under the trademark Promag (40 wt % KCI ¨ 60 wt % MgCl2).
- Economical alternative to existing product sold under the trademark Promag without creating any significant accumulation of sodium within aluminum or aluminum alloys.
, Summary of the Invention [0018] A first preferred aspect of the invention relates to the use of a salt flux for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, said metal being in liquid phase and said salt flux being a binary mixture of NaCI and MgCl2.
[0019] A second preferred aspect of the invention relates to a method for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, wherein said method comprises:
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of a binary mixture of NaCI and MgCl2.
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of a binary mixture of NaCI and MgCl2.
[0020] Another embodiment of the invention relates to a use or a method as defined hereinabove, wherein more than 22 "Yo by weight of said binary mixture consists of NaCl.
[0021] Another embodiment of the invention relates to a use or a method as defined hereinabove, wherein the salt flux:
= is a binary mixture of particles of NaCI and particles of MgC12; or = consists of particles resulting from the grinding of a fused salt of NaCI
and MgC12 in solid state; or = is a liquid mixture of NaCI and MgCl2.
= is a binary mixture of particles of NaCI and particles of MgC12; or = consists of particles resulting from the grinding of a fused salt of NaCI
and MgC12 in solid state; or = is a liquid mixture of NaCI and MgCl2.
[0022] Another embodiment of the invention relates to a use or a method as defined in any one of the above-mentioned embodiments, wherein the binary mixture = CA 02668473 2012-08-21 comprises: a) from 40 to 50% by weight of NaCI; and b) from 50 to 60% by weight of MgCl2. More particularly, this binary mixture comprises 45% by weight of NaCI
and 55% by weight of MgC12 to form an eutectic mixture having a melting point of about 439 C.
[0022-a] Another embodiment of the invention relates to a use of a salt flux for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, said metal being in a liquid phase and said salt flux consisting of:
= a binary mixture of particles of NaCI and particles of MgC12, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 %
by weight of MgCl2; or = a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgC12comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12; or = a liquid binary mixture of NaCI and MgC12 comprising more than 22 % by weight of the binary mixture consists of NaCl.
[0022-b] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is a binary mixture of particles of NaCI
and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
[0022-c] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is in the form of particles obtained by grinding a fused salt of NaCI and MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12.
7a [0022-d] Another embodiment of the invention relates to a use as defined hereinabove, wherein the binary mixture of particles comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgC12;
to form an eutectic binary mixture having a melting point of about 439 C.
[0022-e] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is a liquid binary mixture of NaCI and MgCl2 wherein more than 22 % by weight of the binary mixture consists of NaCI.
[0022-f] Another embodiment of the invention relates to a use as defined hereinabove, wherein the liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCl; and b) from 50 to 60 % by weight of MgC12.
[0022-g] Another embodiment of the invention relates to a use as defined hereinabove, wherein the liquid binary mixture comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgC12.
[0022-h] Another embodiment of the invention relates to a use of a salt flux for the purification of an aluminum alloy having a silicon content higher than 10 % by weight, said metal being in a liquid phase and said salt flux consisting of:
= a binary mixture of particles of NaCI and particles of MgC12 wherein more than 22% by weight of the binary mixture consists of NaCI; or = a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgCl2; or 7b = a liquid binary mixture of NaCI and MgCl2.
[0022-i] Another embodiment of the invention relates to a method for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, wherein said method comprises:
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of:
o a binary mixture of particles of NaCI and particles of MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or o a binary mixture of particles obtained by grinding a fused salt of NaCI
and Mg C12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12; or o a liquid binary mixture of NaCI and MgC12 comprising more than 22 %
by weight of the binary mixture consists of NaCl.
[0022-j] Another embodiment of the invention relates to a method as defined hereinabove, wherein the salt flux is a binary mixture of particles of NaCI
and particles of MgC12, said binary mixture comprising from from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
[0022-k] Another embodiment of the invention relates to a method as defined hereinabove, wherein said salt flux is in the form of particles obtained by grinding a fused salt of NaCI and MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12.
[0022-1] Another embodiment of the invention relates to a method as defined hereinabove, wherein the binary mixture of particles comprises:
a) 45 A by weight of NaCI; and 7c b) 55 % by weight of Mg C12;
to form an eutectic binary mixture having a melting point of 439 C.
[0022-m] Another embodiment of the invention relates to a method as defined hereinabove, wherein said salt flux is a liquid binary mixture of NaCI and MgC12 comprising more than 22 % by weight of the binary mixture consists of NaCI.
[0022-n] Another embodiment of the invention relates to a method as defined hereinabove, wherein said liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgC12.
[0022-0] Another embodiment of the invention relates to a method as defined hereinabove, wherein said liquid binary mixture comprises:
a) 45 c1/0 by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of about 439 C.
[0022-p] Another embodiment of the invention relates to a method for the purification of an aluminum alloy having a silicon content higher than 10 '3/0 by weight, wherein said method comprises:
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of:
o a binary mixture of particles of NaCI and particles of MgC12 MgC12 wherein more than 22% by weight of the binary mixture consists of NaCI; or 7d o a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgC12; or 0 a liquid binary mixture of NaCI and MgC12.
and 55% by weight of MgC12 to form an eutectic mixture having a melting point of about 439 C.
[0022-a] Another embodiment of the invention relates to a use of a salt flux for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, said metal being in a liquid phase and said salt flux consisting of:
= a binary mixture of particles of NaCI and particles of MgC12, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 %
by weight of MgCl2; or = a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgC12comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12; or = a liquid binary mixture of NaCI and MgC12 comprising more than 22 % by weight of the binary mixture consists of NaCl.
[0022-b] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is a binary mixture of particles of NaCI
and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
[0022-c] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is in the form of particles obtained by grinding a fused salt of NaCI and MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12.
7a [0022-d] Another embodiment of the invention relates to a use as defined hereinabove, wherein the binary mixture of particles comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgC12;
to form an eutectic binary mixture having a melting point of about 439 C.
[0022-e] Another embodiment of the invention relates to a use as defined hereinabove, wherein the salt flux is a liquid binary mixture of NaCI and MgCl2 wherein more than 22 % by weight of the binary mixture consists of NaCI.
[0022-f] Another embodiment of the invention relates to a use as defined hereinabove, wherein the liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCl; and b) from 50 to 60 % by weight of MgC12.
[0022-g] Another embodiment of the invention relates to a use as defined hereinabove, wherein the liquid binary mixture comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgC12.
[0022-h] Another embodiment of the invention relates to a use of a salt flux for the purification of an aluminum alloy having a silicon content higher than 10 % by weight, said metal being in a liquid phase and said salt flux consisting of:
= a binary mixture of particles of NaCI and particles of MgC12 wherein more than 22% by weight of the binary mixture consists of NaCI; or = a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgCl2; or 7b = a liquid binary mixture of NaCI and MgCl2.
[0022-i] Another embodiment of the invention relates to a method for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, wherein said method comprises:
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of:
o a binary mixture of particles of NaCI and particles of MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or o a binary mixture of particles obtained by grinding a fused salt of NaCI
and Mg C12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12; or o a liquid binary mixture of NaCI and MgC12 comprising more than 22 %
by weight of the binary mixture consists of NaCl.
[0022-j] Another embodiment of the invention relates to a method as defined hereinabove, wherein the salt flux is a binary mixture of particles of NaCI
and particles of MgC12, said binary mixture comprising from from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
[0022-k] Another embodiment of the invention relates to a method as defined hereinabove, wherein said salt flux is in the form of particles obtained by grinding a fused salt of NaCI and MgC12 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgC12.
[0022-1] Another embodiment of the invention relates to a method as defined hereinabove, wherein the binary mixture of particles comprises:
a) 45 A by weight of NaCI; and 7c b) 55 % by weight of Mg C12;
to form an eutectic binary mixture having a melting point of 439 C.
[0022-m] Another embodiment of the invention relates to a method as defined hereinabove, wherein said salt flux is a liquid binary mixture of NaCI and MgC12 comprising more than 22 % by weight of the binary mixture consists of NaCI.
[0022-n] Another embodiment of the invention relates to a method as defined hereinabove, wherein said liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgC12.
[0022-0] Another embodiment of the invention relates to a method as defined hereinabove, wherein said liquid binary mixture comprises:
a) 45 c1/0 by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of about 439 C.
[0022-p] Another embodiment of the invention relates to a method for the purification of an aluminum alloy having a silicon content higher than 10 '3/0 by weight, wherein said method comprises:
= heating the metal to a liquid phase; and = contacting the liquid metal with a salt flux consisting of:
o a binary mixture of particles of NaCI and particles of MgC12 MgC12 wherein more than 22% by weight of the binary mixture consists of NaCI; or 7d o a binary mixture of particles obtained by grinding a fused salt of NaCI
and MgC12; or 0 a liquid binary mixture of NaCI and MgC12.
[0023] Another embodiment of the invention relates to a use or a method as defined in any one of the above-mentioned embodiments, wherein when the salt flux is in the form of particles, those particles have an average particle size between 100 pm and 3.35 mm. Preferably, said particles may have a particle size between 0.85 mm and 3.15 mm or between 100 pm and 1 mm.
[0024] Another embodiment of the invention relates to a use or a method as defined in any one of the above-mentioned embodiments, wherein the particles are contacted with the liquid metal by injection with a gas injection equipment. A
non-limiting example of a gas injection equipment may consist of a rotary injector known under the tradename SNIF PHD-50 commercialized by the Applicant.
non-limiting example of a gas injection equipment may consist of a rotary injector known under the tradename SNIF PHD-50 commercialized by the Applicant.
[0025] Another embodiment of the invention relates to a use or a method as defined in any one of the above-mentioned embodiments, wherein the metal is an aluminum alloy having a magnesium content higher than 3% by weight.
[0026] Another embodiment of the invention relates to a use or a method as defined in any one of the above-mentioned embodiments, wherein the metal is an aluminum alloy having a silicon content higher than 10% by weight.
[0027] The present invention will be better understood with reference to the following drawings:
= Figure 1: a phase diagram of a fused salt KCl/NaCl/MgC12;
= Figure 2: a phase diagram of a fused salt KCl/MgC12;
OMMED
, = Figure 3: a phase diagram of a fused salt NaCl/MgC12; and = Figure 4: a comparative graphic concerning examples 5 to 8.
Phase diagrams of Figures 1 to 3 were extracted from factsage web site (http://factsage.com).
DESCRIPTION OF EMBODIMENTS OF THE INVENTION
= Figure 1: a phase diagram of a fused salt KCl/NaCl/MgC12;
= Figure 2: a phase diagram of a fused salt KCl/MgC12;
OMMED
, = Figure 3: a phase diagram of a fused salt NaCl/MgC12; and = Figure 4: a comparative graphic concerning examples 5 to 8.
Phase diagrams of Figures 1 to 3 were extracted from factsage web site (http://factsage.com).
DESCRIPTION OF EMBODIMENTS OF THE INVENTION
[0028] In the following examples, the Applicant has noted, contrary to apprehensions of those skilled in the art, that formulations of salt fluxes comprising a binary mixture of NaCI and MgC12 do not involve an increase of the concentration of metallic sodium in an aluminum alloy having magnesium content. A non limiting example of such an aluminum alloy may consist of an aluminum alloy having a magnesium content of 5 `)/0 by weight. Consequently, it appears that there is no counter-indication of using a binary salt flux comprising NaCI and MgCl2 for cleaning aluminum, especially in the case of an aluminum alloy with high magnesium content.
[0029] Formulations based on NaCI and MgC12 proposed according to the present invention, show melting points that are lower than those of salt flux compositions sold by the Applicant under the trademark Promag (40 wt % KCI, 60 wt % MgC12), for equivalent amounts of MgCl2 which is the chemically active agent for the withdrawal of impurities. The lowering of melting points represents a lowering of energy costs when melting the solid salt flux.
[0030] Two fused salts have been evaluated in examples hereinafter, that is (on a weight basis) the following binary system salt flux and ternary system salt flux (prior art):
= 45 % NaCI and 55 A MgCl2 with a melting point of 439 C; and , , = 20 % NaCI, 20 % KCI and 60% MgC12 with a melting point of 396 C.
= 45 % NaCI and 55 A MgCl2 with a melting point of 439 C; and , , = 20 % NaCI, 20 % KCI and 60% MgC12 with a melting point of 396 C.
[0031] Also, example 1 illustrates an unexpected effect with regard to the sodium concentration in an aluminum alloy when NaCI is added in a liquid aluminum alloy, that is, no increase of the sodium content in the alloy obtained.
[0032] Preparation of each salt flux was made by mixing the salts in an anhydrous solid phase in an appropriate oven. Then, by increasing the temperature of the oven, a fused compound in liquid form was obtained. The liquid was then cooled down quickly, grinded and sifted to obtain a granulometry that was appropriate for the selected method. In example 7 hereinafter, the salt flux was made only by mixing the salts in an anhydrous solid phase.
[0033] Salt fluxes have shown an optimal efficiency for the withdrawal of Ca, Na and Li when used with a rotary injector such as a SNIF PHD-50 (tradename) commercialized by the Applicant (Pyrotek). Of course, other methods of addition well known to those skilled in the art and already mentioned for use in connection with prior art purification methods can be used to carry out the purification. The concentrations of salt fluxes required to carry out the purification may vary depending on the selected method.
Example 1 [0034] In a crucible made of graphite, one hundred grams (100 g) of NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL, were agitated in 1.5 kg of a liquid AA110 aluminum (sold under the trademark Alcan) in which 5 wt % of solid magnesium were added. The crucible was maintained at 850 C during the whole test. Samples were taken every day during 7 days. According to these daily analyses, the sodium content of the resulting aluminum alloy was at a minimal level of 2 ppm during the whole test, showing that, contrary to apprehensions of those skilled in the art, an addition of NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content.
Example 2 [0035] In a graphite crucible, fifteen grams (15 g) of a salt flux consisting of a binary 5 mixture of 45 wt % NaCI and 55 wt % MgC12 were agitated in 1.5 kg of a liquid AA1100 aluminum alloy (sold under the trademark Alcan) in which 5 wt % of magnesium were added. The crucible was maintained at 720 C during 90 minutes and samples were taken every 30 minutes. The sodium level in the crucible was maintained at a minimal level of 3 ppm during the whole experiment, showing that an 10 addition of a flux comprising NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content. The salt flux was prepared from NaCI
in powder form and sold under the trademark SIFTO INDUSTRIAL and MgC12 in flake form and sold under the trademark SKYLINE.
Example 3 (prior art) [0036] In a graphite crucible, fifteen grams (15 g) of a salt flux consisting of a ternary mixture of 20 wt % NaCI, 20 wt % KCI and 60 wt % MgC12 were agitated and added in 1.5 kg of a liquid AA1100 aluminum alloy (sold under the trademark Alcan) in which 5 wt % of magnesium were added. The crucible was maintained at 720 C
during 90 minutes and samples were taken every 30 minutes. The sodium level in the crucible was maintained at a minimal level of 3 ppm during the whole experiment, showing that an addition of a ternary flux comprising a small amount of NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content. The salt flux was prepared from NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL, KCI in powder form and sold under the trademark IMC KALIUM and MgC12 in flake form and sold under the trademark SKYLINE.
, Example 4:
Example 1 [0034] In a crucible made of graphite, one hundred grams (100 g) of NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL, were agitated in 1.5 kg of a liquid AA110 aluminum (sold under the trademark Alcan) in which 5 wt % of solid magnesium were added. The crucible was maintained at 850 C during the whole test. Samples were taken every day during 7 days. According to these daily analyses, the sodium content of the resulting aluminum alloy was at a minimal level of 2 ppm during the whole test, showing that, contrary to apprehensions of those skilled in the art, an addition of NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content.
Example 2 [0035] In a graphite crucible, fifteen grams (15 g) of a salt flux consisting of a binary 5 mixture of 45 wt % NaCI and 55 wt % MgC12 were agitated in 1.5 kg of a liquid AA1100 aluminum alloy (sold under the trademark Alcan) in which 5 wt % of magnesium were added. The crucible was maintained at 720 C during 90 minutes and samples were taken every 30 minutes. The sodium level in the crucible was maintained at a minimal level of 3 ppm during the whole experiment, showing that an 10 addition of a flux comprising NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content. The salt flux was prepared from NaCI
in powder form and sold under the trademark SIFTO INDUSTRIAL and MgC12 in flake form and sold under the trademark SKYLINE.
Example 3 (prior art) [0036] In a graphite crucible, fifteen grams (15 g) of a salt flux consisting of a ternary mixture of 20 wt % NaCI, 20 wt % KCI and 60 wt % MgC12 were agitated and added in 1.5 kg of a liquid AA1100 aluminum alloy (sold under the trademark Alcan) in which 5 wt % of magnesium were added. The crucible was maintained at 720 C
during 90 minutes and samples were taken every 30 minutes. The sodium level in the crucible was maintained at a minimal level of 3 ppm during the whole experiment, showing that an addition of a ternary flux comprising a small amount of NaCI does not involve an absorption of sodium in an aluminum alloy with high magnesium content. The salt flux was prepared from NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL, KCI in powder form and sold under the trademark IMC KALIUM and MgC12 in flake form and sold under the trademark SKYLINE.
, Example 4:
[0037] About seventy-five kilos (75kg) of A356 alloy were melted and maintained in a liquid state at 700 C in a crucible made of silicon carbide. Then, 535g of an aluminum alloy containing 10 % by weight of calcium were added to the liquid alloy while mixing it with an agitator having straight blades. Then the resulting aluminum alloy contained in the crucible was left without agitation for 5 hours. During this time, the calcium content of the resulting aluminum alloy was reduced from 350 ppm to 150 ppm. Then, three hundred and sixty grams (360g) of a salt flux made of 45 wt % NaCI and 55 wt % MgCl2 were added to the resulting alloy while agitating it in order to further purify it. The salt flux was prepared from NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL and MgC12 in flake form and sold under the trademark SKYLINE.
[0038] Analyses made on the purified aluminum alloy have shown a reduction of the Ca content from 150 ppm to 70 ppm, that is a reduction of 53 %, immediately after the addition of the salt flux, and this Ca content drops to 25 ppm 3 hours after the addition. Also, analyses have shown that the sodium content was in the order of 2 ppm.
Example 5 [0039] Fifty grams of a flux were prepared in a small alumina crucible by mixing 22.5 grams of NaCI in powder form and sold under the trademark SIFTO
INDUSTRIAL, and 27.5 grams of MgC12 in flake form and sold under the trademark SKYLINE. The mixture was subjected to a temperature of 550 C during 45 minutes.
The liquid mixture obtained was then poured into an enamelled-coated bowl for quick solidification. The salt flux obtained was then grinded with in a mortar and sifted. The fraction having a particle size lower than 3150 microns and higher than 105 microns was recovered.
, , [0040] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid state at 700 C in a graphite crucible. To this alloy, 2 grams of an aluminum alloy consisting of 90 wt % of aluminum and 10 wt `)/0 of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. The agitation was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the flux formed hereinabove were added to the liquid aluminum alloy doped with calcium while agitating for 2 minutes. Samples were taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
Example 5 [0039] Fifty grams of a flux were prepared in a small alumina crucible by mixing 22.5 grams of NaCI in powder form and sold under the trademark SIFTO
INDUSTRIAL, and 27.5 grams of MgC12 in flake form and sold under the trademark SKYLINE. The mixture was subjected to a temperature of 550 C during 45 minutes.
The liquid mixture obtained was then poured into an enamelled-coated bowl for quick solidification. The salt flux obtained was then grinded with in a mortar and sifted. The fraction having a particle size lower than 3150 microns and higher than 105 microns was recovered.
, , [0040] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid state at 700 C in a graphite crucible. To this alloy, 2 grams of an aluminum alloy consisting of 90 wt % of aluminum and 10 wt `)/0 of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. The agitation was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the flux formed hereinabove were added to the liquid aluminum alloy doped with calcium while agitating for 2 minutes. Samples were taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
[0041] Analyses of samples have shown a reduction of the Ca level from 115 ppm to 3 ppm after the addition of the salt flux. Thirty minutes later, the calcium level was under 2 ppm. No increase in the sodium content was noted during the test. The level of sodium in the alloy was in the order of 2 ppm.
Example 6 (prior art) [0042] Fifty grams of a salt flux were prepared in a small alumina crucible by mixing 10 grams of NaCI in powder form and sold under the trademark SIFTO
INDUSTRIAL, 10 grams of KCI in powder form and sold under the trademark IMC
KALIUM, and 30 grams of MgCl2 in flake form and sold under the trademark SKYLINE. The mixture was subjected to a temperature of 550 C during 45 minutes.
The liquid mixture obtained was then poured into an enamelled-coated bowl for quick solidification. The salt flux obtained was then grinded in a mortar and sifted.
The fraction having a particle size lower than 3150 microns and higher than microns was recovered.
Example 6 (prior art) [0042] Fifty grams of a salt flux were prepared in a small alumina crucible by mixing 10 grams of NaCI in powder form and sold under the trademark SIFTO
INDUSTRIAL, 10 grams of KCI in powder form and sold under the trademark IMC
KALIUM, and 30 grams of MgCl2 in flake form and sold under the trademark SKYLINE. The mixture was subjected to a temperature of 550 C during 45 minutes.
The liquid mixture obtained was then poured into an enamelled-coated bowl for quick solidification. The salt flux obtained was then grinded in a mortar and sifted.
The fraction having a particle size lower than 3150 microns and higher than microns was recovered.
[0043] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid state at 700 C in a graphite crucible. To this alloy, 2 grams , of an aluminum alloy consisting of 90 wt (21/0 of aluminum and 10 wt % of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. The agitation was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the salt flux formed hereinabove were added to the liquid aluminum alloy doped with calcium while agitating for 2 minutes. The agitation was stopped and samples were taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
[0044] The analysis of samples shows a reduction of the Ca level from 108 ppm to 7 ppm after the addition of the salt flux. Thirty minutes later, the calcium level was at 2 ppm and after 60 minutes the calcium level was under 1 ppm. No increase in sodium content was noted during the test. The sodium level was in the order of 2 ppm. This example shows that a ternary flux having a low content in NaCI
does not increase the level of sodium in the alloy.
Exemple 7 [0045] Fifty grams of a salt flux were prepared only by mixing 22.5 grams of NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL with a granulometry 95% lower than 840 microns and 95 A higher than 300 microns, and 27.5 grams of MgC12 in flake form and sold under the trademark SKYLINE with a granulometry 90 % lower than 4.7 mm and 85 % higher to 1 mm.
does not increase the level of sodium in the alloy.
Exemple 7 [0045] Fifty grams of a salt flux were prepared only by mixing 22.5 grams of NaCI in powder form and sold under the trademark SIFTO INDUSTRIAL with a granulometry 95% lower than 840 microns and 95 A higher than 300 microns, and 27.5 grams of MgC12 in flake form and sold under the trademark SKYLINE with a granulometry 90 % lower than 4.7 mm and 85 % higher to 1 mm.
[0046] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid phase at 700 C in a graphite crucible. To this alloy, 2 grams of an aluminum alloy consisting of 90 wt % of aluminum and 10 wt % of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. The agitation was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the salt flux formed hereinabove were added to the liquid aluminum alloy doped with calcium while agitating for 2 minutes. Agitation was stopped and samples were taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
[0047] Analyses of samples have shown a reduction of the Ca level from 77 ppm to 2 ppm after the addition of the salt flux. Thirty minutes later, the calcium level was under 1 ppm. No increase in the sodium content was noted during the test. The sodium level was in the order of 2 ppm.
Example 8 [0048] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid state at 700 C in a graphite crucible. To this alloy, 2 grams of an aluminum alloy consisting of 90 wt % of aluminum and 10 wt % of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. Stirring was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the PROMAG SI (trademark) formed of 40 wt % KCI and 60 wt % MgCl2, with a granulometry 99% lower than 3150 microns and 95 % higher than 850 microns, were added to the alloy doped with calcium while agitating for 2 minutes. The agitation was stopped and samples were later taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
Example 8 [0048] Two kg of AA1100 aluminum alloy (sold under the trademark Alcan) were melted and kept in liquid state at 700 C in a graphite crucible. To this alloy, 2 grams of an aluminum alloy consisting of 90 wt % of aluminum and 10 wt % of calcium (sold under the trademark KB Alloys) were added in a vortex formed with an agitator in the liquid metal, said agitator having straight blades. Stirring was maintained during 2 minutes. A sample of the metal was taken for analysis. Two grams of the PROMAG SI (trademark) formed of 40 wt % KCI and 60 wt % MgCl2, with a granulometry 99% lower than 3150 microns and 95 % higher than 850 microns, were added to the alloy doped with calcium while agitating for 2 minutes. The agitation was stopped and samples were later taken immediately after the end of the agitation as well as 30, 60 and 90 minutes later.
[0049] Analyses of samples have shown a reduction of the Ca level from 75 ppm to 7 ppm after the addition of the salt flux. Thirty minutes later the calcium level was under 5 ppm (see Figure 4). These analyses show that binary fluxes of NaCI and MgC12 are more efficient than a ternary flux of NaCI, KCI and MgC12 or binary flux, KC! and MgCl2.
Ex. 5 Ex. 6 Ex. 7 Ex. 8 Reference NaCI- NaCI-KCI- NaCI- Promag SI* (no flux) MgCl2 MgCl2 MgCl2 (KCI -(45-55) (20-20-60) (45-55) MgC12) Fused Fused Mix (40-60) Time After Ca 115 108 77 75 77 After salt 3 7 2 7 -30 min <1 2 <1 <5 58 60 min <1 <1 <1 <5 -90 min <1 <1 <1 <5 -120min - - - - 39 * trademark [0050] The present invention has been described with respect to its preferred embodiments. The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole. It will be clear to those skilled in the art that numerous variations and modifications can be made to the implementation of the invention without being outside the scope of the invention.
Such variations and modifications are covered by the present invention.
Ex. 5 Ex. 6 Ex. 7 Ex. 8 Reference NaCI- NaCI-KCI- NaCI- Promag SI* (no flux) MgCl2 MgCl2 MgCl2 (KCI -(45-55) (20-20-60) (45-55) MgC12) Fused Fused Mix (40-60) Time After Ca 115 108 77 75 77 After salt 3 7 2 7 -30 min <1 2 <1 <5 58 60 min <1 <1 <1 <5 -90 min <1 <1 <1 <5 -120min - - - - 39 * trademark [0050] The present invention has been described with respect to its preferred embodiments. The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole. It will be clear to those skilled in the art that numerous variations and modifications can be made to the implementation of the invention without being outside the scope of the invention.
Such variations and modifications are covered by the present invention.
Claims (28)
1. Use of a salt flux for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, said metal being in a liquid phase and said salt flux consisting of:
.cndot. a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .cndot. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 %
by weight of MgCl2; or .cndot. a liquid binary mixture of NaCI and MgCl2 wherein more than 22 % by weight of the binary mixture consists of NaCI.
.cndot. a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .cndot. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 %
by weight of MgCl2; or .cndot. a liquid binary mixture of NaCI and MgCl2 wherein more than 22 % by weight of the binary mixture consists of NaCI.
2. Use according to claim 1, wherein the salt flux is a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
3. Use according to claim 1, wherein the salt flux is in the form of particles obtained by grinding a fused salt of NaCI and MgCl2 comprising from 40 to 50 %
by weight of NaCI and from 50 to 60 % by weight of MgCl2.
by weight of NaCI and from 50 to 60 % by weight of MgCl2.
4. Use according to claim 2 or 3, wherein the binary mixture comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of 439°C.
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of 439°C.
5. Use according to any one of claims 2 to 4, wherein the particles have an average particle size comprised between 100 µm and 3.35mm.
6. Use according to any one of claims 2 to 4, wherein the particles have an average particle size comprised between 0.85 mm and 3.15 mm.
7. Use according to any one of claims 2 to 4, wherein the particles have an average particle size comprised between 100 µm and 1 mm.
8. Use according to any one of claims 2 to 7, wherein said particles are contacted with the metal in liquid phase by injection with a gas injection equipment.
9. Use according to claim 1, wherein the salt flux is a liquid binary mixture of NaCI and MgCl2 wherein more than 22 % by weight of the binary mixture consists of NaCI.
10. Use according to claim 9, wherein the liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgCl2.
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgCl2.
11. Use according to claim 10, wherein the liquid binary mixture comprises :
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2.
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2.
12. Use according to any one of claims 1 to 11, wherein the metal is an aluminum alloy having a magnesium content higher than 3 % by weight.
13. Use of a salt flux for the purification of an aluminum alloy having a silicon content higher than 10 % by weight, said aluminum alloy being in a liquid phase and said salt flux consisting of:
.cndot. a binary mixture of particles of NaCI and particles of MgCl2 wherein more than 22% by weight of the binary mixture consists of NaCI; or .cndot. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2; or .cndot. a liquid binary mixture of NaCI and MgCl2.
.cndot. a binary mixture of particles of NaCI and particles of MgCl2 wherein more than 22% by weight of the binary mixture consists of NaCI; or .cndot. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2; or .cndot. a liquid binary mixture of NaCI and MgCl2.
14. Use according to any one of claims 1 to 11, wherein the metal is an aluminum alloy having a silicon content higher than 10 % by weight.
15. A method for the purification of a metal selected from the group consisting of aluminum and aluminum alloys, wherein said method comprises:
.cndot. heating the metal to a liquid phase; and .cndot. contacting the liquid metal with a salt flux consisting of:
.circle. a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .circle. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .circle. a liquid binary mixture of NaCI and MgCl2 wherein more than 22 %
by weight of the binary mixture consists of NaCI.
.cndot. heating the metal to a liquid phase; and .cndot. contacting the liquid metal with a salt flux consisting of:
.circle. a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .circle. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2 comprising from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2; or .circle. a liquid binary mixture of NaCI and MgCl2 wherein more than 22 %
by weight of the binary mixture consists of NaCI.
16. The method according to claim 15, wherein the salt flux is a binary mixture of particles of NaCI and particles of MgCl2, said binary mixture comprising from from 40 to 50 % by weight of NaCI and from 50 to 60 % by weight of MgCl2.
17. The method according to claim 15, wherein said salt flux is in the form of particles obtained by grinding a fused salt of NaCl and MgCl2 comprising from to 50 % by weight of NaCl and from 50 to 60 % by weight of MgCl2.
18. Use according to claim 16 or 17, wherein the binary mixture of particles comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of 439°C.
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of 439°C.
19. The method according to any one of claims 15 to 18, wherein said particles have an average particle size comprised between 100 pm and 3.35mm.
20. The method according to any one of claims 15 to 18, wherein said particles have an average size particle comprised between 0.85 mm and 3.15 mm.
21. The method according to any one of claims 15 to 18, wherein said particles have an average particle size comprised between 100 µm and 1 mm.
22. The method according to any one of claims 15 to 21, wherein said particles are contacted with the liquid metal by injection with a gas injection equipment.
23. The method according to claim 15, wherein said salt flux is a liquid binary mixture of NaCI and MgCl2, and wherein more than 22 % by weight of the liquid binary mixture consists of NaCI.
24. The method according to claim 23, wherein said liquid binary mixture comprises:
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgCl2.
a) from 40 to 50 % by weight of NaCI; and b) from 50 to 60 % by weight of MgCl2.
25. The method according to claim 24, wherein said liquid binary mixture comprises:
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of about 439°C.
a) 45 % by weight of NaCI; and b) 55 % by weight of MgCl2;
to form an eutectic binary mixture having a melting point of about 439°C.
26. The method according to any one of claims 15 to 25, wherein the metal is an aluminum alloy having a magnesium content higher than 3 % by weight.
27. A method for the purification of a metal consisting of an aluminum alloy having a silicon content higher than 10 % by weight, wherein said method comprises:
.cndot. heating the metal to a liquid phase; and .cndot. contacting the liquid metal with a salt flux consisting of:
.circles. a binary mixture of particles of NaCI and particles of MgCl2wherein more than 22% by weight of the binary mixture consists of NaCI; or .circles. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2; or .circles. a liquid binary mixture of NaCI and MgCl2.
.cndot. heating the metal to a liquid phase; and .cndot. contacting the liquid metal with a salt flux consisting of:
.circles. a binary mixture of particles of NaCI and particles of MgCl2wherein more than 22% by weight of the binary mixture consists of NaCI; or .circles. a binary mixture of particles obtained by grinding a fused salt of NaCI and MgCl2; or .circles. a liquid binary mixture of NaCI and MgCl2.
28. The method according to any one of claims 15 to 25, wherein the metal is an aluminum alloy having a silicon content higher than 10 % by weight.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2668473A CA2668473C (en) | 2009-06-08 | 2009-06-08 | Use of a binary salt flux of nacl and mgcl2 for the purification of aluminum or aluminum alloys, and method thereof |
| PCT/CA2010/000866 WO2010142025A1 (en) | 2009-06-08 | 2010-06-08 | USE OF A BINARY SALT FLUX OF NaCl AND MgCI2 FOR THE PURIFICATION OF ALUMINUM OR ALUMINUM ALLOYS, AND METHOD THEREOF |
| JP2012514304A JP2012529565A (en) | 2009-06-08 | 2010-06-08 | Use of NaCl and MgCl2 binary salt fluxes for the purification of aluminum or aluminum alloys and methods thereof |
| AU2010258042A AU2010258042B2 (en) | 2009-06-08 | 2010-06-08 | Use of a binary salt flux of NaCl and MgCl2 for the purification of aluminum or aluminum alloys, and method thereof |
| CN201080025076XA CN102459663A (en) | 2009-06-08 | 2010-06-08 | Use of a binary salt flux of nacl and mgci2 for the purification of aluminum or aluminum alloys, and method thereof |
| BRPI1015440A BRPI1015440A2 (en) | 2009-06-08 | 2010-06-08 | "use of a nacl and mgcl2 binary salt flux for the purification of aluminum and aluminum alloys and their relationship" |
| ES10785623T ES2862528T3 (en) | 2009-06-08 | 2010-06-08 | Use of a binary saline flux of NaCl and MgCl2 for the purification of aluminum or aluminum alloys, and method of the same |
| EP10785623.9A EP2446065B2 (en) | 2009-06-08 | 2010-06-08 | USE OF A BINARY SALT FLUX OF NaCl AND MgCI2 FOR THE PURIFICATION OF ALUMINUM OR ALUMINUM ALLOYS, AND METHOD THEREOF |
| RU2011147513/02A RU2011147513A (en) | 2009-06-08 | 2010-06-08 | APPLICATION OF A BINARY SALT FLUX CONTAINING NaCl AND MgCl2 FOR CLEANING ALUMINUM OR ALUMINUM ALLOYS AND CLEANING METHOD |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2668473A CA2668473C (en) | 2009-06-08 | 2009-06-08 | Use of a binary salt flux of nacl and mgcl2 for the purification of aluminum or aluminum alloys, and method thereof |
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| Publication Number | Publication Date |
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| CA2668473A1 CA2668473A1 (en) | 2010-12-08 |
| CA2668473C true CA2668473C (en) | 2014-08-19 |
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Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2446065B2 (en) |
| JP (1) | JP2012529565A (en) |
| CN (1) | CN102459663A (en) |
| AU (1) | AU2010258042B2 (en) |
| BR (1) | BRPI1015440A2 (en) |
| CA (1) | CA2668473C (en) |
| ES (1) | ES2862528T3 (en) |
| RU (1) | RU2011147513A (en) |
| WO (1) | WO2010142025A1 (en) |
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| WO2013013321A1 (en) * | 2011-07-28 | 2013-01-31 | Pyrotek Inc. | Use of a tertiary salt flux of nac1, kcl, and mgc12 for the purification of aluminum or aluminum alloys, and method thereof |
| CN104862496A (en) * | 2015-05-13 | 2015-08-26 | 上海交通大学 | Melt composite treatment agent for segregation method refined aluminium purification and preparation method thereof |
| CN104831079B (en) * | 2015-05-13 | 2016-08-31 | 上海交通大学 | Segregation method refined aluminium effectively removes the method for vanadium in purifying |
| CN105177311A (en) * | 2015-09-15 | 2015-12-23 | 沈阳航空航天大学 | Sodium-chloride-salt-containing fusion used for aluminum melt treatment and production method of sodium-chloride-salt-containing fusion |
| CN105177335B (en) * | 2015-09-15 | 2017-03-22 | 沈阳航空航天大学 | Alloy element additive used for aluminum alloy production and preparation method thereof |
| IT201700074924A1 (en) * | 2017-07-04 | 2019-01-04 | Foundry Ecocer S R L | Flux for melting the molten metal. |
| CA3031491C (en) * | 2019-01-03 | 2020-03-24 | 2498890 Ontario Inc. | Systems, methods, and cored wires for treating a molten metal |
| CN115198106B (en) * | 2022-07-08 | 2023-08-29 | 中国铝业股份有限公司 | Aluminum extraction refining agent for aluminum ash and preparation method and use method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US1377374A (en) | 1918-07-24 | 1921-05-10 | Dow Chemical Co | Manganese-magnesium alloy and method of making same |
| US1476192A (en) * | 1921-11-26 | 1923-12-04 | Dow Chemical Co | Method of casting light metal alloys |
| US1519128A (en) | 1923-07-09 | 1924-12-16 | Dow Chemical Co | Flux for magnesium and alloys thereof |
| US1754788A (en) | 1923-07-13 | 1930-04-15 | Dow Chemical Co | Purifying light-metal alloys |
| US2262105A (en) | 1939-11-20 | 1941-11-11 | Magnesium Elektron Ltd | Flux for use in the treatment of light metal |
| FR2325727A1 (en) | 1975-09-26 | 1977-04-22 | Servimetal | FLOWS FOR THE REMOVAL OF ALKALINE AND ALKALINO-EARTH METALS FROM ALUMINUM AND ITS ALLOYS AND PROCESSING METHODS |
| CH599979A5 (en) † | 1976-12-21 | 1978-06-15 | Alusuisse | |
| JPS5336965Y2 (en) * | 1977-10-04 | 1978-09-08 | ||
| GB8322020D0 (en) * | 1983-08-16 | 1983-09-21 | Alcan Int Ltd | Filtering molten metal |
| DE3472973D1 (en) * | 1983-08-16 | 1988-09-01 | Alcan Int Ltd | Method of filtering molten metal |
| CN86105578A (en) * | 1986-07-19 | 1988-02-24 | 江苏工学院 | Refining modification fluxing agent |
| JP2927476B2 (en) * | 1989-12-29 | 1999-07-28 | 株式会社ショーワ | Flux supply device |
| CN1026709C (en) * | 1991-12-16 | 1994-11-23 | 东北工学院 | Slag remover for refining Al or Al alloy |
| US5405427A (en) | 1994-05-18 | 1995-04-11 | Eckert; C. Edward | Salt flux for addition to molten metal adapted for removing constituents therefrom and methods of using |
| US5427602A (en) * | 1994-08-08 | 1995-06-27 | Aluminum Company Of America | Removal of suspended particles from molten metal |
| CN1195084C (en) * | 2001-12-27 | 2005-03-30 | 上海交通大学 | Filtering process of eliminating non-metallic foreign impurity ion aluminium melt |
| JP2007528443A (en) * | 2003-11-19 | 2007-10-11 | コラス、テクノロジー、ベスローテン、フェンノートシャップ | Method for cooling molten metal during fractional crystallization |
| JP4584682B2 (en) * | 2004-11-12 | 2010-11-24 | ヤマハ発動機株式会社 | Method for removing oxide from casting aluminum alloy |
-
2009
- 2009-06-08 CA CA2668473A patent/CA2668473C/en active Active
-
2010
- 2010-06-08 ES ES10785623T patent/ES2862528T3/en active Active
- 2010-06-08 WO PCT/CA2010/000866 patent/WO2010142025A1/en active Application Filing
- 2010-06-08 RU RU2011147513/02A patent/RU2011147513A/en not_active Application Discontinuation
- 2010-06-08 AU AU2010258042A patent/AU2010258042B2/en active Active
- 2010-06-08 BR BRPI1015440A patent/BRPI1015440A2/en not_active IP Right Cessation
- 2010-06-08 EP EP10785623.9A patent/EP2446065B2/en active Active
- 2010-06-08 JP JP2012514304A patent/JP2012529565A/en active Pending
- 2010-06-08 CN CN201080025076XA patent/CN102459663A/en active Pending
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|---|---|
| AU2010258042B2 (en) | 2014-01-23 |
| JP2012529565A (en) | 2012-11-22 |
| EP2446065A4 (en) | 2017-03-15 |
| CA2668473A1 (en) | 2010-12-08 |
| AU2010258042A1 (en) | 2011-12-22 |
| EP2446065B2 (en) | 2024-02-21 |
| EP2446065B1 (en) | 2020-12-16 |
| WO2010142025A1 (en) | 2010-12-16 |
| ES2862528T3 (en) | 2021-10-07 |
| RU2011147513A (en) | 2013-07-20 |
| CN102459663A (en) | 2012-05-16 |
| EP2446065A1 (en) | 2012-05-02 |
| BRPI1015440A2 (en) | 2018-07-17 |
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