CA2661801C - Monofilaments with split ends - Google Patents

Monofilaments with split ends Download PDF

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Publication number
CA2661801C
CA2661801C CA2661801A CA2661801A CA2661801C CA 2661801 C CA2661801 C CA 2661801C CA 2661801 A CA2661801 A CA 2661801A CA 2661801 A CA2661801 A CA 2661801A CA 2661801 C CA2661801 C CA 2661801C
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CA
Canada
Prior art keywords
monofilaments
monofilament
voids
bristles
bristle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA2661801A
Other languages
French (fr)
Other versions
CA2661801A1 (en
Inventor
Robert L. Rackley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to CA2661801A priority Critical patent/CA2661801C/en
Priority claimed from CA002560512A external-priority patent/CA2560512C/en
Publication of CA2661801A1 publication Critical patent/CA2661801A1/en
Application granted granted Critical
Publication of CA2661801C publication Critical patent/CA2661801C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0292Bristles having split ends
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • D01D5/247Discontinuous hollow structure or microporous structure
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Brushes (AREA)

Abstract

Monofilaments with split ends. The monofilaments can be used to form toothbrush bristles having flagged or feathered tips. Each of the monofilaments has a plurality of internal fusion lines and at least four voids, wherein the voids comprise between 5 and 20 % of the cross-sectional area of the monofilaments. Preferably, the monofilaments each have a diameter in a range of 0.0025 to 0.012 inches, and have a hexalocular or an octalocular configuration. The monofilaments are manufactured by extruding a plurality of thermoplastic polymeric streams, rotating a plurality of cutting blades above 1000 rpm, and placing a plurality of cutting blades in contact with end portions of the plurality of thermoplastic polymeric streams to form split ends.

Description

BACKGROUND OF THE INVFNTTON
1. Field of the Invention This invention relates generally to monofilaments, and cnore particularly to monofilaments having split ends, which may be used for example as toothbrush bristles.
2. Description of the Related Art Thermoplastic polymers have long been used to form brush bristles in a wide variety of configurations. To increase the effectiveness of these brushes, the ends of such bristles have been split or "feathered" to provide a soft bristle tip. In the past, however, various difficulties have been encountered in splitting bristle tips.
In particular, various techniques have been used to split paintbrush bristles to improve painting performance. Such procedures have been particularly suited to paintbrush bristles because long splits which propagate along a large portion (up to one inch) are particularly desirable. With certain brushes, however, only splitting of the tips is desirable. For example, the length of a typical toothbrush bristle is about (or less than) one half inch. If splitting were to occur along a large portion of a toothbrush bristle, the bristles would not be sufficiently rigid to adequately clean teeth. Accordingly, currently available splitting techniques fail to adequately address difficulties associated with splitting the tips of toothbrush bristles and other bristles in which long splits are undesirable.

SLT1bIIVIARY OF THE INVBNTION
This invention relates to a monofilament having a portion with a plurality of internal fusion lines and at least four voids, wherein the voids comprise between 5 and 20% of the cross-sectional area of the monofilament.
This invention also relates to a monofilament having a .2-diameter in a range of 0.0025 to 0.012 inches, wherein the monofilament has a hexalocular, an octalocular, or a near circular shape.
In addition, this invention relates to a method of manufacturing extruded monofilaments having split ends, including the steps of extruding a plurality of thennoplastic polymeric streams to form a plurality of monofilaments, spinning a plurality of cutting blades above 1000 rpm, and placing a plurality of cutting blades in contact with end portions of the monofilaments to form split ends. In one embodiment of the present invention, the blades are spun at or near the natural frequency of the monofilaments.

BRIEF DFSCRIPTION OF THE DRAWINGS
Fig. la is a cross-sectional view of a hexalocular monofilament of the present invention.
Fig. lb is a cross-sectional view of a spinnerette capillary used to extrude the monofilament of Fig la.
Fig. 2a is a cross-sectional view of another hexalocular monofilament of the present invention.
Fig. 2b is a cross-sectional view of a spinnerette capillary used to extnide the monofilament of Fig 2a.
Fig. 3a is a cross-sectional view of another hexalocular monofilament of the present invention.
Fig. 3b is a cross-sectional view of a spinnerette capillary used to extrude the monofilament of Fig 3a.
Fig. 4a is a cross-sectional view of another hexalocular monofilament of the present invention.
Fig. 4b is a cross-sectional view of a spinnerette capillary used to =
extrude the monofilament of Fig 4a.
Fig. 5a is a cross-sectional view of another hexalocular monofilament of the present invention.
Fig. 5b is a cross-sectional view of a spinnerette capillary used to extrude the monofilament of Fig 5a.
Fig. 6a is a front view of a spinnerette having a plurality of spinnerette capillary locations.
Fig. 6b is a side view of the spinnerette of Fig. 6a.
Fig. 7a is a plan view of a blade used in manufacturing a monofilament having split ends.
Fig. 7b is a front view of a structure having three blades mounted on a common shaft for use in splitting the ends of the monofilaments of the present invention.
Fig. 7c is a side view of the structure of Figure 7b.
Fig. 8 is a graph of the natural frequency for a 612 monofilament with a 550,000 psi modulus and various lengths and diameters.
Fig. 9 is a perspective view of a toothbrush having a plurality of feathered bristles.
Fig. 10 is a side view of a plurality of bristles with split ends that produce a plurality of soft fine tips.
Fig. 11 is a side view of a comparison of a feathered toothbrush bristle which spreads-out on a tooth surface with an ordinary solid tip which provides only a single contact point.
Fig. 12 is a view of feathered toothbrush bristles which penetrate deeper at the gum line for better cleaning without hurting the gum of a patient.
Fig. 13 is a cross-sectional view of an octalocular monofilament in accordance with the present invention.

DETAILED DESCRIPTTON OF THE PREFERRED EMBODIMENTS
OF THE PRESENT nfNENZTON

Which reference to the drawings, several embodiments of the present invention, and their corresponding method of manufacture, will now be described = in greater detail. Which reference to Figs. la, 2a, 3a, 4a and 5a, examples of a monofilament having a hexalocular shape are shown. Such shapes were achieved through an extrusion procEss using the respeCtive spinnerette capillarirs of Figs.
lb, 2b, 3b, 4b and 5b. Such monofilaments were pnepared by the fusion of six polymer streams. Each of these monofilamcnu 10 include a plurality of voids 20 and a plurality of weld or fusion lines. The voids result in a void content of between 5 and 20% of the cross-sexbonal area of the monofilaments. The brush bristle of the present invention can be prepared from a wide variety of thermoplastic polymeric materials ineluding polyamides, polyesters and polyolefins.
Polyamides for use in brush manufacturing including nylon 6,6.
nylon 610 (pofyhexaatethylene sebaccamide), and nylon 612 (hexamethylene, diamine). Polycsters which have been found particularly well suited to bristle manufacture include polybutylene tcrephthalate and polyethylene terephthalate.
A
polyolefin which has been found particularly well-suited to bristle manufacture is polypropylene.
The overall diameter, or overall maximum cross-soctional dimension, of the brush bristles of the present invention is in the range of 0.0025 to 0.012 inches (0.064 to 0.3 mm).
The bristles of the present invention are preferably formed by extruding six or more individual streams of polymeric material from a spinnerette including the spinnerette capillaries shown in Figs lb, 2b, 3b, 4b, and Sb, and joining the streams to form a single filament. A spinnerette, such as the one shown in Figures 6a and 6b, includes a plurality of spinnerette capillaries.
With reference to FIgs. lb, 2b, 3b, and Sb, in the extrusion of the thermoplastic polymer streams, the polymer is extruded through openings 40. The fusion of the sareams results in fusion lines at the interface of the individual streams, and the formation of longitudinal voids along the fusion lines. The general configuration of the voids can vary widely.
After extrusion of the thermoplastic polymer streams at elevated temperatuYes into a single filament, the monofilament is quenched and then drawn as gcnerally described, for example, in U.S. Pat. No. 2,418,492.
= . M

After cxVusion and quenching of tho monofilament, the fil atnent is orientod by stnetching to improve the longitudiaal strength. In addidon, the filament can be subjected to othar treatments to improve pbysieal pnoperties, such S as treatment wlth saturated steam as describod in U.S. patent No. 3,595,952,-=
The filament may be heat set after drawing for good bend recovay.
Tha heat setting can be carried out either In a gas such as by blowing hot air o+rcr the filament, or a liquid bath such as by passing the ftFament through a bath of oil.
The filaments are then cut into Iengths suitable for brush manufacture. The individual bristles are then gathered into bundles, the bundles are tufted into brushes, and ehe brushes are tipped and flagged by a procedore descn-bad below.
With referiance to Fig. 7a, a plan view of a euttiag blade for use in sp}itting the ends of the bristle of the present invention is shoa+n, An arrangement of three such blades which are separated by spacers on a common shaft by about 3/16 of an Inch and wluch are approxirnately rotated from one another by 120 degrer.s Is shown in Figs. 7b and 7c. It has been found that by rotating such a blada above 1000 rpm and placing such a blade in contdet with the bristks otch:eves a fine feathering (sptitting), effect. In one example of the present invention, the blades are rotatcd at 30,000 rpm with a router motor. The interference between the bristle and the blade Is varied depending on the depth of the sp}it desired, although it has been found that 1/8 to 1/4 of an inch is preferable.
Essentially,.by spinning the blades at a high rate of speed and placing the b]ades in con4ct with the bristle tips, a fast and violcnt bristle cutting action Is achieved, thereby causing optimal bristle splitting.
It bas also been found that by rotating the blades at or near the naturat f tequency of a tnonofilament wiU obtain optimal splltting of the bristles.
'T'he natural frequency of a uniform beam is Na tura.I FxeqUency A ~r u~

where A=3.52 for a cantilever beam;
d4 I=area moment of inertia = ~ 64 5 E is Young's Modulus of Elasticity; is mass per unit length; and 1= length.
The natural frequency is usually stated in radians per second which can also be expressed in revolutions per minute by dividing by 2z- and multiplying by 60 seconds per minute.
With reference to Fig. 8, a graph of the natural frequency for a 612 monofilament bristle with a 550,000 psi modulus and various lengths and diameters is shown.
The monofilament bristles of the present invention produce a larger number of smaller ends ("flags") than previously known monofilament bristles of the same diameter. The bristles exhibit excellent durability and cleanability, and are particularly useful as toothbrush bristles to produce remarkably soft, fine tips.
By using such a technique, the bristles of the present invention are split rather than end rounded to give a plurality of smaller ends that scrub the gingival area more effectively. It has also be found that the more dense area achieved by such flagged ends scrub major tooth areas better by keeping toothpaste in contact with the tooth surface as well as achieving a softer feel when contact is made with soft tissue in the mouth.
With reference to Fig. 9, a perspective view of a toothbrush having a plurality of feathered bristles is shown. With reference to Fig. 10, a plurality of bristles with split ends that produce a plurality of soft fine tips is also shown.
These feathered filaments spread-out on tooth surfaces to provide a plurality of contact points, unlike ordinary solid tips which provide only one contact point. A
comparison of these plurality of contact points to the single contact point of a solid tip is shown in Fig. 11. The fine feathered filaments of the present invention also produce a greater and deeper penetration at the gum line for better cleaning without hurting the gum line of a patient. Such deeper penetration at the gum line is shown in Fig. 12. Accordingly, these soft filament tips carry sweeping power action along with a beneficial interdental and gumline cleaning. In fact, it has been found that such feathered tips reach farther between teeth, provide better cleaning coverage than ordinary soft filament tips because of the increase in contact surfaces, and thus holds toothpaste in contact with teeth. Such an arrangement also provides a unique cushioning effect at the tips which adds extra softness to the brush. Such softness reduces bleeding of the gums during brushing. Moreover, such bristles have proven to be as hygienic as round filaments.
Although the present invention has been described with reference to a hexalocular bristle structure having six voids, it has also been found that an octalocular bristle structure (having eight voids) provides numerous beneficial effects. Such an octalocular bristle is shown in Figure 13. It is also to be understood that although six and eight streams have been used to achieve hexalocular and octalocular structures, respectively, a greater number of streams may be used to produce additional structures having a corresponding greater number of voids. The outer shape of such hexalocular, octalocular or other structures may be manufactured so as to have a circular or near circular shape.
Such a near circular outer shape is shown in Figure 13.
The percentage of the cross-sectional area occupied by the voids in the monofilaments is determined by the size, location, symmetry and shape of the voids. It has been found that a certain level of hollow space (voids) will result in an optimal splitting of brushes having relatively short lengths, such as toothbrushes. The voids optimally result in a void content of between 5 and 20%
of the cross-sectional area of the monofilaments. With such brushes, if the voids are too small, such as the voids disclosed in U.S. Patent No. 5,128,208, any feathering effect would result in broken bristle ends rather than in achieving feathering. If the voids are too large, such as the voids disclosed in U.S.
Patent No. 4,279,053, the bristle would feather easily, but the splits would likely propagate down the bristle during use. With use as a toothbrush bristle, it is important that the tips of the bristles be split without the split propagating down the filament, either during manufacture or use by a patient. This may also be true of other types of brushes, depending on the particular use of the brush and/or length of the bristles.
With regard to the location of the voids within the monofilament, the voids should be located about 1/2 way between the center and the outside edge.
It has also been found that a longer and slender void achieves a greater flagging effect than a rounded void.
It is also to be noted that the voids may be either symmetrical or asymmetrical, although it is to be noted that an asymmetrical void may have a natural curvature which is often undesirable in particular uses, such as a toothbrush. Preferably, openings 40 of the spinnerette capilaries, as shown in Figs. lb, 2b, 3b, have a radius of curvature r in the range of 5 to 12 mils.
Openings 40 of the spinnerette capillary of Fig. 2b have an internal radius (or radius of curvature) of 9 mils, while the openings of the spinnerette capillary of Fig. 3b have a radius of 8 mils. Interestingly, use of the spinnerette capillary of Figure 2b results in the asymmetrical monofilament of Fig. 2a, while use of the spinnerette capillary of Fig. 3b results in the symmetrical monofilament of Fig. 3a.
It is important to note that the asymmetrical monofilament of Fig. 2a is not due to problems in the symmetry of the design, but with the large size of the lobes.
With large lobes, the streams are not knitted together as the center is pulled. As such, insufficient space is left for two of the streams to be pulled into the monofilament.

The void content is determined on the basis of the weight of the hollow bri stle and the weight of a hypothetical solid bristle of the same exterior configuration, according to the following formula:

t Void Content = 10 0 t1_ we.ight of hollow bristlel weight of solid bristle Although the present invention has been described in terms of certain pr+efcrred esnbodirnents, other embodiments that are apparent to those of ordinary sk.ill in the art are also intended to be within the scope of the present invention.
pCCondingly, the scope of the present invention is ipcettded to be limited only by the claims appended theroto, t5

Claims (3)

1. A brush monofilament having a portion with a plurality of internal fusion lines and at least four voids, wherein said voids occupy between 5 and 20% of a cross-sectional area of the monofilament, said brush monofilament having a hexalocular, or an octalocular shape.
2. The brush monofilament of claim 1 wherein said brush monofilament is a toothbrush bristle.
3. The brush monofilament of claim I or 2 wherein said brush monofilament comprises thermoplastic polymeric material that is nylon 610, nylon 612, a polyamide, or polybutylene terephthalate.
CA2661801A 1997-04-24 1997-04-24 Monofilaments with split ends Expired - Lifetime CA2661801C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2661801A CA2661801C (en) 1997-04-24 1997-04-24 Monofilaments with split ends

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2661801A CA2661801C (en) 1997-04-24 1997-04-24 Monofilaments with split ends
CA002560512A CA2560512C (en) 1997-04-24 1997-04-24 Monofilaments with split ends

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CA002560512A Division CA2560512C (en) 1997-04-24 1997-04-24 Monofilaments with split ends

Publications (2)

Publication Number Publication Date
CA2661801A1 CA2661801A1 (en) 1998-10-29
CA2661801C true CA2661801C (en) 2012-01-24

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016058083A1 (en) * 2014-10-13 2016-04-21 Tarkett Inc. Tubular monofilament fiber

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Publication number Publication date
CA2661801A1 (en) 1998-10-29

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