CA2660990A1 - Biomass hydrothermal decomposition apparatus, method thereof, and organic material production system using biomass material - Google Patents

Biomass hydrothermal decomposition apparatus, method thereof, and organic material production system using biomass material

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Publication number
CA2660990A1
CA2660990A1 CA 2660990 CA2660990A CA2660990A1 CA 2660990 A1 CA2660990 A1 CA 2660990A1 CA 2660990 CA2660990 CA 2660990 CA 2660990 A CA2660990 A CA 2660990A CA 2660990 A1 CA2660990 A1 CA 2660990A1
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Prior art keywords
biomass
hydrothermal decomposition
main body
biomass material
fed
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CA 2660990
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French (fr)
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CA2660990C (en )
Inventor
Isao Ishida
Seiichi Terakura
Hideo Suzuki
Seiji Kobayashi
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Mitsubishi Heavy Industries Mechatronics Systems Ltd
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Mitsubishi Heavy Industries Ltd
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/09Means for pre-treatment of biological substances by enzymatic treatment
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/12Bioreactors or fermenters specially adapted for specific uses for producing fuels or solvents
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M27/00Means for mixing, agitating or circulating fluids in the vessel
    • C12M27/02Stirrer or mobile mixing elements
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/14Pressurized fluid
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/12Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/30Means for regulation, monitoring, measurement or control, e.g. flow regulation of concentration
    • C12M41/36Means for regulation, monitoring, measurement or control, e.g. flow regulation of concentration of biomass, e.g. colony counters or by turbidity measurements
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/02Means for pre-treatment of biological substances by mechanical forces; Stirring; Trituration; Comminuting
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/04Phase separators; Separation of non fermentable material; Fractionation

Abstract

A biomass hydrothermal decomposition apparatus includes, a biomass feeder (31) that feeds biomass material (11) under normal pressure to under increased pressure, a hydrothermal decomposition device (42A) that allows the fed biomass material (11) to be gradually moved inside a device main body (42A) from either end thereof in a consolidated condition, and also allows hot compressed water (15) to be fed from an other end of a feed section for the biomass material into the main body (42A), so as to cause the biomass material (11) and the hot compressed water (15) to countercurrently contact with each other and undergo hydrothermal decomposition, and that elutes a lignin component and a hemicellulose component into the hot compressed water, so as to separate the lignin component and the hemicellulose component from the biomass material (11); and a biomass discharger (51) that discharges, from the side where the hot compressed water is fed into the device main body, a biomass solid residue (17) under increased pressure to under normal pressure.

Description

`.:

DESCRIPTION
BIOMASS HYDROTHERMAL DECOMPOSITION APPARATUS, METHOD
THEREOF, AND ORGANIC MATERIAL PRODUCTION SYSTEM USING

BIOMASS MATERIAL
TECHNICAL FIELD
[0001] The present invention relates to a biomass hydrothermal decomposition apparatus and a method thereof that enable efficient hydrothermal decomposition of biomass material, and to an organic material production system using biomass material, which system enables efficient production of organic materials such as alcohols, substitutes for petroleum, or amino acids by using such apparatus and method.

BACKGROUND ART

[0002] Technologies for producing ethanol or the like have been commercialized that involve converting woody biomass or other biomass into sugars with dilute sulfuric acid or concentrated sulfuric acid, and then subjecting them to solid-liquid separation, neutralizing the liquid phase thereof, and utilizing the resultant components as biomass materials for ethanol fermentation or the like (Patent Documents 1 and 2). Further, by using sugar as starting material, production of chemical industrial raw material (e.g., lactic fermentation) has been considered.
Biomass as used herein refers to a living organism integrated in material circulation in the global biosphere or accumulation of organic materials derived from living organisms (see JIS K 3600 1258).

[0003] Sugarcane, corn, and other materials, currently used as alcohol raw materials, have been originally used for food. Using such food resources as long-term stable industrial resources is not preferable in view of life cycle of valuable food.

[0004] For this reason, it is a challenge to efficiently use cellulose resources such as herbaceous biomass and woody biomass, which are considered as potentially useful resources.

[0005] Cellulose resources include cellulose ranging from 38% to 50%, hemicelluloses components ranging from 23%
to 32%, and lignin components, which are not used as fermentation materials, ranging from 15% to 22%. Due to many challenges, the industrial studies have been conducted targeting certain fixed materials, and no technologies have been disclosed yet on production systems taking into account diversity of the materials.

[0006] Production systems targeting fixed materials see almost no point regarding countermeasures for waste problems and global warming, because those systems have attempted such countermeasures with a method that brings more disadvantages to fermentation materials than starch materials. Thus, there has been a need for a method applicable to a variety of wastes in broader sense.
Enzymatic saccharification methods are also considered as a future challenge due to its low efficiency. Acid treatment only achieves a low saccharification rate of about 75% (a basis for components that can be saccharified), due to excessive decomposition of sugar. Thus, the ethanol yield achieves only 25% by weight of cellulose resources (Non-Patent Document 1 and Patent Document 3).

[0007] [Patent Document 1] Japanese Patent Application Laid-open No. 9-507386 [Patent Document 2] Japanese Patent Application Laid-open No. 11-506934 [Patent Document 3] Japanese Patent Application Laid-open No. 2005-168335 [Non-Patent Document 1] Nikkei Biotechnology & Business, p.
52, September 2002 [Non-Patent Document 2] Biomass-Extensive Use of Bioresources, edited by Japanese Society for Bioscience, Biotechnology, and Agrochemistry, Asakura Publishing Co., Ltd., September 1985 DISCLOSURE OF INVENTION
PROBLEM TO BE SOLVED BY THE INVENTION

[0008] In the proposals disclosed in Patent Documents 1 and 2 above, sulfuric acid necessary for reaction needs to be constantly supplied from outside the reaction system.
With increasing the production scale, this poses problems, such as increasing the cost for purchasing equipment resistant to the acid and large amounts of sulfuric acid, while increasing the cost for disposing used sulfuric acid (e.g., cost for processing with a gypsum desulfulation), and the cost for recovering such sulfuric acid.

[0009] The proposal disclosed in Patent Document 3 above involves subjecting various types of cellulose resources to hydrothermal treatment, and converting them into sugars with enzymatic saccharification. During the hydrothermal treatment, cellulase inhibitors such as lignin components (Non-Patent Document 2) that inhibit enzymatic saccharification of cellulose are not removed and mixed with cellulose. This poses a problem of reducing the efficiency in cellulose enzymatic saccharification.

[0010] Other than cellulose, hemicellulose components are also contained in cellulose resources. This poses a problem that enzymes r^sre^t=T=^'y suitable for cellulose and hemicellulose components are necessary for enzymatic saccharification.

[0011] The resulting sugar solution includes a hexose solution from cellulose, and a pentose solution from hemicellulose components. For example, for alcohol fermentation, yeasts suitable for the respective solutions are necessary. Thus, alcohol fermentation needs to be improved low efficiency for fermenting a mixture of a hexose solution and a pentose solution.

[0012] As such, conventional technologies have caused a phenomenon that side reaction products inhibit enzymatic saccharification, reducing the sugar yield. Thus, what has been needed is a hydrothermal decomposition apparatus that removes inhibitors for enzymatic saccharification and thereby improves enzymatic saccharification of cellulose-based components.

[0013] In view of the foregoing problems, the present invention has an object to provide: a biomass hydrothermal decomposition apparatus and a method thereof that enable separation of cellulose-based components from biomass material; and an organic material production system using biomass material, which can efficiently produce a sugar solution using such apparatus and method, and can efficiently produce various types of organic materials (e.g., alcohols, substitutes for petroleum, or amino acids) using the sugar solution as a base material.

MEANS FOR SOLVING PROBLEM

[0014] To achieve the above object, according to the first invention, a biomass hydrothermal decomposition apparatus includes a biomass feeder that feeds biomass material under normal pressure to under increased pressure, a hydrothermal decomposition device that allows the fed biomass material to be gradually moved inside a device main body from either end thereof in a consolidated condition, and also allows hot compressed water to be fed from an other end of a feed section for the biomass material into the main body, so as to cause the biomass material and the hot compressed water to countercurrently contact with each other and undergo hydrothermal decomposition, and that elutes a lignin component and a hemicellulose component into the hot compressed water, so as to separate the lignin component and the hemicellulose component from the biomass material; and a biomass discharger that discharges, from the side where the hot compressed water is fed into the device main body, a biomass solid residue under increased pressure to under normal pressure.

[0015] According to the second invention, the biomass hydrothermal decomposition apparatus according to the first invention, further include a fixed stirring unit or a rotating stirring unit that stirs the biomass material inside the device main body.

[0016] According to the third invention, in the biomass hydrothermal decomposition apparatus according to the first invention or the second invention, the biomass feeder is a pressing unit that presses the biomass.

[0017] According to the fourth invention, the biomass hydrothermal decomposition apparatus according to any one of the first to third inventions, further include an excess water drain line through which excess water is drained from pulverized biomass to be fed into the device main body.

[0018] According to the fifth invention, the biomass hydrothermal decomposition apparatus according to any one of the first to fourth inventions, further includes a plurality of feed sections through which the hot compressed water is fed into the device main body, and a plurality of discharge sections through which hot water is discharged from the device main body.

[0019] According to the sixth invention, the biomass hydrothermal decomposition apparatus according to any one of the first to fifth inventions, further includes a filter section that filtrates the hot water to be discharged from the device main body.

[0020] According to the seventh invention, the biomass hydrothermal decomposition apparatus according to any one of the first to sixth inventions, further includes a density monitoring unit that monitors a biomass solid residue content inside the device main body.

[0021] According to the eighth invention, in the biomass hydrothermal decomposition apparatus according to the second invention, the rotating stirring unit includes a scraper that prevents occlusion of an outlet for discharged hot water.

[0022] According to the ninth invention, in the biomass hydrothermal decomposition apparatus according to any one of the first to eighth inventions, the hydrothermal decomposition device has a reaction temperature ranging from 180 C to 240 C and has a condition of hot compressed water.

[0023] According to the tenth invention, in the biomass hydrothermal decomposition apparatus according to any one of the first to ninth inventions, a weight ratio of the fed biomass material and the fed hot compressed water is within 1:1 to 1:10.

[0024] According to the eleventh invention, a method for biomass hydrothermal decomposition includes feeding biomass material under normal pressure to under increased pressure, allowing the fed biomass material to be gradually moved inside a device main body from either end thereof in a consolidated condition and allowing hot compressed water to be fed from an other end of a feed section for the biomass material into the main body, so as to cause the biomass material and the hot compressed water to countercurrently contact with each other and undergo hydrothermal decomposition, eluting a lignin component and a hemicellulose component into the hot compressed water, so as to separate the lignin component and the hemicellulose component from the biomass material, and discharging, from the side where the hot compressed water is fed into the device main body, a biomass solid residue under increased pressure to under normal pressure.

[0025] According to the twelfth invention, an organic material production system using biomass material includes a pretreatment device that pretreats the biomass material, the hydrothermal decomposition apparatus according to any one of the first to tenth inventions, a first enzymatic hydrolysis device that treats, with an enzyme, cellulose in a biomass solid residue discharged from the hydrothermal decomposition device, so as to enzymatically hydrolyze the cellulose to a sugar solution containing hexose; and a fermenter that produces, using the sugar solution obtained by the first enzymatic hydrolysis device, any one of alcohols, substitutes for petroleum, or amino acids by fermentation.

[0026] According to the thirtieth invention, the organic material production system using biomass material according to the twelfth invention, includes a second enzymatic hydrolysis device that treats, with an enzyme, a hemicellulose component in discharged hot water, so as to enzymatically hydrolyze the hemicellulose component to a sugar solution containing pentose, and a fermenter that produces, using the sugar solution obtained by the second enzymatic hydrolysis device, any one of alcohols, substitutes for petroleum, or amino acids by fermentation.
EFFECT OF THE INVENTION

[0027] According to the present invention, with use of a hydrothermal decomposition apparatus that causes biomass material and hot compressed water to countercurrently contact with each other in a consolidated condition, side reaction products (lignin components and hemicellulose components) resulting from the reaction for producing a target component, i.e., cellulose, (that is enzymatically saccharified to a hexose solution) are transferred into the hot compressed water. In this way, the cellulose-based biomass solid residue can be obtained. Accordingly, by efficiently saccharifying it to the hexose solution and using the sugar solution as a substrate material, various types of organic materials (e.g., alcohols, substitutes for petroleum, or amino acids) can be produced efficiently.

[0028] By causing biomass material and hot compressed water to countercurrently contact with each other, their components are sequentially discharged to the outside the reaction system in order of solubility in the hot water.
Further, due to the temperature gradient from a portion where the biomass is fed to a portion where the hot water is fed, excessive decomposition of hemicellulose components is prevented. As a result, pentose components can be recovered efficiently.

BRIEF DESCRIPTION OF DRAWINGS

[0029] [Fig. 1] Fig. 1 is a schematic of a hydrothermal decomposition apparatus according to a first embodiment.
[Fig. 2] Fig. 2 is a schematic of another hydrothermal decomposition apparatus according to a first embodiment.
[Fig. 3] Fig. 3 is a schematic of another hydrothermal decomposition apparatus according to a first embodiment.

[Fig. 4] Fig. 4 is a schematic of another hydrothermal decomposition apparatus according to a first embodiment.
[Fig. 5] Fig. 5 is a schematic of another hydrothermal decomposition apparatus according to a first embodiment.

[Fig. 6] Fig. 6 is a schematic of another hydrothermal decomposition apparatus according to a first embodiment.
[Fig. 7] Fig. 7 is a schematic view of a biomass feeder according to the first embodiment.

[Fig. 8] Fig. 8 is a schematic view of another biomass feeder according to the first embodiment.

[Fig. 9] Fig. 9 is a graph of temperature distribution in a reactor.

[Fig. 10] Fig. 10 is a schematic of an alcohol production system according to a second embodiment.

[Fig. 11] Fig. 11 is a schematic of an alcohol production system according to a third embodiment.

EXPLANATIONS OF LETTERS OR NUMERALS

[0030] 10-1, 10-2 alcohol production system 11 biomass material 12 pretreatment device 13 pulverized biomass 41-1A to 41-1C, 41-2, 41-3 hydrothermal decomposition device 15 hot compressed water 16 discharged hot water 17 biomass solid residue 18 enzyme 19 enzymatic hydrolysis device 19-1 first enzymatic hydrolysis device 19-2 second enzymatic hydrolysis device 20-1 first sugar solution (hexose) 20-2 second sugar solution (pentose) 23 ethanol BEST MODE(S) FOR CARRYING OUT THE INVENTION

[0031] Exemplary embodiments of the present invention are described with reference to the accompanying drawings.
The present invention is not limited to the embodiments.

Constituting elements in the embodiments include elements easily achieved by a person skilled in the art, or elements being substantially equivalent to those elements.
First Embodiment [0032] A biomass hydrothermal decomposition apparatus according to an embodiment of the present invention is described with reference to the drawings. Fig. 1 is a schematic of a biomass hydrothermal decomposition apparatus according to the embodiment. As shown in Fig. 1, a biomass hydrothermal decomposition apparatus 41-1A according to the present embodiment includes: a biomass feeder 31 that feeds biomass material (e.g., straw in the present embodiment) 11 under normal pressure to under increased pressure; a horizontal device main body (hereinafter, "device main body") 42A that allows the fed biomass material 11 to be gradually moved therethrough from an end on either the left or the right side (on the left side in the present embodiment) thereof in a consolidated condition, and also allows hot compressed water 15 to be fed therein from an end (on the right side in the present embodiment), which is different from the side from which the biomass material 11 is fed, so as to cause the biomass material 11 and the hot compressed water 15 to countercurrently contact with each other and undergo hydrothermal decomposition, and that transfers lignin components and hemicellulose components into the hot compressed water 15, so as to separate the lignin components and the hemicellulose components from the biomass material 11; and a biomass discharger 51 that discharges a biomass solid residue 17 under increased pressure to under normal pressure, at the side from which the hot compressed water 15 is fed into the device main body 42A. Examples of the biomass feeder 31 that feeds biomass under normal pressure to under increased pressure may include a pump unit such as a piston pump or a slurry pump.

[0033] In the present embodiment, inside the device main body 42A is provided a fixed stirring unit 61-1 that stirs the biomass material 11 in a consolidated condition, so called in plug flow. With this arrangement, the biomass material 11 fed therein is stirred by stirring action when moved axially.

[0034] By providing the fixed stirring unit 61-1, the pressurized water on the surface of the solid and inside the solid is progressively mixed in the device main body 42A, so that the reaction is facilitated.

[0035] According to the present invention, for the flowage of the hot compressed water 15 and the flowage of the biomass material 11 inside the device main body 42A of the hydrothermal decomposition apparatus 41-1A, the hot compressed water 15 and the biomass material 11 are countercurrently contacted, preferably with agitated flow.

[0036] The hydrothermal decomposition apparatus 41-1A

performs decomposition in plug flow and has a simple configuration. Thus, the solid, the biomass material 11 is moved parallel to a central axis of its pipe, while being stirred in a direction perpendicular to the central axis of the pipe. On the contrary, the hot compressed water 15 (hot water, the liquid dissolving decomposed products) is moved while being soaked in solid particles by the counter-current flow against the solid.

[0037] In the plug flow, the hot compressed water 15 is flowed uniformly. This is because, when the solid biomass material 11 is decomposed in the hot compressed water 15, the decomposed products are dissolved in the hot water.
Accordingly, the viscosity around a decomposed portion is increased, so that the hot water is moved toward an undecomposed portion dominantly, causing decomposition of the undecomposed portion. This creates a uniform flow of the hot water, enabling uniform decomposition.

[0038] In the device main body 42A of the hydrothermal decomposition apparatus 41-1A, due to the resistance of its inner pipe wall, the solid density at the outlet side for the biomass material 11 is reduced compared with that at the inlet side for the biomass material 11. In addition, the amount of the biomass solid residue 17 is reduced by the decomposition. As a result, the ratio of the hot compressed water 15 is increased, and the liquid retention time is prolonged, causing excessive decomposition of decomposed components in the liquid. For this reason, the fixed stirring unit can be provided as appropriate.

[0039] The fixed stirring unit 61-1 may have grooves formed thereon, or may be installed at various pitches.
Further, the fixed stirring unit 61-1 may have screws in series at multiple stages, so that each screw performs stirring individually. The device main body 42A of the hydrothermal decomposition apparatus 41-1A may have a taper shape. Specifically, in the device main body 42A, the outlet for the biomass material 11 may have a smaller cross-sectional area than the inlet. With this arrangement, the solid density of the biomass material 11 is increased in the device main body 42A.

[0040] Further, an unstiffing function may be provided for preventing the solid from occluding the device main body 42A. Further, the solid-liquid weight ratio in the device main body 42A may be controlled appropriately by controlling, for example, the torque of a rotating stirring unit, the capacitance and the ultrasonic wave in the device main body 42A, and the weight of components inside the device main body 42A.

[0041] Biomass to be fed to the hydrothermal decomposition apparatus 41-1A is not limited to any specific type, and is a living organism integrated in material circulation in global biosphere or accumulation of organic materials derived from living organisms (see JIS K
3600 1258). In the present invention, particularly, cellulose resources of wood materials such as broadleaf trees and plant materials; agricultural wastes; and food wastes are preferably used.

[0042] The biomass material 11 is preferably broken into particles having a diameter of 5 millimeters or less, though not limited to this particle diameter. In the present embodiment, biomass may be subjected to pretreatment with pretreatment equipment such as pulverizing equipment, before being fed. In addition, biomass may be cleaned with cleaning equipment. When the biomass material 11 is rice husk, for example, the biomass material 11 can be fed to the hydrothermal decomposition apparatus 41-1A, without being subjected to pulverization.

[0043] In the hydrothermal decomposition apparatus 41-1A, the reaction temperature ranges from 180 C to 240 C
preferably, and from 200 C to 230 C more preferably.

This is because, at temperatures below 180 C, the hydrothermal decomposition takes place at a low rate and requires a longer time, increasing the apparatus size, which are not preferable. On the contrary, at temperatures above 240 C, the decomposition rate is too high and more cellulose components are transferred from the solid phase to the liquid phase, facilitating excessive decomposition of hemicellulose sugars, which are not preferable.

Dissolution of hemicellulose components starts at about 140 C, dissolution of cellulose starts at about 230 C, and dissolution of lignin components starts at about 140 C.

The temperature is preferably set within a range from 180 C
to 240 C that allows cellulose to be remained in the biomass solid residue, and that enables hemicellulose components and lignin components to be decomposed at adequate rates.

[0044] The reaction pressure is preferably set to a pressure higher by 0.1 MPa to 0.5 MPa than the saturated vapor pressure of water at each temperature, which allows the hot compressed water to stay inside the device main body. The reaction time is preferably three minutes to ten minutes, not more than 20 minutes. This is because a longer reaction time increases the ratio of excessively decomposed products and is not preferable.

[0045] For these reasons, preferably, the hydrothermal decomposition apparatus 41-1A creates a uniform flow of hot compressed water while causing the biomass material 11 and the hot compressed water 15 to countercurrently contact with each other.

[0046] The hot compressed water 15 is flowed by the counter-current flow, so that the heat is directly exchanged. This results in a temperature distribution as shown in Fig. 9, preventing excessive decomposition of decomposed products (such as lignin components), which are decomposed and discharged into the liquid.

[0047] The hot compressed water 15 to be fed into the device main body 42A is preferably less in weight relative to the biomass material 11, because it enables reduction in amount of steam used for warming during the hydrothermal decomposition. The weight ratio of the biomass material 11 and the hot compressed water 15 both to be fed is, for example, 1:1 to 1:10 preferably, and 1:1 to 1:5 more preferably, though it varies accordingly depending on the apparatus configuration. Particularly, in the present embodiment, the plug flow is composed of solid phase and liquid phase, i.e. the biomass material 11 and the hot compressed water 15, and is moved through the device main body 42A in the consolidated condition. The solid-to-liquid ratio can be 1:1 to 1:5. As described, the weight ratio of the biomass material 11 and the hot compressed water 15 both to be fed into the device main body 42A is made 1:1 to 1:10, thereby reducing the heat necessary for the hydrothermal decomposition apparatus.

[0048] Further, by controlling the solid-to-liquid weight ratio inside the device main body 42A, the conditions for hydrothermal decomposition are stabilized, and the biomass solid residue 17 is stably discharged from the biomass discharger 51.

[0049] By causing'the biomass material 11 and the hot compressed water 15 to countercurrently contact with each other inside the hydrothermal decomposition apparatus 41-1A, the solid-liquid separation is performed. This reduces the amount of excessively decomposed products to be brought into the solid, cellulose. Because lignin components and the like are precipitated at low temperatures, the separation is difficult at low temperatures. Thus, after the hydrothermal decomposition, the decomposed products are taken out from the reaction system and subjected to the separation. In this way, it is possible to reduce the heat loss when flush occurs due to a transition from a high temperature and high pressure condition to a normal temperature and normal pressure condition. Further, the discharged liquid containing the decomposed products is separated with improved efficiency. This arrangement is realized considering the fact that the hydrothermal decomposition products are polysaccharide components precipitated at low temperatures and therefore the separation is hardly carried out at low temperatures.

[0050] According to the present embodiment, the weight of the biomass material 11 to be fed into the hydrothermal decomposition apparatus 41-1A is increased, relative to the weight of the hot compressed water 15. This enables reduction in the apparatus size, thus contributing to improve economic efficiency.

[0051] Inside the hydrothermal decomposition apparatus 41-1A, the temperature of the biomass material 11 is increased by causing it to contact the hot compressed water in the device main body 42A and directly exchanging the heat. The temperature may be increased by using steam or the like from the outside as necessary. Alternatively, saturated steam may be directly fed into the device main 15 body 42, instead of the hot water.

[0052] In the present embodiment, the biomass feeder 31 employs a mechanism for feeding the biomass material 11, including a piston pump 31a. With this arrangement, the biomass feeder 31 feeds the solid biomass material 11 under normal pressure to under increased pressure. By using the piston pump 31a and applying pressure with the piston, the biomass material 11 is reliably fed into the device main body 42A.

[0053] Specifically, use of the piston pump 31a enables the solid in the counter-current flow of solid and liquid, i.e., the biomass material 11, to be moved by operation of the piston pump 31a, without providing a rotational moving unit or the like for moving the solid inside the device main body 42A. Further, use of the piston pump 31a also enables control of the density inside the device main body 42A (the solid-to-liquid weight ratio). Specifically, it is possible to control the retention time of the hot compressed water inside the device main body 42A.

[0054] The biomass discharger 51 employs a feeding mechanism including a screw feeder 52a and a hydraulic cylinder 52b. This enables the solid reacted inside the hydrothermal decomposition apparatus 41-1A to be compressed, so that a biomass plug 53 is formed. The biomass plug 53 serves as a material seal for keeping the pressure inside the hydrothermal decomposition apparatus 41-1A. Gradually pressed by the screw feeder 52a, the biomass under the increased pressure can be gradually discharged from an edge of the hydraulic cylinder 52b to under the normal pressure.
When the biomass solid residue 17 compressed, the residual water is removed from the biomass plug 53.

[0055] This dewatered solution 54 includes components soluble in hot compressed water (lignin components and hemicellulose components). Thus, the dewatered solution 54 is treated together with the discharged hot water 16.

[0056] As a result, it is possible to dewater the hot compressed water containing the components soluble in the hot compressed water and normally accompanying the biomass solid residue 17. This improves the yield of pentose using hemicellulose components (described later), while contributing to reduce accompanied hexose enzyme inhibitors (e.g., lignin components).

[0057] Because the pressure is changed from increased pressure to normal pressure inside the biomass discharger 51, the biomass solid residue 17 to be discharged is steam-exploded, causing breakage of its fiber structure. This improves the efficiency of enzymatic saccharification in the subsequent process.

[0058] The biomass discharger 51 can remove both of enzymatic saccharification inhibitors and ethanol fermentation inhibitors, or either of them, which are low-molecular-weight volatile inhibitors.

[0059] In the present embodiment, the hot compressed water is discharged at a portion near the inlet for feeding the biomass. Alternatively, a liquid outlet for the hot compressed water may be provided in a middle portion and the discharged liquid may be subjected to either or both of heating and cooling so that an ideal temperature distribution is plotted. Then, the discharged liquid may be fed into the device main body 42A again.

[0060] The concentration of inhibitors such as furfral in the liquid may be measured near a discharged section for the hot compressed water, so that the feed amount of the hot compressed water 15 is controlled based on the measured value. Alternatively, the sugar concentration may be measured near the biomass discharger 51, so that the feed amount of the hot compressed water 15 is controlled based on the measured value.

[0061] In the present embodiment, the hot compressed water 15 may be fed from one section. The present invention is not limited to this, and the hot compressed water 15 may be fed from a plurality of sections for temperature control.

[0062] In the present invention, by causing biomass material and hot compressed water to countercurrently contact with each other, their components are sequentially discharged in order of solubility in the hot water.
Further, due to the concentration gradient and the temperature gradient from where the biomass is fed to where the hot water is fed, excessive decomposition of hemicellulose components is prevented. As a result, pentose components can be recovered efficiently. Further, by causing the biomass material and the hot compressed water to countercurrently contact with each other, the heat is recovered, which is preferable in view of system efficiency.

[0063] Fig. 2 depicts a modification of the present embodiment. As shown in Fig. 2, a hydrothermal decomposition apparatus 41-1B is a vertical type of the horizontal type shown in Fig. 1. As shown in Fig. 2, the biomass feeder 31 is provided near a lower end of the device main body 42A, so that the biomass material 11 is fed from the lower end, while the hot compressed water 15 is fed from an upper end thereof. By causing the biomass material 11 and the hot compressed water 15 to countercurrently contact with each other, their components are sequentially discharged as the discharged hot water 16, in order of solubility in the hot compressed water 15.

Further, the biomass solid residue 17 is discharged from the biomass discharger 51 provided near the upper end.

[0064] In the present embodiment, the device main body is arranged as a vertical type. The present invention is not limited to this, and the device main body may be a slanted type. The device main body may be arranged as a slanted type or a vertical type, because it is preferable regarding that the gas resulting from the hydrothermal decomposition reaction, the gas brought into the biomass material, and the like can be released quickly from the upper side. This arrangement is also preferable in view of the discharging efficiency, because decomposed products are discharged with the hot compressed water 15 and therefore the concentration of the discharged materials is increased from the upper side to the lower side.

[0065] Fig. 3 depicts a modification of the present embodiment. In a hydrothermal decomposition apparatus 41-1C shown in Fig. 3, the dewatered solution 54, separated in the biomass discharger 51, is fed again into the device main body 42A. This arrangement reduces the amount of the hot compressed water to be fed into the apparatus. Further, a desirable counter-current flow is realized.

[0066] Fig. 4 depicts another modification of the present embodiment. As shown in Fig. 4, a hydrothermal decomposition apparatus 41-1D includes an excess water removal line 32, so that excess water 33 contained in the biomass is removed from the section for feeding the biomass material 11 into the device main body 42A. The excess water may be used to make the biomass material 11 wet.

Specifically, an excess water outlet 32a is provided away from a liquid outlet 16a for the discharged hot water 16-1, and the pressure (P1) at the excess water outlet 32a is made greater than the pressure (P2) at the liquid outlet 16a. In this way, the amount of the liquid to be discharged is controlled. This arrangement prevents the reverse flow and excessive decomposition, while reducing the heat loss.

[0067] The liquid outlet for the discharged hot water may be provided at a plurality of sections (two sections 16a and 16b in the present embodiment), and the properties of the discharged hot water at the liquid outlet(s) and/or the properties of the biomass solid residue may be measured.
Then, based on the measured values, the liquid outlet(s) for the discharged hot water may be changed appropriately.
In this way, the decomposition time is controlled.

[0068] Further, a hot water inlet for the hot compressed water may be provided at a plurality of sections (two sections 15a and 15b in the present embodiment), and either or both of the properties of the discharged hot water at the liquid outlet(s) and the properties of the solid at the outlet may be measured. Then, based on the measured values, the liquid outlet(s) for the discharged hot water may be changed. In this way, the decomposition time is controlled.

[0069] The feed amount of the biomass material 11 and the amount of the discharged hot water at the liquid outlet(s) may be controlled so that the solid-to-liquid weight ratio becomes a predetermined value in the hydrothermal decomposition apparatus 41-iD.

[0070] Fig. 5 depicts still another modification of the present embodiment. As shown in Fig. 5, a rotating stirring unit 61-2 may be provided inside a device main body 42-2 so that the biomass material 11 and the hot compressed water 15 may actively and countercurrently contact with each other to be mixed and stirred.

[0071] The rotating stirring unit 61-2 may have grooves formed thereon, or may be installed at various pitches.
Further, the rotating stirring unit 61-2 may have screws in series at multiple stages, so that each screw performs stirring individually.

[0072] Further, a filter unit 71 is provided through which the hot water 16 is discharged from the device main body 42-2, as shown in Fig. 5.

[0073] With straw biomass for example, its consolidated layer with a thickness of a several centimeters can serve as a material seal. The consolidated layer having a thickness equal to or less than that thickness allows the liquid to pass therethrough, thus serving as a self filter and enabling the liquid-solid separation at the liquid outlet(s). Alternatively, a scraper mechanism (not shown) for maintaining a predetermined thickness may be provided.
In addition to the self filter, a sand filtration filter may be provided.

[0074] The scraper mechanism may be controlled by the pressure at the liquid outlet(s).

[0075] Fig. 6 depicts still another modification of the present embodiment. As shown in Fig. 6, a device main body 42-3 of a hydrothermal decomposition apparatus 41-3 includes load cells 61a and 61b as units each monitoring a concentration of the solid inside the device main body 42-3.
The load cells 61a and 61b detect the weight of the solid, and change the rotation number and the rotation direction of the paddles, so as to control the concentration. In this way, the reaction efficiency is improved.

[0076] Referring to Figs. 7 and 8, the following describes an injection method using a piston pump as a pressing unit, for injecting the biomass material 11 into the device main body 42-3. As a pressing unit, for example, a slurry pump or a screw feeder may be used appropriately, other than the piston pump.

[0077] As shown in Fig. 7, the biomass material 11, which has been made wet, is consolidated in the cylinder.
If a consolidation force is equal to or less than a set value, air and excess water are discharged from an opened air/excess water discharge valve V1. When the consolidation force reaches the set value, the air/excess water discharge valve V1 is closed. With this arrangement, the biomass material 11 may be filled via a gate valve 34 into the device main body 42A of the hydrothermal decomposition apparatus.

[0078] When the biomass material is a dried material (containing little water), the material is consolidated in the cylinder. If a consolidation force is equal to or less than a set value, air is discharged from the opened air/excess water discharge valve V1. When the consolidation force reaches the set value, water is fed from a water feeding valve V2, excess water is discharged from the air/excess water discharge valve V1r and the both valves are closed. With this arrangement, the biomass material 11 may be filled via the gate valve 34 into the device main body 42A of the hydrothermal decomposition apparatus.

[0079] In the first embodiment, constituting elements of the biomass hydrothermal decomposition apparatus are described individually with reference to Figs. 1 to 8.
These elements may be combined appropriately.

Second Embodiment [0080] With reference to the drawings, the following describes a system of producing an organic material, i.e., alcohol, with use of biomass material according to an embodiment of the present invention. Fig. 10 is a schematic of an organic material production system using biomass material according to the embodiment. As shown in Fig. 10, an alcohol production system 10-1 using biomass material according to the present embodiment includes: a pretreatment device 12 that pulverizes the biomass material 11; the hydrothermal decomposition apparatus 41-1A (shown in Fig. 1) that hydrothermally decomposes pulverized biomass 13 by causing it to countercurrently contact the hot compressed water 15, transfers lignin components and hemicellulose components into the hot compressed water 15, and separates the lignin components and the hemicellulose components from the biomass; a first enzymatic hydrolysis device 19-1 that treats cellulose in the biomass solid residue 17, discharged from the hydrothermal decomposition apparatus 41-1A, with an enzyme (cellulase) 18-1 to enzymatically hydrolyze it to a sugar solution containing hexose; a first alcohol fermenter 21-1 that produces an alcohol (ethanol in the present embodiment) by fermentation using a first sugar solution (hexose) 20-1 obtained by the first enzymatic hydrolysis device 19-1; and a first refiner 25-1 that refines a first alcohol fermentation liquid 22-1, so as to separate it into a target product, i.e., ethanol 23, and a residue 24-1.

[0081] According to the present invention, in the hydrothermal decomposition apparatus 41-1A shown in Fig. 1, use of the counter-current flow transfers lignin components and hemicellulose components to the liquid phase, i.e., the hot compressed water 15, while allowing cellulose to remain in the solid, i.e., the biomass solid residue 17. In this way, the first sugar solution (hexose) 20-1 is obtained at the first enzymatic hydrolysis device 19-1 for performing enzymatic saccharification. Accordingly, it is possible to establish a fermentation process suitable for a hexose (fermentation suitable for an end product: in the present embodiment, fermentation for obtaining the ethanol 23 using the first alcohol fermenter 21-1).

[0082] Although the present embodiment describes an example that an alcohol, ethanol, is obtained by fermentation, the present invention is not limited to this example. Other than alcohols, substitutes for petroleum used as chemical product material, or amino acids used as food and feed materials can be obtained with a fermenter.

[0083] Examples of industrial products produced from a sugar solution as a base material may include liquefied petroleum gas (LPG), auto fuel, aircraft jet fuel, heating oil, diesel oil, various types of heavy oils, fuel gas, naphtha, and naphtha decomposed products such as ethylene glycol, ethanolamine, alcohol ethoxylate, vinyl chloride polymer, alkylaluminum, polyvinyl acetate (PVA), vinyl acetate emulsion, polystyrene, polyethylene, polypropylene, polycarbonate, methyl methacrylate (MMA) resin, nylon, and polyester. Thus, substitutes for industrial products derived from crude oil, which is fossil fuel, and sugar solution derived from biomass, which is a biomass material for producing such substitutes, can be used efficiently.

Third Embodiment [0084] With reference to the drawings, the following describes a system of producing an organic material, i.e., alcohol, with use of biomass material according to an embodiment of the present invention. Fig. 11 is a schematic of a system of producing an organic material, i.e., alcohol, with use of biomass material according to the present embodiment. As shown in Fig. 11, an alcohol production system 10-2 using biomass material according to the present embodiment is constituted by the alcohol production system 10-1 shown in Fig. 10 that includes a second enzymatic hydrolysis device 19-2. The second enzymatic hydrolysis device 19-2 treats hemicellulose components, transferred into the hot water 16 discharged from the hydrothermal decomposition apparatus 41-1A, with an enzyme to enzymatically hydrolyze it to a sugar solution 20-2 containing pentose. Two enzymatic hydrolysis devices, two alcohol fermenters, and two refiners are provided (the first enzymatic hydrolysis device 19-1, the second enzymatic hydrolysis device 19-2, the first alcohol fermenter 21-1, a second alcohol fermenter 21-2, the first refiner 25-1, and a second refiner 25-2). The ethanol 23 is obtained by performing an enzymatic hydrolysis process, an alcohol fermentation process, and an alcohol refining process that are suitable for each of the first sugar solution (hexose) 20-1 and a second sugar solution (pentose) 20-2.

[0085] In the present embodiment, the ethanol 23 can be produced by fermentation, using the second sugar solution (pentose) 20-2 obtained by the second enzymatic hydrolysis device 19-2.

[0086] The discharged hot water is not necessarily treated in a separate system. For example, processes subsequent to the enzymatic hydrolysis devices, processes subsequent to the alcohol fermenters, or processes subsequent to the refiners may be arranged as common processes, or other modification may be made appropriately.

[0087] According to the present invention, in the hydrothermal decomposition apparatus 41-1A, use of the counter-current flow allows cellulose to remain in the solid phase which is the biomass solid residue 17.
Accordingly, the first sugar solution (hexose) 20-1 is obtained by the first enzymatic hydrolysis device 19-1 for performing enzymatic saccharification. Further, hemicellulose components dissolved in the liquid phase which is the hot compressed water 15, are separated therefrom as the discharged hot water 16, so that the second sugar solution (pentose) 20-2 is obtained by the second enzymatic hydrolysis device 19-2 for separately performing enzymatic sacchrification. This enables the solid and the liquid to be separated efficiently and saccharified individually. Accordingly, fermentation processes suitable for hexose and pentose (fermentation suitable for an end product: e.g., ethanol fermentation) can be established.

[0088] As such, in the hydrothermal decomposition apparatus 41-1A, use of the counter-current flow transfers a side reaction product and a lignin component soluble in hot compressed water, both acting as inhibitors during enzymatic saccharification reaction for obtaining hexose, to the hot compressed water 15. Accordingly, the cellulose-based biomass solid residue 17 is obtained, improving the yield of hexose in the subsequent enzymatic saccharification reaction.

[0089] On the other hand, hemicellulose components contained in the separated discharged hot water 16 is saccharified later at the second enzymatic hydrolysis device 19-2, so that a sugar solution containing pentose can be obtained. Then, by using yeasts etc. suitable for hexose and pentose, ethanol can be obtained by fermentation individually and efficiently.

[0090] As described above, the present invention provides: a biomass hydrothermal decomposition apparatus and a method thereof that can produce, by transferring cellulose-based components and hemicellulose components from the biomass material to the hot compressed water and separating them from each other, sugar solutions suitable for the cellulose-based components and the hemicellulose components (hexose sugar solution and pentose sugar solution), and that can efficiently produce, using the sugar solutions as substrate materials, various types of organic materials (e.g., alcohols, substitutes for petroleum, or amino acids); and an organic material production system using biomass material. However, a conventional technology causes a phenomenon that a side reaction product inhibits enzymatic saccharification and a sugar yield is reduced.

INDUSTRIAL APPLICABILITY

[0091] As described, according to the present invention, a hydrothermal decomposition apparatus separates cellulose-based components from biomass material, so as to efficiently produce a sugar solution. Further, using the sugar solution as a substrate material, various types of organic materials (e.g., alcohols, substitutes for petroleum, or amino acids) can be efficiently produced.

Claims (13)

1. A biomass hydrothermal decomposition apparatus comprising:

a biomass feeder that feeds biomass material under normal pressure to under increased pressure;

a hydrothermal decomposition device that allows the fed biomass material to be gradually moved inside a device main body from either end thereof in a consolidated condition, and also allows hot compressed water to be fed from an other end of a feed section for the biomass material into the main body, so as to cause the biomass material and the hot compressed water to countercurrently contact with each other and undergo hydrothermal decomposition, and that elutes a lignin component and a hemicellulose component into the hot compressed water, so as to separate the lignin component and the hemicellulose component from the biomass material; and a biomass discharger that discharges, from the side where the hot compressed water is fed into the device main body, a biomass solid residue under increased pressure to under normal pressure.
2. The biomass hydrothermal decomposition apparatus according to claim 1, further comprising a fixed stirring unit or a rotating stirring unit that stirs the biomass material inside the device main body.
3. The biomass hydrothermal decomposition apparatus according to claim 1 or 2, wherein the biomass feeder is a pressing unit that presses the biomass.
4. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 3, further comprising an excess water drain line through which excess water is drained from pulverized biomass to be fed into the device main body.
5. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 4, further comprising:

a plurality of feed sections through which the hot compressed water is fed into the device main body; and a plurality of discharge sections through which hot water is discharged from the device main body.
6. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 5, further comprising a filter section that filtrates the hot water to be discharged from the device main body.
7. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 6, further comprising a density monitoring unit that monitors a biomass solid residue content inside the device main body.
8. The biomass hydrothermal decomposition apparatus according to claim 2, wherein the rotating stirring unit includes a scraper that prevents occlusion of an outlet for discharged hot water.
9. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 8, wherein the hydrothermal decomposition device has a reaction temperature ranging from 180°C to 240°C and has a condition of hot compressed water.
10. The biomass hydrothermal decomposition apparatus according to any one of claims 1 to 9, wherein a weight ratio of the fed biomass material and the fed hot compressed water is within 1:1 to 1:10.
11. A method for biomass hydrothermal decomposition comprising:

feeding biomass material under normal pressure to under increased pressure;

allowing the fed biomass material to be gradually moved inside a device main body from either end thereof in a consolidated condition and allowing hot compressed water to be fed from an other end of a feed section for the biomass material into the main body, so as to cause the biomass material and the hot compressed water to countercurrently contact with each other and undergo hydrothermal decomposition;

eluting a lignin component and a hemicellulose component into the hot compressed water, so as to separate the lignin component and the hemicellulose component from the biomass material; and discharging, from the side where the hot compressed water is fed into the device main body, a biomass solid residue under increased pressure to under normal pressure.
12. An organic material production system using biomass material, the organic material production system comprising:

a pretreatment device that pretreats the biomass material;

the hydrothermal decomposition apparatus according to any one of claims 1 to 10;

a first enzymatic hydrolysis device that treats, with an enzyme, cellulose in a biomass solid residue discharged from the hydrothermal decomposition device, so as to enzymatically hydrolyze the cellulose to a sugar solution containing hexose; and a fermenter that produces, using the sugar solution obtained by the first enzymatic hydrolysis device, any one of alcohols, substitutes for petroleum, or amino acids by fermentation.
13. The organic material production system using biomass material according to claim 12, comprising:
a second enzymatic hydrolysis device that treats, with an enzyme, a hemicellulose component in discharged hot water, so as to enzymatically hydrolyze the hemicellulose component to a sugar solution containing pentose; and a fermenter that produces, using the sugar solution obtained by the second enzymatic hydrolysis device, any one of alcohols, substitutes for petroleum, or amino acids by fermentation.
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