CA2642244A1 - Foamed treatment fluids and associated methods - Google Patents

Foamed treatment fluids and associated methods Download PDF

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Publication number
CA2642244A1
CA2642244A1 CA002642244A CA2642244A CA2642244A1 CA 2642244 A1 CA2642244 A1 CA 2642244A1 CA 002642244 A CA002642244 A CA 002642244A CA 2642244 A CA2642244 A CA 2642244A CA 2642244 A1 CA2642244 A1 CA 2642244A1
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CA
Canada
Prior art keywords
alkyl
ether sulfate
alkali salt
alkyl amidopropyl
surfactant mixture
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Granted
Application number
CA002642244A
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French (fr)
Other versions
CA2642244C (en
Inventor
Jiten Chatterji
Karen L. King
Bobby J. King
Stanley J. Heath
Darrell Chad Brenneis
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Halliburton Energy Services Inc
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Individual
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Filing date
Publication date
Priority claimed from US11/354,418 external-priority patent/US7407916B2/en
Priority claimed from US11/355,059 external-priority patent/US7134497B1/en
Application filed by Individual filed Critical Individual
Publication of CA2642244A1 publication Critical patent/CA2642244A1/en
Application granted granted Critical
Publication of CA2642244C publication Critical patent/CA2642244C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/38Gaseous or foamed well-drilling compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/516Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
    • C09K8/518Foams
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C09K8/536Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning characterised by their form or by the form of their components, e.g. encapsulated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • C09K8/70Compositions for forming crevices or fractures characterised by their form or by the form of their components, e.g. foams
    • C09K8/703Foams
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/92Compositions for stimulating production by acting on the underground formation characterised by their form or by the form of their components, e.g. encapsulated material
    • C09K8/94Foams

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Gas Separation By Absorption (AREA)
  • Detergent Compositions (AREA)

Abstract

Foamed treatment fluids comprising water, a gas, and a foaming and foam stabilizing surfactant mixture comprising an alkali salt of an alkyl ether sulfate, wherein the alkali salt of the alkyl ether sulfate comprises an alkali salt of a C6-10 alkyl ether sulfate, and an alkali salt of a C4 alkyl ether sulfate, an alkyl amidopropyl amphoteric surfactant selected from the group consisting of an alkyl amidopropyl hydroxysultaine, an alkyl amidopropyl betaine, and combinations thereof, and an alkyl amidopropyl dimethylamine oxide. Methods comprising providing the foamed treatment fluid and introducing the foamed treatment fluid into a subterranean formation.

Claims (40)

1. A foamed treatment fluid comprising:
water;
a gas; and a foaming and foam stabilizing surfactant mixture comprising:
an alkali salt of an alkyl ether sulfate, wherein the alkali salt of the alkyl ether sulfate comprises an alkali salt of a C6-10 alkyl ether sulfate, and an alkali salt of a C4 alkyl ether sulfate;
an alkyl amidopropyl amphoteric surfactant selected from the group consisting of an alkyl amidopropyl hydroxysultaine, an alkyl amidopropyl betaine, and combinations thereof, and an alkyl amidopropyl dimethylamine oxide.
2. The foamed treatment fluid of claim 1 wherein the alkali salt of the C6-alkyl ether sulfate has in range of from about 1.5 moles to about 2 moles of ethylene oxide substitution, and the alkali salt of the C4 alkyl ether sulfate has in range of from about 1.8 moles to about 2.5 moles of ethylene oxide substitution.
3. The foamed treatment fluid of claim 1 wherein the alkali salt of the C6-10 alkyl ether sulfate is present in the alkali salt of the ether sulfate in an amount in the range of from about 60% to about 75% by weight of the alkali salt of the alkali ether sulfate, and the alkali salt of the C4 alkyl ether sulfate is present in the alkali salt of the ether sulfate in an amount in the range of from about 10% to about 35% by weight of the alkali salt of the alkali ether sulfate.
4. The foamed treatment fluid of claim 1 the alkali salt of the alkyl ether sulfate comprises an ammonium salt of the alkyl ether sulfate.
5. The foamed treatment fluid of claim 1 wherein the alkali salt of the alkali ether sulfate further comprise an ammonium sulfate.
6. The foamed treatment fluid of claim 1 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a radical selected from the group consisting of a decyl radical, a cocoyl radical, a lauryl radical, a cetyl radical, and an oleyl radical.
7. The foamed treatment fluid of claim 1 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a cocoyl radical.
8. The foamed treatment fluid of claim 1 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a radical selected from the group consisting of a decyl radical, a cocoyl radical, a lauryl radical, a cetyl radical, and an oleyl radical.
9. The foamed treatment fluid of claim 1 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a cocoyl radical.
10. The foamed treatment fluid of claim 1 wherein the alkyl amidopropyl dimethylamine oxide comprises a cocamidopropyl dimethylamine oxide.
11. The foamed treatment fluid of claim 1:
wherein the alkali salt of the alkyl ether sulfate is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 60%
to about 75% by weight of the surfactant mixture;
wherein the alkyl amidopropyl amphoteric surfactant is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 15%
to about 25% by weight of the surfactant mixture; and wherein the alkyl amidopropyl dimethylamine oxide is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 1%
to about 10% by weight of the surfactant mixture.
12. The foamed treatment fluid of claim 1 wherein the foaming and foam stabilizing surfactant mixture further comprises an alkali salt comprising at least one member selected from the group of sodium chloride, ammonium chloride, potassium chloride and combinations thereof.
13. The foamed treatment fluid of claim 1 wherein the foaming and foam stabilizing surfactant mixture is present in the foamed treatment fluid in an amount in the range of from about 0.2% to about 2.0% by volume of the water present in the foamed treatment fluid.
14. The foamed treatment fluid of claim 1 wherein the foamed treatment fluid further comprises a gelling agent.
15. The foamed treatment fluid of claim 1 wherein the foamed treatment fluid further comprises particulates.
16. A foamed fracturing fluid comprising:
water;
a gas; and a foaming and foam stabilizing surfactant mixture comprising:
an alkali salt of an alkyl ether sulfate, wherein the alkali salt of the alkyl ether sulfate comprises an alkali salt of a C6-10 alkyl ether sulfate, and an alkali salt of a C4 alkyl ether sulfate, an alkyl amidopropyl amphoteric surfactant selected from the group consisting of an alkyl amidopropyl hydroxysultaine, an alkyl amidopropyl betaine, and combinations thereof, and an alkyl amidopropyl dimethylamine oxide; and proppant particulates.
17. The foamed fracturing fluid of claim 16:
wherein the alkali salt of the alkyl ether sulfate is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 60%
to about 75% by weight of the surfactant mixture;
wherein the alkyl amidopropyl amphoteric surfactant is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 15%
to about 25% by weight of the surfactant mixture; and wherein the alkyl amidopropyl dimethylamine oxide is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 1%
to about 10% by weight of the surfactant mixture.
18. The foamed fracturing fluid of claim 16 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a cocoyl radical.
19. The foamed fracturing fluid of claim 16 wherein the alkyl amidopropyl amphoteric surfactant comprises an alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a cocoyl radical.
20. A foamed treatment fluid comprising:
water;
a gelling agent;
a gas; and a foaming and foam stabilizing surfactant mixture comprising:
an ammonium salt of an alkyl ether sulfate, wherein the ammonium salt of the alkyl ether sulfate comprises an ammonium salt of a C6-10 alkyl ether sulfate having in the range of from about 1.5 moles to about 2 moles of ethylene oxide substitution, and an alkali salt of a C4 alkyl ether sulfate having in the range of from about 1.8 to about 2.5 moles of ethylene oxide substitution, a cocamidopropyl amphoteric surfactant selected from the group consisting of a cocamidopropyl hydroxysultaine, a cocamidopropyl betaine, and combinations thereof, and a cocamidopropyl dimethylamine oxide.
21. A method of treating a subterranean formation comprising:
providing a foamed treatment fluid comprising:
water, a gas, and a foaming and foam stabilizing surfactant mixture comprising:
an alkali salt of an alkyl ether sulfate, wherein the alkali salt of the alkyl ether sulfate comprises an alkali salt of a C6-10 alkyl ether sulfate, and an alkali salt of a C4 alkyl ether sulfate, an alkyl amidopropyl amphoteric surfactant selected from the group consisting of an alkyl amidopropyl hydroxysultaine, an alkyl amidopropyl betaine, and combinations thereof, and an alkyl amidopropyl dimethylamine oxide; and introducing the foamed treatment fluid into the subterranean formation.
22. The method of claim 21 wherein the alkali salt of the C6-10 alkyl ether sulfate has in range of from about 1.5 moles to about 2 moles of ethylene oxide substitution, and the alkali salt of the C4 alkyl ether sulfate has in range of from about 1.8 moles to about 2.5 moles of ethylene oxide substitution.
23. The method of claim 21 wherein the alkali salt of the C6-10 alkyl ether sulfate is present in the alkali salt of the ether sulfate in an amount in the range of from about 65% to about 90% by weight of the alkali salt of the alkali ether sulfate, and the alkali salt of the C4 alkyl ether sulfate is present in the alkali salt of the ether sulfate in an amount in the range of from about 10% to about 35% by weight of the alkali salt of the alkali ether sulfate.
24. The method of claim 21 wherein the alkali salt of the alkali ether sulfate further comprises an ammonium sulfate.
25. The method of claim 21 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a radical selected from the group consisting of a decyl radical, a cocoyl radical, a lauryl radical, a cetyl radical, and an oleyl radical.
26. The method of claim 21 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a cocoyl radical.
27. The method of claim 21 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a radical selected from the group consisting of a decyl radical, a cocoyl radical, a lauryl radical, a cetyl radical, and an oleyl radical.
28. The method of claim 21 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a cocoyl radical.
29. The method of claim 21 wherein the alkyl amidopropyl dimethylamine oxide comprises a cocamidopropyl dimethylamine oxide.
30. The method of claim 21:
wherein the alkali salt of the alkyl ether sulfate is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 60%
to about 75% by weight of the surfactant mixture;
wherein the alkyl amidopropyl amphoteric surfactant is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 15%
to about 25% by weight of the surfactant mixture; and wherein the alkyl amidopropyl dimethylamine oxide is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 1%
to about 10% by weight of the surfactant mixture.
31. The method of claim 21 wherein the foaming and foam stabilizing surfactant mixture further comprises an alkali salt.
32. The method of claim 21 wherein the foaming and foam stabilizing surfactant mixture is present in the foamed treatment fluid in an amount in the range of from about 0.2% to about 2.0% by volume of the water present in the foamed treatment fluid.
33. The method of claim 21 wherein the foamed treatment fluid further comprises a gelling agent.
34. The method of claim 21 wherein the foamed treatment fluid further comprises particulates.
35. A method of fracturing a subterranean formation comprising:
providing a foamed treatment fluid comprising:
water, a gas, and a foaming and foam stabilizing surfactant mixture comprising:
an alkali salt of an alkyl ether sulfate, wherein the alkali salt of the alkyl ether sulfate comprises an alkali salt of a C6-10 alkyl ether sulfate, and an alkali salt of a C4 alkyl ether sulfate, an alkyl amidopropyl amphoteric surfactant selected from the group consisting of an alkyl amidopropyl hydroxysultaine, an alkyl amidopropyl betaine, and combinations thereof, an alkyl amidopropyl dimethylamine oxide; and introducing the foamed treatment fluid into the subterranean formation at or above a pressure sufficient to create one or more fractures in the subterranean formation.
36. The method of claim 35:
wherein the alkali salt of the alkyl ether sulfate is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 60%
to about 75% by weight of the surfactant mixture;
wherein the alkyl amidopropyl amphoteric surfactant is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 15%
to about 25% by weight of the surfactant mixture; and wherein the alkyl amidopropyl dimethylamine oxide is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 1%
to about 10% by weight of the surfactant mixture.
37. The method of claim 35 wherein the alkyl amidopropyl amphoteric surfactant comprises the alkyl amidopropyl betaine, the alkyl amidopropyl betaine comprising a cocoyl radical.
38. The method of claim 35 wherein the alkyl amidopropyl amphoteric surfactant comprises an alkyl amidopropyl hydroxysultaine, the alkyl amidopropyl hydroxysultaine comprising a cocoyl radical.
39. A method of fracturing a subterranean formation comprising:
providing a foamed treatment fluid comprising:
water, a gelling agent, a gas, and a foaming and foam stabilizing surfactant mixture comprising:
an ammonium salt of an alkyl ether sulfate, wherein the ammonium salt of the alkyl ether sulfate comprises an ammonium salt of a C6-10 alkyl ether sulfate having in the range of from about 1.5 moles to about 2 moles of ethylene oxide substitution, and an alkali salt of a C4 alkyl ether sulfate having in the range of from about 1.8 moles to about 2.5 moles of ethylene oxide substitution, a cocamidopropyl amphoteric surfactant selected from the group consisting of a cocamidopropyl hydroxysultaine, a cocamidopropyl betaine, and combinations thereof, and a cocamidopropyl dimethylamine oxide; and introducing the foamed treatment fluid into the subterranean formation at or above a pressure sufficient to create one or more fractures in the subterranean formation.
40. The method of claim 39:
wherein the alkali salt of the alkyl ether sulfate is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 60%
to about 75% by weight of the surfactant mixture;
wherein the alkyl amidopropyl amphoteric surfactant is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 15%
to about 25% by weight of the surfactant mixture; and wherein the alkyl amidopropyl dimethylamine oxide is present in the foaming and foam stabilizing surfactant mixture in an amount in the range of from about 1%
to about 10% by weight of the surfactant mixture.
CA2642244A 2006-02-15 2007-02-07 Foamed treatment fluids and associated methods Expired - Fee Related CA2642244C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US11/354,418 US7407916B2 (en) 2006-02-15 2006-02-15 Foamed treatment fluids and associated methods
US11/354,418 2006-02-15
US11/355,059 2006-02-15
US11/355,059 US7134497B1 (en) 2006-02-15 2006-02-15 Foamed treatment fluids and associated methods
PCT/GB2007/000443 WO2007093767A2 (en) 2006-02-15 2007-02-07 Foamed treatment fluids and associated methods

Publications (2)

Publication Number Publication Date
CA2642244A1 true CA2642244A1 (en) 2007-08-23
CA2642244C CA2642244C (en) 2011-11-01

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Family Applications (1)

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CA2642244A Expired - Fee Related CA2642244C (en) 2006-02-15 2007-02-07 Foamed treatment fluids and associated methods

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AR (1) AR059504A1 (en)
CA (1) CA2642244C (en)
WO (1) WO2007093767A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2619965C2 (en) 2013-04-19 2017-05-22 Мульти-Чем Груп, Ллс Treatment fluids, containing low emulsionizing surface-active agents, and related methods
CN110835522B (en) * 2018-08-17 2022-02-15 中国石油化工股份有限公司 Temperature-resistant and salt-resistant type super-thick oil emulsifying viscosity reducer and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1379754A1 (en) * 2001-04-16 2004-01-14 Halliburton Energy Services, Inc. Methods of treating subterranean zones penetrated by well bores
US20030114315A1 (en) * 2001-12-12 2003-06-19 Clearwater, Inc. Polymeric gel system and use in hydrocarbon recovery
US20040121917A1 (en) * 2002-12-20 2004-06-24 Pakulski Marek K Synergistic mixtures containing an amino acid derivative and a method of using the same to foam brines
AR043362A1 (en) * 2003-02-03 2005-07-27 Mi Llc COLLOIDAL SYSTEMS AND STABILIZED COLOIDAL TYPE
US7013975B2 (en) * 2004-07-26 2006-03-21 Halliburton Energy Services, Inc. Foamed cement slurries, additives and methods

Also Published As

Publication number Publication date
AR059504A1 (en) 2008-04-09
WO2007093767A2 (en) 2007-08-23
CA2642244C (en) 2011-11-01
WO2007093767A3 (en) 2007-11-01

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