CA2620504A1 - Printed thermoformable laminate with increased security against forgery - Google Patents

Printed thermoformable laminate with increased security against forgery Download PDF

Info

Publication number
CA2620504A1
CA2620504A1 CA002620504A CA2620504A CA2620504A1 CA 2620504 A1 CA2620504 A1 CA 2620504A1 CA 002620504 A CA002620504 A CA 002620504A CA 2620504 A CA2620504 A CA 2620504A CA 2620504 A1 CA2620504 A1 CA 2620504A1
Authority
CA
Canada
Prior art keywords
film
print
laminate
pvc
thermoformable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002620504A
Other languages
French (fr)
Inventor
Erwin Pasbrig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3A Composites International AG
Original Assignee
Alcan Technology & Management Ltd.
Erwin Pasbrig
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alcan Technology & Management Ltd., Erwin Pasbrig filed Critical Alcan Technology & Management Ltd.
Publication of CA2620504A1 publication Critical patent/CA2620504A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/286Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysulphones; polysulfides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • B32B2307/4023Coloured on the layer surface, e.g. ink
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/716Degradable
    • B32B2307/7163Biodegradable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/738Thermoformability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/80Medical packaging

Landscapes

  • Laminated Bodies (AREA)
  • Wrappers (AREA)
  • Credit Cards Or The Like (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)

Abstract

The invention relates to a printed thermoformable laminate comprised of at least two plastic films. The printing is placed between plastic films inside the laminate in order to increase protection against forgery. Preferred laminates have the following structure: film A / print / laminating agent /
film C; film A / print / laminating agent / film B / laminating agent / film C, and; film A / print / laminating agent / film B / laminating agent / print / film C.

Description

Printed thermoformabMe laminate with increased security against forgery The invention relates to a printed thermoformable laminate made of at least two plastics material films.
Thermoformable plastics material laminates may be printed for customer information before or after forming. The printing of the laminates before the thermoforming into containers or beakers takes place prirriarily on the container wall with current printirig methods. If the plastics material laminate is printed before the thermoforming the printing may detach to a greater or lesser extent from the laminate surface during forming or during the logistics because of the reduced adhesion of the printing dyes to the background, as a function of the degree of forming.

In the two cases of conventional printing, the print is located on the outside of the laminate surface formirig the packaging and is therefore easily accessible for forgeries, in that the print can be removed from the packaging and can easily be replaced by printing on new information.

When using pre-printed laminates, there is also the possibility that these may be produced by forgers, as plastics material films and laminates made of plastics materials are available to an almost unlimited extent commercially.

The invention is based on the object of providing a thermoformable laminate of the type mentioned at the outset with a printing such that, in comparison to the printed thermoformable laminates according to the prior art, a substantially higher degree of security against forgery is produced.

The fact that the printing is arranged between adjacent plastics material films to increase the security against forgery leads to the achievement of the object according to the invention.

The followirig structures are preferred for the laminates according to the invention:

film A/ print / laminating means / film C
film A/ print i laminating means / film B/ laminating means / film C
film A/ print / laminating means / film B/ laminating rrieans / print / film C.
The films A, B and C; are thermoformable plastics material films based on chlorinated hydrocarboris, such as polyvinyl chloride and polyvinylidene chloride, chlorofluorocarbons, for example ACLARO, polyolefins, polyethyleneterephthalates, polyacrylonitriles, for example BAREX , cycloolefin copolymers, cycloolefiri polymers, polysulphones or biologically degradable plastics materials, or combinations of these plastics materials in the laminate.
PVDC may be a film or a coating.

The total thickness of the laminates is 150 to 500 pm and also 90 to 150 pm in PVC/PE laminates.

The lamination takes place with laminatirig adhesives based on water, with solvent-based or solvent-free laminating adhesives and/or by extrusion lamination as monoextrusion or coextrusion. In the case of COC or COP laminates with PE
or PP, a lacquer lamination or else the production of a partial laminate by coextrusion is recommended.

The interlaminar bond of the individual layers should be at least 2 N/15 mm.

When using dyed films for the printing, the colour of the printed image may be changed by a corresponding choice of colour. For example, blue printing of a film which is dyed yellow leads to a printed image which appears green. The security against forgery of printed laminates cari be further iricreased with colour combinations of this type.
The preferred film combinations for the laminates according to the invention are compiled in Table 1. The abbreviations of the plastics materials on which the films are based mean~
PVC polyvinyl chloride PVDC polyvinylidene chloride PAN polyacrylonitrile PE polyethylene of various densities, including the metallocenes PP polypropylenes, including the rnetallocenes COC cycloolefir copolymer COP cycloolefir polymer PSU polysulphone PCTFE polychlorotrifluoroethylene EVOH ethylene vinyl alcohol PGA polyglycolic acid Containers thermoformed from the laminate, in particular blister base parts, or beakers, preferably for packaging pharmaceutical and medical products are a preferred application area of the thermoformable laminate according to the invention.
Table 1: Preferred laminate structures Film A Film B Film C
Laminate number 1 _ PVC PVC
- - - ~ ~

- -~ PE - {
PVC PVDC
COC or COP
k6 7 } PVC PVC PVC PVC
PVC PCTFE PVC
- -- - --- - -- - - ---~- -- - ----- -_ _ _ PVC PAN PVC
-- ~--- -- -- -PVC EVOH or PGA PVC
11 PVC PE PVC ~
- - - - -13 PVC COC or COP PVC
14 PVC COC or COP pp ---_ _ - - _ I -----PVC COC or COP PVDC
- , . . - - - 16 PVC COC or COP PCTFE
17 PVC COC or COP PAN

-- - -- -P _ - f PCTFE
21 pP { PVDC
22 PP COC or COP
~
23 pp PCTFE
PP
24 PP 1 EVOH or PGA i, PP
PP COC or COP PP
-- - --- ---PAN PP
! 26 PP
.27 r pp COC or COP PVDC
-----28 --PP COC or COP - -PCTFE
--29 PET !PET
-----I'ET PCTFE , - -- -- ------ --IDSU PVC
--- - - _ ~_ - --- -~ - - -- - - -34 I'SU pp 35 PSU COC or COP PP
- _ ---- ----- -- - J
36 I'SU PVC PCTFE

38. PSU ! PET PCTFE

Claims (5)

1. Thermoformable laminate made of at least two plastics material films with printing, characterised in that the printing is arranged inside the laminate between the plastics material films to increase the security against forgery.
2. Thermoformable laminate according to claim 1, characterised in that the laminate is constructed as follows:
film A / print / laminating means / film C
film A/ print / laminating means / film B/ laminating means / film C
film A/ print / laminating means / film B/ laminating means / print /
film C.
3. Thermoformable laminate according to claim 2, characterised in that the films A, B and/or C are thermoformable plastics material films or combinations of these plastics material films based on chlorinated hydrocarbons, chlorofluorocarbons, polyolefins, polyethyleneterephthalates, polyacrylonitriles, cycloolefin copolymers, cycloolefin polymers, polysulphones or biologically degradable plastics materials.
4. Thermoformed container, in particular blister base part, or beaker made of a thermoformable laminate according to any one of the preceding claims.
5. Use of thermoformed containers and beakers according to claim 4 for the packaging of pharmaceutical and medical products.
CA002620504A 2005-09-27 2006-09-07 Printed thermoformable laminate with increased security against forgery Abandoned CA2620504A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05405560A EP1767346A1 (en) 2005-09-27 2005-09-27 Printed thermoformable laminate with increased forgery-proof nature
EP05405560.3 2005-09-27
PCT/EP2006/008739 WO2007036289A2 (en) 2005-09-27 2006-09-07 Printed thermoformable laminate with increased protection against forgery

Publications (1)

Publication Number Publication Date
CA2620504A1 true CA2620504A1 (en) 2007-04-05

Family

ID=36588840

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002620504A Abandoned CA2620504A1 (en) 2005-09-27 2006-09-07 Printed thermoformable laminate with increased security against forgery

Country Status (12)

Country Link
EP (2) EP1767346A1 (en)
JP (1) JP2009509795A (en)
KR (1) KR20080061360A (en)
CN (1) CN101272909A (en)
AU (1) AU2006296808A1 (en)
BR (1) BRPI0616753A2 (en)
CA (1) CA2620504A1 (en)
IL (1) IL190272A0 (en)
MX (1) MX2008001986A (en)
RU (1) RU2008116318A (en)
WO (1) WO2007036289A2 (en)
ZA (1) ZA200801808B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK172837B1 (en) * 1996-04-12 1999-08-09 Danisco Multilayer packaging material, especially for flexible packaging
US20030170428A1 (en) * 2002-03-07 2003-09-11 Willis Rickie A. Overwrapping film and method of use

Also Published As

Publication number Publication date
MX2008001986A (en) 2008-03-25
AU2006296808A1 (en) 2007-04-05
EP1767346A1 (en) 2007-03-28
CN101272909A (en) 2008-09-24
BRPI0616753A2 (en) 2011-06-28
RU2008116318A (en) 2009-11-10
WO2007036289A3 (en) 2007-07-19
EP1931513A2 (en) 2008-06-18
JP2009509795A (en) 2009-03-12
WO2007036289A2 (en) 2007-04-05
KR20080061360A (en) 2008-07-02
ZA200801808B (en) 2009-05-27
IL190272A0 (en) 2009-09-22

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Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued