CA2594803A1 - Reforming catalyst with chelated promoter - Google Patents
Reforming catalyst with chelated promoter Download PDFInfo
- Publication number
- CA2594803A1 CA2594803A1 CA002594803A CA2594803A CA2594803A1 CA 2594803 A1 CA2594803 A1 CA 2594803A1 CA 002594803 A CA002594803 A CA 002594803A CA 2594803 A CA2594803 A CA 2594803A CA 2594803 A1 CA2594803 A1 CA 2594803A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- component
- support
- tin
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract 16
- 238000002407 reforming Methods 0.000 title claims abstract 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims abstract 4
- 239000002184 metal Substances 0.000 claims abstract 4
- 238000000034 method Methods 0.000 claims abstract 3
- 229910052702 rhenium Inorganic materials 0.000 claims abstract 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000003606 tin compounds Chemical class 0.000 claims abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 4
- 239000002738 chelating agent Substances 0.000 claims 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 2
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims 2
- FUOOLUPWFVMBKG-UHFFFAOYSA-N 2-Aminoisobutyric acid Chemical compound CC(C)(N)C(O)=O FUOOLUPWFVMBKG-UHFFFAOYSA-N 0.000 claims 1
- 239000004471 Glycine Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims 1
- 108010077895 Sarcosine Proteins 0.000 claims 1
- 235000004279 alanine Nutrition 0.000 claims 1
- 229940009098 aspartate Drugs 0.000 claims 1
- 238000001833 catalytic reforming Methods 0.000 claims 1
- 239000013522 chelant Substances 0.000 claims 1
- 108700003601 dimethylglycine Proteins 0.000 claims 1
- 229930195712 glutamate Natural products 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229930182817 methionine Natural products 0.000 claims 1
- 229940078490 n,n-dimethylglycine Drugs 0.000 claims 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229940043230 sarcosine Drugs 0.000 claims 1
- -1 tin chelate complex Chemical class 0.000 claims 1
- 239000003446 ligand Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
A process for preparing a naphtha reforming catalyst has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid (EDTA). The aqueous solution of the chelating ligand and a tin compound is used to impregnate a support, e.g., alumina extrudates. A platinum-group metal is also an essential component of the catalyst. Rhenium may also be a component. A reforming process using the catalyst has enhanced yield, activity, and stability for conversion of naphtha into valuable gasoline and aromatic products.
Claims (10)
1. A catalyst effective for naphtha reforming comprising a particulate refractory inorganic oxide support having distributed throughout a stannous tin component, a platinum-group metal component, and a rhenium component; the catalyst characterized in that the tin is uniformly distributed throughout the support and the platinum-group metal is uniformly distributed throughout the support; the tin being distributed throughout the support with an impregnation using a tin chelate complex.
2. The catalyst as claimed in claim 1 wherein the chelate is a chelating agent selected from the group consisting of ethylenediaminetetraacetic acid, nitrilotriacetic acid, N-methylaminodiacetic acid, iminodiacetic acid, glycine, alanine, sarcosine, .alpha.-aminoisobutyric acid, N,N-dimethylglycine, .alpha.,.beta.-diaminopropionate, aspartate, glutamate, histidine, and methionine
3. The catalyst as claimed in claims 1 or 2 wherein the chelating agent is ethylenediaminetetraacetic acid.
4. The catalyst as claimed in claims 1, 2, or 3 wherein the catalyst further comprises 0.1 to 10 mass-% on an elemental basis of a halogen component.
5. The catalyst as claimed in claims 1 to 3, or 4 wherein the support is alumina.
6. The catalyst as claimed in claims 1 to 4, or 5 wherein the stannous tin component is present in an amount of 0.01 to 5 mass-% on an elemental basis.
7. The catalyst as claimed in claims 1 to 5, or 6 wherein the platinum-group metal component is platinum, which is present in an amount of 0.01 to 2 mass-% on an elemental basis.
8. The catalyst as claimed in claims 1 to 6, or 7 wherein the rhenium component is present in an amount of 0.05 to 5 mass-% on an elemental basis.
9. The catalyst as claimed in claims 2 to 7, or 8 wherein the chelating agent and stannous tin compound are present in a ratio of 1 to 8.
10. A process for the catalytic reforming of a naphtha feedstock which comprises contacting the feedstock at reforming conditions with the catalyst as claimed in claims 1 to 8, or 9, wherein the reforming conditions comprise a temperature of 315°C
to 600°C, a pressure of 100 kPa to 7 MPa (abs), a liquid hourly space velocity of 0.1 to 20 hr-1, and a mole ratio of hydrogen to naphtha feedstock of 1 to 20.
to 600°C, a pressure of 100 kPa to 7 MPa (abs), a liquid hourly space velocity of 0.1 to 20 hr-1, and a mole ratio of hydrogen to naphtha feedstock of 1 to 20.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2005/001545 WO2006078240A1 (en) | 2005-01-18 | 2005-01-18 | Reforming catalyst with chelated promoter |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2594803A1 true CA2594803A1 (en) | 2006-07-27 |
CA2594803C CA2594803C (en) | 2012-11-27 |
Family
ID=36692536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2594803A Expired - Fee Related CA2594803C (en) | 2005-01-18 | 2005-01-18 | Reforming catalyst with chelated promoter |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1838433A4 (en) |
JP (1) | JP2008526503A (en) |
CA (1) | CA2594803C (en) |
NO (1) | NO20074221L (en) |
WO (1) | WO2006078240A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012082407A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patents Inc. | Dehydrogenation catalyst and process |
EP2691359A1 (en) | 2011-03-28 | 2014-02-05 | Exxonmobil Chemical Patents Inc. | Dehydrogenation process |
US9040451B2 (en) | 2011-11-17 | 2015-05-26 | Basf Se | Process for producing Sn-comprising catalysts |
IN2014DN03136A (en) * | 2011-11-17 | 2015-05-22 | Basf Se | |
RU2747527C1 (en) * | 2020-10-28 | 2021-05-06 | Общество с ограниченной ответственностью "Институт по проектированию предприятий нефтеперерабатывающей и нефтехимической промышленности" (ООО "Ленгипронефтехим") | Method for catalytic reforming with continuous catalyst regeneration |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2889287A (en) * | 1954-10-04 | 1959-06-02 | California Research Corp | Catalyst and method of catalyst preparation |
US3801498A (en) * | 1969-03-17 | 1974-04-02 | Universal Oil Prod Co | Tetrametallic hydrocarbon conversion catalyst and uses thereof |
US3740328A (en) * | 1969-03-17 | 1973-06-19 | Universal Oil Prod Co | Hydrocarbon conversion process and catalyst therefor |
US3790473A (en) * | 1969-03-17 | 1974-02-05 | Universal Oil Prod Co | Tetrametallic hydrocarbon conversion catalyst and uses thereof |
US3632503A (en) * | 1969-09-10 | 1972-01-04 | Universal Oil Prod Co | Catalytic composite of platinum tin and germanium with carrier material and reforming therewith |
BE757342A (en) * | 1969-10-09 | 1971-03-16 | Chevron Res | PROCESS AND CATALYST FOR TRANSFORMATION OF HYDROCARBONS IN THE PRESENCE OF HYDROGEN |
FR2076937A5 (en) * | 1970-01-30 | 1971-10-15 | Chevron Res | |
US3830727A (en) * | 1970-01-30 | 1974-08-20 | Chevron Res | Reforming process with promoted catalyst |
US3642925A (en) * | 1970-04-20 | 1972-02-15 | Universal Oil Prod Co | Hydrocarbon isomerization process |
US3745112A (en) * | 1971-11-23 | 1973-07-10 | Universal Oil Prod Co | Platinum-tin uniformly dispersed hydro-carbon conversion catalyst and process |
US3846283A (en) * | 1971-11-23 | 1974-11-05 | Universal Oil Prod Co | Bimetallic catalytic reforming with halogen addition |
JPS5241189A (en) * | 1975-09-26 | 1977-03-30 | Uop Inc | Preparation of refractory inorganic oxide carried catalysts |
NL8502992A (en) * | 1985-11-01 | 1987-06-01 | Dow Chemical Nederland | METHOD FOR LOADING A MOLDED CARRIER MATERIAL WITH A CATALYTICALLY ACTIVE MATERIAL OR WITH A PRECURSOR OF A CATALYTICALLY ACTIVE MATERIAL AND FORMED CATALYST OBTAINED USING THE METHOD |
US5166121A (en) * | 1990-05-21 | 1992-11-24 | Engelhard Corporation | Catalytic compositions |
US5366617A (en) * | 1992-12-28 | 1994-11-22 | Uop | Selective catalytic reforming with high-stability catalyst |
PT758919E (en) * | 1994-05-13 | 2002-01-30 | Shell Oil Co | CATALYSTS OF HIGH ACTIVITY |
US5482910A (en) | 1994-07-05 | 1996-01-09 | Uop | Process for preparing a hydrocarbon conversion catalyst |
US6291394B1 (en) * | 1999-11-04 | 2001-09-18 | Shell Oil Company | Process for improving catalysts |
-
2005
- 2005-01-18 WO PCT/US2005/001545 patent/WO2006078240A1/en active Application Filing
- 2005-01-18 JP JP2007551239A patent/JP2008526503A/en active Pending
- 2005-01-18 CA CA2594803A patent/CA2594803C/en not_active Expired - Fee Related
- 2005-01-18 EP EP05711584A patent/EP1838433A4/en not_active Withdrawn
-
2007
- 2007-08-17 NO NO20074221A patent/NO20074221L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP1838433A1 (en) | 2007-10-03 |
CA2594803C (en) | 2012-11-27 |
EP1838433A4 (en) | 2009-03-04 |
JP2008526503A (en) | 2008-07-24 |
NO20074221L (en) | 2007-09-25 |
WO2006078240A1 (en) | 2006-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100386435B1 (en) | Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell | |
CA2594803A1 (en) | Reforming catalyst with chelated promoter | |
BR0301141B1 (en) | catalytic palladium / nickel composition including a metallic promoter supported on a support, and process for catalytically hydrogenating organic compounds. | |
KR20090031623A (en) | Direct amination of hydrocarbons | |
Wang et al. | Mild and selective hydrogenation of nitriles into primary amines over a supported Ni catalyst | |
CA2933499C (en) | Heterogeneous alkane dehydrogenation catalyst | |
JP6351589B2 (en) | Method for regenerating catalyst for hydrogenation reaction and method for producing hydride of polyhydric alcohol | |
CN101589009A (en) | Process for producing alkylated aromatic compound | |
BR0312277A (en) | Use of tellurium in carbon supported noble metal containing catalysts for liquid phase oxidation reactions | |
US6737540B2 (en) | Aminonitrile production | |
TW382012B (en) | Reductive coupling of nitrobenzene or nitrobenzenes substituted on the nucleus to give the corresponding azobenzenes and azoxybenzenes by means of redox catalysts | |
CN103772207A (en) | Method for preparing cyclohexylamine with high selectivity from nitrobenzene in one-step catalytic hydrogenation mode | |
RU2007131288A (en) | CATALYST FOR NAFTA REFORMING AND METHOD OF NAFTA CATALYTIC REFORMING | |
CN101161631A (en) | Preparation method of cyclohexylamine | |
KR101336975B1 (en) | Catalyst for manufacturing alkylamine from reductive amination | |
RU2285691C1 (en) | Method for liquid-phase catalytic alkylation of aromatic amines | |
RS20060683A (en) | The synthesis of the micro-porous silica gel and its application to the preparation of catalysts for c2 oxygenates synthesis from syngas | |
Arve et al. | Engineering HC-SCR: Improved low temperature performance through a cascade concept | |
MXPA01011960A (en) | Aminonitrile production. | |
US6521791B1 (en) | Process for regenerating a monolith hydrogenation catalytic reactor | |
CN102557963A (en) | Method for preparing 2,6-diisopropyl aniline | |
KR101988374B1 (en) | Method of preparation of ethylamine or acetonitrile by reductive amination of ethanol | |
JP2009011938A (en) | Catalyst for reducing carbon monoxide, its manufacturing method and method for producing hydrocarbon | |
CN102641734B (en) | Catalyst for aryl hydrogen peroxide hydrogenation reduction and preparation and application thereof | |
Legawiec-Jarzyna et al. | Hydrodechlorination of dichlorodifluoromethane (CFC-12) over Pd/Al 2 O 3 and Pd-Au/Al 2 O 3 catalysts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20180118 |