CA2593886A1 - Integrated ngl recovery in the production of liquefied natural gas - Google Patents
Integrated ngl recovery in the production of liquefied natural gas Download PDFInfo
- Publication number
- CA2593886A1 CA2593886A1 CA002593886A CA2593886A CA2593886A1 CA 2593886 A1 CA2593886 A1 CA 2593886A1 CA 002593886 A CA002593886 A CA 002593886A CA 2593886 A CA2593886 A CA 2593886A CA 2593886 A1 CA2593886 A1 CA 2593886A1
- Authority
- CA
- Canada
- Prior art keywords
- stream
- methane
- enriched
- heat exchanger
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000011084 recovery Methods 0.000 title claims abstract 4
- 239000003949 liquefied natural gas Substances 0.000 title claims 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract 186
- 239000007788 liquid Substances 0.000 claims abstract 41
- 238000010992 reflux Methods 0.000 claims abstract 33
- 238000004821 distillation Methods 0.000 claims abstract 27
- 238000000034 method Methods 0.000 claims abstract 27
- 239000003345 natural gas Substances 0.000 claims abstract 23
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 21
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 21
- 238000001816 cooling Methods 0.000 claims 19
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 15
- 239000003507 refrigerant Substances 0.000 claims 13
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 10
- 230000008016 vaporization Effects 0.000 claims 7
- 239000000047 product Substances 0.000 claims 6
- 238000010792 warming Methods 0.000 claims 6
- 239000001273 butane Substances 0.000 claims 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 5
- 239000001294 propane Substances 0.000 claims 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 4
- 239000012263 liquid product Substances 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0209—Natural gas or substitute natural gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
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- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
- F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
- F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
- F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
- F25J1/0231—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the working-up of the hydrocarbon feed, e.g. reinjection of heavier hydrocarbons into the liquefied gas
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- F25J1/0235—Heat exchange integration
- F25J1/0237—Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
- F25J1/0239—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
- F25J1/0241—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling wherein the overhead cooling comprises providing reflux for a fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/72—Refluxing the column with at least a part of the totally condensed overhead gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/78—Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/30—Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/50—Processes or apparatus using other separation and/or other processing means using absorption, i.e. with selective solvents or lean oil, heavier CnHm and including generally a regeneration step for the solvent or lean oil
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/62—Ethane or ethylene
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/64—Propane or propylene
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/66—Butane or mixed butanes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/12—External refrigeration with liquid vaporising loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/66—Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2280/00—Control of the process or apparatus
- F25J2280/10—Control for or during start-up and cooling down of the installation
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- Engineering & Computer Science (AREA)
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- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
Process for the liquefaction of natural gas and the recovery of components heavier than methane wherein natural gas is cooled and separated in a first distillation column into an overhead vapor enriched in methane and a bottoms stream enriched in components heavier than methane, wherein the first distillation column utilizes a liquefied methane-containing reflux stream. This reflux stream may be provided by a condensed portion of the overhead vapor or a portion of totally condensed overhead vapor that is subsequently warmed. The bottoms stream may be separated in one or more additional distillation columns to provide one or more product streams, any of which are partially or totally withdrawn as recovered hydrocarbons. A stream of unrecovered liquid hydrocarbons may be combined with either the condensed portion of the overhead vapor or a portion of totally condensed overhead vapor that is subsequently warmed.
Claims (30)
1. A process for the liquefaction of natural gas and the recovery of components heavier than methane from the natural gas, wherein the process comprises (a) cooling a natural gas feed to provide a cooled natural gas feed and introducing the cooled natural gas feed into a first distillation column;
(b) withdrawing from the first distillation column an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) cooling and condensing at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
(d) separating the bottoms stream in one or more additional distillation columns to provide one or more product streams selected from the group consisting of a residual vapor stream comprising methane, a liquid stream enriched in ethane, a liquid stream enriched in propane, a liquid stream enriched in butane, and a liquid stream enriched in pentane;
(e) withdrawing as recovered hydrocarbons all or a portion of any of the one or more product streams; and (f) introducing one or more reflux streams into the first distillation column, wherein the one or more reflux streams comprise either (f1) a liquefied methane-containing reflux stream and a stream of unrecovered liquid hydrocarbons that is pumped to a pressure in the first distillation column or (f2) a combined stream comprising the liquefied methane-containing reflux stream and the stream of unrecovered liquid hydrocarbons that is pumped to the pressure in the first distillation column, and wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and withdrawing a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream, (2) cooling and totally condensing a portion of the first overhead vapor stream to provide the liquefied methane-containing reflux stream, and (3) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream.
(b) withdrawing from the first distillation column an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) cooling and condensing at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
(d) separating the bottoms stream in one or more additional distillation columns to provide one or more product streams selected from the group consisting of a residual vapor stream comprising methane, a liquid stream enriched in ethane, a liquid stream enriched in propane, a liquid stream enriched in butane, and a liquid stream enriched in pentane;
(e) withdrawing as recovered hydrocarbons all or a portion of any of the one or more product streams; and (f) introducing one or more reflux streams into the first distillation column, wherein the one or more reflux streams comprise either (f1) a liquefied methane-containing reflux stream and a stream of unrecovered liquid hydrocarbons that is pumped to a pressure in the first distillation column or (f2) a combined stream comprising the liquefied methane-containing reflux stream and the stream of unrecovered liquid hydrocarbons that is pumped to the pressure in the first distillation column, and wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and withdrawing a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream, (2) cooling and totally condensing a portion of the first overhead vapor stream to provide the liquefied methane-containing reflux stream, and (3) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream.
2. The method of Claim 1 wherein the stream of unrecovered liquid hydrocarbons comprises any of (i) a portion of the liquid stream enriched in ethane, (ii) a portion of the liquid stream enriched in propane, (iii) a portion of the liquid stream enriched in butane, (iv) a portion of the liquid stream enriched in pentane, and (v) all or a portion of the residual vapor stream dissolved in a portion of the liquid stream enriched in propane and/or a portion of the liquid stream enriched in butane and/or a portion of the liquid stream enriched in pentane.
3. The method of Claim 1 wherein the liquefied methane-containing reflux stream is introduced into the top of the first distillation column.
4. The method of Claim 1 wherein the stream of unrecovered liquid hydrocarbons is introduced into the top of the first distillation column.
5. The method of Claim 1 wherein the combined stream comprising the liquefied methane-containing reflux stream and the stream of unrecovered liquid hydrocarbons is introduced into the top of the first distillation column.
6. The method of Claim 1 wherein the stream of unrecovered liquid hydrocarbons is introduced into the first distillation column at a location below the top of the column and above a location at which the cooled natural gas feed is introduced into the column.
7. The method of Claim 1 wherein the cooling and condensing of at least a portion of the overhead vapor stream is effected in a main heat exchanger by indirect heat exchange with a first vaporizing refrigerant provided by reducing the pressure of a first cooled multicomponent liquid refrigerant.
8. The method of Claim 7 wherein a portion of the overhead vapor stream is condensed in a heat exchanger separate from the main heat exchanger by indirect heat exchange with a stream of vaporizing refrigerant provided by withdrawing and reducing the pressure of a portion of the first cooled multicomponent liquid refrigerant.
9. The method of Claim 7 wherein the first cooled multicomponent liquid refrigerant is provided by cooling a saturated multicomponent liquid refrigerant in the main heat exchanger and wherein the warming of the portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream is effected in a heat exchanger separate from the main heat exchanger by indirect heat exchange with a portion of the saturated multicomponent liquid refrigerant.
10. The process of Claim 7 comprising subcooling at least a portion of the condensed methane-enriched stream to provide a pressurized liquefied natural gas product, wherein the subcooling is effected in the main heat exchanger by indirect heat exchange with a second vaporizing refrigerant provided by reducing the pressure of a second cooled multicomponent liquid refrigerant.
11. The process of Claim.1 wherein the cooling of the natural gas feed to provide the cooled natural gas feed is effected by indirect heat exchange with the overhead vapor stream enriched in methane.
12. The process of Claim 1 wherein the stream of unrecovered liquid hydrocarbons contains greater than about 50 mole % of hydrocarbons having three or more carbon atoms.
13. The process of Claim 1 wherein the stream of unrecovered liquid hydrocarbons contains greater than about 50 mole % of pentane.
14. The method of Claim 1 wherein the stream of unrecovered liquid hydrocarbons comprises a portion of the liquid stream enriched in propane and a portion of the liquid stream enriched in butane.
15. The method of Claim 14 wherein the stream of unrecovered liquid hydrocarbons comprises a portion of the liquid stream enriched in ethane.
16. The method of Claim 14 wherein the stream of unrecovered liquid hydrocarbons comprises a portion of the residual vapor stream comprising methane dissolved in a liquid comprising hydrocarbons heavier than methane.
17. The method of Claim 1 wherein the molar flow rate of the unrecovered liquid hydrocarbons is less than about 25% of the molar flow rate of the liquefied methane reflux stream of (f1).
18. An apparatus for the liquefaction of natural gas and the recovery of components heavier than methane from the natural gas, wherein the apparatus comprises (a) a cooling system adapted to cool a natural gas feed to provide a cooled natural gas feed;
(b) a first distillation column adapted to separate the cooled natural gas feed into an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) a main heat exchanger adapted to cool and condense at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
(d) one or more additional distillation columns adapted to separate the bottoms stream into one or more product streams selected from the group consisting of a residual vapor stream comprising methane, a liquid stream enriched in ethane, a liquid stream enriched in propane, a liquid stream enriched in butane, and a liquid stream enriched in pentane;
(e) piping adapted to withdraw all or a portion of any of the one or more product streams as recovered hydrocarbons;
(f) piping adapted to introduce one or more reflux streams into the first distillation column, wherein the one or more reflux streams comprise either (f1) a liquefied methane-containing reflux stream and a stream of unrecovered liquid hydrocarbons that is pumped to a pressure in the first distillation column, wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and withdrawing a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream, (2) cooling and totally condensing a portion of the first overhead vapor stream to provide the liquefied methane-containing reflux stream, and (3) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream; or (f2) a combined stream comprising the liquefied methane-containing reflux stream and the stream of unrecovered liquid hydrocarbons that is pumped to the pressure in the first distillation column; and (g) piping and pump or pumps adapted to transfer unrecovered liquid hydrocarbons from the one or more additional distillation columns to the piping adapted to introduce one or more reflux streams into the first distillation column.
(b) a first distillation column adapted to separate the cooled natural gas feed into an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) a main heat exchanger adapted to cool and condense at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
(d) one or more additional distillation columns adapted to separate the bottoms stream into one or more product streams selected from the group consisting of a residual vapor stream comprising methane, a liquid stream enriched in ethane, a liquid stream enriched in propane, a liquid stream enriched in butane, and a liquid stream enriched in pentane;
(e) piping adapted to withdraw all or a portion of any of the one or more product streams as recovered hydrocarbons;
(f) piping adapted to introduce one or more reflux streams into the first distillation column, wherein the one or more reflux streams comprise either (f1) a liquefied methane-containing reflux stream and a stream of unrecovered liquid hydrocarbons that is pumped to a pressure in the first distillation column, wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and withdrawing a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream, (2) cooling and totally condensing a portion of the first overhead vapor stream to provide the liquefied methane-containing reflux stream, and (3) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream; or (f2) a combined stream comprising the liquefied methane-containing reflux stream and the stream of unrecovered liquid hydrocarbons that is pumped to the pressure in the first distillation column; and (g) piping and pump or pumps adapted to transfer unrecovered liquid hydrocarbons from the one or more additional distillation columns to the piping adapted to introduce one or more reflux streams into the first distillation column.
19. The apparatus of Claim 18 comprising a heat exchanger separate from the main heat exchanger that is adapted to condense a portion of the overhead vapor stream from the first distillation column by indirect heat exchange with a stream of vaporizing refrigerant.
20. The apparatus of Claim 18 wherein the main heat exchanger is a wound coil heat exchanger.
21. The apparatus of Claim 20 wherein the main heat exchanger comprises a first bundle adapted to cool and condense at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream and a second bundle adapted to further cool the condensed methane-enriched stream to provide a subcooled liquid product.
22. A process for the liquefaction of natural gas comprising (a) cooling a natural gas feed to provide a cooled natural gas feed and introducing the cooled natural gas feed into a first distillation column;
(b) withdrawing from the first distillation column an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) cooling and condensing at least a portion of the overhead vapor stream in a main heat exchanger to provide a condensed methane-enriched stream; and (d) introducing a liquefied methane-containing reflux stream into the first distillation column, wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) dividing the overhead vapor stream into a first vapor portion and a second vapor portion, and cooling and totally condensing the first vapor portion to provide the liquefied methane-containing reflux stream, and (2) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream, dividing the condensed methane-enriched stream into a first portion and a second portion, warming the first portion to provide a warmed first portion, and utilizing the warmed first portion to provide the liquefied methane-containing reflux stream.
(b) withdrawing from the first distillation column an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) cooling and condensing at least a portion of the overhead vapor stream in a main heat exchanger to provide a condensed methane-enriched stream; and (d) introducing a liquefied methane-containing reflux stream into the first distillation column, wherein the liquefied methane-containing reflux stream is provided by a method selected from the group consisting of (1) dividing the overhead vapor stream into a first vapor portion and a second vapor portion, and cooling and totally condensing the first vapor portion to provide the liquefied methane-containing reflux stream, and (2) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream, dividing the condensed methane-enriched stream into a first portion and a second portion, warming the first portion to provide a warmed first portion, and utilizing the warmed first portion to provide the liquefied methane-containing reflux stream.
23. The method of Claim 22 wherein the first vapor portion of the overhead vapor stream is condensed in a heat exchanger separate from the main heat exchanger by indirect heat exchange with a stream of vaporizing refrigerant.
24. The method of Claim 22 wherein the warming of the first portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream is effected in a heat exchanger separate from the main heat exchanger.
25. The process of Claim 22 comprising subcooling at least a portion of the condensed methane-enriched stream to provide a pressurized liquefied natural gas product, wherein the subcooling is effected in the main heat exchanger by indirect heat exchange with a stream of vaporizing refrigerant.
26. An apparatus for the liquefaction of natural gas comprising (a) a cooling system adapted to cool a natural gas feed to provide a cooled natural gas feed;
(b) a first distillation column adapted to separate the cooled natural gas feed into an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) a main heat exchanger adapted to cool and condense at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
and (d) piping adapted to introduce a liquefied methane-containing reflux stream into the first distillation column, wherein the liquefied methane-containing reflux stream provided by a method selected from the group consisting of (1) cooling and totally condensing a portion of the overhead vapor stream to provide the liquefied methane-containing reflux stream, and (2) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream.
(b) a first distillation column adapted to separate the cooled natural gas feed into an overhead vapor stream enriched in methane and a bottoms stream enriched in components heavier than methane;
(c) a main heat exchanger adapted to cool and condense at least a portion of the overhead vapor stream to provide a condensed methane-enriched stream;
and (d) piping adapted to introduce a liquefied methane-containing reflux stream into the first distillation column, wherein the liquefied methane-containing reflux stream provided by a method selected from the group consisting of (1) cooling and totally condensing a portion of the overhead vapor stream to provide the liquefied methane-containing reflux stream, and (2) cooling and totally condensing the overhead vapor stream to form the condensed methane-enriched stream and warming a portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream.
27. The apparatus of Claim 26 comprising a heat exchanger separate from the main heat exchanger that is adapted to condense the portion of the overhead vapor stream from the first distillation column by indirect heat exchange with a stream of vaporizing refrigerant.
28. The apparatus of Claim 26 comprising a heat exchanger separate from the main heat exchanger that is adapted to warm the portion of the condensed methane-enriched stream to provide the liquefied methane-containing reflux stream.
29. The apparatus of Claim 26 wherein the main heat exchanger is a wound coil heat exchanger.
30. The apparatus of Claim 29 wherein the main heat exchanger comprises a first bundle adapted to cool and condense at least a portion of the overhead vapor stream to provide the condensed methane-enriched stream and a second bundle adapted to further cool at least a portion of the condensed methane-enriched stream to provide a subcooled liquid product.
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- 2007-07-16 EP EP07112504.1A patent/EP1881283A3/en not_active Withdrawn
- 2007-07-16 CA CA2593886A patent/CA2593886C/en not_active Expired - Fee Related
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- 2007-07-17 MY MYPI20071148A patent/MY157897A/en unknown
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US20080016910A1 (en) | 2008-01-24 |
KR20080008984A (en) | 2008-01-24 |
JP4713548B2 (en) | 2011-06-29 |
CN101108977A (en) | 2008-01-23 |
EP1881283A3 (en) | 2013-04-10 |
CA2593886C (en) | 2012-03-27 |
RU2007128005A (en) | 2009-01-27 |
CN101108977B (en) | 2012-07-18 |
EG25242A (en) | 2011-11-20 |
RU2374575C2 (en) | 2009-11-27 |
PE20080391A1 (en) | 2008-05-16 |
KR100891907B1 (en) | 2009-04-06 |
NO20073829L (en) | 2008-01-22 |
MY157897A (en) | 2016-08-15 |
TW200806784A (en) | 2008-02-01 |
AU2007203296A1 (en) | 2008-02-07 |
AU2007203296B2 (en) | 2008-12-18 |
TWI349034B (en) | 2011-09-21 |
EP1881283A2 (en) | 2008-01-23 |
JP2008057962A (en) | 2008-03-13 |
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