CA2546940A1 - Process for simultaneous recovery and cracking/upgrading of oil from solids - Google Patents
Process for simultaneous recovery and cracking/upgrading of oil from solids Download PDFInfo
- Publication number
- CA2546940A1 CA2546940A1 CA002546940A CA2546940A CA2546940A1 CA 2546940 A1 CA2546940 A1 CA 2546940A1 CA 002546940 A CA002546940 A CA 002546940A CA 2546940 A CA2546940 A CA 2546940A CA 2546940 A1 CA2546940 A1 CA 2546940A1
- Authority
- CA
- Canada
- Prior art keywords
- oil
- solids
- sand
- cracking
- upgrading
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007787 solid Substances 0.000 title claims abstract 17
- 238000000034 method Methods 0.000 title claims abstract 13
- 238000011084 recovery Methods 0.000 title claims abstract 13
- 238000005336 cracking Methods 0.000 title claims abstract 12
- 239000004058 oil shale Substances 0.000 claims abstract 10
- 239000011275 tar sand Substances 0.000 claims abstract 10
- 239000004576 sand Substances 0.000 claims 9
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- 238000002485 combustion reaction Methods 0.000 claims 2
- 239000003027 oil sand Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 230000001133 acceleration Effects 0.000 claims 1
- 238000000889 atomisation Methods 0.000 claims 1
- 239000000571 coke Substances 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The present invention relates to a process for the simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale. With this process a number of the obstacles with the existing technology are solved, and the process upgrades the oil into a lighter product than the existing technology, remove sulphur in the order of 40% and heavy metals in the order of 90%.
Claims (9)
1.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, characterized in that oil containing solids are injected into a fluidised bed reactor where the hydrocarbons are evaporated off and where the heat for the evaporation is delivered by internal combustion of a part of the hydrocarbons in the solids or by an external combustor, and that the combustion gasses together with the evaporated hydrocarbons act as a pneumatic carrier of the solids and reduce the partial pressure of the hydrocarbon gasses and where the stream is routed to a cyclone reactor and further to a solids removal separator and further to a condensing system for the condensable gasses.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, characterized in that oil containing solids are injected into a fluidised bed reactor where the hydrocarbons are evaporated off and where the heat for the evaporation is delivered by internal combustion of a part of the hydrocarbons in the solids or by an external combustor, and that the combustion gasses together with the evaporated hydrocarbons act as a pneumatic carrier of the solids and reduce the partial pressure of the hydrocarbon gasses and where the stream is routed to a cyclone reactor and further to a solids removal separator and further to a condensing system for the condensable gasses.
2.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1, characterized in that a portion of the product from the condenser system is routed back to the stream in a riser via a atomisation nozzle whereby the stream of solids acts as a cracking medium by shear forces, heat exchange and sono-luminiscence.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1, characterized in that a portion of the product from the condenser system is routed back to the stream in a riser via a atomisation nozzle whereby the stream of solids acts as a cracking medium by shear forces, heat exchange and sono-luminiscence.
3.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1 and 2, characterized in that the riser have different diameters so as to obtain acceleration, retardation and optimised collisions between the solid particles in the stream.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1 and 2, characterized in that the riser have different diameters so as to obtain acceleration, retardation and optimised collisions between the solid particles in the stream.
4.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1, characterized that the temperature in the regenerator is controlled by the injected wet oil sand into the regenerator.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale, in accordance to claim 1, characterized that the temperature in the regenerator is controlled by the injected wet oil sand into the regenerator.
5.
A process for simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale in accordance to claim 1, characterized in that the oil stripped sand is routed to a fluidised combustor where remaining coke on the sand is burned off by injection of air into the combustor and where the released heat is used for production of steam, and where the exhaust gas from the combustor is alternatively routed to the plenum of the stripping reactor to participate with heat and fluidising gas for stripping of the oil trapped on the sand.
A process for simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale in accordance to claim 1, characterized in that the oil stripped sand is routed to a fluidised combustor where remaining coke on the sand is burned off by injection of air into the combustor and where the released heat is used for production of steam, and where the exhaust gas from the combustor is alternatively routed to the plenum of the stripping reactor to participate with heat and fluidising gas for stripping of the oil trapped on the sand.
6.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that a portion of the stripped sand is mixed with oil sand for heat recovery and homogenising of the sand improving the feed to the reactor.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that a portion of the stripped sand is mixed with oil sand for heat recovery and homogenising of the sand improving the feed to the reactor.
7.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that the fluidized bed reactor has two diameters, where the lower part of the regenerator has a smaller diameter than the upper part in order to reduce the gas velocities in the upper part of the regenerator.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that the fluidized bed reactor has two diameters, where the lower part of the regenerator has a smaller diameter than the upper part in order to reduce the gas velocities in the upper part of the regenerator.
8.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that stripped sand in the regenerator is continuously discharged from the regenerator via a pipe which outside of the regenerator has a "water" trap which may be U formed and where steam or gas is injected into the pipe opposite the "water trap" for pneumatic transport of sand falling into the trap.
A process for simultaneous recovery and cracking/upgrading of oil from solids, such as tar sand and oil shale in accordance with claim 1, characterized in that stripped sand in the regenerator is continuously discharged from the regenerator via a pipe which outside of the regenerator has a "water" trap which may be U formed and where steam or gas is injected into the pipe opposite the "water trap" for pneumatic transport of sand falling into the trap.
9.
A process for simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale in accordance with claim 1, characterized in that a battery of regenerators are arranged around a joint charging system and a joint sand receiving collector and heat recovery fluidiser (L) and where the off gasses from the regenerator share a joint sand separation system and a joint condenser set up and where cooled condensed oil acts as a condensing medium in the oil condenser by direct contact between the hot oil gasses and the cooled condensed oil.
A process for simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale in accordance with claim 1, characterized in that a battery of regenerators are arranged around a joint charging system and a joint sand receiving collector and heat recovery fluidiser (L) and where the off gasses from the regenerator share a joint sand separation system and a joint condenser set up and where cooled condensed oil acts as a condensing medium in the oil condenser by direct contact between the hot oil gasses and the cooled condensed oil.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2546940A CA2546940C (en) | 2006-05-15 | 2006-05-15 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
CNA2007800174764A CN101484550A (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
AU2007250630A AU2007250630B2 (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
BRPI0711480-0A BRPI0711480A2 (en) | 2006-05-15 | 2007-05-10 | process to simultaneously recover and crack / benefit oil from solids |
EP07747631A EP2029695A4 (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
RU2008149093/04A RU2434049C2 (en) | 2006-05-15 | 2007-05-10 | Procedure for oil simultaneous extraction and cracking/refining from solid substances |
US12/300,549 US20090120844A1 (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
MX2008014630A MX2008014630A (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids. |
PCT/NO2007/000170 WO2007133089A1 (en) | 2006-05-15 | 2007-05-10 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
NO20085143A NO20085143L (en) | 2006-05-15 | 2008-12-10 | Procedure for simultaneous recovery and cracking / recovery of oil from solids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2546940A CA2546940C (en) | 2006-05-15 | 2006-05-15 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2546940A1 true CA2546940A1 (en) | 2007-11-15 |
CA2546940C CA2546940C (en) | 2010-09-21 |
Family
ID=38686899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2546940A Expired - Fee Related CA2546940C (en) | 2006-05-15 | 2006-05-15 | Process for simultaneous recovery and cracking/upgrading of oil from solids |
Country Status (10)
Country | Link |
---|---|
US (1) | US20090120844A1 (en) |
EP (1) | EP2029695A4 (en) |
CN (1) | CN101484550A (en) |
AU (1) | AU2007250630B2 (en) |
BR (1) | BRPI0711480A2 (en) |
CA (1) | CA2546940C (en) |
MX (1) | MX2008014630A (en) |
NO (1) | NO20085143L (en) |
RU (1) | RU2434049C2 (en) |
WO (1) | WO2007133089A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO331801B1 (en) * | 2009-01-09 | 2012-04-02 | Tarblaster As | Process for simultaneous recovery and cracking of oil from oil / solid mixtures |
GB201200155D0 (en) | 2012-01-06 | 2012-02-15 | Statoil Asa | Process |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2537153A (en) * | 1946-10-08 | 1951-01-09 | Standard Oil Dev Co | Fluidized carbonization process |
US2534051A (en) * | 1946-11-22 | 1950-12-12 | Standard Oil Dev Co | Method for fluidized low-temperature carbonization of coal |
US2729597A (en) * | 1949-04-30 | 1956-01-03 | Hydrocarbon Research Inc | Process for rendering solid carbonaceous materials non-agglomerative |
US2764531A (en) * | 1952-08-01 | 1956-09-25 | Exxon Research Engineering Co | Process and apparatus for retorting oil shale |
US3501394A (en) * | 1967-04-17 | 1970-03-17 | Mobil Oil Corp | Gas lift retorting process for obtaining oil from fine particles containing hydrocarbonaceous material |
US4105502A (en) * | 1976-06-25 | 1978-08-08 | Occidental Petroleum Corporation | Simplified liquefaction pyrolysis process and apparatus therefor |
US4094767A (en) * | 1976-11-10 | 1978-06-13 | Phillips Petroleum Company | Fluidized bed retorting of tar sands |
US4369100A (en) * | 1977-09-27 | 1983-01-18 | Sawyer Harold T | Method for enhancing chemical reactions |
US4264435A (en) * | 1978-04-05 | 1981-04-28 | The Dow Chemical Company | Crude oil cracking using partial combustion gases |
US4276021A (en) * | 1979-08-08 | 1981-06-30 | Dravo Corporation | Method of recovering heat from hot granular solids |
US4326944A (en) * | 1980-04-14 | 1982-04-27 | Standard Oil Company (Indiana) | Rapid hydropyrolysis of carbonaceous solids |
DE3023670C2 (en) * | 1980-06-25 | 1982-12-23 | Veba Oel Entwicklungsgesellschaft mbH, 4660 Gelsenkirchen-Buer | Method and device for smoldering oil shale |
US4412910A (en) * | 1981-10-21 | 1983-11-01 | Westinghouse Electric Corp. | Recovery of fuel from oil shale |
US4415433A (en) * | 1981-11-19 | 1983-11-15 | Standard Oil Company (Indiana) | Fluid bed retorting process with multiple feed lines |
US4507195A (en) * | 1983-05-16 | 1985-03-26 | Chevron Research Company | Coking contaminated oil shale or tar sand oil on retorted solid fines |
US5076910A (en) * | 1990-09-28 | 1991-12-31 | Phillips Petroleum Company | Removal of particulate solids from a hot hydrocarbon slurry oil |
US5914027A (en) * | 1994-09-12 | 1999-06-22 | Thermtech A/S | Thermo-mechanical cracking and hydrogenation |
KR0171501B1 (en) * | 1996-08-28 | 1999-03-20 | 이성래 | Apparatus and process for reclaiming waste oil |
US6709573B2 (en) * | 2002-07-12 | 2004-03-23 | Anthon L. Smith | Process for the recovery of hydrocarbon fractions from hydrocarbonaceous solids |
NO20040615L (en) * | 2004-02-11 | 2005-08-12 | Ellycrack As | Low temperature catalytic cracking and conversion process for upgrading heavy crude oil |
-
2006
- 2006-05-15 CA CA2546940A patent/CA2546940C/en not_active Expired - Fee Related
-
2007
- 2007-05-10 BR BRPI0711480-0A patent/BRPI0711480A2/en not_active IP Right Cessation
- 2007-05-10 AU AU2007250630A patent/AU2007250630B2/en not_active Ceased
- 2007-05-10 US US12/300,549 patent/US20090120844A1/en not_active Abandoned
- 2007-05-10 RU RU2008149093/04A patent/RU2434049C2/en not_active IP Right Cessation
- 2007-05-10 EP EP07747631A patent/EP2029695A4/en not_active Withdrawn
- 2007-05-10 MX MX2008014630A patent/MX2008014630A/en active IP Right Grant
- 2007-05-10 WO PCT/NO2007/000170 patent/WO2007133089A1/en active Application Filing
- 2007-05-10 CN CNA2007800174764A patent/CN101484550A/en active Pending
-
2008
- 2008-12-10 NO NO20085143A patent/NO20085143L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
RU2434049C2 (en) | 2011-11-20 |
NO20085143L (en) | 2008-12-15 |
AU2007250630B2 (en) | 2011-08-18 |
CA2546940C (en) | 2010-09-21 |
BRPI0711480A2 (en) | 2011-11-16 |
RU2008149093A (en) | 2010-06-20 |
WO2007133089A1 (en) | 2007-11-22 |
CN101484550A (en) | 2009-07-15 |
MX2008014630A (en) | 2009-02-06 |
EP2029695A4 (en) | 2011-11-02 |
US20090120844A1 (en) | 2009-05-14 |
AU2007250630A1 (en) | 2007-11-22 |
EP2029695A1 (en) | 2009-03-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20180515 |