CA2532346A1

CA2532346A1 - Recycling of lignocellulose based board materials

Info

Publication number: CA2532346A1
Application number: CA 2532346
Authority: CA
Inventors: Abrar Jawaid
Original assignee: Individual
Current assignee: Fira International Ltd
Priority date: 2003-07-16
Filing date: 2004-07-16
Publication date: 2005-01-27
Also published as: US20060254731A1; NZ544667A; BRPI0412564A; WO2005007968A1; AU2004257920A1; EP1649103A1

Abstract

A method of recovering a constituent of a board material comprised of a matrix of adhesively bonded lignocellulosic elements, the method comprising subjecting the material to a combination of (i) electromagnetic radiation and (ii) soaking or immersion in a liquid medium, and recovering the constituent.

Description

RECYCLING OF LIGNOCELLULOSE BASED BOARD MATERIALS
The present invention relates to the recycling of lignocellulose based board (or panel) material comprised of a matrix of adhesively bonded lignocellulosic elements so as to permit recovery of constituents of the board material, particularly but not exclusively of the lignocellulose.
It is well-known that various board materials comprise a matrix of lignocellulosic elements (e.g. in the form of chips, particles or fibres) bonded together by means of an adhesive such as, for example, a polyurethane, urea/formaldehyde, melamine-urea or phenolic resin.
Examples of board materials produced in this way include MDF
(Medium Density Fibreboard), particle board and chip board.
Board materials of the type described above are used extensively for producing finished articles such as, for example, furniture. For this purpose, the board materials are entirely satisfactory. However there is a substantial amount of waste material for which disposal poses a problem.
To illustrate the point, the UK furniture manufacturing industry generates over 170,000 tonnes of MDF waste every year. This does not include rejected and damaged furniture items. Ideally the waste material would be recycled to recover constituents thereof, particularly the lignocellulose for reuse. However, no satisfactory recycling process is currently available. The problem is made worse by the fact that the waste board material may be laminated to a surface layer such as, for example, paper foil or plastics (e. g. for decorative purposes) or may have, for example, plastic or metal inserts. As such, any recycling process will need to remove the laminates and/or inserts. In the absence of any suitable recycling process, most of the waste board material will be dumped in landfill site, which is becoming more difficult and very expensive.
It is an object of the present invention to obviate or mitigate the above mentioned disadvantages.
According to the present invention there is provieled a method of recovering a constituent of a board material comprised of a matrix of adhesively bonded lignocellulosic elements, the method comprising subjecting the material to a combination of (i) electromagnetic radiation and (ii) soaking or immersion in a liquid medium, and recovering the constituent.
The constituent to be recovered will generally comprise lignocellulose, which may, however, incorporate residual resin, for example urea-formaldehyde resin.
The electromagnetic radiation will typically have a frequency in the range of from 100 kHz to 300 GHz, more typically from 10 MHz to 300 GHz.
The liquid medium will typically comprises water or an aqueous solution. The liquid medium could', however, comprise any suitable organic or inorganic solvent capable of swelling the material so that the constituent can be recovered. Possible other examples include ethyl alcohol, ethyl alcohol/water mixtures, and dilute sodium hydroxide (for example 0.1-9o by volume). This latter example has been found to improve fibre texture.

The invention has been based in part on our discovery that treatment of board materials comprised of an adhesively bonded matrix of lignocellulosic elements, for example particles or fibres, by exposure to electromagnetic energy in the frequency range of from 10 MHz to 2500 MHz and soaking with a liquid medium such as water produces substantial swelling of the board material, which, we believe, mechanically disrupts and possibly at least -partially hydrolyses the adhesive bonding the lignocellulosic elements together so that these elements can now be readily separated from each other. The degree of swelling achieved is considerably more that that which is obtained simply by soaking the board material in the liquid medium.
Steps (i) and (ii) may be effected simultaneously or sequentially. The degree of swelling achieved in the thickness dimension of the board should generally be in the range of from 3 to 6 times the original thickness.
Separation of the lignocellulosic elements from each other may be achieved using a relatively low degree of mechanical agitation while the treated material is in the liquid medium, for example water. Once the elements have been separated, it is possible to recover a desired constituent of the board, which will usually comprise the lignocellulose. Thus, for example, the resultant dispersion of fibres may be dried, for example by press-drying (if the fibres are to be transported) or by a fan-assisted blowing system (if the fibres are to be re-used on site). Moreover, surface laminates, for example paper, foil, melamine, veneer or other finishes commonly used on board materials to which the invention relates, can readily be separated from the treated board prior to recovery of the fibres, for example by agitation, as may inserts or other bodies included in the panels.
The board material will typically have a density of from 200 Kg m 3 to 1200 Kg m 3.
The invention is applicable to a wide variety of wood based boards, including particle boards and fibre boards.
Specific examples of board materials to which the present invention is applicable include MDF, chip board, hard board, soft board, orientated strand board, flax board and wood chip board, and combination of any two or more thereof.
The invention is applicable both to industrial- and consumer- waste board material.
The electromagnetic radiation used in the process of the invention preferably has a frequency in the range of from 10 MHz to 300 GHz, more preferably from 10 MHz to 2500 MHz. These frequencies have been found to result in substantial swelling of the board material in the liquid medium. The power is preferably~in the range of from 500 W
to 30 kW, more preferably from 3 kW to 15 kW, although certain values in these ranges may be more applicable to some materials rather than others. Thus, for example, the power used should preferably not be so high as to cause charring of the board material. The optimum parameters may readily be determined by a person skilled in the art.

_$_ It is particularly preferred that microwaves in the frequency range from 896 + 20 MHz to 2450 + 25 MHz are employed (such as generated by a magnetron). Thus, for example, the electromagnetic radiation used may be 896 + 20 MHz or 2450 + 25 MHz, both of which are frequencies reserved for domestic/industrial microwave use. These frequencies have been found to result in substantial swelling of the board material in the liquid medium.
Alternatively the electromagnetic energy may have a frequency in the range of from 10 MHz to 50 MHz.
For all embodiments the microwaves may be generated by means of a magnetron in a conventional way. The power output to the cavity, which may, for example, be in the form of a metallic vessel or pipe, is preferably in the range 500 W to 30 kW. The microwaves propagate through the cavity, which contains the wood-based panels immersed in the liquid medium such as water.
Electromagnetic radiation having a frequency in the range of from 100 kHz to 100 MHz may also be used, which is typical of radio frequency (RF) waves. Thus, the process according to the present invention is not restricted to the use of microwaves. RF may also be utilised due to the lower frequencies of operation resulting in greater penetration through the board, which is often advantageous. RF may be defined as all frequencies used for communication, corresponding to 100 kHz to 300 GHz. Further details may be found in Kitchen, R. (2001) RF and Microwave Radiation Safety. Newnes ppl-2.

The invention may be practised in a number of ways. Tn a particularly preferred embodiment, the board material is initially subjected to the electromagnetic radiation and is then immersed substantially immediately into the liquid medium, for example within 5 to 15 seconds. The liquid medium, for example water, is preferably at an elevated temperature, for example 60°-90°C, preferably about 80°C.
For this embodiment, it is desirable that the board material does have internal moisture content, preferably a minimum of 80, which may, if necessary, be enhanced prior to the treatment with electromagnetic radiation. Immersion of the board material that has been subjected to electromagnetic radiation into the liquid medium causes substantial swelling to occur. Typically the exposure time to the electromagnetic radiation will be in the range of from 30 to 90 seconds. Subsequently the material is soaked in the liquid medium to swell the material. Typically the degree of swelling may be to 3 to 6 times the original degree of thickness, for which an immersion time of typically 10-25 minutes in, for example, water may be required, although the exact time will depend on factors such as the nature of the board, the.parameters employed (for example frequency and power) employed during the treatment with electromagnetic energy, and the temperature of the water.
Any surface laminate applied to the board may easily be removed from the swollen board (and in fact the laminate may start to peel-off during the treatment with electromagnetic radiation). Similarly any inserts may also be removed easily. The swollen material may then readily be converted to a fibrous suspension using, for example, a moderate degree of agitation such as provided a low power mechanical blender, for example.
The fibrous suspension may then be dried, for example by press-drying or by means of a fan-assisted blowing system as described previously.
This embodiment of the invention may be effected on a continuous or semi-continuous basis by, for example, passing the material to be treated through or passed a microwave source (with the material, for example, being on a conveyer belt) and then introducing the material into a tank of liquid medium (for example water) for the desired residence time therein.
In an alternative, but less preferred, embodiment of the invention, the board materials is immersed in the liquid medium (for example water) and subjected to electromagnetic radiation as discussed previously followed by soaking in the liquid medium without irradiation. All other conditions being equal, this embodiment of the invention tends to produce a lower degree of swelling of the board than the above described preferred embodiment and does not lend itself as readily to continuous or semi-continuous operation as the above described preferred embodiment. It may however be possible to recover heat from the liquid medium using, for example, a heat exchanger to assist in drying of the board. Moreover, this embodiment involves not only heating of the board material by the electromagnetic radiation but also the liquid medium in which it is immersed, thus reducing energy efficiency. Furthermore, it is envisaged _g_ that this embodiment may provide more problems with effluent disposal than the above described more preferred embodiment.
For all embodiments of the invention, the board material may initially be subjected to a vacuum impregnation so as to increase its moisture content, for example up to 50o by weight. Alternatively, or additionally, the liquid medium in which the board is immersed may incorporate an additive such as, for example a surface active agent or surfactant, to assist penetration of the water into the board.
Furthermore, for all embodiments of the invention, the board material may be "turned°' during treatment with the electromagnetic radiation to ensure uniform exposure.
It will be appreciated that the invention is able to provide clean recycled fibre for a number of possible uses, for example production of other board products, wood plastic components, fillers and insulating materials.
The process according to the present invention can be conducted on a mobile basis if desired.
The invention will be further described, by way of example only, with reference to the following non-limiting Examples and accompanying drawing (Figure 1), which illustrates the result of Example 1.

_9_ Example 1 Two experiments were conducted as detailed under (a) and (b) below.
(a) Samples of MDF measuring (approx. 50 x 50 x 18) mm were immersed (individually) in approximately 1000 ml of water in a non-metallic container and subjected to microwave radiation at a frequency. of 2450 + 25 MHz at power levels of 3 kW to 15 kW for a period of approximately one minute. The samples were allowed to stand in the water for approximately 10 to 15 minutes. The procedure was carried out a total of three times at each power level using fresh MDF samples each time. The thickness of the samples was measured after this treatment and the results plotted in Figure l, which is a graph of the mean of the three thicknesses of the MDF samples (after the treatment) at each power level vs. power level employed.
(b) The procedure of (a) was repeated but using samples of MDF measuring (approx. 150 x 150 x 18) mm using power levels of approximately 12 kW and 15 kW for a period of approximately 60 seconds. The results are also plotted on Figure 1.
For the experiments of Parts (a) and (b), the water temperature was monitored and was found not to exceed 90°C.
It can be seen from the results presented in Figure 1 that all samples swelled as a result of the combination of microwave treatment with simultaneous immersion in water.
For the (50 x 50 x 18) mm samples, best results were obtained at power levels greater than approximately 5 kW, with the samples swelling to a thickness of 60 mm or greater. The (150 x 150 x 18) mm samples provided even greater degrees of swelling. This finding could be indicative of "greater cavity loading'° at higher power levels. Although not illustrated on the graph, a further sample of (approx. 150 x 150 x 18) mm board, which was;
treated for about 45 seconds at 12 kW power, recorded a mean thickness swell of 92.11 mm.
All samples of the swollen material could easily be converted to a fibrous suspension in either approximately two minutes using a pulp disintegrator rated at approximately 1.5 kW or in approximately four minutes using a 700 W laboratory stirrer.
Example 2 A (approx. 150 x 150 x 18) mm sample of MDF was subjected to microwave radiation at a frequency of approximately 2450 + 25 MHz at a power level of approximately 12 kW for a period of about 45 seconds and then added immediately to water at a temperature of above about 60°C and allowed to stand for approximately 10 to 15 minutes.
The MDF was found to have swollen in thickness to approximately 90.42 mm. The swollen material could easily be converted to a fibrous suspension in either approximately 2 minutes using a pulp disintegrator rated at 1.5 kW or in approximately 4 minutes using a 700 W laboratory stirrer.

Claims

1. A method of recovering a constituent of a board material comprised of a matrix of adhesively bonded lignocellulosic elements, the method comprising subjecting the material to a combination of (i) electromagnetic radiation and (ii) soaking or immersion in a liquid medium, and recovering the constituent.

2. A method as claimed in claim 1, wherein the electromagnetic radiation has a frequency in the range of from 100 kHz to 300 GHz.

3. A method as claimed in claim 1 or claim 2, wherein the electromagnetic radiation has a frequency in the range of from 10 MHz to 300 GHz.

4. A method as claimed in any one claims 1 to 3, wherein the electromagnetic radiation has a frequency in the range of from 896 ~ 20 MHz to 2450 ~ 25 MHz.

5. A method as claimed in claim 4, wherein the electromagnetic radiation has a frequency of 896 ~ 20 MHz.

6. A method as claimed in claim 4, wherein the electromagnetic radiation has a frequency of 2450 ~ 25 MHz.

7. A method as claimed in any one of claims 1 to 3, wherein the electromagnetic radiation has a frequency in the range of from 10 MHz to 50 MHz.

8. A method as claimed in claim 1 or claim 2, wherein the electromagnetic radiation has a frequency in the range of from 100 kHz to 100 MHz.

9. A method as claimed in any of claims 1 to 8, wherein the power of the electromagnetic radiation is in the range of from 500 W to 30 kW.

10. A method as claimed in any of claims 1 to 9,-wherein the liquid medium comprises water.

11. A method as claimed in any one of claims 1 to 9, wherein the liquid medium comprises an organic or inorganic solvent.

12. A method as claimed in any of claims 1 to 11, wherein the board material is initially subjected to the electromagnetic radiation (step (i)) and then immersed in the liquid medium (step (ii)).

13. A method as claimed in any one of claims 1 to 12, wherein the liquid medium is at elevated temperature.

14. A method as claimed in claim 13, wherein the liquid medium is at a temperature of from 60° to 90°C.

15. A method as claimed in any one of claims 1 to 11, wherein the board material is immersed in the liquid medium and subjected to the electromagnetic radiation while immersed.

16. A method as claimed in any one of claim 1 to 15, wherein the treated board material is subjected to mechanical agitation in the liquid medium to produce a fibrous suspension.

17. A method as claimed in claim 16, wherein lignocellulose is recovered from the fibrous suspension.

18. A method as claimed in claim 17, wherein the-lignocellulose is recovered by drying of the suspension.

19. A method as claimed in any of claims 1 to 18, wherein the lignocellulose based board is or comprises a particle board or fibre board.

20. A method as claimed in claim 19, wherein the lignocellulose based board is or comprises Medium Density Fibreboard.

21. A method as claimed in claim 1, wherein the electromagnetic radiation comprises microwaves.

22. A method as claimed in claim 1, wherein the electromagnetic radiation comprises radio frequency (RF) waves.