CA2520642A1 - Dispersion - Google Patents
Dispersion Download PDFInfo
- Publication number
- CA2520642A1 CA2520642A1 CA002520642A CA2520642A CA2520642A1 CA 2520642 A1 CA2520642 A1 CA 2520642A1 CA 002520642 A CA002520642 A CA 002520642A CA 2520642 A CA2520642 A CA 2520642A CA 2520642 A1 CA2520642 A1 CA 2520642A1
- Authority
- CA
- Canada
- Prior art keywords
- dispersion
- group
- paper
- sizing agent
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006185 dispersion Substances 0.000 title claims abstract 21
- 238000004513 sizing Methods 0.000 claims abstract 13
- 239000001913 cellulose Substances 0.000 claims abstract 7
- 229920002678 cellulose Polymers 0.000 claims abstract 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract 7
- -1 oxyalkylene phosphate Chemical compound 0.000 claims abstract 7
- 238000004519 manufacturing process Methods 0.000 claims abstract 6
- 238000000034 method Methods 0.000 claims abstract 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 4
- 239000010452 phosphate Substances 0.000 claims abstract 4
- 150000003839 salts Chemical class 0.000 claims abstract 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract 4
- 239000003995 emulsifying agent Substances 0.000 claims abstract 3
- 150000002561 ketenes Chemical class 0.000 claims abstract 3
- 238000002360 preparation method Methods 0.000 claims abstract 2
- 125000000129 anionic group Chemical group 0.000 claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000003381 stabilizer Substances 0.000 claims 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229920001732 Lignosulfonate Polymers 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- 150000001450 anions Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/10—Phosphorus-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
Landscapes
- Paper (AREA)
- Lubricants (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an aqueous dispersion useful for internal sizing or surface sizing in the production of paper, comprising at least one cellulose reactive sizing agent selected from the group consisting of ketene dimers and multimers, at least one cellulose non-reactive sizing agent and at least one emulsifier selected from the group consisting of oxyalkylene phosphate and sulfate esters and salts thereof. The invention further concerns a process for its preparation, use thereof, and processes for the production of paper.
Claims (18)
1. Aqueous dispersion useful for internal sizing or surface sizing in the production of paper, comprising at least one cellulose reactive sizing agent selected from the group consisting of ketene dimers and multimers, at least one cellulose non-reactive sizing agent, and at least one emulsifier selected from the group consisting of oxyalkylene phosphate and sulfate esters and salts thereof.
2. Dispersion as claimed in claim 1 further comprising at least one cationic organic compound having a weight average molecular weight less than about 10000.
3. Dispersion as claimed in any one of the claims 1-2 further comprising at least one anionic stabiliser.
4. Dispersion as claimed in any one of the claims 1-3, comprising at least one emulsifier selected from the group consisting of oxyalkylene phosphate esters and salts thereof.
5. Dispersion as claimed in any one of the claims 1-4, wherein the oxyalkylene phosphate and sulfate esters are of the formula:
where R4 is -OH or -O - A2 - R5 ;
A1 and A2, independently of each others, are oxyalkylene chains;
Q is PO(OH) or SO2; and, R3 and R5, independently of each others, are hydrocarbon groups.
where R4 is -OH or -O - A2 - R5 ;
A1 and A2, independently of each others, are oxyalkylene chains;
Q is PO(OH) or SO2; and, R3 and R5, independently of each others, are hydrocarbon groups.
6. Dispersion as claimed in claim 5, wherein Q is PO(OH).
7. Dispersion as claimed in any one of the claims 1-6, wherein the cellulose non-reactive sizing agent is selected from the group consisting of copolymers of styrene or substituted styrene with at least one other kind of ethylenically unsaturated monomers.
8. Dispersion as claimed in claim 7, wherein said at least one other kind of ethylenically unsaturated monomers are selected from the group consisting of alkyl esters of acrylic acid or methacrylic acid.
9. Dispersion as claimed in any one of the claims 2-8, wherein the cationic organic compound is a surfactant selected from the group consisting compounds having the general formula R4N+ Y-, where each R group, independently of each other, is hydrogen or a hydrocarbon groups having from 1 to 30 carbon atoms, and X is an anion.
10. Dispersion as claimed in any one of the claims 3-9, wherein the anionic stabiliser is selected from the group consisting of condensated naphthalene and lignin sulfonates.
11. Dispersion as claimed in any one of the claims 1-10, wherein the dispersion is predominantly anionic.
12. Dispersion as claimed in any one of the claims 1-11, wherein the pH is from about 2 to about 6.
13. A process for the preparation of a dispersion according to any one of the claims 1-12, comprising the steps of bringing together at least one cellulose reactive sizing agent selected from the group consisting of ketene dimers and multimers, at least one cellulose non-reactive sizing agent, and at least one emulsifer selected from the group consisting of oxylalkylene phosphate and sulfate esters and salts thereof, in the presence of water to obtain a mixture, and homogenising the mixture to obtain an aqueous dispersion.
14. A process as claimed in claim 13 further comprising the steps of adding a cationic organic compound having a weight average molecular weight less than about 10000 and an anionic stabiliser before homogenising the mixture.
15. Use of a dispersion according to any one of the claims 1-12 for surface sizing of paper.
16. Use of a dispersion according to any one of the claims 1-12 for internal sizing at production of paper.
17. A process for the production of paper comprising the steps of forming a paper web from a stock containing cellulosic fibres and applying to the surface of the paper web an aqueous dispersion according to any one of the claims 1-12.
18. A process for the production of paper comprising the steps of adding a dispersion according to any one of the claims 1-12 to a stock containing cellulosic fibres, and dewatering the stock on a wire to obtain paper and white water.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03445042.9 | 2003-04-01 | ||
EP03445042 | 2003-04-01 | ||
PCT/SE2004/000306 WO2004088036A1 (en) | 2003-04-01 | 2004-03-04 | Dispersion |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2520642A1 true CA2520642A1 (en) | 2004-10-14 |
CA2520642C CA2520642C (en) | 2010-03-02 |
Family
ID=33104239
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002520642A Expired - Fee Related CA2520642C (en) | 2003-04-01 | 2004-03-04 | Dispersion |
Country Status (19)
Country | Link |
---|---|
EP (1) | EP1611284B1 (en) |
JP (1) | JP4375625B2 (en) |
KR (1) | KR100771786B1 (en) |
CN (1) | CN100335720C (en) |
AT (1) | ATE526456T1 (en) |
AU (1) | AU2004225562B2 (en) |
BR (1) | BRPI0409152A (en) |
CA (1) | CA2520642C (en) |
ES (1) | ES2373954T3 (en) |
MX (1) | MXPA05009305A (en) |
MY (1) | MY136991A (en) |
NZ (1) | NZ542293A (en) |
PL (1) | PL1611284T3 (en) |
PT (1) | PT1611284E (en) |
RU (1) | RU2309213C2 (en) |
SI (1) | SI1611284T1 (en) |
TW (1) | TWI259224B (en) |
WO (1) | WO2004088036A1 (en) |
ZA (1) | ZA200506665B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113861356A (en) * | 2021-09-03 | 2021-12-31 | 浙江恒达新材料股份有限公司 | Modified lignin particle emulsion and preparation method and application thereof |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2608146C (en) * | 2005-05-16 | 2011-03-22 | Akzo Nobel N.V. | A process for the production of paper |
WO2008009607A1 (en) * | 2006-07-18 | 2008-01-24 | Lamberti Spa | Concentrated gypsum suspensions for coating colour of paper |
KR100983098B1 (en) | 2008-05-19 | 2010-09-17 | 주식회사 파피테크 | Method for the production of dissoluble dust-free paper |
US7998311B2 (en) * | 2008-07-24 | 2011-08-16 | Hercules Incorporated | Enhanced surface sizing of paper |
KR101161272B1 (en) * | 2009-11-17 | 2012-07-02 | 오씨아이에스엔에프 주식회사 | Manufacturing method and application of polyacrylamide which have functional groups of polynaphtalene sulfonate or ligno sulfonate |
JP5754584B2 (en) * | 2010-05-27 | 2015-07-29 | 荒川化学工業株式会社 | Surface sizing agent for papermaking, surface size coating liquid and paper |
CN102011341A (en) * | 2010-06-29 | 2011-04-13 | 上海东升新材料有限公司 | Composite surface sizing agent being capable of replacing internal sizing agent and application thereof |
CN101942780B (en) * | 2010-09-15 | 2011-09-07 | 山东轻工业学院 | Method for preparing AKD emulsion sizing agent |
ES2585556T3 (en) * | 2011-03-31 | 2016-10-06 | Solenis Technologies Cayman, L.P. | Gluing compositions |
CN105283601B (en) * | 2013-06-13 | 2019-01-22 | 艺康美国股份有限公司 | Anhydrous surface sizing composition and the method for handling paper base material with it |
CN103410040A (en) * | 2013-06-28 | 2013-11-27 | 池州浙源纸业有限公司 | Preparation method of corrugated paper with high water resistance |
CN103410042A (en) * | 2013-06-28 | 2013-11-27 | 池州浙源纸业有限公司 | Preparation method for corrugated paper with high strength |
FI126960B (en) * | 2014-02-06 | 2017-08-31 | Kemira Oyj | Stabilized adhesive formulation |
CN103866627B (en) * | 2014-02-28 | 2016-01-13 | 南通玖伍捌科技企业孵化器有限公司 | A kind of polyurethane sizing agent and preparation method thereof |
CN104153245A (en) * | 2014-07-24 | 2014-11-19 | 杭州百事特实业有限公司 | Solid surface sizing agent for paper-making as well as preparation method and application thereof |
CN104153246A (en) * | 2014-07-24 | 2014-11-19 | 杭州百事特实业有限公司 | Papermaking sizing starch substitute as well as preparation method and application thereof |
EP3209627B1 (en) * | 2014-10-23 | 2021-08-04 | Basf Se | A process for hydrophobization of concrete |
RU2691239C2 (en) * | 2014-10-23 | 2019-06-11 | Басф Се | Method of producing prefabricated construction material |
CN105696417B (en) * | 2016-04-26 | 2017-09-19 | 齐鲁工业大学 | A kind of preparation method of the AKD emulsions of surfactant-free |
RU2741610C2 (en) * | 2016-05-03 | 2021-01-27 | Соленис Текнолоджиз, Л.П. | Biopolymer sizing agents |
JP6867802B2 (en) * | 2016-12-26 | 2021-05-12 | 大王製紙株式会社 | Manufacturing method of water-based post-glue crimping paper and water-based post-glue crimping paper |
WO2018169459A1 (en) | 2017-03-15 | 2018-09-20 | Sca Forest Products Ab | Method of preparing a sizing boost additive |
JP7287148B2 (en) * | 2019-06-26 | 2023-06-06 | 荒川化学工業株式会社 | Surface sizing agent for papermaking, method for producing surface sizing agent for papermaking, and coated paper |
KR102549679B1 (en) * | 2021-07-02 | 2023-06-29 | 이해석 | Method for manufacturing dispersant |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4214948A (en) * | 1974-07-31 | 1980-07-29 | National Starch And Chemical Corporation | Method of sizing paper |
US4529447A (en) * | 1982-06-11 | 1985-07-16 | Sanyo Chemical Industries, Ltd. | Sizing composition |
GB9603909D0 (en) * | 1996-02-23 | 1996-04-24 | Allied Colloids Ltd | Production of paper |
US6162328A (en) * | 1997-09-30 | 2000-12-19 | Hercules Incorporated | Method for surface sizing paper with cellulose reactive and cellulose non-reactive sizes, and paper prepared thereby |
US6602994B1 (en) * | 1999-02-10 | 2003-08-05 | Hercules Incorporated | Derivatized microfibrillar polysaccharide |
US6918995B2 (en) * | 2000-08-07 | 2005-07-19 | Akzo Nobel N.V. | Process for the production of paper |
US20030019599A1 (en) * | 2000-08-07 | 2003-01-30 | John Nicholass | Sizing dispersion |
EP1256655A1 (en) * | 2001-05-09 | 2002-11-13 | Akzo Nobel N.V. | Sizing dispersion |
-
2004
- 2004-03-04 PL PL04717341T patent/PL1611284T3/en unknown
- 2004-03-04 RU RU2005133635/12A patent/RU2309213C2/en not_active IP Right Cessation
- 2004-03-04 AT AT04717341T patent/ATE526456T1/en active
- 2004-03-04 MX MXPA05009305A patent/MXPA05009305A/en active IP Right Grant
- 2004-03-04 AU AU2004225562A patent/AU2004225562B2/en not_active Ceased
- 2004-03-04 NZ NZ542293A patent/NZ542293A/en not_active IP Right Cessation
- 2004-03-04 PT PT04717341T patent/PT1611284E/en unknown
- 2004-03-04 CA CA002520642A patent/CA2520642C/en not_active Expired - Fee Related
- 2004-03-04 BR BRPI0409152-3A patent/BRPI0409152A/en not_active Application Discontinuation
- 2004-03-04 SI SI200431799T patent/SI1611284T1/en unknown
- 2004-03-04 CN CNB2004800070140A patent/CN100335720C/en not_active Expired - Fee Related
- 2004-03-04 WO PCT/SE2004/000306 patent/WO2004088036A1/en active IP Right Grant
- 2004-03-04 ZA ZA200506665A patent/ZA200506665B/en unknown
- 2004-03-04 ES ES04717341T patent/ES2373954T3/en not_active Expired - Lifetime
- 2004-03-04 KR KR1020057018299A patent/KR100771786B1/en not_active IP Right Cessation
- 2004-03-04 JP JP2006500760A patent/JP4375625B2/en not_active Expired - Fee Related
- 2004-03-04 EP EP04717341A patent/EP1611284B1/en not_active Expired - Lifetime
- 2004-03-25 TW TW093108096A patent/TWI259224B/en not_active IP Right Cessation
- 2004-03-30 MY MYPI20041151A patent/MY136991A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113861356A (en) * | 2021-09-03 | 2021-12-31 | 浙江恒达新材料股份有限公司 | Modified lignin particle emulsion and preparation method and application thereof |
CN113861356B (en) * | 2021-09-03 | 2024-04-16 | 浙江恒达新材料股份有限公司 | Modified lignin particle emulsion and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
PL1611284T3 (en) | 2012-02-29 |
CN1761789A (en) | 2006-04-19 |
WO2004088036A1 (en) | 2004-10-14 |
RU2005133635A (en) | 2006-03-10 |
TW200502462A (en) | 2005-01-16 |
EP1611284A1 (en) | 2006-01-04 |
RU2309213C2 (en) | 2007-10-27 |
AU2004225562B2 (en) | 2007-05-31 |
JP4375625B2 (en) | 2009-12-02 |
ES2373954T3 (en) | 2012-02-10 |
EP1611284B1 (en) | 2011-09-28 |
ATE526456T1 (en) | 2011-10-15 |
CN100335720C (en) | 2007-09-05 |
MY136991A (en) | 2008-12-31 |
MXPA05009305A (en) | 2005-11-04 |
BRPI0409152A (en) | 2006-03-28 |
AU2004225562A1 (en) | 2004-10-14 |
JP2006522227A (en) | 2006-09-28 |
KR20050118697A (en) | 2005-12-19 |
TWI259224B (en) | 2006-08-01 |
CA2520642C (en) | 2010-03-02 |
PT1611284E (en) | 2011-12-22 |
SI1611284T1 (en) | 2012-01-31 |
NZ542293A (en) | 2008-12-24 |
KR100771786B1 (en) | 2007-10-30 |
ZA200506665B (en) | 2006-12-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20150304 |