CA2482306A1 - Improved cleaning composition - Google Patents

Improved cleaning composition Download PDF

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Publication number
CA2482306A1
CA2482306A1 CA002482306A CA2482306A CA2482306A1 CA 2482306 A1 CA2482306 A1 CA 2482306A1 CA 002482306 A CA002482306 A CA 002482306A CA 2482306 A CA2482306 A CA 2482306A CA 2482306 A1 CA2482306 A1 CA 2482306A1
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CA
Canada
Prior art keywords
cleaning composition
improved cleaning
compound
surfactant
copolymers
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002482306A
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French (fr)
Other versions
CA2482306C (en
Inventor
Andrew Kilkenny
Elias A. Shaheen
Robert L. Blum
Shumanta Mitra
Malcolm A. De Leo
Shona L. Nelson
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Clorox Co
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Individual
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Filing date
Publication date
Priority claimed from US09/939,383 external-priority patent/US20030109411A1/en
Priority claimed from US09/939,179 external-priority patent/US20020183233A1/en
Application filed by Individual filed Critical Individual
Priority to CA2736045A priority Critical patent/CA2736045C/en
Publication of CA2482306A1 publication Critical patent/CA2482306A1/en
Application granted granted Critical
Publication of CA2482306C publication Critical patent/CA2482306C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Abstract

An improved cleaning composition adapted to clean a variety of hard surfaces.
The improved cleaning composition includes a cationic biocide that includes biguanide compounds and/or quats.

Claims (111)

1. An improved cleaning composition comprising a cationic biocide, surfactant, and a polymer, said cationic biocide including a compound selected from the group consisting ofbiguanide compound, quaternary ammonium compound, and mixtures thereof.
2. The improved cleaning composition as defined in claim 1, wherein said surfactant includes a non-ionic surfactant.
3. The improved cleaning composition as defined in claim 1, wherein said surfactant includes a glycoside.
4. The improved cleaning composition as defined in claim 1, wherein said polymer is formulated to enhance the detergency of said surfactant.
5. The improved cleaning composition as defined in claim 1, wherein said polymer includes a compound selected from the group consisting ofvinylpyrrolidone homo-and copolymers, acrylamide homo- and copolymers, polyvinylalcohol and polyvinylacetate homo-and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
6. The improved cleaning composition as defined in claim 5, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
7. The improved cleaning composition as defined in claim 6, wherein said polyvinylpyrrolidone compound includes a copolymer of vinylpyrrolidone and dimethylaminoethylmethacrylate quaternized with diethylsulfate.
8. The improved cleaning composition as defined in claim 1, further including a biocide release agent.
9. The improved cleaning composition as defined in claim 8, wherein said biocide release agent having an ionic strength in said improved cleaning composition of at least about 5 ×
-3 mo/l.
10. The improved cleaning composition as defined in claim 1, wherein said cationic biocide includes a biguanide compound.
11. The improved cleaning composition as defined in claim 1, wherein said cationic biocide includes a quaternary ammonium compound.
12. The improved cleaning composition as defined in claim 10, wherein said cationic biocide further includes a quaternary ammonium compound.
13. The improved cleaning composition as defined in claim 1, further including a solvent.
14. The improved cleaning composition as defined in claim 13, wherein said solvent includes two solvent compounds, one of said solvent compounds has a boiling point less than about 150°C and another solvent compound has a boiling point of at least about 150°C.
15. The improved cleaning composition as defined in claim 1, further including at least an effective amount of builder.
16. The improved cleaning composition as defined in claim 1, further including at least an effective amount of a second surfactant.
17. The improved cleaning composition as defined in claim 1, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
18. The improved cleaning composition as defined in claim 16, wherein said second surfactant includes a fluorosurfactant.
19. An improved cleaning composition comprising a cationic biocide, and a biocide release agent, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound, and mixtures thereof, said biocide release agent having an ionic strength in said improved cleaning composition of at least about 5 × 10-3 mol/1.
20. The improved cleaning composition as defined in claim 19, further including a surfactant.
21. The improved cleaning composition as defined in claim 20, wherein said surfactant includes a non-ionic surfactant.
22. The improved cleaning composition as defined in claim 21, wherein said surfactant includes a glycoside.
23. The improved cleaning composition as defined in claim 22, wherein said glycoside includes alkyl polyglycosides.
24. The improved cleaning composition as defined in claim 20, further including a polymer.
25. The improved cleaning composition as defined in claim 24, wherein said polymer is formulated to enhance the detergency of said surfactant.
26. The improved cleaning composition as defined in claim 24, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers, acrylamide homo- and copolymers, polyvinylalcohol and polyvinylacetate homo-and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
27. The improved cleaning composition as defined in claim 26, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
28. The improved cleaning composition as defined in claim 19, wherein said cationic biocide includes a biguanide compound.
29. The improved cleaning composition as defined in claim 19, wherein said cationic biocide includes a quaternary ammonium compound.
30. The improved cleaning composition as defined in claim 28, wherein said cationic biocide further includes a quaternary ammonium compound.
31. The improved cleaning composition as defined in claim 19, including a solvent.
32. The improved cleaning composition as defined in claim 31, wherein said solvent includes two solvent compounds, one of said solvent compounds has a boiling point less than about 150°C and another solvent compound has a boiling point of at least about 150°C.
33. The improved cleaning composition as defined in claim 19, including at least an effective amount of builder.
34. The improved cleaning composition as defined in claim 20, further including at least an effective amount of a second surfactant.
35. The improved cleaning composition as defined in claim 34, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
36. The improved cleaning composition as defined in claim 34, wherein said second surfactant includes a fluorosurfactant.
37. An improved cleaning composition comprising a cationic biocide, and a dual boiling point solvent system, one of said solvent compounds having a boiling point of less than about 150°C
and another solvent compound having a boiling point of at least about 150°C, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound, and mixtures thereof.
38. The improved cleaning composition as defined in claim 37, further including a biocide release agent, said biocide release agent having an ionic strength in said improved cleaning composition of at least about 5 × 10 -3 moll.
39. The improved cleaning composition as defined in claim 37, further including a surfactant.
40. The improved cleaning composition as defined in claim 39, wherein said surfactant includes a non-ionic surfactant.
41. The improved cleaning composition as defined in claim 40, wherein said surfactant includes a glycoside.
42. The improved cleaning composition as defined in claim 41, wherein said glycoside includes of alkyl polyglycosides.
43. The improved cleaning composition as defined in claim 39, further including a polymer.
44. The improved cleaning composition as defined in claim 43, wherein said polymer is formulated to enhance the detergency of said surfactant.
45. The improved cleaning composition as defined in claim 43, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers, acrylamide homo- and copolymers, polyvinylalcohol and polyvinylacetate homo-and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
46. The improved cleaning composition as defined in claim 45, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
47. The improved cleaning composition as defined in claim 37, wherein said cationic biocide includes a biguanide compound.
48. The improved cleaning composition as defined in claim 37, wherein said cationic biocide includes a quaternary ammonium compound.
49. The improved cleaning composition as defined in claim 47, wherein said cationic biocide further includes a quaternary ammonium compound.
50. The improved cleaning composition as defined in claim 37, further including at least an effective amount of builder.
51. The improved cleaning composition as defined in claim 39, further including at least an effective amount of a second surfactant.
52. The improved cleaning composition as defined in claim 51, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
53. The improved cleaning composition as defined in claim 51, wherein said second surfactant includes a fluorosurfactant.
54. A cleaning material having reduced biocide retention comprising:
a. an absorbent or adsorbent material including a material selected from the group consisting of wood pulp, wood pulp derivative, synthetic fibers, and mixtures thereof; and b. an improved cleaning composition at least partially absorbed or adsorbed on said absorbent or adsorbent material, said improved cleaning composition including cationic biocide, surfactant, and a biocide release agent, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound, and mixtures thereof.
55. The cleaning material as defined in claim 54, wherein said absorbent or adsorbent material is selected from the group consisting of a cleaning wipe, a cleaning pad, a mop head, and combinations thereof.
56. The cleaning material as defined in claim 54, further including a polymer.
57. The improved cleaning composition as defined in claim 56, wherein said polymer is formulated to enhance the detergency of said surfactant.
58. The improved cleaning composition as defined in claim 56, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers, acrylamide homo- and copolymers, polyvinylalcohol and polyvinylacetate homo-and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
59. The cleaning material as defined in claim 58, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
60. The cleaning material as defined in claim 54, wherein said biocide release agent having an ionic strength in said improved cleaning composition of at least about 5 × 10 -3 mol/l.
61. The cleaning material as defined in claim 54, wherein said cationic biocide includes a biguanide compound.
62. The cleaning material as defined in claim 54, wherein said cationic biocide includes a quaternary ammonium compound.
63. The cleaning material as defined in claim 61, wherein said cationic biocide further includes a quaternary ammonium compound.
64. The cleaning material as defined in claim 54, further including a solvent system.
65. The cleaning material as defined in claim 64, further including a dual boiling point solvent system, one of said solvent compounds having a boiling point of less than about 150°C and another solvent compound having a boiling point of at least about 150°C.
66. The cleaning material as defined in claim 54, further including at least an effective amount of builder.
67. The cleaning material as defined in claim 54, further including at least an effective amount of a second surfactant.
68. The improved cleaning composition as defined in claim 67, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
69. The improved cleaning composition as defined in claim 67, wherein said second surfactant includes a fluorosurfactant.
70. A cleaning material having reduced biocide retention comprising:
a. an absorbent or adsorbent material including a material selected from the group consisting of wood pulp, wood pulp derivative, synthetic fibers, and mixtures thereof; and b. an improved cleaning composition at least partially absorbed or adsorbed on said absorbent or adsorbent material, said improved cleaning composition including cationic biocide and surfactant, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound, and mixtures thereof.
71. The cleaning material as defined in claim 70, wherein said absorbent or adsorbent material is selected from the group consisting of a cleaning wipe, a cleaning pad, a mop head, and combinations thereof.
72. The cleaning material as defined in claim 70, further including a polymer.
73. The improved cleaning composition as defined in claim 72, wherein said polymer is formulated to enhance the detergency of said surfactant.
74. The improved cleaning composition as defined in claim 72, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers, acrylamide homo- and copolymers, polyvinylalcohol and polyvinylacetate homo-and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
75. The cleaning material as defined in claim 74, wherein said polymer includes a compound selected from the group consisting ofpolyvinylpyrrolidone compound, quaternaryacrylic copolymer, and mixtures thereof.
76. The cleaning material as defined in claim 70, further including a biocide release agent, said biocide release agent having an ionic strength in said improved cleaning composition of at least about 5 × 10 -3 mol/l.
77. The cleaning material as defined in claim 70, wherein said cationic biocide includes a biguanide compound.
78. The cleaning material as defined in claim 70, wherein said cationic biocide includes a quaternary ammonium compound.
79. The cleaning material as defined in claim 77, wherein said cationic biocide further includes a quaternary ammonium compound.
80. The cleaning material as defined in claim 70, further including a solvent system.
81. The cleaning material as defined in claim 80, further including a dual boiling point solvent system, one of said solvent compounds having a boiling point of less than about 150°C and another solvent compound having a boiling point of at least about 150°C.
82. The cleaning material as defined in claim 70, further including at least an effective amount of builder.
83. The cleaning material as defined in claim 70, further including at least an effective amount of a second surfactant.
84. The improved cleaning composition as defined in claim 83, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
85. The improved cleaning composition as defined in claim 84, wherein said second surfactant includes a fluorosurfactant.
86. A method for cleaning a hard surface comprising:
a. providing an absorbent or adsorbent material, said absorbent or adsorbent material including a material selected from the group consisting of wood pulp, wood pulp derivative, synthetic fibers, and mixtures thereof;
b. at least partially exposing said absorbent or adsorbent material with an improved cleaning composition, said improved cleaning composition including a cationic biocide, surfactant, and biocide release agent, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound and mixtures thereof, and;

c. contacting said hard surface with said absorbent or adsorbent material and said improved cleaning composition.
87. The method as defined inn claim 86, wherein said step of contacting at least partially disinfects, sanitizes, and/or sterilizes said hard surface.
88. The method as defined in claims 86, wherein said absorbent or adsorbent material is at least partially impregnated with said improved cleaning composition prior to said absorbent or adsorbent material contacting said hard surface.
89. The method as defined in claims 86, wherein said absorbent or adsorbent material is selected from the group consisting of a cleaning wipe, a cleaning pad, a mop head, and combinations thereof.
90. The method as defined in claims 86, wherein said improved cleaning composition further includes a polymer.
91. The method as defined in claim 90, wherein said polymer is formulated to enhance the detergency of said surfactant.
92. The method as defined in claim 90, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers acrylamide homo-and copolymers, polyvinylalcohol and polyvinylacetate homo- and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
93. The method as defined in claim 92, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
94. The method as defined in claim 86, further including a solvent.
95. The method as defined in claims 94, wherein said improved cleaning composition includes a dual boiling point solvent solution, one of said solvent compounds having a boiling point of less than about 150°C and another solvent compound has a boiling point of at least about 150°C.
96. The method as defined in claims 86, wherein said improved cleaning composition further includes at least an effective amount of a second surfactant.
97. The method as defined in claim 96, wherein said second surfactant includes a compound that increases the wetting properties of said improved cleaning composition.
98. The method as defined in claim 97, wherein said second surfactant includes a fluorosurfactant.
99. A method for cleaning a hard surface comprising:
a. providing an absorbent or adsorbent material, said absorbent or adsorbent material including a material selected from the group consisting of wood pulp, wood pulp derivative, synthetic fibers, and mixtures thereof;
b. at least partially exposing said absorbent or adsorbent material with an improved cleaning composition, said improved cleaning composition including a cationic biocide, and surfactant, said cationic biocide including a compound selected from the group consisting of biguanide compound, quaternary ammonium compound and mixtures thereof, and;
c. contacting said hard surface with said absorbent or adsorbent material and said improved cleaning composition.
100. The method as defined inn claim 99, wherein said step of contacting at least partially disinfects, sanitizes, and/or sterilizes said hard surface.
101. The method as defined in claims 99, wherein said absorbent or adsorbent material is at least partially impregnated with said improved cleaning composition prior to said absorbent or adsorbent material contacting said hard surface.
102. The method as defined in claims 99, wherein said absorbent or adsorbent material is selected from the group consisting of a cleaning wipe, a cleaning pad, a mop head, and combinations thereof.
103. The method as defined in claims 99, wherein said improved cleaning composition further includes a polymer.
104. The method as defined in claim 103, wherein said polymer is formulated to enhance the detergency of said surfactant.
105. The method as defined in claim 103, wherein said polymer includes a compound selected from the group consisting of vinylpyrrolidone homo- and copolymers, acrylamide homo-and copolymers, polyvinylalcohol and polyvinylacetate homo- and copolymers, quaternary acrylate and methacrylate copolymers, amphoteric acrylate and methacrylate homo- and copolymers, and mixtures thereof.
106. The method as defined in claim 105, wherein said polymer includes a compound selected from the group consisting of polyvinylpyrrolidone compound, quaternary acrylic copolymer, and mixtures thereof.
107. The method as defined in claim 99, further including a solvent.
108. The method as defined in claims 107, wherein said improved cleaning composition includes a dual boiling point solvent solution, one of said solvent compounds having a boiling point of less than about 150°C and another solvent compound has a boiling point of at least about 150°C.
109. The method as defined in claims 99, wherein said improved cleaning composition further includes at least an effective amount of a second surfactant.
110. The method as defined in claim 109, wherein said second surfactant includes compound that increases the wetting properties of said improved cleaning composition.
111. The method as defined in claim 110, wherein said second surfactant includes a fluorosurfactant.
CA2482306A 2001-08-24 2002-08-21 Improved cleaning composition Expired - Fee Related CA2482306C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2736045A CA2736045C (en) 2001-08-24 2002-08-21 Cleaning wipe with biocidal activity

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09/939,383 US20030109411A1 (en) 2001-08-24 2001-08-24 Bactericidal cleaning wipe
US09/939,179 2001-08-24
US09/939,179 US20020183233A1 (en) 2000-12-14 2001-08-24 Bactericidal cleaning wipe
US09/939,383 2001-08-24
PCT/US2002/027032 WO2003018732A1 (en) 2001-08-24 2002-08-21 Improved cleaning composition

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA2736045A Division CA2736045C (en) 2001-08-24 2002-08-21 Cleaning wipe with biocidal activity

Publications (2)

Publication Number Publication Date
CA2482306A1 true CA2482306A1 (en) 2003-03-06
CA2482306C CA2482306C (en) 2011-10-18

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Application Number Title Priority Date Filing Date
CA2482306A Expired - Fee Related CA2482306C (en) 2001-08-24 2002-08-21 Improved cleaning composition

Country Status (3)

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EP (1) EP1419229A4 (en)
CA (1) CA2482306C (en)
WO (1) WO2003018732A1 (en)

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