CA2453424A1 - Polyvinylidene fluoride composites and methods for preparing same - Google Patents
Polyvinylidene fluoride composites and methods for preparing same Download PDFInfo
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- CA2453424A1 CA2453424A1 CA002453424A CA2453424A CA2453424A1 CA 2453424 A1 CA2453424 A1 CA 2453424A1 CA 002453424 A CA002453424 A CA 002453424A CA 2453424 A CA2453424 A CA 2453424A CA 2453424 A1 CA2453424 A1 CA 2453424A1
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- 239000002033 PVDF binder Substances 0.000 title claims abstract 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 title claims abstract 7
- 238000000034 method Methods 0.000 title claims 19
- 150000002222 fluorine compounds Chemical class 0.000 title 1
- 239000002131 composite material Substances 0.000 claims abstract 88
- 239000002071 nanotube Substances 0.000 claims abstract 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 23
- 229920000642 polymer Polymers 0.000 claims abstract 17
- 229920001577 copolymer Polymers 0.000 claims abstract 12
- 239000002041 carbon nanotube Substances 0.000 claims abstract 11
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract 11
- 239000007788 liquid Substances 0.000 claims abstract 5
- 239000002904 solvent Substances 0.000 claims abstract 5
- 230000001376 precipitating effect Effects 0.000 claims abstract 4
- 239000000839 emulsion Substances 0.000 claims abstract 3
- 238000001035 drying Methods 0.000 claims abstract 2
- 238000001914 filtration Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims 16
- 229910052799 carbon Inorganic materials 0.000 claims 9
- 239000000945 filler Substances 0.000 claims 6
- -1 polypropylene, chlorotrifluoroethylene, tetrafluoroethylene Polymers 0.000 claims 6
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims 5
- 239000004793 Polystyrene Substances 0.000 claims 5
- 150000001336 alkenes Chemical class 0.000 claims 5
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims 5
- 229920002223 polystyrene Polymers 0.000 claims 5
- 229920001897 terpolymer Polymers 0.000 claims 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000010439 graphite Substances 0.000 claims 3
- 229910002804 graphite Inorganic materials 0.000 claims 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims 1
- 244000309464 bull Species 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229940113088 dimethylacetamide Drugs 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 238000004890 malting Methods 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/212—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase and solid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/742—Carbon nanotubes, CNTs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/788—Of specified organic or carbon-based composition
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Conductive Materials (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
An electrically conductive composite comprising a polyvinylidene fluoride polymer or copolymer and carbon nanotubes is provided. Preferably, carbon nanotubes may be present in the range of about 0.5-20% by weight of the composite. The composites are prepared by dissolving the polymer in a first solvent to form a polymer solution and then adding the carbon nanotubes into the solution. The solution is mixed using an energy source such as a sonicator or a Waring blender. A precipitating component is added to precipitate out a composite comprising the polymer and the nanotubes. The composite is isolated by filtering the solution and drying the composite. The composites are also prepared by mixing or dispersing carbon nanotubes in polymer emulsion using an energy source such as a Waring blender. The liquid in the mixture is then evaporated to obtain the composite comprising the polymer and the nanotubes.
Claims (62)
1. A polymer composite comprising:
polyvinylidene fluoride; and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
polyvinylidene fluoride; and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
2. The composite of claim 1, wherein the nanotubes comprise carbon fibrils having:
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about
3.5 and 70 nanometers; and a distinct inner core region, each of the layers and the core being disposed substantially concentrically about the cylindrical axis of the fibrils, said fibrils being substantially free of pyrolytically deposited thermal carbon.
3. The composite of claim 1, wherein the nanotubes comprise singled walled carbon fibrils.
3. The composite of claim 1, wherein the nanotubes comprise singled walled carbon fibrils.
4. The composite of claim 1, wherein the nanotubes are present in an amount between about 0.5 to 20% by weight of the composite.
5. The composite of claim 1, wherein the nanotubes are present in an amount between about 1 to 15% by weight of the composite.
6. The composite of claim 1, wherein the nanotubes are present in an amount between about 13 to 20% by weight of the composite.
7. The composite of claim 1, wherein said composite has a bulk resistivity of less than about 10 ohm-cm.
8. The composite of claim 1, wherein said composite has a bulk resistivity of less than about 1 ohm-cm.
9. The composite of claim 1, wherein said composite has a bulk resistivity of between about 0.02 and 0.08 ohm-cm.
10. The composite of claim 1, wherein said composite has a bulk resistivity within the bulk resistivity range of a pure carbon nanotube mat.
11. The composite of claim 1, further comprising a filler.
12. The composite of claim 12, wherein said filler is graphite.
13. A polymer composite comprising:
a copolymer of vinylidene fluoride and another monomer, and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
a copolymer of vinylidene fluoride and another monomer, and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
14. The composite of claim 13, wherein said monomer is selected from the group consisting of hexafluoropropylene, polystyrene, polypropylene, chlorotrifluoroethylene, tetrafluoroethylene, terpolymers and olefins.
15. The composite of claim 13, wherein said monomer is present in an amount less than about 90% by weight of said copolymer.
16. The composite of claim 15, wherein said monomer is present in an amount between about 1 to 70 % by weight of said copolymer.
17. The composite of claim 16, wherein said monomer is present in an amount between about 10 to 50% by weight of said copolymer.
18. The composite of claim 13, wherein the nanotubes comprise carbon fibrils having:
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about 3.5 and 70 nanometers; and a distinct inner core region, each of the layers and the core being disposed substantially concentrically about the cylindrical axis of the fibrils, said fibrils being substantially free of pyrolytically deposited thermal carbon.
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about 3.5 and 70 nanometers; and a distinct inner core region, each of the layers and the core being disposed substantially concentrically about the cylindrical axis of the fibrils, said fibrils being substantially free of pyrolytically deposited thermal carbon.
19. The composite of claim 13, wherein the nanotubes comprise singled walled carbon fibrils.
20. The composite of claim 13, wherein the nanotubes are present in an amount between about 0.5 to 20% by weight of the composite.
21. The composite of claim 13, wherein the nanotubes are present in an amount between about 1 to 15% by weight of the composite.
22. The composite of claim 13, wherein the nanotubes are present in an amount between about 13 to 20% by weight of the composite.
23. The composite of claim 13, wherein said composite has a bulk resistivity of less than about 10 ohm-cm.
24. The composite of claim 13, wherein said composite has a bulk resistivity of less than about 1 ohm-cm.
25. The composite of claim 13, wherein said composite has a bulk resistivity of between about 0.02 and 0.08 ohm-cm.
26. The composite of claim 13, wherein said composite has a bulk resistivity within the bulk resistivity range of a pure carbon nanotube mat.
27. The composite of claim 13, further comprising a filler.
28. The composite of claim 27, wherein said filler is graphite.
29. A polymer composite comprising:
a compound comprising a mixture of at least two substances selected from the group consisting of polyvinylidene fluoride, copolymer of vinylidene fluoride and another monomer, and another polymer; and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
a compound comprising a mixture of at least two substances selected from the group consisting of polyvinylidene fluoride, copolymer of vinylidene fluoride and another monomer, and another polymer; and carbon nanotubes in an amount from about 0.01 to 30% by weight of said composite, wherein said nanotubes have a diameter less than about 100 nanometers.
30. The composite of claim 29, wherein said monomer is selected from the group consisting of hexafluoropropylene, polystyrene, polypropylene, chlorotrifluoroethylene, tetrafluoroethylene, terpolymers and olefins.
31. The composite of claim 29, wherein said monomer is present in an amount less than about 90% by weight of said copolymer.
32. The composite of claim 29, wherein said monomer is present in an amount between about 1 to 70 % by weight of said copolymer.
33. The composite of claim 29, wherein said monomer is present in an amount between about 10 to 50% by weight of said copolymer.
34. The composite of claim 29, wherein the nanotubes comprise carbon fibrils having:
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about 3.5 and 70 nanometers; and a distinct inner core region, each of the layers and the core being disposed substantially concentrically about the cylindrical axis of the fibrils, said fibrils being substantially free of pyrolytically deposited thermal carbon.
a substantially constant diameter;
a length greater than about 5 times the diameter;
an ordered outer region of catalytically grown, multiple, substantially continuous layers of ordered carbon atoms having an outside diameter between about 3.5 and 70 nanometers; and a distinct inner core region, each of the layers and the core being disposed substantially concentrically about the cylindrical axis of the fibrils, said fibrils being substantially free of pyrolytically deposited thermal carbon.
35. The composite of claim 29, wherein the nanotubes comprise singled walled carbon fibrils.
36. The composite of claim 29, wherein the nanotubes are present in an amount between about 0.5 to 20% by weight of the composite.
37. The composite of claim 29, wherein the nanotubes are present in an amount between about 1 to 15% by weight of the composite.
38. The composite of claim 29, wherein the nanotubes are present in an amount between about 13 to 20% by weight of the composite.
39. The composite of claim 29, wherein said composite has a bulk resistivity of less than about 10 ohm-cm.
40. The composite of claim 29, wherein said composite has a bulk resistivity of less than about 1 ohm-cm.
41. The composite of claim 29, wherein said composite has a bulk resistivity of between about 0.02 and 0.08 ohm-cm.
42. The composite of claim 29, wherein said composite has a bulk resistivity within the bulls resistivity range of a pure carbon nanotube mat.
43. The composite of claim 29, further comprising a filler.
44. The composite of claim 43, wherein said filler is graphite.
45. A method for preparing an electrically conductive composite comprising the steps of:
(a) dissolving a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer in a solvent to form a solution;
(b) dispersing nanotubes in said solution; and (c) adding a precipitating component into said solution to precipitate a composite comprising said polymer and said nanotubes.
(a) dissolving a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer in a solvent to form a solution;
(b) dispersing nanotubes in said solution; and (c) adding a precipitating component into said solution to precipitate a composite comprising said polymer and said nanotubes.
46. The method of claim 42, further comprising the step of filtering said solution to isolate said composite.
47. The method of claim 42, further comprising the step of drying said composite.
48. The method of claim 42, wherein said dispersing step is performed with a sonicator or an ultrasonic sonifier.
49. The method of claim 42, wherein said solvent is acetone.
50. The method of claim 42, wherein said solvent is selected from the group consisting of tetrahydrofuran, methyl ethyl ketone, dimethyl formamide, dimethyl acetamide, tetramethyl urea, dimethyl sulfoxide, trimethyl phosphate, pyrrolidone, butyrolacetone, isophorone, and carbitor acetate.
51. The method of claim 42, wherein said precipitating component is water.
52. The method of claim 42, wherein said monomer is selected from the group consisting of hexafluoropropylene, polystyrene, polypropylene, chlorotrifluoroethylene, tetrafluoroethylene, terpolymers or olefins.
53. An electrically conductive composite made by the method of claim 42.
54. A method for malting bipolar plates comprising the steps of:
(a) dissolving a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer in a solvent to form a solution;
(b) dispersing said nanotubes in said solution;
(c) adding a precipitating component into said solution to precipitate out a composite comprising said polymer and said nanotubes;
(d) isolating said composite;
(e) extruding said composite; and (f) engraving one or more flow channels on said composite.
(a) dissolving a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer in a solvent to form a solution;
(b) dispersing said nanotubes in said solution;
(c) adding a precipitating component into said solution to precipitate out a composite comprising said polymer and said nanotubes;
(d) isolating said composite;
(e) extruding said composite; and (f) engraving one or more flow channels on said composite.
55. The method of claim 54, wherein said monomer is selected from the group consisting of hexafluoropropylene, polystyrene, polypropylene, chlorotrifluoroethylene, tetrafluoroethylene, terpolymers or olefins.
56. A method for preparing an electrically conductive composite comprising the steps of:
(a) mixing carbon nanotubes with a polymer emulsion, said emulsion comprising a liquid and a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer;
and (b) removing said liquid to form a composite comprising said nanotubes and said polymer.
(a) mixing carbon nanotubes with a polymer emulsion, said emulsion comprising a liquid and a polymer selected from the group consisting of polyvinylidene fluoride and copolymer of vinylidene fluoride and another monomer;
and (b) removing said liquid to form a composite comprising said nanotubes and said polymer.
57. The method of claim 56, wherein the liquid is water.
58. The method of claim 56, wherein said removing step is performed by evaporating said liquid.
59. The method of claim 56, wherein said mixing step is performed with a high shear blender.
60. The method of claim 56, wherein said mixing step is performed with a blaring blender.
61. The method of claim 56, wherein said monomer is selected from the group consisting of hexafluoropropylene, polystyrene, polypropylene, chlorotrifluoroethylene, tetrafluoroethylene, terpolymers or olefins.
62. An electrically conductive composite made by the method of claim 56.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/903,189 | 2001-07-11 | ||
| US09/903,189 US6783702B2 (en) | 2001-07-11 | 2001-07-11 | Polyvinylidene fluoride composites and methods for preparing same |
| US09/988,973 US6746627B2 (en) | 2001-07-11 | 2001-11-20 | Methods for preparing polyvinylidene fluoride composites |
| US09/988,973 | 2001-11-20 | ||
| PCT/US2002/021754 WO2003007314A1 (en) | 2001-07-11 | 2002-07-10 | Polyvinylidene fluoride composites and methods for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2453424A1 true CA2453424A1 (en) | 2003-01-23 |
| CA2453424C CA2453424C (en) | 2011-01-04 |
Family
ID=27129350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2453424A Expired - Fee Related CA2453424C (en) | 2001-07-11 | 2002-07-10 | Polyvinylidene fluoride composites and methods for preparing same |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1415309A4 (en) |
| JP (1) | JP2005500409A (en) |
| KR (1) | KR100912147B1 (en) |
| CA (1) | CA2453424C (en) |
| MX (1) | MXPA04000240A (en) |
| WO (1) | WO2003007314A1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6680016B2 (en) * | 2001-08-17 | 2004-01-20 | University Of Dayton | Method of forming conductive polymeric nanocomposite materials |
| JP5092197B2 (en) * | 2002-10-29 | 2012-12-05 | ダイキン工業株式会社 | Fluorine-containing resin composition, fluorine-containing molded article, fluorine-containing layer-containing laminate and method of using fluorine-containing layer-containing laminate |
| JP4489558B2 (en) | 2004-10-25 | 2010-06-23 | 三桜工業株式会社 | Multi-layer resin tube |
| JP5228486B2 (en) | 2005-06-24 | 2013-07-03 | ダイキン工業株式会社 | Polymer composite material |
| US7732029B1 (en) | 2006-12-22 | 2010-06-08 | Xerox Corporation | Compositions of carbon nanotubes |
| JP2008163081A (en) * | 2006-12-27 | 2008-07-17 | Fujifilm Corp | Laser-decomposable resin composition and pattern-forming material and laser-engravable flexographic printing plate precursor using the same |
| US9041228B2 (en) * | 2008-12-23 | 2015-05-26 | Micron Technology, Inc. | Molding compound including a carbon nano-tube dispersion |
| JP2010155953A (en) * | 2009-01-05 | 2010-07-15 | National Institute Of Advanced Industrial Science & Technology | Structure composed of filler and non-compatible resin or elastomer, method for producing the same, and use of the same |
| KR101281626B1 (en) | 2010-05-28 | 2013-07-04 | 부산대학교 산학협력단 | Method of manufacturing polymer/carbon nanotube composite, Method of manufacturing polymer/carbon nanotube composite thin film using the same, Polymer/carbon nanotube composite using the method, and Polymer/carbon nanotube composite thin film using the method |
| US9463977B2 (en) | 2012-07-31 | 2016-10-11 | Raytheon Company | Sacrificial limiter filter |
| US10685763B2 (en) * | 2016-01-19 | 2020-06-16 | Xerox Corporation | Conductive polymer composite |
| EP3881379A1 (en) | 2018-11-12 | 2021-09-22 | Fischer Eco Solutions GmbH | Method for bonding two plates together for a fuel cell, especially gluing bipolar plates in a fuel cell |
| KR102430316B1 (en) * | 2020-08-20 | 2022-08-10 | 최재훈 | Fluororesin tube with high thermal conductivity and low gas permeability |
| KR20220055334A (en) * | 2020-10-26 | 2022-05-03 | 주식회사 엘지화학 | Method for preparation of poly(butylene adipate-co-terephthalate)-carbon nanotube composite |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6403696B1 (en) * | 1986-06-06 | 2002-06-11 | Hyperion Catalysis International, Inc. | Fibril-filled elastomer compositions |
| US5445327A (en) * | 1989-07-27 | 1995-08-29 | Hyperion Catalysis International, Inc. | Process for preparing composite structures |
| US5591382A (en) | 1993-03-31 | 1997-01-07 | Hyperion Catalysis International Inc. | High strength conductive polymers |
| US5705120A (en) | 1994-02-08 | 1998-01-06 | Osaka Gas Company, Limited | Method of producing graphite fiber-reinforced fluororesin composites |
| DE19507025A1 (en) * | 1995-03-01 | 1996-09-05 | Huels Chemische Werke Ag | Multi-layer pipe with an electrically conductive inner layer |
| JP2002070938A (en) * | 2000-08-25 | 2002-03-08 | Shimadzu Corp | Piezoelectric damping material |
| CN1189512C (en) * | 2003-02-28 | 2005-02-16 | 清华大学 | High-dielectric composite material containing carbon nanotube and its prepn process |
-
2002
- 2002-07-10 WO PCT/US2002/021754 patent/WO2003007314A1/en active Application Filing
- 2002-07-10 KR KR1020047000483A patent/KR100912147B1/en not_active IP Right Cessation
- 2002-07-10 MX MXPA04000240A patent/MXPA04000240A/en active IP Right Grant
- 2002-07-10 EP EP02749893A patent/EP1415309A4/en not_active Withdrawn
- 2002-07-10 CA CA2453424A patent/CA2453424C/en not_active Expired - Fee Related
- 2002-07-10 JP JP2003512990A patent/JP2005500409A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA04000240A (en) | 2004-05-04 |
| WO2003007314A1 (en) | 2003-01-23 |
| KR100912147B1 (en) | 2009-08-14 |
| JP2005500409A (en) | 2005-01-06 |
| EP1415309A4 (en) | 2006-06-21 |
| KR20040030044A (en) | 2004-04-08 |
| CA2453424C (en) | 2011-01-04 |
| EP1415309A1 (en) | 2004-05-06 |
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