CA2435763A1 - Fuel cell system - Google Patents

Fuel cell system Download PDF

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Publication number
CA2435763A1
CA2435763A1 CA002435763A CA2435763A CA2435763A1 CA 2435763 A1 CA2435763 A1 CA 2435763A1 CA 002435763 A CA002435763 A CA 002435763A CA 2435763 A CA2435763 A CA 2435763A CA 2435763 A1 CA2435763 A1 CA 2435763A1
Authority
CA
Canada
Prior art keywords
fuel cell
heat exchanger
cell system
cell stack
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002435763A
Other languages
French (fr)
Inventor
Manfred Poppinger
Joachim Grosse
Rolf Bruck
Meike Reizig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Vitesco Technologies Lohmar Verwaltungs GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2435763A1 publication Critical patent/CA2435763A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2484Details of groupings of fuel cells characterised by external manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20Fuel cells in motive systems, e.g. vehicle, ship, plane
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029Heat exchange using liquids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04037Electrical heating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04052Storage of heat in the fuel cell system
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40Application of hydrogen technology to transportation, e.g. using fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to a fuel cell system comprising at least one fuel cell stack and means, which are provided for preheating the supply air and which have a heat exchanger. According to the invention, the heat exchanger has, at least in one dimension of the planar arrangement, the same length as the fuel cell stack. This permits the heat exchanger (30) and the fuel cell stack (10) to be easily arranged one behind the other and to be advantageously accommodated inside a shared housing (100).

Description

Description Fuel cell system The invention relates to a fuel cell system having at least one fuel cell stack comprising individual fuel cells and air-guiding passages arranged between the fuel cells and means for preheating the feed air which include a heat exchanger.
Numerous forms of fuel cell facilities for supplying energy to electric motor drives for motor vehicles are known. A common feature of these different fuel cell facilities is the chemical reaction between hydrogen and oxygen to form water. However, gaseous hydrogen cannot be stored on board in a quantity which is sufficient for prolonged driving operation.
For example, the PEM fuel cell (polymer electrolyte membrane, proton exchange membrane), which operate with a proton-conducting membrane, uses gasoline, methanol or another higher hydrocarbon from which hydrogen-rich gas is obtained as fuel gas by means of a reformer and with oxygen from the ambient air. In particular the HT-PEM fuel cell, which operates at relatively high temperatures, is per se insensitive to impurities, which is true in particular of the fuel gas. The oxidizing agent is obtained from ambient air; in principle, the starting point is normal ambient air which, for example, can be taken from the slip stream of a moving vehicle . The ambient air is generally at a significantly lower temperature than the fuel cell.
When the cold air is [inaudible] into the fuel cell, the fuel cell may be damaged in particular at the air inlet.
Therefore, a heat exchanger, which in particular provides the thermal energy for preheating the feed air, is crucial for operation of a fuel cell system of this type in a motor vehicle.
US 6,106,964 A has disclosed a method for humidifying and controlling the temperature of a process gas for a solid polymer fuel cell, in which a heat exchanger comprising two plates is arranged in direct thermal contact on a fuel cell stack. furthermore, JP 09-204924 has disclosed a fuel cell stack comprising individual coated fuel cells in which each individual fuel cell unit is closed off by a cooling board with a coolant line arranged therein. The cooling board has the same dimensions as an individual fuel cell unit.
Working on the basis of the above prior art, it is an object of the invention to assign a heat exchanger of complex design to the fuel cell stack of a fuel cell system in a suitable way.
According to the invention, the object is achieved by the characterizing features of patent claim 1.
Refinements are given in the dependent claims.
According to the invention, the heat exchanger, at least in one dimension, is of the same size as the fuel cell stack and a common edge with the fuel cell stack, the heat exchanger itself forming a stack comprising individual heat exchanger plates with heat exchanger passages which are connected, via the common edge with the fuel cell stack, to the air-feed passages of an individual fuel cell. This ensures optimum guidance of air.
The heat exchanger may be connected upstream of the fuel cell stack as a separate component. However, it is also possible for the heat exchanger to be arranged vertically above the fuel cell stack, in which case an 2000P20291W0 - 2a -aligned arrangement is produced on account of the identical transverse dimensions. In alternative possible arrangements, the heat exchanger and the fuel cell stack are advantageously accommodated in a common housing. The heat exchanger is of particular importance in particular in the latter case.
Further details and advantages of the invention will emerge from the following description of figures illustrating an exemplary embodiment on the basis of the drawings in conjunction with the further subclaims.
In the drawings:
Figure 1 shows a perspective illustration of a fuel cell stack with a heat exchanger aligned in front of it, and Figure 2 shows a perspective illustration of an alternative design compared to Figure 1, in which the heat exchanger is oriented vertically above the fuel cell stack.
Identical units are provided with identical reference symbols in the two figures. The figures are in part described jointly.
The starting point in both figures is a known fuel cell system which has been extensively described in other contexts. A module 10 of the fuel cell system is generally also referred to as a stack. A stack comprises a stacked arrangement of individual fuel cells 11, 11', ... of width b and height h, the overall stack width a being formed by the fuel cell stack 10.
In this case, the individual fuel cells are stacked in such a manner that there is in each case a space between two cells, through which air is passed in order to supply the cells. The individual spaces may be configured in the form of passages.
Fuel cells which operate with a solid electrolyte and are described as PEM (polymer electrolyte membrane) fuel cells are used for the fuel cell system. Fuel cells of this type are known from the prior art, and for mobile applications fuel cells of this type are advantageously operated at higher temperatures than have previously been described. Operating temperatures of between 80°C and 300°C, in particular in the range from 120°C to 200°C, are used for HT (high temperature) PEM fuel cells of this type. For practical operation, advantages are in particular the lack of influence of the humidity of the process gases, on the one hand, and the moisture of the membrane, on the other hand. The membrane used in this case is made from temperature-stable materials which hold a self-dissociating and/or 2000P20291 WO - 3a -autoprotolytic electrolyte. Furthermore, reduced demands are imposed on the purity of the process gas.

In particular, CO impurity levels of up to approx.
10.000 ppm are tolerated.
To maintain the optimum operating temperature, the fuel module is cooled. Cooling is effected, for example, using a liquid medium, e.g. a suitable oil. This fluid is fed to a heat exchanger 30 and thereby heats the feed air.
The heat exchanger 30 is designed as a plate-type heat exchanger with individual plates 31, 31', .... The plates 31, 31', ... are arranged at a distance from one another, so that a space through which the air is guided is formed. The fluid of the heat exchanger 30 is guided in the plates 31, 31', .... The space between the plates 31, 31' ... can in turn be configured in the form of passages .
In both Figures 1 and 2, the heat exchanger 30 described is in each case connected upstream of the fuel cell module 10. The way in which the fluid is guided is indicated. If the heat exchanger 30 has the same dimension a as the stack width of the fuel cell module 10 perpendicular to the surface of the individual cells 11, 11', ..., the heat exchanger 30 can be assigned to the fuel cell module 10 in such a manner that it is aligned therewith in at least one dimension, as shown in Figure 1.
In accordance with Figure 1, the plates 31, 31', ... of the heat exchanger 30 are aligned with respect to the cells 11, 11, ... of the fuel cell module 10. The cooling air is supplied from the front side and, after it has flowed through the heat exchanger 30, is diverted onto the fuel cell stack 10 by means of a suitably arranged plate 20. Therefore, in particular in the case of a self-aspirating fuel cell system, the air which has been preheated after it has flowed 2000P20291 WO - 4a -through the heat exchanger 30 can be fed to the individual fuel cells 11, 11' over their area.

However, as shown in Figure 2, it is also possible for the heat exchanger 30 to be arranged above the fuel cell module 11, 11', .... This is expedient if cell cooling and heat exchanger function are to be integrated in a single component. The air which flows in at the front is in this case diverted before it flows into the arrangement. In this case, the cooling medium successively flows through the heat exchanger 20 and the fuel cell stack 10 in the same direction.
Consequently, the cooling medium of the fuel cells 11, 11', ... therefore serves as a heat transfer medium for the heat exchanger 30. The fuel cell module 10 and the heat exchanger 30 are advantageously arranged in a common housing 100.
In both arrangements, corresponding to Figure 1 or Figure 2, it is advantageous if the spaces or passages formed by the heat exchanger plates 31, 31' ... of the heat exchanger 30 and the spaces or passages formed by the fuel cells 11, 11', ... adjoin one another seamlessly. This makes the system easy to assemble.
In further exemplary embodiments which supplement or modify Figures 1 or 2, the heat exchanger 30 may be assigned to the fuel cell stack 10 together with an evaporator and/or a condenser. The heat exchanger 30 may be electrically heated. Furthermore, the heat exchanger 30 may be assigned a latent heat store. In this case, the heat exchanger serves as a mixer for rectifying the flow of the incoming air.
It has been found that the arrangements described operate particularly advantageously in combination with PEM fuel cells. In particular if fuel cells of this type are operated at elevated temperatures, i.e. the individual fuel cell works as what is known as an HT-PEM fuel cell, the heat exchanger having the properties described is highly advantageous for disruption-free operation of the system as a whole.

Claims (12)

Claims
1. A fuel cell system having at least one fuel cell stack and air-feed passages, which are arranged between the fuel cells, for feed air, and means for preheating the feed air, which includes a heat exchanger, in which system the heat exchanger (30), at least in one dimension, is of the same size as the fuel cell stack, the heat exchanger (30) forming a stack of individual heat exchanger plates (31, 31', ...) with heat exchanger passages which are connected, via the at least one common edge between the heat exchanger (30) and the fuel cell stack (10), to the air-feed passages of an individual fuel cell (11, 11', ...).
2. The fuel cell system as claimed in claim 1, characterized in that heat exchanger (30) and the fuel cell stack (10) have at least one identical cross-sectional area.
3. The fuel cell system as claimed in claim 1 or claim 2, characterized in that heat exchanger (30) and the fuel cell stack (10) in functional terms are connected in series.
4. The fuel cell system as claimed in claim 1, characterized in that the heat exchanger passages (31, 31', ...) of the heat exchanger (30) have the same dimensions as the air-feed passages of the fuel cells (11, 11', ...) and therefore the same cross section of flow.
5. The fuel cell system as claimed in one of the preceding claims, characterized in that the heat exchanger (30) and the fuel cell stack (10) are arranged in a common housing (100).
6. The fuel cell system as claimed in one of the preceding claims, characterized in that the heat exchanger (30) is connected up to the fuel cell stack (10) together with an evaporator and/or a condenser.
7. The fuel cell system as claimed in one of the preceding claims, characterized in that the heat exchanger (30) is electrically heated.
8. The fuel cell system as claimed in one of the preceding claims, characterized in that the heat exchanger (30) includes a latent heat store.
9. The fuel cell system as claimed in one of the preceding claims, characterized in that the heat exchanger (30) acts as a mixer for rectifying the flow of air.
10. The fuel cell system as claimed in one of the preceding claims, characterized in that the cooling medium of the fuel cells (11, 11', ...) is used as a heat transfer medium for the heat exchanger (30).
11. The fuel cell system as claimed in one of the preceding claims, characterized in that the fuel cell stack (10) includes PEM fuel cells (11, 11', ...).
12. The fuel cell system as claimed in one of the preceding claims, characterized in that the fuel cell stack (10) includes HT-PEM fuel cells (11, 11', ...).
CA002435763A 2000-12-29 2001-12-21 Fuel cell system Abandoned CA2435763A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10065308A DE10065308A1 (en) 2000-12-29 2000-12-29 fuel cell plant
DE10065308.1 2000-12-29
PCT/DE2001/004886 WO2002054518A1 (en) 2000-12-29 2001-12-21 Fuel cell system

Publications (1)

Publication Number Publication Date
CA2435763A1 true CA2435763A1 (en) 2002-07-11

Family

ID=7669198

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002435763A Abandoned CA2435763A1 (en) 2000-12-29 2001-12-21 Fuel cell system

Country Status (6)

Country Link
US (1) US20040076862A1 (en)
EP (1) EP1354365A1 (en)
KR (1) KR20030078878A (en)
CA (1) CA2435763A1 (en)
DE (2) DE10065308A1 (en)
WO (1) WO2002054518A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052620A1 (en) * 2007-10-22 2009-04-30 Hydrogenics Corporation Racked power supply ventilation

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005040615A1 (en) * 2005-08-27 2007-03-01 Behr Gmbh & Co. Kg Heat transmitter-device for motor vehicle, has heat transmitters that are interconnected so that hydrogen and cooling agent flow through transmitters, where heat transfer takes place between hydrogen flowing in respective regions
US7923162B2 (en) * 2008-03-19 2011-04-12 Dana Canada Corporation Fuel cell assemblies with integrated reactant-conditioning heat exchangers
DE102011086799A1 (en) * 2011-11-22 2013-05-23 Robert Bosch Gmbh System with a hand tool case and a hand tool battery
US9819044B2 (en) * 2013-11-04 2017-11-14 Bosal Emission Control Systems Nv Apparatus comprising a fuel cell unit and a component, and a stack component for use in such an apparatus

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3576677A (en) * 1967-05-23 1971-04-27 United Aircraft Corp Fuel cell process air control
US3935028A (en) * 1971-06-11 1976-01-27 Siemens Aktiengesellschaft Fuel cell set and method
JP3202292B2 (en) * 1992-01-10 2001-08-27 大阪瓦斯株式会社 Fuel cell power generation system
JPH06103994A (en) * 1992-09-21 1994-04-15 Toshiba Corp Fuel cell power generating system
JPH09204924A (en) * 1996-01-25 1997-08-05 Tanaka Kikinzoku Kogyo Kk Method for humidifying gas of pem type fuel cell and gas humidifier
CA2242176C (en) * 1997-06-30 2009-01-27 Ballard Power Systems Inc. Solid polymer fuel cell system and method for humidifying and adjusting the temperature of a reactant stream
DE19900166C1 (en) * 1999-01-05 2000-03-30 Siemens Ag Liquid-cooled fuel-cell battery with integrated heat exchanger
US6864005B2 (en) * 2000-03-08 2005-03-08 Ballard Power Systems Inc. Membrane exchange humidifier for a fuel cell

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052620A1 (en) * 2007-10-22 2009-04-30 Hydrogenics Corporation Racked power supply ventilation
US8241810B2 (en) 2007-10-22 2012-08-14 Hydrogenics Corporation Racked power supply ventilation
US8563196B2 (en) 2007-10-22 2013-10-22 Hydrogenics Corporation Racked power supply ventilation

Also Published As

Publication number Publication date
KR20030078878A (en) 2003-10-08
DE10065308A1 (en) 2002-07-11
US20040076862A1 (en) 2004-04-22
DE10195796D2 (en) 2004-04-15
WO2002054518A1 (en) 2002-07-11
EP1354365A1 (en) 2003-10-22

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Legal Events

Date Code Title Description
FZDE Discontinued