CA2397440C - Sprayer - Google Patents

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Publication number
CA2397440C
CA2397440C CA002397440A CA2397440A CA2397440C CA 2397440 C CA2397440 C CA 2397440C CA 002397440 A CA002397440 A CA 002397440A CA 2397440 A CA2397440 A CA 2397440A CA 2397440 C CA2397440 C CA 2397440C
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CA
Canada
Prior art keywords
discharge nozzle
sprayer
collision
collision plate
spraying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002397440A
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French (fr)
Other versions
CA2397440A1 (en
Inventor
Takaharu Tasaki
Shigeru Hayakawa
Mitsuhiro Sasazaki
Chitoshi Okawara
Seiichi Watanabe
Shigeru Akutsu
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Yoshino Kogyosho Co Ltd
Original Assignee
Yoshino Kogyosho Co Ltd
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Filing date
Publication date
Priority claimed from JP33092394A external-priority patent/JP3566368B2/en
Application filed by Yoshino Kogyosho Co Ltd filed Critical Yoshino Kogyosho Co Ltd
Publication of CA2397440A1 publication Critical patent/CA2397440A1/en
Application granted granted Critical
Publication of CA2397440C publication Critical patent/CA2397440C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

A sprayer for spraying foamable liquid in the foamed state, comprises a discharge nozzle, and a swirling passage disposed at an upstream side of the discharge nozzle to communicate therewith for swirling the liquid. A
gas-liquid mixing passage is concentrically disposed to communicate with the downstream side of said discharge nozzle. An air inlet allows air to enter into the gas-liquid mixing passage. A collision plate having collision portion and a flow opening is disposed at the downstream side of the gas-liquid mixing passage to face said discharge nozzle. The collision plate is allowed to get away from a position in front of said discharge nozzle. The discharge nozzle, swirling passage, gas-liquid mixing passage, and air inlet are on a front end member to which said collision plate is pivotably mounted.

Description

This is a division of our co-pending Canadian Patent Application No. 2,181,820 dated 5th December 1995.
The present invention relates to a sprayer for spraying liquid, such as liquid detergent and insecticide contained in a container, in the atomized state or foamed state.
There are several kinds of sprayers as disclosed in, for example, Japanese Utility Model Application Laid-Open No. 63-20970 (1988), Japanese Utility Model Application Laid-Open No. 64-12668 (1989), and Japanese Utility Model Publication No. 62-770 (1987). Such sprayers are of a so-called trigger-type. That is, such sprayers are each provided with a trigger energized (force-applied) forward by a coil spring, wherein the trigger can be pulled against elastic force of the coil spring to pressurize liquid in a pump chamber with a piston and to atomize the liquid, and then the trigger and the piston are returned by the elastic force of the coil spring to pump up liquid in the container into the pump chamber.
However, such a conventional sprayer has a problem of installing the coil spring into the sprayer while assembling the sprayer. That is, it is sometimes difficult to insert the coil spring to a hold opening for holding the coil spring because the axis of the coil spring is hard to coincide with the axis of the hold opening. Further, when the coil spring is inserted into the hold opening with the axes not coinciding with each other, the inner surface of the hold opening is sometimes scratched. Then, the coil spring touches the scratch during expansion and contraction of the coil spring, thereby disturbing the smooth expansion and contraction of the coil spring. One of the objects of the present invention is to solve this problem.
As one of the sprayers, a sprayer for foam-spraying liquid is disclosed in, for example, Japanese Patent Publication No. 62-59635 (1987). A conventional sprayer of this type sprays the liquid in a constant foaming state.
That is, the sprayer can not change the foaming state for spraying. However, it may be convenient to change its foaming state in the practical use. One of the objects of the present invention is therefore to easily change its foaming state.
Furthermore, the present applicant has proposed a sprayer having a nozzle cover, which is disposed at the tip end of the spraying member having a spraying outlet at the front and center thereof to cover the spraying outlet and, the end of which is pivotably mounted to the upper end of the spraying member, wherein the sprayer is provided with holding means for holding the nozzle cover not to allow the nozzle cover to be opened while closing the spraying outlet (Japanese Patent Application No. 6-27759 (1994)).
This sprayer can make the spraying outlet held in its closed state while not spraying. When the sprayer .n t ,.Y~"I".n.. ....,I m-.I~n.ien.rr,~.,...~.1~..~
sprays with the nozzle cover held upwardly apart from the spraying outlet, however, there is a possibility of inadvertently pivoting the nozzle cover downward to block the spray. As the nozzle cover blocks the spray, the sprayed particles may be scattered in unexpected directions.
One of the objects of the present invention is therefore to prevent the nozzle cover from inadvertently pivoting downward while spraying.
SUMMARY OF THE INVENTION
The invention provides a sprayer for spraying foamable liquid in the foamed state, comprising: (a) a discharge nozzle, (b) a swirling passage disposed at an upstream side of said discharge nozzle to communicate with said discharge nozzle for swirling the liquid, (c) a gas-liquid mixing passage concentrically disposed at a downstream side of said discharge nozzle to communicate with said discharge nozzle, (d) an air inlet for allowing air to enter into said gas-liquid mixing passage, and (e) a collision plate having a collision portion and a flow opening and disposed at a downstream side of said gas-liquid mixing passage to face said discharge nozzle, said collision plated being movable to an open position from a closed posit=ion in front of said discharge nozzle, wherein said discharge nozzle, said swirling passage, said gas-liquid mixing passage and said air inlet form a front end member, said collision plate being mounted to said front end member so as to spray said liquid in a foamed state with mutually different spray patterns in said open and closed positions.
The liquid becomes swirling flow after passing through the swirling passage and is discharged from the discharge nozzle to the gas-liquid mixing passage. At this point:, the liquid is scattered into sprayed fine particles w Li i.rrh.i r ~~~~I.r,I..~,i~ql~.h I i 3a by the centrifugal force. A negative pressure develops around the discharge nozzle by the discharge of the liquid from the discharge nozzle, thereby entering air from the air inlet to the gas-liquid mixing passage.
When the collision plate is disposed to face the discharge nozzle, part of the sprayed particles sprayed in the gas-liquid mixing passage are scattered by colliding with the gas-liquid mixing passage and the collision portion of the collision plate, and stir the flow in the gas-liquid mixing passage. As a result, the sprayed particles of the liquid and the air are mixed well in the gas-liquid mixing passage and thus become foam. The foam is mixed with the sprayed particles reached without colliding with the collision portion and discharged from the flow outlet. As mentioned above, in case of closing the collision plate, the liquid detergent is well foamed because the flow in the gas-liquid mixing passage is well stirred.
On the other hand, when the collision plate is displaced from a position in front of the discharge nozzle, the effect of stirring in the gas-liquid mixing passage is also weak and foaming is poor because the portion where the sprayed particles sprayed in the gas-liquid mixing passage may collide with is only the inner surface of the gas-liquid mixing passage.
The opened end of the air inlet is preferably disposed near the discharge nozzle because of the mixing effectiveness between the liquid and the air.
The sprayer many preferably comprise a front end member having the discharge nozzle, the swirling passage, the gas-liquid mixing passage, and the air inlet, the collision plate being pivotably mounted to the front end member.
The collision plate many comprise an extending passage for substantially extending the gas-liquid mixing passage in case of disposing the collision plate to face the discharge nozzle, and the collision portion and the flow opening are disposed at a downstream side of the extending passage. It should be noted that the collision plate in the third aspect may not have the extending passage. The collision portion of the collision plate may comprise a 5 plurality of bar-like collision walls extending toward a point on an extension of the center of the discharge nozzle, and the flow opening is disposed among the bar-like collision walls and on the extension of the center of the discharge nozzle. It should be noted that the collision portion and the flow opening in the third aspect may have structures other than those mentioned above.
The invention will further be described, by way of example only, with reference to the accompanying drawings, wherein:
Fig. 1 is a vertical sectional view of a sprayer according to Example 1;
Fig. 2 is a vertical sectional view of a pump chamber used in the sprayer according to Example 1;
Fig. 3 is a front view of a coil spring used in the sprayer according to Example 1;
Fig. 4 is a side view, partly sectioned, of the coil spring of the sprayer according to Example 1;

Fig. 5 is a front view of a modified example of the coil spring of the sprayer according to Example 1;

Fig. 6 is a vertical sectional side view of the S modified exa mple of the coil spring of the sprayer according to Example 1;

Fig. 7 is a vertical sectional view of a discharge portion of a sprayer according to Example 2, in its assembled st ate (taken along a line I-I of Fig. 8);

Fig. 8 is a front view of the discharge portion of the sprayer according to Example 2, in its assembled state;

Fig. 9 is a side view showing the sprayer of Example 2 wh en it is mcunted to a container;

Fig. 10 is a vertical sectional view cf a supporting member used in the sprayer according to Example 2 (taken along a line II-II
of Fig. 11);

Fig. 11 is a front view of the supporting member of the sprayer according to Example 2;

Fig. 12 is a vertical sectional view of a spraying member used in the sprayer according to Example 2 (taken along a line III-III of Fig. 13);

Fig. 13 is a front view of the spraying member of the sprayer according to Example 2;

Fig. 14 is a rear view of the spraying member of the sprayer according to Example 2;

Fig. 15 is a sectional view taken along a line IV-IV of Fig.
13;

Fig. 16 is a side view of a collision plate used in the sprayer according to Example 2;
Fig. 17 is a rear view of the collision plate of the sprayer according to Example 2;
Fig. 18 is a sectional view taken along a line V-V
of Fig. 17;
Fig. 19 is a view showing a spraying state of the sprayer of Example 2 when the collision plate is disposed to face a discharge nozzle;
Fig. 20 is a side view showing the deposited state of foam on a wall surface which is sprayed from the sprayer of Example 2 when the collision plate is disposed to face a discharge nozzle;
Fig. 21 is a front view showing the deposited state of the foam on the wall surface which is sprayed from the sprayer of Example 2 when the collision plate is disposed to face the discharge nozzle;
Fig. 22 is a view showing a spraying state of the sprayer of Example 2 when the collision plate is got away from a position in front of the discharge nozzle;
Fig. 23 is a side view showing the deposited state of the foam on the wall surface which is sprayed from the sprayer of Example 2 when the collision plate is got away from a position in front of the discharge nozzle;
Fig. 24 is a front view showing the deposited sl:atc-:
of the foam on the wall surface which is sprayed from the sprayer of Example 2 when the collision plate is got away from a position in front of the discharge nozzle;
Fig. 25 is a side view showing a portion of a sprayer, partly sectioned, according to Example 3;
Fig. 26 is an assembled perspective view showing the closed state of the spraying outlet in the sprayer of Example 3;
Fig. 27 is an assembled perspective view showing the opend state of the spraying outlet in the sprayer of Example 3;
Fig. 28 is an exploded perspective view of the sprayer of Example 3;
Fig. 29 is a vertical sectional view of a second holding means used in the sprayer of Example 3;
Fig. 30 is an assembled perspective view showing the closed state of the spraying outlet in the sprayer of Example 4;
Fig. 31 is an exploded perspective view of the sprayer of Example 4;
Fig. 32 is a vertical sectional view showing a main part of the sprayer of Example 4 with its spraying outlet opened;
Fig. 33 is an assembled perspective view showing the closed state of the spraying outlet in the sprayer of Example 5;
Fig. 34 is an assembled perspective view showing the opened state of the spraying outlet in the sprayer of Example 5;
Fig. 35 is an exploded perspective view of a sprayer of Example 5;
Fig. 36 is an assembled perspective view showing the closed state of the spraying outlet in the sprayer of Example 6;
Fig. 37 is an assembled perspective view showing the opened state of the apraying outlet in the sprayer of Example 6;
Fig. 38 is a perspective view of a nozzle cover used in the sprayer of Example 6;
Fig. 39 is an assembled perspective view showing the closed state of the spraying outlet of the sprayer of Example 7;
Fig. 40 is an assembled perspective view showing the opened state of the sprayer of Example 7; and Fig. 41 is a perspective view of a nozzle cover used in the sprayer of Example 7.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Hereinafter, preferred embodiments of the present invention will be described with reference to the attached drawings.
Example 1 A sprayer according to Example 1 will be described based on Fig. 1 through Fig. 6.
The sprayer of this example is of a trigger type and is mounted to the neck of a container (not shown) for use. Fig. 1 is a vertical sectional view of the sprayer which comprises a sprayer body B having an injector cylinder B~~ a supporting cylinder Bz, and a grip portion w qrr i.y~nlm.v". ...,.I,e.~.rn.,Mp~wn.lr...l..r B:" a spraying member A disposed on the front end of the sprayer body B, a discharge chamber C, a pump chamber D, a trigger E, and a mounting cap F.
The mounting cap F is attached to the lower end of 5 the supporting cylinder Bz. The sprayer is fixed to the neck of the 'container by the mounting cap F.
The discharge chamber C comprises a discharge cylinder 101 mounted in the supporting cylinder B2. The discharge cylinder 101 is provided with a suction chamber 10 103 at the lower side thereof and a discharge valve chamber lO~l at the upper side Chereof. The l.c~wr:r c:nd ot~ t_he discharge cylinder I01 is connected to a suction pipe 102 whereby the suction chamber 103 communicates with the inside of the container.
A valve seat 106 is formed on the inner wall of the suction chamber 103 and just~above the suction pipe 102, and a valve ball 105 contained in the suction chamber 103 can sit on or move apart from the valve seat 106.
In the discharge valve chamber 104, a discharge valve 107, which has an elastic deformable portion 108 engaging the upper end of the discharge valve chamber 104, is contained. The discharge valve 107 can sit on or move apart from a valve seat 109 disposed between the suction chamber 103 and the discharge valve chamber 144.
The discharge cylinder 101 is provided with an opening 110 allowing the suction chamber 103 to communicate with a cylinder chamber 129 described later, and an opening 111 allowing the discharge valve chamber 104 to communicate with a discharge passage 112 described later.
The injector cylinder B~ is provided with the discharge passage 112 communicating with the discharge valve chamber 104 through the opening 111. The spraying member A is provided with passages 113, 114 communicating with the discharge passage I12, and a spraying outlet 115 communicating with the passage 119.
The pump chamber D comprises a cylinder 120 and a piston 130. Fig. 2 is an enlarged sectional view of the pump chamber D. The cylinder 120 is provided with an outer cylinder 121, a bottom wall 122, and an inner cylinder 123 so that a cylinder chamber 124 is formed between the inner surface of the cylinder 120 and an end face 136 of the piston 130.
In the inner cylinder 123, it is provided a supporting hole 125 for holding a coil spring I40 described later therein, and a plurality of projections 125a for supporting the coil spring 140 disposed on the inner surface thereof.
The bottom wall 122 of the cylinder 120 is provided with an opening 126 communicating with the suction chamber 103 through the opening 110. The outer cylinder 121 is provided, at the lower side thereof, with an air inlet 12'7 allowing the inside of the container to communicate with the atmosphere at the end of the forward motion of the piston 130. In this specification, the expression "the foward motion of the piston 130" means that the piston 130 moves in the direction approaching the bottom wall 122 ~f the cylinder 120. The air inlet 127 communicates through the passage 117 with an opening 116 disposed in the discharge cylinder I01 at the lower side thereof, and further communicates with the container through the opening S 116.
The piston 130 is provided with a cylindrical portion 131 and a piston portion I32. The cylindrical portion 132 has a concavity 134 formed in an end 133 thereof for engaging with a trigger E, and a supporting hole 135 formed therein for supporting the coil spring 140.
The supporting hole 135 has a step 135a and a plurality of projections I35b for holding the coil spring 140 which are disposed on the inner surface thereof.
The piston portion 132 is made of an elastic material and comprises an outer slider 132a air-tightly sliding on the inner surface of the outer cylinder 121 of the cylinder 120, an inner slider 132b air-tightly sliding on the outer surface of the inner cylinder 123 of the cylinder 120, and the end face 136 facing to the~cyl=nder chamber 124.
The outer slider 132a is formed in an arch-like configuration and has diameters of the both ends thereof are set to be slightly larger than the inner diameter of the outer cylinder 121 of the cylinder 120. This is because the air-tightness of the cylinder 120 must be kept when the piston I30 is inserted into the cylinder 120. The end face 136 of the piston 130 is provided with annular grooves 136a, 136b formed therein for absorbing the deformation when the piston 130 is inserted into the cylinder 120.
The trigger E has a handle member 151, which is pivotably mounted to the injector cylinder B, at one end thereof, and a pushing piece 152 disposed on the handle member 151. The pushing piece 152 engages with the concavity 134 of the piston 130.
The coil spring 140 for elastically returning the trigger E is mounted between the cylindrical portion 131 of the piston 130 and the inner cylinder 123 of the cylinder 120.
The coil spring 140 in this example is described with reference to Fig. 3 and Fig. 4. Fig. 3 is a front view of the coil spring 140 and Fig. 4 is a partially sectioned side view of it.
The coil spring 140 comprises a coil wire 141 and is formed so that both wire end portions 142 of the coil wire 141 are in contact with the adjacent coil wire portions 144, respectively and are inwardly deflected, and a portion of each wire end portion 142 which extends in a predetermined length from each end 143 of the coil wire 141 is positioned on a plane perpendicular or nearly perpendicular to the axis P of the coil spring 140.
While the deflected portion of the wire end portion 142 is preferably positioned on a plane perpendicular to the axis, it is not necessary that the deflected portion is positioned precisely on a plane perpendicular to the axis, that is, the deflected portion may be positioned nearly perpendicular to the axis.
Fig. 3 shows a case where a portion which extends from the end 143 to have an angle 8 (hereinafter, referred to as the deflection angle 6) about the axis P of the coil spring 140 is positioned on a plane perpendicular or nearly perpendicular to the axis P of the coil spring 140, and the end 193 is deflected from the circumscribed circle of the coil wire 141 by a length s (hereinafter, referred to as the deflection length s).
There is a relation among the wire diameter of the coi 1. W re 191 , t_tm <.ic:I le:cU.i.on l enc~tt~ 5, urad Lloe d~f LecL ion angle 8. For example, when the deflection angle 8 is 90°, the deflection length s is approximately 0.66d.
As shown in Fig. 5 and Fig. 6, when the deflection angle 8 is 180°, the deflection length s is approximately 0.87d.
The coil spring 140 as structured above is quite advantageous for assembling the pump chamber D. Now, the description will be made as regard to this.
For assembling the pump chamber D, one end of the coil spring 140 is inserted into the supporting hole 135 of the piston 130 and the wire end portion 142 of the coil spring 140 is engaged with the step 135a. Since the wire end portion 142 is positioned on a plane nearly perpendicular to the axis P of the coil spring 140, the axis P of the coil spring 140 becomes substantially the same as the axis of the piston 130 by engaging the wire end portion 142 with the step 135a.

n ,p~ ~.~",i~,...~... ...Iml~~..aw.a".n..p.., Then, the piston 130 to which the coil spring 140 ~is mounted is mounted to the cylinder 120. At this point, t:he other end side of the coil spring 140 must be inserted to the supporting hole 125 of the cylinder 120 at the same 5 tame that the piston 130 is inserted to the cylinder 120.
In a case of this sprayer, the axis P of the coil spring 190 is substantially the same as the axis of the piston 130 as mentioned above, whereby the insertion of the piston 130 to the cylinder 120 and the insertion of the 10 other end side of the coil spring 190 into the supporting hole 125 can be smoothly and securely achieved at the same time. Therefore, it can prevent the incomplete installation of the coil spring.
In addition, when the other end side of the coil 15 spring 190 is inserted to the supporting hole 125 of the cylinder 120, there is no chance to scratch the inner surface of the supporting hole 125. As a result, there is also no chance to disturb the smooth expansion and contraction of the coil spring 190.
As described above, for making the assembly of the pump chamber D easy, the lager deflection angle 8 of the wire end portion 142 of the coil spring 140 is better.
Practically, the advantage as mentioned above can be obtained upon setting it to satisfy the formula: s 2 0.5d.
Hereinafter, the description will be made as regard t:o the operation of this sprayer. Upon pushing the trigger E; of the sprayer fixed to the neck of the container in the direction of teh arrow G, the pushing piece 152pushes the concavity 134 of the front end 133 of the piston 130. As a result of this, the end face 136 of the piston portion 132 moves until coming in contact with the bottom wall 122 ~f the cylinder 120 so as to push out the liquid filling the cylinder chamber I24 from the opening 126 to the suction chamber 103. Then the discharge valve 107 is pushed upwardly by the hydraulic pressure in the suction chamber 103.
The discharge valve 107 rises from the valve seat 109 according to the elastic deformation of the elastic deformable portion 108 to open valve. As a result, the liquid is entered from the suction chamber 103 into the discharge valve chamber 104 and further into the discharge passage 112 through the opening 111. Furthermore, through the passages 113, 114, the liquid is atomized from the spray output 115.
During this process, the cylindrical portion 131 of the piston 130 compresses the coil spring 140 and the valve ball 105 is seated on the valve seat 106 by the hydraulic pressure in the suction chamber 103 to close valve.
Upon completion of the spraying of the liquid from the spraying outlet 115, by releasing the trigger E from being pressed, the piston 130 is returned to the position shown in Fig. 1 by the elastic force of the coil spring 140. As a result, t:he cylinder chamber 124 becomes larc~c~r so that a negative pressure develops in the cylinder chamber 124. The negative pressure effects the discharge valve 107 and valve ball 105. That is, the negative pressure seats the discharge valve 107 on the valve seat 109 to close the valve and makes the valve ball 105 apart from the valve seat 106 to open the valve. As a result of this, the liquid in the container is sucked up to the suction chamber 103 through the suction pipe 102 and, further, charged into the cylinder chamber 129 through the openings 110, 126 in preparation for the next spraying.
The air inlet 127 formed in the outer cylinder 121 of the cylinder 120 communicates with the at=mosphere to introduce the atmosphere into the container through the passage 117 and the opening 116 when the end face 136 of the piston 130 approaches to the bottom wall 122 of the cylinder 120. After that, the air inlet 127 is designed to be closed by the outer slider 132a of the piston 130 when 1S the piston 130 is returned to the position shown in Fig. 1 thereby preventing the liquid in the container from spilling out from the air inlet 127 even when the container is toppled.
Though the axis of the pump chamber D is arranged parallel to that of the injector cylinder B, in this example, the coil spring 140 as structured above may be used in a sprayer in which the axis of the pump chamber D
is arranged to intersect the axis of the injector cylinder BI as disclosed in Japanese Utility Model Publication ivo.
62-770 (1987).
Example 2 A sprayer according to Example 2 will tie describec.i with reference to Fig. 7 through Fig. 24.
Fig. 9 is a side view of the outside of the sprayer, which is fixed to the neck of a container 80 filled with liquid detergent (foamable liquid), through a cap 90.
The sprayer is of a trigger-type and comprises a frame 1, a trigger 2 energized forward by a spring (not shown), a spraying member 20 mounted to the front end of the frame 1. Tn this sprayer, when the trigger 2 is forward returned by the elastic force of the spring, the liquid detergent in the container 80 is pumped up into the frame 1 and, when the trigger 2 is pulled rearwardly, the liquid detergent pumped up in the frame 2 is sprayed in a foam state from the front end of the spraying member 20.
Fig. 7 is a vertical sectional view of a discharge portion of the sprayer (taken along the line I-I of Fig.
8), and Fig. 8 is a front view of the same.
The frame 1 is provided with a discharge tube 3 at the front end portion thereof, to which a supporting member 10 is fixed.
Fig. 10 is a vertical sectional view of the supporting member 10 (taken along the line II-II of Fig.
11), and Fig. 11 is a front view of the same. The supporting member 10 has a base cylinder 12, a holding cylinder 13, and a partition 11 disposed between the base cylinder 12 and the holding cylinder 13 which are eccentric to each other. The base cylinder 12 is sealingly fixed to the outside of the discharge tube 3.
The base cylinder 12 and the holding cylinder 13 communicate with each other through a through hole 14 formed in the partition 11. A column-like shaft member 15 which is concentrically disposed inside the holding cylinder 13 projects from the partition 11. The shaft member 15 is provided with two vertical grooves 16, 16 which are formed in a front-side outer surface thereof, extend to the front end face of the shaft member 15 in the longitudinal direction thereof, and are spaced apart from each other by 180° with respect to the circumferentia_l.
direction.
The spraying member 20 is mounted to the holding cylinder 13 of the supporting membE:r 10. Fig. 12 is a vertical sectional view of the spraying member 20 (taken along the line III-III of Fig. 13), Fig. 13 is a front view of the same, Fig. 14 is a rear view of the same, and Fig.
15 is a sectional view taken along the line IV-IV of Fig.
13.
The spraying member 20 has a vertical wall 22 through which a discharge nozzle 21 is formed in the center thereof. An inner cylinder 23, a middle cylinder 24, and an outer cylinder 25 each of which is formed in an annulus-ring shape, project rearwardly from the vertical wall 22 in a concentric arrangement with the discharge nozzle 21.
The bottom face 29 of the inner cylinder 23 is provided with a round small-diameter concavity 26 which is concentric with the discharge nozzle 21, and two grooves (swirling passages) 27, 27 which oppositely extend from the small concavity 26 to the outside in the tangential direction of the inner circumference of the small-diameter concavity 26. The inner surface of the inner cylinder 23 5 has two vertical grooves 28, 28 at the top side thereof, which linearly extend from the top end to a position in front of the bottom face 29 of the inner cylinder 23 and are spaced apart from each other by 180° with respect to the circumferential direction. The grooves 27, 27 lie on 10 the extensions of the vertical grooves 28, 28, respectively.
The spraying member 20 is mounted to the supporting member 10 to allow it to be rotated and not to allow it to be removed by closely, rotatablely inserting the shaft 15 member 15 of the supporting member 10 into the inner cylinder 23, closely, rotatably inserting the outer surface of the middle cylinder 24 into the front-side inner surface of the holding cylinder I3 of the supporting member 10, and engaging an engaging ring 30 disposed on the inner surface 20 of the outer cylinder 25 with the engaging ring 17 disposed on the outer surface of the holding cylinder 13. The end face of the shaft member 15 of the supporting member 10 comes in contact with the bottom face 29 of the inner cylinder 23 to close the small-diameter concavity 26.
The rotation of the spraying member 20 relative Lo the supporting member 10 can make the rear ends of the vertical grooves 16 of the supporting member 10 coincide with and come out of the front ends of the vertical grooves 28 of the spraying member 20, respectively.
Fig. 7 shows a state in which the rear ends of the vertical grooves 16 coincide with the front ends of the vertical grooves 28, respectively. In this state, the grooves 27 communicate with the vertical grooves 28 through the vertical grooves 16. When the vertical grooves 16 and 28 are positioned not to coincide with each other, the vertical grooves 28 are closed with the outer surface of the shaft member 15 and the vertical grooves 16 are closed with the inner surface of the inner cylinder 23, thereby shutting off the communication between the vertical grooves 16 and vertical grooves 28.
From the vertical wall 22 of the spraying member 20, a hollow projection 31 and the shell-like wall 32 project forward. In the inside of the projection 31, a round small-diameter concavity 33 communicating with the discharge nozzle 21 and a round large-diameter concavity 3~
are formed in a concentric arragement with the discharge nozzle 21. The shell-like wall 32 is disposed outside the projection 31 and the front end of the shell-like wall 32 projects forward more than the projection 31.
On the inner surface of the small-diameter concavity 33, four air holes (air inlets) 35 are formed, each of which communicates with one of air passages 36 opened in the outer surface of the shell-like wall 32. The shell-like wall 32 has cutouts 37, 38 in the upper and lower sides, respectively, and also has through holes 39, 39 formed at the both sides of the upper cutout 37 and through holes 40, 40 formed at the both sides of the lower cutout 38.
A collision plate 50 is mounted to the front end of the spraying member 20. Fig. 16 is a side view of the collision plate 50, Fig. 17 is a rear view of the same (from the right side of the Fig. 16j, and Fig. 18 is a sectional view taken along the line V-V of Fig. 17.
The collision plate 50 is provided with a pair of supporting shaft portions 51, 51 on the upper side thereof.
By inserting the supporting shaft portions 51, 51 info the through holes 39, 39 of the spraying member 20, respectively, the collision plate 50 is pivotably supported. It should be noted that the supporting shaft portions 51 is tightly fitted into the through hole 39, thereby preventing the collision plate 50 from inadvertently pivoting.
The collision plate 50 is designed to have a configuration and a size to be fit inside the shell-like wall 32 of the spraying member 20 when the collision plate 50 is suspended as shown in Fig. 7 and Fig. 8 (hereinafter, referred to as the closed state of the collision plate 50j.
The collision plate 50 has a tongue 52 disposed on the lower side thereof to extend lower than the shell wall 32.
Engaging protrusions 53, 53 provided on the both sides of the tongue 52 engage the through holes 40, 90 of the shell-like wall 32, respectively, whereby the collision plate 50 can be locked in the closed state.
The collision plate 50 has a through hole (extending passage) 54 which is concentric with the discharge nozzle 21 when the collision plate 50 is in the closed state. The through hole 54 has an inner diameter slightly larger than the inner diameter of the large-diameter concavity 34 of the spraying member 20. The through hole 54 is provided with a step hole 55 having a inner diameter larger than that of the through hole 54, at the rear side thereof. In the closed state of the collision plate 50, the front end of the projection 31 of the spraying member 20 is in the step hole 55 so that it is positioned closely to the stepped portion.
The collision plate 50 has five bar-like collision walls (collision wall portions) 56 extending from the inner surface of the through hole 54 toward the center of the through hole 54, at the front end side at even intervals.
The tips of the bar-like collision walls 56 are spaced from each other. The front end of the though hole 54 is divided into a center opening (flow opening) 57 and five fan-shaped openings (flow opening) 58 positioned around the center opening 57 by the five bar-like collision walls.
The description will now be made as regard to the operation of the sprayer. By rotating the spraying member 20 to bring the vertical groove 16 of the supporting member 10 to communicate with the vertical groove 28 of the spraying member 20, and pulling the trigger 2 rearwardly, the liquid detergent in the container 80 is pumped up to the discharge tube 3. The liquid detergent passes through the base cylinder 12, the through hole 14, and the holding cylinder 13 of the supporting member 10 and then entered into the small-diameter concavity 26 through the vertical grooves 16, 28 and grooves 27.
The liquid detergent becomes high-speed swirling flow when it is entered into the small-diameter concavity 26 from the grooves 27 and flows through the discharge nozzle 21 while swirling at a high speed. The liquid detergent from the discharge nozzle 21 is discharged to the small-diameter concavity 33 and the large-diameter concavity 34 while it is scattered into small particles by centrifugal force. As the liquid detergent is discharged from the discharge nozzle 21, a negative pressure develops in the small-diameter concavity 33 whereby air is entered into the small-diameter concavity 33 through the air hole 35.
In this sprayer, the spray state of the sprayed liquid detergent can be suitably selected by opening or closing the collision plate 50. Hereinafter, the description will be made as regard to this.
<In case of closing the collision plate 50>
Fig. 19 shows a spray state of the sprayed liquid detergent when the collision plate 50 is located to face a discharge nozzle 21. In this case, the small-diameter concavity 33 and the large-diameter concavity 34 of the spraying member 20 and the through hole 54 of the collision plate 50 form together a gas-liquid mixing passage so that part of sprayed particles of the liquid detergent sprayed from the discharge nozzle 21 become smaller particles and scatter by colliding with the inner surface of the aforementioned gas-liquid mixing passage or the bar-life collision walls 56 of the Collision plate 50, and stir the 5 flow in the gas-liquid mixing passage. As a result of this, the sprayed particles of the liquid detergent are mixed with air entered from the air holes in the gas-liquid mixing passage so as to become foams. The foams are mixed with the sprayed particles directly reached without colliding with the bar-like walls 56 and the like and then discharged from the openings 57, 58 of the collision plate 50.
When the collision plate 50 is closed as mentioned above, the flow is stirred well in the gas-liquid mixing 15 passage so that the detergent is foamed well. Since the distance between the discharge nozzle 21 and the front end of the gas-liquid mixing passage is long and the scattered angle is limited, the foams and the sprayed particles discharged from the openings 57, 58 are sprayed forward in 20 the bundle state with little scattering.
As a result of observing the deposited state of the liquid detergent on the wall surface X-X which is located approximately 25-30 cm apart from the spraying member 20 in the forward direction when the liquid detergent is 25 discharged with the collision plate being closed as shown in Fig. 19, the deposited state is observed as shown in the side view of Fig. 20 and the front view of Fig. 21. That is, in this case, the liquid detergent is deposited in a small range on the wall surface in the volumed foaming state.
<In case of getting away upward the collision plate 50>
Fig. 22 shows a spray state of the sprayed liquid detergent when the collision plate 50 is pivoted upwardly to get away from a position in front of the discharge nozzle 21. In this case, the small-diameter concavity 33 and the large-diameter concavity 34 of the spraying member 20 form together a gas-liquid mixing passage. Therefore, the gas-liquid mixing passage has a whole length shorter than that in case of closing the collision plate 50.
Part of the sprayed particles of the liquid detergent sprayed from the discharge nozzle 21 become smaller particles and acatter by colliding with the inner surface, of the gas-liquid mixing passage, and stir the flow in the gas-liquid mixing passage. However, since the collision plate 50 is got away in this case, the scatter of the sprayed particles is narrower than the case of closing the collision plate 50 and the effect of stirring in the gas-liquid mixing passage is also weak. Therefore, the liquid detergent is not so foamed by comparison with the case of closing the collision plate 50. The foams are mixed with the sprayed particles directly reached without colliding with the inner surface of the gas-liquid mixing passage and then discharged from the large-diameter concavity 34 of the spraying member 20.
Thus, since the distance between the discharge nozzle 21 and the front end of the gas-liquid mixing passage is short and the scattered angle is wide in case of getting away the collision wall 50, the foam and the sprayed particles are scattered and sprayed from the large-diameter concavity 34.
As a result of observing the deposited state of the liquid detergent on the wall surface X-X which is located approximately 25-30 cm apart from the spraying member 20 in the forward direction when the liquid detergent is discharged with the collision plate being got away upward in the opened state as shown in Fig. 22, the deposited state is observed as shown in the side view of Fig. 23 and the front view of Fig. 24. That is, in this case, the liquid detergent is deposited in a wide range on the wall surface, the center of which is in the foamed state and the periphery of which is in the atomized state.
As described above, the sprayer according to this example, the collision plate 50 located to face the discharge nozzle 21 is disposed so that it can be got away from a position in front of the discharge nozzle 21, thereby allowing the selection whether the liquid is sprayed in the well foamed state or in the not-so-well foamed state.
When the collision plate 50 has the through hole 59 for substantially extending the gas-liquid mixing passage in case of disposing the collision plate 50 to face the discharge nozzle 21, the scattering of the foam sprayed out from the flow opening of the collision plate 50 can be reduced.
example 3 The description will now be made as regard to a sprayer according to Example 3 with referred to Fig. 25 through Fig. 29. Fig. 25 is a front view of the sprayer 200 partially sectioned. The sprayer 200 of this example is of the trigger type and is mounted to the neck of a container 300 for use. Both the sprayer 200 and the container 300 are made of synthetic resin.
The sprayer 200 has a spraying member 210, the outline of which is formed in an inverted triangle when seen from the front side, at the front end thereof. The spraying member 210 is provided with a cavity 211 formed in the front middle portion thereof. The cavity 211 is provided with a nozzle cylinder 212 protruding from the center thereof. A spraying outlet 213 for spraying out, which has a swirling passage therein, is provided in the center of the nozzle cylinder 212.
As shown in Fig. 26 through Fig. 28, the spraying member 210 is widely cut out in the front upper portion thereof. A pair of bearings 220 is formed in the both sides of the cut-out portion. On the side surfaces facing each other, shaft supporting holes 221 and insertion grooves 222 extending from the shaft supporting holes 221 to the front end of the spaying member 210 are formed.
The spraying member 210 is also cut. out in the front lower portion thereof to have a cutout 230.
A nozzle cover 290 is detachably mounted to the cavity 211 of the spraying member 210 to cover the spraying outlet 213. To describe it in more detail, the nozzle cover 240 has a pair of pivot shafts 242 protruding from both sides of a base portion 241 thereof. The pivot shafts 242 is rotatably inserted in the shaft supporting holes 221, respectively, so that: the nozzle ever 24U is pivotably supported by the spraying member 210. It should be noted that the pivot shafts 292 c:an be easily inserted into the shaft supporting holes 221 by fitting the pivot shafts 242 in the insertion grooves 222 and pushing them to the shaft supporting holes 221.
In the nozzle cover 240, a portion connected to the base portion 291 is formed to a hinge portion 244, connected to the base portion 241, which is thin and flexible.
The nozzle cover 240 has a closing projection 243 projecting from the inner surface center thereof for closing the spraying outlet 213, and an engaging protrusion 246 protruding from the inner surface thereof and formed in a nearly ring shape around the closing projection 243, for engaging with the outside of the nozzle cylinder 212.
The lower side of the nozzle cover 240 is formed to an engaging end 245 for detachably engaging with the cutout 230.
A first holding means 250 is disposed between the engaging end 245 and the cutout 230 for holding the spraying outlet 213 in the closed state.
The first holding means comprise a pair of engaging protrusions 251 protruding from both sides of the engaging end 245, and a pair of engaging holes 252 formed in the 5 sides of the cutout 230 facing each other wherein the engaging protrusions 251 are engageable with and detachable from the engaging holes 252, respectively.
On the other hand, a second holding means 260 is disposed between the engaging end 245 and the top surface 10 of the spraying member 210 for holding the spraying out=let=
213 in the opened state.
The second holding means 260 comprises a hook 261 disposed on the outer surface of the engaging end 245 and an engaging concavity 262 formed in the top surface rear 15 side of the spraying member 210 wherein the hook 261 is engageable with and detachable from the engaging concavity 262.
According to the sprayer 200 as structured above, when spraying is not needed, the nozzle cover 240 is closed 20 and the engaging protrusions 251 of the first holding means 250 are engaged with the engaging holes 252, respectively, thereby holding the spraying outlet 213 in the closed state.
On the other hand, when spraying is needed, the 25 first holding means 250 is released by detaching the engaging protrusions 251 from the engaging holes 252 and the nozzle cover 240 is pivoted upwardly and further pivoted rearwardly. The hook 261 of the second holding means 260 is then engaged with the engaging concavity 262 as shown in Fig. 29, thereby holding the spraying outlet 213 in the opened state.
Fig. 27 shows the sprayer 200 during the second holding means 260 is operated. When the second holding means 260 is operated as shown, there is no possibility of inadvertently pivoting the nozzle cover 240 downward thereby surely preventing the nozzle cover 240 from blocking the spraying. Therefore, the sprayed particles are not scattered in unexpected directions due to co).lision with the nozzle cover.
After spraying, the second holding means 260 is released, the nozzle cover 240 is pivoted downward, and the first holding means 250 is operated again.
The structures of the first holding means 250 and the second holding means 260 are quite simple structures so that a mold for molding them from synthetic resin can be easily manufactured at a low cost, thereby also reducing the production cost for the sprayer 200.
Example 9 The description will now be made as regard to a sprayer 200 according to Example 4 with referred to Fig. 30 through Fig. 32. It should be noted that the sprayer 200 of Example 4 is one of modified examples of the sprayer 200 of Example 3 so that the description will be made as regard only to the differences from Example 3, and the same parts as those of the sprayer 200 of the third embodiment will be marked by the same reference numerals, respectively, and the description about the same parts will be omitted.
In the sprayer 200 of Example 4, the nozzle cover 240 does not have the flexible hinge portion 294 so that the structure of the second holding means 260 is different.
In Example 4, the base portion 241 of the nozzle cover 240 has an engaging protrusion 263 protruding from the top surface thereof. When the nozzle cover 290 is pivoted upwardly and rearwardly, at the end of this pivotal movement, the engaging protrusion 263 passes over an upper edge 212a of the nozzle cylinder 212 of the spraying member 210 to hold the engaging protrusion 263 by the upper edge 212a, as shown in Fig. 32. In a state that the engaging protrusion 263 is held by the upper edge 212a of the nozzle cylinder 212 as mentioned above, there is no possibility of inadvertently pivoting the nozzle cover 240 downward.
As a result of this, the spraying outlet 213 can be held in the opened state for spraying and the second holding means 260 can securely prevent the nozzle cover 240 from blocking the spraying so that the sprayed particles are not scattered in unexpected directions due to collision with the nozzle cover 240.
That is, the second holding means 260 comprises the engaging protrusion 263 and the upper edge 212a of the nozzle cylinder 212 in Example 9.
When spraying is not needed, the second holding means 260 is released by pivoting the nozzle cover 240 forward to force the engaging protrusion 263 to pass over the upper edge 212a of the nozzle cylinder 222, and the first holding means 250 is operated by further pivoting the nozzle cover 240 downward as shown in Fig. 30.
The structures of the first holding means 250 and the second holding means 260 are quite simple so that a mold for molding them from synthetic resin can be easily manufactured at a low cost, thereby also reducing the production cost for the sprayer 200.
Example 5 L0 The description will now be made as regard to a sprayer 200 according to Example 5 with referred to Fig. 33 through Fig. 35. It should be noted that the sprayer 200 of Example S is one of modified examples of the sprayer 200 of Example 3 so that the description will be made as regard only to the differences from Example 3, and the same parts as those of the sprayer 200 of Example 3 will be marked by the same reference numerals, respectively, and the description about the same parts will be omitted.
In the sprayer 200 of Example 5, the nozzle cover 240 does not have the flexible hinge portion 244 so that the structure of the second holding means 260 is different.
In Example 5, as shown in Fig. 35, the base portion 241 of the nozzle cover 240 has a pair of engaging protrusions 264 protruding from both sides thereof and located beneath the pivot shafts 242, respectively, and the bearings 220 have engaging holes 265 formed in the side surfaces facing each other, wherein the engaging protrusions 264 are engageable with and detachable from the engaging holes 265. The second holding means 260 comprises the engaging protrusions 264 and the engaging holes 265 in Example 5.
For spraying, the engaging protrusions 264 of the second holding means 260 are engaged with the engaging holes 265 as shown in Fig. 34, by pivoting the nozzle cover 240 upwardly and rearwardly, in Example 5. When the second holding means 260 is operated as mentioned above, there is no possibility of inadvertently pivoting tree nozzle cover 240 downward.
As a result of this, the spraying outlet 2I3 can be held in the opened state for spraying and the second holding means 260 can securely prevent the nozzle cover 240 from blocking the spraying so that the sprayed particles are not scattered in unexpected directions due to collision with the nozzle cover 240.
When spraying is not needed, the second holding means 260 is released by pivoting the nozzle cover 290 forward, and the first holding means 250 is operated by further pivoting the nozzle cover 240 downward as shown in Fig. 33.
The structures of the first holding means 250 and the second holding means 260 are quite simple so that a 2S mold for molding them from synthetic resin can be easily manufactured at a low cost, thereby also reducing the production cost for the sprayer 200.

Examgle 6 The description will now be made as regard to a sprayer 200 according to Example 6 with referred to Fig. 36 through Fig. 38. It should be noted that the sprayer 200 5 of Example 6 is one of modified examples of the sprayer 200 of Example 3 so that the description will be made as regard only to the differences from Example 3, and the same parts as those of the sprayer 200 of Example 3 will be marked by the same reference numerals, respectively, and the 10 description about the same parts will be omitted.
In the sprayer 200 of Example 6, the nozzle cover 240 does not have the flexible hinge portion 244 so that the structure of the second holding means 260 is different.
In Example 6, the nozzle cover 290 has a pair of 15 step portions 266 formed in the middle of both sides thereof, respectively, as shown in Fig. 38. When the nozzle cover 240 is pivoted upwardly and rearwardly, at the end of this pivotal movement, the nozzle cover 240 tilts rearwardly so that the step portions 266 sit on the top 20 surfaces of both bearings 220, respectively, as shown in Fig. 37. In a state that the step portions 266 sit on the top surfaces of both bearings 220 as mentioned above, there is no possibility of inadvertently pivoting the nozzle cover 240 downward.
25 As a result of this, the spraying outlet 213 can be held in the opened state for spraying and the second holding means 260 can securely prevent the nozzle cover 240 from blocking the spraying so that the sprayed particles are not scattered in unexpected directions due to collision with the nozzle cover 240.
That is, the second holding means 260 comprises the step portions 266 and the top surfaces of the bearings 220 in Example 6.
When spraying is not needed, the first holding means 250 is operated by further pivoting the nozzle cover 240 forward and downward, as shown in Fig. 36.
The structures of the first holding means 250 and the second holding means 260 are quite simple so that a mold for molding them from synthetic resin can be easily manufactured at a low cost, thereby also reducing the production cost for the sprayer 200.
Ex .ample 7 The description will now be made as regard to a sprayer 200 according to Example 7 with referred to Fig. 39 through Fig. 41. It should be noted that the sprayer 200 of Example 7 is one of modified examples of the sprayer 200 of Example 3 so that the description will be made as regard only to the differences from Example 3, and the same parts as those of the sprayer 200 of Example 3 will be marked by the same reference numerals, respectively, and the description about the same parts will be omitted.
In the sprayer 200 of Example 7, the nozzle cover 290 does not have the flexible hinge portion 294 so that the structure of the second holding means 260 is different.
In Example 7, as shown in Fig. 39, the cut-out portion has a deep hollow 267 at the rear side of the bearings 220 and the both sides of the nozzle cover 240 are cut to have parallel planes 247.
When the nozzle cover 240 is pivoted upwardly and rearwardly, at the end of this pivotal movement, the nozzle cover 290 tilts rearwardly so that parts of the parallel planes 247 of the nozzle cover 240 are deeply inserted into the hollow 267 as shown in Fig. 40. In a state that the nozzle cover 290 tilts rearwardly and the parts of the parallel planes 247 of the nozzle cover 24U are deeply inserted into the hollow 267 as mentioned above, there is no possibility of inadvertently pivoting the nozzle cover 240 downward.
As a result of this, the spraying outlet 213 can be held in the opened state for spraying and the second holding means 260 can securely prevent the nozzle cover 240 from blocking the spraying so that the sprayed particles are not scattered in unexpected directions due to collision with the nozzle cover 240.
That is, the second holding means 260 comprises the parts of the parallel planes 247 and the hollow 267.
When spraying is not needed, the first holding means 250 is operated by further pivoting the nozzle cover 240 forward and downward as shown in Fig. 39.
The structures of the first holding means 250 and the second holding means 260 are quite simple so that a mold for molding them from synthetic resin can be easily manufactured at a low cost, thereby also reducing the production cost for the sprayer 200.
It should be noted that the second holding means 260 of the nozzle cover 240 described in Example 3 through Example 7 may be used as the means for holding the collision plate 50 in the got-away-upward position in the sprayer of Example 2.
INDUSTRIAL APPLICABILITY
The present invention may be available as a sprayer for spraying liquid, such as liquid detergent, liquid insecticide, or liquid for other purposes, in the atomized state or foamed state.

Claims (5)

CLAIMS:
1. A sprayer for spraying foamable liquid in the foamed state, comprising:
(a) a discharge nozzle, (b) a swirling passage disposed at an upstream side of said discharge nozzle to communicate with said discharge nozzle for swirling the liquid, (c) a gas-liquid mixing passage concentrically disposed at a downstream side of said discharge nozzle to communicate with said discharge nozzle, (d) an air inlet for allowing air to enter into said gas-liquid mixing passage, and (e) a collision plate having a collision portion and a flow opening and disposed at a downstream side of said gas-liquid mixing passage to face said discharge nozzle, said collision plate being movable to an open position from a closed position in front of said discharge nozzle, wherein said discharge nozzle, said swirling passage, said gas-liquid mixing passage and said air inlet form a front end member, said collision plate being mounted to said front end member so as to spray said liquid in a foamed state with mutually different spray patterns in said open and closed positions.
2. A sprayer according to claim 1, wherein said collision plate comprises an extending passage for extending said gas-liquid mixing passage when said collision plate is disposed to face said discharge nozzle, and said collision portion and said flow opening are disposed at a downstream side of said extending passage.
3. A sprayer according to claim 1, wherein said collision portion of said collision plate comprises a plurality of bar-like collision walls extending toward a point on an extension of the center of said discharge nozzle.
4. A sprayer according to claim 1, wherein said collision portion of said collision plate comprises a plurality of bar-like collision walls extending toward a point on an extension of the center of said discharge nozzle, and said flow opening is disposed among the bar-like collision walls and on the extension of the center of the discharge nozzle.
5. A sprayer according to claim 1, wherein said collision plate has a substantially flat front surface exposed outside when the collision plate is in said closed position.
CA002397440A 1994-12-09 1995-12-05 Sprayer Expired - Fee Related CA2397440C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP33092394A JP3566368B2 (en) 1994-12-09 1994-12-09 Spring member of trigger sprayer
JP6-330923 1994-12-09
CA002181820A CA2181820C (en) 1994-12-09 1995-12-05 Sprayer with nozzle cover and holding means

Related Parent Applications (1)

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CA002181820A Division CA2181820C (en) 1994-12-09 1995-12-05 Sprayer with nozzle cover and holding means

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CA2397440A1 CA2397440A1 (en) 1996-06-13
CA2397440C true CA2397440C (en) 2006-06-20

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CA002450182A Abandoned CA2450182A1 (en) 1994-12-09 1995-12-05 Sprayer
CA002397440A Expired - Fee Related CA2397440C (en) 1994-12-09 1995-12-05 Sprayer

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CA002450182A Abandoned CA2450182A1 (en) 1994-12-09 1995-12-05 Sprayer

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CA2450182A1 (en) 1996-06-13

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