CA2380664C

CA2380664C - Reusable heat pack

Info

Publication number: CA2380664C
Application number: CA002380664A
Authority: CA
Inventors: Chhatrapal Sharma; Rajendra Kumar Sharma; Chandra Kant; Ajit Kumar Sarkar
Original assignee: Council of Scientific and Industrial Research CSIR
Current assignee: Council of Scientific and Industrial Research CSIR
Priority date: 2001-03-30
Filing date: 2001-03-30
Publication date: 2008-01-15
Anticipated expiration: 2021-03-30
Also published as: HUP0303373A2; KR20020092346A; KR100476123B1; NO20021232D0; CA2380664A1; PL357248A1; JP2004516876A; PL199033B1; RO119342B1; SK4392002A3; AU771018B2; AU6059501A; NO20021232L; WO2002078584A1; CZ20021110A3; SK287136B6

Abstract

The invention discloses a reusable heat pack comprising a soft sealed plastic bag containing a mixture of supercooled supersaturated recrystalizable solution of inorganic substance, alcohol, chemical compound additives, and means to trigger recrystallization of supercooled supersaturated recrystalizable solution of inorganic substance.

Description

REUSABLE HEAT PACK
Field of the invention The present invention relates to a reusable heat pack. The present invention also relates to a trigger device for a heat pack. The invention also relates to a supercooled supersaturated recrystalizable solution for use in heat pack and to a process for the preparation thereof.
Background of the invention Use of heating or cooling for many applications has been done by a variety of 1o techniques depending on the specific need. For example, persons suffering from muscular pains normally use rubber bags filled with hot boiling water to alleviate the pain. ln case of any head injury normally the doctor's prescription is to apply ice as a first aid. In case of high fever the common house remedy, has been to apply a cloth soaked in cold water on the forehead to bring down the temperature. Many a time on a recreational trip people tend to take packed food or even carry cooking apparatus and the raw, materials for cooking food. The other need of heat energy is in the remote areas where availability of the fuels may not be possible or may be very expensive.
Therefore to get over all these difficult situations it is necessary to clevise ways and means to generate heat in an economical way and preferably without the use of conventional fuels. To address this very need, development of device called the heat pack has occurred over the past 15 years. The main principle underlying the heat pack is to use heat generated due to a start of a chemical reaction between two or more chemicals 'or due to triggering of initiation of crystallization of a supercooled chemical solution. In the context of the present invention it is the second aspect which is disclosed Several; warming materials are available in the market such as hot water bag, portable electrical bag warmer or battery operated warmer. However, in case of hot water bag, hotwater is to be poured in the bag which can only be obtained either by using fuel or electrical energy. Further the heat of the water bag does not last lorxg 3o enough for giving any observable effect. In case of electrical bag warmer a permanent supply of electricity is needed. This limits the use of this heating device to only such places where there is electricity available i:e only indoors. Irt case of battery operated warmer the battery needs to be charged regularly and needs replacement as and when . . . . . . .,]
i it gets exhausted. In all these cases another drawback is that the use is very liainited and safety precautions need to be taken in case of electrical heat packs.
A non-conventional heat pack has been disclosed in a US Patent 4,532,110 (1985). In this disclosure heat energy is generated by a trigger action on a supercooled .
saturated solution of sodium acetate. The triggering is accomplished by a specially designed device. The entire assembly of trigger and the supercooled solution is kept in a plastic container made of PVC, polyurethane or the like. The drawback in the invention is that the trigger used to initiate the crystallization of the super cooled sodium acetate solution has to have a protective layer of gold or silver to prevent any lo corrosion due to contact with the chemical. This is not desirable since the material usedfor the trigger is already an expensive CuBe alloy. Further the PVC
material for the heat pack manufacturing has a very limited shelf life due to inevitable leaching of the chloride ion due to the presence of sodium salt solution.. This drawback is present in the other disclosed inventions as well as disclosed in US Patents 4,572,158;
5,058,563 and 5,205,278. A further drawback in the disclosed inventions, except in 5,058,563, isthat the supercooled solution tends to flow to one side giving rise to uneven heating effects thereby rendering the heat pack difficult to use by needing to adjust the contour of the pack for a particular application before initiation of crystallisation and resultant heat generation.
In [7S Patent 5,058,563 use has been made of an additive to induce gelation during crystallisation. This gelation helps in maintaining the desired density of the solution and hence uniformity of heat over the entire useful area. The gelation material used in the said disclosure is a water soluble hydroethyl cellulose polymer.
This material though giving the advantage of gelling the solution suffers from the disadvantage of being unstable, thereby rendering the heat pack in capable of reuse.
US Patent 5,843,145 discloses a reusable heat pack wherein a mixture of thi-ee constituents forming a,gel, is sealed in a plastic bag. This reusable heat pack needs an external heating or cooling means to give a useful application of the device.
Ln case of heating application, the heat pack is put in a microwave oven or any other heating means to energise the pack. It is claimed that the temperature of the heat pack is maintained for a sufficient length oftime thereby claiming its use as a heat pack. In view of the fact; that the pack needs an external heating means, the invention proves to be disadvantageous in its claimed use as-a heat pack. This is mainly due to the fact that in the invention discloses that the preeonditioning of -the pack is to be done for a time period typically two hours. This renders the pack as disclosed not advantageous in an emergency practical situation and also in remote areas, where heating means such as microwave oven may not be available.

JP 58180575 discloses a cooling pack with a mixture provided therein containing inter alia, aniline chloride. However, in this disclosure, the mixture acts as an endothermic material wherein the material when dissolved in water absorbs heat and produces a cooling effect.

The present invention circumvents the drawbacks of the inventions of the prior art.

Summary of the invention The present invention provides a reusable heat pack which obviates or at least mitigates the drawbacks mentioned above. The invention provides a heat pack with a shelf life of at least six months. The present invention provides a heat pack which can be recycled at least a hundred times. The present invention provides a heat pack with heat retention for at least two hours. The present invention provides a heat pack capable of being used for therapeutic application.

Accordingly the present invention provides a reusable heat pack, which comprises a soft sealed plastic bag containing a mixture of supercooled supersaturated recrystalizable solution of inorganic substance, alcohol, chemical compound additives, and means to trigger recrystallization of supercooled supersaturated recrystalizable solution of inorganic substance.

In an embodiment of the invention the plastic bag is made of polypropylene or polyvinyl chloride.

3a In another embodiment of the invention, the inorganic substance is selected from sodium acetate and calcium nitrate.

In still another embodiment of the present invention the supercooled supersaturated recrystalizable solution of inorganic substance is made in good quality water.

NF t68/01 In a further embodiment of the invention, the good quality water is bacteria free municipal supply or distilled water.
In a further embodiment of the present invention the alcohol is selected from ethylene glycol and glycerol.
In yet another ern.bodiment of the present invention the chemical additive comprises an organic amine.
In a further embodiinent of the invention, the organic amine comprises aniline.
In another embodiment of the invention, the supercooled supersaturated recrystalizable solution comprises a mixture of hydrated salt of sodium acetate 50 -70 wt%, ethylene glycol I - 10 wt%; aniline 10 - 20 wt% and water 10 - 29 wt%.
In another embodiment of the - present invention the means for triggering recrystallization comprises a mechanical device selected from the group consisting of crocodile clip and a safety pin.
In a further embodiment of the present invention the material of the means ~or trigger comprises a noncorrosive material.
In a fiarther embodiment of the invention, the non-corrosive material for the trigger means comprises stainless steel.
In a further embodiment of the invention the heat pack has a shelf life of at least six months.
In sti11another embodiment of the invention the heat pack is capable of being recycled for at.least 100 cycles.
In another embodiment of thepresent invention the heat pack retains heat for at least two hours.
In still another embodiment of the present invention the heat pack is used for therapeutic applications, body warming in high altitudes.
The invention also relates to a process for the preparation of a reusable heat pack said process comprising preparinga hydrated solution of an inorganic substance in water, adding an alcohol to this solution and mixing thoroughly, adding aniline and thoroughly mixing the resultant mixture, enclosing the mixture in a soft sealed plastic bag and adding; a trigger means thereto.
The present invention also relates to a mixture for use in reusable heat packs;
said mixture comprising a solution of an inorganic substance in water, alcohol and aniline.

NF 168f01 In one embodiment of the invention, the mixture comprises a mixture of hydrated salt of sodium acetate 50 - 70 wt%, ethylene glycol 1- 10 wt%, anilirm. 10 - 20 wt% and water 10 - 29 wt%a.
The invention also relates to sprocess for the preparation of a mixture for use in reusable heat packs, said process comprising preparing a hydrated solution of an inorganic substance in water, adding an alcohol to this solution and mixing thoroughly, adding aniline and thoroughly mixing the resultant mixture.
The mixture of the invention for use in a reusable heat pack is a synergistic admixture with properties over and above the aggregation of properties of the individual constituents and is not a simple admixture.
Detailed descriptionof the invention First a hydrated solution of preferably sodium acetate of a preferred purity of was prepared in ordinary water by mixing 500-7-00 gms. in 0.1 to 0.3 liters of water.
The solution was prepared by thoroughly mixing sodium acetate in water. To this was added a polyhydric alcohol and preferably ethylene glycol. This mixture was thoroughly mixed and to this was then added another additive and preferably aniline and the resultant nzixture was thoroughly mixed. The addition of polyhydric alcohol is to provide smoothness to the recrystallised supercooled saturated solution of sodium acetate. This is achieved by controlled increase in viscosity of the resulting mixture after recrystallisation due to triggering action by a mechanical device. The use of aniline in the mixture of the heat pack increases the shelf life of the heat pack and also to give the unique property of recyclability of the heat pack. After the mixture has been prepared the same is poured into a plastic bag of preferred dimension of 100mm2 and made of thin sheet of polyvinyl chloride (PVC). The use of aniline as an additive gives the desired property of preventing the leaching of the plastic material and thereby enhancing the shelf life. Astainless steel crocodile clip is inserted in the heat pack and then finally sealed from the open end. The heat pack is now ready having typical contents, but not limited to, of hydrated salt of sodiuni acetate 50wt%, ethylene glycollwt%, aniline 20wt%o and water 29 wt%. The recrystallisation activity, was initiated by softly p'ressing the crocodile clip and instantaneously releasing the same. The re crystallization took place and instantaneously heat was generated over the entire heat pack. This heat pack could be easily contoured over a body part and the part warmed thereby. The temperature of the pack was 45 C above ambient and;
maintained for about two to three hours depending on the size of the heat pack.

NF 168/Oi In a typical therapeutic application, after energizing the pack the same is wrapped in a towel and applied on the patient. The cooling of the pack to ambient took place in about four hours time. The pack was reactivated by putting the same in hot water resulting in melting of the crystallized content of the pack and then taking it out from hot water and cooled to ambient temperature. This way the heat pack was ready for use again.
The principle underlying the invention is that the formation of the hydrated salt results in an endothermic reaction absorbing heat of crystallization.
When the crystallization is effected by the triggering action the heat of crystallization is released to the container thereby heating the exterior surface of the container,. This renders the device useful for any application. The temperature attainable with the heat pack can be fixed by the amount of the supercooled supersaturated solution of the hydrated salt.
Accordingly the shelf life of the device will also be adjusted by correspondingly increasing the quantity of the aniline or any of the other additives like hydroxides or carbonates.
The novelty of the present invention lies in the heat pack being reusable and having a long shelf life and being, capable of recyclable.
This no,velty of the heat pack is due to the inveritive step of adding hydroxides, carbonates or amines to the recrystallizable mixture.
In the embodiment of the -examples the heat pack is manufactured by first dissolving hydrated salt of sodium acetate in water. Ethylene glycol was added to this.
This was mixed thoroughly and to this aniline was added. Again the mixture was thoroughly mixed and ihen poured in a plastic bag of PVC. The trig),er used is a stainless steel erocodile clip and is put inside the bag and then the whole assembly was sealed.

The following exatnples are given by way of illustration only and slaould not be construed to limit the scope of the invention.

Example 1:
Heat pack contained hydrated salt of sodium acetate 50 wt%o, ethylene glycol 1wt%, aniline 20 wt lo and water 29 wt o. Triggering action was done by pressing the clip three times. The crystallization resulted in instantaneous temperature rise to 75 C.
The cooling of the pack to reach to ambient temperature took place in about four hours time.

Example 2=
Heat pack contained hydrated salt of sodium acetate 60 wt%, ethylene glycol 4wt%, aniline 15 wt% and water 21 wt% n. The triggering action was done by pressing the clip three times.. The crystallization resulted in instantaneous temperature rise to 65 C. The cooling of the pack to reach to ambient temperature took place in about four hours time.

Example 3:
Heat pack contained hydrated salt of sodium acetate 70 wtolo, ethylene glycol 6wtolo, aniline 10 wt% and water 14 wt%o. The triggering, action was done by pressing io the clip three times. The crystallization resulted in instantaneous temperature rise to 75 C. The cooling of the pack.. to. reac.h to am:hie:nt. temperature took place in about four hours time.

Example 4;
Heat pack contained hydrated salt of sodium acetate 70 wt%, ethylene glycol lOwt%, aniline 10 wt% and water 10 wt%, The triggering action was done by pressing the clip three times. The crystallization resulted in instantaneous temperature rise to 70 C. The cooling of the. pack to reach ta ambient temperature took place in about four hours time.
Table 1 shows the consolidated results of the examples.
Table -1 Item Wei.ght percent, of materials Sodium acetate 50 60 70 70 Ethylene Glycol 1 4 6 10 Aniline 20 15 10 10 Water 29 21 14 10 Temp of Heat pack C 75 65 75 70 The main advantages of the present invention are:
1. It is easy to manufacture from commonly available chemicals and of moderate purity.
2. The heat pack can be stored for at least six months 3. The pack' can be easily put on any contour due to its being flexible even after re crystallization.

Claims

CLAIMS:

1. A reusable heat pack, which comprises a soft sealed plastic bag containing a mixture of a supercooled supersaturated recrystalizable solution of an inorganic substance, an alcohol, aniline, and means to trigger recrystallization of the supercooled supersaturated recrystalizable solution of the inorganic substance.

2. A reusable heat pack as claimed in claim 1, wherein the plastic bag is made of polypropylene or polyvinyl chloride.

3. A reusable heat pack as claimed in claim 1 or 2, wherein the inorganic substance is selected from sodium acetate and calcium nitrate.

4. A reusable heat pack as claimed in any one of claims 1 to 3, wherein the supercooled supersaturated recrystalizable solution of inorganic substance is made in substantially pure water.

5. A reusable heat pack as claimed in claim 4, wherein the substantially pure water comprises bacteria free municipal supply or distilled water.

6. A reusable heat pack as claimed in any one of claims 1 to 5, wherein the alcohol used is selected from ethylene glycol and glycerol.

7. A reusable heat pack as claimed in any one of claims 1 to 6, wherein the supercooled supersaturated recrystalizable solution comprises a mixture of 50 - 70 wt%
of a hydrated salt of sodium acetate, 1 - 10 wt% ethylene glycol, 10 - 20 wt% aniline and 10 - 29 wt% water.

8. A reusable heat pack as claimed in any one of claims 1 to 7, wherein the means for triggering recrystallization comprises a mechanical device selected from the group consisting of a crocodile clip and a safety pin.

9. A reusable heat pack as claimed in any one of claims 1 to 8, wherein the material of the means for triggering recrystallization comprises a non-corrosive material.

10. A reusable heat pack as claimed in claim 9, wherein the non-corrosive material for the trigger means comprises stainless steel.

11. A supercooled supersaturated recrystalizable solution for use in a heat pack, wherein said supercooled supersaturated recrystalizable solution comprises a mixture of a solution of an inorganic substance, an alcohol and aniline.

12. A supercooled supersaturated recrystalizable solution as claimed in claim 11, comprising a mixture of 50 - 70 wt% of a hydrated salt of sodium acetate, 1- 10 wt%
ethylene glycol, 10 - 20 wt% aniline and 10 - 29 wt% water.

13. A process for the preparation of a mixture for use in a reusable heat pack, said process comprising preparing a hydrated solution of an inorganic substance in water, adding an alcohol to the solution and mixing thoroughly, adding aniline and thoroughly mixing the resultant mixture.

14. A method for the manufacture of a reusable heat pack, said method comprising preparing a hydrated solution of an inorganic substance in water, adding an alcohol to the solution and mixing thoroughly, adding aniline and thoroughly mixing the resultant mixture, enclosing the mixture in a soft sealed plastic bag and adding a trigger means thereto.