CA2336623C - Detergent tablet with high mechanical and dissolution characteristics - Google Patents
Detergent tablet with high mechanical and dissolution characteristics Download PDFInfo
- Publication number
- CA2336623C CA2336623C CA002336623A CA2336623A CA2336623C CA 2336623 C CA2336623 C CA 2336623C CA 002336623 A CA002336623 A CA 002336623A CA 2336623 A CA2336623 A CA 2336623A CA 2336623 C CA2336623 C CA 2336623C
- Authority
- CA
- Canada
- Prior art keywords
- tablet
- acid
- particulate material
- tablets
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 58
- 238000004090 dissolution Methods 0.000 title description 18
- 239000011236 particulate material Substances 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 37
- 238000005406 washing Methods 0.000 claims abstract description 37
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000007864 aqueous solution Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 110
- 239000007844 bleaching agent Substances 0.000 claims description 46
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000003752 hydrotrope Substances 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 239000003093 cationic surfactant Substances 0.000 claims description 7
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 abstract description 66
- 230000000694 effects Effects 0.000 abstract description 24
- 239000000463 material Substances 0.000 abstract description 23
- 239000003826 tablet Substances 0.000 description 162
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 42
- 239000010457 zeolite Substances 0.000 description 37
- 229910021536 Zeolite Inorganic materials 0.000 description 35
- 239000012190 activator Substances 0.000 description 30
- 239000002253 acid Substances 0.000 description 27
- 239000002245 particle Substances 0.000 description 27
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 26
- 238000000576 coating method Methods 0.000 description 24
- 239000000843 powder Substances 0.000 description 24
- 239000011230 binding agent Substances 0.000 description 23
- 239000011248 coating agent Substances 0.000 description 23
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 22
- 239000002585 base Substances 0.000 description 22
- 229910021653 sulphate ion Inorganic materials 0.000 description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- -1 Hydrotrope compound Chemical class 0.000 description 19
- 239000000243 solution Substances 0.000 description 18
- 125000000129 anionic group Chemical group 0.000 description 17
- 238000002156 mixing Methods 0.000 description 17
- 229920001223 polyethylene glycol Polymers 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 17
- 102000004190 Enzymes Human genes 0.000 description 16
- 108090000790 Enzymes Proteins 0.000 description 16
- 102000004882 Lipase Human genes 0.000 description 15
- 108090001060 Lipase Proteins 0.000 description 15
- 229940088598 enzyme Drugs 0.000 description 15
- 239000004367 Lipase Substances 0.000 description 14
- 235000019421 lipase Nutrition 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 239000002202 Polyethylene glycol Substances 0.000 description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 12
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 12
- 108091005804 Peptidases Proteins 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 108010059892 Cellulase Proteins 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 11
- 125000002091 cationic group Chemical group 0.000 description 11
- 229940106157 cellulase Drugs 0.000 description 11
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 11
- 239000011701 zinc Substances 0.000 description 11
- 229910052725 zinc Inorganic materials 0.000 description 11
- 239000004365 Protease Substances 0.000 description 10
- 229910000323 aluminium silicate Inorganic materials 0.000 description 10
- 229920005646 polycarboxylate Polymers 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 239000002304 perfume Substances 0.000 description 9
- 159000000000 sodium salts Chemical class 0.000 description 9
- 239000002689 soil Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 8
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 7
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 6
- 108010065511 Amylases Proteins 0.000 description 6
- 102000013142 Amylases Human genes 0.000 description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Natural products O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 235000019418 amylase Nutrition 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 229940045872 sodium percarbonate Drugs 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 102000035195 Peptidases Human genes 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000004851 dishwashing Methods 0.000 description 5
- 239000007884 disintegrant Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 230000002538 fungal effect Effects 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 150000004760 silicates Chemical class 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000004382 Amylase Substances 0.000 description 4
- 108010084185 Cellulases Proteins 0.000 description 4
- 102000005575 Cellulases Human genes 0.000 description 4
- 102000003992 Peroxidases Human genes 0.000 description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 4
- 239000002552 dosage form Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 238000004900 laundering Methods 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 description 3
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 108010056079 Subtilisins Proteins 0.000 description 3
- 102000005158 Subtilisins Human genes 0.000 description 3
- 229920006243 acrylic copolymer Polymers 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229940025131 amylases Drugs 0.000 description 3
- 238000005056 compaction Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
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- ILSQBBRAYMWZLQ-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-propan-2-ylpropan-2-amine Chemical compound C1=CC=C2SC(SN(C(C)C)C(C)C)=NC2=C1 ILSQBBRAYMWZLQ-UHFFFAOYSA-N 0.000 description 3
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 3
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- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
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- 229910019142 PO4 Inorganic materials 0.000 description 2
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- 239000004480 active ingredient Substances 0.000 description 2
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- 125000002877 alkyl aryl group Chemical group 0.000 description 2
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- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
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- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
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- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 1
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- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- SIXNTGDWLSRMIC-UHFFFAOYSA-N sodium;toluene Chemical compound [Na].CC1=CC=CC=C1 SIXNTGDWLSRMIC-UHFFFAOYSA-N 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 239000002700 tablet coating Substances 0.000 description 1
- 238000009492 tablet coating Methods 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000005019 zein Substances 0.000 description 1
- 229940093612 zein Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98870151.2 | 1998-07-10 | ||
| EP98870151 | 1998-07-10 | ||
| EP98870181A EP0971029B1 (de) | 1998-07-10 | 1998-08-24 | Waschmitteltablette mit hohen mechanischen und Lösungseigenschaften |
| EP98870181.9 | 1998-08-24 | ||
| PCT/US1999/015676 WO2000002994A1 (en) | 1998-07-10 | 1999-07-12 | Detergent tablet with high mechanical and dissolution characteristics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2336623A1 CA2336623A1 (en) | 2000-01-20 |
| CA2336623C true CA2336623C (en) | 2005-03-22 |
Family
ID=26152274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002336623A Expired - Fee Related CA2336623C (en) | 1998-07-10 | 1999-07-12 | Detergent tablet with high mechanical and dissolution characteristics |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0971029B1 (de) |
| JP (1) | JP2002520446A (de) |
| KR (1) | KR20010053468A (de) |
| CN (1) | CN1309691A (de) |
| AR (1) | AR019366A1 (de) |
| AT (1) | ATE289347T1 (de) |
| AU (1) | AU5096199A (de) |
| BR (1) | BR9911986A (de) |
| CA (1) | CA2336623C (de) |
| CZ (1) | CZ20004657A3 (de) |
| DE (1) | DE69829044T2 (de) |
| ES (1) | ES2238754T3 (de) |
| MA (1) | MA24924A1 (de) |
| WO (1) | WO2000002994A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE60039518D1 (de) * | 1999-08-10 | 2008-08-28 | Procter & Gamble | Hydrotrope enthaltende waschmittel |
| AU6288999A (en) * | 1999-10-06 | 2001-05-10 | Procter & Gamble Company, The | Detergent tablet with high dissolution and mechanical characteristics |
| GB2367830A (en) | 2000-10-12 | 2002-04-17 | Procter & Gamble | Process for preparing tablets |
| DE102009057222A1 (de) * | 2009-12-05 | 2011-06-09 | Clariant International Ltd. | Bleichkatalysator-Compounds, Verfahren zu ihrer Herstellung und ihre Verwendung |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1077067A (en) * | 1963-10-18 | 1967-07-26 | Unilever Ltd | Detergent tablet |
| US3331780A (en) * | 1963-11-26 | 1967-07-18 | Fmc Corp | Detergent tablets and method of producing same |
| DE3669101D1 (de) * | 1985-11-12 | 1990-04-05 | Douwe Egberts Tabaksfab | Geformte reinigungsmittel. |
| DE4203031A1 (de) * | 1992-02-04 | 1993-08-05 | Henkel Kgaa | Verfahren zur herstellung fester wasch- und reinigungsmittel mit hohem schuettgewicht und verbesserter loesegeschwindigkeit |
| JPH07286199A (ja) * | 1994-04-15 | 1995-10-31 | Lion Corp | タブレット洗剤組成物の製造方法 |
| JPH0987696A (ja) * | 1995-09-27 | 1997-03-31 | Lion Corp | 錠剤型ノニオン洗剤組成物 |
| JPH0987695A (ja) * | 1995-09-27 | 1997-03-31 | Lion Corp | 錠剤型ノニオン洗剤組成物 |
| DE19611013A1 (de) * | 1996-03-21 | 1997-09-25 | Henkel Kgaa | Festes Tensid- und Builder-haltiges Wasch- oder Reinigungsmittel mit hohem Schüttgewicht oder Compound hierfür |
| ES2284164T3 (es) * | 1996-12-06 | 2007-11-01 | THE PROCTER & GAMBLE COMPANY | Pastilla de detergente recubierta y procedimiento para producir la misma. |
-
1998
- 1998-08-24 AT AT98870181T patent/ATE289347T1/de not_active IP Right Cessation
- 1998-08-24 EP EP98870181A patent/EP0971029B1/de not_active Expired - Lifetime
- 1998-08-24 ES ES98870181T patent/ES2238754T3/es not_active Expired - Lifetime
- 1998-08-24 DE DE69829044T patent/DE69829044T2/de not_active Expired - Fee Related
-
1999
- 1999-07-12 WO PCT/US1999/015676 patent/WO2000002994A1/en not_active Ceased
- 1999-07-12 BR BR9911986-2A patent/BR9911986A/pt not_active Application Discontinuation
- 1999-07-12 AR ARP990103367A patent/AR019366A1/es unknown
- 1999-07-12 CN CN99808500A patent/CN1309691A/zh active Pending
- 1999-07-12 KR KR1020017000377A patent/KR20010053468A/ko not_active Ceased
- 1999-07-12 JP JP2000559216A patent/JP2002520446A/ja not_active Withdrawn
- 1999-07-12 AU AU50961/99A patent/AU5096199A/en not_active Abandoned
- 1999-07-12 CA CA002336623A patent/CA2336623C/en not_active Expired - Fee Related
- 1999-07-12 MA MA25673A patent/MA24924A1/fr unknown
- 1999-07-12 CZ CZ20004657A patent/CZ20004657A3/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69829044T2 (de) | 2006-02-09 |
| CA2336623A1 (en) | 2000-01-20 |
| JP2002520446A (ja) | 2002-07-09 |
| WO2000002994A1 (en) | 2000-01-20 |
| MA24924A1 (fr) | 2000-04-01 |
| BR9911986A (pt) | 2001-03-27 |
| CZ20004657A3 (cs) | 2001-09-12 |
| AR019366A1 (es) | 2002-02-13 |
| ATE289347T1 (de) | 2005-03-15 |
| DE69829044D1 (de) | 2005-03-24 |
| CN1309691A (zh) | 2001-08-22 |
| AU5096199A (en) | 2000-02-01 |
| KR20010053468A (ko) | 2001-06-25 |
| EP0971029B1 (de) | 2005-02-16 |
| EP0971029A1 (de) | 2000-01-12 |
| ES2238754T3 (es) | 2005-09-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |