CA2334014A1

CA2334014A1 - Desiccant blended in a thermoplastic

Info

Publication number: CA2334014A1
Application number: CA002334014A
Authority: CA
Inventors: Ihab M. Hekal
Original assignee: Individual
Current assignee: CSP Technologies Inc
Priority date: 1998-06-04
Filing date: 1999-05-25
Publication date: 1999-12-09
Also published as: WO1999062697A1; AU4204799A; EP1112175A1; CN1308574A; WO1999062697A9; BR9910917A; NO20006172L; JP2002516917A; NO20006172D0; EP1112175A4

Abstract

The present invention relates to a package or container (01) having desiccating abilities. The package or container (01) includes an insert (200 ) in the shape of a plug, film, sheet or pellet having desiccating abilities that is included in the package or container (01). Alternatively, the insert (200) may be molded within the body (12) of the package or container. The insert (200) is formed by blending a desiccant and thermoplastic.

Description

WO 99/62697 PC'T/US99/11565 DESICCANT BLENDED IN A THERMOPLASTIC

3 FIELD OF INVENTION:

4 The present invention relates to packages having desiccating abilities. More S particularly, the present invention relates to a thermoplastic having a desiccant blended therein.
6 BACKGROUND OF THE INVENTION:
7 There are many articles that are preferably stored, shipped and/or utilized in an 8 environment that is as moisture free as possible. Therefore, containers and/or packages having 9 the ability to absorb excess moisture trapped therein have been recognized as desirable. One application in which moisture absorbing containers are desired is for the shipment and storage of 11 medications whose efficacy is compromised by moisture. The initial placement of medicines 12 into a sealed moisture free container is usually controllable. Furthermore, the container for the 13 medicine is selected so that is has a low permeability to moisture.
Therefore, the medication will 14 normally be protected from moisture until it reaches the end user. Once the medicine is received by the customer, however, the container must be repeatedly opened and closed to access the 16 medication. Each time the container is opened and unsealed, moisture bearing air will most 17 likely be introduced into the container and sealed therein upon closure.
Unless this moisture is 18 otherwise removed from the atmosphere or head space of the container, it may be detrimentally 19 absorbed by the medication. For this reason, it is a well known practice to include a desiccating unit together with the medication in the container.
21 In other instances, moisture may be released from items that have been placed in 22 containers or sealed in packaging wrap for shipping and/or storage. Prime examples of such 23 items are food stuffs that release moisture during shipping and storage. In the instance of 24 containers that are sealed and substantially impermeable to moisture, the released moisture will remain within the container. If not removed, this released moisture may have ill effects on the 26 very item that released the moisture. It has been found that a substantial amount of moisture is 27 released from certain food products within the first forty-eight (48) hours after manufacture and 28 packaging. This released moisture will remain until removed. If the moisture is not removed 29 shortly after its release, it may cause the food to degrade into a condition that is not saleable and/or useable. In these cases, desiccants may be included together with the contained item or 31 items to continually absorb the released moisture until the product is unpacked. In this way, a 32 . relatively dry environment is maintained about the stored item.
33 The need to eliminate moisture from within sealed containers has been previously 34 recognized. Early attempts to achieve these goals included the provision of desiccant materials in fabric or similar bags that are placed in the containers together and commingled with the matter 36 being shipped or stored. A consumer related problem, however, exists when the desiccant is 37 loose and commingled together with consumable items. If not carefully and thoroughly SUBSTITUTE SHEET (RULE 26) 1 processed upon unpacking, the desiccant may not be separated from the consumables and could 2 harm a person if unknowingly ingested.
3 , Another known mode by which a desiccant may be provided within a container includes 4 coating.the interior surface of the container vessel with a desiccant bearing material. Still further, S it is known to provide desiccating abilities in a container through the use of layered structures in 6 which a desiccant is "sandwiched" between moisture permeable material that confines the 7 desiccant. These layered structures often take the form of flexible sheeting that may be formed 8 into bag type containers into which items requiring a reduced moisture environment are placed.
9 Several of the known means by which desiccant bearing containers are constructed require multiple steps and result in more complex and layered structures than are desired.
1 I Furthermore, the provision of desiccant capsules together with contained items is not always 12 satisfactory. As previously explained, commingling of desiccant with food items and 13 medications is undesirable from a consumer stand point in that the desiccant may be 14 inadvertently ingested. Still further, if the desiccant is not integrally constructed with the container, or at least attached thereto, it may be prematurely removed while still needed for 16 continued removal of moisture from within the container. Therefore, a need has been recognized 17 for containers that include a desiccant as an integral component of the container's body or 18 package. Regarding the included desiccant of the container, it is desired to enhance its 19 capabilities of moisture absorption with respect to both rate and quantity.
Still further, as in all manufacturing processes, it is desired to reduce the required steps for constructing desiccating 21 containers and simplify the resulting structures.
22 SUMMARY OF THE INVENTION:
23 In one embodiment of the present invention, a container, and process for constructing 24 the container is provided that satisfies the need for more effective desiccating storage and shipping containers. The containers of the present invention provide superior desiccating 26 abilities, while at the same time permitting efficient construction of a container that has and 27 maintains structural integrity. Furthermore, the present invention provides a means by which the 28 container may be formed having a substantially unitized and continuous body. In another 29 embodiment, the present invention may be used to form an insert, integral or non-integral, for the container or package in the form of a shaped article such as a sheet, film, or pellets, for example, 31 in the base or bottom of the container and not capable by itself of containing the contents of the 32 container.
33 BRIEF DESCRIPTION OF DRAWINGS:
34 Figure I is a cross-sectional view of a desiccating cantainer with an insert in the form of a disc molded therein.
36 Figure 2 is a cross-sectional view of a desiccating container with an insert in the form of 37 a liner molded therein.
SUBSTITUTE SHEET (RULE 26) WO 99/6269'I PC'T/US99/11565 Figure 3 is a partial cross-sectional view of the container body showing a lip retainer.
2 Figure 4 is a side view of a mold in partial section mounted upon a rotatable table for 3 transport between injection stations and showing a container and insert molded therein.
4 Figure 5 is a side view of a mold in partial section showing a container and insert molded therein in a single station configuration with two injection ports.
6 Figure 6 is a schematic of the method by which the container is co-molded.
7 Among those benefits and improvements that have been disclosed, other objects and 8 advantages of this invention will become apparent from the following description taken in 9 conjunction with the accompanying drawings. The drawings constitute a part of this specification and include exemplary embodiments of the present invention and illustrate various 11 objects and features thereof.
12 DETAILED DESCRIPTION OF THE INVENTION:
13 As required, detailed embodiments of the present invention are disclosed herein;
14 however, it is to be understood that the disclosed embodiments are merely exemplary of the 1 S invention that may be embodied in various forms. The figures are not necessarily to scale, some 16 features may be exaggerated to show details of particular components.
Therefore, specific 17 structural and functional details disclosed herein are nat to be interpreted as limiting, but merely 18 as a basis for the claims and as a representative basis for teaching one skilled in the art to 19 variously employ the present invention.
The presently disclosed invention includes and is applicable to the manufacture of 21 similar containers. The containers O1 disclosed herein, however, are not limited to vials. It is 22 contemplated that containers O1 constructed according to the present invention may be larger or 23 smaller than the vials of 4,783,056 and of variable shape. Furthermore, the caps 14 may be 24 integrally formed with the bodies 12 of the containers O1, or they may be manufactured as separate units. Still further, the present invention may be embodied exclusively within the body 26 of a container 12 or a cap 14 for a container O 1.
27 The material used in the construction of these containers O l typically provides a barner 28 between the interior 201 and exterior 202 of the container O1 that is substantially moisture 29 impermeable and most often is a thermoplastic. While it is contemplated that any thermoplastic may be utilized, polypropylene is preferred for the constructian of the body 12 of the container 31 O1. Polypropylene is desirable because of its durability, rigidity and resistance to breakage after 32 being molded into the form of a container 01. Examples of suitable thermoplastics may be 33 selected from the following groups: polyolefin, polyethylene, polycarbonate, polyamide, 34 ethylene-vinyl acetate copolymer, ethylene-methacrylate copolymer, polyvinyl chloride, polystyrene, polyester, polyester amide, polyacrylic ester. and poIyvinylidene chloride, acrylic, 36 polyurethane, polyacetal, and polycarbonate. These and other thermoplastics may be utilized 37 either singularly, or in combinations.
SUBSTITUTE SHEET (RULE 26) The present invention includes the manufacture of a container O1 in which the majority 2 of the container's body l2 is constructed from the base thermoplastic, e.g.
polypropylene, 3 because of its durability and resistance to breakage. To establish and/or increase a desiccating 4 capacity of the molded container O1, an insert 200 that has been formed from a desiccant S entrained thermoplastic is integrally constructed with the body 12 of the container O 1. The heat 6 molded insert of the present invention consists essentially of the thermoplastic material with the 7 entrained desiccant. The term "consisting essentially of ' is used herein to denote that the molded 8 insert may contain other materials so long as they do not materially effect the moisture removal 9 properties of the insert. For example, the heat molded insert may have also entrained carbon black or other coloring agents to provide color or other aesthetic properties to the insert.
11 The concentration of desiccant entrained (e.g. mixed or blended) within the insert 200 12 may exceed seventy-five percent (75%) to not greater than eighty percent (80%) by weight, so 13 that about seventy-five percent (75%) may extend to eighty percent (80%) by weight. Typically, 14 however, the desiccant concentration in the insert 200 will fall within a range of forty to seventy-five (40-75%) desiccant to thermoplastic, by weight. This concentration is considered to be a 16 high concentration for most thermoplastics. The maximum desiccant bearable concentrations 17 will vary among the various types of thermoplastics due to their differing characteristics. In the 18 instance of polyethylene or polypropylene, for example, the maximum concentration of desiccant 19 will be about seventy-five percent (75%) by weight. As the desiccant concentrations within the thermoplastics increase, the performance of the material degenerates to unacceptable levels. At 21 lower levels of desiccant concentrations, about forty percent (40%) could extend to as low as 22 thirty percent (30%) where the limits of a viable product are reached.
23 In one embodiment, the insert 200 is located in the base or bottom 203 of the container 24 body 12 and is exposed to the interior space 201 of the container O 1. The configuration of this embodiment is similar to a sample vial. Because the durability and resistance to breakage is 26 lessened in the higher ranges of desiccant content, it is advantageous to have the polypropylene 27 used in the construction of the container's body 12 formed about the insert 200 except for at 28 those surfaces to be exposed to the interior 201 of the container O1. A
container O 1 of this 29 configuration provides desired structural integrity while also providing the greater desiccating ability of the high desiccant laden insert 200 that is directly exposed to the interior 201 of the 31 container O1. It is also contemplated that the insert 200 may be included in the construction of 32 the container's cap 14. In this case, the insert will be integrally formed with the cap 14 so that an 33 exterior surface of the insert 200 is exposed to the interior 201 of the container O 1 when installed 34 thereupon.
As a further alternative embodiment, the insert 200 may be less localized, and extended 36 to a greater degree about a greater portion of the interior surface 204 of the container body 12. In 37 this instance, the high desiccant bearing thermoplastic forms more of a liner 205 at the interior SUBSTITUTE SHEET (RULE 26) WO 99/62697 ' PCT/US99/11565 1 surface 204 of the container O 1. To provide maximum desiccating abilities, the liner 205 may 2 completely cover the interior surface 204 of the container 01; this may optionally include the 3 interiorly exposed surfaces of a cap 14 of a closed container O 1.
4 One contemplated method for the manufacture of the container O1 includes the provision of a performed insert 200 about which the thernuoplastic of the remainder of the body 6 12 of the container O l is injection molded. In this process, it is important that the insert 200 be 7 affixed to or within the body 12 of the container O 1. This may be achieved merely by molding 8 the body 12 about the insert 200 so that the two components are mechanically connected one to 9 the other. The mechanical connection may take the form of a retaining lip 206 formed by the container body 12 about the insert 200 that effectively fixes the insert 200 with respect to the rest 11 of the body O 1.
12 As shown by the various embodiments of the present invention, the insert of the present 13 invention is formed by heat molding the desiccant entrained thermoplastic of the present 14 invention. For example, the insert may be heat molded using any conventional technique such as co-extruding, extrusion blow moulding, injection blow molding, reaction injection moulding or 16 extruding.
17 Alternatively, it is also contemplated that a "shrink-fit" may be achieved by the body 12 18 forming thermoplastic about the insert 200. A particular example of this shrink-fit application 19 would be the provision of a desiccant loaded insert 200 constructed from a base thermoplastic of polyethylene and a container body 12 molded thereabout from a base thermoplastic of 21 polypropylene. Upon cooling after being injection molded, palyethylene shrinks less than 22 polypropylene under similar circumstances. Therefore, if a polypropylene body is injection 23 molded about a polyethylene insert 200 that has been either previously formed, or is injection 24 molded contemporaneously with the container body 12, the polypropylene container body 12 will shrink about the polyethylene insert 200. This shrink-fit method may be implemented whether or 26 not the insert 200 is relatively small and localized with respect to the container body 12 or 27 whether or not the insert 200 is relatively small and localized with respect to the container body 28 12 or whether the insert 200 takes the form of a previously described liner 205 configuration. In 29 either case, the exteriorly formed container body 12 may shrink about the insert 200 if the thermoplastics from which the insert 200 and container body l2 are appropriately selected. The 31 use of the retaining lip 206 and shrink-fit method of affixing the insert 200 or liner 205 to the 32 container body 12 is used primarily when the materials of construction of the insert 200 and 33 container body 12 are not compatible. The two components will be considered incompatible if 34 they do not automatically adhere one to the other as a result of the manufacturing process.
Alternatively, the insert 200 will be constructed from a material that bonds to the body 36 12 of the container O 1 when the body 12 is placed thereabout. Therefore, one method for 37 constructing the insert 200 bearing container O 1 of the present invention is co-molding. That is, SUBSTTfUTE SHEET (RULE 26) 1 the primary body 12 of the container O l is molded, while the high desiccant insert 200 is also 2 molded. The two portions are said to be co-molded because they are either simultaneously or 3 sequentially injection molded in a single process. The process of co-molding results in the 4 construction of a unitized container body 12 in which the insert 200 is seamlessly combined with the body 12. In most instances, the insert 200 and container body 12 adhere one to the other as a 6 result of a melding together of the base thermoplastics from which each is constructed at an 7 interface therebetween. The melding action takes place when the insert 200 and container body 8 12 are each injected into the mold 10 sufficiently closely with respect to time so that each is in at 9 least a semi-molten state while in contact one with the other.
.Alternatively, heat from the thermoplastic of a body 12 injected about an insert 200 may cause the contacted portions of the 11 insert 200 to melt slightly and meld with the thermoplastic of the body 12 adjacent thereto. In 12 each case, there will be a phase between the high desiccant concentrate insert 200 and container 13 body 12 in which the two construction materials blend to some degree creating a seamless 14 interface and therefore unitized container O1 out of the two components.
In any event, the thermoplastic in which the desiccant is entrained is moisture 16 permeable to the degree that moisture from the interior 201 of the container O1 may be 17 transferred to and stored in the desiccant. It is possible that the thermoplastic from which the 18 insert 200 is manufactured may have a higher moisture permeability than that from which the 19 remainder of the body 12 of the container O1 is constructed. In this case, the insert 200 may be enclosed within the container O1 by a lower moisture permeable thermoplastic of the container's 21 body 12. In this way, moisture will not readily be transferred from outside the container O1 to the 22 interior. In view of the possibility of desiring differing moisture permeabilities in the insert 200 23 and the container body 12, it is contemplated that the two components 200, 12 may be 24 constructed from different materials that are potentially incompatible.
The process of the present invention in which the insert 200 is co-molded within the 26 primary body 12 of the container O 1 may vary. In a first embodiment of the molding process, it 27 is contemplated that the mold 10 will move between two injection stations.
An injection 28 assembly that is generally designated by reference numeral 9ti may be installed and withdrawn 29 from the mold frame 24. At one station, typically the first station, the insert 200 will be injection molded. In order to mold the insert 200, a ring shaped barner will be provided that has a 31 circumference substantially matching the perimeter of a lower end of care 48. It is desired that 32 the thickness of the insert 200 be approximately one-eighth of an inch, therefore the thickness or 33 height of the barrier ring will likewise be one-eighth of an inch. As the injection assembly 96 is 34 installed within the mold frame 24, the barrier ring is the leading component. The ring contacts the lower surface of the core 48 forming a barner within which thermoplastic may be injected.
36 High concentrate desiccant thermoplastic is then injected into the interior of the ring thereby 37 forming the insert 200. The high concentrate desiccant thermoplastic of the insert 200 may be b SUBSTTTUTE SHEET (RULE 26) t injected at a temperature that is less than the temperature at which the thermoplastic of the 2 container body l2 is injected. The lowered temperature may be required so that the desiccant 3 contained therein does not degrade. The necessity of the lowered temperature may be obviated 4 by using different and/or high-grade desiccants that are not susceptible to degradation within the normal temperature ranges of the injection process.
b It is anticipated that the rate of absorption into the insert 200 may be controlled by the 7 amount of surface area of the insert 200 exposed to the container's O I
interior 201. If greater 8 absorption rates are desired, more surface area of the insert 200 may be exposed. If it is desired 9 that a more prolonged absorption process be achieved, then less surface area will be exposed. It is further contemplated that the rate of absorption by the insert. 200 may be controlled by 11 encapsulation of the insert 200. If slower rates of absorption are desired, then the insert 200 can 12 be encased to greater degrees by the thermoplastic that forms the body 12 of the container O1 and 13 which is less permeable to moisture. The rate of absorption may also be controlled by using 14 different types of thermoplastics having different moisture permeability rates. Unless otherwise specified, the moisture permeability rates of the thermoplastics of the present invention are 16 determined by ASTM test method F 1249-90, entitled "Standard Test Method for Water Vapor 17 Transmission Rate Through Plastic Film and Sheeting Using a Modulated Infrared Sensor."
18 Using ASTM F 1249-90 test method, the thermoplastics suitable for the present invention have a 19 moisture vapor transmission rate of less than about 30g/mil/100 in2/24 hours.
For example, polyethylene typically has a moisture vapor transmission rate of about 3 21 to about S gm per mil per I 00 square inches per 24 hours. In one embodiment, the polyethylene 22 that is suitable in the present invention is made by Dow Chemical Co. and has a tradename of 23 polyethylene 4012. In another example, polypropylene homopolymer typically has a moisture 24 vapor transmission rate below 10 gm per mil per 100 square inches per 24 hours. In one embodiment, the polypropylene that is suitable in the present invention is made by Exxon 26 Chemicals and has a tradename of Escorenea Polypropylene--PP 35056. In a further example, 27 low density polyethylene butene copolymer typically has a moisture vapor transmission rate of 28 about 1 to about 2 gm per mil per 100 square inches per 24 hours. In one embodiment, the low 29 density polyethylene butene copolymer that is suitable in the present invention is made by Union Carbide Corp. and has a tradename of GRSN-1539.
31 The amount of moisture that can be absorbed by the insert 200 may be controlled in 32 several ways. It is contemplated that the amount of moisture absorbable by the insert 200 may be 33 effected by changing the concentration of desiccant within acceptable ranges; the greater the 34 concentration, the greater the amount of moisture that can be captured.
In an alternative embodiment, the thermoplastic from which the body 12 is constructed 36 may also have desiccant entrained and suspended therein, but in lesser concentrations than the 37 insert 200. It has been found that the concentration of desiccant in the thermoplastic affects the SUBSTITUTE SHEET (RULE 26) 1 performance characteristics of the molded container O 1. As an example, it has been found that 2 while,the plastic will carry relatively high percentages of desiccant, desirable characteristics such 3 as durability and resistance to breakage may degrade at higher desiccant concentrations. It has 4 also been found that the plastic may be combined with lower concentrations of desiccant without S appreciably degrading the performance of the thermoplastic material in its molded and solid state.
6 In a typical application, a relatively low concentration will fall within the rate of five to fifteen 7 percent (5 - I S%) desiccant by weight to thermoplastic, with a preferred concentration being 8 approximately seven and one-half (7.5%). Additionally, for the purpose of the disclosure made 9 herein, desiccant-free thermoplastic may also be considered low concentration thermoplastic. In another embodiment, the thermoplastic having the lower concentration of desiccant is molded 11 with the thermoplastic having the higher concentration of desiccant. That is, the primary body 12 12 of the container O1 is molded, while the high desiccant insert 200 is also molded. The two 13 portions are said to be co-molded. This process results in a unitized contained body 12.
14 Various concentrations of desiccant bearing thermoplastic are commercially available in pellet form. Custom concentrations may be achieved by dry blending higher concentration 16 desiccant pellets with lower concentration or desiccant-free pellets of thermoplastic. When 17 blended in appropriate proportions, any desiccant concentration less than that of the high 18 concentration desiccant pellets may be accomplished. After the drying blending process, the 19 resulting mixture of pellets may be injection molded in a typical manner.
The type of desiccants that are suitable for use in the present invention obtain their 21 moisture adsorbing capabilities through physical adsorption. The adsorption process is 22 accomplished because of a fine capillary morphology of the desiccant particles which pulls 23 moisture therethrough. The pore size of the capillaries, as well as the capillaries' density 24 determine the absorption properties of the desiccant. Examples of these physical adsorption desiccants include molecular sieves, silica gels, clays and starches. In several embodiments, the 26 molecular sieve pore sizes that are suitable for use in the present invention include between about 27 3 to 15 Angstroms; about 3 to S Angstroms, about 5 to 8; 3 Angstroms; 4 Angstroms; S
28 Angstroms; 8 Angstroms and 10 Angstroms. In one embodiment, the pore size of silica gel is 29 about 24 Angstroms. Because these types of physical adsorption desiccants are both inert and non-water soluble, they are preferred for many applications. Among other reasons, these 31 innocuous characteristics are particularly compatible with food products and medicinal products 32 such as pharmaceutical drugs and devices that may be enclosed within containers formed from 33 the desiccant entrained polymers, or at least exposed thereto. As stated previously, however, any 34 of the three types may be employed within the polymer bases of the present invention for the purposes of producing a desiccant entrained polymer. Suitable desiccating agents of the present 36 invention include silica gel, molecular sieve and naturally occurring clay compounds which 37 would also include montmorillimite clay.

SUBSTTTUTE SHEET (RULE 26) WO 99/b2697 PCT/US99/11565 1 In another embodiment of the present invention. the desiccant that is suitable for use in 2 the present invention is zinc chloride. This type absorbs water or moisture and forms crystals of 3 a stable salt.
4 One of the many advantages of the present invention is that the molded insert can be S produced by mixing the components, heating and molding the mixture. The mixing conditions 6 are chosen so that the desiccant is sufficiently entrained by substantially uniformly blending in 7 the thermoplastic. For example, the components are mixed using a conventional mixer, for 8 example, a Hensehel mixer. The present invention does not require further processing by 9 stretching (e.g. uniaxial or biaxial orientation method) or expanding (e.g.
stretching at fast rates then exposing the material to its crystalline melt point) to produce a porous material.
11 The present invention is particularly suited for applications where a product's (e.g.
12 pharmaceutical drug or device) efficacy may be compromised by a threshold amount of moisture.
13 Unless the moisture above this threshold amount is removed within a certain time period, this 14 moisture may detrimentally affect the product. The present invention solves this problem by removing this excess moisture within the desired time period. This is achieved by the present 16 heat molded insert having a combination of: (a) a thermoplastic having certain moisture vapor 17 transmission rate characteristics; (b) a certain type of desiccant; (c) the insert having a certain 18 minimum and maximum weight % of desiccant; and (d) the insert having a minimum moisture 19 adsorption after 8 hours at 10% relative humidity ("Rh") without stretching or expanding. As a result, the novel insert has previously unattained moisture adsorption in packaging applications.
21 Unless otherwise specified, the % Rh is measured at 72°F by the test method described in 22 Example 1.
23 Desiccant entrained plastic structures, and their constituent compounds have been 24 described herein. As previously stated, detailed embodiments of the present invention are disclosed herein; however, it is to be understood that the disclosed embodiments are merely 26 exemplary of the invention that may be embodied in various forms. It will be appreciated that 27 many modifications and other variations that will be appreciated by those skilled in the art are 28 within the intended scope of this invention as claimed below without departing from the 29 teachings, spirit and intended scope of the invention.
The present invention will be illustrated in greater detail by the following specific 31 examples. It is understood that these examples are given by way of illustration and are not meant 32 to be limited to the disclosure or claims. For example, although the following examples were 33 tested at 10% and 55% Rh at 72°F, the insert of the present invention is also suited for other Rh 34 conditions. All percentages in the examples are elsewhere in the specification are by weight unless otherwise specified.

SUBSTITUTE SHEET (RULE 26) 1 This example illustrates a desiccant blended in a thermoplastic consisting essentially of 2 a thermoplastic of polypropylene (Exxon Chemicals, tradename Escorenea Polypropylene 3 3505G) and a desiccant of molecular sieve (Elf Atochem, tradename Siliporitea molecular sieves;
4 NK 10). The desiccant and thermoplastic were weighed to achieve the weight percent of each shown in the table. The desiccant and thermoplastic were then mixed in a Henschel FM-200 high 6 intensity mixer. The material was then fed to a Leistritz twin screw extruder at a temperature in 7 the ten zones ranging from about 200° to 320°F, at about 400 rpm and at about 30 Ibs./hr to 8 produce a pelletized material of about 1 /8 inch diameter. The pelletized material was fed directly 9 to a hot roll press. A film was formed of desired thickness ( 10 mil).
The film was then evaluated for moisture adsorption of its total weight by using the 11 following test method (a) the environmental chamber was preset for 72°F and the desired 12 relative humidity ("Rh"); (b) the dish was weighed and the weight recorded;
(c) the scale was 13 then tared to remove the weight of the dish from the balance; (d) the film was then added to the 14 weighed dish; (e) the material was then weighed and the weight recorded;
(f) the weigh dish I S with the sample was placed in the environmental chamber; (g) the sample was left in the I 6 chamber for the desired time; (h) after the desired time was reached, the dish with the sample 17 was removed, re-weighed and the weight recorded; and (i) percent of moisture absorbed per 18 gram of material was calculated by:
19 final weight - original weig_,ht * 100 original weight 22 The results are presented in Table I.
SUBSTITUTE SKEET (RULE 26) 2 % Moisture Adsorption 3 % desiccant 10% Rh 55%Rh 4 per total weight 8hr 24 hr 8 hr 24 hr 10 .5 .8 .S .6 6 20 .7 1.0 .7 1.3 7 30 .7 1.0 1.5 1.9 8 60 1.5 2.6 3 4.5 9 70 4 6 8 11.5 12 This example illustrates a desiccant blended in a thermoplastic consisting essentially of a 13 thermoplastic of a low density polyethylene butene copolymer (Union Carbide, tradename 1137) 14 and of a desiccant of molecular sieve (Elf Atochaem, tradename Siliporitea molecular sieves, NK10). The desiccant and thermoplastic were prepared in a manner similar to the method 16 discussed in Example 1 to produce a pellet. The pellet was then formed into a film by using a 17 platen press. The pellet was placed in the press between 2 sheets of Mylar film. The pellet was 18 pressed at 425°F at 25 tons for about I S-20 seconds. The desired thickness was achieved by 19 placing shims inside press. The film was removed and allowed to cool for about 15-20 seconds and then placed in a vacuum sealed brown bag. The film was also evaluated by the same method 21 as discussed in Example 1. The results are presented in Table II.

23 % Moisture ption Adsor 24% desiccant Film 10% Rh 55%Rh 25per total weiehtThickness (mil)8hr 24 hr 8 hr 24 hr 2650 3.5 3 S.5 4.5 7 2750 10 1.5 3 3 5 2860 S 2.5 4.5 3.5 6.5 2960 10 2 3.5 3 5 3170 30 1 2 1.5 3 3270 53 2 4 3.5 6.5 3380 20 1 2 1.5 3 3480 44 1.5 3 2 4 3580 90 2 3 2.5 4 37The previous examples demonstratethat an insert can be produced, within the scope of the 38 present invention, by adjusting the following parameters: (a) type of thermoplastic; (b) desiccant 39 loading level; (c) thickness of insert; and (d) type of desiccant..
SUBSTITUTE SHEET (RULE 26)

Claims

1. A heat molded insert consisting essentially of desiccant entrained in thermoplastic wherein: (a) the thermoplastic has a moisture vapor transmission rate of less than about 30 grams per mil thickness per 100 square inches in area per 24 hours, (b) the desiccant is selected from the group consisting of molecular sieve, silica gel, clay and zinc chloride, (c) the insert has between about 40 and about 75 weight % of desiccant by weight of the desiccant and thermoplastic content of the molded insert, and (d) the molded insert is capable of adsorbing without stretching or expanding at least 1% moisture by weight of its total weight after 8 hours at 10% relative humidity.

2. A heat molded insert as claimed in claim 1 wherein the molded insert is capable of adsorbing without stretching or expanding at least 2.5% moisture by weight of its total weight after 8 hours at 55% relative humidity.

3. The desiccant molded article of claim 1, wherein the thermoplastic is selected from the group consisting of polyolefins, polycarbonates and polyamides.

4. The desiccant molded article of claim 2, wherein the thermoplastic is selected from the group consisting of polyolefins, polycarbonates and polyamides.