CA2325018A1 - Stabilised quaternary ammonium compositions - Google Patents
Stabilised quaternary ammonium compositions Download PDFInfo
- Publication number
- CA2325018A1 CA2325018A1 CA002325018A CA2325018A CA2325018A1 CA 2325018 A1 CA2325018 A1 CA 2325018A1 CA 002325018 A CA002325018 A CA 002325018A CA 2325018 A CA2325018 A CA 2325018A CA 2325018 A1 CA2325018 A1 CA 2325018A1
- Authority
- CA
- Canada
- Prior art keywords
- quaternary ammonium
- ammonium material
- stabilising agent
- group
- stabilising
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Abstract
Stabilised compositions comprising quaternary ammonium material containing at least one ester group characterised in that they further comprise one or more stabilising agents containing at least one ester group via the steps of adding at least one stabilising agent to the quaternary ammonium material, wherein the stabilising agent is a strong hydrogen bond donor is also provided.
Claims (7)
1. Stabilised compositions comprising quaternary ammonium material represented by the formula:
wherein each R1 group is independently selected from C1-4 alkyl, hydroxyalkyl or C2-4 alkenyl groups; and wherein each R2 group is independently selected from C8-28 alkyl or alkenyl groups; X- is any suitable counter-ion.~~~
T is or ; and n is an integer from 1-5 or is 0 characterised in that they further comprise one or more stabilising agent(s) wherein the one or more stabilising agents are strong hydrogen bond donors and are present at levels of 0.05 to 10% of the weight of the quaternary ammonium material, preferably 0.5 to 6.0%, even more preferably 0.5 to 4%, with the proviso that the composition is in a liquid, molten, semi-solid or solid form containing less than 10% by weight water.
wherein each R1 group is independently selected from C1-4 alkyl, hydroxyalkyl or C2-4 alkenyl groups; and wherein each R2 group is independently selected from C8-28 alkyl or alkenyl groups; X- is any suitable counter-ion.~~~
T is or ; and n is an integer from 1-5 or is 0 characterised in that they further comprise one or more stabilising agent(s) wherein the one or more stabilising agents are strong hydrogen bond donors and are present at levels of 0.05 to 10% of the weight of the quaternary ammonium material, preferably 0.5 to 6.0%, even more preferably 0.5 to 4%, with the proviso that the composition is in a liquid, molten, semi-solid or solid form containing less than 10% by weight water.
2. A composition according to claim 1 wherein the stabilising agent is chosen from one or more of the group comprising:
a) urea, b) urea derivative c) primary or secondary amides, and/or d) polyhydric alcohols.
a) urea, b) urea derivative c) primary or secondary amides, and/or d) polyhydric alcohols.
3. Process of stabilising quaternary ammonium material represented by the formula:
wherein each R1 group is independently selected from C1-4 alkyl, hydroxyalkyl or C2-4 alkenyl groups; and wherein each R2 group is independently selected from C8-28 alkyl or alkenyl groups; X- is any suitable counter-ion.
T is ; and n is an integer from 1-5 or is 0 via the steps of adding at least one stabilising agent to the quaternary ammonium material, wherein the stabilising agent is a strong hydrogen bond donor and is present at levels of 0.05 to 10% of the weight of the quaternary ammonium material, preferably 0.5 to 6.0%, even more preferably 0.5 to 4%, with the proviso that the composition is in a liquid, molten or semi-solid form containing less than 10% by weight water.
wherein each R1 group is independently selected from C1-4 alkyl, hydroxyalkyl or C2-4 alkenyl groups; and wherein each R2 group is independently selected from C8-28 alkyl or alkenyl groups; X- is any suitable counter-ion.
T is ; and n is an integer from 1-5 or is 0 via the steps of adding at least one stabilising agent to the quaternary ammonium material, wherein the stabilising agent is a strong hydrogen bond donor and is present at levels of 0.05 to 10% of the weight of the quaternary ammonium material, preferably 0.5 to 6.0%, even more preferably 0.5 to 4%, with the proviso that the composition is in a liquid, molten or semi-solid form containing less than 10% by weight water.
4. A process according to claim 3 wherein the stabilising agent is chosen from one or more of the group comprising a) urea, b) urea derivative c) primary or secondary amides, and/or d) polyhydric alcohols.
5. Process according to either claim 3 or 4 wherein the step of adding at least one stabilising agent occurs during the manufacture of the quaternary ammonium material, preferably following the quaternisation step in the synthesis of the quaternary ammonium material.
6. Process according to either claim 3 or 4 wherein the step of adding at least one stabilising agent occurs after manufacture of the quaternary ammonium material, preferably during storage of the quaternary ammonium material.
7. Use of a stabilising agent as defined in claim 1 or claim 2 to reduce the level of discoloration of quaternary ammonium material containing at least one ester group.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9810655.2A GB9810655D0 (en) | 1998-05-18 | 1998-05-18 | Stable ammonium compositions |
| GB9810655.2 | 1998-05-18 | ||
| PCT/EP1999/003366 WO1999060081A1 (en) | 1998-05-18 | 1999-05-12 | Stabilised quaternary ammonium compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2325018A1 true CA2325018A1 (en) | 1999-11-25 |
| CA2325018C CA2325018C (en) | 2010-07-13 |
Family
ID=10832260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2325018A Expired - Fee Related CA2325018C (en) | 1998-05-18 | 1999-05-12 | Stabilised quaternary ammonium compositions |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP1080171B1 (en) |
| JP (1) | JP2002515551A (en) |
| CN (1) | CN1192083C (en) |
| AR (1) | AR016032A1 (en) |
| AU (1) | AU732651B2 (en) |
| BR (1) | BR9910549B1 (en) |
| CA (1) | CA2325018C (en) |
| CZ (1) | CZ300743B6 (en) |
| DE (1) | DE69923175T2 (en) |
| ES (1) | ES2234259T3 (en) |
| GB (1) | GB9810655D0 (en) |
| HU (1) | HUP0101910A3 (en) |
| PL (1) | PL190329B1 (en) |
| RO (1) | RO121133B1 (en) |
| RU (1) | RU2220190C2 (en) |
| TR (1) | TR200003386T2 (en) |
| WO (1) | WO1999060081A1 (en) |
| ZA (1) | ZA200006734B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0207484D0 (en) * | 2002-03-28 | 2002-05-08 | Unilever Plc | Solid fabric conditioning compositions |
| US20090312428A1 (en) | 2008-06-13 | 2009-12-17 | Fernando Figueredo | Biocide Compositions Comprising Quaternary Ammonium and Urea and Methods for Their Use |
| MA34103B1 (en) * | 2010-04-01 | 2013-03-05 | Evonik Degussa Gmbh | An effective formula for the fabric binder |
| EP2385099A1 (en) * | 2010-05-06 | 2011-11-09 | The Procter & Gamble Company | Process of making liquid fabric softening compositions |
| WO2014003180A1 (en) * | 2012-06-29 | 2014-01-03 | ライオン株式会社 | Liquid fabric softener composition |
| NZ756322A (en) * | 2017-03-01 | 2021-12-24 | Ecolab Usa Inc | Mechanism of urea/solid acid interaction under storage conditions and storage stable solid compositions comprising urea and acid |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2454465A1 (en) * | 1974-11-16 | 1976-05-20 | Hoechst Ag | Powdery germ inhibiting soft rinsing compsns for textiles - contg cationic soft rinse, cationic disinfectant, urea and non ionic dispersant |
| EP0258923B1 (en) * | 1986-09-02 | 1993-10-06 | Akzo Nobel N.V. | Fabric softening composition and detergent-composition comprising the same |
| US5282983A (en) * | 1990-08-22 | 1994-02-01 | Kao Corporation | Fabric softener composition and ammonium salt |
| US5259964A (en) * | 1991-12-18 | 1993-11-09 | Colgate-Palmolive Co. | Free-flowing powder fabric softening composition and process for its manufacture |
| US5543067A (en) * | 1992-10-27 | 1996-08-06 | The Procter & Gamble Company | Waterless self-emulsiviable biodegradable chemical softening composition useful in fibrous cellulosic materials |
| DE4307186A1 (en) * | 1993-03-08 | 1994-09-15 | Henkel Kgaa | Aqueous fabric softener composition |
| DE4308792C1 (en) * | 1993-03-18 | 1994-04-21 | Henkel Kgaa | Stabilised quaternised fatty acid tri:ethanolamine ester salt(s) prodn. - having stable colour and odour characteristics |
| CZ4999A3 (en) * | 1996-07-11 | 1999-05-12 | The Procter & Gamble Company | Polyhydroxyl solvent, which is substantially without aroma, process of its preparation and a liquid detergent and brightening agent for substances in which it is comprised |
| DE19629666A1 (en) * | 1996-07-23 | 1998-01-29 | Henkel Kgaa | Process for the hydrophilic finishing of fibers or nonwovens |
-
1998
- 1998-05-18 GB GBGB9810655.2A patent/GB9810655D0/en not_active Ceased
-
1999
- 1999-05-12 EP EP99924984A patent/EP1080171B1/en not_active Expired - Lifetime
- 1999-05-12 CZ CZ20004292A patent/CZ300743B6/en not_active IP Right Cessation
- 1999-05-12 CN CNB998061689A patent/CN1192083C/en not_active Expired - Fee Related
- 1999-05-12 CA CA2325018A patent/CA2325018C/en not_active Expired - Fee Related
- 1999-05-12 BR BRPI9910549-7A patent/BR9910549B1/en not_active IP Right Cessation
- 1999-05-12 RU RU2000131616/04A patent/RU2220190C2/en not_active IP Right Cessation
- 1999-05-12 TR TR2000/03386T patent/TR200003386T2/en unknown
- 1999-05-12 JP JP2000549690A patent/JP2002515551A/en not_active Withdrawn
- 1999-05-12 WO PCT/EP1999/003366 patent/WO1999060081A1/en active IP Right Grant
- 1999-05-12 HU HU0101910A patent/HUP0101910A3/en unknown
- 1999-05-12 ES ES99924984T patent/ES2234259T3/en not_active Expired - Lifetime
- 1999-05-12 RO ROA200001089A patent/RO121133B1/en unknown
- 1999-05-12 DE DE69923175T patent/DE69923175T2/en not_active Expired - Lifetime
- 1999-05-12 AU AU41438/99A patent/AU732651B2/en not_active Ceased
- 1999-05-12 PL PL99344240A patent/PL190329B1/en not_active IP Right Cessation
- 1999-05-18 AR ARP990102345A patent/AR016032A1/en active IP Right Grant
-
2000
- 2000-11-17 ZA ZA200006734A patent/ZA200006734B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2220190C2 (en) | 2003-12-27 |
| WO1999060081B1 (en) | 2000-01-20 |
| GB9810655D0 (en) | 1998-07-15 |
| CN1192083C (en) | 2005-03-09 |
| CA2325018C (en) | 2010-07-13 |
| CZ300743B6 (en) | 2009-07-29 |
| BR9910549B1 (en) | 2009-01-13 |
| EP1080171A1 (en) | 2001-03-07 |
| CN1301293A (en) | 2001-06-27 |
| DE69923175D1 (en) | 2005-02-17 |
| PL344240A1 (en) | 2001-10-08 |
| ES2234259T3 (en) | 2005-06-16 |
| WO1999060081A1 (en) | 1999-11-25 |
| EP1080171B1 (en) | 2005-01-12 |
| DE69923175T2 (en) | 2005-06-23 |
| TR200003386T2 (en) | 2001-06-21 |
| BR9910549A (en) | 2001-01-30 |
| RO121133B1 (en) | 2006-12-29 |
| PL190329B1 (en) | 2005-11-30 |
| HUP0101910A2 (en) | 2001-11-28 |
| HUP0101910A3 (en) | 2002-08-28 |
| CZ20004292A3 (en) | 2001-12-12 |
| WO1999060081A8 (en) | 2001-03-22 |
| AR016032A1 (en) | 2001-05-30 |
| AU732651B2 (en) | 2001-04-26 |
| ZA200006734B (en) | 2001-11-19 |
| AU4143899A (en) | 1999-12-06 |
| JP2002515551A (en) | 2002-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FI962478A0 (en) | New compositions for foams, in particular rectal foams and foams made therefrom | |
| JP2003513123A5 (en) | ||
| GB1522125A (en) | Transparent hair conditioning composition | |
| FR2668927B1 (en) | COSMETIC ANHYDROUS COMPOSITION IN AEROSOL FORM FOR THE FORMATION OF A FOAM. | |
| NO308792B1 (en) | Derivatives of valproic acid and 2-valproic acid amides, their pharmaceutical composition and their use in the preparation of a pharmaceutical preparation | |
| KR880014090A (en) | Soft detergent composition | |
| CA2325018A1 (en) | Stabilised quaternary ammonium compositions | |
| KR830005152A (en) | Method for preparing N-phenylpyrazole derivatives | |
| KR890008589A (en) | Liquid crystal composition | |
| KR850006320A (en) | Surface disinfection antimicrobial composition | |
| GB2378952A (en) | Stabiliser mixtures | |
| CA2329959A1 (en) | Stable quaternary ammonium compositions | |
| RU2000131616A (en) | STABILIZED COMPOSITIONS OF QUARTERLY AMMONIUM COMPOUNDS | |
| KR970006329A (en) | Surfactant, emulsifier for emulsion polymerization, dispersant for suspension polymerization, and resin modifier | |
| US4460760A (en) | Anaerobically curable compositions | |
| GB2118221A (en) | Concentrated fabric softening compositions | |
| CA2039386A1 (en) | Alkoxy-(2-ethyl)hexyl-aliphatic methyl quaternary ammonium compounds and their precursor amines | |
| KR850005228A (en) | Aminoalkanosephosphonic acid and its derivatives as fungicides | |
| FR2401969A1 (en) | COATING COMPOSITION IN THE FORM OF STABLE AQUEOUS EMULSIONS | |
| TW340883B (en) | Fabric softening composition containing a cationic softener and having good storage stability and dispensability | |
| MY108165A (en) | Improved soap bars | |
| EP0398749A3 (en) | Polyisocyanatoalkylphenyl-isocyanurates, method for the preparation thereof and use thereof | |
| TH36051C3 (en) | Stable ammonium mixtures | |
| CA2054738A1 (en) | 15-deoxyprostaglandin derivatives | |
| TH59262A3 (en) | Stable ammonium mixtures |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20150512 |