CA2314123A1 - Method of treating spent potliner material from aluminum reduction cells - Google Patents
Method of treating spent potliner material from aluminum reduction cells Download PDFInfo
- Publication number
- CA2314123A1 CA2314123A1 CA002314123A CA2314123A CA2314123A1 CA 2314123 A1 CA2314123 A1 CA 2314123A1 CA 002314123 A CA002314123 A CA 002314123A CA 2314123 A CA2314123 A CA 2314123A CA 2314123 A1 CA2314123 A1 CA 2314123A1
- Authority
- CA
- Canada
- Prior art keywords
- gas component
- aluminum
- compounds
- sulfate
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A process for treating spent potliner material from aluminum reduction cells and recovering useful products. In the process, spent potliner material is introduced into an acid digester containing, for example, sulfuric acid.
A gas component is produced which includes hydrogen fluoride and hydrogen cyanide. A slurry component is produced which includes carbon, silica, alumina, sodium compounds such as sodium sulfate, aluminum compounds such as aluminum sulfate, iron compounds such as iron sulfate, magnesium and calcium compounds such as magnesium and calcium sulfate. The slurry component remains in the digester after the gas component is removed. The gas component is recovered and heated an effective amount to convert or decompose the hydrogen cyanide to a remaining gas component including CO2, H2O, and nitrogen oxides, as well as HF gas. The remaining gas component is directed through a water scrubber in which the HF gas is converted to liquid hydrofluoric acid. The hydrofluoric acid is then admixed with alumina trihydrate to form aluminum fluoride and water. Valuable refractory materials and salts are recovered also.
A gas component is produced which includes hydrogen fluoride and hydrogen cyanide. A slurry component is produced which includes carbon, silica, alumina, sodium compounds such as sodium sulfate, aluminum compounds such as aluminum sulfate, iron compounds such as iron sulfate, magnesium and calcium compounds such as magnesium and calcium sulfate. The slurry component remains in the digester after the gas component is removed. The gas component is recovered and heated an effective amount to convert or decompose the hydrogen cyanide to a remaining gas component including CO2, H2O, and nitrogen oxides, as well as HF gas. The remaining gas component is directed through a water scrubber in which the HF gas is converted to liquid hydrofluoric acid. The hydrofluoric acid is then admixed with alumina trihydrate to form aluminum fluoride and water. Valuable refractory materials and salts are recovered also.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1997/022650 WO1999029625A1 (en) | 1995-12-08 | 1997-12-11 | Method of treating spent potliner material from aluminum reduction cells |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2314123A1 true CA2314123A1 (en) | 1999-06-17 |
CA2314123C CA2314123C (en) | 2006-06-20 |
Family
ID=22262248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2314123 Expired - Fee Related CA2314123C (en) | 1997-12-11 | 1997-12-11 | Method of treating spent potliner material from aluminum reduction cells |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU749436B2 (en) |
CA (1) | CA2314123C (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006086868A1 (en) * | 2005-02-16 | 2006-08-24 | Novafrit International Inc. | Process and apparatus for converting spent potliners into a glass frit, and resulting products |
CN108926977A (en) * | 2018-09-17 | 2018-12-04 | 云南云铝润鑫铝业有限公司 | A kind of pre- leaching system of aluminium electroloysis waste lining |
CN111517349A (en) * | 2020-05-13 | 2020-08-11 | 河南联宜环保工程有限公司 | Method for recovering aluminum fluoride from overhaul residues of aluminum electrolytic cell |
CN113292088A (en) * | 2021-05-19 | 2021-08-24 | 神华准能资源综合开发有限公司 | Method for producing low-magnesium and low-calcium alumina from crystalline aluminum chloride |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4113831A (en) * | 1975-10-02 | 1978-09-12 | National Fluoride And Chemical Corporation | Recovery of sodium fluoride and other chemicals from spent carbon liners |
-
1997
- 1997-12-11 CA CA 2314123 patent/CA2314123C/en not_active Expired - Fee Related
- 1997-12-11 AU AU58975/98A patent/AU749436B2/en not_active Ceased
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006086868A1 (en) * | 2005-02-16 | 2006-08-24 | Novafrit International Inc. | Process and apparatus for converting spent potliners into a glass frit, and resulting products |
CN108926977A (en) * | 2018-09-17 | 2018-12-04 | 云南云铝润鑫铝业有限公司 | A kind of pre- leaching system of aluminium electroloysis waste lining |
CN111517349A (en) * | 2020-05-13 | 2020-08-11 | 河南联宜环保工程有限公司 | Method for recovering aluminum fluoride from overhaul residues of aluminum electrolytic cell |
CN113292088A (en) * | 2021-05-19 | 2021-08-24 | 神华准能资源综合开发有限公司 | Method for producing low-magnesium and low-calcium alumina from crystalline aluminum chloride |
Also Published As
Publication number | Publication date |
---|---|
AU5897598A (en) | 1999-06-28 |
CA2314123C (en) | 2006-06-20 |
AU749436B2 (en) | 2002-06-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |