CA2313955A1 - Sunscreen aerosol composition - Google Patents
Sunscreen aerosol composition Download PDFInfo
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- CA2313955A1 CA2313955A1 CA 2313955 CA2313955A CA2313955A1 CA 2313955 A1 CA2313955 A1 CA 2313955A1 CA 2313955 CA2313955 CA 2313955 CA 2313955 A CA2313955 A CA 2313955A CA 2313955 A1 CA2313955 A1 CA 2313955A1
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- sunscreen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The present invention is a sunscreen composition in the form of an aerosol that foams. The composition contains a sunscreen agent, an emulsifier, a foam builder/stabilizer, a counterion, and a propellant. In addition, the ratio of the foam builder/stabilizer to counterion is about 1:4 to about 5:1.2 to ensure the foam quality and integrity.
Description
SUNSGR~IN AEROSOL COMPOSITION
I. Field of the Invention s The present invention relates to sunscreens. More particularly, the present invention relates to sunscreen compositions dispensed in the form of an aerosol product that foams.
II. Description of the Prior Art to Sunscreen compositions are applied to the skin to protect the skin from the sun's ultraviolet rays that can lead to erythema, a reddening of the skin also known as sunburn. Sunlight or ultraviolet radiation in the UV-B
range has a wavelength of 290nm to 320nm and is known to be the primary cause of sunburn. Ultraviolet rays at a wavelength of 320nm to d00nm, 15 known as UV-A radiation, produces tanning of the skin. However, in the process of doing so, the UV-A rays can damage or harm the skin.
Besides the immediate malady of sunburn, excessive sunlight exposure can lead to skin disorders. For instance, prolonged and constant zo exposure to the sun may lead to actinic keratoses and carcinomas.
Another long-term effect is premature aging of the skin. This condition is characterized by skin that is wrinkled, cracked and has lost its elasticity.
As stated above, sunscreens are typically formulated with the goal of 25 inhibiting skin damage from the sun's rays. The sunscreen composition filters or blocks the harmful UV-A and UV-B rays that can damage and harm the skin. It is believed that sunscreen agents accomplish this by absorbing the UV-A and/or UV-B rays.
3o In general, sunscreen compositions are oil and water emulsions. In this system, the UV-absorbing compounds are typically incorporated into the oil phase.
Sunscreens may also include physical or inorganic metal oxides that block the sun's rays. Titanium dioxide and zinc oxide are commonly used for this purpose.
s Consumers consider many factors when purchasing a sunscreen product. One of the most important considerations is the sun protection factor (SPF). This determines the amount of protection that the sunscreen composition provides over a given period of time. There are many to choose from and selection will be based upon the consumer's needs. The consumer also gives consideration to the substantivity of the product, that is how durable is the product after applying it over the skin. This effects how often the composition will need to be applied when the consumer is out in the sun. A third consideration is product feel and how well the product spreads over the skin. Typically, consumers want a product that feels smooth and silky and be applied in a smooth continuous film over the skin. Another factor is the shelf life of the product. which is determined by the chemical and physical stability of the sunscreen composition. In addition, product form will also play a part since there is a variety of choices such as lotions, gels, creams, sprays, and aerosols that are available.
2o Form preference could ultimately determine whether the consumer decides to purchase the product.
The unique product forms can be appealing to many consumers who are looking for something different. Sunscreens that are made in the form 25 of an aerosol are not commonplace, particularly, aerosols that deliver the product as a foam.
BRIEF SUMMARY OF THE INVENTION
It is an object of the present invention to provide a sunscreen ao composition that is dispensed as an aerosol product in the form of a foam.
It is also an object of the present invention to provide such a sunscreen composition that delivers superior foam quality.
I. Field of the Invention s The present invention relates to sunscreens. More particularly, the present invention relates to sunscreen compositions dispensed in the form of an aerosol product that foams.
II. Description of the Prior Art to Sunscreen compositions are applied to the skin to protect the skin from the sun's ultraviolet rays that can lead to erythema, a reddening of the skin also known as sunburn. Sunlight or ultraviolet radiation in the UV-B
range has a wavelength of 290nm to 320nm and is known to be the primary cause of sunburn. Ultraviolet rays at a wavelength of 320nm to d00nm, 15 known as UV-A radiation, produces tanning of the skin. However, in the process of doing so, the UV-A rays can damage or harm the skin.
Besides the immediate malady of sunburn, excessive sunlight exposure can lead to skin disorders. For instance, prolonged and constant zo exposure to the sun may lead to actinic keratoses and carcinomas.
Another long-term effect is premature aging of the skin. This condition is characterized by skin that is wrinkled, cracked and has lost its elasticity.
As stated above, sunscreens are typically formulated with the goal of 25 inhibiting skin damage from the sun's rays. The sunscreen composition filters or blocks the harmful UV-A and UV-B rays that can damage and harm the skin. It is believed that sunscreen agents accomplish this by absorbing the UV-A and/or UV-B rays.
3o In general, sunscreen compositions are oil and water emulsions. In this system, the UV-absorbing compounds are typically incorporated into the oil phase.
Sunscreens may also include physical or inorganic metal oxides that block the sun's rays. Titanium dioxide and zinc oxide are commonly used for this purpose.
s Consumers consider many factors when purchasing a sunscreen product. One of the most important considerations is the sun protection factor (SPF). This determines the amount of protection that the sunscreen composition provides over a given period of time. There are many to choose from and selection will be based upon the consumer's needs. The consumer also gives consideration to the substantivity of the product, that is how durable is the product after applying it over the skin. This effects how often the composition will need to be applied when the consumer is out in the sun. A third consideration is product feel and how well the product spreads over the skin. Typically, consumers want a product that feels smooth and silky and be applied in a smooth continuous film over the skin. Another factor is the shelf life of the product. which is determined by the chemical and physical stability of the sunscreen composition. In addition, product form will also play a part since there is a variety of choices such as lotions, gels, creams, sprays, and aerosols that are available.
2o Form preference could ultimately determine whether the consumer decides to purchase the product.
The unique product forms can be appealing to many consumers who are looking for something different. Sunscreens that are made in the form 25 of an aerosol are not commonplace, particularly, aerosols that deliver the product as a foam.
BRIEF SUMMARY OF THE INVENTION
It is an object of the present invention to provide a sunscreen ao composition that is dispensed as an aerosol product in the form of a foam.
It is also an object of the present invention to provide such a sunscreen composition that delivers superior foam quality.
It is another object of the present invention to provide such a sunscreen composition that is effective in protecting the skin against UV-A
and UV-B rays.
It is still another object of the present invention to provide such a sunscreen composition that spreads uniformly over the skin.
To accomplish the foregoing objects and advantages, the present invention, in brief summary, is a sunscreen composition that is dispensed as an aerosol product. The composition contains a sunscreen agent, an emulsifier, a foam builder/stabilizer, a counterion, and a propellant. In a preferred embodiment, the sunscreen composition also contains an emollient, a hurnectant, a preservative/antioxidant, and water.
~5 Furthermore, the ratio of the foam builder/stabilizer to counterion must be about 1:4 to about 5:1.2. More preferably, the ratio is about 1:1 to about 5:1.
DETAILED DESCRIPTION OF THE INVENTION
2o The present invention is a sunscreen composition in the form of an aerosol comprising a sunscreen agent, an emulsifier, a foam builder/stabilizer, a counterion, and a propellant.
Sunscreen agents 25 The sunscreen agents that can be used in the present invention must be capable of absorbing or blocking the harmful effects of ultraviolet radiation. In addition, they must be non-toxic and non-irritating when applied to the skin. Suitable sunscreen agents include, for example, para-aminobenzoic acid (PABA), benzophenone-1, benzophenone-2, 3o benzophenone-3, benzophenone-4, benzophenone-6, benzophenone-8, benzophenone-12, methoxycinnamate, ethyl dihydroxypropyl-PABA, glyceryl PABA, homosalate, methyl anthranilate, octocrylene, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate, PABA, 2-phenylbenzimidazole-5-sulphonic acid, triethanolamine salicylate, 3-(4-methylbenzylidane)-camphor. red petrolatum, and mixtures thereof. The preferred sunscreen agents are octyl methoxycinnamate, octyl salicylate, benzophenone-3, and mixtures thereof.
The sunscreen agents may be present in an amount about 1 wt.% to about 40 wt.% of the total weight of the composition of the present invention. The total amount of sunscreen agents in the composition will depend upon the sun protection factor (SPF) desired. Normally, the higher the SPF, the greater the total amount of sunscreen agents. Preferably, the sunscreen agents are included at about 4 wt.% to about 30 wt.%.
Emulsifiers An emulsifier is an essential component of the present invention. An emulsifier enables two or more immiscible liquids to be combined ~5 homogeneously, while increasing the viscosity of the composition.
Moreover, the emulsifier acts to stabilize the composition. Emulsifiers that may be used In the present invention include sorbitan oleate, sorbitan sesquioleate, sorbitan isostearate, sorbitan trioleate, polyglyceryl-3-diisostearate, polyglycerol esters of oleic~sostearic acid, polyglyceryl-6 20 hexaricinolatc, polyglyceryl-4-oleate. polygylceryl-4 oleate/PEG-8 propylene glycol cocoate, oleamide DEA, sodium glyceryl oleate phosphate, hydrogenated vegetable glycerides phosphate and mixtures thereof.
25 Furthermore, one or more synthetic polymers may be used as an emuls~er. For example, PVP Eicvsene copolymer, acrylates/C~o-C3o alkyl acrylate crosspolymer, acrylates/steareth-20 methacrylate copolymer, PEG-22/dodecyl glycol copolymer, PEG-45/dodecyl glycol copolymer, and mixtures thereof.
The preferred emuls~ers are PVP Eicos~ne copolymer, acrylates/C,o-Cao alkyl acrylate crosspolymer. PEG-20 sorbitan isostearate, sorbitan isostearate, and mixtures thereof.
and UV-B rays.
It is still another object of the present invention to provide such a sunscreen composition that spreads uniformly over the skin.
To accomplish the foregoing objects and advantages, the present invention, in brief summary, is a sunscreen composition that is dispensed as an aerosol product. The composition contains a sunscreen agent, an emulsifier, a foam builder/stabilizer, a counterion, and a propellant. In a preferred embodiment, the sunscreen composition also contains an emollient, a hurnectant, a preservative/antioxidant, and water.
~5 Furthermore, the ratio of the foam builder/stabilizer to counterion must be about 1:4 to about 5:1.2. More preferably, the ratio is about 1:1 to about 5:1.
DETAILED DESCRIPTION OF THE INVENTION
2o The present invention is a sunscreen composition in the form of an aerosol comprising a sunscreen agent, an emulsifier, a foam builder/stabilizer, a counterion, and a propellant.
Sunscreen agents 25 The sunscreen agents that can be used in the present invention must be capable of absorbing or blocking the harmful effects of ultraviolet radiation. In addition, they must be non-toxic and non-irritating when applied to the skin. Suitable sunscreen agents include, for example, para-aminobenzoic acid (PABA), benzophenone-1, benzophenone-2, 3o benzophenone-3, benzophenone-4, benzophenone-6, benzophenone-8, benzophenone-12, methoxycinnamate, ethyl dihydroxypropyl-PABA, glyceryl PABA, homosalate, methyl anthranilate, octocrylene, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate, PABA, 2-phenylbenzimidazole-5-sulphonic acid, triethanolamine salicylate, 3-(4-methylbenzylidane)-camphor. red petrolatum, and mixtures thereof. The preferred sunscreen agents are octyl methoxycinnamate, octyl salicylate, benzophenone-3, and mixtures thereof.
The sunscreen agents may be present in an amount about 1 wt.% to about 40 wt.% of the total weight of the composition of the present invention. The total amount of sunscreen agents in the composition will depend upon the sun protection factor (SPF) desired. Normally, the higher the SPF, the greater the total amount of sunscreen agents. Preferably, the sunscreen agents are included at about 4 wt.% to about 30 wt.%.
Emulsifiers An emulsifier is an essential component of the present invention. An emulsifier enables two or more immiscible liquids to be combined ~5 homogeneously, while increasing the viscosity of the composition.
Moreover, the emulsifier acts to stabilize the composition. Emulsifiers that may be used In the present invention include sorbitan oleate, sorbitan sesquioleate, sorbitan isostearate, sorbitan trioleate, polyglyceryl-3-diisostearate, polyglycerol esters of oleic~sostearic acid, polyglyceryl-6 20 hexaricinolatc, polyglyceryl-4-oleate. polygylceryl-4 oleate/PEG-8 propylene glycol cocoate, oleamide DEA, sodium glyceryl oleate phosphate, hydrogenated vegetable glycerides phosphate and mixtures thereof.
25 Furthermore, one or more synthetic polymers may be used as an emuls~er. For example, PVP Eicvsene copolymer, acrylates/C~o-C3o alkyl acrylate crosspolymer, acrylates/steareth-20 methacrylate copolymer, PEG-22/dodecyl glycol copolymer, PEG-45/dodecyl glycol copolymer, and mixtures thereof.
The preferred emuls~ers are PVP Eicos~ne copolymer, acrylates/C,o-Cao alkyl acrylate crosspolymer. PEG-20 sorbitan isostearate, sorbitan isostearate, and mixtures thereof.
The one or more emulsifiers are present in a total amount about 0.01 wt.°~ to about 15 wt.% of the total weight of the composition of the present invention. Preferably, about 0.1 wt.% to about 3 wt.°~ of emulsifiers are used.
Foam Builder/Stabilizer The composition of the present invention must include a foam builder/stabilizer. The preferred foam builder/stabilizer is cetyl phosphate.
DEA cetyl phosphate, TEA myristate, TEA stearate, magnesium stearate, 1o sodium stearate, potassium laurate, potassium ricinoleate, sodium cocoate.
sodium tallowate, potassium castorate, sodium oleate, and mixtures thereof. The foam builder/stabilizer in an amount about 0.1 wt.% to about 5 wt.% must be added to the composition of the present invention.
Preferably, the foam buildeNstabilizer is present in an amount about 0.1 ~ 5 wt.% to about 3 wt. %.
Counterions Counterions are in the composition of the present invention to neutralize components such as an emulsifier and a foam builders/stabilizer.
2o Sodium hydroxide, potassium hydroxide, diethanolamine, triethanolamine, aminomethyl propanol, trisodium ethylenediaminetetraacetic acid, and mixtures thereof, arc examples of suitable counterions used in the present invention. The preferred counterlon is triethanolamine.
2s Counterion is present in an amount about 0.01 wt.% to about 8 wt.%
in the composition of the present invention. Preferably, counterion is present in an amount about 1 wt.% to about 5 wt.%.
A critical feature of the present invention is the ratio of the foam 3o builder/stabilizer to counterion. To ensure superior foam quality and integrity, the ratio must be about 1:4 to about 5:1.2. Preferably. the ratio is about 1:1 to about 5:1.
Propellant The propellant must be capable of producing a sufficiQnt pressure for expelling the composition from an aerosol container. Furthermore, the propellant must be non-irritating. non-toxic and compatible with the ingredients used in the composition. Suitable propellants are butane, isobutane, propane, dimethyl ether, dichlorodlfluoromethane, tetrafluoromethane, dichlorotetrafluoroethane, chlorodifluoromethane, chlorodifluoroethane, difluoroethane, and mixtures thereof. The preferred propellant of the present invention is a blend of isobutane and propane.
commonly known as A-48 propellant. Propellant is present in the range about 3 wt.°~ to about 15 wt.% of the present invention. Preferably, the propellant is about 5 wt.% to about 9 wt.%.
Water The composition of the present invention optionally can have water.
Water can be present in an amount up to about 80 wt.%, preferably, from 30 wt. % to 70 wt. % of water.
Emollients The present composition may additionally contain one or more 2o emollients. An emollient provides a softening yr soothing effect on the skin surtace and is generally considered safe for topical use. Emollients also help control the rate of evaporation and the tackiness of the composition.
Preferred emollients include mineral oil, lanolin oil, coconut oil, cocoa butter, olive oil, aloe extracts, jojoba oils, castor oil, fatty acids such as oleic and stearic, fatty alcohols such as cetyl and hexadecyl (ENJAY), diisopropyl adipate, hydroxybenzoate esters, benzoic acid esters of C9-C~5 alcohots, isononyl iso-nonanoate, slkanes such as mineral oil, silicones such as dimethyl polysiloxane, ethers such as polyoxypropylene butyl ethers and polyoxypropylene cetyl ethers, and C,Z-C,5 alkyl benzoates. and 3o mixtures thereof. The most preferred emollients are hydroxybenzoate esters, aloe oars, C,2-C~5 alkyl benzoates, and mixtures thereof.
Emollient Is present In an amount about 1 wt.% to about 20 wt.% of the total weight of the composition. The preferred amount of emollient is about 2 wt.°~fo to about 15 wt,%, and most preferrably about 4 wt.°~ to about wt. %.
Humectants 3 A moistening agent, such as a humectant, may be incorporated into the present invention. Suitable humcctants include glycerin, polyethylene glycol, polypropylene glycol, sorbitol, PEGS, and mixtures thereof.
One or more humeciants are optionally present at about 0.5 wt.% to to about 8 wt.% in the present invention. Preferably, about 1 wt.% to about 5 wt.% of humectants may be used.
Titanium dioxide Optionally, titanium dioxide may be added to the composition of the present invention. This material is generally considered safe for typical use since it is physiologically inert and has a low degree of irritation and toxicity.
It functions by reflecting and absorbing sunlight. In the present invention, the titanium dioxide is suspended throughout the composition.
The composition of the present invention may have about 0.5 wt.%
to about 10 wt.% of titanium dioxide. Preferably, there is present about 1 wt.% to about 3 wt.% titanium dioxide.
Preservatives/Antioxidants Optionally, preservatives/antioxidants may be in the present composition. Diazolldinyl urea, iodopropynyl butylcarbamate, vitamin E, vitamin E acetate, vitamin C, butylated hydroxytoluene, methylparaben, and mixtures thereof may be a preservative/antioxidant in the present composition.
One or more preservatives/antioxidants may be present in an amount about 0.01 wt.% to about 2 wt.% of the total weight of the present invention. Preferably, one or more preservatives/antioxidants are present in an amount about 0.1 wt.% to about 1 wt.%.
Foam Builder/Stabilizer The composition of the present invention must include a foam builder/stabilizer. The preferred foam builder/stabilizer is cetyl phosphate.
DEA cetyl phosphate, TEA myristate, TEA stearate, magnesium stearate, 1o sodium stearate, potassium laurate, potassium ricinoleate, sodium cocoate.
sodium tallowate, potassium castorate, sodium oleate, and mixtures thereof. The foam builder/stabilizer in an amount about 0.1 wt.% to about 5 wt.% must be added to the composition of the present invention.
Preferably, the foam buildeNstabilizer is present in an amount about 0.1 ~ 5 wt.% to about 3 wt. %.
Counterions Counterions are in the composition of the present invention to neutralize components such as an emulsifier and a foam builders/stabilizer.
2o Sodium hydroxide, potassium hydroxide, diethanolamine, triethanolamine, aminomethyl propanol, trisodium ethylenediaminetetraacetic acid, and mixtures thereof, arc examples of suitable counterions used in the present invention. The preferred counterlon is triethanolamine.
2s Counterion is present in an amount about 0.01 wt.% to about 8 wt.%
in the composition of the present invention. Preferably, counterion is present in an amount about 1 wt.% to about 5 wt.%.
A critical feature of the present invention is the ratio of the foam 3o builder/stabilizer to counterion. To ensure superior foam quality and integrity, the ratio must be about 1:4 to about 5:1.2. Preferably. the ratio is about 1:1 to about 5:1.
Propellant The propellant must be capable of producing a sufficiQnt pressure for expelling the composition from an aerosol container. Furthermore, the propellant must be non-irritating. non-toxic and compatible with the ingredients used in the composition. Suitable propellants are butane, isobutane, propane, dimethyl ether, dichlorodlfluoromethane, tetrafluoromethane, dichlorotetrafluoroethane, chlorodifluoromethane, chlorodifluoroethane, difluoroethane, and mixtures thereof. The preferred propellant of the present invention is a blend of isobutane and propane.
commonly known as A-48 propellant. Propellant is present in the range about 3 wt.°~ to about 15 wt.% of the present invention. Preferably, the propellant is about 5 wt.% to about 9 wt.%.
Water The composition of the present invention optionally can have water.
Water can be present in an amount up to about 80 wt.%, preferably, from 30 wt. % to 70 wt. % of water.
Emollients The present composition may additionally contain one or more 2o emollients. An emollient provides a softening yr soothing effect on the skin surtace and is generally considered safe for topical use. Emollients also help control the rate of evaporation and the tackiness of the composition.
Preferred emollients include mineral oil, lanolin oil, coconut oil, cocoa butter, olive oil, aloe extracts, jojoba oils, castor oil, fatty acids such as oleic and stearic, fatty alcohols such as cetyl and hexadecyl (ENJAY), diisopropyl adipate, hydroxybenzoate esters, benzoic acid esters of C9-C~5 alcohots, isononyl iso-nonanoate, slkanes such as mineral oil, silicones such as dimethyl polysiloxane, ethers such as polyoxypropylene butyl ethers and polyoxypropylene cetyl ethers, and C,Z-C,5 alkyl benzoates. and 3o mixtures thereof. The most preferred emollients are hydroxybenzoate esters, aloe oars, C,2-C~5 alkyl benzoates, and mixtures thereof.
Emollient Is present In an amount about 1 wt.% to about 20 wt.% of the total weight of the composition. The preferred amount of emollient is about 2 wt.°~fo to about 15 wt,%, and most preferrably about 4 wt.°~ to about wt. %.
Humectants 3 A moistening agent, such as a humectant, may be incorporated into the present invention. Suitable humcctants include glycerin, polyethylene glycol, polypropylene glycol, sorbitol, PEGS, and mixtures thereof.
One or more humeciants are optionally present at about 0.5 wt.% to to about 8 wt.% in the present invention. Preferably, about 1 wt.% to about 5 wt.% of humectants may be used.
Titanium dioxide Optionally, titanium dioxide may be added to the composition of the present invention. This material is generally considered safe for typical use since it is physiologically inert and has a low degree of irritation and toxicity.
It functions by reflecting and absorbing sunlight. In the present invention, the titanium dioxide is suspended throughout the composition.
The composition of the present invention may have about 0.5 wt.%
to about 10 wt.% of titanium dioxide. Preferably, there is present about 1 wt.% to about 3 wt.% titanium dioxide.
Preservatives/Antioxidants Optionally, preservatives/antioxidants may be in the present composition. Diazolldinyl urea, iodopropynyl butylcarbamate, vitamin E, vitamin E acetate, vitamin C, butylated hydroxytoluene, methylparaben, and mixtures thereof may be a preservative/antioxidant in the present composition.
One or more preservatives/antioxidants may be present in an amount about 0.01 wt.% to about 2 wt.% of the total weight of the present invention. Preferably, one or more preservatives/antioxidants are present in an amount about 0.1 wt.% to about 1 wt.%.
Rheological Additives The present invention may include a Theological additive, such as magnesium aluminum silicate, hydroxypropyl cellulose, carbomer, s cellulose, guar gum, xanthan gum, bentonite, acrylate copolymers, and mixtures thereof. The Theological additive assists in building the viscosity of the present invention.
The Theological additive may optionally be present at about 0.05 1o wt.% to about 5 wt.% in the composition of the present invention.
Preferably, about 0.1 wt.% to about 2 wt.% of Theological additives are present in the present composition.
Optional Additives ~5 The sunscreen composition of the present invention may also contain optional additives. For instance, a fragrance, colorant, plant extract, absorbent, waterproofing agent, and mixtures thereof may be included.
2o Process The process used to manufacture the present invention must be capable of forming a homogeneous composition that can be sprayed or dispensed from an aerosol can.
25 Typically, aerosol products are made by filling a concentrate into a can and then filling the can with propellant under vacuum conditions.
The concentrate of the present invention may be prepared by using tcchniqucs and methods well known in the art. In general, ingredients are ao incorporated by mixing and applying heat if necessary, until the concentrate is uniform and homogeneous. If necessary, the concentrate may be homogenized to ensure homogeneity.
The Theological additive may optionally be present at about 0.05 1o wt.% to about 5 wt.% in the composition of the present invention.
Preferably, about 0.1 wt.% to about 2 wt.% of Theological additives are present in the present composition.
Optional Additives ~5 The sunscreen composition of the present invention may also contain optional additives. For instance, a fragrance, colorant, plant extract, absorbent, waterproofing agent, and mixtures thereof may be included.
2o Process The process used to manufacture the present invention must be capable of forming a homogeneous composition that can be sprayed or dispensed from an aerosol can.
25 Typically, aerosol products are made by filling a concentrate into a can and then filling the can with propellant under vacuum conditions.
The concentrate of the present invention may be prepared by using tcchniqucs and methods well known in the art. In general, ingredients are ao incorporated by mixing and applying heat if necessary, until the concentrate is uniform and homogeneous. If necessary, the concentrate may be homogenized to ensure homogeneity.
The concentrate i3 then placed in an aorosol can which is Later filled with propellant.
Having thus described the present invention with particular reference s to preferred embodiments thereof, it will be apparent that various changes and modifications may be made therein without departing from the spirit and scope of the invention as d~fined in the appended claims.
Having thus described the present invention with particular reference s to preferred embodiments thereof, it will be apparent that various changes and modifications may be made therein without departing from the spirit and scope of the invention as d~fined in the appended claims.
Claims (22)
1. A sunscreen composition comprising:
(a) a sunscreen agent;
(b) an emulsifier, (c) a foam builder/stabilizer;
(d) a counterion; and (e) a propellant.
(a) a sunscreen agent;
(b) an emulsifier, (c) a foam builder/stabilizer;
(d) a counterion; and (e) a propellant.
2. The composition of claim 1, wherein said ratio of foam builder/stabilizer to said counterion is about 1:4 to about 5:1.2.
3. The composition of claim 1, wherein said foam builder/stabilizer is selected from the group consisting of cetyl phosphate, DEA cetyl phosphate, sodium stearate, potassium ricinoleate, sodium tallowate, and mixtures thereof.
4. The composition of claim 1, wherein said foam builder/stabilizer is about O.1 wt.% to about 5 wt.% of the total weight of the composition.
5. The composition of claim 1, wherein said counterion is selected from the group consisting of sodium hydroxide, potassium hydroxide. diethanolamine, triethanolamine. aminomethyl propanol, trisodium ethylenediaminetetraacetic acid, and mixtures thereof.
6. The composition of claim 1, wherein said counterion is about 0.01 wt.% to about 8 wt.% of the total weight of the composition.
7. The composition of claim 1, wherein said sunscreen agent is about 4 wt.% to about 30 wt.% of the total weight of the composition.
8. The composition of claim 7, wherein said sunscreen agent is selected from the group consisting of benzophenone-3, octyl methoxycinnamate, octyl sallcylate, homosalate, and mixtures thereof.
9. The composition of claim 1, wherein said emulsifier is about 0.01 wt.% to about 15 wt.% of the total weight of the composition.
10. The composition of claim 9, wherein said emulsifier is selected from the group consisting of PVP Eicosene copolymer, sorbitan isostearate, acrylates/C10-C30 alkyl acrylate crosspolymer, PEG-20 sorbitan isostearate, and mixtures thereof.
11. The composition of claim 1, wherein said propellant is a blend of isobutane and propane.
12. The composition of claim 1. further comprising water.
13. The composition of claim 1, further comprising an emollient.
14. The composition of claim 13. wherein said emollient is selected from the group consisting of hydroxybenzoate esters, C12-C15 alkyl benzoates. aloe vera, and mixtures thereof.
15. The composition of claim 1, further comprising a humectant.
16. The composition of claim 15, wherein said humectant is PEG-4
17. The composition of claim 1, further comprising titanium dioxide.
18. The composition of claim 1, further comprising a rheological additive.
19. The composition of claim 18, wherein said rheological additive is magnesium aluminum silicate.
20. The composition of claim 1, further comprising a preservative/antioxidant.
21. The composition of claim 20, wherein said preservative/antioxidant is selected from the group consisting of diazolidinyl urea, iodopropynyl butylcarbamate, vitamin E, vitamin E acetate, vitamin C, butylated hydroxytoluene, methylparaben, and mixtures thereof.
22. The composition of claim 1, further comprising optional ingredients selected from the group consisting of a fragrance, colorant, plant extract. absorbent, waterproofing agent, and mixtures thereof.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US14426499P | 1999-07-15 | 1999-07-15 | |
US60/144,264 | 1999-07-15 |
Publications (1)
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CA2313955A1 true CA2313955A1 (en) | 2001-01-15 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CA 2313955 Abandoned CA2313955A1 (en) | 1999-07-15 | 2000-07-14 | Sunscreen aerosol composition |
Country Status (5)
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EP (1) | EP1200054A1 (en) |
AU (1) | AU6106500A (en) |
CA (1) | CA2313955A1 (en) |
MX (1) | MXPA02000457A (en) |
WO (1) | WO2001005366A1 (en) |
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US6551857B2 (en) | 1997-04-04 | 2003-04-22 | Elm Technology Corporation | Three dimensional structure integrated circuits |
WO2003011238A2 (en) * | 2001-07-31 | 2003-02-13 | Merck Patent Gmbh | Sunscreen composition |
KR20030013945A (en) * | 2001-08-10 | 2003-02-15 | 이인혜 | Process for preparing a spray type sunscreen agent |
WO2004037225A2 (en) | 2002-10-25 | 2004-05-06 | Foamix Ltd. | Cosmetic and pharmaceutical foam |
IL152486A0 (en) | 2002-10-25 | 2003-05-29 | Meir Eini | Alcohol-free cosmetic and pharmaceutical foam carrier |
US9265725B2 (en) | 2002-10-25 | 2016-02-23 | Foamix Pharmaceuticals Ltd. | Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof |
US10117812B2 (en) | 2002-10-25 | 2018-11-06 | Foamix Pharmaceuticals Ltd. | Foamable composition combining a polar solvent and a hydrophobic carrier |
US9211259B2 (en) | 2002-11-29 | 2015-12-15 | Foamix Pharmaceuticals Ltd. | Antibiotic kit and composition and uses thereof |
US20080138296A1 (en) | 2002-10-25 | 2008-06-12 | Foamix Ltd. | Foam prepared from nanoemulsions and uses |
US7820145B2 (en) | 2003-08-04 | 2010-10-26 | Foamix Ltd. | Oleaginous pharmaceutical and cosmetic foam |
US7704518B2 (en) | 2003-08-04 | 2010-04-27 | Foamix, Ltd. | Foamable vehicle and pharmaceutical compositions thereof |
US9668972B2 (en) | 2002-10-25 | 2017-06-06 | Foamix Pharmaceuticals Ltd. | Nonsteroidal immunomodulating kit and composition and uses thereof |
US8900554B2 (en) | 2002-10-25 | 2014-12-02 | Foamix Pharmaceuticals Ltd. | Foamable composition and uses thereof |
US7700076B2 (en) | 2002-10-25 | 2010-04-20 | Foamix, Ltd. | Penetrating pharmaceutical foam |
CA2515731C (en) | 2003-02-12 | 2012-07-24 | Connetics Australia Pty Ltd | Sunscreen hydroethanolic foam |
US8795693B2 (en) | 2003-08-04 | 2014-08-05 | Foamix Ltd. | Compositions with modulating agents |
WO2006099687A1 (en) * | 2005-03-24 | 2006-09-28 | Ensign Laboratories Pty Ltd | Sunscreen aerosol spray |
DE102005028388A1 (en) * | 2005-06-20 | 2007-01-04 | Wella Ag | Product delivery system for spraying hair or skin cosmetic compositions containing UV filters |
US20080260655A1 (en) | 2006-11-14 | 2008-10-23 | Dov Tamarkin | Substantially non-aqueous foamable petrolatum based pharmaceutical and cosmetic compositions and their uses |
US8636982B2 (en) | 2007-08-07 | 2014-01-28 | Foamix Ltd. | Wax foamable vehicle and pharmaceutical compositions thereof |
WO2009069006A2 (en) | 2007-11-30 | 2009-06-04 | Foamix Ltd. | Foam containing benzoyl peroxide |
WO2009090495A2 (en) | 2007-12-07 | 2009-07-23 | Foamix Ltd. | Oil and liquid silicone foamable carriers and formulations |
WO2010125470A2 (en) | 2009-04-28 | 2010-11-04 | Foamix Ltd. | Foamable vehicle and pharmaceutical compositions comprising aprotic polar solvents and uses thereof |
WO2011013009A2 (en) | 2009-07-29 | 2011-02-03 | Foamix Ltd. | Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses |
CA2769677A1 (en) | 2009-07-29 | 2011-02-03 | Foamix Ltd. | Non surface active agent non polymeric agent hydro-alcoholic foamable compositions, breakable foams and their uses |
US9849142B2 (en) | 2009-10-02 | 2017-12-26 | Foamix Pharmaceuticals Ltd. | Methods for accelerated return of skin integrity and for the treatment of impetigo |
WO2011064631A1 (en) | 2009-10-02 | 2011-06-03 | Foamix Ltd. | Surfactant-free, water-free, foamable compositions and breakable foams and their uses |
US8206691B2 (en) | 2009-11-04 | 2012-06-26 | Conopco, Inc. | Sunscreen composition with fatty acid alkanolamides |
US8173108B2 (en) | 2009-11-04 | 2012-05-08 | Conopco, Inc. | Sunscreen composition |
US10398641B2 (en) | 2016-09-08 | 2019-09-03 | Foamix Pharmaceuticals Ltd. | Compositions and methods for treating rosacea and acne |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3537622B2 (en) * | 1996-02-26 | 2004-06-14 | 株式会社資生堂 | UV absorbing composition |
-
2000
- 2000-07-14 CA CA 2313955 patent/CA2313955A1/en not_active Abandoned
- 2000-07-14 MX MXPA02000457A patent/MXPA02000457A/en unknown
- 2000-07-14 AU AU61065/00A patent/AU6106500A/en not_active Abandoned
- 2000-07-14 WO PCT/US2000/019459 patent/WO2001005366A1/en not_active Application Discontinuation
- 2000-07-14 EP EP00947462A patent/EP1200054A1/en not_active Withdrawn
Also Published As
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MXPA02000457A (en) | 2002-07-30 |
WO2001005366A1 (en) | 2001-01-25 |
EP1200054A1 (en) | 2002-05-02 |
AU6106500A (en) | 2001-02-05 |
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