CA2310470C - Fluid applicators - Google Patents

Fluid applicators Download PDF

Info

Publication number
CA2310470C
CA2310470C CA002310470A CA2310470A CA2310470C CA 2310470 C CA2310470 C CA 2310470C CA 002310470 A CA002310470 A CA 002310470A CA 2310470 A CA2310470 A CA 2310470A CA 2310470 C CA2310470 C CA 2310470C
Authority
CA
Canada
Prior art keywords
applicator
applicator system
flowable composition
spout
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002310470A
Other languages
French (fr)
Other versions
CA2310470A1 (en
Inventor
Lee Burrowes
Lesley Allen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CA2310470A1 publication Critical patent/CA2310470A1/en
Application granted granted Critical
Publication of CA2310470C publication Critical patent/CA2310470C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D24/00Hair combs for care of the hair; Accessories therefor
    • A45D24/22Combs with dispensing devices for liquids, pastes or powders
    • A45D24/26Combs with dispensing devices for liquids, pastes or powders with flexible walls of the liquid, paste, or powder storing device
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D19/00Devices for washing the hair or the scalp; Similar devices for colouring the hair
    • A45D19/02Hand-actuated implements, e.g. hand-actuated spray heads
    • A45D19/026Hand-actuated implements, e.g. hand-actuated spray heads having brush or comb applicators
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D19/00Devices for washing the hair or the scalp; Similar devices for colouring the hair
    • A45D19/0041Processes for treating the hair of the scalp
    • A45D19/0066Coloring or bleaching
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D19/00Devices for washing the hair or the scalp; Similar devices for colouring the hair
    • A45D19/02Hand-actuated implements, e.g. hand-actuated spray heads
    • A45D19/028Hand-actuated implements, e.g. hand-actuated spray heads having applicators other than brushes or combs, e.g. rollers, balls or sponges
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D24/00Hair combs for care of the hair; Accessories therefor
    • A45D24/22Combs with dispensing devices for liquids, pastes or powders
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/05Details of containers
    • A45D2200/054Means for supplying liquid to the outlet of the container

Abstract

An applicator system, for use in delivering a flowable composi-tion: wherein a container ( 10) in which the flowable composition is to be contained: and at least three applicators (114, 106, 72) of different type, each of the applicators having at least one outlet (148, 108, 88) through which the flowable composition is to be applied, with at least a first of the applicators (72) being securable to the container, and with at least a second of the applicators (114, 106) being securable to the first of the applicators; wherein only at least one outlet of a selected one of the at least three applicators is exposed at any one time while applying the flowable composition therethrough.

Description

WO 99/26510 PCT/US98/2483~
APPLICATORS
The present invention relates generally applicators and more especially but not exclusively to applicators for use in applying hair and/or scalp compositions to the hair and/or scalp in a time-efficient, controlled and mess-free manner.
In a hair colouring treatment, it would be desirable to be able to control flow of a colouring fluid accurately and to be able to target the areas to be coloured by the coiourir:a fluid precisely. It would also be desirable to be able ~o minimise mess during applica~ior_ and maripulatior., and to be able to achieve an even colour distribution throughout the areas to be coloured by the colouring fluid.
These objectives are to be achievable even when the applicator is to be handled by the person to whom the colouring fluid is to be applied.
Different aspects of the present invention which address these objectives, and similar objectives in situations using other flowable compositions, will now be discussed, in turn, with preferred applicators embodying more than one or all of the different aspects of the present invention.
A. It is known from US-A-4209027 for a hair treatment device to be securable to a squeeze bottle containing a hair treating liquid which is to be dispensed by a user through discharge orifices in different applicators simultaneously presented by the hair treatment device.
One of the applicators has an elongate tip for use primarily as part'_ng means, and others of the applicators are alternative brushes and combs for use primaril}- as spreading means, with a valve being provided for enabling the hair treating hiquid to be directed to the parting means or the spreading means or both.
A practical disadvantage of this known hair treatment device is that it can be awkward to handle in a contrclled and mess-free manner.
The result of this is that, when using one of the spreading means, hair which is not to be treated or has already been treated may be locally damaged or discoloured by undesired contact with hair treating liquid in and around the discharge orifice of the parting means, and fur tze=-more hair treating liquid may drip or be flicked 'rom the parting means onto the user's skin, clothes or surroundings .
According to a first aspect of the present invention, however, an applicator system for use in delivering a flowable composition comprises:-a container in which the flowable composition is to be contained; and at least three applicators of different type, each of the applicators having at least one outlet through which the fiowable composition is to be applied, with a~ least a first of the applicators being securable to the container, and with at least a second of the applicators being securable to the 'first of the applicators:
characterised in that only the at least one outlet of a selected one of the at least three applicators is exposed at any one time while applying the flowable composition therethrough.

WO 99/26510 PCTNS98I2483~
s The fact that only the at least one outie~ o' the selected applicator is exposed, during use, means that manipulation of the selected applicator does not involve any rise: of mess by any flowable composition left ~.. o; on the other applicators.
B. Many hair treatment devices have an applicator in the form o. an elongate dispensing spout which gradually narrows along its length to a free end provided with a discr.arcre eryfice.
As disclosed in JP(UM)-A-7-2295'_, suca hair :.reatment device can also have an applicator ir. the form of G comb provided with an internal passage for directing a hair composition from the discharge orifice of the spout to a plurality ef small holes in teeth of the comb.
In use, the comb is a push fit over the spout such that the comb extends beyond the free end of the spout and is retained along part of the length of the spout by friction.
It has been found, in practice, that if movement of the comb is impeded by any knots or tangles in the hair, ~he bending moment and torque at the junction of the comb with the spout can be such that the comb is sim~,~ltaneously pulled off the spout and rotated about the spout.
A similar structure is disclosed in JP-A-9-118375, whic~ discloses how two liquids can be mixed and then delivered through a comb which is detachably securable to a nozzle by any appropriate means. The two liauids may form a hair colouring composition. However, spillage of hair colouring composition down the outside of the nozzle could result in failure to be able to attach the comb to WO 99/26510 PCTNS98I2483~

the nozzle. This is because the ha=r ..cicuring composition. would act as a lubricar:~ anc would deleteriously affect any snap and/or threaded fit of the comb to the nozzle.
According to a second aspect of the present inver.~ior~, however, an applicator system fcr use in:
delivering a flowable composition comprises:-a container in which the flowable composition. is to be contained;
'first applicator means having first outlet means, the first applicator means being attachable to the container in a manner such that the flowable composition in the container can be dispensed through the first outlet means;
and second applicator means having second outlet means, the second applicator means being locatable over the first applicator means in a manner such that the flowable composition can pass through the first outlet means before being dispensed through the second outlet means;
characterised in that the second applicator means is attachable to the container.
The fact that the second applicator means is attached to the container, during use, rather than being attached to the first applicator means, can result in a stronger construction in which the second applicator means is far less likely to rotate or come apart.
C,D. Hair treatment devices are typically provided with different types of applicator to suit different hair treatment situations.

WO 99/26510 PC'f/US98/2s83~
o_- example, there can be advantages in :-~avir.g a dispensing spout to allow a line of hair composition. tc be applied, a dispensing pervious member such as a cloth t;
allow heir composition to be wiped over the hair, and a dispensing comb or brush to allow hair composition to be thorcughly worked throughout the length of the hair.
lr.deed US-A-4211247 discloses such dispensing applicators and also discloses non-dispensing sponges for use _.. :~ere;y spreading hair composition after the hair composit~c~ :gas beer. applied by a dispensing app'~icator.
According to a third aspect of the present invention, however, an applicator system for use in delivering a flowable composition. comprises:-a container in which the flowable composition is to be contained; and at least three applicators of different type, including a line applicator in which the flowable composition is delivered through a single outlet, a surface applicator in which the flowable composition is delivered through a plurality of outlets onto a surface, and a brush/comb-like applicator in which the flowable composition is delivered through a plurality of outlets and dispersed by a plurality of elongate parting members;
characterised in that the surface applicator is of foam o. sponge material having a resiliently compressible porous structure from which the flowable composition is to be delivered.
The fact that the surface applicator is in the form of a resiliently compressible foam or sponge means that, t.
during use, t::ere car. be a muci: more ever. app;icat~cr c~
the 'lowabie composition than had hitherto been possible just by wining with a cloth because the foam or sponge can absorb and redistribute the flowable composition..
According to a fourth aspect of the present invention, moreove r an applicator system for use i.-.
delivering a fiowable composition comprises:-a container in which the flowable composi~ior. is t be contained; and at ~_eas~ t:.ree aaali'ators oz d~.'ferer_~ hype including a line applicator in which the =lowable composition. is delivered through a single cutlet, a surface aoclicator i:: which the flowable composition. is delivered through a plurality of outlets onto a surface, and a brush/comb-like applicator in which the flowable composition is delivered through a plurality of outlets and dispersed by a plurality of elongate parting members:
characterised in that at least two of the plura'_ity of outlets in the brush/comb-like applicator are formed in respective ones of the elongate parting members.
The fact that at least two of the elongate parting members have their own outlets means,that, during use, the elongate parting members are better able to disperse the flowable composition, which is particularly important when the flowable composition is a hair colouring composition..
In a particularly preferred embodiment of an applicator system, embodying all four of the above-noted different aspects of the present invention:-(a; one of t:~e applicators is a spout having a single WO 99/26510 PCT/US98/2483~
., elo.~.gate passageway through which the flowab':= co:~posi Lion is to be dispensed, (b) another of the applicators is of foam or sponge material having a resiliently compressible porous structure from which the flowable composition~. is to be delivered, and (c) yet another of the applicators has a plurality of elongate parting members projecting from a support to which the flowable composition is delivered through a housing.
Preferably, the foam or sponge material is in the forr.; of a pad at or near one end of a carrier. For ease of assembly, the carrier may be a detachabie,pusr. fit on the spout. For ease of application, particu~.arly when targeting specific areas, the pad may extend only partly around the circumference of the carrier.
Preferably, each of the elongate parting members is in the form of a substantially rigid tooth. For ease of manufacture, particularly when moulding in a plastics material, the teeth may be arranged in at least one row.
The teeth may but need not necessarily have generally triangular outlines of different transverse dimensions when viewed from an end of the at least one row. For ease of subsequent dispersal, the flowable composition may be delivered from the teeth and, for example, a free end of each of the teeth may have at least one of the outlets.
Preferably, the elongate parting members and the support are removably detachable from the housing. This allows the provision of a plurality of the supports, from which one is to be selected by a user, the elongate parting members of different supports being of different type. For example, a comb-like support with substantially WO 99/26510 PCT/US98I2483~

rigid teeth may be replaced by a brus'.~.~.-lit:e support with flexible filaments.
Preferably the elongate parting members and the support are formed as a unit which is securable to the housing by securing means including a catch. The catch may be resiliently deflectable and engageabie wits an aperture extending through the housing such that the catch is releasable remotely from the elongate parting members.
There may be a further catch operable as a pivot. The resil=entlv deflectable catch should be releasable by finger pressure - it may however, be possible for the elongate pa=tina members and the support to be removed from the housing merely by rolling the housing over a hard surface, thereby releasing the resiliently deflectable catch .
For ease and strength of assembly the housing may be a removable screw fit with the container, both the housing and the container being formed with lug means which snap passed one another when the housing has been fully screwed onto the container at a predetermined alignment.
The spout may be a push fit with the container.
To facilitate delivery of the flowable composition, when the flowable composition passes through an applicator in the form of a spout before being dispensed through an applicator in the form of a housing and a support with a plurality of elongate parting members projecting from the support, the housing may have a guide tube which receives a free end of the spout when the housing is located over the spout.
Preferably, the container is a bag-in-bottle container such that the flowable composition can be WO 99/26510 PC'T/US98/2483~

delivered at any orientation of the bag-_..-b:tt_e container.
In such containers, an inner collapsible layer defines a reservoir, and an outer deformable layer is separated from the inner collapsible layer by a buffer cone. Valve means is operable to control entry of a_r into the buffer zone (bottle) and exit of flowable composition from the reservoir (bag). In cede= tc sir.:plify assembly, wish consequent commercial advantages, the valve means may comprise a valve member c' ~~itary ccnsLruc:.ion.
Indee~~, the valve member may comprise a~ ann;:lar flapper valve ~or cor.trclling the opening of one or more air _..'-ets ir. the spout, the annular flapper valve surrounding a central quadrolobe valve for controlling the opening of the single elongate passageway in the spout, and the central quadrolobe valve being a push fit within the single elongate passageway in the spout.
I~ will be appreciated that the fiowable composition may be a hair and/or scalp composition.
An applicator system, according to the present invention, will now be described in greater detail, by way of example only, with reference to the accompanying drawings, wherein:-Figure 1 is an exploded perspective view of a cap a bottle, a flexible bag, a support tube an insert, a valve a spout, a sponge pad, a comb housing and a comb -all being components in a hair colouring kit embodying the present invention;
Figure 2 is a fragmentary enlarged cross-sectional WO 99/26510 PC'T/US98124835 view sowinc -he cao w~~en secured to the bottle;
Figure 3 is a plan view of the insert;
Figure 9 is a schematic cross-sectional ~-iew, taken perpendicularly to the cross-sectional view o~ Figure ~, showing a dye container when docked with the vnsert to allow dve in the dve container to be added to t:~e flexible bag;
Figure 5 is a perspective view showing the spoilt when secured to the bottle;
Figure n is a fragmentary enlarged cross-sectional view of Figure 5;
Figure ~ is a perspective view similar to Figure 5 but showing the sponge pad when secured to the spout;
Figure 8 is a cross-sectional view of Figure 7;
Figure 9 is a perspective view showing the comb housing when secured to the bottle with the comb secured to the comb housing;
Figure 10 is a cross-sectional view of Figure 9; and Figures 11 and 12 are, respectively, cross-sectional views of the comb and the comb housing before being secured together.
The accompanying drawings illustrate a hair colouring kit embodying all aspects of the present invention - the different inventive aspects, for which protection is being sought in the present and several contemporaneous patent applications, relate to a delivery system as well as to WO 99,"16510 PCTNS98124835 ~1 various applicators a:~d applicator svstesa for use _..
delivering a flowable composition.
Although the flowable composition is preferably a hair colouring composition, no aspect of the present invention is restricted to such a specific flowabie composition. Other examples of flowable compositions are:
medicaments e.g. for petcare; foodstuffs e.g. cake mixes;
cleaning fluids e.g. for garmentcare or carpetcare;
cosmetics e.g. body lotions or moisturisers; adhesives or lubricants.
;;se of a hair colouring composition can be aroblematical.
One problem is gnat the hair colouring composition may need to be prepared from two or more component materials just prior tc use. This means that the component materials need to be stored separately in a manner allowing a user to mix the component materials when required. Typically, one of the component materials is hydrogen peroxide and another of the component materials is a dye. The user must not, however, be exposed to any danger or any risk of staining when adding the dye to the hydrogen peroxide.
Another problem is that the hair colouring composition may need to be applied to the hair through an applicator at any angle. If the applicator is fed from a simple squeeze bottle, the applicator will be ready for use in any orientation when the squeeze bottle is full.
However, as the squeeze bottle is progressively emptied, it is found that the applicator is not ready for immediate use in any orientation, but may first need to be primed to offset the effect of any suckback of the hair colouring composition. This makes it difficult to control the WO 99/26510 PCTIUS98I2483~
., app__cation or the hair cclourinc~mp~cs_t~o::, particularly tc the hairline wrilst avoiding stay~_g c the skin.
The present hair colouring kit not only ~'_lows the hair colouring composition to be prepared just prior tc use, but has applicators fed by a user-controlled delivery system in which the hair colouring composition is discharged by a mechanically generated aressure differential (not an aeroso' ) in such a way that the :air colouring composition is always ready tc be disc:~.a=gec at any o=ientation o' the delivery system.
F~1= orientation delivery is possible for all oa the hair colouring composition which is discharged - whic:~ can be over 900 or even 950 of the hair colouring compcsiLion which :~as been prepared.
The present hair colouring kit also allows the hair colouring composition to be delivered in user-regulated amounts through applicators to specific areas to achieve an even colour distribution with minimal mess.
No one applicator is equally suitable, even if carefully manipulated, for applying hair colouring composition to the roots, the hairline and the main body of a head of hair. It is therefore usual to provide applicators of different types selected from a line applicator, a surface applicator and a brush/comb-like applicator. The line applicator can be a spout with a single outlet and the surface applicator can be of porous material with a plurality of outlets. The brush/comb-like applicator can have a plurality of outlets for dispensing hair colouring composition which is then dispersed by a plurality of elongate parting members. As might be expected, the elongate parting members might resemble the , CA 02310470 2000-OS-17 WO 99/26510 PCT1US98~~a83~
bristles cf a brus~ or the Teeth of a coma.-,. _._~ cf t:.e different applicator types are to be brouai:t intc fluid communication with a container for the hair colouring composition.
Specific advantages of the present hair colouring kit are that:-la) only a selected one of three applicators of different type is exposed during use so that there is nc risk during manipulation of the hair of mess being caused by anv hair colouring composition left in or on the other anclicators;
(b1 G surface applicator from three appi«ators of different type is of foam or sponge materia_ having a resiliently compressible porous structure to provide improved spreading of the hair colouring composition;
and (c) a brush/comb-like applicator from three applicators of different type has at least two of its outlets formed in respective ones of its elongate parting members to provide improved dispersal of the hair colouring composition.
Other specific advantages of the present hair colouring kit are that a one-piece valve simultaneously Derforms the dual functions of controlling entry of air and exit of hair colouring composition, a support for elongate parting members is secured to a housing by at least one catch which is releasable from a position remote from t:.e hair colouring composition and with a line applicator attached to a container, a brush/comb-like applicator is locatable over the line applicator yet is still attachable directly to the container.

~4 Before describing a surface applicator wit: reference to Figures 7 and 8, and a brush/comb-like applicator with reference to Figures 9 to i2, a delivery system incorporating a line applicator will be described with reference to FiQUres 1 to 6.
A bottle 10 may be formed with a hollow body ~2 which is ef generally oval section. and is closed at a lower end but has an open. neck 14 at an upper end. The neck: may be formed with an externa_ thread 16. The neck '~ may also be fcr~~ed with a pair of opposed lug means =~ of w::ich cne ~ s show.~. ~ r. Figure 1 . Each of the lug means 18 ~re~erab'_y includes a gap 20 approached by a ramp 2~ for a Durpose to be described hereinafter.
At least the body 12 may be formed of a resiliently deformable plastics material such that the bottle 10 can quickly reform in shape when released from having been squeezed. The plastics material may be low density polyethylene, linear low density polyethylene (LLDPE) or polypropylene and may be transparent. If not transparent, the plastics material is preferably translucent and may or may not be coloured.
A flexible bag 24 may be formed of two overlapping sheets 26 of the same shape which are sealed together around most of their common periphery to form a side sealed sachet having an upper opening 28 and a lower V-shaped edge 30. The bag 24 defines a reservoir for a first material, such as hydrogen peroxide, and should therefore provide a good moisture barrier. Each of the sheets 26 may be of laminated metallised material, and preferably W eludes the following three layers: LLDPE
sealant/adhesive/metallised PET (polyethylterphalate).

WO 99J26510 PCTlUS98~2483~
The bag 24 is insertabie into the bottle 1C ,...roug::
the neck 14 to form a container with a: cuter defc~~:abie layer (body i2) and~ar. inner collapsible layer sheets 20'~
separated from one another by a buffer zone 32, as s:~own in FiQUre 4.
As also shown in Figure 4, a support tube 34 may be insertable _into the bag 24 through the opening 28. The tube 34 may have a plurality of holes 36 along l is length and provide ar: at least partially rigid c:~annei which is open in cross-section. A lower end 38 of the tube 34 may be open or closed. The lower end 38 of the tube 34 can be it contact with the bag 24 - alternatively, t:~e lower end 38 of the tube 34 may be close to but not in contact with the v-shaped edge 30 of the bag 24. An upper end of the t~,ibe 34 may be secured to an insert 40 by any suitable method or means. and may be a simple push fit in the insert 40.
The insert 40 is partially insertable into the bag 24 through the opening 28 and is also partially insertable irte the bottle 10 through the neck 14. Preferably, the insert is permanently fixed in a fluid tight manner to the sheets 26 around the opening 28, for example by heat or ultrasonic welding. The insert 40 and the bag 24 could alternatively be of unitary construction. The insert 40 is preferably irremovably fixed to the neck ;4 by a simple push fit or any other suitable method or means but could alternatively be removable by a user to achieve a refillable system.
As shown in Figures 2, 4 and 6, the insert 40 may be a one-piece plastics moulding having a tubular member 42 which defines an orifice and extends centrally of a side wall 44, a transverse wall 46 and a pair of opposed lower sections 48.

WO 99/26510 PCT/US98/2483~

The side wall 49 is shown with an outwarcly extending flange 50 at i is upper end, for limiting inset tion o~ the insert 40 into the bottle 10, and an inwardly directed rib 52 at a position generally mid-way between the f'_ange 50 and t'.~.e transverse wail 96. The transverse wail 46 is shown with a plurality of holes 54 therethroug:: for joining the buffer zone 32 to an annular channel 56 defined between the tubular member 42 and the side wall 44 and thus surrounding the tubular member 42. The opposed lower sections 48 are shown as hollow. to prevent sinkage in -mouldi~:g, and thereby facilitate the fluid tight fixing cf the ,:aert 40 to the bag 24.
A lower end of the t~,ibular member 42 may be inwardly recessed for receiving the upper end of the tube 34 and an upper end of the tubular member 42 may be inwardly chamfered.
Typically the bag 29 will be supplied to a user when already partially filled with a first material, such as hydrogen peroxide. It will therefore be necessary to prevent the first material escaping through the tube 34 and the tubular member 42. A removable flip top cap could be provided for closing the upper end of the tubular member 42. Alternatively, the upper end of the tubular member 42 could be closed by a rupturable film seal.
Preferably, however, a removable cap 58 is provided, as shown in Figure 2.
The cap 58, which may again be a one-piece plastics moulding, may have a plug seal 60 for sealingly closing the upper end of the tubular member 42. A securing part 62 of the cap 58 could be an airtight fit with the neck 14 of the bottle 10. However, there are advantages in forming the securing part 62 of the cap 58 as a non-airtig::t fit. For example, tzere could be a:: .~..terna_ thread 64 which is a breathable screw fit with t:~e external thread 16 on the neck 19 of the bootee iC to provide an air passageway to atmosphere from the annular channel 56.
One advantage is that, if hydrogen peroxide _.. t:~.e bag 24 became unstable and produced oxygen, the bag ~4 could expand with air in the buffer zone 3~ escaping throucth the hcles 54 in the inser t 40 and then between t:~e t::r eads 16 and 64 .
~zother advantage is that, if the buffer cone 32 were to be subjected to an unwanted pressure change, for example as a result of air travel, air could again either escape from or enter the buffer zone 32 by the above-indicated route.
The hair colouring kit as so far described allows a user to prepare a hair colouring composition or other flowable composition just prior to use.
In practice, at least a second material is added to the first material in the reservoir. If the reservoir had been supplied in an empty state, or had been emptied in a previous use, it would of course first be necessary to add some first material to the reservoir. In any event, the initially separated materials need to be allowed to mix.
As shown schematically, in Figure 4, the second material may be stored in an entirely independent container 66. .f the first material is hydrogen peroxide, the second material is likely to be a dye. As dyes can be oxygen sensitive, the container 66 may need to provide an excellent oxygen barrier. Moreover, if the dye is in the form of a gel, cream or paste, for example, the container WO 99/26510 PCT/G'S98I2a835 6o could need to be plastically defcrmable to ~-low a use.
to squeeze the dye therefrom. On the other hand, if the dye is in the form of a liquid, the dye might be able tc exit the container 66 under the influence of gravity.
If the container 66 is resiliently defo~able, the bag 24 is preferably inflated with air above the _irs material - if the container 66 is not resi_iently deformable, the bag 24 is preferably deflated.
T_::e user may be supplied with a plura'_ity cf the containers 66 and eaci: of the containers 66 may contain a different material suc:~ as a different shade o~ hair coicrant with the intention that one or more cf the containers 66 are to be emptied into the reservoir to form a particular flowable composition such as a hai= colouring composition of specifically selected shade.
It is desirable for the container 66, or each of the containers 66, to include a long nozzle 68 which can extend completely through the tubular member 42 into the tube 34. T.'.~.is can give good docking in that the container 66 is less likely to come apart from the bottle 10 even whey. the user is using both hands to squeeze the container 66. It can also promote good mixing in that the contents ef the container 66 might be squirted from close range directly into the contents of the bag 24. Clearly, it will be necessary for the container 66 to be opened before ,insertion of the long nozzle 68 into the tubular member 42, and opening may be effected by breaking o~f, cutting off or twisting off the nozzle's tip 70 (shown in broken outline in Figure 4).
It will be appreciated that, as the second material is emptied from the container 66 into the bag 24, the volume or any air in the bag 24 above the first material WO 99 6510 PC'TNS98~24835 wi~.l De progresSlVely reduced, and any ssch compressed air should be encouraged to escape to prevent the bag 2~ frem expanding.
.f the nozzle 68 is a loose fit in the tubular member 42, t:~e compressed air will escape through that loose fit.
Alternatively, one or more splines could be formed along the 'length of the nozzle 68 and/or one or more air escape castellations could be formed on the dye container adjace.~.t a base of the nozzle 68. Dependent on the nature of the second material in the container 6d, and the dimensions, the coTpressed air might inject upwards throuch the seco~d material to form an air pocket l:. the ~ontainer 66 which expands as the air pocket in the bag 24 contracts.
Even if the bag 24 does expand, air in the buffer zone 32 would escape through the holes 54 in the transverse wall 46 of the insert 40, as previously described.
AFter sufficient of the second material has been added to the first material, the container 66 is removed from the bottle 10 and is either discarded, or resealed and saved for future use.
As alternatives to adding the second material to the first material by decanting, the second material may be contained in a container which is formed with or located within the bag 24 and which is rupturable. for example by squeezing the body 12 of the bottle 10, or which is otherwise capable of allowing the second material to be added to the first material.
When the second material has been added to the first material, they are preferably mixed at this stage by WO 99/26510 PCTNS98I2.i83~
.' shat:inc the bottle 1C. __ would be possible for the user to prevent escape of the contents of the bag 24 by placing a gloved finger over the upper end o' the tubuia= member 42 whilst shaking. It may be more convenient, however, for the user to replace the cap 58 so that the plug seal 60 closes the upper end of the t~,:bular member 42. In either case, the tube 34 acts to restrain the bag 25, while shaking and/or inverting the bottle 10, and thereby aids mixing by allowing the contents of the bag 24 to move more freely than the bag 24. It is believed that optimum mixir.Q by shaking occurs if around l00 of the volume of the bag 24 is left as headspace. If the bag 24 and the body 12 of the bottle 10 are both translucent, it is possible to check visually whether or not mixing ras been completed.
To prepare for discharge of the flowable composition formed by the first and the second materials, or more specifically the hair colouring composition formed by the hydrogen peroxide and the dye, the insert 90 is again exposed to allow a spout 72 to be attached to the insert 40, as shown in Figures 5 and 6.
The spout 72 may once again be a one-piece plastics moulding, here comprising a cylindrical portion 74 leading to a domed portion 7o which itself leads to a tapered portion 78. A bottom end of the cylindrical portion 74 is . formed with an outwardly directed rib 80. A top end of the cylindrical portion 74 is formed adjacent a shoulder 82 presented by the domed portion 76. One or more, such as three, air inlets 84 extend through the domed portion 76 and may be equally circumferentially spaced around the domed portion 76. The tapered portion 78 is formed with an elongate passageway 86 which gradually narrows along its length from a larger lower end to a single outlet 88 at a smaller upper end. An annular recess 90 is formed in WO 99/26510 PCTIGiS98~'2483 ., .
G.
an inner s~,:rface cf the tapered portion ~8 near t:ze ~a~ge=
lower end of the passageway 86. An annular _'.b a~ _s formed o:. an outer surface of the tapered Fort~on ''8 near the smaller upper end of the passageway 86.
A valve member 99, which may be formed of ~ silicone polymer and may be of unitary construction, is atta:.rab-~e to the snout 72.
?=e'erably, the valve member 94 includes an inlet part _.. the form of an annular flapper valve 96 w::ich acts as a cne-way check valve to control entry of air throug the air ir.'_e:.s 8':.
Preferably, the valve member 94 also includes an outlet hart in the form of a central quadrolobe valve 98 which acts as a one-way check valve to control exit of hair colouring composition through the passageway 86. A
quadrolobe valve 98 is preferred because it opens from the centre not the side and thus gives a smoother flow of hair colouring composition therethrough. However, as alternatives to a quadrolobe valve 9B,-the outlet part of the valve member 94 could be a flapper valve, an umbrella valve or a duckbill valve.
The flapper valve 96 and the quadrolobe valve 98 may be joined by an intermediate part including a transverse sealing wall 100 and a frusto-conical locating wall 102 whose outer surface has an annular rib 104.
The valve member 94 is easily attached to the spout 72 by pushing the quadrolobe valve 98 into the passageway 86 until the annular rib 104 on the valve member 99 engages with the annular recess 90 in the spout '%2.
:he snout '72 is then itself easily attached to the insert 40 by pushing the cylindrical portion %4 of the snout 72 into the annular channel 56 c' the insert 4C' until the rib 80 on the cylindrical portio: % 4 s:.aps passed the rib 52 on the insert 40, with an audible o_- at least tangible click, at which time the shoulder 82 of the spout 72 is brought into abutment with the flange 5C of the insert 40 and the sealing wall 100 of the valve member 94 is brought into sealing engagement with the upper end of the tubular member 42 of the insert 40.
In a:~ alternative construction, the spout 72 car be attached to the insert 40 by a screw fit rather than the above-..~.o ted push ~ l t .
The bottl a 10 could be shaken of ter the spout 72 has been attached to the insert 40 in order to mix or re-mix the flowable composition.
In order to deliver the hair colouring composition from the bag 29 to the outlet 88 in the spout 72, from where the hair colouring composition is discharged in a line to for example the roots of a head of hair, the body 12 of the bottle 10 is squeezed by the user. This compresses the air in the buffer zone 32 but the compressed air cannot escape through the fluid passageway including the holes 54, the annular channel 56 and the air inlets 84 because the flapper valve 96 acts to close the air inlets 84. Instead, the compressed air acts to partly collapse the bag 24 so that some hair colouring composition is forced out through the fluid passageway including the tube 34, the tubular member 42, the frusto-conical locating wall 102 and the quadrolobe valve 98, which opens to let the hair colouring composition therethrough. When the user stops squeezing the body 12 of the bottle 10, the bottle 10 quickly reforms in shape so that the buffer zone 32 expands. The quadroiobe valve WO 99 6510 PCT/US98/2483~
.~: 3 96 doses to prevent suc'r:bac't: of the hay= coiourinc composition beyond the quadrolobe valve 98 and she bag 2y maintains its partly collapsed state. Instead, air i~
sucked into the buffer zone 32 past the flapper valve 90 which opens to let air in through the air inlets 84.
Squeezing of the body 12 of the bottle 1G ~s repeated by the user with whatever pressure and frequency is deemed appropriate to the circumstances.
It will be appreciated ~:7at the holes 3ti in the tube 3~ can prevent the hair colouring composition becoming trapped, as the bag 24 is progressively collapsed to bring the sheets 26 of the bag 24 into contact with one another, and the tube 39 might itself collapse to allow flowable composition in the tube 34 to be discharged.
As the hair colouring composition is dispensed, the user may see through the at least translucent body 12 that the bag 24 is collapsing. This should reassure a user who feared that the hair colouring composition could run out without warning.
Although the reservoir for the first material may be a side sealed sachet, as hereinbefore described, the reservoir could take other forms - for example, an inner collapsible layer distinct from an outer deformable layer would also be provided by an inverting-half-bag bottle or a delaminating bottle, the latter preferably peeling progressively away from a neck thereof, or by a compression blown bag integrally moulded with the insert.
Moreover, although the valve member may be of unitary construction but dual function, as hereinbefore described, the valve member could take other forms - for example, separate valves could be provided for controlling exit of WO 99/26510 PCT/US98;:483~
,, .
y hair colcurina compos_tion and entry o= air, the latter possibly being a simple air hole in the body cf the bottle which a user closes with a finger.
Referring now to Figures 7 and 8. a surface applicator 106 is shown removably secured over the outlet 88 of the spout 72. More particularly, the sur=ace applicator 106 may include a pad 108 of foam or sponge material zaving a resiliently compressible porous structure. Such a structure not only has a pi~ralit~~~ of outlets, but allows hair colouring composition emerging 'ros. t':a outlet 88 to pass through the pad 108 and by careful manipulation be evenly spread along the hair'_ine.
The pad 108 may be located at or near an upper end ef a carrier 110 w;th a lower half of the carrier 110 being frusto-conical in the direction leading from a smaller upper end to a larger lower end. An inner surface of the lower half of the carrier 110 may be formed with an annular recess 112 for detachably engaging with the annular rib 92 on the spout 72 when the carrier 110 is pushed onto the spout 72. The carrier 110 and the spout %2 may be mutually configured to avoid relative rotation.
The pad 108 may present a curved face, to facilitate accurate application, with the curved face extending only partly around the circumference of an upper half of the carrier 110. If the pad lOB is formed of a plastics material, and the carrier 110 is also formed of a plastics material, the pad 108 may be fixed to the carrier 110 by use of an adhesive. Clearly, if the original surface applicator 106 is not to be cleaned and re-used, a range of surface applicators 106 could be provided which are either similar if intended to be disposable or different if intended to be interchangeable.
As shown in Figures 9 to 12, a brush/comb-like applicator 114 could be removably secured over the outlet WO 99/26510 PCT/US98;24835 88 or the spout 72 instead of the s~,:rface applicator C6, the brush/comb-like applicator 114 including a housi~c _'~c and a releasable unit 118.
The brush/comb-like applicator 114 could be a screw fit or a snap fit to the neck 14.
The housing 116 is yet another one-piece plastics moulding here defining, considered from the top, an aperture 120, a tapered open chamber 122 having .. series of slotted webs 124 on its opposed major side walls, a guide tube 120' ensuring open communication. into the charnbeY 1 ?2 °rom a chamber 128, a slot 13C at a:: upper end of the chamber 128, an internal thread 132 near a lower end o' the chamber 128, and a pair of opposed lug means 134 at the lower end o' the chamber 128.
The internal thread 132 is preferably strippable from a mould without screwing.
The housing I16 is a removable screw fit with the bottle 10 by virtue of the internal thread 132 in the chamber 128 engaging the external thread 16 on the neck 14. As the housing 116 is progressively screwed on, the outlet 88 of the spout 72 enters the guide tube 126.
Finally, the lug means 134 cam along the ramps 22 of the lug means 18 and then snap into the gaps 20 of the lug means 18. The snap may give an audible or at least tangible click to indicate that the housing 116 has been fully screwed onto the bottle 10. In this final position, with the lug means 18 and 132 interengaged, the chamber 122 opens in the direction of the major axis of the body 12, which it will be recalled is of generally oval section.
The releasable unit 118, which is the final component WO 99/26510 PCT/US98J2483~

of the present hair colouring kit, may again b. formed as a one-piece moulding cf a plastics material suc:, as polypropylene, with an additive such as silicone tc give a low coefficient of friction.
The releasable unit 118 can be at least in part translucent to signal to a user that the flowable composition is about to be delivered.
The unit i18 comprises a support i36 which is generally planar and gradually tapers from a narrower upper end to a wider lower end. The narrower upper end :gas a resiliently deflectable catch 138 extending therefrom wits a barb-like leading end 138a. The wirier lower end has a rigid catch 140 extending therefrom with a barb-li~:e leading end 140a. The periphery of the support 136 vs formed with a skirt 142 which is of complementary outline to the opening of the chamber 122. A plurality of elongate parting members such as substantially rigid teeth 199, project from the support 136 in a direction opposed to the resiliently deflectable catch 138, the rigid catch 190 and the skirt 142. A plurality of outlets 196 for the flowable composition can extend through the support 136.
As shown most clearly in Figure 9. the teeth 144 may be arranged in two rows. The teeth 144 may but need not necessarily have generally triangular outlines of different transverse dimensions when viewed from the ends of the two rows. The transverse dimensions of the teeth 144 may progressively increase from the narrower upper end of the support 136 to the wider lower end of the support 136. Moreover, the teeth 144 of the different rows may be staggered with respect to one another, and may again have generally triangular outlines but now of generally similar thicknesses when viewed from the sides of the twc rows.

WO 99126510 PCT/US98~'24835 As shown most clearly in Figure 11, at least two but possibly all of the outlets 146 further extend through respective ones of the teeth 144. However, .t may be desirable for one or more of the outlets 146 not tc extend throucr:. the teeth 144. For example, at least one outlet 146 may be positioned in the support ;36 between adjacent ones o° the teeth 144. At least two but possibly all of the outlets 146 w:~ich extend through the teeth 144 may emerge r!:rough cri°ices 148 at the free ends of the teeth .44.
r fact, although it is convenient tc state that the c=ifices 148 are at the free ends of the teeth 144, the orifices 148 may be sprightly set back from the free ends ef the Teeth 144, partly to avoid direct coating of the scalp, and partly as a result of a preferred moulding techniaue known as the passing face shut off technique, which allows the orifices 148 to be formed by a simple two-part mould without need of side pins.
'r'c assemble the uni t 118 with the housing 116, it is merely necessary to locate the barb-like leading end 140a of the rigid catch 140 in the slot 130 and then pivot.
This brings the free edge of the skirt 142 into engagement with the slotted webs 124 and also deflects the barb-like leading end 138a of the catch 138 to allow entry of the catch 138 into the aperture 120. The unit 118 is fully secured to the housing 116 when the barb-like leading end 138a of the catch 138 emerges from the aperture 120 to snap engage with the material of the housing 116 around the aperture 120.
To remove the unit 118 from the housing 116, the reverse procedure is followed. The catch 138 is releasable by finger pressure. Alternatively, it may be possible to release the catch 138 by rolling ''.:e :.c~;ainc 116 over ~ hard surface in a manner such that the and surface knocks the barb-like leading end 138a of the catch 138 back into the aperture 120. It will be appreciated that release of the catch 138 occurs remotely o. the orifices 148.
One reason for removing the unit 118 from the hcusing 116 may be to facilitate cleaning of any residual hair colouring composition.
A.~.other reason for removing the unit lib trom the housing 116 may be to allow replacement by another unit 1.8 0' different type. For example, it may be desirable to replace the substantially rigid teeth 144, which give a comb-like construction, by either a brush-like construction including a plurality of resiliently flexible bristles, or a sponge-like construction or, indeed, another comb-like construction in which there are teeth and/or orifices of different dimensions and/or different configurations. This may facilitate thorough dispersal of dispensed hair colouring composition in different situations, such as different hair lengths or different hair types.
The dimensions, positions and shapes of the orifices 148 may be changed, in different units 118, dependent on the rheology of the hair colouring composition, or on the need for different colouring results such as root coverage, streaking or highlighting.
As a general matter, relevant to all of the present disclosure, the first container in which the first material is to be held can be construed as including the bottle when fitted with any one or combination of the different applicators.

WO 99126510 PC'T/US98/24835 As another Qenera'~ matter, relevant t~ all .... the present disclosure, the flowable compositicn can be capable of demonstrating pseudo-plastic flow behaviour, here meaning that the flowable composition decreases in viscosity as it is sheared and, once the shearing has stopped, the internal structure of the flowable composition (which was responsible for the original viscosity) rebuilds very quickly causing an increase in viscosity approac'.~.ing t:-pat of the original viscosity.
The f'_owable, composition should be capable o~ the above-noted pseudo-plastic flow behaviour within a shear strain gate range of O.Ols-l to 10,000s-', which is the most probable shear strain. rate range to be encountered when the flowable compositicn is a hair colouring composition.
An example of a suitable flowable composition could have a viscosity of no less than 0. 01 ~~a-. s- :(preferably no less than 0.15 Pa. s ) when measured at a shear strain rate of 2000s-' and no more than S Pa.s (preferably no more than 1.4 Pa. s) when measured at a shear strain rate of 10s-'.

Claims (32)

What is claimed is:
1. An applicator system, for use in delivering a flowable composition, comprising:
a container in which the flowable composition is to be contained; and at least three applicators of different type, including a line applicator in which the flowable composition is delivered through a single outlet, a surface applicator in which the flowable composition is delivered through a plurality of outlets onto a surface, and a brush/comb-like applicator in which the flowable composition is delivered through a plurality of outlets and dispersed by a plurality of elongate parting members;
characterised in that the surface applicator is of foam or sponge material having a resiliently compressible porous structure from which the flowable composition is to be delivered.
2. An applicator system according to claim 1, wherein the line applicator is a spout.
3. An applicator system according to claim 2, wherein the spout has a single elongate passageway through which the flowable composition is to be dispensed.
4. An applicator system according to claim 2, wherein the spout is a push fit connection with the container.
5. An applicator system, for use in delivering a flowable composition, comprising:
a container in which the flowable composition is to be contained; and at least three applicators of different type, including a line applicator in which the flowable composition is delivered through a single outlet, a surface applicator in which the flowable composition is delivered through a plurality of outlets onto a surface, and a brush/comb-like applicator in which the flowable composition is delivered through a plurality of outlets and dispersed by a plurality of elongate parting members;

characterised in that at least two of the plurality of outlets in the brush/comb-like applicator are formed in respective ones of the elongate parting members.
6. An applicator system according to claim 5, wherein the line applicator is a spout.
7. An applicator system according to claim 6, wherein the spout has a single elongate passageway through which the flowable composition is to be dispensed.
8. An applicator system according to claim 7, wherein a plurality of air inlets in the spout are openable by operation of a valve member.
9. An applicator system according to claim 8, wherein the single elongate passageway in the spout is also openable by operation of the valve member.
10. An applicator system according to claim 9, wherein the valve member comprises an annular flapper valve surrounding a central quadrolobe valve which is a push fit connection within the single elongate passageway in the spout.
11. An applicator system according to claim 6, wherein the elongate parting members project from a support to which the flowable composition is delivered through a housing.
12. An applicator system according to claim 11, wherein the housing has a guide tube which receives a free end of the spout when the housing is located over the spout.
13. An applicator system according to claim 11, wherein each of the elongate parting members is in the form of a substantially rigid tooth.
14. An applicator system according to claim 13, wherein the teeth are arranged in at least one row, with a free end of each of the teeth having at least one of the outlets.
15. An applicator system according to claim 14, wherein the elongate parting members and the support are removably detachable from the housing.
16. An applicator system according to claim 15, wherein the elongate parting members and the support are formed as a unit which is securable to the housing by securing means including a catch.
17. An applicator system according to claim 16, wherein the catch is resiliently deflectable and engageable with an aperture extending through the housing, the catch being releasable remotely from the elongate parting members.
18. An applicator system according to claim 17, wherein there is a further catch operable as a pivot.
19. An applicator system according to claim 15, wherein there is a plurality of the supports from which one is to be selected by a user, the elongate parting members of different supports being of different type.
20. An applicator system according of claim 11, wherein the housing is a removable screw fit with the container.
21. An applicator system according to claim 20, wherein the housing and the container are formed with lug means which snap passed one another when the housing has been fully screwed onto the container.
22. An applicator system according to claim 5, wherein only a selected one of the applicators is exposed at any one time while applying the flowable composition therethrough.
23. An applicator system according to claim 5, wherein the surface applicator is of porous material.
24. An applicator system according to claim 23 wherein the porous material is a resiliently compressible foam or sponge material.
25. An applicator system according to claim 24, wherein the foam or sponge material is in the form of a pad at one end of a carrier.
26. An applicator system according to claim 24, wherein the foam or sponge material is in the form of a pad near one end of a carrier.
27. An applicator system according to claim 26, wherein the line applicator is a spout, and wherein the carrier is a detachable push fit connection on the spout.
28. An applicator system according to claim 26, wherein the pad extends only partly around the circumference of the carrier.
29. An applicator system according to claim 5, wherein the container is a bag-in-bottle container such that the flowable composition can be delivered at any orientation of the bag-in-bottle container.
30. An applicator system according to claim 29, wherein a valve member of unitary construction is operable to control both entry of air into the bottle and exit of flowable composition from the bag.
31. An applicator system according to claim 5, wherein the flowable composition is to be applied to the hair, the scalp, or both.
32. An applicator system according to claim 31, wherein the flowable composition is a hair coloring composition.
CA002310470A 1997-11-21 1998-11-20 Fluid applicators Expired - Fee Related CA2310470C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9724714.2A GB9724714D0 (en) 1997-11-21 1997-11-21 Applicators
GB9724714.2 1997-11-21
PCT/US1998/024835 WO1999026510A1 (en) 1997-11-21 1998-11-20 Fluid applicators

Publications (2)

Publication Number Publication Date
CA2310470A1 CA2310470A1 (en) 1999-06-03
CA2310470C true CA2310470C (en) 2004-03-16

Family

ID=10822492

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002310470A Expired - Fee Related CA2310470C (en) 1997-11-21 1998-11-20 Fluid applicators

Country Status (14)

Country Link
EP (1) EP1032287B1 (en)
JP (1) JP2001523501A (en)
KR (1) KR20010086210A (en)
CN (1) CN1168408C (en)
AT (1) ATE269015T1 (en)
AU (1) AU1531899A (en)
BR (1) BR9815315A (en)
CA (1) CA2310470C (en)
CO (1) CO5050377A1 (en)
DE (1) DE69824623T2 (en)
ES (1) ES2222618T3 (en)
GB (1) GB9724714D0 (en)
PE (1) PE20000028A1 (en)
WO (1) WO1999026510A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2138936B1 (en) * 1998-06-30 2000-09-16 Clemente Marco Juan Carlos APPLICATOR BRUSH FOR TREATMENT OF HAIR AND / OR LEATHER.
FR2805442B1 (en) * 2000-02-25 2003-02-14 Oreal DEVICE FOR PACKAGING AND APPLYING A HAIR COMPOSITION
JP4517532B2 (en) * 2001-04-27 2010-08-04 花王株式会社 Hair dye application brush
JP4517531B2 (en) * 2001-04-27 2010-08-04 花王株式会社 Hair dye application brush
DE60219520T2 (en) * 2001-12-20 2007-12-27 Koninklijke Philips Electronics N.V. APPARATUS FOR APPLYING HAIR TREATMENT PRODUCTS
US8316863B2 (en) 2002-07-17 2012-11-27 L'oreal S.A. Applicator nozzle and applicator assembly incorporating such a nozzle
MX2007003487A (en) 2004-09-24 2007-05-18 Procter & Gamble Method of pre-treatment for hair colourants and bleaches.
WO2012020841A1 (en) * 2010-08-12 2012-02-16 三菱鉛筆株式会社 Application tool
CN102772189A (en) * 2011-05-09 2012-11-14 张凤飞 Portable shoe cleaner
WO2014092340A1 (en) * 2012-12-13 2014-06-19 Kim Dong Hyun Apparatus for foam dyeing hair
KR101252431B1 (en) * 2012-12-13 2013-04-08 김동현 Dyed hair bubble device
CN105142456A (en) * 2013-07-23 2015-12-09 阿波罗工业株式会社 Push head unit of pump dispenser
FR3009208B1 (en) * 2013-07-31 2018-04-27 Aptar France Sas HEAD OF DISTRIBUTION AND APPLICATION
FR3032334B1 (en) * 2015-02-06 2019-04-19 Hawa Anne INTERCHANGEABLE HAIR BRUSH WITH PRODUCT REFILL
ES1143784Y (en) * 2015-05-18 2015-12-07 Del Cano Mauricio Campo Configurable fluid applicator system
WO2017078745A1 (en) * 2015-11-02 2017-05-11 Intel Plastics Inc. Material dispenser/applicator
FR3063609B1 (en) * 2017-03-09 2019-03-29 Aptar France Sas FLUID PRODUCT DISPENSING AND APPLICATION ASSEMBLY.
WO2019165538A1 (en) * 2018-02-27 2019-09-06 Lev Yael Hair-coloring composition and method
KR101892674B1 (en) 2018-07-11 2018-10-04 주식회사 딥포인트 Cosmetic containers with comb elements

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH118931A (en) * 1926-10-15 1927-02-16 Rudolf Schneitter Robert Brush for cum etc.
US4209027A (en) 1974-06-21 1980-06-24 Shila Morganroth Hair treatment devices and packaging therefor
US4211247A (en) 1974-06-21 1980-07-08 Shila Morganroth Devices for use in selectively altering hair color
US4011879A (en) * 1976-06-03 1977-03-15 Roberts Shepard D Combination applicator-dispenser hair styler
US4781311A (en) * 1984-08-17 1988-11-01 The Clorox Company Angular positioned trigger sprayer with selective snap-screw container connection
GB2174356A (en) * 1985-05-03 1986-11-05 Albyn Of Stonehaven Limited Container with closure and spreader
GB8901320D0 (en) * 1989-01-21 1989-03-15 Elopak Systems Nozzle
DE8902166U1 (en) * 1989-02-23 1989-06-15 Schwan-Stabilo Schwanhaeusser Gmbh & Co, 8500 Nuernberg, De
DE3931111A1 (en) * 1989-09-18 1991-03-28 Rupert Soltenau Cap for hair-treatment receptacle - is used with gel or foam and consists of plastics cap with comb teeth on outside, and inner ducts
US5299877A (en) * 1991-11-26 1994-04-05 Donald Birden Liquid applicator
US5316403A (en) * 1992-12-15 1994-05-31 Mansour Amin F Apparatus for applying a film of liquid
JPH0722951U (en) 1993-09-29 1995-04-25 花王株式会社 Pouring container
JPH08164954A (en) * 1994-12-15 1996-06-25 Yoshida Kogyo Kk <Ykk> Tube container
US5643403A (en) * 1994-12-19 1997-07-01 Robert N. Poole Wall covering removal system with a surface cleaning apparatus and a surface scarifying apparatus
JPH09118375A (en) 1995-10-26 1997-05-06 Shiseido Co Ltd Container two-liquid mixing

Also Published As

Publication number Publication date
CN1168408C (en) 2004-09-29
KR20010086210A (en) 2001-09-10
CO5050377A1 (en) 2001-06-27
CA2310470A1 (en) 1999-06-03
DE69824623T2 (en) 2005-02-03
GB9724714D0 (en) 1998-01-21
EP1032287A1 (en) 2000-09-06
ATE269015T1 (en) 2004-07-15
PE20000028A1 (en) 2000-03-19
ES2222618T3 (en) 2005-02-01
BR9815315A (en) 2000-10-24
AU1531899A (en) 1999-06-15
CN1279590A (en) 2001-01-10
JP2001523501A (en) 2001-11-27
DE69824623D1 (en) 2004-07-22
WO1999026510A1 (en) 1999-06-03
EP1032287B1 (en) 2004-06-16

Similar Documents

Publication Publication Date Title
US6302607B1 (en) Fluid applicators
US6505986B1 (en) Applicator systems
US6334449B1 (en) Fluid delivery system
CA2310470C (en) Fluid applicators
US5755241A (en) Applicator for applying fluid
US20050072442A1 (en) Self-contained hair-coloring system for touch-up, highlighting and less than full treatment applications
US6168335B1 (en) Applicator and dispensing device using same
EP3034426B1 (en) Valve assembly for a hair color bottle
US5913314A (en) Combination salon tool device
EP1032359B1 (en) Fluid delivery system
EP1032286B1 (en) Applicator systems
WO2002022466A1 (en) Applicator
AU2002300056B2 (en) Fluid delivery system
CA2309107A1 (en) Applicators
MXPA00004906A (en) Fluid applicators
JP2004262505A (en) Liquid container with pouring unit
MXPA00004904A (en) Applicator systems
AU684666C (en) Applicator for applying a fluid
MXPA00004905A (en) Fluid delivery system
CZ20001658A3 (en) Device for supply of liquid
MXPA00004903A (en) Applicators

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20131120