CA2295734A1 - Catalyst component for polymerization of olefins, polymerization catalysts and process of polymerization of olefins by using the same - Google Patents

Catalyst component for polymerization of olefins, polymerization catalysts and process of polymerization of olefins by using the same Download PDF

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Publication number
CA2295734A1
CA2295734A1 CA002295734A CA2295734A CA2295734A1 CA 2295734 A1 CA2295734 A1 CA 2295734A1 CA 002295734 A CA002295734 A CA 002295734A CA 2295734 A CA2295734 A CA 2295734A CA 2295734 A1 CA2295734 A1 CA 2295734A1
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Canada
Prior art keywords
polymerization
olefins
catalyst component
radical
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002295734A
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French (fr)
Other versions
CA2295734C (en
Inventor
Toshifumi Takemori
Shigeharu Yamamoto
Masatoshi Tsuchitani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Maruzen Petrochemical Co Ltd
Original Assignee
Maruzen Petrochemical Co., Ltd.
Toshifumi Takemori
Shigeharu Yamamoto
Masatoshi Tsuchitani
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Application filed by Maruzen Petrochemical Co., Ltd., Toshifumi Takemori, Shigeharu Yamamoto, Masatoshi Tsuchitani filed Critical Maruzen Petrochemical Co., Ltd.
Publication of CA2295734A1 publication Critical patent/CA2295734A1/en
Application granted granted Critical
Publication of CA2295734C publication Critical patent/CA2295734C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The present invention relates to a metallocene compound as a catalyst component for the polymerization of olefins, said compound, is stable to air and moisture so that generates no hydrogen halide by hydrolysis and easily handled, and has a high storage stability arid a high catalyst activity. Specifically, the catalyst component for the polymerization of olefins comprises a transition metal composition represented by the general formula [1] and [2]:
(R a Cp)a (R'b Cp) M (-X-Ar-Y c)4 -(m+n) . . . . [1]
R" (R d Cp) (R'a Cp) M (-X-Ar-Y c)2 . . . . [2]
.wherein M is Ti, Zr or Hf; (R a Cp), (R'b Cp), (R d Cp) and (R"c Cp) each is a radical having the cyclopentadienyl skeleton; R" is a radical which links (R d Cp) and (R'c Cp); (-X-Ar-Y c) is a grouping in which the aromatic ring Ar substituted by a specified radical Y bonds to M through an oxygen or sulphur atom X.
CA002295734A 1997-07-09 1997-12-04 Catalyst component for polymerization of olefins, polymerization catalysts and process of polymerization of olefins by using the same Expired - Fee Related CA2295734C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP18419997 1997-07-09
JP9/184199 1997-07-09
PCT/JP1997/004441 WO1999002571A1 (en) 1997-07-09 1997-12-04 Catalytic components for the polymerization of olefins, polymerization catalysts, and process for polymerizing olefins by using the same

Publications (2)

Publication Number Publication Date
CA2295734A1 true CA2295734A1 (en) 1999-01-21
CA2295734C CA2295734C (en) 2005-02-08

Family

ID=16149099

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002295734A Expired - Fee Related CA2295734C (en) 1997-07-09 1997-12-04 Catalyst component for polymerization of olefins, polymerization catalysts and process of polymerization of olefins by using the same

Country Status (8)

Country Link
US (3) US6350831B1 (en)
EP (2) EP1426386B1 (en)
JP (1) JP3244124B2 (en)
CN (1) CN100460422C (en)
CA (1) CA2295734C (en)
DE (2) DE69737368T2 (en)
TW (1) TW464658B (en)
WO (1) WO1999002571A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2000262096A1 (en) * 2000-07-12 2002-01-21 E.I. Du Pont De Nemours And Company Metallocene polymerization catalyst
JP2002069248A (en) * 2000-08-30 2002-03-08 Sumitomo Chem Co Ltd Polyolefin resin composition and film made of the same
US7923437B2 (en) 2001-02-16 2011-04-12 Cargill, Incorporated Water soluble β-glucan, glucosamine, and N-acetylglucosamine compositions and methods for making the same
US8222232B2 (en) 2001-02-16 2012-07-17 Cargill, Incorporated Glucosamine and N-acetylglucosamine compositions and methods of making the same fungal biomass
US7816514B2 (en) 2001-02-16 2010-10-19 Cargill, Incorporated Glucosamine and method of making glucosamine from microbial biomass
JP2002249527A (en) * 2001-02-27 2002-09-06 Nippon Zeon Co Ltd Addition copolymer, hydrogenated addition copolymer, and their production methods
JP2003012682A (en) * 2001-06-27 2003-01-15 Sumitomo Chem Co Ltd Zirconium compound, method for producing the same and use thereof
US7094723B2 (en) * 2002-04-18 2006-08-22 Equistar Chemicals Lp Catalysts containing at least one heterocyclic ligand for improving the catalysts' performance of olefin polymerization
CN1302016C (en) * 2002-08-29 2007-02-28 Lg化学株式会社 Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
DE10250062A1 (en) 2002-10-25 2004-05-06 Basell Polyolefine Gmbh New racemic metallocene complexes are useful as catalysts or catalyst components for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective syntheses
US6710005B1 (en) * 2003-04-10 2004-03-23 Equistar Chemicals, Lp Aluminoxane modification
US6930156B2 (en) * 2003-10-22 2005-08-16 Equistar Chemicals, Lp Polymer bound single-site catalysts
JP4133772B2 (en) 2003-12-01 2008-08-13 丸善石油化学株式会社 Olefin polymerization catalyst and olefin polymerization method using the same
US6967184B2 (en) * 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US7125939B2 (en) * 2004-08-30 2006-10-24 Equistar Chemicals, Lp Olefin polymerization with polymer bound single-site catalysts
CN1310970C (en) * 2005-06-17 2007-04-18 中国科学院长春应用化学研究所 Polymerisation catalyst precursor of olefins N and preparation thereof
US7423098B2 (en) * 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
KR101060838B1 (en) * 2006-04-24 2011-08-30 에스케이이노베이션 주식회사 Bis-arylaryloxy catalyst system for preparing ethylene homopolymer or copolymer with α-olefin
WO2008008112A1 (en) * 2006-07-14 2008-01-17 Exxonmobil Chemical Patents Inc. Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof
WO2008060512A1 (en) 2006-11-14 2008-05-22 Univation Technologies, Llc. Catalyst systems and polymerization processes
DE102007009862A1 (en) * 2007-02-28 2008-09-04 Chemtura Organometallics Gmbh Preparing bridged, stereo-rigid diphenoxide metallocene compound, useful as a catalyst to prepare polyolefin, comprises reacting a metallocene dihalide compound with an alkylating reagent and reacting the mixture with e.g. phenol
FR2916199B1 (en) * 2007-05-14 2012-10-19 Inst Francais Du Petrole OLEFIN OLIGOMERIZATION METHOD USING A CATALYTIC COMPOSITION COMPRISING AN ORGANOMETALLIC COMPLEX CONTAINING A HETERO-ATOMIC FUNCTIONALIZED PHENOXY LIGAND
KR101151606B1 (en) * 2007-12-31 2012-06-08 에스케이이노베이션 주식회사 Transition metal complexes, catalysts composition containing the same, and process for preparing ethylene homopolymers or copolymers of ethylene and a-olefins using the same
US7884165B2 (en) 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
KR101077071B1 (en) * 2008-11-03 2011-10-26 에스케이이노베이션 주식회사 Ethylene Copolymer with Improved Impact Resistance
US9181371B2 (en) 2011-11-08 2015-11-10 Univation Technologies, Llc Methods for producing polyolefins with catalyst systems

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Also Published As

Publication number Publication date
EP1426386A1 (en) 2004-06-09
DE69737776D1 (en) 2007-07-12
CN1259963A (en) 2000-07-12
EP1426386B1 (en) 2007-05-30
WO1999002571A1 (en) 1999-01-21
TW464658B (en) 2001-11-21
DE69737776T2 (en) 2008-01-31
JP3244124B2 (en) 2002-01-07
US6323149B1 (en) 2001-11-27
EP0997480B1 (en) 2007-02-14
CA2295734C (en) 2005-02-08
US20020039963A1 (en) 2002-04-04
EP0997480A1 (en) 2000-05-03
CN100460422C (en) 2009-02-11
DE69737368D1 (en) 2007-03-29
DE69737368T2 (en) 2007-10-31
US6350831B1 (en) 2002-02-26
US6569800B2 (en) 2003-05-27
EP0997480A4 (en) 2000-09-06

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