CA2282336A1 - Detergent bars comprising adjuvant powders for delivering benefit agent and process for manufacture of said bars - Google Patents
Detergent bars comprising adjuvant powders for delivering benefit agent and process for manufacture of said bars Download PDFInfo
- Publication number
- CA2282336A1 CA2282336A1 CA002282336A CA2282336A CA2282336A1 CA 2282336 A1 CA2282336 A1 CA 2282336A1 CA 002282336 A CA002282336 A CA 002282336A CA 2282336 A CA2282336 A CA 2282336A CA 2282336 A1 CA2282336 A1 CA 2282336A1
- Authority
- CA
- Canada
- Prior art keywords
- powder
- surfactant
- benefit agent
- bars
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title abstract 8
- 239000003795 chemical substances by application Substances 0.000 title abstract 5
- 239000002671 adjuvant Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000003599 detergent Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 6
- 239000004094 surface-active agent Substances 0.000 abstract 3
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract 1
- 239000002280 amphoteric surfactant Substances 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 229920006317 cationic polymer Polymers 0.000 abstract 1
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 229920001477 hydrophilic polymer Polymers 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/40—Proteins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Adjuvant powder compositions contain a benefit agent or agents and which powder compositions are used in detergent bar compositions to enhance delivery of the benefit agent. The carriers used to form adjuvants must have melting point high enough to survive spray-drying process. Specifically, the invention relates to a bar compositions comprising (A) about 1% to 30 % powder comprising: (a) 1% to 70 %
by wt. powder benefit agent; (b) 15 % to 98 % by wt. powder carrier; (c) 1% to 10 % by wt. powder water; and (d) 0% to 30 % by wt.
powder deposition/processing aid (e.g., surfactant, cationic polymer and/or hydrophilic polymer); and (B) 99 % to 70 % chips comprising % to 90 % of a surfactant system wherein the surfactant is selected from the group consisting of soap, anionic surfactant, nonionic surfactant, amphoteric surfactant, cationic surfactant and mixtures thereof.
The present invention also provides a process for making bars wherein (A) and (B) are separately prepared; wherein (a), (b), (c) and optional (d) are mixed at 40° to 80 °C; wherein the mixture of (a) and (b) is spray dried at 80 °C to 200 °C at a pressure of 0.10 to 0.30 MPa; and wherein (A) and (B) are mixed, plodded, and extruded into a final bar.
by wt. powder benefit agent; (b) 15 % to 98 % by wt. powder carrier; (c) 1% to 10 % by wt. powder water; and (d) 0% to 30 % by wt.
powder deposition/processing aid (e.g., surfactant, cationic polymer and/or hydrophilic polymer); and (B) 99 % to 70 % chips comprising % to 90 % of a surfactant system wherein the surfactant is selected from the group consisting of soap, anionic surfactant, nonionic surfactant, amphoteric surfactant, cationic surfactant and mixtures thereof.
The present invention also provides a process for making bars wherein (A) and (B) are separately prepared; wherein (a), (b), (c) and optional (d) are mixed at 40° to 80 °C; wherein the mixture of (a) and (b) is spray dried at 80 °C to 200 °C at a pressure of 0.10 to 0.30 MPa; and wherein (A) and (B) are mixed, plodded, and extruded into a final bar.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/821501 | 1997-03-21 | ||
| US08/821,501 US5770556A (en) | 1997-03-21 | 1997-03-21 | Process for making bar compositions having enhanced deposition of benefit agent comprising use of specific spray dryable adjuvant powders |
| US08/821502 | 1997-03-21 | ||
| US08/821,502 US5955409A (en) | 1997-03-21 | 1997-03-21 | Bar compositions comprising adjuvant powders for delivering benefit agent |
| PCT/EP1998/000528 WO1998042814A1 (en) | 1997-03-21 | 1998-01-23 | Detergent bars comprising adjuvant powders for delivering benefit agent and process for manufacture of said bars |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2282336A1 true CA2282336A1 (en) | 1998-10-01 |
| CA2282336C CA2282336C (en) | 2007-05-22 |
Family
ID=27124549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002282336A Expired - Fee Related CA2282336C (en) | 1997-03-21 | 1998-01-23 | Detergent bars comprising adjuvant powders for delivering benefit agent and process for manufacture of said bars |
Country Status (17)
| Country | Link |
|---|---|
| EP (1) | EP0973858B1 (en) |
| JP (1) | JP2001518100A (en) |
| KR (1) | KR100498944B1 (en) |
| CN (1) | CN1137981C (en) |
| AR (1) | AR012088A1 (en) |
| AU (1) | AU736652B2 (en) |
| BR (1) | BR9808284A (en) |
| CA (1) | CA2282336C (en) |
| CZ (1) | CZ296195B6 (en) |
| DE (1) | DE69816058T2 (en) |
| ES (1) | ES2202811T3 (en) |
| HK (1) | HK1025119A1 (en) |
| ID (1) | ID23412A (en) |
| IN (1) | IN189608B (en) |
| PL (1) | PL188422B1 (en) |
| RU (1) | RU2188854C2 (en) |
| WO (1) | WO1998042814A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6919446B1 (en) | 1998-01-20 | 2005-07-19 | Grain Processing Corp. | Reduced malto-oligosaccharides |
| BR9907096A (en) | 1998-01-20 | 2000-10-24 | Grain Processing Corp | Reduced malto-oligosaccharides |
| US6380379B1 (en) | 1999-08-20 | 2002-04-30 | Grain Processing Corporation | Derivatized reduced malto-oligosaccharides |
| ATE332638T1 (en) | 1999-10-20 | 2006-08-15 | Grain Processing Corp | COMPOSITIONS CONTAINING REDUCED MALTO-OLIGOSACCHARIDE AS A PRESERVATIVE |
| WO2001029164A1 (en) * | 1999-10-20 | 2001-04-26 | Grain Processing Corporation | Reduced malto-oligosaccharide cleansing compositions |
| US7226899B2 (en) | 2003-12-23 | 2007-06-05 | Kimberly - Clark Worldwide, Inc. | Fibrous matrix of synthetic detergents |
| JP5276770B2 (en) * | 2005-09-01 | 2013-08-28 | ポーラ化成工業株式会社 | Cosmetics for wrinkle removal massage |
| AU2015415925B2 (en) * | 2015-12-04 | 2019-05-16 | Colgate-Palmolive Company | Cleansing bars with taurine |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA773077B (en) * | 1976-06-04 | 1979-01-31 | Colgate Palmolive Co | Process for making a toilet soap bar |
| US5096608A (en) * | 1985-05-13 | 1992-03-17 | The Procter & Gamble Company | Ultra mild skin cleansing composition |
| US4808322A (en) * | 1988-03-10 | 1989-02-28 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
| US5154849A (en) * | 1990-11-16 | 1992-10-13 | The Procter & Gamble Company | Mild skin cleansing toilet bar with silicone skin mildness/moisturizing aid |
| ES2158939T3 (en) * | 1994-03-30 | 2001-09-16 | Procter & Gamble | COMPOSITION IN PADS FOR CLEANING AND HYDRATION OF THE SKIN. |
| US5520840A (en) * | 1995-03-22 | 1996-05-28 | Lever Brothers Company | Detergent bars comprising water soluble starches |
-
1997
- 1997-03-10 IN IN128BO1997 patent/IN189608B/en unknown
-
1998
- 1998-01-23 DE DE69816058T patent/DE69816058T2/en not_active Expired - Fee Related
- 1998-01-23 WO PCT/EP1998/000528 patent/WO1998042814A1/en active IP Right Grant
- 1998-01-23 RU RU99122352/13A patent/RU2188854C2/en not_active IP Right Cessation
- 1998-01-23 CN CNB988051079A patent/CN1137981C/en not_active Expired - Fee Related
- 1998-01-23 ID IDW991050A patent/ID23412A/en unknown
- 1998-01-23 PL PL98335807A patent/PL188422B1/en not_active IP Right Cessation
- 1998-01-23 CZ CZ0335199A patent/CZ296195B6/en not_active IP Right Cessation
- 1998-01-23 ES ES98904167T patent/ES2202811T3/en not_active Expired - Lifetime
- 1998-01-23 BR BR9808284-1A patent/BR9808284A/en not_active IP Right Cessation
- 1998-01-23 CA CA002282336A patent/CA2282336C/en not_active Expired - Fee Related
- 1998-01-23 AU AU62148/98A patent/AU736652B2/en not_active Ceased
- 1998-01-23 EP EP98904167A patent/EP0973858B1/en not_active Expired - Lifetime
- 1998-01-23 JP JP54478198A patent/JP2001518100A/en not_active Ceased
- 1998-01-23 KR KR10-1999-7008551A patent/KR100498944B1/en not_active IP Right Cessation
- 1998-03-17 AR ARP980101193A patent/AR012088A1/en unknown
-
2000
- 2000-07-10 HK HK00104222A patent/HK1025119A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ID23412A (en) | 2000-04-20 |
| CZ296195B6 (en) | 2006-02-15 |
| AU6214898A (en) | 1998-10-20 |
| CN1255942A (en) | 2000-06-07 |
| PL188422B1 (en) | 2005-01-31 |
| KR20010005494A (en) | 2001-01-15 |
| IN189608B (en) | 2003-03-29 |
| HK1025119A1 (en) | 2000-11-03 |
| RU2188854C2 (en) | 2002-09-10 |
| EP0973858B1 (en) | 2003-07-02 |
| CZ9903351A3 (en) | 2000-12-13 |
| PL335807A1 (en) | 2000-05-22 |
| WO1998042814A1 (en) | 1998-10-01 |
| DE69816058D1 (en) | 2003-08-07 |
| KR100498944B1 (en) | 2005-07-04 |
| DE69816058T2 (en) | 2003-12-24 |
| AR012088A1 (en) | 2000-09-27 |
| AU736652B2 (en) | 2001-08-02 |
| CN1137981C (en) | 2004-02-11 |
| JP2001518100A (en) | 2001-10-09 |
| ES2202811T3 (en) | 2004-04-01 |
| BR9808284A (en) | 2000-05-16 |
| EP0973858A1 (en) | 2000-01-26 |
| CA2282336C (en) | 2007-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |