CA2272428C - Secondary battery - Google Patents

Secondary battery Download PDF

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Publication number
CA2272428C
CA2272428C CA002272428A CA2272428A CA2272428C CA 2272428 C CA2272428 C CA 2272428C CA 002272428 A CA002272428 A CA 002272428A CA 2272428 A CA2272428 A CA 2272428A CA 2272428 C CA2272428 C CA 2272428C
Authority
CA
Canada
Prior art keywords
secondary battery
injection hole
safety member
cap assembly
electrolyte injection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002272428A
Other languages
French (fr)
Other versions
CA2272428A1 (en
Inventor
Un Sick Park
Young Bae Song
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung SDI Co Ltd
Original Assignee
Samsung Display Devices Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Display Devices Co Ltd filed Critical Samsung Display Devices Co Ltd
Publication of CA2272428A1 publication Critical patent/CA2272428A1/en
Application granted granted Critical
Publication of CA2272428C publication Critical patent/CA2272428C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/574Devices or arrangements for the interruption of current
    • H01M50/578Devices or arrangements for the interruption of current in response to pressure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • H01M50/609Arrangements or processes for filling with liquid, e.g. electrolytes
    • H01M50/627Filling ports
    • H01M50/636Closing or sealing filling ports, e.g. using lids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • H01M50/3425Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Gas Exhaust Devices For Batteries (AREA)
  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Filling, Topping-Up Batteries (AREA)

Abstract

A secondary battery comprises a can into which an electrode assembly is inserted, a cap assembly mounted to an opening of the can; and an electrolyte injection hole formed on at least one of the can and cap assembly, and a safety member to close the electrolyte injection hole. The electrolyte injection hole is formed on a negative portion of the cap assembly. The safety member is inserted into and welded on the electrolyte injection hole.

Description

SECONDARY BATTERY
TECHNICAL FIELD
The present invention relates to a secondary battery and, more particularly, a safety system of a secondary battery which can reduce internal pressure thereof to prevent the explosion of the secondary battery.
BACKGROUND ART
Generally, a secondary battery is a rechargeable battery such as a 1 o nickel-metal hydride battery, a lithium battery or a lithium-ion battery which is widely used in many applications. Such a secondary battery is subject to high internal pressures due to gases generated by chemical reactions when it is discharged and recharged. Though not common, it is possible for the battery to explode as a result of the gases produced.
Therefore, many presently known secondary batteries have a cap assembly provided with a safety valve which can discharge gases through a discharge hole formed on a cap cover so as to reduce the pressure in the batteries when the pressure in the battery is excessively raised.
The lithium-ion battery comprises an electrode assembly inserted 2o into a cap. A cap assembly is mounted on an upper end of the can.
Electrolyte is injected into the can through an inlet port formed on the cap assembly. Insulating members are disposed between the electrode assembly and the can.
Referring to Fig. 3, there is shown a conventional cap assembly 2.
The cap assembly 2 comprises a negative portion 4 welded on an upper end of the can, a positive portion 6 disposed on a central portion of the negative portion 4, and an insulating plate 8 disposed between the negative portion 4 and positive portion 6. A rivet 10 penetrates through the negative potion 4 and positive portion 6 is coupled to the positive electrode of the roll 3o electrode assembly.
In the above described conventional lithium-ion battery, if the pressure within the battery is abruptly increased by the gas generated therein, the battery may explode. Thus, there is provided gas release means in the secondary battery.
'That is, safety grooves 12 are formed in the negative portion 4 of the cap assembly 2 through a mechanical process, etching or electrofoaming process.
The safety grooves 12 are broken open when the internal pressure of the battery is increased above a predetermined level, thereby preventing the batter's I-rom exploding.
An electrolyte injection hole 14 is formed on the negative portion 4 of the cap assembly 2. After the electrolyte is injected through the hole 14, a plug 16 is snugly f tted into the hole 14 and is then welded to provide a seal.
FIG. 4 shows another example of a conventional cap assembly 2.
In this example, a ball(not shown) is inserted into the injection hole 18 and is then welded to provide a seal.
In the above described conventional cap assembly shown in FIGS. 3 and 4, since the safety grooves and the electrolyte injection hole are formed on the negative portion which is small in size, it is difficult to design and manufacture the same.
In the conventional cap assembly shown in FIG. 4, since the diameter of the injection hole is small, it is difficult to inject electrolyte into the can.
DISCLOSURE OF INVENTION
Therefore, the present invention has been made in an effort to solve the above described drawbacks of the prior art.
It is an object of the present invention to provide a cap assembly for a secondary battery, in which safety means can precisely operate at a pre-set pressure to prevent the battery from exploding.
It is another object of the present invention to provide a cap assembly in which the safety means can be easily formed, thereby reducing manufacturing costs.
To achieve the above objects, the present invention provides a secondary battery comprising a can and a cap assembly, and further comprising: an electrolyte injection hole formed on at least one of the can and the cap assembly; and a safety member breakable by a predetermined battery pressure to close the electrolyte injection hole.
Preferably, the electrolyte injection hole is formed on a negative portion of the cap assembly.
Preferably, the safety member is inserted into and welded on the electrolyte injection hole.
Alternatively, the safety member is disposed on the electrolyte injection hole and is welded on the negative portion.
Preferably, the safety member is made of a material selected from the group consisting of aluminum, nickel, stainless steel, and nickel gilding steel plate.
Preferably, the safety member is designed to be broken by battery pressure of about 10-30 kgf/cm2.
Alternatively, the safety member is provided with a plurality of grooves.
BRIEF DESCRIPTION OF DRAWINGS
The present invention will become more fully understood from the detailed description given hereinbelow and the accompanying drawings which are given by way of illustration only, and thus are not limitative of present invention and wherein:
I~ IG. 1 is a cross sectional view illustrating a secondary battery where a cap assembly according to a preferred embodiment of the present invention is employed;
FIG. 2 is a plane view illustrating a cap assembly of a secondary battery according to a preferred embodiment of the present invention;
FIG. 3 is a plane view illustrating a conventional cap assembly ol~ a secondary battery; and Fig. 4 is a plane view illustrating another conventional cap assembly of a secondary battery.
BEST MODE FOR CARRYING OUT THE INVENTION
The following is the description of the preferred embodiments according to the present invention. In the drawing, like reference numerals have been used to identify like elements in each figure.
Referring first to Figs. 1 and 2, there are respectively shown a sectional view of a secondary battery where a cap assembly 24 according to the present invention is employed and a plane view of the cap assembly 24.
The cap assembly 24 of the present invention is coupled on an upper end of a can 22 in which a roll electrode assembly 20 consisting of a positive electrode, a negative electrode, and a separator, and electrolyte are ~5 received. The can 22 contacts the negative electrode by a tap (not shown).
Insulating plates 26 are provided at upper and lower ends of the electrode assembly 20 to prevent the electrode assembly 20 from contacting the cap assembly 24 and the can 22.
The cap assembly 24 comprises a negative portion 28 which is 2o welded to the upper end of the can 22, a positive portion 32 fomned on a central portion of the negative portion 28, and a rivet 34 mounted penetrating a central portion of the negative portion 28 and positive portion 32. An insulating member 30 is disposed between the negative portion 28 and positive portion 32. The rivet 34 is used as coupling means for 25 coupling the positive portion 32 with the negative portion 28. An insulating member 36 is disposed between the rivet 34 and the negative portion 28. The rivet 34 is connected to the positive electrode of the electrode assembly through a tap 38. That is, the rivet is used as a terminal for connecting the positive electrode to the positive portion 32.
3o An electrolyte injection hole 40 is formed on the negative portion 28 to inject electrolyte into the can.
Although, in this embodiment, an electrolyte injection hole 40 is formed on the negative portion 28, the location of the electrolyte injection hole 40 is not limited to this structure but can be formed on the can 22.
After the electrolyte is injected into the can 22, the injection hole 40 is tightly closed by a safety plate 42. In this embodiment, the safety plate 42 tray be formed having the same size as that of the injection hole and inserted into and welded on the injection hole 40.
Alternatively, the safety plate 42 may be formed having the larger size as that of the injection hole 40 and is positioned to cover the injection hole 40.
~I~he safety plate 42 positioned on the injection hole 40 is welded on the negative portion 28.
rfhe safety plate 42 is for preventing the explosion ofthe battery. That is, The safety plate 42 is formed having the thickness or rigidity less than that of the negative portion 28.
Alternatively, in the case where the safety plate 42 is made in the same material as the negative portion 28, safety grooves 44 are formed on the safety plate 42 through a mechanical process, etching or electrofoaming process. The safety plate 42 are broken open when the internal pressure of the battery is increased above a predetermined level, thereby preventing the battery from exploding.
More in detail, the safety plate 42 may be made of a material selected from the group consisting of aluminum, nickel, stainless steel, and nickel gilding steel plate.
Preferably, the safety plate 42 is designed to be broken by the internal pressure of about 10-30 kgf/cmZ.
Therefore, when the internal pressure of the battery is increased above a predetermined level by gas generated when the battery is charged and discharged, the safety plate 42 is removed or cracked, thereby enabling gas from the battery to be exhausted to reduce the internal pressure.
While this invention has been described in connection with what is presently considered to be the most practical and preferred embodiments, it is to understood that the invention is not limited to the disclosed embodiment, but, on the contrary is intended to cover various modifications and equivalent arrangements and methods included within the spirit and scope of the appended claims.

Claims (11)

What is claimed is:
1. ~A secondary battery comprising a can and a cap assembly, and further comprising:
an electrolyte injection hole formed on at least one of the can and the cap assembly; and a safety member to close the electrolyte injection hole, the safety member breakable for reducing an internal pressure in the can once the internal pressure exceeds a predetermined level.
2. ~A secondary battery of claim 1, wherein the electrolyte injection hole is formed on a negative electrode portion of the cap assembly.
3. ~A secondary battery of claim 1, wherein the safety member is inserted into and welded on the electrolyte injection hole.
4. ~A secondary battery of claim 2, wherein the safety member is disposed on the electrolyte injection hole and is welded on the negative electrode portion thereof.
5. ~A secondary battery of claim 1, wherein the safety member is made of a material selected from the group consisting of aluminum, nickel. stainless steel, and nickel gilding steel plate.
6. ~A secondary battery of claim 1, wherein the safety member is designed to be broken by battery pressure of about 10-30 kgf/cm2.
7. ~A secondary battery of claim 2, wherein the safety member is provided with a plurality of grooves.
8. A secondary battery of claim 7, wherein the safety member is inserted into and welded on the electrolyte injection hole.
9. A secondary battery of claim 7, wherein the safety member is disposed on the electrolyte injection hole and is welded on the negative electrode portion thereof.
10. A secondary battery of claim 7, wherein the safety member is made of a material selected from the group consisting of aluminum, nickel, stainless steel and nickel gilding steel plate.
11. A secondary battery of claim 7, wherein the safety member is designed to be broken by battery pressure of about 10-30 kgf/cm2.
CA002272428A 1997-11-24 1998-04-06 Secondary battery Expired - Lifetime CA2272428C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR97-62414 1997-11-24
KR1019970062414A KR19990041760A (en) 1997-11-24 1997-11-24 Cap Assembly of Secondary Battery
PCT/KR1998/000082 WO1999027591A1 (en) 1997-11-24 1998-04-06 Secondary battery

Publications (2)

Publication Number Publication Date
CA2272428A1 CA2272428A1 (en) 1999-06-03
CA2272428C true CA2272428C (en) 2007-01-09

Family

ID=36748005

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002272428A Expired - Lifetime CA2272428C (en) 1997-11-24 1998-04-06 Secondary battery

Country Status (9)

Country Link
US (1) US6472096B2 (en)
EP (1) EP0981834B1 (en)
JP (2) JP2001519965A (en)
KR (1) KR19990041760A (en)
CN (2) CN1324726C (en)
AT (1) ATE233950T1 (en)
CA (1) CA2272428C (en)
DE (1) DE69811881T2 (en)
WO (1) WO1999027591A1 (en)

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Also Published As

Publication number Publication date
CN1244294A (en) 2000-02-09
US6472096B2 (en) 2002-10-29
WO1999027591A1 (en) 1999-06-03
EP0981834B1 (en) 2003-03-05
DE69811881D1 (en) 2003-04-10
JP2001519965A (en) 2001-10-23
ATE233950T1 (en) 2003-03-15
JP2010238672A (en) 2010-10-21
CA2272428A1 (en) 1999-06-03
CN1324726C (en) 2007-07-04
CN1763991A (en) 2006-04-26
CN100346503C (en) 2007-10-31
EP0981834A1 (en) 2000-03-01
US20020006542A1 (en) 2002-01-17
KR19990041760A (en) 1999-06-15
DE69811881T2 (en) 2004-03-11

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Effective date: 20180406