CA2268633A1

CA2268633A1 - Detergent compositions

Detergent compositions Download PDF

Info

Publication number: CA2268633A1
Authority: CA; Canada
Prior art keywords: alkyl; weight; detergent composition; composition according; formula
Prior art date: 1996-10-18
Legal status : Abandoned

Application number

CA002268633A

Other languages

English (en)

French (fr)

Inventor

Michael Alan John Moss

Robin Gibson Hall

Current Assignee

Procter and Gamble Co

Original Assignee

Individual

Priority date

1996-10-18

Filing date

1997-10-02

Publication date

1998-04-30

1996-10-18 Priority claimed from GB9621799A external-priority patent/GB2318363A/en

1996-10-18 Priority claimed from GB9621791A external-priority patent/GB2318362A/en

1997-03-20 Priority claimed from GB9705816A external-priority patent/GB2323378A/en

1997-10-02 Application filed by Individual filed Critical Individual

1998-04-30 Publication of CA2268633A1 publication Critical patent/CA2268633A1/en

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 219
239000003599 detergent Substances 0.000 title claims abstract description 122
125000000217 alkyl group Chemical group 0.000 claims abstract description 74
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 48
239000003093 cationic surfactant Substances 0.000 claims abstract description 35
125000003342 alkenyl group Chemical group 0.000 claims abstract description 19
125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 10
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 6
-1 alkyl phenol Chemical compound 0.000 claims description 102
150000001875 compounds Chemical class 0.000 claims description 62
239000004094 surface-active agent Substances 0.000 claims description 55
239000007844 bleaching agent Substances 0.000 claims description 32
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 28
239000010457 zeolite Substances 0.000 claims description 28
229910021536 Zeolite Inorganic materials 0.000 claims description 26
239000003945 anionic surfactant Substances 0.000 claims description 23
238000000034 method Methods 0.000 claims description 23
238000005406 washing Methods 0.000 claims description 20
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 18
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 16
229910052783 alkali metal Inorganic materials 0.000 claims description 16
235000014113 dietary fatty acids Nutrition 0.000 claims description 15
239000000194 fatty acid Substances 0.000 claims description 15
229930195729 fatty acid Natural products 0.000 claims description 15
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
150000004665 fatty acids Chemical class 0.000 claims description 14
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 13
150000001340 alkali metals Chemical class 0.000 claims description 11
150000008051 alkyl sulfates Chemical class 0.000 claims description 11
150000004996 alkyl benzenes Chemical class 0.000 claims description 9
239000002736 nonionic surfactant Substances 0.000 claims description 6
229940071207 sesquicarbonate Drugs 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
150000001767 cationic compounds Chemical class 0.000 claims description 5
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
150000001342 alkaline earth metals Chemical class 0.000 claims description 3
150000002989 phenols Chemical class 0.000 claims description 3
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
229940077388 benzenesulfonate Drugs 0.000 claims description 2
239000013042 solid detergent Substances 0.000 claims description 2
QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical compound [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 claims 1
125000005526 alkyl sulfate group Chemical group 0.000 claims 1
230000000750 progressive effect Effects 0.000 claims 1
102000004190 Enzymes Human genes 0.000 description 47
108090000790 Enzymes Proteins 0.000 description 47
229940088598 enzyme Drugs 0.000 description 47
239000002243 precursor Substances 0.000 description 39
150000003839 salts Chemical class 0.000 description 36
239000002253 acid Substances 0.000 description 31
239000000047 product Substances 0.000 description 30
239000004367 Lipase Substances 0.000 description 26
108090001060 Lipase Proteins 0.000 description 25
102000004882 Lipase Human genes 0.000 description 25
108091005804 Peptidases Proteins 0.000 description 25
102000035195 Peptidases Human genes 0.000 description 25
239000002518 antifoaming agent Substances 0.000 description 25
239000003054 catalyst Substances 0.000 description 25
239000004365 Protease Substances 0.000 description 24
235000019421 lipase Nutrition 0.000 description 24
229920001296 polysiloxane Polymers 0.000 description 22
102000013142 Amylases Human genes 0.000 description 21
108010065511 Amylases Proteins 0.000 description 21
239000000463 material Substances 0.000 description 21
239000011734 sodium Substances 0.000 description 21
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 20
235000019418 amylase Nutrition 0.000 description 20
229910052708 sodium Inorganic materials 0.000 description 20
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
108010084185 Cellulases Proteins 0.000 description 19
102000005575 Cellulases Human genes 0.000 description 19
239000002245 particle Substances 0.000 description 19
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 18
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
125000000129 anionic group Chemical group 0.000 description 16
230000000694 effects Effects 0.000 description 16
239000011572 manganese Substances 0.000 description 15
229910052757 nitrogen Inorganic materials 0.000 description 15
229920000768 polyamine Polymers 0.000 description 15
235000019419 proteases Nutrition 0.000 description 15
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 14
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 14
150000002148 esters Chemical class 0.000 description 14
238000009472 formulation Methods 0.000 description 14
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
239000004382 Amylase Substances 0.000 description 13
150000001204 N-oxides Chemical class 0.000 description 13
229920001577 copolymer Polymers 0.000 description 13
150000002500 ions Chemical class 0.000 description 13
229920000642 polymer Polymers 0.000 description 13
229920000036 polyvinylpyrrolidone Polymers 0.000 description 13
239000003352 sequestering agent Substances 0.000 description 13
239000000243 solution Substances 0.000 description 13
108010059892 Cellulase Proteins 0.000 description 12
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 12
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 11
150000007513 acids Chemical class 0.000 description 11
229940025131 amylases Drugs 0.000 description 11
239000003795 chemical substances by application Substances 0.000 description 11
150000004965 peroxy acids Chemical class 0.000 description 11
229920005646 polycarboxylate Polymers 0.000 description 11
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 10
150000001768 cations Chemical class 0.000 description 10
229940106157 cellulase Drugs 0.000 description 10
229910001385 heavy metal Inorganic materials 0.000 description 10
150000004967 organic peroxy acids Chemical class 0.000 description 10
239000002304 perfume Substances 0.000 description 10
239000000344 soap Substances 0.000 description 10
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
229910000323 aluminium silicate Inorganic materials 0.000 description 9
125000003118 aryl group Chemical group 0.000 description 9
125000002091 cationic group Chemical group 0.000 description 9
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
229910052748 manganese Inorganic materials 0.000 description 9
229910052700 potassium Inorganic materials 0.000 description 9
239000011591 potassium Substances 0.000 description 9
239000000843 powder Substances 0.000 description 9
229960003010 sodium sulfate Drugs 0.000 description 9
229910052938 sodium sulfate Inorganic materials 0.000 description 9
239000002689 soil Substances 0.000 description 9
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 8
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
229910019142 PO4 Inorganic materials 0.000 description 8
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 8
238000004851 dishwashing Methods 0.000 description 8
JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 8
125000000623 heterocyclic group Chemical group 0.000 description 8
229920000620 organic polymer Polymers 0.000 description 8
235000021317 phosphate Nutrition 0.000 description 8
229920001223 polyethylene glycol Polymers 0.000 description 8
235000011152 sodium sulphate Nutrition 0.000 description 8
241000894007 species Species 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
239000000654 additive Substances 0.000 description 7
238000004061 bleaching Methods 0.000 description 7
238000004140 cleaning Methods 0.000 description 7
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 7
239000000975 dye Substances 0.000 description 7
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 7
VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 6
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 6
229920002134 Carboxymethyl cellulose Polymers 0.000 description 6
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
125000001931 aliphatic group Chemical group 0.000 description 6
125000002947 alkylene group Chemical group 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
235000010948 carboxy methyl cellulose Nutrition 0.000 description 6
125000001183 hydrocarbyl group Chemical group 0.000 description 6
229910052739 hydrogen Chemical group 0.000 description 6
238000010348 incorporation Methods 0.000 description 6
239000007788 liquid Substances 0.000 description 6
230000008569 process Effects 0.000 description 6
235000019832 sodium triphosphate Nutrition 0.000 description 6
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 6
238000012546 transfer Methods 0.000 description 6
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 5
241000193830 Bacillus <bacterium> Species 0.000 description 5
102220644676 Galectin-related protein_D96L_mutation Human genes 0.000 description 5
CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 5
102000003992 Peroxidases Human genes 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
150000001408 amides Chemical class 0.000 description 5
235000003704 aspartic acid Nutrition 0.000 description 5
OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
150000007942 carboxylates Chemical class 0.000 description 5
239000002270 dispersing agent Substances 0.000 description 5
239000004744 fabric Substances 0.000 description 5
239000003446 ligand Substances 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
239000010452 phosphate Substances 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
125000006850 spacer group Chemical group 0.000 description 5
239000007921 spray Substances 0.000 description 5
241001480714 Humicola insolens Species 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
TTZMPOZCBFTTPR-UHFFFAOYSA-N O=P1OCO1 Chemical compound O=P1OCO1 TTZMPOZCBFTTPR-UHFFFAOYSA-N 0.000 description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
101710194948 Protein phosphatase PhpP Proteins 0.000 description 4
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 4
108010056079 Subtilisins Proteins 0.000 description 4
102000005158 Subtilisins Human genes 0.000 description 4
241000223258 Thermomyces lanuginosus Species 0.000 description 4
239000012190 activator Substances 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
125000002877 alkyl aryl group Chemical group 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
150000001413 amino acids Chemical group 0.000 description 4
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
239000012876 carrier material Substances 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
229960004106 citric acid Drugs 0.000 description 4
108010005400 cutinase Proteins 0.000 description 4
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 4
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
239000001257 hydrogen Chemical group 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
230000002401 inhibitory effect Effects 0.000 description 4
230000002366 lipolytic effect Effects 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
230000003287 optical effect Effects 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
150000004760 silicates Chemical class 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
229940045872 sodium percarbonate Drugs 0.000 description 4
239000007787 solid Substances 0.000 description 4
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
239000003826 tablet Substances 0.000 description 4
QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 4
239000002888 zwitterionic surfactant Substances 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
CCPHAMSKHBDMDS-UHFFFAOYSA-N Chetoseminudin B Natural products C=1NC2=CC=CC=C2C=1CC1(SC)NC(=O)C(CO)(SC)N(C)C1=O CCPHAMSKHBDMDS-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
102000004157 Hydrolases Human genes 0.000 description 3
108090000604 Hydrolases Proteins 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 3
125000002723 alicyclic group Chemical group 0.000 description 3
239000004411 aluminium Substances 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
239000002280 amphoteric surfactant Substances 0.000 description 3
230000003625 amylolytic effect Effects 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
230000001580 bacterial effect Effects 0.000 description 3
150000001642 boronic acid derivatives Chemical class 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
150000004649 carbonic acid derivatives Chemical class 0.000 description 3
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
150000001860 citric acid derivatives Chemical class 0.000 description 3
239000004927 clay Substances 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
235000011187 glycerol Nutrition 0.000 description 3
230000002209 hydrophobic effect Effects 0.000 description 3
150000003949 imides Chemical class 0.000 description 3
210000003141 lower extremity Anatomy 0.000 description 3
229920000609 methyl cellulose Polymers 0.000 description 3
239000001923 methylcellulose Substances 0.000 description 3
235000010981 methylcellulose Nutrition 0.000 description 3
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
238000006384 oligomerization reaction Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
125000004430 oxygen atom Chemical group O* 0.000 description 3
125000005342 perphosphate group Chemical group 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 3
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
108010042388 protease C Proteins 0.000 description 3
229910052710 silicon Inorganic materials 0.000 description 3
239000010703 silicon Substances 0.000 description 3
229960001922 sodium perborate Drugs 0.000 description 3
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
239000000758 substrate Substances 0.000 description 3
150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
239000003760 tallow Substances 0.000 description 3
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
108010075550 termamyl Proteins 0.000 description 3
238000005809 transesterification reaction Methods 0.000 description 3
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 3
239000001993 wax Substances 0.000 description 3
WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 description 2
BETLSGXAHKBRAR-UHFFFAOYSA-N 10-ethylphenothiazine-4-carboxylic acid Chemical compound C1=CC=C(C(O)=O)C2=C1N(CC)C1=CC=CC=C1S2 BETLSGXAHKBRAR-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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239000012071 phase Substances 0.000 description 1
RRCSSMRVSNZOFR-UHFFFAOYSA-N phenyl 3,5,5-trimethylhexanoate;sodium Chemical compound [Na].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1 RRCSSMRVSNZOFR-UHFFFAOYSA-N 0.000 description 1
125000005496 phosphonium group Chemical group 0.000 description 1
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150000003138 primary alcohols Chemical class 0.000 description 1
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150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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150000003335 secondary amines Chemical class 0.000 description 1
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229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
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HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
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239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
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OYNITBPACPPTCI-UHFFFAOYSA-M sodium;boric acid;hydrogen carbonate Chemical compound [Na+].OB(O)O.OC([O-])=O OYNITBPACPPTCI-UHFFFAOYSA-M 0.000 description 1
239000012265 solid product Substances 0.000 description 1
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239000000600 sorbitol Substances 0.000 description 1
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239000007858 starting material Substances 0.000 description 1
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125000001424 substituent group Chemical group 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
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108010038851 tannase Proteins 0.000 description 1
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229960003080 taurine Drugs 0.000 description 1
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238000012360 testing method Methods 0.000 description 1
DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
125000000341 threoninyl group Chemical group [H]OC([H])(C([H])([H])[H])C([H])(N([H])[H])C(*)=O 0.000 description 1
230000001052 transient effect Effects 0.000 description 1
QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
125000005591 trimellitate group Chemical group 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
210000001364 upper extremity Anatomy 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
239000004474 valine Substances 0.000 description 1
125000002987 valine group Chemical group [H]N([H])C([H])(C(*)=O)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1