CA2250432C - Method of making polymers containing hydroxamate functional groups - Google Patents

Abstract

A process is disclosed for the formation of highly anionic hydroxamic acid polymers whereby (meth)acrylic acid polymers are esterified in aqueous solution to poly(meth)acrylates. The resultant polymers are then reacted with an hydroxylamine to produce hydroxamated (meth)acrylic acid containing polymers. The esterified polymers, their hydroxamated derivatives and their use to flocculate Bayer Process streams are also disclosed.

Description

METHOD OF MAKING POLYMERS CONTAINING
HYDROXAMATE FUNCTIONAL GROUPS
Background of the Invention The production of hydroxamate group containing polymers has become of increased importance in the fast few years, mostly due to the increased use of such polymers as flocculants in the Bayer Process for the recovery of alumina. The polymers have become accepted worldwide and have virtually replaced the acrylates, especially in the separation of red mud in the primary settlers.
Primarily, these hydroxamated polymers have been prepared from acrylamide-based polymers by reaction with a hydroxylamine under basic conditions, e.g. a pH of over about 9, see U.S. Patent Nos. 4,902,751 and 5,128,420.
Other procedures for preparing hydroxamated polymers have also been patented, see U.S. Patent No. 4,868,248, which discloses the use of polyacrylic acid as a starting material instead of an amide polymer. Although this process provides a high degree of anionicity to the hydroxamated polymer, the process suffers from various disadvantages which renders it less useful from a commercial standpoint in that the reaction is conducted under acidic conditions, i.e., a pH of 1-6 and appears to be limited to the use of rather low molecular weight polymers.
In U.S. Patent No. 4,767,540, there is disclosed a method whereby acrylic acid-methyl acrylate copolymers are hydroxamated. The copolymers are disclosed as being produced directly from the corresponding monomers, i.e., acrylic acid and methyl acrylate and where low amounts of methyl acrylate result in the copolymer, e.g. 10%, low conversion of the ester to the hydroxamate is reported. Additionally, because of the presence of the acrylate monomer, the molecular weights of the resultant polymers are far lower than would be preferred for most applications. Similar low molecular weight polymers are taught in U.S. Patent No. 4,587,306 as drilling mud additives.
Although the acrylamide-based hydroxamated polymers have found enormous success in the marketplace, there still remains certain applications for which high molecular weight hydroxamated polymers containing higher levels of acrylic acid moieties than are obtainable using previously available processes may be preferred. It was recognized that if hydroxamated polymers could be prepared at a high molecular weight and contain both hydroxamate groups and acrylic acid groups, both of which have been found to be effective in the primary settlers, without the presence of non-ionic acrylamide groups which are known to be detrimental therein, a more efficient flocculation of Bayer Process streams may be achieved by the user thereof.
While hydroxamation of esters proceeds readily under easily controlled conditions, the resultant polymers do not possess a sufficiently high molecular weight so as to be commercially attractive because polymerization of acrylic acid esters per se results in polymers having molecular weights which are less than those preferred for flocculation purposes. See H. L. Cohen, "Journal of Poty Science," Volume 14, pages 7-22 (1976);
Maa, Macromolecules, Volume 22, pages 2036-2039 (1989); Cho, Macromolecules;
Volume 17, pages 2937-2939 (1984). Kern, "Angewandte Chemie" Volume 69, Jahrg. 1957;
Nr. 5 pages 153-171 Hatano, CA 65-15532(g); Renfrow, "Journal of American Chemical Society,"
Volume 59, pages 2308-2314 (1937).
On the other hand, acrylic acid monomers (or their salts) polymerize readily to high-molecular weight polymers but are less easily hydroxamated than the acrylate esters. See U.S. Patent No. 4,868,248; Vranken et al, Journal of Poly Science, Volume XIV, pages 521-534 (i954), in that acidic conditions are required to be used.
Furthermore, in the hydroxamation of ester group containing polymers, solvents must be employed because the polymers are generally not water-soluble, thereby rendering the reaction dangerous and environmentally unattractive. The ester group containing polymers, because of their insolubility, also cannot be polymerized via water-in-oil (inverse) emulsion polymerization, a procedure which is effective for obtaining high molecular weight polymers, because the monomers are soluble in the oil phase of the emulsions.
SUMMARY OF THE INVENTION
A novel procedure has now been found whereby high molecular weight, highly anionic polymers are produced, which polymers contain both acrylate ester and acrylic acid linkages, optionally with other pendant groups. The procedure comprises ~esterifying-a high molecular weight acrylic acid polymer in aqueous solution. The-resuttant..polymer is then hydroxamated.
Petrie, Analytical Chemistry, Volume 37, No. 7, pages 919-920, June 1965 teaches that a hydroxamic acid chelate ion exchange resin can be formed from Ambertite (a weakly acidic cation exchanger containing 4 percent cross-linkage made from methacrylic acid and divinyl benzene) by a process disclosed by Renfrow, Journal of American Chemistry Society Volume 59, pages 2308 (1937); however, all reactions are conducted in organic solvent solution and no polymerizable monomers are disclosed, much less polymers.
*Trade-mark - , a , _.. "
, ,~ ~ an ns DESCRIPTION OF THE INVENTION INCLUDING PREFERRED EMBODIMENTS
The present invention relates to a process which comprises esterifying a water-soluble polymer of a (meth)acrylic acid or salt thereof having a molecular weight of over one million in aqueous solution to provide a (meth)acrylic acid alkyl (meth)acrylate polymer. In a second phase of the process, the resultant esterified polymer is hydroxamated.
The instant invention also relates to water-soluble polymers of (meth) acrylic acid and a (meth) acrylic acid ester, the polymers having a weight average molecular weight of over 10,000,000. Preferably, the polymers are comprised of (meth) acrylic acid and alkyl (meth) acrylate units represented by the formula (I):
R
CH-C CH2 ~ Z
2 ~ x I Y ~ ~z C= O C= O
OH O-R' wherein each R is, individually, hydrogen or methyl R' is a C,-C4 alkyl group, Z is the polymerization residue of a monoethylenically unsaturated monomer copolymerizable with (meth) acrylic acid, x ranges from 5 to 95, preferably 10 to 90, y ranges from 5 to 50, preferably 10 to 40, and z ranges from 0 to 90, preferably 0 to 80.
This invention also relates to hydroxamated polymers of those polymers of formula I wherein from 5% to 100% of the ester groups thereof are hydroxamated to R
-~ C H2 ~ ~ groups =O
~HOX
wherein X is hydrogen or a cation.

AMENDED SME~T

Also falling within the scope of the present invention is the use of the above-described hydroxamated polymers in the removal of suspended solids from the Bayer alumina process wherein a Bayer Process stream is contacted with the hydroxamated, water-soluble polymer of (meth) acrylic ,acid and (meth) acrylic acid ester having a weight average molecular weight of at least (preferably over) 10,000,000 in an amount effective to flocculate the suspended solids therein and the flocculated solids are removed.
The polymers are added to the Bayer Process streams in the form of dilute aqueous solutions in an amount at least sufficient to flocculate the suspended solids therein.
Generally, satisfactory results are achieved when from 0.1 mg of the polymer per liter of the process stream are employed, preferably from 1.0 mg of polymer per liter of process stream.
Amounts of added polymer may deviate from the above-disclosed amounts and still fall within the scope of the present invention as Long as the desired flocculation is achieved.
The esterification is carried out by' reacting the acrylic acid polymer in aqueous solution with an alkylating agent to convert at least a portion of the acrylic acid groups to the corresponding esters. Basically, any water-soluble polymer containing carboxylic acid groups or their salts can be used in the present process, however, acrylic acid and methacrylic acid polymers are preferred. The (meth) acrylic acid polymer should contain at least about ~ 0 percent, by weight, of the (meth) acrylic acid, the remainder being any monomer copolymerizable therewith which will result in a water-soluble polymer.
Preferably, the polymer should have at least 25 weight percent of (meth) acrylic acid recurring units in its structure, and most preferably the polymer is homopolymer of (meth) acrylic acid or salt thereof.
The charge polymers of (meth) acrylic acid should have a molecular inreight of at least 1 million, preferably at least 5 million arid most preferably, at least 10 million.
The esterification reaction may be conducted on the polymer of (meth) acrylic acid in aqueous solution. By the term "aqueous solution", as used herein, is meant, solutions , of the polymer in water, dispersions of the polymer in water, or water-in-oil emulsions as described in U.S. Patent Nos. 3,284,393; 5,354,801, in macro or micro sized micelles of the aqueous polymer solution. Esterification (and subsequent hydroxamation) of the polymer in aqueous solution as a water-in-oil emulsion is preferred.

, , , ."
. ,,, ~ , - . , n w w ' , , w a a w a s Any known alkylating agent may be used to esterify the (meth) acrylic acid polymer with dialkyl sulfates such as dimethyl sulfate, diethyl sulfate being preferred. Other useful alkylating agents include the alkyl halides such as methyl chloride, ethyl chloride, allyl chloride, methyl bromide, methyl iodide; the halohydrins such as epichlorohydrin; the alkylene oxides such as ethylene oxide, propylene oxide; 1,2-epoxybutane and the like.
When the alkyl halides are used in esterifying the (meth) acrylic acid polymer, catalysts such as potassium iodide may be used so as to accelerate and improve the reaction efficiency. Additionally, those alkylating agents which are gases under the conditions of the esterification reaction should be used under pressure.
The esterification reaction is conducted at a temperature ranging from 0° to 80°C, preferably from 10° to 70°C such as to provide at least 5 percent ester groups in the resultant polymer, the only criteria being that the resultant esterified polymer must be either soluble in the water of the reaction media or reactively dispersed therein.
Preferably, conversion of the available carboxyl groups of the polymer to ester groups should result ii-~
from 5-50 percent, most preferably 10-40 percent, of the ester groups in the resultant polymer.
The novel process comprising the hydroxamation of the esterified polymer discussed above is carried out under at least slightly basic conditions, i.e., at a pH
of at least over 7.0 so as to neutralize the hydroxylamine salt with which the esterified polymer is reacted. The slightly basic conditions can be effected by addition of caustic, e.g. NaOH as is known in the art, or by the use of a carbonate such as, for example, sodium carbonate.
Temperatures ranging from 10°C to 80°C may be employed and from at least about 5 percent, by weight, of the available ester groups of the esterified (meth) acrylic acid polymer are hydroxamated, preferably at least 10 percent, by weight. Most preferably, all the ester groups are hydroxamated. The hydroxamation procedure disclosed in the above-referenced U.S. Patent 4,902,751 to Lewellyn et al may be followed for the hydroxamation step of the instant process.
Exemplary hydroxylamine salts include the phosphates, perchlorates, sulfates, sulfites, hydrochlorides, acetates, propionates and the like with the sulfates being preferred.
Hydroxylamine to ester group mole ratios should range from 0.1 to 2.0, preferably 0.5 to 1.5.
Examples of monomer which may be copolymerized with the (meth) acrylic acid monomer to form the polymers which are esterified hereunder and which are represented AMENDED SHE~fT

by recurring unit Z, above, include malefic anhydride, vinyl acetate, vinyl pyrrolidone, styrene, acrylamide, methacrylamide, 2-acrylamida-2-methylpropane sulfonic acid, acrylonitrile and the like.
The following examples are set forth for purposes of illustration only and are not to be construed as limitations on the present invention except as set forth in the appended claims. All parts and percentages are by weight unless otherwise specified.
Exams la a 1 Esterification of a Sodium Polyrjacryrlate) Emulsion with Dimethyl Sulfate To 300 parts of homopolymeric sodium poiyacrylate oil-continuous emulsion (21.7%
polymer solids; weight average M.W. range 10 to 20 million) are added 34.2 parts of dimethyl sulfate (DMS). The reactants are mixed vigorously for 2.5 hours, after which Carbon 13 NMR indicates 30% conversion of the carboxylic acid groups to the methyl ester in the final emulsion copolymer, representing an essentially quantitative yield. The weight average molecular weight remains over 10 million.
Exam lep s 2-8 Using the general procedure described in Example 1, a range of esterified poly(acrylate) emulsions are prepared, as shown in Table I, below, with equivalent results.
Table I
Addition Level,% Acid Converted Example Alkylating AgentMole % to Ester, NMR

y 8 (comp.) DMS 60 emulsion gelled (comp.) = comparative As can be seen, gellation occurs when the ester level gets too high and the polymer becomes insoluble in the aqueous phase of the emulsion.
Example 9 Esterification of an Ammonium Pc~l ,r(acrylate~ Emulsion with Dimeth~rl Sulfate To 300 parts of homopolymeric ammonium poly(acrylate) oil-continuous emulsion {30% polymer solids; M.W. range 10-20 million) are added 48.3 parts of dimethyl sulfate.
The mixture is stirred vigorously for 2 hours. Carbon 13 NMR indicates 27%
methyl ester in the final copolymer of over 10 million weight average molecular weight.
Examples 10-15 Using the general procedure of Example 9, a range of esterified poly(acrylate) polymers are prepared using dimethyl sulfate (DMS). The results are shown in Table II, below, to be substantially equivalent.
Table II
Addition Level,% Acid Example Alkylating AgentMole % Converted to 15 (comp.) DMS 100 product precipitated (comp.) = comparative Again, precipitation {gellation) occurs when the ester polymer becomes insoluble in water.

Exam Ip a 16 Esterification of a Sodium Poly(ac .ryrlate~Emulsion with Meth~rl Chloride To 300 parts of homopoiymeric sodium poly(acrylate) oil-continuous emulsion (21.4% polymer solids; M.W. range 10 to 20 million) in a high-pressure autoclave are added 70.7 parts of methyl chloride. The reaction is heated to 80°C for 2 hours with vigorous stirring. Carbon 13 NMR indicates 15% methyl ester in the final copolymer of over 10 million weight average molecular weight.
Examples 17-23 Using the procedure in Example 16, a range of esterified poly(acryiate) emulsions are prepared using various alkylating agents. The results are set forth in Table III, below.
Again, they are substantially equivalent.
Table III
After Alkylation Reaction 3 Example AIlcylating Level, Temperature Hours-Agent C Acid Mole Converted 17 Methyl bromide 20 80 100 18 Methyl bromide 20 80 15 19 Epichlorohydrin20 60 30 20 Propylene Oxide20 90 4 (gel) 21 1,2 Epoxy butane20 100 2 (gel) 22 Allyl Chloride 50 80 7 23 Allyl Chloride 50 100 16 (gel) Example 24 Esterification of a Sodium Poly~acryrlate) Emulsion with Ethyl Chloride To 300 parts of homopolymeric sodium poly(acrylate) oil-continuous emulsion (21.4% polymer solids; M.W. range 10 to 20 million) in a high-pressure autoclave are added 84 parts of ethyl chloride and 14.9 parts of 10% KI solution. The reaction is heated to 100°C for 3 hours with vigorous stirring after which infrared analysis indicates 16%
esterification resulting in a copolymer of weight average molecular weight over 10 million.
Exam Ip a 25 Esterification of a Sodium Poly(acrylate) Emulsion with Allyl Chloride To 300 parts of homopolymeric sodium poly(acrylate) oil-continuous emulsion {21.4% polymer solids; M.W. range 10 to 20 million) in a high-pressure autoclave are added 31.8 parts of ally) chloride and 13 parts of 10% KI solution. The reaction is heated to 80°C
for 2.5 hours with vigorous stirring, after which carbon 13 analysis indicates 7%
esterification. The weight average molecular weight of the copolymer produced remains about the same as the charge polymer.
Example 26 Esterification of a Sodium Poly(acr~ fi ate) Emulsion with Epichloroh~rdrin To 300 parts of homopolymeric sodium poly{acrylate) oil-continuous emulsion (21.4% polymer solids; M.W. over 10 million) are added 16.5 parts of epichlorohydrin. After stirring vigorously for 0.25 hour, the reaction is heated to 60°C
without stirring for 8 hours.
Carbon 13 NMR indicates 30% ester in the final copolymer of about the same weight average molecular weight as the charge polymer.
Examlhe 2727 Esterification of a Copolymer Emulsion with Dimethyl Sulfate To 300 parts of a 50:50 sodium acrylate/acrylamide copolymer oil-continuous emulsion (24.7% polymer solids; M.W. about 15 million) are added 26 parts of dimethyl sulfate {DMS). The mixture is mixed vigorously for 2.5 hours. Carbon 13 NMR
indicates 17% conversion of the carboxylic acid groups to methyl ester in the final terpolymer, representing an 85% yield based on DMS. The weight average molecular weight of the terpolymer is also about 15 million.
Examples 28-32 The procedure of Example 27 is used to esterify acrylic acid copolymers of varying compositions. The results are set forth in Table IV, below.

Table IV
DMS Addition Example Copolymer Additional Level,% Acid Converted AA/AMD* Mole to Ester %

29 10:90 10 10 30 30:70 30 30 (IR) 31 50:50 50 50 (IR) 32 90:10 20 15 (NMR) 33 90:10 30 32 (NMR) *AA= acrylic acid AMD = acrylamide Example 33 Esterification of a Copolymer Emulsion with Methyl Chloride To 300 parts of a sodium acrylatelacrylamide 50150 copolymer are continuous emulsion (24.7% polymer solids; M.W. 15 million) in a high-pressure autoclave added 39.6 parts of methyl chloride and 17.3 parts of 10% KI solution. The reaction is heated to 80°C
for 3 hours with vigorous stirring. Carbon 13 NMR indicates 14% methyl ester in the final terpolymer whose weight average molecular weight is over 15 million.
Example 34 To 300 parts of the emulsion copolymer (30% ester) of Example 1 are added an aqueous solution containing 63.3 parts of 30% hydroxylamine sulfate, 83 parts of 50%
sodium hydroxide (100 mole% excess based on total monomer) and 12 parts of sodium thiosulfate as a stabilizer. The mixture is mixed vigorously for 1 hour. The resulting terpolymer contains 12% hydroxamate according to carbon 13 NMR analysis, 18%
methyl acrylate and 70% acrylic acid recurring units. The weight average molecular weight is virtually unchanged.

,.
~~,., - ", ~ ~ . r, o o~ ~ oo e~
Examples 35-47 The procedure described in Example 34 is again used to hydroxamate the acrylic acid/methyl acrylate copolymer of Example 1 under a variety of reaction stoichiometries.
The results are set forth in the table immediately below.
Moles of Example Excess HXamine Ester CarboxylateHydroxamat Caustic*to -% Ester Group a 35C 0 1.00 30 70 0 36 10 1.00 21 71 8 37 20 1.00 20 72 8 38 25 1.00 12 84 4 39 30 1.00 10 86 4 40 35 1.00 3 89 8 41 40 1.00 0 92 8 42 50 1.00 0 88 12 43 100 0.20 0 96 4 44 100 0.35 0 95 5 45 100 0.50 0 93 7 46 100 1.00 0 88 12 47 100 2.50 0 88 12 *Based on total monomer ,,.
HX = hydroxyl Exam I
A 90:10 ammonium acrylate/acrylamide copolymer emulsion product (25.4% polymer solids - weight average M.W. = 11 million) is esterified to the extent of 30%
using dimethyl sulfate, in accordance with Example 1. To 300 parts of the ester terpolymer are added an aqueous reagent solution containing 95.6 parts of 30% hydroxylamine sulfate, 114 parts of 50% sodium hydroxide (100 mole % excess based on total monomer) and 23 parts of sodium thiosulfate as a stabilizer. The reaction mixture is agitated vigorously for 1 hour.
The resulting product contains 9% hydroxamate, 10% amide and 81 % carboxyl groups AMENDED SHEET

according to carbon 13 NMR analysis and has a weight average molecular weight of about 11 million.
Examples 49-56 The esterified polymers of Examples 17-23, inclusive, are hydroxamated in accordance with the procedure of Example 34. in each instance, similar results are achieved.
Examples 57-66 The hydroxamated polymer of Example 45 is compared with a conventional commercial polyacrylate red mud flocculant and two commercially available hydroxamated polymers derived by hydroxamation of amide polymers. Evaluations are carried out by first digesting at elevated temperature and pressure a difficult-to- flocculate Jamaican bauxite in alumina plant spent liquor to obtain a slurry containing approximately 100 g/L of mud solids, and then diluting said slurry with additional spent liquor to provide a slurry with 40 g/L of mud solids. Portions of the hot slurry are placed in one liter graduated cylinders and flocculated by adding thereto varying amounts of the flocculants to be tested as dilute aqueous solutions, mixing the added flacculant with the slurry by means of a perforated plunger. The settling rate of the mud interface and the clarity of the supernatant liquor after mud settling are then measured.

Dosage Settling Clarity, Example Fiocculant Level, Rate, m/hr.Mg/L
g/T

57C Polyacrylate 234 0.2 >540 58C Commercial Hydroxamate184 20 38 Polymer A

59C Commercial Hydroxamate138 18 45 Polymer A

60C Commercial Hydroxamate92 7 144 Polymer A

61 C Commercial Hydroxamate172 12 6 Polymer B

62C Commercial Hydroxamate128 11 72 Polymer B

63C Commercial Hydroxamate86 5 48 Polymer B

64 Polymer of Example 164 33 14 65 Polymer of Example 123 14 6 66 Polymer of Example 82 9 22 C = comparative Polymer A = 9% hydroxamation - wt. ave. m.w. 20 million Polymer B = 18% hydroxamation - wt. ave. m.w. 20 million Examples 67-80 Hydroxamated polymers of the instant invention are evaluated in the laboratory using a red mud slurry from an operating Bayer alumina plant. The laboratory settling tests are carried out similarly to those described for Examples 57-66, except that the hot slurry is taken from the plant instead of being prepared in a laboratory digestion.

Dosage Settling Clarity, Example Flocculant Level, Rate, m/hr.Mg/L
g/T

67 Polymer of Example 64 9 124 68 Polymer of Example 85 15 100 69 Polymer of Example 108 39 112 70 Polymer of Example 64 10 121 71 Polymer of Example 85 31 137 72 Polymer of Example 108 47 121 73 Polymer of Example 64 11 154 74 Polymer of Example 85 14 161 75C Commercial Hydroxamate72 11 126 Polymer A

76C Commercial Hydroxamate97 34 125 Polymer A

77C Commercial Hydroxamate121 77 125 Polymer A

78C Commercial Hydroxamate74 8 71 Polymer C

79C Commercial Hydroxamate92 15 62 Polymer C

80C Commercial Hydroxamate99 28 73 Polymer C

81 C Commercial Hydroxamate124 ~. 45 61 Polymer C

C=comparative Polymer A = 9% hydroxamation - wt. ave. m.w. 20 million Polymer C = 14% hydroxamation - wt. ave. m.w. 20 million

Claims (23)

CLAIMS:

1. A method which comprises esterifying a water-soluble polymer of an acrylic acid or salt thereof having a weight average molecular weight of over 1 million in aqueous solution and hydroxamating the resultant esterified polymer, wherein the water-soluble polymer is in the dispersed phase of a water-in-oil emulsion.

2. The method of claim 1, wherein the polymer to be esterified contains from 5% to 95%, by mole, of the acrylic acid.

3. The method of claim 1 or 2, wherein the polymer to be esterified has a weight average molecular weight of at least 5 million.

4. The method of claim 1 or 2, wherein the polymer to be esterified has a weight average molecular weight of at least 10 million.

5. The method of claim 1, 2 or 3, wherein the esterified polymer is at least 5% esterified.

6. The method of claim 1, 2 or 3, wherein the esterified polymer is from 5% to 50% esterified.

7. The method of claim 1, 2 or 3, wherein the esterified polymer is from 10% to 40% esterified.

8. The method of claim 1, 2, 3, 4, 5, 6 or 7, wherein the hydroxamated polymer is at least 5% hydroxamated.

9. The method of claim 1, 2, 3, 4, 5, 6 or 7, wherein the hydroxamated polymer is at least 10% hydroxamated.

10. The method of claim 1, 2, 3, 4, 5, 6, 7, 8 or 9, wherein the acrylic acid is a (meth) acrylic acid.

11. The method of claim 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, wherein a molar ratio of hydroxylamine to ester groups is 0.1 to 2Ø

12. The method of claim 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, wherein a molar ratio of hydroxylamine to ester groups is 0.5 to 1.5.

13. The method of claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, wherein the esterification is achieved by contacting the water-soluble polymer with an alkylating agent at a temperature of from 0°C to 80°C.

14. The method of claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 or 13, wherein the hydroxamation is achieved by contacting the esterified polymer with an hydroxylamine salt at a pH of at least over 7.0 at a temperature of from 10°C
to 80°C.

15. The method of claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13 or 14, wherein the acrylic acid salt is an ammonium or sodium salt.

16. A water-soluble polymer of a (meth) acrylic acid and a (meth) acrylic acid ester having a weight average molecular weight of over 10 million.

17. The polymer according to claim 16, wherein the (meth) acrylic acid is acrylic acid and the (meth) acrylic acid ester is methyl acrylate.

18. A hydroxamated, water-soluble polymer of a (meth) acrylic acid and (meth) acrylic acid ester having a weight average molecular weight of over 10 million.

19. The hydroxamated, water-soluble polymer according to claim 18 having a molar ratio of hydroxylamine to ester groups of 0.1 to 2Ø

20. The hydroxamated, water-soluble polymer according to claim 18 having a molar ratio of hydroxylamine to ester groups of 0.5 to 1.5.

21. A process for removing suspended solids from a Bayer alumina process, the improvement comprising contacting a Bayer Process stream with a hydroxamated, water-soluble polymer of a (meth) acrylic acid and a (meth) acrylic acid ester having a weight average molecular weight of at least 10 million in an amount effective to flocculate the suspended solids therein and removing the flocculated solids from the process stream.

22. The process of claim 21, wherein the hydroxamated, water-soluble polymer has a molar ratio of hydroxylamine to ester groups of 0.1 to 2Ø

23. The process of claim 21, wherein the hydroxamated, water-soluble polymer has a molar ratio of hydroxylamine to ester groups of 0.5 to 1.5.