CA2249286A1 - High strength spunbond fabric from high melt flow rate polymers - Google Patents

Abstract

A spunbond nonwoven fabric is provided which has superior strength characteristics to conventional fabrics yet is comparably soft. The fabric is a laminate having a web made from a high melt flow rate polyolefin polymer and a low melt flow rate polymer. The spunbond laminate fabric of this invention may have therebetween a layer of meltblown nonwoven fabric or film. The laminate produced according to this invention has a strength which is at least 10 % greater than a comparable fabric made without the high melt flow rate polymer web. The nonwoven fabric of this invention may be used in products such as, for example, garments, personal care products, medical products, protective covers and outdoor fabrics.

Description

W O 97/40225 PCT~US97106027 HIGH STRENGTH SPUNBOND FABRIC
FROM HIGH MELT FLOW RATE POLYMERS

BACKGROUND OF THE INVENTION

This invention relates generally to a nonwoven fabric or web which is formed from spunbond fibers of a the" llopl~tic resin and laminates using such a web as a component.
Thel ",oplaslic resins have been extruded to form fibers, fabrics and webs for a number of years. The most common thermoplastics for this application are polyolefins, particularly polypropylene. Other ~ rials such as polyesters, polyetheresters, polyamides andpolyurethanes are also used to form spunbond fabrics.
Nonwoven fabrics or webs are useful for a wide variety of applications such as diapers, feminine hygiene products, towels, and recreational or protective fabrics. The nonwoven fabrics used in these applications are often in the form of laminates like spunbond/spunbond (SS) laminates or spunbond/meltblown/spunbond (SMS) laminates.
One of the desired characteristics of nonwoven fabrics is that they be as soft as possible. Previously, improving softness has generally involved a trade-off with other desi, ''e properties of the web such as tensile strength. For example, polyethylene webs are very soft but also quite weak.
It is an object of this invention to provide a spunbond polyolefin nonwoven fabric or web which is softer than those conventionally produced but which has comparable strength characteristics .
SUMMARY OF THE INVENTION

A soft and strong nonwoven spunbond polyolefin fabric is provided which is a multilayer laminate of a first web of high melt flow polymer fibers and a second web of low melt flow polymer fibers. The web of low melt flow polymer fibers is produced from polyolefin polymer ~ having a melt flow rate of below 50 grams /10 minutes according to ASTM D-1238-9Ob condition L. The web of high melt flow polymer fibers is produced from polyolefin polymer having a melt flow rate of at least 50 grams /10 minutes according to ASTM D-1238-9Ob condition L wherein the polyolefin polymer is initially produced as a reactor granule through the use of a Ziegler-Natta catalyst with a melt flow rate below 50 grams/10 minutes at 230~C
and subsequently modified by a method such as the addition of up to 1000 ppm of peroxide, WO 97/40225 PCT~US97/06027 the addition of up to 5 weight percent of an organo-metallic compound and the addition of up to 5 weight percent of a transition metal oxide. This treatment increases the meit flow rate of the polymer by a factor of at least two. Such a laminate has a tensile strength of at least 10% greater than a similar laminate made without a high melt flow rate web but instead with 5 a web of the same type as the second web. The fabric of this invention may also have various layers disposed between the first and second webs.
The nonwoven fabric of this invention may be used in products such as, for example, gar,l,ents, personal care products, medical products, protective covers and outdoor fabrics.

As used herein the term "nonwoven fabric or web" means a web having a structure of individual fibers or threads which are interlaid, but not in an identifiable manner as in a knitted fabric. Nonwoven fabrics or webs have been formed from many processes such as 15 for example, meltblowing processes, spunbonding processes, and bonded carded web processes. The basis weight of nonwoven fabrics is usually expressed in ounces of material per square yard (osy) or grams per square meter (gsm) and the fiber diameters useful are usually expressed in "~i~;,ons. (Note that to convert from osy to gsm, multiply osy by 33.91).

As used herein the term "microfibers" means small diameter fibers having an average dian ,eter not greater than about 75 microns, for example, having an average diameter of from about 0.5 microns to about 50 microns, or more particularly, microfibers may have an average diameter of from about 2 microns to about 40 microns. The diameter of, for example, a polypropylene fiber given in microns, may be converted to denier by squaring, and multiplying the result by 0.00629, thus, a 15 micron polypropylene fiber has a denier of about 1.42 (152 x 0.00629 = 1.415).
As used herein the term "spunbonded fibers" refers to small diameter fibers which are formed by extruding molten thermoplastic material as filan~ents from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Patent no. 4,340,563 to Appel et al., and U.S. Patent no. 3,692,618 to Dorschner et al., U.S. Patent no. 3,802,817 to Matsuki et al., U.S. Patent nos. 3,338,992 and 3,341,394 to Kinney, U.S. Patent nos. 3,502,763, and U.S.
Patent no. 3,542,615 to Dobo et al. Spunbond fibers are generally continuous and larger than 7 microns, more particularly, they are usually between about 15 and 50 microns.
As used herein the term "meltblown fibers" means fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as W O 97/40225 PCTrUS97/06027 molten threads or rilc""enls into a high velocity gas (e.g. air) stream which attenuates the rilarnenl~ of molten thermopl-~tic "~aterial to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown fibers. Such a process is disclosed, for example, in U.S. Patent no. 3,849,241 to - Butin. Meltblown fibers are microfibers which are generally smaller than 10 microns in dian~et~r. The term meltblowing used herein is meant to enco" ,pass the meltspray process.
As used herein the term "polymer" generally includes but is not limited to, ho",opolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, etc. and blends and modifications thereof. Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible geometrical configuration of the material. These configurations include, but are not limited to isotactic, syndiotactic and random s~" "r"el, ies.
As used herein the term "bicol"ponent fibers" refers to fibers which have been formed from at least two polymers extruded from separate extruders but spun together to form one fiber. The polymers are arranged in sul)~tanlially conslanlly positioned distinct zones across the cross-section of the bico" ,ponent fibers and extend continuously along the length of the bicol"~onent fibers. The configuration of such a bicomponent fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another or may be a side by side arrangement or an "islands-in-the-sea" arrangement. Bicomponent fibers are taught in U.S. Patent 5,108,820 to Kaneko et al., U.S. Patent 5,336,552 to Strack et al., and European Patent 0586924. The polymers may be present in ratios of 75/25, 50/50, 25/75 or any other desired ratios.
As used herein the term "b ~nsLiluent fibers" refers to fibers which have been formed from at least two polymers extruded from the same extruder as a blend. The term "blend" is defined below. Biconstituent fibers do not have the various polymer components arranged in relatively constantly positioned distinct zones across the cross-sectional area of the fiber and the various polymers are usually not continuous along the entire length of the fiber, instead usually forming fibrils which start and end at random. Biconstituent fibers are sometimes also referred to as multiconstituent fibers. Fibers of this general type are discussed in, for example, U.S. Patent 5,108,827 to Gessner. Bicomponent and biconstituent fibers are also discussed in the textbook Polvmer Blends and ComDosites by ~ John A. Manson and Leslie H. Sperling, copyright 1976 by Plenum Press, a division of Plenum Publishing Corporation of New York, IBSN 0-306-30831-2, at pages 273 through 277.

W O 97/40225 PCT~US97/06027 As used herein the term "blend" means a mixture of two or more polymers while the term "alloy" means a sub-class of blends wherein the components are immiscible but have been compatibilized. "Miscibility" and "immiscibility" are defined as blends having negative and positive values, respectively, for the free energy of mixing. Further, "compatibili~ation"
5 is defined as the process of modifying the interfacial properties of an immiscible polymer blend in order to make an alloy.
As used herein the term "prodey~adanr refers to materials which promote the degradation of the melt flow of a polymer from low melt flow rate to high melt flow rate.
As used herein, the term "garment" means any type of apparel which may be worn.
10 This includes industrial work wear and coveralls, undergarments, pants, shirts, jackets, gloves, socks, and the like.
As used herein, the term "medical product" means surgical gowns and drapes, facemasks, head coverings, shoe coverings wound dressings, bandages, sterilization wraps, wipers and the like.
As used herein, the term "personal care product" means diapers, training pants, absorbent underpants, adult incontinence products, and feminine hygiene products.
As used herein, the term "protective cover" means a cover for vehicles such as cars, trucks, boats, airplanes, motorcycles, bicycles, golf carts, etc., covers for equipment often left outdoors like grills, yard and garden equipment 20 (mowers, roto-tillers, etc.) and lawn furniture, as well as floor coverings, table cloths and picnic area covers.
As used herein, the term "outdoor fabric" means a fabric which is primarily, though not exclusively, used outdoors. Outdoor fabric includes fabric used in protective covers, camper/trailer fabric, tarpaulins, awnings, canopies, tents, agricultural fabrics and outdoor 25 apparel such as head coverings, industrial work wear and coveralls, pants, shirts, jackets, gloves, socks, shoe coverings, and the like.

TEST METHODS

Handle-O-Meter: The softness of a nonwoven fabric may be measured according to the "Handle-O-Meter" test. The test used herein is the INDA standard test 1st 90.0-75 (R
82) with two modifications: 1. the specimen size was 4 inches by 4 inches and 2. five specimens were tested rather than two. The test was carried out on Handle-O-Meter model number 211-5 from the Thwing-Albert Instrument Co., 10960 Dutton Road, Phila. PA 19154.
The Handle-O-Meter reading is in units of grams.

W 097/40225 PCT~US97/06027 Tensile: The tensile strength of a fabric may be measured according to the ASTM
test D-1682-64. This test measures the strength in pounds and elongation in percent of a fabric.
Melt Flow Rate: The melt flow rate (MFR) is a measure of the viscosity of a 5 polymers. The MFR is expressed as the weight of "laterial which flows from a capillary of known dil "ensions under a specified load or shear rate for a measured period of time and is measured in grams/10 minutes at 230~C accordi, lg to, for example, ASTM test D-1238-9Ob, condilion L.

DETAILED DESCRIPTION

The il"poilanl properties of polyolefins used in the spunbonding process are known to those skilled in the art. The melt flow rate and the viscosity are interrelated and are quite important in characterizing a polymer. The melt flow rate is related to the viscosity of the polymer with a higher number indicating a lower viscosity. The test for the melt flow rate is defined above.
The spunbond process generally uses a hopper which supplies polymer to a heated extruder. The extruder supplies melted poiymer to a spinneret where the polymer is fiberized as it passes through fine openings arranged in one or more rows in the spinneret, forming a curtain of rllanlenls. The rllal"e"ls are usually quenched with air at a low pressure, drawn, usually pneumalically and deposited on a moving foraminous mat, belt or "forming wire" to form the nonwoven fabric. Polymers useful in the spunbond process generally have a process melt temperature of between about 400~F to about 610~F (200~C
to 320~C).
The fibers produced in the spunbond process are usually in the range of from about 15 to about 50 microns in diameter, depending on process conditions and the desired end use for the fabrics to be produced from such fibers. For example, increasing the polymer molecular weight or decreasing the processing temperature results in larger diameter fibers.
Changes in the quench fluid temperature and pneumatic draw pressure can also affect fiber diameter. In this invention, the particular polymer used allows the fibers to be produced at a smaller diameter than usual for spunbonding.
The fabric of this invention is a multilayer lan ,;"al~ incorporating the high melt flow polymer fiber web and may be formed by a number of different techniques including but not limited to using adhesive, needle punching, ultrasonic bonding, thermal calendering and any other method known in the art. Such a multilayer laminate may be an embodiment wherein some of the layers are spunbond and some meltblown such as a W O 97/40225 PCTrUS97/06027 spunbond/meltblown/spunbond (SMS) laminate as disclosed in U.S. Patent no. 4,041,203 to Brock et al. and U.S. Patent no. 5,169,706 to Collier, et al. or as a spunbond/spunbond laminate. An SMS laminate may be made by sequentially depositing onto a moving conveyor belt or forming wire first a spunbond fabric layer, then a meltblown fabric layer and 5 last another spunbond layer and then bonding the laminate in a manner described above.
Alternatively, the three fabric layers may be made individually, collected in rolls, and combined in a separate bonding step.
Various pattems for calender rolls have been developed. One example is the expanded Hansen Pennings pattern with about a 15% bond area with about 100 bonds/square inch as taught in U.S. Patent 3,855,046 to Hansen and Pennings. Another common pattern is a diamond pattern with repeating and slightly offset diamonds.The fabric of this invention may also be laminated with films, glass fibers, staple fibers, paper, and other commonly used materials known to those skilled in the art.
Areas in which the fabric of this invention may find utility are garments, medical products, personal care products, and outdoor fabrics. More particularly, fabrics produced according to this invention are useful in heavier basis weight applications such as protective covers. Protective covers usually have basis weights ranging from about 2 osy (68 gsm) to about 8 osy (271 gsm), according, a fabric produced according to this invention will prefer~bly have basis weights ranging from about 0.2 osy (7 gsm) to about 3 osy (102 gsm).
A polyolefin polymer useful in this invention must have a high melt flow rate and low viscosity. The melt flow rate desired for the polyolefin to be used in this invention is at least 50 gms/10 min according to ASTM D-1238-9Ob condition L, and preferably in the range from about 50 gms/10 min to about 150 gms/10 min according to ASTM D-1238-9Ob condition L.
The viscosity of the polymer is measured at 180~C and must be at least 2.5 x 103dynes.sec/cm2 and preferably in the range of about 2.5 x 103 dynes.sec/cm2 to about 6.5 x 103 dynes.sec/cm2. The high melt flow rate and low viscosity allows the fibers to be drawn more highly than otherwise, producing very fine spunbond fibers. Fibers produced with the high melt flow polyolefin employed herein are in the range of about 11 to about 20 microns in diar"eter.
One advantage of fine spunbond fibers may be seen in non-adhesive where energy is applied to the web through various means to induce the fibers to melt together slightly. It is believed by the inventors that smaller fibers made from lower viscosity polymers enable more polymer to flow at the bond points during bonding, thus ensuring a strong bond, yet the web retains the advantage of softness which smaller fibers also give.
The production of a high melt flow rate polyolefin may be achieved when starting with a conventional low melt flow polyolefin through the action of free radicals which degrade the polymer from low to high melt flow. Such free radicals can be created and/or rendered more stable through the use of a prudeg,adant such as a peroxide, an organo-metallic compound or a transition metal oxide. Depending on the prodegradant chosen, stabilizers may be useful.
One example of a way to make a high melt flow polyolefin from a conventional low melt flow polyolefin is to incorporate a peroxide into the polymer.
Peroxide additiot1 to a polymer for meltblowing appl..,2t cns is taught in U.S. Patent 5,213,881 to Timmons et al. In Timmons, up to about 3000 ppm of peroxide is added to a polymer which has been polymerized with a Ziegler-Natta catalyst. The polymer is in the 10 form of reactor granules and has a molecular weight distribution of 4.0 to 4.5 Mw/Mn and a melt flow rate of about 400 gms/10 min according to ASTM D-1238-9Ob condition L prior to modification. Such a polymer is modified by the peroxide to have a molecular weight distribution in the range of about 2.2 to 3.5 Mw/Mn and a melt flow rate of about 800 to 5000 gms/10 min according to ASTM D-1238-9Ob condition L. Peroxide addition to polymer pellets is also addressed in U.S. Patent 4,451,589 to Morman et al.
Peroxide addition to a polymer for spunbonding applications is done by adding up to 1000 ppm of peroxide to cor"lnercially available low melt flow rate polyolefin polymer and mixing thoroughly. The resulting modified polymer will have a melt flow rate of app,uki,,,ately two to three times that of the starting polymer, depending upon the rate of 20 peroxide addition and mixing time.
Another way to make a high melt flow pûlyolefin from a conventional low melt flow polyolefin is to add an organo-metallic compound to the polyolefin. The organo-metallic compound has the effect of increasing the stability of free radicals within the polymer which allows them to remain active for a longer period of time, and thus to degrade the polymer 25 from low to high melt flow. Typically, the melt flow may be changed from about 35 to the range of about 70 to 85 using this method.
The suitable organo-metallic compound is sodium bis(para-t-butylphenyl) phosphate.
An example of a suitable commercially available organo-metallic compound is that sold by Witco Chemical Company of New Jersey under the trade name Mark 2180. When an 30 organo-metallic compound is used it may be used in an amount of from about 0.1 weight percent to about 5 weight percent. Organo-metallic compounds have the added benefit of giving the fabric enhanced ultraviolet light resistance, important in outdoor applications, as well as giving color to the fabric, as most organo-metallic compounds are also pigments.
The organo-metallic compound may be added to the polyolefin to be spun prior to 35 entering the extruder. It is important that the organo-metallic compound and the polyolefin be mixed as thoroughly as possible in order to provide as uniform a mixture as possible to W O 97/40225 PCTrUS97/06027 the spinneret. Ullirul~lliLy in the co",posi~ion fed to the spinneret helps to ensure uniform fiber production and to reduce broken fibers and shot. One suit~hle method of mixing the polyolefin and organo-metallic compound is to add the organo-metallic compound, generally a powder, to the polyolefin, generally in pellet form, in a large mixing vessel prior to addition to the hopper as described previously. Alternatively, the organo-metallic compound may be added to the polyolefin in the hopper.
Still another method is to add the organo-metallic compound in a controlled manner at a number of points along the length of the extruder as the polyolefin is melted and moved forward toward the spinneret. This method would allow the greatest conL~ ty of the process yet also provides the least margin for error in the addition rate, as changes in the addition rate would most immediately affect the unif~ r",iLy of the fibers produced.
Yet another way to make a high melt flow polyolefin from a conventional low melt flow polyolefin is to add a llansition metal oxide to the polymer during processing. Suitable l,~nsilion metal oxides are, for example, ferric oxides. An example of a suitable commercially available transition metal oxide is that sold by Engelhard Corporation under the trade name Fe-0301-P. When a l,~nsition metal oxide is used it may be used in an amount of from about 0.1 weight percent to about 5 weight percent. Transition metal oxides may be added to the polyolefin in the manner described above. Transition metal oxides have the added benefit of giving the fabric enhanced ultraviolet light resistance, important in outdoor applic~tions, as well as giving color to the fabric, as most transition metal oxides are also pigments.
It is also believed that a combination of a number of the above techniques will also be successful in producing polyolefin of the desired melt flow rate.
The polyolefin useful in this invention may be polyethylene, polypropylene, polybutylene or copolymer and mixtures thereof. Polypropylene is preferred.
In addition to the above methods, high melt flow polypropylenes are commerciallyavailable from Shell Chemical Co., Houston, Texas as WRD5-1131, WRD5-1155 through 1157, WRD5-1160 through 1162, from Exxon Chemical Co., Baytown, Texas as PLTD-739, PLTD-766, PLTD-782, PLTD 926, PLTD-927 and others, and from the Himont Corporation of Wilmington, Delaware as X11029-20-1 and X1129-20-2. These materials have melt flow rates of above 60 according to ASTM D-1238-9Ob, condition L. Commercially available polymers may or may not have been chemically treated and/or modified in order to raise their melt flow rates.
The polymers employed in the practice of this invention provide not only a high melt flow rate, but are also believed to be responsible for the higher strength in the resulting fabric after bonding. Thus, it has been surprisingly found that the fabric of this invention has a tensile ~ ngll, of at least 10% more than the fabric made from the same polymer without modification to a high melt flow rate.
While the fabric made from the high melt flow rate polymer fibers described above may be used in a laminate with only a low melt flow rate polymer web, it is preferred that the 5 fabric be laminated to other " ,dl~ri~ls as well. Such materials include meltblown webs, films and other spunbond webs.
Films, and meltblown & spunbond webs may be made from any material known in the art to be suitable for such applic~lions. This includes polyamides, polyethers, polyellle,t:sh,:" polyurethanes, polyolefins and copolymers, terpolymers and mixtures 10 thereof. Webs may be made of fibers constructed in a bicomponent configuration as defined above. Elastomeric thermopl~stic polymers may be used to form such films and webs also. Elastomeric polymers are prererably selected from those made from styrenic block copolymers, polyurethanes, polyamides, copolyesters, ethylene vinyl acetates (EVA) and the like.
Styrenic block copolymers include styrene/butadiene/styrene (SBS) block copolymers, styrene/isopr~ne/styrene (SIS) block copolymers, styrene/ethylene-propylene/styrene (SEPS) block copolymers, styrene/ethylene-butadiene/styrene (SEBS) block copolymers. For example, useful elastollleric fiber forming resins include block copolymers having the general formula A-B-A' or A-B, where A and A' are each a 20 the", lopl ~ lic polymer endblock which contains a styrenic moiety such as a poly (vinylarene) and where B is an elas~ol "eric polymer midblock such as a conjugated diene or a lower alkene polymer. Block copolymers of the A-B-A' type can have different or the same ther" lopl?stic block polymers for the A and A' blocks, and the present block copolymers are intended to embrace linear, branched and radial block copolymers. In this regard, the radial 25 block copolymers may be designated (A-B)m-X, wherein X is a polyfunctional atom or molecule and in which each (A-B)m- radiates from X in a way that A is an endblock. In the radial biock copolymer, X may be an organic or inorganic polyfunctional atom or molecule and m is an integer having the same value as the functional group originally present in X. It is usually at least 3, and is frequently 4 or 5, but not limited thereto. Thus, in the present 30 invention, the expression "block copolymer", and particularly "A-B-A"' and "A-B" block copolymer, is intended to embrace all block copolymers having such rubbery blocks and thermoplastic blocks as discussed above, which can be extruded (e.g., by meltblowing), and without limitation as to the number of blocks.
U.S. Patent 4,663,220 to Wisneski et al. discloses a web including "licluribers 35 comprising at least about 10 weight percent of an A-B-A' block copolymer where "A" and "A"' are each a the""oplaslic endblock which comprises a styrenic moiety and where "B" is an elastomeric poly(ethylene-butylene) midblock, and from greater than 0 weight percent up to about 90 weight percent of a polyolefin which when blended with the A-B-A' block copolymer and subjected to an effective combination of elevated temperature and elevated pressure condilions, is adapted to be extruded, in blended form with the A-B-A' block 5 copolymer. Polyolefins useful in Wisneski et al. may be polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, butene copolymers, and mixtures thereof.
Commercial exa~ 'es of such elastomeric copolymers are, for example, those known as KRATON~) materials which are available from Shell Chemical Company of 10 Houston, Texas. KRATON~ block copolymers are available in several different formulations, a number of which are identified in U.S. Patent 4,663,220, hereby incorporated by reference. Particularly suitable elastomeric polymers are elastomeric poly(styrene/ethylene-butylene/styrene) block copolymers available from the Shell Chemical Company of Houston, Texas under the trade designations KRATONO G-1657 and 15 KRATON~) G-2740.
In the laminate of this invention it has been found that an intermediate layer, such as a meltblown layer, does not appreciably change the strength and softness properties of the final laminate when compared to those without the intermediate layer.
Drape is a measure of the softness of a fabric and refers to how well the fabric20 conforms to an object over which it is laid. A soft fabric will drape more in conrur,l ,ance with the outline of the obiect upon which it is draped than will a stiffer fabric. Drape is measured by the Handle-O-Meter test which was previously defined.
The strength of a fabric is measured by the tensile test which was previously defined.
Fabrics made according to this invention have been found to have comparable drape 25 and superior tensile properties as fabrics made from conventional polypropylenes.
The following Control and Exd",ples show the characLeristics of fibers from polymers which satisfy the requirements of this invention versus those that do not. All of the samples were bonded with the expanded Hansen-Pennings pattern described above. The results are shown in table 1.
CONTROL

A fabric was produced which was a spunbond/spunbond (SS) la~ Le. The basis weight of the layers was 1 osy (34 gsm) and 1 osy (34 gsm). Both layers were made from 35 the same low melt flow rate polypropylene: Himont Chemical Co.'s PF-301. The fibers were spun at a temperature of about 390-440~F (199-221~C). The spinneret hole size was 0.6 W 097/40225 PCT~US97/06027 mm with throughput between 0.5 and 0.7 grams/hole/minute (ghm) to produce fiber of 21 microns in diameter.

A fabric was produced which was a spunbond/spunbond (SS) laminate. One of the layers was produced from a high melt flow rate polypropylene and the other from a conventional low melt flow rate polypropylene. The basis weight of the layers was 1 osy for the high melt flow rate layer and 1 osy for the low melt flow rate layer. The high melt flow rate polypropylene was produced by the addition of 1000 to 1500 ppm of peroxide to Himont's PF-301 polypropylene. The melt flow rate of the polymer after peroxide treatment was about 110 according to ASTM D-1238-9Ob condilion L. The high melt flow rate fibers were spun at a temperature of about 390-430~F (199-221~C). The spinneret hole size was 0.6 mm with throughput between 0.5 and 0.7 grams/hole/minute (ghm) to produce fiber of 15 microns in diameter.
The low melt flow rate polypropylene used was Himont's PF-301. The fabric was produced by spinning fibers at the conditions of the Control.
The laminate was produced by first depositing the low melt flow layer onto a forming wire and then depositing the high melt flow polymer layer directly onto the warm low melt flow rate polymer layer.

A fabric was produced which was a spunbond/spunbond (SS) laminate. One of the layers was produced from a high melt flow rate polypropylene and the other from a conventional low melt flow rate polypropylene. The basis weight of the layers was the same as in Example 1. The high melt flow rate polypropylene was produced by the addition of 0.65 weight percent of an organo-metallic compound to Himont's PF-301 polypropylene.
The melt flow rate of the polymer after organo-metallic treatment was 80 according to ASTM
D-1238-9Ob condition L. The organo-metallic compound used was pthalo-Fe2O3-cynanine which is available commercially as a blue-grey pigment from the Standridge Chemical Company of Social Circle, Georgia, as SCC6142. After addition, the polypropylene/organo-metallic mixture was thoroughly mixed.
The high melt flow rate fibers were spun at the same conditions as in Example 1 to produce fiber of 12 mE ons in diameter.

WO 97/40225 PCT/US97tO6027 The low melt flow rate polypropylene was Himont' PF-301. The fabric was produced by spinning fibers at the same conditions as in Example 1 to produce fibers of 19.5 microns in diameter.
The laminate was produced by first depositing the low melt flow layer onto a forming 5 wire and then depositing the high melt flow polymer layer directly onto the warm low melt flow rate polymer layer.

10 A fabric was produced which was a spunbond/spunbond (SS) laminate. One of thelayers was produced from a high melt flow rate polypropylene and the other from a conventional low melt flow rate polypropylene. The basis weight of the layers was the same as in Example 1. The high melt flow rate polypropylene was produced by the adcliLion of 0.65 weight percent of an organo-metallic compound to Himont's PF-301 polypropylene.
15 The melt flow rate of the polymer after organo-metallic treatment was 80 according to ASTM
D-1238-9Ob condiLion L. The organo-metallic compound used is designated Fe2O3/Fe and is available commercially from the Engelhard Corporation. After addition, the polypropylene/organo-metallic mixture was thoroughly mixed. The high melt flow rate fibers were spun at the same conditions as in Example 1 to produce fiber of 15 microns in 20 diar, leter.
The low melt flow rate polypropylene was a mixture of Himont' PF-301 and Exxon Chemical Company's Escorene(g) 3445. The fabric was produced by spinning fibers at the same conditions as in Example 1 to produce fiber of 19.5 microns in diameter.
The laminate was produced by first depositing the low melt flow layer onto a forming 25 wire and then depositing the high melt flow polymer layer directly onto the warm low melt flow rate polymer layer.

Fiber-Size Elongation Normalized Tensile Energy Handle-O-Meter # Sample IdBW(", ~,uns) Cd Md Cd Cd Md 0 Control 2 19-25 30 60 54.3 82.8 97.7 Example 1 2 19-25 34 67 74 56.4 94.2 2 Example 2 2 19-25 39 78.5 78.6 89.8 82.6 3 Example 3 2 19-25 38.5 76 76 51.1 73 The results show that laminates made from fibers spun from polyolefin having thedesignated characteristics can have greater strength than those from unmodified polymers. Strong polyolefin spunbond webs have not been produced as far as the 15 inventors are aware with comparable softness to that of conventional polyolefin spunbond webs in the past.

Claims (18)

We claim

1. A soft and strong nonwoven spunbond polyolefin fabric comprising:
a first web of spunbond fibers produced from polyolefin polymer having a melt flow rate of at least 50 grams /10 minutes wherein said polyolefin polymer is initially produced as a reactor granule through the use of a Ziegler-Natta catalyst with amelt flow rate below 50 grams/10 minutes and subsequently modified by a method selected from the group consisting of the addition of from a positive amount up to 1000 ppm of peroxide, the addition of from a positive amount up to 5 weight percent of sodium bis(para-t-butylphenyl) phosphate and the addition of from a positive amount up to 5 weight percent of a transition metal oxide, in order to increase the melt flow rate by a factor of at least two, and;
a second web of spunbond fibers produced from polyolefin polymer having a melt flow rate of below 50 grams /10 minutes;
wherein said webs are bonded together to form a laminate having a strength at least 10% greater than the same laminate made when said first web polymer melt flow rate does not exceed 50 grams/10 minutes at 230°C.

2. The nonwoven spunbond fabric of claim 1 which has a basis weight between about 0.2 osy and about 3 osy.

3. The nonwoven fabric of claim 1 further comprising a third layer selected from the group consisting of meltblown webs and films and disposed between said first andsecond webs.

4. The nonwoven fabric of claim 3 wherein said third layer is a meltblown web which is made from a polymer selected from the group consisting of polyurethanes, polyetherester, polyamides, polyolefins, polyolefin copolymers and mixtures thereof.

5. The nonwoven fabric of claim 4 wherein said third layer is a meltblown web which is made from a styrenic block copolymer.

6. The nonwoven fabric of claim 3 wherein said third layer is a film which is made from a film forming polymer selected from the group consisting of polyurethanes, polyetherester, polyamides, polyolefins, polyolefin copolymers and mixtures thereof.

7. The nonwoven fabric of claim 6 wherein said film forming polymer is a styrenic block copolymer.

8. The nonwoven fabric of claim 3 wherein said layers are bonded together to form a laminate by a method selected from the group consisting of thermal bonding, ultrasonic bonding, needlepunch bonding and adhesive bonding.

9. The nonwoven fabric of claim 3 which is present in a product selected from the group consisting of medical products, garments, personal care products and outdoor fabrics.

10. A diaper comprising the fabric of claim 3.

11. A feminine hygiene product comprising the fabric of claim 3.

12. A surgical gown comprising the fabric of claim 3.

13. A face mask comprising the fabric of claim 3.

14. A wiper comprising the fabric of claim 3.

15. A soft and strong nonwoven spunbond polyolefin fabric comprising:
a first web of spunbond fibers produced from polyolefin polymer having a melt flow rate of at least 50 grams /10 minutes and a viscosity of at least 2500 dynes.sec/cm2 and;
a second web of spunbond fibers produced from polyolefin polymer having a melt flow rate of below 50 grams /10 minutes;
wherein said webs are bonded together to form a laminate having a strength at least 10% greater than the same laminate made when said first web polymer melt flow rate does not exceed 50 grams/10 minutes at 230°C.

16. The nonwoven fabric of claim 15 further comprising a third layer selected from the group consisting of meltblown webs and films and disposed between said first andsecond webs.

17. The nonwoven fabric of claim 16 wherein said third layer is a meltblown web which is made from a polymer selected from the group consisting of polyurethanes, polyetherester, polyamides, polyolefins, polyolefin copolymers and mixtures thereof.

18. The nonwoven fabric of claim 16 wherein said third layer is a film which is made from a film forming polymer selected from the group consisting of polyurethanes,polyetherester, polyamides, polyolefins, polyolefin copolymers and mixtures thereof.