CA2248974A1 - Catalyst and process for hydrocracking hydrocarbon fractions - Google Patents

Catalyst and process for hydrocracking hydrocarbon fractions

Info

Publication number
CA2248974A1
CA2248974A1 CA002248974A CA2248974A CA2248974A1 CA 2248974 A1 CA2248974 A1 CA 2248974A1 CA 002248974 A CA002248974 A CA 002248974A CA 2248974 A CA2248974 A CA 2248974A CA 2248974 A1 CA2248974 A1 CA 2248974A1
Authority
CA
Canada
Prior art keywords
catalyst
sio2
al2o3 ratio
hydrocarbon fractions
hydrocracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002248974A
Other languages
French (fr)
Other versions
CA2248974C (en
Inventor
Nathalie George-Marchal
Samuel Mignard
Slavik Kasztelan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of CA2248974A1 publication Critical patent/CA2248974A1/en
Application granted granted Critical
Publication of CA2248974C publication Critical patent/CA2248974C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un catalyseur d'hydrocraquage renfermant au moins un métal du groupe VIB, et/ou au moins un métal du groupe VIII de la classification périodique, une matrice alumine, du phosphore, éventuellement au moins un élémen t du groupe VIIA (fluor) et une zéolithe Y non désaluminée globalement de paramètr e cristallin supérieur à 2,438 nm, de rapport SiO2/Al2O3 global inférieur à 8, de rapport SiO2/Al2O3 de charpente inférieur à 21 et supérieur au rapport SiO2/Al2O3 global . L'invention concerne également un procédé d'hydrocraquage avec ce catalyseur, notamment aux basses pressions de 7,5 à 11 MPa.The invention relates to a hydrocracking catalyst containing at least one metal from group VIB, and / or at least one metal from group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA ( fluorine) and a globally non dealuminated Y zeolite with a crystalline parameter greater than 2.438 nm, with an overall SiO2 / Al2O3 ratio less than 8, with a structural SiO2 / Al2O3 ratio less than 21 and greater than the overall SiO2 / Al2O3 ratio. The invention also relates to a hydrocracking process with this catalyst, in particular at low pressures of 7.5 to 11 MPa.

CA002248974A 1997-10-20 1998-10-19 Catalyst and process for hydrocracking hydrocarbon fractions Expired - Fee Related CA2248974C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9713128A FR2769856B1 (en) 1997-10-20 1997-10-20 CATALYST AND METHOD FOR HYDROCRACKING HYDROCARBON CUT
FR9713128 1997-10-20

Publications (2)

Publication Number Publication Date
CA2248974A1 true CA2248974A1 (en) 1999-04-20
CA2248974C CA2248974C (en) 2008-05-13

Family

ID=9512436

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002248974A Expired - Fee Related CA2248974C (en) 1997-10-20 1998-10-19 Catalyst and process for hydrocracking hydrocarbon fractions

Country Status (9)

Country Link
US (1) US6174429B1 (en)
EP (1) EP0911077B1 (en)
JP (1) JP4088731B2 (en)
KR (1) KR100635307B1 (en)
BR (1) BR9804013A (en)
CA (1) CA2248974C (en)
DE (1) DE69838470T2 (en)
ES (1) ES2294808T3 (en)
FR (1) FR2769856B1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2778343B1 (en) 1998-05-06 2000-06-16 Inst Francais Du Petrole CATALYST BASED ON ZEOLITH Y NOT GLOBALLY DESALUMINATED, BORON AND / OR SILICON AND HYDROCRACKING PROCESS
CN1096296C (en) 1998-11-13 2002-12-18 中国石油化工集团公司 Hydrocracking catalyst for producing middle distillate and its preparation method
US6387246B1 (en) * 1999-05-19 2002-05-14 Institut Francais Du Petrole Catalyst that comprises a partially amorphous Y zeolite and its use in hydroconversion of hydrocarbon petroleum feedstocks
FR2793705B1 (en) * 1999-05-19 2001-06-29 Inst Francais Du Petrole CATALYST COMPRISING A PARTIALLY AMORPHOUS ZEOLITH, AN ELEMENT OF THE VB GROUP AND ITS USE IN HYDROCONVERSION AND HYDROREFINING OF HYDROCARBON OIL LOADS
US6596662B2 (en) 2000-03-24 2003-07-22 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
US6747182B2 (en) 2000-03-24 2004-06-08 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
ES2200701B1 (en) * 2002-07-16 2005-05-01 Universidad Politecnica De Valencia HYDROCRACHING CATALYST CONTAINING A MICROPOROUS CRYSTAL SOLID MATERIAL AND USE OF SUCH CATALYST FOR HYDROCARBON FEEDING HYDROCRACHING.
US6902664B2 (en) * 2002-11-08 2005-06-07 Chevron U.S.A. Inc. Extremely low acidity USY and homogeneous, amorphous silica-alumina hydrocracking catalyst and process
FR2863913B1 (en) * 2003-12-23 2006-12-29 Inst Francais Du Petrole ZEOLITHIC CATALYST, SILICO-ALUMINUM MATRIX AND ZEOLITE BASE, AND METHOD FOR HYDROCRACKING HYDROCARBON LOADS
US7323100B2 (en) * 2004-07-16 2008-01-29 Conocophillips Company Combination of amorphous materials for hydrocracking catalysts
US7611689B2 (en) * 2004-09-24 2009-11-03 Shell Oil Company Faujasite zeolite, its preparation and use in hydrocracking
CN100389178C (en) * 2005-01-14 2008-05-21 中国石油化工股份有限公司 Fluorine-containing hydrogenation catalyst and method for preparing the same
JP5185816B2 (en) * 2005-06-29 2013-04-17 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット Pentasil catalysts for light olefins in fluidized contact units
EP2258476A4 (en) * 2008-03-28 2017-02-22 Petroleum Energy Center, A Juridical Incorporated Foundation Hydrocracking catalyst for heavy oil
AU2010238811B2 (en) 2009-04-21 2015-01-29 Albemarle Europe Sprl Hydrotreating catalyst containing phosphorus and boron
US8080492B2 (en) * 2009-04-29 2011-12-20 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7931799B2 (en) * 2009-04-29 2011-04-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
JP5547923B2 (en) * 2009-08-03 2014-07-16 出光興産株式会社 Heavy oil hydrocracking catalyst and method for hydrotreating heavy oil using the same
CN102463131B (en) * 2010-11-04 2014-07-23 中国石油化工股份有限公司 Hydrocracking catalyst and preparation method thereof
FR2970259B1 (en) * 2011-01-07 2014-07-18 IFP Energies Nouvelles HYDROCRACKING PROCESS USING A ZEOLITHIC CATALYST CONTAINING TWO DISTINCT HYDROGENANT FUNCTIONS
CN103191772B (en) * 2012-01-06 2014-09-17 中国石油化工股份有限公司 Preparation method of hydrocracking catalyst
CN103191775B (en) * 2012-01-06 2014-08-20 中国石油化工股份有限公司 Preparation method of hydrocracking catalyst
CN103191774B (en) * 2012-01-06 2014-08-20 中国石油化工股份有限公司 Method for preparing hydrocracking catalyst
CN105536854B (en) * 2014-11-03 2018-04-10 中国石油化工股份有限公司 A kind of method for preparing the hydrocracking catalyst containing Y molecular sieve
CN105536855B (en) * 2014-11-03 2018-04-10 中国石油化工股份有限公司 A kind of preparation method of the hydrocracking catalyst containing Y molecular sieve
FR3046176A1 (en) 2015-12-23 2017-06-30 Axens HYDROPROCESSING OR HYDROCONVERSION PROCESS WITH STRIPER AND LOW PRESSURE SEPARATOR BALL ON THE FRACTION SECTION

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US5288396A (en) * 1979-10-15 1994-02-22 Union Oil Company Of California Hydrocracking process using a catalyst selective for making middle distillates
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Also Published As

Publication number Publication date
DE69838470D1 (en) 2007-11-08
FR2769856A1 (en) 1999-04-23
FR2769856B1 (en) 1999-12-03
KR100635307B1 (en) 2007-06-07
JPH11192437A (en) 1999-07-21
DE69838470T2 (en) 2008-01-10
KR19990037213A (en) 1999-05-25
JP4088731B2 (en) 2008-05-21
EP0911077A1 (en) 1999-04-28
CA2248974C (en) 2008-05-13
US6174429B1 (en) 2001-01-16
BR9804013A (en) 1999-12-07
ES2294808T3 (en) 2008-04-01
EP0911077B1 (en) 2007-09-26

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