CA2248359C - Procede de preparation de propanediol-1,3 - Google Patents
Procede de preparation de propanediol-1,3 Download PDFInfo
- Publication number
- CA2248359C CA2248359C CA002248359A CA2248359A CA2248359C CA 2248359 C CA2248359 C CA 2248359C CA 002248359 A CA002248359 A CA 002248359A CA 2248359 A CA2248359 A CA 2248359A CA 2248359 C CA2248359 C CA 2248359C
- Authority
- CA
- Canada
- Prior art keywords
- cobalt
- water
- hydroxypropanal
- catalyst
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
- C07C45/58—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in three-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La préparation de propanediol-1,3 s'effectue dans le cadre d'un procédé faisant réagir de l'oxyde d'éthylène avec du monoxyde de carbone et de l'hydrogène dans un solvant quasiment non miscible à l'eau en présence d'une quantité efficace d'un catalyseur au cobalt dépourvu de ligand du type phosphine et d'une quantité efficace d'un promoteur catalytique et ce, dans des conditions de réaction à même de produire un mélange intermédiaire comportant moins de 15 % en poids d'hydroxypropanal-3. A partir de ce mélange, on extrait l'hydroxypropanal-3 dans l'eau sous une forme davantage concentrée, la majeure partie du catalyseur au cobalt demeurant dans la phase solvant pour recyclage aux fins de la réaction d'hydroformylation. On débarrasse, partiellement du moins, la phase aqueuse suivant l'extraction de tout catalyseur résiduel par le biais d'une nouvelle extraction faisant intervenir un solvant non miscible à l'eau, puis on recycle cette phase aux fins de la réaction d'hydroformylation. L'hydroxypropanal-3 est alors hydrogéné dans une solution aqueuse jusqu'à obtenir le propanediol-1,3 désiré.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/615,544 US5770776A (en) | 1994-09-30 | 1996-03-11 | Process for preparing 1,3-propanediol |
US08/615,544 | 1996-03-11 | ||
PCT/EP1997/001172 WO1997033851A1 (fr) | 1996-03-11 | 1997-03-06 | Procede de preparation de propanediol-1,3 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2248359A1 CA2248359A1 (fr) | 1997-09-18 |
CA2248359C true CA2248359C (fr) | 2006-10-24 |
Family
ID=37387463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002248359A Expired - Fee Related CA2248359C (fr) | 1996-03-11 | 1997-03-06 | Procede de preparation de propanediol-1,3 |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA2248359C (fr) |
-
1997
- 1997-03-06 CA CA002248359A patent/CA2248359C/fr not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2248359A1 (fr) | 1997-09-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |