CA2242418A1 - Machine dishwashing compositions - Google Patents
Machine dishwashing compositions Download PDFInfo
- Publication number
- CA2242418A1 CA2242418A1 CA 2242418 CA2242418A CA2242418A1 CA 2242418 A1 CA2242418 A1 CA 2242418A1 CA 2242418 CA2242418 CA 2242418 CA 2242418 A CA2242418 A CA 2242418A CA 2242418 A1 CA2242418 A1 CA 2242418A1
- Authority
- CA
- Canada
- Prior art keywords
- bismuth
- diphosphonate
- acid
- compound
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 150
- 238000004851 dishwashing Methods 0.000 title description 12
- -1 bismuth diphosphonate compound Chemical class 0.000 claims abstract description 94
- 238000000034 method Methods 0.000 claims abstract description 48
- 239000003599 detergent Substances 0.000 claims abstract description 46
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 35
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000007844 bleaching agent Substances 0.000 claims abstract description 32
- 238000004061 bleaching Methods 0.000 claims abstract description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical compound [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 claims abstract description 23
- 239000000243 solution Substances 0.000 claims description 79
- 150000001875 compounds Chemical class 0.000 claims description 71
- 150000003839 salts Chemical class 0.000 claims description 54
- 239000002243 precursor Substances 0.000 claims description 52
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical group OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 27
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 15
- XXCBDJHHAKURGV-UHFFFAOYSA-H P(=O)([O-])OP(=O)[O-].[Bi+3].P(=O)([O-])OP(=O)[O-].P(=O)([O-])OP(=O)[O-].[Bi+3] Chemical compound P(=O)([O-])OP(=O)[O-].[Bi+3].P(=O)([O-])OP(=O)[O-].P(=O)([O-])OP(=O)[O-].[Bi+3] XXCBDJHHAKURGV-UHFFFAOYSA-H 0.000 claims description 14
- 150000004965 peroxy acids Chemical class 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 12
- 238000005054 agglomeration Methods 0.000 claims description 11
- 230000002776 aggregation Effects 0.000 claims description 10
- 238000005187 foaming Methods 0.000 claims description 8
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 7
- 150000001621 bismuth Chemical class 0.000 claims description 7
- 229910001451 bismuth ion Inorganic materials 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 239000012670 alkaline solution Substances 0.000 claims 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 239000013042 solid detergent Substances 0.000 claims 2
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000005494 tarnishing Methods 0.000 abstract description 4
- 230000002829 reductive effect Effects 0.000 abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 34
- 229910052709 silver Inorganic materials 0.000 description 29
- 239000004332 silver Substances 0.000 description 29
- 239000011248 coating agent Substances 0.000 description 28
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 27
- 125000000217 alkyl group Chemical group 0.000 description 26
- 239000002689 soil Substances 0.000 description 26
- 239000002253 acid Substances 0.000 description 23
- 239000003795 chemical substances by application Substances 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- 239000000047 product Substances 0.000 description 19
- 102000004190 Enzymes Human genes 0.000 description 18
- 108090000790 Enzymes Proteins 0.000 description 18
- 238000000576 coating method Methods 0.000 description 18
- 229940088598 enzyme Drugs 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 238000005260 corrosion Methods 0.000 description 14
- 230000007797 corrosion Effects 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 14
- 229910001385 heavy metal Inorganic materials 0.000 description 13
- 125000003118 aryl group Chemical group 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000003112 inhibitor Substances 0.000 description 12
- 239000003352 sequestering agent Substances 0.000 description 12
- 239000005977 Ethylene Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 11
- 150000004967 organic peroxy acids Chemical class 0.000 description 11
- 229920005646 polycarboxylate Polymers 0.000 description 11
- 241000894007 species Species 0.000 description 11
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 10
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 10
- 229910052681 coesite Inorganic materials 0.000 description 10
- 229910052906 cristobalite Inorganic materials 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 10
- 235000012239 silicon dioxide Nutrition 0.000 description 10
- 229910052682 stishovite Inorganic materials 0.000 description 10
- 229910052905 tridymite Inorganic materials 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000004115 Sodium Silicate Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 150000002191 fatty alcohols Chemical class 0.000 description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
- 229910052911 sodium silicate Inorganic materials 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 125000002877 alkyl aryl group Chemical group 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 235000021317 phosphate Nutrition 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000004367 Lipase Substances 0.000 description 7
- 108090001060 Lipase Proteins 0.000 description 7
- 102000004882 Lipase Human genes 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 235000019421 lipase Nutrition 0.000 description 7
- 229920000620 organic polymer Polymers 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229940100515 sorbitan Drugs 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- 108010065511 Amylases Proteins 0.000 description 6
- 102000013142 Amylases Human genes 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 108091005804 Peptidases Proteins 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 238000013270 controlled release Methods 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical class [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 235000019418 amylase Nutrition 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 235000010980 cellulose Nutrition 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 150000002194 fatty esters Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical class OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 235000019795 sodium metasilicate Nutrition 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000000087 stabilizing effect Effects 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- 239000005662 Paraffin oil Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- 229940025131 amylases Drugs 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical class O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 239000003966 growth inhibitor Substances 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 244000228957 Ferula foetida Species 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- TTZMPOZCBFTTPR-UHFFFAOYSA-N O=P1OCO1 Chemical compound O=P1OCO1 TTZMPOZCBFTTPR-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004365 Protease Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 229960004106 citric acid Drugs 0.000 description 3
- 150000001860 citric acid derivatives Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000013110 organic ligand Substances 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 229940045872 sodium percarbonate Drugs 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 229960002920 sorbitol Drugs 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
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- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NJKRDXUWFBJCDI-UHFFFAOYSA-N propane-1,1,2,3-tetracarboxylic acid Chemical class OC(=O)CC(C(O)=O)C(C(O)=O)C(O)=O NJKRDXUWFBJCDI-UHFFFAOYSA-N 0.000 description 1
- NJEVMKZODGWUQT-UHFFFAOYSA-N propane-1,1,3,3-tetracarboxylic acid Chemical class OC(=O)C(C(O)=O)CC(C(O)=O)C(O)=O NJEVMKZODGWUQT-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 108010080511 serum sodium transport inhibitor Proteins 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- SZINDZNWFLBXKV-UHFFFAOYSA-M sodium;2-(2-hydroxyethoxy)ethanesulfonate Chemical group [Na+].OCCOCCS([O-])(=O)=O SZINDZNWFLBXKV-UHFFFAOYSA-M 0.000 description 1
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/386—Polyphosphonic acids containing hydroxy substituents in the hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
There is provided a bismuth diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1:0.7 to 1:7. Bleaching and detergent compositions adapted for use in machine diswashing having reduced silver-tarnishing, as well as good cleaning performance are also provided. The compositions contain an oxygen bleach and the bismuth diphosphonate compound.
Preferred processes for making the compositions are described.
Preferred processes for making the compositions are described.
Description
l\IACHINE DISHWASHING COMPO~ITIONS
Technical Field The present invention relates to bi~mnth diphosphonate compounds and methods of m~kin~ such compounds and their use in oxygen-bleach cont~inin~ compositions, adapted for use in machine dishwashing, which exhibit good bleachable stain removal and reduced silver-tarni~hir~
properties.
B~çk~round to the Invention ~ompositions designed for use in automatic dishwasher machines are well known, and a consistent effort has been made by detergent m~nllf~cturers to improve the cleaning and/or rinsing efficiency of said compositions on chinaware, glassware and silverware, as reflected by numerous patent publications.
The satisfactory removal of bleachable soils such as tea, fruit juice and coloured vegetable soils, such as carotenoid soils is a particular challenge to the formulator of a machine dishwashing composition. Traditionally, the removal of such soils has been enabled by the use of bleach components such as oxygen and chlorine bleaches.
A problem encountered with the use of oxygen bleaches, in particular, is the tarni~hing of any silverware components of the washload. Chlorine bleaches can under certain circumstances give rise to silver tarni~hin~, but " the problem is significantly less pronounced than that arising from the use of oxygen bleaches. The level of tarni~hinP observed with oxygen bleaches can range from slight discolouration of the silverware to the formation of a dense black coating on the surface of the silverware.
. CA 02242418 1998-07-07 W O 97~5405 PCTAUS97/00471 The formulator thus faces the dual challenge of form~ tin~ an oxygen bleach cont~ining product which maximises bleachable soil cleaning but minimiceS the occurrence of tarni~hinr~ of any silverware components of the washload.
It has been surprisingly found that reduced silver tarnishing as well as good cle~nin~ performance can be achieved through the inclusion in an oxygen bleach cont~inin~ formulation of certain bism~lth diphosphonate compounds. These compounds also demonstrate good 'in product' storage stability characteristics.
It has also been found that the presence of water-soluble sulphate salts surprisingly enhances the silver tarnish inhibition capability of the bi~m~
diphosphonate compound. In particular excellent results are obtained when - a particle, formed for example, by agglomeration methods, comprising both sulphate and bismuth diphosphonate compound components is employed.
To further reduce the occurence of silver tarni~hing, the rate of release of the oxygen bleach is preferably also controlled. The rate of release of oxygen bleach is preferably rapid enough to provide satisfactory cleaning, but not so rapid that tarnishing is enabled.
Compositions having low ~lk~linity, and in particular those having ~lk~linity systems including a minor proportion of a metasilicate component are preferred, as are compositions having a pH which is not unduly high.
UK Patent Specif~cation No. 1,586,067 in the name of the Procter and Gamble Company, discloses automatic dishwashing compositions cont~ininf~: bismuth salts to provide protection to china overglaze without any negative glassware irridescence effects. Bi.~mllth diphosphonate compounds are not explicitly described. It is taught therein that chlorine bleaching agents are preferable components of these compositions and specific examples of chlorine containing compositions are given. The use of oxygen bleaches in such compositions is not disclosed. The problem of W O 97/25405 PCT~US97/00471 silver tarni~hin~ is not addressed by this document, nor is any teaching provided of the use of bismuth salts as silver tarnish inhibition agents.
Sllmm~ry of the Invention There is provided a bismuth diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1:0.7 to l :7.
There is additionally provided a process for m~kin~ an ~lk~line bismuthdiphosphonate solution comprising the following steps:
(i) formation of an ~lk~line solution cont~inin~ a diphosphonate species;
(ii) agitatative addition of a solution cont~ininf~ bismuth ions to said ~lk:~lin~
solution wherein the amount of bismuth to diphosphonate species corresponds to a molar ratio of from 1:0.7 to 1:7.
Said bismuth diphosphonate solution can be sprayed onto a bleaching composition to form a bleaching product. In a preferred aspect, the bleaching composition also contains detergent components.
There is further provided a process for m~kinp a bismuth disphosphonatecont~inin~ particle by agglomeration of an inorganic salt cont~inin~ an anion capable of forming a salt, preferably an insoluble salt, with bismuth with an ~lk~line bismuth diphosphonate solution, and optionally an organic binder, preferably an organic polymeric compound.
There are also provided bleaching and detergent compositions, adapted for use in machine dishwashing methods, cont~ining an oxygen-releasing bleaching system and bismuth diphosphonate compound. In a preferred aspect the detergent compositions contain no phosphate builder compound.
- WO 97/25405 PCT~US97/00471 Detailed ~escription Qf the Invention Bismuth diphosphonate compound According to one aspect of the present invention there is provided a bi.~mlltll diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1 :0.7 to 1 :7, preferably from 1: 1 to 1:6, more preferably from 1:2 to 1:5.
The bismuth diphosphonate compound may be essentially any salt or complex of bismuth with essentially any organic diphosphonic acid. By organo diphosphonic acid it is meant herein an organo diphosphonic acid which does not contain nitrogen as part of its chemical structure. This definition therefore excludes the organo aminophosphonates, which however may be included in any compositions in accord with the invention as heavy metal ion sequestrant components.
The organo diphosphonic acid is preferably a Cl-C4 diphosphonic acid, more preferably a C2 diphosphonic acid, such as ethylene diphosphonic acid, or most preferably ethane l-hydroxy-l,l-diphosphonic acid (HEDP) and may be present in partially or fully ionized form, particularly as a salt or complex.
The compound cont~ining bismuth and HEDP at a 1:3.5 molar ratio is mostpreferred.
Process for m~kin~ a bismuth diphosphonate solution According to another aspect of the present invention there is provided a step-wise process for making a bi.cm~th diphosphonate solution in~rolving seq~enti~lly the formation of an ~lk~line solution cont~inin~ a diphosphonate species followed by addition of a solution cont~inin~
bismuth ions. This solution has been found to be both storage and transport stable, and may be employed in the m~kin~ of bleaching and/or detergent compositions, as described hereinafter.
The advantage provided by the step-wise process versus a process in which both steps take place concurrently is that, in the latter case, a heavy yellow essentially insoluble precipitate, believed to be bismuth hydroxide, is formed. This precipitate impedes the further processing of the solution, and limits its usefulness in the making of bleaching and/or detergent compositions.
The process comprises as a first step the formation of an ~lk~line solution cont~inin~ a diphosphonate species. The ~lk~line solution may for example, be formed by direct addition, preferably with agitation, of a diphosphonic acid to an aqueous ~lk~line solution, such as NaOH solution. In a preferred aspect said addition is continuous, but carried out at a relatively slow rate such as to avoid excess generation of heat from the neutralization reaction.
The process has as a second step the agitative addition of a solution cont~ining bismuth ions to the ~lk~line solution cont~inin~ the diphosphonate species. By agitative addition it is meant addition in the presence of some means of agitation, such as may be provided by carrying out the addition in a mixer apparatus. The solution cont~ininp bismuth ions may comprise a solution of any suitable salt or complex of bismuth with essentially any inorganic or organic counter anion. Preferred inorganic bismuth salts for use in m~kinp up the solution are selected from the bismuth trihalides, bismuth nitrate and bismuth phosphate. Bi~mllth acetate and citrate are preferred salts with an organic counter anion.
The amount of ~lk~line diphosphonate and bismuth ion solutions employed in this process aspect is adjusted such as to result in the formation of a bismuth diphosphonate solution having a molar ratio of bismuth to diphosphonate species of from 1:0.7 to 1:7.
~, The bismuth diphosphonate solution can be sprayed onto a bleaching composition to form a bleaching product. In a preferred aspect, the bleaching composition also contains detergent components, and the bi.~mllfh O 97/25405 PCT~US97/00471 diphosphonate solution is thus sprayed onto both bleaching and detergent components.
Rismuth diphosphonate ~gplomerate particle According to another aspect of the invention there is provided a process for m~kinp a bismuth disphosphonate-cont~ininP particle by agglomeration of an inorganic salt with an ~lk~line bismuth diphosphonate solution preferably obtained by the process described hereinabove. The inorganic salt comprises an anion capable of forming a salt, especially an insoluble salt, with bi~mlltll The advantage provided by the use of an ~lk~line rather than neutral, or acidic bismuth diphosphonate solution in the agglomeration step is that the llnt1e~irable ~ormation of (other) bismuth salts, particularly insoluble ones, is prevented.
The ~lk~line. diphosphonate solution preferably has a pH of at least 9.0, more preferably at least 10Ø
The inorganic salt may be essentially any salt of an inorganic anion capable also of forming a bismuth salt, such as sulfates, carbonates and phosphates with any counter cation, including the alkali and ~lk~line earth metals.
Preferred salts are selected from the sulfates of the alkali and ~lk~line earth metals, particularly sodium sulfate.
The weight ratio of the inorganic salt to bismuth diphosphonate compound in the particle is preferably from 200:1 to 2:1, more preferably from 100:1 to 5:1, most preferably from 50:1 to 10:1.
In a preferred aspect the particle comprises an organic binder material. The organic binder material is preferably selected from any of the organic polymeric compounds described in detail hereinafter, and any mixtures thereof.
CA 022424l8 l998-07-07 W O 97i25405 PCT~US97/00471 Other suitable binders include the Clo-C20 alcohol ethoxylates cont~inin~
from ~ - 100 moles of ethylene oxide per mole of alcohol and more preferably the Cls-C20 primary alcohol ethoxylates cont~ining from 20 -100 moles of ethylene oxide per mole of alcohol. Polyvinylpyrrolidones with an average molecular weight of from 12,000 to 700,000 and polyethylene glycols (PEG) with an average molecular weight of from 600 to S x 106 preferably 10~)0 to 400,000 most preferably 1000 to 10,0(~0 are also suitable binders. Cellulose derivatives such as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose, and homo- or co-polymeric polycarboxylic acids or their salts are other examples of binders suitable for use herein.
The agglomeration method employed can be any of those known in the art.
Any conventional agglomerator/mixer may be used including, but not limited to pan, rotary drum and vertical blender types. Mixers sold by Schugi (tradename) and Lodige (tradename) for use in agglomeration methods are particularly suitable. Agglomeration processes employing 'in series' combinations of mixers are also envisaged.
Bleachin~ compositions The bismuth diphosphonate compounds and particles cont~ininP such compounds described hereinbefore may be incorporated into compositions cont~inin~ an oxygen-releasing bleaching system.
Oxy en-releasing bleaching system In one preferred aspect the bleaching system contains a hydrogen peroxide source and an organic peroxyacid bleach precursor compound. The production of the organic peroxyacid occurs by an in situ reaction of the precursor with a source of hydrogen peroxide. Preferred sources of hydrogen peroxide include inorganic perhydrate bleaches. In an alternative preferred aspect a preformed organic peroxyacid is incorporated directly into the composition. Compositions cont~ining mixtures of a hydrogen W O 97/2540~ PCT~US97/00471 -peroxide source and organic peroxyacid precursor in combination with a pre~ormed organic peroxyacid are also envisaged.
Inor~anic perhydrate bleaches The compositions in accord with the invention preferably include a hydrogen peroxide source, as an oxygen-releasing bleach. Suitable hydrogen peroxide sources include the inorganic perhydrate salts.
The inorganic perhydrate salts are normally incorporated in the form of the sodium salt at a level of from 1% to 40~ by weight, more preferably from 2% to 3(~% by weight and most preferably from 5% to 25% by weight of the coInpositions.
Examples of inorganic perhydrate salts include perborate, percarbonate, perphosphate, persulfate and persilicate salts. The inorganic perhydrate salts are normally the alkali metal salts. The inorganic perhydrate salt may be included as the crystalline solid without additional protection. For certain perhydrate salts however, the preferred executions of such granular compositions utilize a coated form of the material which provides better storage stability for the perhydrate salt in the granular product.
Sodium perborate can be in the form of the monohydrate of nominal formula NaB02H202 or the tetrahydrate NaB02H202.3H20.
Alkali metal percarbonates, particularly sodium percarbonate are preferred perhydrates for inclusion in compositions in accordance with the invention.
Sodium percarbonate is an addition compound having a formula corresponding to 2Na2C03.3H202, and is available commercially as a crystalline solid. Sodium percarbonate, being a hydrogen peroxide addition compound tends on dissolution to release the hydrogen peroxide quite rapidly which can increase the tendency for localised high bleach concentrations to arise. The percarbonate is most pre~erably incorporated into such compositions in a coa~ed form which provides in product stability.
W O 97/254Q5 PCT~US97/00471 A suitable coating material providing in product stability comprises mixed salt of a water soluble alkali metal sulphate and carbonate. Such coatings together with coating processes have previously been described in GB-1,46~,799, granted to Interox on 9th March 1977. The weight ratio of the mixed salt coating material to percarbonate lies in the range ~rom 1: 200 to 1: 4, more preferably from 1: 99 to 1: 9, and most preferably from 1:
49 to 1: 19. Preferably, the mixed salt is of sodium sulphate and sodium carbonate which has the general formula Na2SO4.n.Na2~O3 wherein n is from 0.1 to 3, preferably n is from 0.3 to 1.0 and most preferably n is from 0.2 to 0.5.
Other coatings which contain silicate (alone or with borate salts or boric acids or other inorganics), waxes, oils, fatty soaps can also be used advantageously within the present invention.
Potassium peroxymonopersulfate is another inorganic perhydrate salt ofutility in the compositions herein.
Peroxyacid bleach precursor Peroxyacid bleach precursors are compounds which react with hydrogen peroxide in a perhydrolysis reaction to produce a peroxyacid. Generally peroxyacid bleach precursors may be represented as o Il x-C--L
where L is a leaving group and X is essentially any functionality, such that on perhydroloysis the structure of the peroxyacid produced is ..
x--C-OOH
Peroxyacid bleach precursor compounds are preferably incorporated at a level of from 0.5~o to 20~o by weight, more preferably from 1 % to 10%
by weight, most preferably from 1.5% to 5% by weight of the compositions.
Suitable peroxyacid bleach precursor compounds typically contain one ormore N- or O-acyl groups, which precursors can be selected from a wide range of classes. Suitable classes include anhydrides, esters, imides, lactams and acylated derivatives of imidazoles and oximes. Examples of useful materials within these classes are disclosed in GB-A-15867~39.
Suitable esters are disclosed in GB-A-836988, 864798, 1147871, 2143231 and EP-A-0170386.
W 097/25405 PCT~US97/00471 Leavin~ roups The leaving group, hereinafter L group, must be sufficiently reactive for the perhydrolysis reaction to occur within the o~ lum time frame (e.g., a wash cycle). However, if L is too reactive, this activator will be difficult to stabilize for use in a bleaching composition.
PrefelLed L groups are selected from the group consisting of:
_o~, o~Y, and --~~
1 3 L=l ' R3 Y
lR3 r --O--CH=C--CH=CH2--O--CH=C--CH=CH2 -O--C--R1 _N/ NR4 ~C~NR4 O O
--O--C=CHR4 , andIN i--CH--R4 R3 o and mixtures thereof, wherein Rl is an alkyl, aryl, or alkaryl group cont~ininf~ from 1 to 14 carbon atoms, R3 is an alkyl chain cont~inin~ from 1 to 8 carbon atoms, R4 is H or R3, and Y is H or a solubilizing group.
Any of Rl, R3 and R4 may be substituted by essentially any functional group including, for example alkyl, hydroxy, alkoxy, halogen, amine, nitrosyl, amide and ammonium or alkyl ~mmmonium groups The ~re~l 1 ed solubilizing groups are -S03-M +, -C02-M +, -S04-M ~, -N+(R3)~X- and O < --N(R3)3 and most preferably -S03-M + and -C~2 M wherein R is an alkyl chain cont~inin~ from 1 to 4 carbon atoms, M is a cation which provides solubility to the bleach activator and X
is an anion which provides solubility to the bleach activator. Preferably, M
is an alkali metal, ammonium or substihlte-l ammonium cation, with sodium and potassium being most preferred, and X is a halide, hydroxide, methylsulfate or acetate anion.
Perbenzoic acid precursor Perbenzoic acid precursor compounds provide perbenzoic acid on perhydrolysis.
Suitable O-acylated perbenzoic acid precursor compounds include the substituted and unsubstituted benzoyl oxybenzene sulfonates, including for example benzoyl oxybenzene sulfonate:
o (~o4~3So3-Also suitable are the benzoylation products of sorbitol, glucose, and all saccharides with benzoylating agents, including for example:
W O 97/25405 PCT~US97/00471 OAc AcO ~Lo ~,OAc - / OAc OBz Ac = COCH3; Bz = Benzoyl Perbenzoic acid precursor compounds of the imide type include N-benzoyl succinimide, tetrabenzoyl ethylene ~ mine and the N-benzoyl substituted ureas. Suitable imidazole type perbenzoic acid precursors include N-benzoyl imid~7.ole and N-benzoyl benzimidazole and other useful N-acyl group-cont~ining perbenzoic acid precursors include N-ben_oyl pyrrolidone, dibenzoyl taurine and benzoyl pyroglutamic acid.
Other perbenzoic acid precursors include the benzoyl diacyl peroxides, the benzoyl tetraacyl peroxides, and the compound having the formula:
O O
[~0'~1~O--COOH
Phthalic anhydride is another suitable perbenzoic acid precursor compound herein:
~0 ., O
Suitable N-acylated lactam perbenzoic acid precursors have the formula:
W O 97/25405 PCT~US97/00471 R6--C ~
wherein n is from O to 8, preferably from O to 2, and R6 is a benzoyl group.
Perbenzoic acid derivative precursors Perbenzoic acid derivative precursors provide substituted perbenzoic acids on perhydrolysis.
Suitable substituted perbenzoic acid derivative precursors include any of the herein disclosed perbenzoic precursors in which the benzoyl group is substituted by essentially any non-positively charged (ie; non-cationic) functional group including, for example alkyl, hydroxy, alkoxy, halogen, amine, nitrosyl and amide groups.
A preferred class of substituted perbenzoic acid precursor compounds are the amide substituted compounds of the following general formulae:
O R5 0 or R5 O O
wherein R~ is an aryl or alkaryl group with from 1 to 14 carbon atoms, R2 is an arylene, or alkarylene group cont~ining from 1 to 1~ carbon atoms, and R5 is H or an alkyl, aryl, or alkaryl group cont~ining 1 to 10 carbon atoms and L can be essentially any leaving group. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be aryl, substituted aryl or alkylaryl cont~inin~ branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, aryl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. R5 is preferably H or methyl. Rl and R5 should not contain more than 18 carbon atoms in total. Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
Cationic peroxyacid precursors Cationic peroxyac;d precursor compounds produce cationic peroxyacids on perhydrolysis.
W O 97/25405 PCT~US97/00471 Typically, cationic peroxyacid precursors are formed by substituting the peroxyacid part of a suitable peroxyacid precursor compound with a positively charged functional group, such as an ammonium or alkyl mmmonium group, preferably an ethyl or methyl ammonium group.
Cationic peroxyacid precursors are typically present in the compositions as a salt with a suitable anion, such as for example a halide ion or a methylsulfate ion.
The peroxyacid precursor compound to be so cationically substituted maybe a perbenzoic acid, or substituted derivative thereof, precursor compound as described hereinbefore. Alternatively, the peroxyacid precursor compound may be an alkyl percarboxylic acid precursor compound or an amide substituted alkyl peroxyacid precursor as described hereinafter Cationic peroxyacid precursors are described in U.S. Patents 4,904,406;4,751,015; 4,988,451; 4,397,7~7; 5,269,962; 5,127,852; 5,093,0~2;
5,106,528; U.K. 1,382,594; EP 475,512, 458,396 and 284,292; a~nd in JP
87-318,332.
Examples of preferred cationic peroxyacid precursors are described in UK
Patent Application No. 9407944.9 (attorney's docket no. CM642F~ and US
Patent Application Nos. 08/298903, 08/298650, 0~/298904 and 08/298906 (attorney's docket no.s 5413 to 5416).
Suitable cationic peroxyacid precursors include any of the ammonium or alkyl ammonium substituted alkyl or benzoyl oxybenzene sulfonates, N-acylated caprol~ct~m~, and monobenzoyltetraacetyl glucose benzoyl peroxides.
A preferred cationically substituted benzoyl oxybenzene sulfonate is the 4-(trimethyl ammonium) methyl derivative of benzoyl oxybenzene sulfonate:
W O 97/25405 PCT~US97/00471 ~ ,_~o~S~3-\N+
/ ~
A preferred cationically substituted alkyl oxybenzene sulfonate has the formula:
~/ N ~ ~0~
Preferred cationic peroxyacid precursors of the N-acylated caprolactam class include the trialkyl ammonium methylene benzoyl caprolactams, particularly trimethyl ammonium methylene benzoyl caprolactam:
,~,J~ N
Other preferred cationic peroxyacid precursors of the N-acylated caprolactam class include the trialkyl ammonium methylene alkyl caprolactams:
O o )~N~
+~(CH2~n where n is from 0 to 12, particularly from 1 to 5.
W O 97/25405 PCT~US97/00471 Another preferred cationic peroxyacid precursor is 2-(N,N,N-trimethyl ammonium) ethyl sodium 4-sulphophenyl carbonate chloride.
Alkyl percarboxylic acid bleach precursors Alkyl percarboxylic acid bleach precursors form percarboxylic acids on perhydrolysis. Preferred precursors of this type provide peracetic acid on perhydrolysis.
Preferred alkyl percarboxylic precursor compounds of the imide type include the N-,N,NlNl tetra acetylated alkylene ~ mines wherein the alkylene group contains from 1 to 6 carbon atoms, particularly those compounds in which the alkylene group contains 1, 2 and 6 carbon atoms.
Tetraacetyl ethylene rli~mine ~I'AED) is particularly preferred.
Other preferred alkyl percarboxylic acid precursors include sodiunn 3,5,5-tri-methyl hexanoyloxybenzene sulfonate (iso-NOBS), sodium nonanoyloxybenzene sulfonate (NOBS), sodium acetoxybenzene sulfonate (ABS) and pentaacetyl glucose.
A~nide substituted alkyl peroxyacid precursors Amide substituted alkyl peroxyacid precursor compounds are also suitable, including those of the following general formulae:
Il l 11 1 11 11 O R5 O or R5 O O
wherein Rl is an alkyl group with from 1 to 14 carbon atoms, R2 is an alkylene group cont~inin~ from 1 to 14 carbon atoms, and R5 is H or an alkyl group conf~inin.~ 1 to 10 carbon atoms and L can be essentially any leaving group. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be straight chain or branched alkyl cont~inin~ branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for . ~
W O 97/25405 PCTnJS97/00471 example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. R5 is preferably H
or methyl. Rl and R5 should not contain more than 18 carbon atoms in total. Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
Benzoxazin organic peroxyacid precursors Also suitable are pr~cursor compounds of the benzoxazin-type, as disclosed for example in EP-A-332,294 and EP-A-482,807, particularly those having the formula:
~ ,~C--R1 including the substituted benzoxazins of the type R4~ - Rl wherein Rl is H, alkyl, alkaryl, aryl, arylalkyl, and wherein R2, R3, R4, and R5 may be the same or different substituents selected from H, halogen, alkyl, alkenyl, aryl, hydroxyl, alkoxyl, amino, alkyl amino, COOR6 (wherein R6 is H or an alkyl group) and carbonyl functions.
An especially preferred precursor of the benzoxazin-type is:
.
~ ,C~>
Prçformed organic peroxyacid The organic peroxyacid bleaching system may contain, in addition to, or as an alternative to, an organic peroxyacid bleach precursor compound, a preformed organic peroxyacid, typically at a level of from 0.5 % to 25 %
by weight, more preferably from 1% to 10~ by weight of the composition.
A preferred class of organic peroxyacid compounds are the amide substituted compounds of the following general formulae:
O R5 O or R5 O O
wherein Rl is an alkyl, aryl or alkaryl group with from 1 to 14 carbon atoms, R2 is an aLkylene, arylene, and alkarylene group cont~ining from 1 to 14 carbon atorns, and R5 is H or an aLkyl, aryl, or alkaryl group conf~ininp 1 to 10 carbon atoms. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be straight chain or branched alkyl, substit~te~l aryl or alkylaryl cont~inin~
branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, aryl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. RS is preferably H or methyl. Rl and R5 should not contain nnore than 18 carbon atoms in total. Amide substituted organic peroxyacid compounds of this type are described in EP-A-0170386.
Other organic peroxyacids include diacyl and tetraacylperoxides, especially diperoxydodecanedioc acid, diperoxytetradecanedioc acid, and diperoxyhexadecanedioc acid. Dibenzoyl peroxide is a preferred organic peroxyacid herein. Mono- and diperazelaic acid, mono- and diperbrassylic acid, and N-phthaloylaminoperoxicaproic acid are also suitable herein.
Additional corrosion inhibitor compound The compositions may contain additional corrosion inhibitors preferably selected from organic silver coating agents, particularly paraffin, nitrogen-cont~ininE corrosion inhibitor compounds and Mn(II) compounds, particularly Mn(II) salts of organic ligands.
Organic silver coating agents are described in PCT Publication No.
WO94/16047 (attorney's docket no. CM497M) and copending UK
Application No. UK 9413729.6 (attorney's docket no. CM750F). Nitrogen-cont~ining corrosion inhibitor compounds are disclosed in copending European Application no. EP 93202095.1 (attorney's docket no. CM571F).
Mn(II) compounds for use in corrosion inhibition are described in copending UK Application No. 9418567.5 (attorney's docket no.
CM719FM) .
C)rpanic silver coatin~ a~ents Organic silver coating agent may be incorporated at a level of from 0.05 %
to 10%, preferably from 0.1 ~o to 5% by weight of the total composition.
The functional role of the silver coating agent is to form 'in use' a protective coating layer on any silverware components of the washload to which the compositions of the invention are being applied. The silver coating agent should hence have a high affinity for attachment to solid silver surfaces, particularly when present in as a component of an aqueous - w~hinp and bleaching solution with which the solid silver surfaces are being treated.
WO 97/2~405 PCT~US97/00471 Suitable organic silver coating agents herein include fatty esters of mono-or polyhydric alcohols having from 1 to about 40 carbon atoms in the hydrocarbon chain.
The fatty acid portion of the fatty ester can be obtained from mono- orpoly-carboxylic acids having from 1 to about 40 carbon atoms in the hydrocarbon chain. Suitable examples of monocarboxylic fatty acids include behenic acid, stearic acid, oleic acid, palmitic acid, myristic acid, lauric acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, lactic acid, glycolic acid and ,~,~'- dihydroxyisobutyric acid.
Examples of suitable polycarboxylic acids include: n-butyl-malonic acid, isocitric acid, citric acid, maleic acid, malic acid and succinic acid.
The fatty alcohol radical in the fatty ester can be represented by mono- or polyhydric alcohols having from 1 to 40 carbon atoms in the hydrocarbon chain. Examples of suitable fatty alcohols include; behenyl, arachidyl, cocoyl, oleyl and lauryl alcohol, ethylene glycol, glycerol, ethanol, isopropanol, vinyl alcohol, diglycerol, xylitol, sucrose, erythritol, pentaerythritol, sorbitol or sorbitan.
Preferably, the fatty acid and/or fatty alcohol group of the fatty ester adjunct material have from 1 to 24 carbon atoms in the alkyl chain.
Preferred fatty esters herein are ethylene glycol, glycerol and sorbitan esters wherein the fatty acid portion of the ester normally comprises a species selected ~rom behenic acid, stearic acid, oleic acid, palmitic acid or myristic acid.
The glycerol esters are also highly preferred. These are the mono-, di- or tri-esters of glycerol and the fatty acids as defined above.
Specific examples of fatty alcohol esters ~or use herein include: stearyl acetate, palmityl di-lactate, cocoyl isobutyrate, oleyl maleate, oleyl dimaleate, and tallowyl proprionate. Fatty acid esters useful herein include: xylitol monop~lmit~te, pentaerythritol monostearate, sucrose W O 97/25405 PCT~US97/00471 monostearate, glycerol monostearate, ethylene glycol monostearate, sorbitan esters. Suitable sorbitan esters include sorbitan monostearate, sorbitan p~lmit~te, sorbitan monolaurate, sorbitan monomyristate, sorbitan monobehenate, sorbitan mono-oleate, sorbitan dilaurate, sorbitan distearate, sorbitan dibehenate, sorbitan dioleate, and also mixed tallowalkyl sorbitan mono- and di-esters.
Glycerol monostearate, glycerol mono-oleate, glycerol monopalmitate, glycerol monobehenate, and glycerol distearate are preferred glycerol esters herein.
Suitable organic silver coating agents include triglycerides, mono or diglycerides, and wholly or partially hydrogenated derivatives thereof, and any mixtures thereof. Suitable sources of fatty acid esters include vegetable and fish oils and ~nim~l fats. Suitable vegetable oils include soy bean oil, cotton seed oil, castor oil, olive oil, peanut oil, safflower oil, sunflower oil, rapeseed oil, grapeseed oil, palm oil and corn oil.
Waxes, including microcrystalline waxes are suitable organic silver coating agents herein. Prerelred waxes have a melting point in the range from about 35~C to about 110~C and comprise generally from 12 to 70 carbon atoms. Preferred are petroleum waxes of the paraffin and microcrystalline type which are composed of long-chain saturated hydrocarbon compounds.
Alginates and gelatin are suitable organic silver coating agents herein.
Dialkyl amine oxides such as C12-C20 methylamine oxide, and dialkyl quaternary ammonium compounds and salts, such as the C12-C20 methylammonium halides are also suitable.
Other suitable organic silver coating agents include certain polymeric materials. Polyvinylpyrrolidones with an average molecular weight of from - 12,000 to 700,000, polyethylene glycols (PEG) with an average molecular weight of from 600 to 10,000, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimid~70le, and cellulose derivatives such W O 97/25405 PCT~US97/00471 as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose are examples of such polymeric materials.
Certain perfume materials, particularly those demonstrating a high substantivity for metallic surfaces, are also useful as the organic silver coating agents herein.
Polymeric soil release agents known to those skilled in the art of form~ ting laundry detergent compositions can be used as the organic silver coating agent herein.
Suitable polymeric soil release agents include those soil release agents having: (a) one or more nonionic hydrophile components consisting essentially of (i) polyoxyethylene segments with a degree of polymerization of at least 2, or (ii) oxypropylene or polyoxypropylene segments with a degree of polymerization of from 2 to 10, wherein said hydrophile segment does not encompass any oxypropylene unit unless it is bonded to ad~acent moieties at each end by ether linkages, or (iii) a mixture of oxyalkylene units comprising oxyethylene and from 1 to about 30 oxypropylene units, said hydrophile segments preferably comprising at least about 25 ~o oxyethy}ene units and more preferably, especially for such components having about 20 to 30 oxypropylene units, at least about 50% oxyethylene units; or (b) one or more hydrophobe components comprising (i) ¢3 oxyalkylene tereph~h~l~te segments, wherein, if said hydrophobe components also comprise oxyethylene terephth~l~te, the ratio of oxyethylene terephth~l~te:C3 oxyalkylene terephthalate units is about 2:1 or lower, (ii) C4-C6 alkylene or oxy C4-C6 alkylene segments, or mixtures therein, (iii) poly (vinyl ester) segments, preferably polyvinyl acetate, having a degree of polymerization of at least 2, or (iv) C1-C4 alkyl ether or C4 hydroxyalkyl ether substituents, or mixtures therein, wherein said substituents are present in the form of C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivatives, or mixtures therein, or a combination of (a) and (b).
~ .
CA 022424l8 l998-07-07 WO 97n5405 PCTAUS97/00471 Typically, the polyoxyethylene segments of (a)(i) will have a degree of polymerization of from about 200, although higher levels can be used, preferably from 3 to about 150, more preferably from 6 to about 100.
Suitable oxy C4-C6 alkylene hydrophobe segments include, but are not limited to, end-caps of polymeric soil release agents such as MO3S(CH2)nOCH2CH2O-, where M is sodium and n is an integer from 4-6, as disclosed in U.S. Patent 4,721,580, issued January 26, 1988 to Gosselink.
Polymeric soil release agents useful herein also include cellulosic derivatives such as hydroxyether cellulosic polymers, copolymeric blocks of ethylene terephtl~ te or propylene terephth~l~te with polyethylene oxide or polypropylene oxide terephth~l~te, and the like. Such agents are commercially available and include hydroxyethers of cellulose such as METHOCEL (Dow). Cellulosic soil release agents for use herein also include those selected from the group consisting of Cl-C4 alkyl and C4 hydroxyalkyl cellulose; see U.S. Patent 4,000,093, issued December 28, 1976 to Nicol, et al.
Soil release agents characterized by poly(vinyl ester) hydrophobe segments include graft copolymers of poly~vinyl ester), e.g., Cl-C6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones, such as polyethylene oxide backbones. See European Patent Application 0 219 048, published April 22, 1987 by Kud, et al.
Another suitable soil release agent is a copolymer having random blocks of ethylene terephth~ e and polyethylene oxide (P~O) terephth~l~te. The molecular weight of this polymeric soil release agent is in the range of from about 25,000 to about 55,000. See U.S. Patent 3,959,230 to Hays, issued May 25, 1976 and U.S. Patent 3,893,929 to R~ lr issued July 8, 1975.
- Another suitable polymeric soil release agent is a polyester with repeat units of ethylene terephthalate units contains 10-15% by weight of ethylene terephth~l~te units together with 90-80% by weight of polyoxyethylene terephth~l~te units, derived from a polyoxyethylene glycol of average rnolecular weight 300-5,000.
Another suitable polymeric soil release agent is a sulfonated product of a subst~nti~lly linear ester oligomer comprised of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and terminal moieties covalently attached to the backbone. These soil release agents are described fully in U.S. Patent 4,968,451, issued November 6, l990 to J.J.
Scheibel and E.P. Gosselink. Other suitable polymeric soil release agents include the tereph~h~l~te polyesters of U.S. Patent 4,711,730, issued December 8, 1987 to Gosselink et al, the anionic end-capped oligomeric esters of U.S. Patent 4,721,580, issued January 26, 1988 to Gosselink, and the block polyester oligomeric compounds of U.S. Patent 4,702,857, issued October 27, 1987 to Gosselink. Other polymeric soil release agents also include the soil release agents of U.S. Patent 4,877,896, issued October 31, 1989 to Maldonado et al, which discloses anionic, especially sulfoarolyl, end-capped terephth~1~te esters.
Another soil release agent is an oligomer with repeat units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably termin~ted with modified isethionate end-caps. A particularly preferred soil release agent of this type comprises about one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy and oxy-1,2-propyleneoxy units in a ratio of from about 1.7 to about 1.8, and two end-cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate.
A preferred organic silver coating agent is a paraffin oil, typically apredomin~ntly branched aliphatic hydrocarbon having a number of carbon atoms in the range of from 20 to 50; preferred paraffin oil selected from predomin~ntly branched C2s 45 species with a ratio of cyclic to noncyclic hydrocarbons of from 1:10 to 2:1, preferably from 1:5 to 1:1. A paraffin oil meeting these characteristics, having a ratio of cyclic to noncyclic hydrocarbons of about 32:68, is sold by Wintershall, Salzbergen, Germany, under the trade name WINOG 70.
W O g7/25405 PCTrUS97100471 Nitrogen-cont~inin~ corrosion inhibitor compounds Suitable nitrogen-cont~inin~ corrosion inhibitor compounds include imi(l~7ole and derivatives thereof such as ben~imi(l~7ole, 2-heptadecyl im~ 7ole and those imi~l~7ole derivatives described in Czech Patent No. 139, 279 and British Patent GB-A-1,137,741, which also disc~oses a method for m~kin~ imicl~ole compounds.
Also suitable as nitrogen-cont~inin~ corrosion inhibitor compounds are pyrazole compounds and their derivatives, particularly those where the pyrazole is substituted in any of the 1, 3, 4 or 5 positions by substituents Rl, R3, R4 and Rs where Rl is any of H, CH20H, CONH3, or COCH3, R3 and Rs are any of C1-C20 alkyl or hydroxyl, and R4 is any of H, NH2 or N02.
Other suitable nitrogen-cont~inin corrosion inhibitor compounds include benzotriazole, 2-mercaptobenzothiazole, 1-phenyl-5-mercapto-1,2,3,4-tetrazole, thionalide, morpholine, melamine, c~icte~rylamine, stearoyl stearamide, cyanuric acid, aminotriazole, aminotetrazole and indazole.
Nitrogen-cont~inin~ compounds such as amines, especially distearyl~mine and ammonium compounds such as ammonium chloride, ammonium bromide, ammonium sulphate or ~ mmonium hydrogen citrate are also suitable.
Mn(II) corrosion inhibltor compounds The compositions may contain an Mn(II) corrosion inhibitor compound.
The MnaI) compound is preferably incorporated at a level of from 0.005 %
to 5 % by weight, more preferably from 0.01 % to 1%, most preferably from 0.02% to 0.4% by weight of the compositions. Preferably, the Mn(II) compound is incorporated at a level to provide from 0.1 ppm to 250 ppm, WO 97/2540S PCTrUS97/00471 more preferably from 0.5 pprn to 50 ppm, most preferably from 1 ppm to 20 ppm by weight of Mn(II) ions in any bleaching solution.
The Mn (II) compound may be an inorganic salt in anhydrous, or any hydrated forms. Suitable salts include m~n~ne.se sulphate, m~n~nese carbonate, m~n~nese phosphate, m~n~nese nitrate, manganese acetate and m~n~nese chloride. The Mn(II3 compound may be a salt or complex of an organic fatty acid such as m~n~nese acetate or m~ng~nese stearate.
The Mn(II) compound may be a salt or complex of an organic liga.nd. In one prer~r,ed aspect the organic ligand is a heavy metal ion sequestrant. In another preferred aspect the organic ligand is a crystal growth inhibitor.
Other corrosion inhibitor compounds Other suitable additional corrosion inhibitor compounds include, mercaptans and diols, especially mercaptans with 4 to 20 carbon atoms including lauryl mercaptan, thiophenol, thionapthol, thionalide and thioanthranol. Also suitable are saturated or llns~ rated Clo-C20 fatty acids, or their salts, especially aluminium tristearate. The C12-C20 hydroxy fatty acids, or their salts, are also suitable. Phosphonated octa-~lec~ne and other anti-oxidants such as betahydroxytoluene (BHT) are also suitable.
C~opolymers of butadiene and maleic acid, particularly those supplied under the trade reference no. 07787 by Polysciences Inc have been found to be of particular utility as corrosion inhibitor compounds.
Total Available Oxy~en (AvO) Level It has been found that, for optimal anti-silver tarni~hinf~ performance, the level of available oxygen in the present compositions, measured in units of % available oxygen by weight of the composition, is preferably controlled;
the level of available oxygen should hence preferably be in the range from W O 97/25405 PCT~US97/00471 0.3% to 2.5%, preferably from 0.5% to 1.7%, more preferably from 0.6%
to 1.5%, most preferably from 0.75~ to 1.2%, measured according to the method described hereunder.
Rate of Release of AvO
The rate of release of available oxygen is preferably also controlled; the rate of release of available oxygen from the compositions herein preferably should be such that, when using the method described hereinafter, the available oxygen is not completely released from the composition until after 3.5 minutes, preferably the available oxygen is released in a time interval of from 3.5 minutes to 10.0 mimltes, more preferably from 4.0 minutes to 9.0 minutes, most preferably from 5.0 minutes to 8.5 minutes.
Method for Measurin Level of Total Available Oxygen (AvO) and Rate of Release of AvO in a Deter~ent Composition Method 1. A beaker of water (typically 2L) is placed on a stirrer Hotplate, and the stirrer speed is selected to ensure that the product is evenly dispersed through the solution.
2. The detergent composition (typically 8g of product which has been sampled down from a bulk supply using a Pascal sampler), is added and simultaneously a stop clock is started.
3. The temperature control should be adjusted so as to m~int~in a constant temperature of 20~C throughout the experiment.
Technical Field The present invention relates to bi~mnth diphosphonate compounds and methods of m~kin~ such compounds and their use in oxygen-bleach cont~inin~ compositions, adapted for use in machine dishwashing, which exhibit good bleachable stain removal and reduced silver-tarni~hir~
properties.
B~çk~round to the Invention ~ompositions designed for use in automatic dishwasher machines are well known, and a consistent effort has been made by detergent m~nllf~cturers to improve the cleaning and/or rinsing efficiency of said compositions on chinaware, glassware and silverware, as reflected by numerous patent publications.
The satisfactory removal of bleachable soils such as tea, fruit juice and coloured vegetable soils, such as carotenoid soils is a particular challenge to the formulator of a machine dishwashing composition. Traditionally, the removal of such soils has been enabled by the use of bleach components such as oxygen and chlorine bleaches.
A problem encountered with the use of oxygen bleaches, in particular, is the tarni~hing of any silverware components of the washload. Chlorine bleaches can under certain circumstances give rise to silver tarni~hin~, but " the problem is significantly less pronounced than that arising from the use of oxygen bleaches. The level of tarni~hinP observed with oxygen bleaches can range from slight discolouration of the silverware to the formation of a dense black coating on the surface of the silverware.
. CA 02242418 1998-07-07 W O 97~5405 PCTAUS97/00471 The formulator thus faces the dual challenge of form~ tin~ an oxygen bleach cont~ining product which maximises bleachable soil cleaning but minimiceS the occurrence of tarni~hinr~ of any silverware components of the washload.
It has been surprisingly found that reduced silver tarnishing as well as good cle~nin~ performance can be achieved through the inclusion in an oxygen bleach cont~inin~ formulation of certain bism~lth diphosphonate compounds. These compounds also demonstrate good 'in product' storage stability characteristics.
It has also been found that the presence of water-soluble sulphate salts surprisingly enhances the silver tarnish inhibition capability of the bi~m~
diphosphonate compound. In particular excellent results are obtained when - a particle, formed for example, by agglomeration methods, comprising both sulphate and bismuth diphosphonate compound components is employed.
To further reduce the occurence of silver tarni~hing, the rate of release of the oxygen bleach is preferably also controlled. The rate of release of oxygen bleach is preferably rapid enough to provide satisfactory cleaning, but not so rapid that tarnishing is enabled.
Compositions having low ~lk~linity, and in particular those having ~lk~linity systems including a minor proportion of a metasilicate component are preferred, as are compositions having a pH which is not unduly high.
UK Patent Specif~cation No. 1,586,067 in the name of the Procter and Gamble Company, discloses automatic dishwashing compositions cont~ininf~: bismuth salts to provide protection to china overglaze without any negative glassware irridescence effects. Bi.~mllth diphosphonate compounds are not explicitly described. It is taught therein that chlorine bleaching agents are preferable components of these compositions and specific examples of chlorine containing compositions are given. The use of oxygen bleaches in such compositions is not disclosed. The problem of W O 97/25405 PCT~US97/00471 silver tarni~hin~ is not addressed by this document, nor is any teaching provided of the use of bismuth salts as silver tarnish inhibition agents.
Sllmm~ry of the Invention There is provided a bismuth diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1:0.7 to l :7.
There is additionally provided a process for m~kin~ an ~lk~line bismuthdiphosphonate solution comprising the following steps:
(i) formation of an ~lk~line solution cont~inin~ a diphosphonate species;
(ii) agitatative addition of a solution cont~ininf~ bismuth ions to said ~lk:~lin~
solution wherein the amount of bismuth to diphosphonate species corresponds to a molar ratio of from 1:0.7 to 1:7.
Said bismuth diphosphonate solution can be sprayed onto a bleaching composition to form a bleaching product. In a preferred aspect, the bleaching composition also contains detergent components.
There is further provided a process for m~kinp a bismuth disphosphonatecont~inin~ particle by agglomeration of an inorganic salt cont~inin~ an anion capable of forming a salt, preferably an insoluble salt, with bismuth with an ~lk~line bismuth diphosphonate solution, and optionally an organic binder, preferably an organic polymeric compound.
There are also provided bleaching and detergent compositions, adapted for use in machine dishwashing methods, cont~ining an oxygen-releasing bleaching system and bismuth diphosphonate compound. In a preferred aspect the detergent compositions contain no phosphate builder compound.
- WO 97/25405 PCT~US97/00471 Detailed ~escription Qf the Invention Bismuth diphosphonate compound According to one aspect of the present invention there is provided a bi.~mlltll diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1 :0.7 to 1 :7, preferably from 1: 1 to 1:6, more preferably from 1:2 to 1:5.
The bismuth diphosphonate compound may be essentially any salt or complex of bismuth with essentially any organic diphosphonic acid. By organo diphosphonic acid it is meant herein an organo diphosphonic acid which does not contain nitrogen as part of its chemical structure. This definition therefore excludes the organo aminophosphonates, which however may be included in any compositions in accord with the invention as heavy metal ion sequestrant components.
The organo diphosphonic acid is preferably a Cl-C4 diphosphonic acid, more preferably a C2 diphosphonic acid, such as ethylene diphosphonic acid, or most preferably ethane l-hydroxy-l,l-diphosphonic acid (HEDP) and may be present in partially or fully ionized form, particularly as a salt or complex.
The compound cont~ining bismuth and HEDP at a 1:3.5 molar ratio is mostpreferred.
Process for m~kin~ a bismuth diphosphonate solution According to another aspect of the present invention there is provided a step-wise process for making a bi.cm~th diphosphonate solution in~rolving seq~enti~lly the formation of an ~lk~line solution cont~inin~ a diphosphonate species followed by addition of a solution cont~inin~
bismuth ions. This solution has been found to be both storage and transport stable, and may be employed in the m~kin~ of bleaching and/or detergent compositions, as described hereinafter.
The advantage provided by the step-wise process versus a process in which both steps take place concurrently is that, in the latter case, a heavy yellow essentially insoluble precipitate, believed to be bismuth hydroxide, is formed. This precipitate impedes the further processing of the solution, and limits its usefulness in the making of bleaching and/or detergent compositions.
The process comprises as a first step the formation of an ~lk~line solution cont~inin~ a diphosphonate species. The ~lk~line solution may for example, be formed by direct addition, preferably with agitation, of a diphosphonic acid to an aqueous ~lk~line solution, such as NaOH solution. In a preferred aspect said addition is continuous, but carried out at a relatively slow rate such as to avoid excess generation of heat from the neutralization reaction.
The process has as a second step the agitative addition of a solution cont~ining bismuth ions to the ~lk~line solution cont~inin~ the diphosphonate species. By agitative addition it is meant addition in the presence of some means of agitation, such as may be provided by carrying out the addition in a mixer apparatus. The solution cont~ininp bismuth ions may comprise a solution of any suitable salt or complex of bismuth with essentially any inorganic or organic counter anion. Preferred inorganic bismuth salts for use in m~kinp up the solution are selected from the bismuth trihalides, bismuth nitrate and bismuth phosphate. Bi~mllth acetate and citrate are preferred salts with an organic counter anion.
The amount of ~lk~line diphosphonate and bismuth ion solutions employed in this process aspect is adjusted such as to result in the formation of a bismuth diphosphonate solution having a molar ratio of bismuth to diphosphonate species of from 1:0.7 to 1:7.
~, The bismuth diphosphonate solution can be sprayed onto a bleaching composition to form a bleaching product. In a preferred aspect, the bleaching composition also contains detergent components, and the bi.~mllfh O 97/25405 PCT~US97/00471 diphosphonate solution is thus sprayed onto both bleaching and detergent components.
Rismuth diphosphonate ~gplomerate particle According to another aspect of the invention there is provided a process for m~kinp a bismuth disphosphonate-cont~ininP particle by agglomeration of an inorganic salt with an ~lk~line bismuth diphosphonate solution preferably obtained by the process described hereinabove. The inorganic salt comprises an anion capable of forming a salt, especially an insoluble salt, with bi~mlltll The advantage provided by the use of an ~lk~line rather than neutral, or acidic bismuth diphosphonate solution in the agglomeration step is that the llnt1e~irable ~ormation of (other) bismuth salts, particularly insoluble ones, is prevented.
The ~lk~line. diphosphonate solution preferably has a pH of at least 9.0, more preferably at least 10Ø
The inorganic salt may be essentially any salt of an inorganic anion capable also of forming a bismuth salt, such as sulfates, carbonates and phosphates with any counter cation, including the alkali and ~lk~line earth metals.
Preferred salts are selected from the sulfates of the alkali and ~lk~line earth metals, particularly sodium sulfate.
The weight ratio of the inorganic salt to bismuth diphosphonate compound in the particle is preferably from 200:1 to 2:1, more preferably from 100:1 to 5:1, most preferably from 50:1 to 10:1.
In a preferred aspect the particle comprises an organic binder material. The organic binder material is preferably selected from any of the organic polymeric compounds described in detail hereinafter, and any mixtures thereof.
CA 022424l8 l998-07-07 W O 97i25405 PCT~US97/00471 Other suitable binders include the Clo-C20 alcohol ethoxylates cont~inin~
from ~ - 100 moles of ethylene oxide per mole of alcohol and more preferably the Cls-C20 primary alcohol ethoxylates cont~ining from 20 -100 moles of ethylene oxide per mole of alcohol. Polyvinylpyrrolidones with an average molecular weight of from 12,000 to 700,000 and polyethylene glycols (PEG) with an average molecular weight of from 600 to S x 106 preferably 10~)0 to 400,000 most preferably 1000 to 10,0(~0 are also suitable binders. Cellulose derivatives such as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose, and homo- or co-polymeric polycarboxylic acids or their salts are other examples of binders suitable for use herein.
The agglomeration method employed can be any of those known in the art.
Any conventional agglomerator/mixer may be used including, but not limited to pan, rotary drum and vertical blender types. Mixers sold by Schugi (tradename) and Lodige (tradename) for use in agglomeration methods are particularly suitable. Agglomeration processes employing 'in series' combinations of mixers are also envisaged.
Bleachin~ compositions The bismuth diphosphonate compounds and particles cont~ininP such compounds described hereinbefore may be incorporated into compositions cont~inin~ an oxygen-releasing bleaching system.
Oxy en-releasing bleaching system In one preferred aspect the bleaching system contains a hydrogen peroxide source and an organic peroxyacid bleach precursor compound. The production of the organic peroxyacid occurs by an in situ reaction of the precursor with a source of hydrogen peroxide. Preferred sources of hydrogen peroxide include inorganic perhydrate bleaches. In an alternative preferred aspect a preformed organic peroxyacid is incorporated directly into the composition. Compositions cont~ining mixtures of a hydrogen W O 97/2540~ PCT~US97/00471 -peroxide source and organic peroxyacid precursor in combination with a pre~ormed organic peroxyacid are also envisaged.
Inor~anic perhydrate bleaches The compositions in accord with the invention preferably include a hydrogen peroxide source, as an oxygen-releasing bleach. Suitable hydrogen peroxide sources include the inorganic perhydrate salts.
The inorganic perhydrate salts are normally incorporated in the form of the sodium salt at a level of from 1% to 40~ by weight, more preferably from 2% to 3(~% by weight and most preferably from 5% to 25% by weight of the coInpositions.
Examples of inorganic perhydrate salts include perborate, percarbonate, perphosphate, persulfate and persilicate salts. The inorganic perhydrate salts are normally the alkali metal salts. The inorganic perhydrate salt may be included as the crystalline solid without additional protection. For certain perhydrate salts however, the preferred executions of such granular compositions utilize a coated form of the material which provides better storage stability for the perhydrate salt in the granular product.
Sodium perborate can be in the form of the monohydrate of nominal formula NaB02H202 or the tetrahydrate NaB02H202.3H20.
Alkali metal percarbonates, particularly sodium percarbonate are preferred perhydrates for inclusion in compositions in accordance with the invention.
Sodium percarbonate is an addition compound having a formula corresponding to 2Na2C03.3H202, and is available commercially as a crystalline solid. Sodium percarbonate, being a hydrogen peroxide addition compound tends on dissolution to release the hydrogen peroxide quite rapidly which can increase the tendency for localised high bleach concentrations to arise. The percarbonate is most pre~erably incorporated into such compositions in a coa~ed form which provides in product stability.
W O 97/254Q5 PCT~US97/00471 A suitable coating material providing in product stability comprises mixed salt of a water soluble alkali metal sulphate and carbonate. Such coatings together with coating processes have previously been described in GB-1,46~,799, granted to Interox on 9th March 1977. The weight ratio of the mixed salt coating material to percarbonate lies in the range ~rom 1: 200 to 1: 4, more preferably from 1: 99 to 1: 9, and most preferably from 1:
49 to 1: 19. Preferably, the mixed salt is of sodium sulphate and sodium carbonate which has the general formula Na2SO4.n.Na2~O3 wherein n is from 0.1 to 3, preferably n is from 0.3 to 1.0 and most preferably n is from 0.2 to 0.5.
Other coatings which contain silicate (alone or with borate salts or boric acids or other inorganics), waxes, oils, fatty soaps can also be used advantageously within the present invention.
Potassium peroxymonopersulfate is another inorganic perhydrate salt ofutility in the compositions herein.
Peroxyacid bleach precursor Peroxyacid bleach precursors are compounds which react with hydrogen peroxide in a perhydrolysis reaction to produce a peroxyacid. Generally peroxyacid bleach precursors may be represented as o Il x-C--L
where L is a leaving group and X is essentially any functionality, such that on perhydroloysis the structure of the peroxyacid produced is ..
x--C-OOH
Peroxyacid bleach precursor compounds are preferably incorporated at a level of from 0.5~o to 20~o by weight, more preferably from 1 % to 10%
by weight, most preferably from 1.5% to 5% by weight of the compositions.
Suitable peroxyacid bleach precursor compounds typically contain one ormore N- or O-acyl groups, which precursors can be selected from a wide range of classes. Suitable classes include anhydrides, esters, imides, lactams and acylated derivatives of imidazoles and oximes. Examples of useful materials within these classes are disclosed in GB-A-15867~39.
Suitable esters are disclosed in GB-A-836988, 864798, 1147871, 2143231 and EP-A-0170386.
W 097/25405 PCT~US97/00471 Leavin~ roups The leaving group, hereinafter L group, must be sufficiently reactive for the perhydrolysis reaction to occur within the o~ lum time frame (e.g., a wash cycle). However, if L is too reactive, this activator will be difficult to stabilize for use in a bleaching composition.
PrefelLed L groups are selected from the group consisting of:
_o~, o~Y, and --~~
1 3 L=l ' R3 Y
lR3 r --O--CH=C--CH=CH2--O--CH=C--CH=CH2 -O--C--R1 _N/ NR4 ~C~NR4 O O
--O--C=CHR4 , andIN i--CH--R4 R3 o and mixtures thereof, wherein Rl is an alkyl, aryl, or alkaryl group cont~ininf~ from 1 to 14 carbon atoms, R3 is an alkyl chain cont~inin~ from 1 to 8 carbon atoms, R4 is H or R3, and Y is H or a solubilizing group.
Any of Rl, R3 and R4 may be substituted by essentially any functional group including, for example alkyl, hydroxy, alkoxy, halogen, amine, nitrosyl, amide and ammonium or alkyl ~mmmonium groups The ~re~l 1 ed solubilizing groups are -S03-M +, -C02-M +, -S04-M ~, -N+(R3)~X- and O < --N(R3)3 and most preferably -S03-M + and -C~2 M wherein R is an alkyl chain cont~inin~ from 1 to 4 carbon atoms, M is a cation which provides solubility to the bleach activator and X
is an anion which provides solubility to the bleach activator. Preferably, M
is an alkali metal, ammonium or substihlte-l ammonium cation, with sodium and potassium being most preferred, and X is a halide, hydroxide, methylsulfate or acetate anion.
Perbenzoic acid precursor Perbenzoic acid precursor compounds provide perbenzoic acid on perhydrolysis.
Suitable O-acylated perbenzoic acid precursor compounds include the substituted and unsubstituted benzoyl oxybenzene sulfonates, including for example benzoyl oxybenzene sulfonate:
o (~o4~3So3-Also suitable are the benzoylation products of sorbitol, glucose, and all saccharides with benzoylating agents, including for example:
W O 97/25405 PCT~US97/00471 OAc AcO ~Lo ~,OAc - / OAc OBz Ac = COCH3; Bz = Benzoyl Perbenzoic acid precursor compounds of the imide type include N-benzoyl succinimide, tetrabenzoyl ethylene ~ mine and the N-benzoyl substituted ureas. Suitable imidazole type perbenzoic acid precursors include N-benzoyl imid~7.ole and N-benzoyl benzimidazole and other useful N-acyl group-cont~ining perbenzoic acid precursors include N-ben_oyl pyrrolidone, dibenzoyl taurine and benzoyl pyroglutamic acid.
Other perbenzoic acid precursors include the benzoyl diacyl peroxides, the benzoyl tetraacyl peroxides, and the compound having the formula:
O O
[~0'~1~O--COOH
Phthalic anhydride is another suitable perbenzoic acid precursor compound herein:
~0 ., O
Suitable N-acylated lactam perbenzoic acid precursors have the formula:
W O 97/25405 PCT~US97/00471 R6--C ~
wherein n is from O to 8, preferably from O to 2, and R6 is a benzoyl group.
Perbenzoic acid derivative precursors Perbenzoic acid derivative precursors provide substituted perbenzoic acids on perhydrolysis.
Suitable substituted perbenzoic acid derivative precursors include any of the herein disclosed perbenzoic precursors in which the benzoyl group is substituted by essentially any non-positively charged (ie; non-cationic) functional group including, for example alkyl, hydroxy, alkoxy, halogen, amine, nitrosyl and amide groups.
A preferred class of substituted perbenzoic acid precursor compounds are the amide substituted compounds of the following general formulae:
O R5 0 or R5 O O
wherein R~ is an aryl or alkaryl group with from 1 to 14 carbon atoms, R2 is an arylene, or alkarylene group cont~ining from 1 to 1~ carbon atoms, and R5 is H or an alkyl, aryl, or alkaryl group cont~ining 1 to 10 carbon atoms and L can be essentially any leaving group. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be aryl, substituted aryl or alkylaryl cont~inin~ branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, aryl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. R5 is preferably H or methyl. Rl and R5 should not contain more than 18 carbon atoms in total. Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
Cationic peroxyacid precursors Cationic peroxyac;d precursor compounds produce cationic peroxyacids on perhydrolysis.
W O 97/25405 PCT~US97/00471 Typically, cationic peroxyacid precursors are formed by substituting the peroxyacid part of a suitable peroxyacid precursor compound with a positively charged functional group, such as an ammonium or alkyl mmmonium group, preferably an ethyl or methyl ammonium group.
Cationic peroxyacid precursors are typically present in the compositions as a salt with a suitable anion, such as for example a halide ion or a methylsulfate ion.
The peroxyacid precursor compound to be so cationically substituted maybe a perbenzoic acid, or substituted derivative thereof, precursor compound as described hereinbefore. Alternatively, the peroxyacid precursor compound may be an alkyl percarboxylic acid precursor compound or an amide substituted alkyl peroxyacid precursor as described hereinafter Cationic peroxyacid precursors are described in U.S. Patents 4,904,406;4,751,015; 4,988,451; 4,397,7~7; 5,269,962; 5,127,852; 5,093,0~2;
5,106,528; U.K. 1,382,594; EP 475,512, 458,396 and 284,292; a~nd in JP
87-318,332.
Examples of preferred cationic peroxyacid precursors are described in UK
Patent Application No. 9407944.9 (attorney's docket no. CM642F~ and US
Patent Application Nos. 08/298903, 08/298650, 0~/298904 and 08/298906 (attorney's docket no.s 5413 to 5416).
Suitable cationic peroxyacid precursors include any of the ammonium or alkyl ammonium substituted alkyl or benzoyl oxybenzene sulfonates, N-acylated caprol~ct~m~, and monobenzoyltetraacetyl glucose benzoyl peroxides.
A preferred cationically substituted benzoyl oxybenzene sulfonate is the 4-(trimethyl ammonium) methyl derivative of benzoyl oxybenzene sulfonate:
W O 97/25405 PCT~US97/00471 ~ ,_~o~S~3-\N+
/ ~
A preferred cationically substituted alkyl oxybenzene sulfonate has the formula:
~/ N ~ ~0~
Preferred cationic peroxyacid precursors of the N-acylated caprolactam class include the trialkyl ammonium methylene benzoyl caprolactams, particularly trimethyl ammonium methylene benzoyl caprolactam:
,~,J~ N
Other preferred cationic peroxyacid precursors of the N-acylated caprolactam class include the trialkyl ammonium methylene alkyl caprolactams:
O o )~N~
+~(CH2~n where n is from 0 to 12, particularly from 1 to 5.
W O 97/25405 PCT~US97/00471 Another preferred cationic peroxyacid precursor is 2-(N,N,N-trimethyl ammonium) ethyl sodium 4-sulphophenyl carbonate chloride.
Alkyl percarboxylic acid bleach precursors Alkyl percarboxylic acid bleach precursors form percarboxylic acids on perhydrolysis. Preferred precursors of this type provide peracetic acid on perhydrolysis.
Preferred alkyl percarboxylic precursor compounds of the imide type include the N-,N,NlNl tetra acetylated alkylene ~ mines wherein the alkylene group contains from 1 to 6 carbon atoms, particularly those compounds in which the alkylene group contains 1, 2 and 6 carbon atoms.
Tetraacetyl ethylene rli~mine ~I'AED) is particularly preferred.
Other preferred alkyl percarboxylic acid precursors include sodiunn 3,5,5-tri-methyl hexanoyloxybenzene sulfonate (iso-NOBS), sodium nonanoyloxybenzene sulfonate (NOBS), sodium acetoxybenzene sulfonate (ABS) and pentaacetyl glucose.
A~nide substituted alkyl peroxyacid precursors Amide substituted alkyl peroxyacid precursor compounds are also suitable, including those of the following general formulae:
Il l 11 1 11 11 O R5 O or R5 O O
wherein Rl is an alkyl group with from 1 to 14 carbon atoms, R2 is an alkylene group cont~inin~ from 1 to 14 carbon atoms, and R5 is H or an alkyl group conf~inin.~ 1 to 10 carbon atoms and L can be essentially any leaving group. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be straight chain or branched alkyl cont~inin~ branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for . ~
W O 97/25405 PCTnJS97/00471 example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. R5 is preferably H
or methyl. Rl and R5 should not contain more than 18 carbon atoms in total. Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
Benzoxazin organic peroxyacid precursors Also suitable are pr~cursor compounds of the benzoxazin-type, as disclosed for example in EP-A-332,294 and EP-A-482,807, particularly those having the formula:
~ ,~C--R1 including the substituted benzoxazins of the type R4~ - Rl wherein Rl is H, alkyl, alkaryl, aryl, arylalkyl, and wherein R2, R3, R4, and R5 may be the same or different substituents selected from H, halogen, alkyl, alkenyl, aryl, hydroxyl, alkoxyl, amino, alkyl amino, COOR6 (wherein R6 is H or an alkyl group) and carbonyl functions.
An especially preferred precursor of the benzoxazin-type is:
.
~ ,C~>
Prçformed organic peroxyacid The organic peroxyacid bleaching system may contain, in addition to, or as an alternative to, an organic peroxyacid bleach precursor compound, a preformed organic peroxyacid, typically at a level of from 0.5 % to 25 %
by weight, more preferably from 1% to 10~ by weight of the composition.
A preferred class of organic peroxyacid compounds are the amide substituted compounds of the following general formulae:
O R5 O or R5 O O
wherein Rl is an alkyl, aryl or alkaryl group with from 1 to 14 carbon atoms, R2 is an aLkylene, arylene, and alkarylene group cont~ining from 1 to 14 carbon atorns, and R5 is H or an aLkyl, aryl, or alkaryl group conf~ininp 1 to 10 carbon atoms. Rl preferably contains from 6 to 12 carbon atoms. R2 preferably contains from 4 to 8 carbon atoms. Rl may be straight chain or branched alkyl, substit~te~l aryl or alkylaryl cont~inin~
branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat. Analogous structural variations are permissible for R2. The substitution can include alkyl, aryl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds. RS is preferably H or methyl. Rl and R5 should not contain nnore than 18 carbon atoms in total. Amide substituted organic peroxyacid compounds of this type are described in EP-A-0170386.
Other organic peroxyacids include diacyl and tetraacylperoxides, especially diperoxydodecanedioc acid, diperoxytetradecanedioc acid, and diperoxyhexadecanedioc acid. Dibenzoyl peroxide is a preferred organic peroxyacid herein. Mono- and diperazelaic acid, mono- and diperbrassylic acid, and N-phthaloylaminoperoxicaproic acid are also suitable herein.
Additional corrosion inhibitor compound The compositions may contain additional corrosion inhibitors preferably selected from organic silver coating agents, particularly paraffin, nitrogen-cont~ininE corrosion inhibitor compounds and Mn(II) compounds, particularly Mn(II) salts of organic ligands.
Organic silver coating agents are described in PCT Publication No.
WO94/16047 (attorney's docket no. CM497M) and copending UK
Application No. UK 9413729.6 (attorney's docket no. CM750F). Nitrogen-cont~ining corrosion inhibitor compounds are disclosed in copending European Application no. EP 93202095.1 (attorney's docket no. CM571F).
Mn(II) compounds for use in corrosion inhibition are described in copending UK Application No. 9418567.5 (attorney's docket no.
CM719FM) .
C)rpanic silver coatin~ a~ents Organic silver coating agent may be incorporated at a level of from 0.05 %
to 10%, preferably from 0.1 ~o to 5% by weight of the total composition.
The functional role of the silver coating agent is to form 'in use' a protective coating layer on any silverware components of the washload to which the compositions of the invention are being applied. The silver coating agent should hence have a high affinity for attachment to solid silver surfaces, particularly when present in as a component of an aqueous - w~hinp and bleaching solution with which the solid silver surfaces are being treated.
WO 97/2~405 PCT~US97/00471 Suitable organic silver coating agents herein include fatty esters of mono-or polyhydric alcohols having from 1 to about 40 carbon atoms in the hydrocarbon chain.
The fatty acid portion of the fatty ester can be obtained from mono- orpoly-carboxylic acids having from 1 to about 40 carbon atoms in the hydrocarbon chain. Suitable examples of monocarboxylic fatty acids include behenic acid, stearic acid, oleic acid, palmitic acid, myristic acid, lauric acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, lactic acid, glycolic acid and ,~,~'- dihydroxyisobutyric acid.
Examples of suitable polycarboxylic acids include: n-butyl-malonic acid, isocitric acid, citric acid, maleic acid, malic acid and succinic acid.
The fatty alcohol radical in the fatty ester can be represented by mono- or polyhydric alcohols having from 1 to 40 carbon atoms in the hydrocarbon chain. Examples of suitable fatty alcohols include; behenyl, arachidyl, cocoyl, oleyl and lauryl alcohol, ethylene glycol, glycerol, ethanol, isopropanol, vinyl alcohol, diglycerol, xylitol, sucrose, erythritol, pentaerythritol, sorbitol or sorbitan.
Preferably, the fatty acid and/or fatty alcohol group of the fatty ester adjunct material have from 1 to 24 carbon atoms in the alkyl chain.
Preferred fatty esters herein are ethylene glycol, glycerol and sorbitan esters wherein the fatty acid portion of the ester normally comprises a species selected ~rom behenic acid, stearic acid, oleic acid, palmitic acid or myristic acid.
The glycerol esters are also highly preferred. These are the mono-, di- or tri-esters of glycerol and the fatty acids as defined above.
Specific examples of fatty alcohol esters ~or use herein include: stearyl acetate, palmityl di-lactate, cocoyl isobutyrate, oleyl maleate, oleyl dimaleate, and tallowyl proprionate. Fatty acid esters useful herein include: xylitol monop~lmit~te, pentaerythritol monostearate, sucrose W O 97/25405 PCT~US97/00471 monostearate, glycerol monostearate, ethylene glycol monostearate, sorbitan esters. Suitable sorbitan esters include sorbitan monostearate, sorbitan p~lmit~te, sorbitan monolaurate, sorbitan monomyristate, sorbitan monobehenate, sorbitan mono-oleate, sorbitan dilaurate, sorbitan distearate, sorbitan dibehenate, sorbitan dioleate, and also mixed tallowalkyl sorbitan mono- and di-esters.
Glycerol monostearate, glycerol mono-oleate, glycerol monopalmitate, glycerol monobehenate, and glycerol distearate are preferred glycerol esters herein.
Suitable organic silver coating agents include triglycerides, mono or diglycerides, and wholly or partially hydrogenated derivatives thereof, and any mixtures thereof. Suitable sources of fatty acid esters include vegetable and fish oils and ~nim~l fats. Suitable vegetable oils include soy bean oil, cotton seed oil, castor oil, olive oil, peanut oil, safflower oil, sunflower oil, rapeseed oil, grapeseed oil, palm oil and corn oil.
Waxes, including microcrystalline waxes are suitable organic silver coating agents herein. Prerelred waxes have a melting point in the range from about 35~C to about 110~C and comprise generally from 12 to 70 carbon atoms. Preferred are petroleum waxes of the paraffin and microcrystalline type which are composed of long-chain saturated hydrocarbon compounds.
Alginates and gelatin are suitable organic silver coating agents herein.
Dialkyl amine oxides such as C12-C20 methylamine oxide, and dialkyl quaternary ammonium compounds and salts, such as the C12-C20 methylammonium halides are also suitable.
Other suitable organic silver coating agents include certain polymeric materials. Polyvinylpyrrolidones with an average molecular weight of from - 12,000 to 700,000, polyethylene glycols (PEG) with an average molecular weight of from 600 to 10,000, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimid~70le, and cellulose derivatives such W O 97/25405 PCT~US97/00471 as methylcellulose, carboxymethylcellulose and hydroxyethylcellulose are examples of such polymeric materials.
Certain perfume materials, particularly those demonstrating a high substantivity for metallic surfaces, are also useful as the organic silver coating agents herein.
Polymeric soil release agents known to those skilled in the art of form~ ting laundry detergent compositions can be used as the organic silver coating agent herein.
Suitable polymeric soil release agents include those soil release agents having: (a) one or more nonionic hydrophile components consisting essentially of (i) polyoxyethylene segments with a degree of polymerization of at least 2, or (ii) oxypropylene or polyoxypropylene segments with a degree of polymerization of from 2 to 10, wherein said hydrophile segment does not encompass any oxypropylene unit unless it is bonded to ad~acent moieties at each end by ether linkages, or (iii) a mixture of oxyalkylene units comprising oxyethylene and from 1 to about 30 oxypropylene units, said hydrophile segments preferably comprising at least about 25 ~o oxyethy}ene units and more preferably, especially for such components having about 20 to 30 oxypropylene units, at least about 50% oxyethylene units; or (b) one or more hydrophobe components comprising (i) ¢3 oxyalkylene tereph~h~l~te segments, wherein, if said hydrophobe components also comprise oxyethylene terephth~l~te, the ratio of oxyethylene terephth~l~te:C3 oxyalkylene terephthalate units is about 2:1 or lower, (ii) C4-C6 alkylene or oxy C4-C6 alkylene segments, or mixtures therein, (iii) poly (vinyl ester) segments, preferably polyvinyl acetate, having a degree of polymerization of at least 2, or (iv) C1-C4 alkyl ether or C4 hydroxyalkyl ether substituents, or mixtures therein, wherein said substituents are present in the form of C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivatives, or mixtures therein, or a combination of (a) and (b).
~ .
CA 022424l8 l998-07-07 WO 97n5405 PCTAUS97/00471 Typically, the polyoxyethylene segments of (a)(i) will have a degree of polymerization of from about 200, although higher levels can be used, preferably from 3 to about 150, more preferably from 6 to about 100.
Suitable oxy C4-C6 alkylene hydrophobe segments include, but are not limited to, end-caps of polymeric soil release agents such as MO3S(CH2)nOCH2CH2O-, where M is sodium and n is an integer from 4-6, as disclosed in U.S. Patent 4,721,580, issued January 26, 1988 to Gosselink.
Polymeric soil release agents useful herein also include cellulosic derivatives such as hydroxyether cellulosic polymers, copolymeric blocks of ethylene terephtl~ te or propylene terephth~l~te with polyethylene oxide or polypropylene oxide terephth~l~te, and the like. Such agents are commercially available and include hydroxyethers of cellulose such as METHOCEL (Dow). Cellulosic soil release agents for use herein also include those selected from the group consisting of Cl-C4 alkyl and C4 hydroxyalkyl cellulose; see U.S. Patent 4,000,093, issued December 28, 1976 to Nicol, et al.
Soil release agents characterized by poly(vinyl ester) hydrophobe segments include graft copolymers of poly~vinyl ester), e.g., Cl-C6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones, such as polyethylene oxide backbones. See European Patent Application 0 219 048, published April 22, 1987 by Kud, et al.
Another suitable soil release agent is a copolymer having random blocks of ethylene terephth~ e and polyethylene oxide (P~O) terephth~l~te. The molecular weight of this polymeric soil release agent is in the range of from about 25,000 to about 55,000. See U.S. Patent 3,959,230 to Hays, issued May 25, 1976 and U.S. Patent 3,893,929 to R~ lr issued July 8, 1975.
- Another suitable polymeric soil release agent is a polyester with repeat units of ethylene terephthalate units contains 10-15% by weight of ethylene terephth~l~te units together with 90-80% by weight of polyoxyethylene terephth~l~te units, derived from a polyoxyethylene glycol of average rnolecular weight 300-5,000.
Another suitable polymeric soil release agent is a sulfonated product of a subst~nti~lly linear ester oligomer comprised of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and terminal moieties covalently attached to the backbone. These soil release agents are described fully in U.S. Patent 4,968,451, issued November 6, l990 to J.J.
Scheibel and E.P. Gosselink. Other suitable polymeric soil release agents include the tereph~h~l~te polyesters of U.S. Patent 4,711,730, issued December 8, 1987 to Gosselink et al, the anionic end-capped oligomeric esters of U.S. Patent 4,721,580, issued January 26, 1988 to Gosselink, and the block polyester oligomeric compounds of U.S. Patent 4,702,857, issued October 27, 1987 to Gosselink. Other polymeric soil release agents also include the soil release agents of U.S. Patent 4,877,896, issued October 31, 1989 to Maldonado et al, which discloses anionic, especially sulfoarolyl, end-capped terephth~1~te esters.
Another soil release agent is an oligomer with repeat units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably termin~ted with modified isethionate end-caps. A particularly preferred soil release agent of this type comprises about one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy and oxy-1,2-propyleneoxy units in a ratio of from about 1.7 to about 1.8, and two end-cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate.
A preferred organic silver coating agent is a paraffin oil, typically apredomin~ntly branched aliphatic hydrocarbon having a number of carbon atoms in the range of from 20 to 50; preferred paraffin oil selected from predomin~ntly branched C2s 45 species with a ratio of cyclic to noncyclic hydrocarbons of from 1:10 to 2:1, preferably from 1:5 to 1:1. A paraffin oil meeting these characteristics, having a ratio of cyclic to noncyclic hydrocarbons of about 32:68, is sold by Wintershall, Salzbergen, Germany, under the trade name WINOG 70.
W O g7/25405 PCTrUS97100471 Nitrogen-cont~inin~ corrosion inhibitor compounds Suitable nitrogen-cont~inin~ corrosion inhibitor compounds include imi(l~7ole and derivatives thereof such as ben~imi(l~7ole, 2-heptadecyl im~ 7ole and those imi~l~7ole derivatives described in Czech Patent No. 139, 279 and British Patent GB-A-1,137,741, which also disc~oses a method for m~kin~ imicl~ole compounds.
Also suitable as nitrogen-cont~inin~ corrosion inhibitor compounds are pyrazole compounds and their derivatives, particularly those where the pyrazole is substituted in any of the 1, 3, 4 or 5 positions by substituents Rl, R3, R4 and Rs where Rl is any of H, CH20H, CONH3, or COCH3, R3 and Rs are any of C1-C20 alkyl or hydroxyl, and R4 is any of H, NH2 or N02.
Other suitable nitrogen-cont~inin corrosion inhibitor compounds include benzotriazole, 2-mercaptobenzothiazole, 1-phenyl-5-mercapto-1,2,3,4-tetrazole, thionalide, morpholine, melamine, c~icte~rylamine, stearoyl stearamide, cyanuric acid, aminotriazole, aminotetrazole and indazole.
Nitrogen-cont~inin~ compounds such as amines, especially distearyl~mine and ammonium compounds such as ammonium chloride, ammonium bromide, ammonium sulphate or ~ mmonium hydrogen citrate are also suitable.
Mn(II) corrosion inhibltor compounds The compositions may contain an Mn(II) corrosion inhibitor compound.
The MnaI) compound is preferably incorporated at a level of from 0.005 %
to 5 % by weight, more preferably from 0.01 % to 1%, most preferably from 0.02% to 0.4% by weight of the compositions. Preferably, the Mn(II) compound is incorporated at a level to provide from 0.1 ppm to 250 ppm, WO 97/2540S PCTrUS97/00471 more preferably from 0.5 pprn to 50 ppm, most preferably from 1 ppm to 20 ppm by weight of Mn(II) ions in any bleaching solution.
The Mn (II) compound may be an inorganic salt in anhydrous, or any hydrated forms. Suitable salts include m~n~ne.se sulphate, m~n~nese carbonate, m~n~nese phosphate, m~n~nese nitrate, manganese acetate and m~n~nese chloride. The Mn(II3 compound may be a salt or complex of an organic fatty acid such as m~n~nese acetate or m~ng~nese stearate.
The Mn(II) compound may be a salt or complex of an organic liga.nd. In one prer~r,ed aspect the organic ligand is a heavy metal ion sequestrant. In another preferred aspect the organic ligand is a crystal growth inhibitor.
Other corrosion inhibitor compounds Other suitable additional corrosion inhibitor compounds include, mercaptans and diols, especially mercaptans with 4 to 20 carbon atoms including lauryl mercaptan, thiophenol, thionapthol, thionalide and thioanthranol. Also suitable are saturated or llns~ rated Clo-C20 fatty acids, or their salts, especially aluminium tristearate. The C12-C20 hydroxy fatty acids, or their salts, are also suitable. Phosphonated octa-~lec~ne and other anti-oxidants such as betahydroxytoluene (BHT) are also suitable.
C~opolymers of butadiene and maleic acid, particularly those supplied under the trade reference no. 07787 by Polysciences Inc have been found to be of particular utility as corrosion inhibitor compounds.
Total Available Oxy~en (AvO) Level It has been found that, for optimal anti-silver tarni~hinf~ performance, the level of available oxygen in the present compositions, measured in units of % available oxygen by weight of the composition, is preferably controlled;
the level of available oxygen should hence preferably be in the range from W O 97/25405 PCT~US97/00471 0.3% to 2.5%, preferably from 0.5% to 1.7%, more preferably from 0.6%
to 1.5%, most preferably from 0.75~ to 1.2%, measured according to the method described hereunder.
Rate of Release of AvO
The rate of release of available oxygen is preferably also controlled; the rate of release of available oxygen from the compositions herein preferably should be such that, when using the method described hereinafter, the available oxygen is not completely released from the composition until after 3.5 minutes, preferably the available oxygen is released in a time interval of from 3.5 minutes to 10.0 mimltes, more preferably from 4.0 minutes to 9.0 minutes, most preferably from 5.0 minutes to 8.5 minutes.
Method for Measurin Level of Total Available Oxygen (AvO) and Rate of Release of AvO in a Deter~ent Composition Method 1. A beaker of water (typically 2L) is placed on a stirrer Hotplate, and the stirrer speed is selected to ensure that the product is evenly dispersed through the solution.
2. The detergent composition (typically 8g of product which has been sampled down from a bulk supply using a Pascal sampler), is added and simultaneously a stop clock is started.
3. The temperature control should be adjusted so as to m~int~in a constant temperature of 20~C throughout the experiment.
4. Samples are taken from the detergent solution at 2 minute time intervals for 20 minutes, starting after 1 minute, and are titrated by the "titration procedure" described below to determine the level of available oxygen at each point.
5 PCT~US97/00471 Titration Procedure 1. An aliquot from the detergent solution (above) and 2ml sulphuric acid are added into a stirred beaker 2. Approximately 0.2g ammonium molybdate catalyst (tetra hydrate form) are added 3. 3mls of 10~ sodium iodide solution are added 4. Titration with sodium thiosulphate is conducted until the end point.
The end point can be seen using either of two procedures. First procedure consists simply in seeing the yellow iodine colour fading to clear. The second and preferred procedure consists of 7J~lk1ing soluble starch when the yellow colour is becoming faint, turning the solution blue. More thiosulphate is added until the end point is reached (blue starch complex is decolourised).
The level of AvO, me~ red in units of % available oxygen by weight, forthe sample at each time interval corresponds to the amount of titre according to the following equation Vol S203(ml) x Molarity (S2'03) x 8 Sample mass (g) AvO level is plotted versus time to determine the maximum level of AvO,and the rate of release of AvO
Controlled rate of release - means A means may be provided for controlling the rate of release of oxygen bleach to the wash solution.
WO 97/2~;405 PCT/US97/00471 Means for controlling the rate of release of the bleach may provide forcontrolled release of peroxide species to the wash solution. Such means could, for example, include controlling the release of any inorganic perhydrate salt, acting as a hydrogen peroxide source, to the wash solution.
Suitable controlled release means can include coating any suitable component with a coating designed to provide the controlled release. The coating may therefore, for example, comprise a poorly water soluble material, or be a coating of sufficient thickness that the kinetics of dissolution of the thick coating provide the controlled rate of release.
The coating material may be applied using various methods. Any coating material is typically present at a weight ratio of coating material to bleach of from 1:99 to 1:2, preferably from 1:49 to 1:9.
Suitable coating materials include triglycerides (e.g. partially) hydrogenated vegetable oil, soy bean oil, cotton seed oil) mono or diglycerides, microcrystalline waxes, gelatin, cellulose, fatty acids and any mixtures thereof.
Other suitable coating materials can comprise the alkali and ~lk~line earth metal sulphates, silicates and carbonates, including calcium carbonate and silicas.
A preferred coating material, particularly for an inorganic perhydrate salt bleach source, comprises sodium silicate of SiO2: Na2O ratio from 1.8: 1 to 3.0: 1, preferably 1.8:1 to 2.4:1, and/or sodium metasilicate, preferably applied at a level of from 2% to 10%, ~normally from 3% to 5%) of SiO2 by weight of the inorganic perhydrate salt. Magnesium silicate can also be included in the coating.
Other means of providing the required controlled release include mechanical means for altering the physical characteristics of the bleach to control its solubility and rate of release. Suitable protocols could include compaction, mechanical injection, m~n~l~l injection, and adjustment of the WO 97n5405 PCTnU~97/00471 solubility of the bleach compound by selection of particle size of any particulate component.
Whilst the choice of particle size will depend both or~ the composition of the particulate component, and the desire to meet the desired controlled release kinetics, it is desirable that the particle size should be more than 500 micrometers, preferably having an average particle diameter of from 800 to 1200 micrometers.
Additional protocols for providing the means of controlled release include the suitable choice of any other components of the detergent composition matrix such that when the composition is introduced to the wash solution the ionic strength environment therein provided enables the required controlled release kinetics to be achieved.
Deter~ent compositions According to another aspect of the invention detergent compositions cont~inin~ the bleaching compositions hereinbefore described and one or more detergent ingredients are provided. The detergent ingredients are preferably selected from builder compounds, sources of alkalinity, surfactants, heavy metal ion sequestrants, crystal growth inhibitors, enzymes, organic polymeric compounds, and suds suppressors.
The binding constant for bismuth with organic diphosphonate ligands has, in general, been found to be high enough to ensure the stability of the salt or complex in a bleaching/detergent product, but weak enough such that on introduction of the product to a wash solution the bismuth ions are readily released from the compound to the wash solution.
The detergent compositions preferably contain the bismuth diphosphonatecompound at a level of from 0.005% to 20%, more preferably from 0.01%
to 5 %, most preferably from 0.1 % to 1 % by weight of the detergent composition.
W O 97/25405 PCT~US97/00471 PLefe~,ed detergent compositions herein are adapted for use in a machine dishwashing method. Such compositions are formulated to enable the removal of, typically food based, soils and stains from soiled tableware under the conditions present in a machine dishwasher. Typically the compositions are low foaming, preferably cont~inin_ only low levels of low-foaming surfactants.
A preferred detergent composition herein comprises a detergent component selected from the group consisting of a water soluble builder compound, a low foaming surfactant system and any mixtures thereof, and the hereinbefore described bleaching composition.
Water-soluble builder compound The detergent compositions of the present invention may contain as a highly preferred component a water-soluble builder compound, typically present at a level of from 1% to 8()% by weight, preferably from lO~o to 70% by weight, most preferably from 20~o to 60% by weight of the composition.
Suitable water-soluble builder compounds include the water soluble monomeric polycarboxylates, or their acid forms, homo or copolymeric polycarboxylic acids or their salts in which the polycarboxylic acid comprises at least two carboxylic radicals separated from each other by not more that two carbon atoms, carbonates, bicarbonates, borates, phosphates, and mixtures of any of the foregoing.
The carboxylate or polycarboxylate builder can be monomeric or oligomeric in type although monomeric polycarboxylates are generally preferred for reasons of cost and performance.
Suitable carboxylates cont~ining one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof.
Polycarboxylates cont~inin~ two carboxy groups include the water-solublè
salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic CA 022424l8 l998-07-07 acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates. Polycarboxylates cont~ining three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No.
1,379,241, lactoxysuccinates described in British Patent No. 1,389,732, and aminosuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate ma~erials such as 2-oxa-1,1,3-propane tricarboxylates described in British Patent No. 1,387,447.
Polycarboxylates con~ining four carboxy groups include oxydisuccinates disclosed in British Patent No. 1,261,829, 1,1,2,2-ethane tetracarboxylates, 1,1,3,3-propane tetracarboxylates and 1,1,2,3-propane tetracarboxylates.
Polycarboxylates Con~ining sulfo substituents include the sulfosuccinate derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in U.S. Patent No. 3,936,448, and the sulfonated pyrolysed citrates described in British Patent No. 1,439,000.
Alicyclic and heterocyclic polycarboxylates include cyclopentane-cis,cis,cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2,3,4,5-tetrahydrofuran - cis, cis, cis-tetracarboxylates, 2,5-tetrahydrofuran - cis -dicarboxylates, 2,2,5,5-tetrahydrofuran - tetracarboxylates, 1,2,3,4,5,6-hexane - hexacarboxylates and carboxymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol. Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in British Patent No. 1,425,343.
Of the above, the preferred polycarboxylates are hydroxycarboxylates cont~inin~ up to three carboxy groups per molecule, more particularly citrates.
The parent acids of the monomeric or oligomeric polycarboxylate chelating agents or mixtures thereof with their salts, e.g. citric acid or citrate/citric acid mixtures are also contemplated as useful builder components.
..
W O 97/25405 PCT~US97/00471 Borate builders, as well as builders con~inin~ borate-forming materialsthat can produce borate under detergent storage or wash conditions can also be used but are not preferred at wash conditions less that about 50~C, especially less than about 40~C.
F.x~mples of carbonate builders are the ~lk~line earth and alkali metalcarbonates, including sodium carbonate and sesqui-carbonate and mixtures thereof with ultra-fine calcium carbonate as disclosed in German Patent Application No. 2,321,001 published on November 15, 1973.
Specific examples of water-soluble phosphate builders are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21, and salts of phytic acid.
Partially soluble or insoluble builder compound The detergent compositions of the present invention may less preferablycontain a partially soluble or insoluble builder compound. Examples of partially water soluble builders include the crystalline layered silicates as disclosed for example, in EP-A-0164514, ~E-A-3417649 and DE-A-3742043. Examples of largely water insoluble builders include the sodium aluminosilicates, including Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite MAP, Zeolite HS and mixtures thereof.
~lk~linity system The detergent compositions preferably contain an ~lk~linity system con~inin~ sodium silicate having an SiO2: Na2O ratio of from 1.8 to 3.0, preferably from 1.8 to 2.4, most preferably 2.0, present preferably at a level of less than 20 %, preferably from 1 ~ to 15 %, most preferably from 3% to 12% by weight of SiO2. The alkali metal silicate may be in the form of either the anhydrous salt or a hydrated salt.
W O 97~5405 PCT~US97/00471 The ~lk~linity system also preferably contains sodium metasilicate, present at a level of at least 0.4% SiO2 by weight. Sodium metasilicate h,as a nominal SiO2: Na2O ratio of 1Ø The weight ratio of said sodium silicate to said sodium metasilicate, measured as SiO2, is preferably from 50:1 to 5:4, more preferably from 15:1 to 2:1, most preferably from 10:1 to 5:2.
Surfactant A highly preferred component of the detergent compositions of the invention is a surfactant system comprising surfactant selected from anionic, cationic, nonionic ampholytic and zwitterionic surfactants and mixtures thereof. Automatic dishwashing machine products should be low foaming in character and thus the foaming of the surfactant system must be suppressed or more preferably be low foaming, typically nonionic in character. The surfactant system is typically present at a level of from 0.2% to 3C)~ by weight, more preferably from 0.5% to 10~ by weight, most preferably from 1~ to 5~ by weight of the compositions.
A typical listing of anionic, nonionic, arnpholytic and zwitterionic classes, and species of these surfactants, is given in U.S.P. 3,929,678 issued to hl;n and Heuring on December, 30, 1975. A list of suitable cationic surfactants is given in U.S.P. 4,259,217 issued to Murphy on March 31,1981. A listing of surfactants typically included in automatic dishwashing detergent compositions is given for example, in EP-A-0414 549 and PCT Applications No.s WO 93/08876 (attorney's dockel; no.
CM465M) and WO 93/08874 (attorney's docket no. CM595M)..
Nonionic surfactant Essentially any nonionic surfactants useful for detersive purposes can be included in the compositions. Preferred, non-limiting classes of usefùl nonionic surfactants are listed below.
=
W O 97/25405 PCTrUS97/00471 NonioniG ethoxylated alcohol surfactant The alkyl ethoxylate condensat;on products of aliphatic alcohols with from r about 1 to about 25 moles of ethylene oxide are suitable for use herein. The alkyl chain of the aliphatic alcohol can e;ther be straight or branched, primary or secondary, and generally contains from 6 to 22 carbon atoms.
Particularly preferred are the condensation products of alcohols having an alkyl group cont~inin~: from 8 to 20 carbon atoms with from about 2 to about 10 moles of ethylene oxide per mole of alcohol.
Nonionic ethoxylated/propoxylated fatty alcohol surfactant The ethoxylated C6-Clg fatty alcohols and C6-Clg mixed ethoxylated/propoxylated fatty alcohols are suitable surfactants for use herein, particularly where water soluble. Preferably the ethoxylated fatty alcohols are the Clo-Clg ethoxylated fatty alcohols with a degree of ethoxylation of from 3 to 50, most preferably these are the C12-Clg ethoxylated fatty alcohols with a degree of ethoxylation from 3 to 40.
Preferably the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 10.
Nonionic EO/PO condensates with propylene ~lycol The condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol are suitable for use herein. The hydrophobic portion of these compounds preferably has a molecular weight of from about 1500 to about 1800 and exhibits water insolubility. Examples of compounds of this type include certain of the commercially-available PluronicTM surfactants, marketed by BASF.
W 097/25405 PCT~US97/00471 . 38 Nonionic EO condensation products with propylene oxide/ethylene ~ mine adducts The condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene~ mine are sui~able for use herein. The hydrophobic moiety of these products consists of the reaction product of ethylene~ mine and excess propylene oxide, and generally has a molecular weight of from about 2500 to about 3000.
~xamples of this type of nonionic surfactant include certain of the commercially available TetronicTM compounds, marketed by BASF.
Heavy metal ion sequestrant The detergent compositions of the invention preferably contain as an optional component a heavy metal ion sequestrant. By heavy metal ion sequestrant it is meant herein components which act to sequester (chelate) heavy metal ions. These components may also have calcium and magnesiurn chelation capacity, but preferentially they show selectivity to binding heavy metal ions such as iron, m~ng~nese and copper.
Heavy metal ion sequestrants are generally present at a level of from 0.005% to20~,preferablyfromO.1% to 10%, morepreferablyfrom 0.25 % to 7 .5 % and most preferably from 0.5 % to 5 % by weight of the compositions.
~eavy metal ion sequestrants, which are acidic in nature, having for example phosphonic acid or carboxylic acid functionalities, may be present either in their acid form or as a complex/salt with a suitable counter cation such as an alkali or ~lk~line metal ion, ammonium, or substituted ammonium ion, or any mixtures thereof. Preferably any salts/connplexes are water soluble. The molar ratio of said counter cation to the heavy metal ion sequestrant is preferably at least 1:1.
Suitable heavy metal ion sequestrants for use herein include organic phosphonates, such as the am;no alkylene poly (alkylene phosphonates), .
alkali metal ethane l-hydroxy disphosphonates and nitrilo trimethylene phosphonates. Preferred among the above species are diethylene triamine penta (methylene phosphonate), ethylene ~ mine tri (methylene phosphonate) hexamethylene ~i~mine tetra (methylene phosphonate) and hydroxy-ethylene 1,1 diphosphonate.
Other suitable heavy metal ion sequestrant for use herein include nitrilotriacetic acid and polyaminocarboxylic acids such as ethylene~ minotetracetic acid, ethylenetriamine pentacetic acid, ethylene~i~mine disuccinic acid, ethylene~ mine diglutaric acid, 2-hydroxypropylenetli~mine disuccinic acid or any salts thereof.
Especially preferred is ethylenediamine-N,N'-disuccinic acid (EDDS) or the alkali metal, ~Ik~ine earth metal, ammonium, or substituted ammonium salts thereof, or mixtures thereof. Pleferled EDDS compounds are the free acid form and the sodium or m~nesium salt or complex thereof.
Crystal growth inhibitor component The detergent compositions, in addition to the bismuth diphosphonate compound, preferably contain a crystal growth inhibitor component, preferably an additional organodiphosphonate component, incorporated preferably at a level of from 0.01 % to 5%, more preferably from 0.1 % to 2~ by weight of the compositions.
By organo diphosphonate it is meant herein an organo diphosphonate saltor organo diphosphonic acid which does not contain nitrogen as part of its chemical structure. This definition therefore excludes the organo aminophosphonates, which however may be included in compositions of the invention as heavy metal ion sequestrant components.
-The organo diphosphonate is preferably a Cl-C4 diphosphonate, more preferably a C2 diphosphonate, such as ethylene diphosphonate, or most preferably ethane l-hydroxy-l,l-diphosphonate (HEDP) and may be present in partially or ~ully ionized form, particularly as a salt or complex.
_ WO 97i25405 PCT~US97/00471 l~nzyme Another optional ingredient useful in the detergent compositions is one or more enzymes. Preferred enzymatic materials include the commercially available lipases, amylases, neutral and ~qlk~line proteases, esterases, cellulases, pectinases, lactases and peroxidases conventionally incorporated into detergent composi~ions. Suitable enzymes are discussed in US Patents 3,~19,570 and 3,533,139.
Preferred commercially available protease enzymes include those sold under the tradenames Alcalase, Savinase, Primase, Durazym, and Esperase by Novo Industries A/S (Denmark), those sold under the tradename Maxatase, Maxacal and Maxapem by Gist-Brocades, those sold by Genencor International, and those sold under the tradename Opticlean and Optimase by Solvay Enzymes. Protease enzyme may be incorporated into the compositions in accordance with the invention at a level of from 0.0001% to 4% active enzyme by weight of the composition.
Preferred amylases include, for example, oc-amylases obtained from a special strain of B licheniformis, described in more detail in GB-1,269,839 (Novo). Preferred commercially available amylases include for example, those sold under the tradename Rapidase by Gist-Brocades, and those sold under the tradename Termamyl and BAN by Novo Industries A/S.
Amylase enzyme may be incorporated into the composition in accordance with the invention at a level of from 0.0001 ~o to 2% active enzynne by weight of the composition.
Lipolytic enzyme ~lipase) may be present at levels of active lipolytic enzyme of from 0.0001% to 2~ by weight, preferably 0.001% to 1% by weight, most preferably from 0.001% to 0.5 % by weight of the compositions. The lipase may be fungal or bacterial in origin. Lipase from chemically or genetically modified mutants of these strains are also useful herein. A preferred lipase is described in Granted European Patent, EP-B-0218272.
W O 97/2540S PCT~US97/00471 An especially pref~lled lipase herein is obtained by cloning the gene from Humicola lanuginosa and expressing the gene in Aspergillus orvza, as host, as described in European Patent Application, EP-A-0258 068, which is commercially available from ~ovo Tnclllstri A/S, Bagsvaerd, Denmark, under the trade name Lipolase. This lipase is also described in U.S. Patent 4,810,414, Huge-Jensen et al, issued March 7, 1989.
Enzyme Stabilizin~ System Preferred enzyme-cont~ining compositions herein may comprise from about 0.001% to about 10%, preferably from about 0.005% to about 8%, most preferably from about 0.01% to about 6%, by weight of an enzyme stabilizing system. The enzyme stabilizing system can be any stabilizing system which is compatible with the detersive enzyme. Such stabilizing systems can comprise calcium ion, boric acid, propylene glycol, short chain carboxylic acid, boronic acid, chlorine bleach scavengers and mixtures thereof. Such stabilizing systems can also comprise reversible enzyme inhibitors, such as reversible protease inhibitors.
Or~anic polymeric compound Organic polymeric compounds may be added as preferred components of the detergent compositions in accord with the invention. By organic polymeric compound it is meant essentially any polymeric organic compound commonly used as dispersants, and anti-redeposition and soil suspension agents in detergent compositions.
Organic polymeric compound is typically incorporated in the detergent compositions of the invention at a level of from 0.1 % to 30%, preferably fromO.~% to 15~, mostpreferablyfrom 1% to 10% byweightofthe compositions.
Examples of organic polymeric compounds include the water soluble organic homo- or co-polymeric polycarboxylic acids or their salts in which W O 97n5405 PCTAUS97/~0471 the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of the latter type are disclosed in GB-A-1,596,756. Examples of such salts are polyacrylates of molecular weight 2000-10000 and their copolymers with any suitab~e other monomer units including modified acrylic, fumaric, maleic, itaconic, aconitic, mesaconic, citraconic and methylenemalonic acid or their salts, maleic anhydride, acryl~micle, alkylene, vinylmethyl ether, styrene and any mixtures thereof. Plefelled are the copolymers of acrylic acid and maleic anhydride having a molecular weight of from 20,000 to 100,000.
Preferred commercially available acrylic acid con~ining polymers having a molecular weight below 15,000 include those sold under the tradename Sokalan PA30, PA20, PA15, PA10 and Sokalan CP10 by BASF GmbH, and those sold under the tradename Acusol 45N by Rohm and Haas.
Preferred acrylic acid cont~inin.~ copolymers include those which contain as monomer units: a) from 90% to 10%, preferably from 80% to 20% by weight acrylic acid or its salts and b) from 10% to 90~0, preferably from 20% to 80% by weight of a sub~tit~l~e~l acrylic monomer or its salts having the general formula -[CR2-CR1(CO-O-R3)]- wherein at least one of the substituents R1, R2 or R3, preferably R1 or R2 is a 1 to 4 carbon alkyl or hydroxyalkyl group, R1 or R2 can be a hydrogen and R3 can be a hydrogen or alkali metal salt. Most preferred is a substituted acrylic monomer wherein R1 is methyl, R2 is hydrogen (i.e. a methacrylic acid monomer~. The most preferred copolymer of this type has a molecular weight of 3500 and contains 60% to 80% by weight of acrylic acid and 40% to 20% by weight of methacrylic acid.
The polyamino compounds are useful herein including those derived from aspartic acid such as those disclosed in EP-A-305282, EP-A-305283 and EP-A-35 1629.
WO 97/25405 PCT~US97/00471 I~ime soap dispersant compound The detergent compositions of the invention may contain a lime soap dispersant compound, preferably present at a level of from 0.1 % to 40%
by weight, more preferably 1 % to 20% by weight, most preferably from 2~ to 10~ by weight of the compositions.
A lime soap dispersant is a material that prevents the precipitation o~ alkali metal, ammonium or amine salts of fatty acids by calcium or magnesium ions. Preferred lime soap disperant compounds are disclosed in PCT
Application No. W093/08877 (attorney's docket no. CM466M).
Suds ~u~ressing system The detergent compositions of the invention, when form~ ted for use in machine w~hin~ compositions, preferably comprise a suds ~u~JL)ressing system present at a level of from 0.01 % to 15 %, preferably from 0.05 % to 10%, most preferably from 0.1 % to 5% by weight of the composition.
Suitable suds ~u~pl-essing systems for use herein may comprise essentially any known antifoam compound, including, for example silicone antifoam compounds, 2-alkyl and alcanol antifoam compounds. Preferred suds suppressing systems and antifoam compounds are disclosed in PCT
Application No. W093/08876 (attorney's docket no. CM465M) and copen~lin European Application No. 93870132.3 (attorney' s docket no.
CM562F).
Polymeric dye transfer inhibitin~ ~ents The detergent compositions herein may also comprise from 0.01 % to 10 - ~, preferably from 0.05 % to 0.5 % by weight of polymeric dye transfer inhibiting agents.
W O 97/25405 PCTrUS97/00471 The polymeric dye transfer inhibiting agents are preferably select;ed from polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimkl~7.Qle, polyvinylpyrrolidonepolymers or combinations thereof.
pH o~ the compositions The present detergent compositions are preferably not formulated to have an unduly high pH, in preference having a pH measured as a 1% solution in distilled water of from 8.0 to 12.0, more preferably from 9.0 to 11.~, most preferably from 9.5 to 11.5.
Form of the compositions The detergent compositions of the invention can be formulated in any desirable form such as powders, granulates, pastes, liquids, gels and tablets, solid, particularly granular forms being preferred.
The bulk density of the granular detergent compositions in accordance with the present invention is typically of at least 650 g/litre, more usually at least 700 g/litre and more preferably from 800 g/litre to 1200 g/litre.
The particle size of the components of granular compositions in accordance with the invention should preferably be such that no more that S ~ of particles are greater than 1 .4mm in diameter and not more than 5 % of particles are less than 0.15mm in ~ mçter.
Generally, if the compositions are in liquid form the liquid should be thixotropic (ie; exhibit high viscosity when subjected to low stress and lower viscosity when subjected to high stress), or at least have very high viscosity, for example, of from 1,000 to 10,000,000 centipoise.
Machine dishwashin~ method Any suitable methods for machine washing or cle~nin~E soiled tableware,particularly soiled silverware are envisaged.
- . -W O 97/25405 PCT~US97/00471 A preferred machine dishw~hing method comprises treating soiled articles selected from crockery, glassware, hollowware, silverware and cutlery and mixtures thereof, with an aqueous liquid having dissolved or dispensed therein an effective amount of a machine dishwashing composition in accord with the invention. By an effective amount of the machine dishw~hin~ composition it is meant from 8g to 60g of product dissolved or dispersed in a wash solution of volume from 3 to 10 litres, as are typical product dosages and wash solution volumes commonly employed in conventional machine dishwashing methods.
In the Examples, the abbreviated component identifications have the following me~nin~
Nonionic : C13-Cls mixed ethoxylated/propoxylated fatty alcohol with an average degree of ethoxylation of 3.8 and an average degree of propoxylation of 4.5 sold under the tradename Plurafac LF404 by BASF Gmbh (low foaming) Metasilicate : Sodium metasilicate (SiO2:Na2O ratio = 1.0) Silicate : Amorphous Sodium Silicate (SiO2:Na2O ratio = 2.0) Carbonate : Anhydrous sodium carbonate Phosphate : Sodium tripolyphosphate - 480N : Random copolymer of 3:7 acrylic/methacrylic acid, average molecular weight about 3,500 Citrate : Tri-sodium citrate dihydrate WO 97/25405 PC~rUS97/00471 PB 1 : Anydrous sodium perborate monohyblrate TAED : Tetraacetyl ethylene ~ mine Cationic precursor C~ationic peroxyacid bleach precursor salt of trialkyl ammonium methylene Cs-alkyl caprolactam with tosylate BzP : Dibenzoyl peroxide DETPMP : Diethylene triamine penta (methylene phosphonic acid), marketed by Monsanto under the tradename Dequest 2060 Hl~.DP Fth~n~. l-hydroxy-l ,1-diphosphonic acid Paraffin : Paraffin oil sold under the tradename Winog 70 by Wintershall.
BD/MA : Copolymer of butadiene/maleic acid as sold by Polysciences inc under the tradename reference no. 07787 Protease : Proteolytic enzyme sold under the tradename Savinase by Novo Industries A/S (approx 2%
enzyme activity).
Amylase : Arnylolytic enzyme sold under the tradename Termamyl 60T by Novo Industries A/S
(approx 0.9% enzyme activity) BSA : Amylolytic enzyme sold under the tradename LE17 by Novo Industries A/S (approx 1%
enzyme activity) W O 97/25405 PCT~US97/00471 Sulphate : Anhydrous sodium sulphate.
pH : Measured as a 1% solution in distilled water at 20~C
In the following examples all levels of enzyme quoted are expressed as %
active enzyme by weight of the composition.
li',xample 1 Agglomerate particles cont~ining bismuth diphosphonate compounds were prepared as follows:
(a) Makin~ of bismuth HEDP solutions Three different bismuth HEDP solutions were made up according to the following procedure. The exact volumes of HEDP solution and bismuth nitrate solution employed were adjusted such as to give final bismuth HEDP solutions with molar ratios of bismuth to HEDP of approximately 1:2 .1, 1:3 .5 and 1:5 .0 respectively.
(i) 1:5.0 ratio 560g of 32% NaOH solution was taken. To this was continuously added with stirring 334g of a 60% solution of HEDP over a time period of 20 mimltes. The temperature was not allowed to exceed 80~C. To the resulting solution was added with stirring 122g of a 23 % solution of bismuth nitrate over a period of 2 minutes.
(ii) 1:3.5 ratio 480g of 29% NaOH solution was taken. To this was continuously added - with stirring 238g of a 60% solution of HE~:)P over a time period of 20 minutes. The temperature was not allowed to exceed 80~C. To the resulting W O 97/25405 PCT~US97/00471 solution was added with stirring 122g of a 23 ~ solution of bismuth nitrate over a period of 2 minlltes.
(iii) 1:2.1 ratio 400g of 25% NaOH solution was taken. To this was continuously added with stirring 144g of a 60% solution of HEDP over a time period of 20 minlltes. The temperature was not allowed to exceed 80~C. To the resulting solution was added with stirring 1 22g of a 23 % solution of bismuth nitrate over a period of 2 min~ltes.
For each of (i) to (iii) above, on addition of the bismuth nitrate a white precipitate forrned, but this dissolved rapidly on further stirring of the resultant mixture.
(b) ~akin~ of bismuth HEDP particles Bi.cmlltl~ HEDP particles were made by co-agglomeration of a solution formed by mixing the 1:2.1, 1:3.5 and 1:5.0 ~lk~line bismuth HEDP
solutions with an ~Ik~lin~ solution (pH 12.0~ of 480N binder, (formed by ~cldin~ 333g of 480N binder with 10g of 50% NaOH) with sodiurn sulfate powder.
The exact amounts of ~lk~3line bismuth HEDP added to the ~lk~line 480N
binder solution were:
1:5.0 ratio 127g of 1:5.0 bismuth HEDP solution 1:3.5 ratio 105g of 1:3.5 bismuth HEDP solution 1:2.1 ratio 83g of 1:2.1 bismuth HEDP solution - The agglomeration was carried out 20 minlltes after preparation of the ~lk~line bismuth HEDP/binder solution as follows:
CA 022424l8 l998-07-07 W O 97/25405 PCTrUS97/00471 . 49 500g of anyhydrous sodium sulfate powder was placed in a Kenwood Chef (tradename) mixin~ bowl. The K-beater (tradename) attachment was secured to the mixer and the sulfate mixed. During this mixing the ~1k7~line bismuth HEDP/binder solution was trickled slowly onto the sulfate until this became slightly moist. The mixing was then stopped and the contents of the mixing bowl transferred to a fluid bed drier glass vessel. The sulphate was therein dried whilst fluidising at 80-90~C. After 5 minlltes drying the sulfate was transferred back to the mixing bowl and rnore solution added slowly until the sulfate was again moist. These liquid addition/drying steps were repeated 15-20 times until all of the solution had been used up. The resultant particles were then finally dried and sieved through a 1700 ~m mesh to reduce oversize.
The resulting agglomerates had the following compositions (% parts by weight), where n = 2.1, 3.5 or 5.0:
Bismuth (1 :n) 480N Sodium sulfate HEDP
Bismuth (1:2.1) 2.0 22.8 75.2 HEDP particle Bismuth (1:3.5) 3.0 22.8 74.2 HEDP particle Bismuth (1:5.0) 4.0 22.8 73.2 HEDP particle W O 97~5405 PCT~US97/00471 Example 2 The following bleach-cont~inin~ machine dishwashing compositions were prepared (parts by weight). Compositions A is a comparative composition, compositions B to H are in accord with the invention. The Bismuth HEDP
particles were made in accord with the process set out in Example 1.
A B C D E F G H
Citrate 15.0 15.0 15.0 15.0 15.0 15.0 15.0 480N 6.0 - - - - - - -Carbonate 17.5 17.5 17.5 17.5 17.5 17.5 17.5 Phosphate - - - - - - - 38.0 Silicate (as 8.0 8.0 8.0 8.0 8.0 8.0 8.0 14.0 SiO7) Metasilicate 1.2 1.2 1.2 1.2 1.2 1.2 1.2 2.5 (as SiO2) PBl (AvO) 1.5 1.5 1.5 1.5 1.5 2.2 1.2 1.2 TAED 2.2 2.2 2.2 2.2 - - 2.2 2.2 BzP - - - - 0.8 Cationic - - - - - 3.3 precursor Paraf~m 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 CA Oi242418 1998-07-07 Bismuth - 26.3 - - - - - -(1 :2. 1) HEDP
particle Bismuth - - 26.3 - 26.3 26.3 26.3 25.0 (1 :3.5 HEDP
particle Bismuth - - - 26.3 - - - 0.5 (1 :5.0) HEDP
particle Protease 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 Amylase 0.03 0.03 0.03 0.03 0.03 0.03 DETPMP 0.13 0.13 0.13 0.13 0.13 0.13 0.13 -HEDP- Q.3 0.3 0.3 0.3 0.3 0.3 0.5 powder form Nonionic 2.0 2.0 2.0 2.0 2.0 2.0 2.0 1.5 Sulphate 19.5 - - - - - - 0.3 misc inc moisture to balance pH (1% 10.7 10.7 10.7 10.7 10.7 10.7 10.7 11.0 solution) W O 97/25405 PCT~US97/00471 - Comparative testin~ - silver tarnishing The silver tarnish prevention pelrolmance of Compositions B to D, in accord with the invention was compared to that of comparative Composition A using the following twenty cycle test procedure. A set of three silver spoons were placed in the cutlery basket of each of four Bosch (tradename) machine dishwashers. Twenty grams of background soil, comprising 1 part by weight of each of Prince's (tradename) tinned stewing steak, Heinz (tradename) tinned baked beans and Ambrosia (tradename) tinned creamed rice, well mixed together, was added to each dishwasher by placing the soil in a 50 cm3 plastic beaker which was stood inverted in the upper rack of the dishwasher. A spike comprising 10 cm3 of 0.262~ by weight CaC12. 6H20 solution was added by pipette to the bottom of each dishwasher. The 65~C wash setting was selected, the wash process comprising main wash and rinse cycles. 20 grams of each composition was employed for each complete wash process. The feed water hardness was 8~ Clark Hardness (114.3 ppm CaC03 equivalent). Each set of three spoons was washed five times in each of the four machines (ie: 20 complete wash + rinse cycles).
At the end of the final wash process the spoons were removed and then graded for silver tarni~hin~. The grading was performed by 4 expert graders and the results averaged for each of the four sets of three spoons.
Grading was through visual inspection according to the following scale:
0 = no tarnish (shiny silver) 1 = very slight tarnish 2 = tarnish 3 = very tarnished 4 = severe tarnish (black coverage) Results were as follows: (average of the 4 gradings from the panellists) Composition A B C D
Tarnish grade 2.0 1.0 0.5 1.0 CA 022424l8 l998-07-07 WO 97/25405 PCT~US97/00471 Comparison of the grade obtained for Composition A with that obtained for Compositions B to D shows that less silver tarni~hin~ is obtained for the compositions in accord with the invention.
Stora~e stability A lkg sample of Composition C, as defined above, was stored in a plastic bottle for t~,vo weeks at 40~C and ambient h~lmiclity. The performance testing protocol as described above was then repeated with the Composition after storage. A tarnish grade of 0.5 was obtained, indicating that the bi~mlltl /HEDP compound does not lose performance capability upon storage under these conditions.
The end point can be seen using either of two procedures. First procedure consists simply in seeing the yellow iodine colour fading to clear. The second and preferred procedure consists of 7J~lk1ing soluble starch when the yellow colour is becoming faint, turning the solution blue. More thiosulphate is added until the end point is reached (blue starch complex is decolourised).
The level of AvO, me~ red in units of % available oxygen by weight, forthe sample at each time interval corresponds to the amount of titre according to the following equation Vol S203(ml) x Molarity (S2'03) x 8 Sample mass (g) AvO level is plotted versus time to determine the maximum level of AvO,and the rate of release of AvO
Controlled rate of release - means A means may be provided for controlling the rate of release of oxygen bleach to the wash solution.
WO 97/2~;405 PCT/US97/00471 Means for controlling the rate of release of the bleach may provide forcontrolled release of peroxide species to the wash solution. Such means could, for example, include controlling the release of any inorganic perhydrate salt, acting as a hydrogen peroxide source, to the wash solution.
Suitable controlled release means can include coating any suitable component with a coating designed to provide the controlled release. The coating may therefore, for example, comprise a poorly water soluble material, or be a coating of sufficient thickness that the kinetics of dissolution of the thick coating provide the controlled rate of release.
The coating material may be applied using various methods. Any coating material is typically present at a weight ratio of coating material to bleach of from 1:99 to 1:2, preferably from 1:49 to 1:9.
Suitable coating materials include triglycerides (e.g. partially) hydrogenated vegetable oil, soy bean oil, cotton seed oil) mono or diglycerides, microcrystalline waxes, gelatin, cellulose, fatty acids and any mixtures thereof.
Other suitable coating materials can comprise the alkali and ~lk~line earth metal sulphates, silicates and carbonates, including calcium carbonate and silicas.
A preferred coating material, particularly for an inorganic perhydrate salt bleach source, comprises sodium silicate of SiO2: Na2O ratio from 1.8: 1 to 3.0: 1, preferably 1.8:1 to 2.4:1, and/or sodium metasilicate, preferably applied at a level of from 2% to 10%, ~normally from 3% to 5%) of SiO2 by weight of the inorganic perhydrate salt. Magnesium silicate can also be included in the coating.
Other means of providing the required controlled release include mechanical means for altering the physical characteristics of the bleach to control its solubility and rate of release. Suitable protocols could include compaction, mechanical injection, m~n~l~l injection, and adjustment of the WO 97n5405 PCTnU~97/00471 solubility of the bleach compound by selection of particle size of any particulate component.
Whilst the choice of particle size will depend both or~ the composition of the particulate component, and the desire to meet the desired controlled release kinetics, it is desirable that the particle size should be more than 500 micrometers, preferably having an average particle diameter of from 800 to 1200 micrometers.
Additional protocols for providing the means of controlled release include the suitable choice of any other components of the detergent composition matrix such that when the composition is introduced to the wash solution the ionic strength environment therein provided enables the required controlled release kinetics to be achieved.
Deter~ent compositions According to another aspect of the invention detergent compositions cont~inin~ the bleaching compositions hereinbefore described and one or more detergent ingredients are provided. The detergent ingredients are preferably selected from builder compounds, sources of alkalinity, surfactants, heavy metal ion sequestrants, crystal growth inhibitors, enzymes, organic polymeric compounds, and suds suppressors.
The binding constant for bismuth with organic diphosphonate ligands has, in general, been found to be high enough to ensure the stability of the salt or complex in a bleaching/detergent product, but weak enough such that on introduction of the product to a wash solution the bismuth ions are readily released from the compound to the wash solution.
The detergent compositions preferably contain the bismuth diphosphonatecompound at a level of from 0.005% to 20%, more preferably from 0.01%
to 5 %, most preferably from 0.1 % to 1 % by weight of the detergent composition.
W O 97/25405 PCT~US97/00471 PLefe~,ed detergent compositions herein are adapted for use in a machine dishwashing method. Such compositions are formulated to enable the removal of, typically food based, soils and stains from soiled tableware under the conditions present in a machine dishwasher. Typically the compositions are low foaming, preferably cont~inin_ only low levels of low-foaming surfactants.
A preferred detergent composition herein comprises a detergent component selected from the group consisting of a water soluble builder compound, a low foaming surfactant system and any mixtures thereof, and the hereinbefore described bleaching composition.
Water-soluble builder compound The detergent compositions of the present invention may contain as a highly preferred component a water-soluble builder compound, typically present at a level of from 1% to 8()% by weight, preferably from lO~o to 70% by weight, most preferably from 20~o to 60% by weight of the composition.
Suitable water-soluble builder compounds include the water soluble monomeric polycarboxylates, or their acid forms, homo or copolymeric polycarboxylic acids or their salts in which the polycarboxylic acid comprises at least two carboxylic radicals separated from each other by not more that two carbon atoms, carbonates, bicarbonates, borates, phosphates, and mixtures of any of the foregoing.
The carboxylate or polycarboxylate builder can be monomeric or oligomeric in type although monomeric polycarboxylates are generally preferred for reasons of cost and performance.
Suitable carboxylates cont~ining one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof.
Polycarboxylates cont~inin~ two carboxy groups include the water-solublè
salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic CA 022424l8 l998-07-07 acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates. Polycarboxylates cont~ining three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No.
1,379,241, lactoxysuccinates described in British Patent No. 1,389,732, and aminosuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate ma~erials such as 2-oxa-1,1,3-propane tricarboxylates described in British Patent No. 1,387,447.
Polycarboxylates con~ining four carboxy groups include oxydisuccinates disclosed in British Patent No. 1,261,829, 1,1,2,2-ethane tetracarboxylates, 1,1,3,3-propane tetracarboxylates and 1,1,2,3-propane tetracarboxylates.
Polycarboxylates Con~ining sulfo substituents include the sulfosuccinate derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in U.S. Patent No. 3,936,448, and the sulfonated pyrolysed citrates described in British Patent No. 1,439,000.
Alicyclic and heterocyclic polycarboxylates include cyclopentane-cis,cis,cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2,3,4,5-tetrahydrofuran - cis, cis, cis-tetracarboxylates, 2,5-tetrahydrofuran - cis -dicarboxylates, 2,2,5,5-tetrahydrofuran - tetracarboxylates, 1,2,3,4,5,6-hexane - hexacarboxylates and carboxymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol. Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in British Patent No. 1,425,343.
Of the above, the preferred polycarboxylates are hydroxycarboxylates cont~inin~ up to three carboxy groups per molecule, more particularly citrates.
The parent acids of the monomeric or oligomeric polycarboxylate chelating agents or mixtures thereof with their salts, e.g. citric acid or citrate/citric acid mixtures are also contemplated as useful builder components.
..
W O 97/25405 PCT~US97/00471 Borate builders, as well as builders con~inin~ borate-forming materialsthat can produce borate under detergent storage or wash conditions can also be used but are not preferred at wash conditions less that about 50~C, especially less than about 40~C.
F.x~mples of carbonate builders are the ~lk~line earth and alkali metalcarbonates, including sodium carbonate and sesqui-carbonate and mixtures thereof with ultra-fine calcium carbonate as disclosed in German Patent Application No. 2,321,001 published on November 15, 1973.
Specific examples of water-soluble phosphate builders are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21, and salts of phytic acid.
Partially soluble or insoluble builder compound The detergent compositions of the present invention may less preferablycontain a partially soluble or insoluble builder compound. Examples of partially water soluble builders include the crystalline layered silicates as disclosed for example, in EP-A-0164514, ~E-A-3417649 and DE-A-3742043. Examples of largely water insoluble builders include the sodium aluminosilicates, including Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite MAP, Zeolite HS and mixtures thereof.
~lk~linity system The detergent compositions preferably contain an ~lk~linity system con~inin~ sodium silicate having an SiO2: Na2O ratio of from 1.8 to 3.0, preferably from 1.8 to 2.4, most preferably 2.0, present preferably at a level of less than 20 %, preferably from 1 ~ to 15 %, most preferably from 3% to 12% by weight of SiO2. The alkali metal silicate may be in the form of either the anhydrous salt or a hydrated salt.
W O 97~5405 PCT~US97/00471 The ~lk~linity system also preferably contains sodium metasilicate, present at a level of at least 0.4% SiO2 by weight. Sodium metasilicate h,as a nominal SiO2: Na2O ratio of 1Ø The weight ratio of said sodium silicate to said sodium metasilicate, measured as SiO2, is preferably from 50:1 to 5:4, more preferably from 15:1 to 2:1, most preferably from 10:1 to 5:2.
Surfactant A highly preferred component of the detergent compositions of the invention is a surfactant system comprising surfactant selected from anionic, cationic, nonionic ampholytic and zwitterionic surfactants and mixtures thereof. Automatic dishwashing machine products should be low foaming in character and thus the foaming of the surfactant system must be suppressed or more preferably be low foaming, typically nonionic in character. The surfactant system is typically present at a level of from 0.2% to 3C)~ by weight, more preferably from 0.5% to 10~ by weight, most preferably from 1~ to 5~ by weight of the compositions.
A typical listing of anionic, nonionic, arnpholytic and zwitterionic classes, and species of these surfactants, is given in U.S.P. 3,929,678 issued to hl;n and Heuring on December, 30, 1975. A list of suitable cationic surfactants is given in U.S.P. 4,259,217 issued to Murphy on March 31,1981. A listing of surfactants typically included in automatic dishwashing detergent compositions is given for example, in EP-A-0414 549 and PCT Applications No.s WO 93/08876 (attorney's dockel; no.
CM465M) and WO 93/08874 (attorney's docket no. CM595M)..
Nonionic surfactant Essentially any nonionic surfactants useful for detersive purposes can be included in the compositions. Preferred, non-limiting classes of usefùl nonionic surfactants are listed below.
=
W O 97/25405 PCTrUS97/00471 NonioniG ethoxylated alcohol surfactant The alkyl ethoxylate condensat;on products of aliphatic alcohols with from r about 1 to about 25 moles of ethylene oxide are suitable for use herein. The alkyl chain of the aliphatic alcohol can e;ther be straight or branched, primary or secondary, and generally contains from 6 to 22 carbon atoms.
Particularly preferred are the condensation products of alcohols having an alkyl group cont~inin~: from 8 to 20 carbon atoms with from about 2 to about 10 moles of ethylene oxide per mole of alcohol.
Nonionic ethoxylated/propoxylated fatty alcohol surfactant The ethoxylated C6-Clg fatty alcohols and C6-Clg mixed ethoxylated/propoxylated fatty alcohols are suitable surfactants for use herein, particularly where water soluble. Preferably the ethoxylated fatty alcohols are the Clo-Clg ethoxylated fatty alcohols with a degree of ethoxylation of from 3 to 50, most preferably these are the C12-Clg ethoxylated fatty alcohols with a degree of ethoxylation from 3 to 40.
Preferably the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 10.
Nonionic EO/PO condensates with propylene ~lycol The condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol are suitable for use herein. The hydrophobic portion of these compounds preferably has a molecular weight of from about 1500 to about 1800 and exhibits water insolubility. Examples of compounds of this type include certain of the commercially-available PluronicTM surfactants, marketed by BASF.
W 097/25405 PCT~US97/00471 . 38 Nonionic EO condensation products with propylene oxide/ethylene ~ mine adducts The condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene~ mine are sui~able for use herein. The hydrophobic moiety of these products consists of the reaction product of ethylene~ mine and excess propylene oxide, and generally has a molecular weight of from about 2500 to about 3000.
~xamples of this type of nonionic surfactant include certain of the commercially available TetronicTM compounds, marketed by BASF.
Heavy metal ion sequestrant The detergent compositions of the invention preferably contain as an optional component a heavy metal ion sequestrant. By heavy metal ion sequestrant it is meant herein components which act to sequester (chelate) heavy metal ions. These components may also have calcium and magnesiurn chelation capacity, but preferentially they show selectivity to binding heavy metal ions such as iron, m~ng~nese and copper.
Heavy metal ion sequestrants are generally present at a level of from 0.005% to20~,preferablyfromO.1% to 10%, morepreferablyfrom 0.25 % to 7 .5 % and most preferably from 0.5 % to 5 % by weight of the compositions.
~eavy metal ion sequestrants, which are acidic in nature, having for example phosphonic acid or carboxylic acid functionalities, may be present either in their acid form or as a complex/salt with a suitable counter cation such as an alkali or ~lk~line metal ion, ammonium, or substituted ammonium ion, or any mixtures thereof. Preferably any salts/connplexes are water soluble. The molar ratio of said counter cation to the heavy metal ion sequestrant is preferably at least 1:1.
Suitable heavy metal ion sequestrants for use herein include organic phosphonates, such as the am;no alkylene poly (alkylene phosphonates), .
alkali metal ethane l-hydroxy disphosphonates and nitrilo trimethylene phosphonates. Preferred among the above species are diethylene triamine penta (methylene phosphonate), ethylene ~ mine tri (methylene phosphonate) hexamethylene ~i~mine tetra (methylene phosphonate) and hydroxy-ethylene 1,1 diphosphonate.
Other suitable heavy metal ion sequestrant for use herein include nitrilotriacetic acid and polyaminocarboxylic acids such as ethylene~ minotetracetic acid, ethylenetriamine pentacetic acid, ethylene~i~mine disuccinic acid, ethylene~ mine diglutaric acid, 2-hydroxypropylenetli~mine disuccinic acid or any salts thereof.
Especially preferred is ethylenediamine-N,N'-disuccinic acid (EDDS) or the alkali metal, ~Ik~ine earth metal, ammonium, or substituted ammonium salts thereof, or mixtures thereof. Pleferled EDDS compounds are the free acid form and the sodium or m~nesium salt or complex thereof.
Crystal growth inhibitor component The detergent compositions, in addition to the bismuth diphosphonate compound, preferably contain a crystal growth inhibitor component, preferably an additional organodiphosphonate component, incorporated preferably at a level of from 0.01 % to 5%, more preferably from 0.1 % to 2~ by weight of the compositions.
By organo diphosphonate it is meant herein an organo diphosphonate saltor organo diphosphonic acid which does not contain nitrogen as part of its chemical structure. This definition therefore excludes the organo aminophosphonates, which however may be included in compositions of the invention as heavy metal ion sequestrant components.
-The organo diphosphonate is preferably a Cl-C4 diphosphonate, more preferably a C2 diphosphonate, such as ethylene diphosphonate, or most preferably ethane l-hydroxy-l,l-diphosphonate (HEDP) and may be present in partially or ~ully ionized form, particularly as a salt or complex.
_ WO 97i25405 PCT~US97/00471 l~nzyme Another optional ingredient useful in the detergent compositions is one or more enzymes. Preferred enzymatic materials include the commercially available lipases, amylases, neutral and ~qlk~line proteases, esterases, cellulases, pectinases, lactases and peroxidases conventionally incorporated into detergent composi~ions. Suitable enzymes are discussed in US Patents 3,~19,570 and 3,533,139.
Preferred commercially available protease enzymes include those sold under the tradenames Alcalase, Savinase, Primase, Durazym, and Esperase by Novo Industries A/S (Denmark), those sold under the tradename Maxatase, Maxacal and Maxapem by Gist-Brocades, those sold by Genencor International, and those sold under the tradename Opticlean and Optimase by Solvay Enzymes. Protease enzyme may be incorporated into the compositions in accordance with the invention at a level of from 0.0001% to 4% active enzyme by weight of the composition.
Preferred amylases include, for example, oc-amylases obtained from a special strain of B licheniformis, described in more detail in GB-1,269,839 (Novo). Preferred commercially available amylases include for example, those sold under the tradename Rapidase by Gist-Brocades, and those sold under the tradename Termamyl and BAN by Novo Industries A/S.
Amylase enzyme may be incorporated into the composition in accordance with the invention at a level of from 0.0001 ~o to 2% active enzynne by weight of the composition.
Lipolytic enzyme ~lipase) may be present at levels of active lipolytic enzyme of from 0.0001% to 2~ by weight, preferably 0.001% to 1% by weight, most preferably from 0.001% to 0.5 % by weight of the compositions. The lipase may be fungal or bacterial in origin. Lipase from chemically or genetically modified mutants of these strains are also useful herein. A preferred lipase is described in Granted European Patent, EP-B-0218272.
W O 97/2540S PCT~US97/00471 An especially pref~lled lipase herein is obtained by cloning the gene from Humicola lanuginosa and expressing the gene in Aspergillus orvza, as host, as described in European Patent Application, EP-A-0258 068, which is commercially available from ~ovo Tnclllstri A/S, Bagsvaerd, Denmark, under the trade name Lipolase. This lipase is also described in U.S. Patent 4,810,414, Huge-Jensen et al, issued March 7, 1989.
Enzyme Stabilizin~ System Preferred enzyme-cont~ining compositions herein may comprise from about 0.001% to about 10%, preferably from about 0.005% to about 8%, most preferably from about 0.01% to about 6%, by weight of an enzyme stabilizing system. The enzyme stabilizing system can be any stabilizing system which is compatible with the detersive enzyme. Such stabilizing systems can comprise calcium ion, boric acid, propylene glycol, short chain carboxylic acid, boronic acid, chlorine bleach scavengers and mixtures thereof. Such stabilizing systems can also comprise reversible enzyme inhibitors, such as reversible protease inhibitors.
Or~anic polymeric compound Organic polymeric compounds may be added as preferred components of the detergent compositions in accord with the invention. By organic polymeric compound it is meant essentially any polymeric organic compound commonly used as dispersants, and anti-redeposition and soil suspension agents in detergent compositions.
Organic polymeric compound is typically incorporated in the detergent compositions of the invention at a level of from 0.1 % to 30%, preferably fromO.~% to 15~, mostpreferablyfrom 1% to 10% byweightofthe compositions.
Examples of organic polymeric compounds include the water soluble organic homo- or co-polymeric polycarboxylic acids or their salts in which W O 97n5405 PCTAUS97/~0471 the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of the latter type are disclosed in GB-A-1,596,756. Examples of such salts are polyacrylates of molecular weight 2000-10000 and their copolymers with any suitab~e other monomer units including modified acrylic, fumaric, maleic, itaconic, aconitic, mesaconic, citraconic and methylenemalonic acid or their salts, maleic anhydride, acryl~micle, alkylene, vinylmethyl ether, styrene and any mixtures thereof. Plefelled are the copolymers of acrylic acid and maleic anhydride having a molecular weight of from 20,000 to 100,000.
Preferred commercially available acrylic acid con~ining polymers having a molecular weight below 15,000 include those sold under the tradename Sokalan PA30, PA20, PA15, PA10 and Sokalan CP10 by BASF GmbH, and those sold under the tradename Acusol 45N by Rohm and Haas.
Preferred acrylic acid cont~inin.~ copolymers include those which contain as monomer units: a) from 90% to 10%, preferably from 80% to 20% by weight acrylic acid or its salts and b) from 10% to 90~0, preferably from 20% to 80% by weight of a sub~tit~l~e~l acrylic monomer or its salts having the general formula -[CR2-CR1(CO-O-R3)]- wherein at least one of the substituents R1, R2 or R3, preferably R1 or R2 is a 1 to 4 carbon alkyl or hydroxyalkyl group, R1 or R2 can be a hydrogen and R3 can be a hydrogen or alkali metal salt. Most preferred is a substituted acrylic monomer wherein R1 is methyl, R2 is hydrogen (i.e. a methacrylic acid monomer~. The most preferred copolymer of this type has a molecular weight of 3500 and contains 60% to 80% by weight of acrylic acid and 40% to 20% by weight of methacrylic acid.
The polyamino compounds are useful herein including those derived from aspartic acid such as those disclosed in EP-A-305282, EP-A-305283 and EP-A-35 1629.
WO 97/25405 PCT~US97/00471 I~ime soap dispersant compound The detergent compositions of the invention may contain a lime soap dispersant compound, preferably present at a level of from 0.1 % to 40%
by weight, more preferably 1 % to 20% by weight, most preferably from 2~ to 10~ by weight of the compositions.
A lime soap dispersant is a material that prevents the precipitation o~ alkali metal, ammonium or amine salts of fatty acids by calcium or magnesium ions. Preferred lime soap disperant compounds are disclosed in PCT
Application No. W093/08877 (attorney's docket no. CM466M).
Suds ~u~ressing system The detergent compositions of the invention, when form~ ted for use in machine w~hin~ compositions, preferably comprise a suds ~u~JL)ressing system present at a level of from 0.01 % to 15 %, preferably from 0.05 % to 10%, most preferably from 0.1 % to 5% by weight of the composition.
Suitable suds ~u~pl-essing systems for use herein may comprise essentially any known antifoam compound, including, for example silicone antifoam compounds, 2-alkyl and alcanol antifoam compounds. Preferred suds suppressing systems and antifoam compounds are disclosed in PCT
Application No. W093/08876 (attorney's docket no. CM465M) and copen~lin European Application No. 93870132.3 (attorney' s docket no.
CM562F).
Polymeric dye transfer inhibitin~ ~ents The detergent compositions herein may also comprise from 0.01 % to 10 - ~, preferably from 0.05 % to 0.5 % by weight of polymeric dye transfer inhibiting agents.
W O 97/25405 PCTrUS97/00471 The polymeric dye transfer inhibiting agents are preferably select;ed from polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimkl~7.Qle, polyvinylpyrrolidonepolymers or combinations thereof.
pH o~ the compositions The present detergent compositions are preferably not formulated to have an unduly high pH, in preference having a pH measured as a 1% solution in distilled water of from 8.0 to 12.0, more preferably from 9.0 to 11.~, most preferably from 9.5 to 11.5.
Form of the compositions The detergent compositions of the invention can be formulated in any desirable form such as powders, granulates, pastes, liquids, gels and tablets, solid, particularly granular forms being preferred.
The bulk density of the granular detergent compositions in accordance with the present invention is typically of at least 650 g/litre, more usually at least 700 g/litre and more preferably from 800 g/litre to 1200 g/litre.
The particle size of the components of granular compositions in accordance with the invention should preferably be such that no more that S ~ of particles are greater than 1 .4mm in diameter and not more than 5 % of particles are less than 0.15mm in ~ mçter.
Generally, if the compositions are in liquid form the liquid should be thixotropic (ie; exhibit high viscosity when subjected to low stress and lower viscosity when subjected to high stress), or at least have very high viscosity, for example, of from 1,000 to 10,000,000 centipoise.
Machine dishwashin~ method Any suitable methods for machine washing or cle~nin~E soiled tableware,particularly soiled silverware are envisaged.
- . -W O 97/25405 PCT~US97/00471 A preferred machine dishw~hing method comprises treating soiled articles selected from crockery, glassware, hollowware, silverware and cutlery and mixtures thereof, with an aqueous liquid having dissolved or dispensed therein an effective amount of a machine dishwashing composition in accord with the invention. By an effective amount of the machine dishw~hin~ composition it is meant from 8g to 60g of product dissolved or dispersed in a wash solution of volume from 3 to 10 litres, as are typical product dosages and wash solution volumes commonly employed in conventional machine dishwashing methods.
In the Examples, the abbreviated component identifications have the following me~nin~
Nonionic : C13-Cls mixed ethoxylated/propoxylated fatty alcohol with an average degree of ethoxylation of 3.8 and an average degree of propoxylation of 4.5 sold under the tradename Plurafac LF404 by BASF Gmbh (low foaming) Metasilicate : Sodium metasilicate (SiO2:Na2O ratio = 1.0) Silicate : Amorphous Sodium Silicate (SiO2:Na2O ratio = 2.0) Carbonate : Anhydrous sodium carbonate Phosphate : Sodium tripolyphosphate - 480N : Random copolymer of 3:7 acrylic/methacrylic acid, average molecular weight about 3,500 Citrate : Tri-sodium citrate dihydrate WO 97/25405 PC~rUS97/00471 PB 1 : Anydrous sodium perborate monohyblrate TAED : Tetraacetyl ethylene ~ mine Cationic precursor C~ationic peroxyacid bleach precursor salt of trialkyl ammonium methylene Cs-alkyl caprolactam with tosylate BzP : Dibenzoyl peroxide DETPMP : Diethylene triamine penta (methylene phosphonic acid), marketed by Monsanto under the tradename Dequest 2060 Hl~.DP Fth~n~. l-hydroxy-l ,1-diphosphonic acid Paraffin : Paraffin oil sold under the tradename Winog 70 by Wintershall.
BD/MA : Copolymer of butadiene/maleic acid as sold by Polysciences inc under the tradename reference no. 07787 Protease : Proteolytic enzyme sold under the tradename Savinase by Novo Industries A/S (approx 2%
enzyme activity).
Amylase : Arnylolytic enzyme sold under the tradename Termamyl 60T by Novo Industries A/S
(approx 0.9% enzyme activity) BSA : Amylolytic enzyme sold under the tradename LE17 by Novo Industries A/S (approx 1%
enzyme activity) W O 97/25405 PCT~US97/00471 Sulphate : Anhydrous sodium sulphate.
pH : Measured as a 1% solution in distilled water at 20~C
In the following examples all levels of enzyme quoted are expressed as %
active enzyme by weight of the composition.
li',xample 1 Agglomerate particles cont~ining bismuth diphosphonate compounds were prepared as follows:
(a) Makin~ of bismuth HEDP solutions Three different bismuth HEDP solutions were made up according to the following procedure. The exact volumes of HEDP solution and bismuth nitrate solution employed were adjusted such as to give final bismuth HEDP solutions with molar ratios of bismuth to HEDP of approximately 1:2 .1, 1:3 .5 and 1:5 .0 respectively.
(i) 1:5.0 ratio 560g of 32% NaOH solution was taken. To this was continuously added with stirring 334g of a 60% solution of HEDP over a time period of 20 mimltes. The temperature was not allowed to exceed 80~C. To the resulting solution was added with stirring 122g of a 23 % solution of bismuth nitrate over a period of 2 minutes.
(ii) 1:3.5 ratio 480g of 29% NaOH solution was taken. To this was continuously added - with stirring 238g of a 60% solution of HE~:)P over a time period of 20 minutes. The temperature was not allowed to exceed 80~C. To the resulting W O 97/25405 PCT~US97/00471 solution was added with stirring 122g of a 23 ~ solution of bismuth nitrate over a period of 2 minlltes.
(iii) 1:2.1 ratio 400g of 25% NaOH solution was taken. To this was continuously added with stirring 144g of a 60% solution of HEDP over a time period of 20 minlltes. The temperature was not allowed to exceed 80~C. To the resulting solution was added with stirring 1 22g of a 23 % solution of bismuth nitrate over a period of 2 min~ltes.
For each of (i) to (iii) above, on addition of the bismuth nitrate a white precipitate forrned, but this dissolved rapidly on further stirring of the resultant mixture.
(b) ~akin~ of bismuth HEDP particles Bi.cmlltl~ HEDP particles were made by co-agglomeration of a solution formed by mixing the 1:2.1, 1:3.5 and 1:5.0 ~lk~line bismuth HEDP
solutions with an ~Ik~lin~ solution (pH 12.0~ of 480N binder, (formed by ~cldin~ 333g of 480N binder with 10g of 50% NaOH) with sodiurn sulfate powder.
The exact amounts of ~lk~3line bismuth HEDP added to the ~lk~line 480N
binder solution were:
1:5.0 ratio 127g of 1:5.0 bismuth HEDP solution 1:3.5 ratio 105g of 1:3.5 bismuth HEDP solution 1:2.1 ratio 83g of 1:2.1 bismuth HEDP solution - The agglomeration was carried out 20 minlltes after preparation of the ~lk~line bismuth HEDP/binder solution as follows:
CA 022424l8 l998-07-07 W O 97/25405 PCTrUS97/00471 . 49 500g of anyhydrous sodium sulfate powder was placed in a Kenwood Chef (tradename) mixin~ bowl. The K-beater (tradename) attachment was secured to the mixer and the sulfate mixed. During this mixing the ~1k7~line bismuth HEDP/binder solution was trickled slowly onto the sulfate until this became slightly moist. The mixing was then stopped and the contents of the mixing bowl transferred to a fluid bed drier glass vessel. The sulphate was therein dried whilst fluidising at 80-90~C. After 5 minlltes drying the sulfate was transferred back to the mixing bowl and rnore solution added slowly until the sulfate was again moist. These liquid addition/drying steps were repeated 15-20 times until all of the solution had been used up. The resultant particles were then finally dried and sieved through a 1700 ~m mesh to reduce oversize.
The resulting agglomerates had the following compositions (% parts by weight), where n = 2.1, 3.5 or 5.0:
Bismuth (1 :n) 480N Sodium sulfate HEDP
Bismuth (1:2.1) 2.0 22.8 75.2 HEDP particle Bismuth (1:3.5) 3.0 22.8 74.2 HEDP particle Bismuth (1:5.0) 4.0 22.8 73.2 HEDP particle W O 97~5405 PCT~US97/00471 Example 2 The following bleach-cont~inin~ machine dishwashing compositions were prepared (parts by weight). Compositions A is a comparative composition, compositions B to H are in accord with the invention. The Bismuth HEDP
particles were made in accord with the process set out in Example 1.
A B C D E F G H
Citrate 15.0 15.0 15.0 15.0 15.0 15.0 15.0 480N 6.0 - - - - - - -Carbonate 17.5 17.5 17.5 17.5 17.5 17.5 17.5 Phosphate - - - - - - - 38.0 Silicate (as 8.0 8.0 8.0 8.0 8.0 8.0 8.0 14.0 SiO7) Metasilicate 1.2 1.2 1.2 1.2 1.2 1.2 1.2 2.5 (as SiO2) PBl (AvO) 1.5 1.5 1.5 1.5 1.5 2.2 1.2 1.2 TAED 2.2 2.2 2.2 2.2 - - 2.2 2.2 BzP - - - - 0.8 Cationic - - - - - 3.3 precursor Paraf~m 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 CA Oi242418 1998-07-07 Bismuth - 26.3 - - - - - -(1 :2. 1) HEDP
particle Bismuth - - 26.3 - 26.3 26.3 26.3 25.0 (1 :3.5 HEDP
particle Bismuth - - - 26.3 - - - 0.5 (1 :5.0) HEDP
particle Protease 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 Amylase 0.03 0.03 0.03 0.03 0.03 0.03 DETPMP 0.13 0.13 0.13 0.13 0.13 0.13 0.13 -HEDP- Q.3 0.3 0.3 0.3 0.3 0.3 0.5 powder form Nonionic 2.0 2.0 2.0 2.0 2.0 2.0 2.0 1.5 Sulphate 19.5 - - - - - - 0.3 misc inc moisture to balance pH (1% 10.7 10.7 10.7 10.7 10.7 10.7 10.7 11.0 solution) W O 97/25405 PCT~US97/00471 - Comparative testin~ - silver tarnishing The silver tarnish prevention pelrolmance of Compositions B to D, in accord with the invention was compared to that of comparative Composition A using the following twenty cycle test procedure. A set of three silver spoons were placed in the cutlery basket of each of four Bosch (tradename) machine dishwashers. Twenty grams of background soil, comprising 1 part by weight of each of Prince's (tradename) tinned stewing steak, Heinz (tradename) tinned baked beans and Ambrosia (tradename) tinned creamed rice, well mixed together, was added to each dishwasher by placing the soil in a 50 cm3 plastic beaker which was stood inverted in the upper rack of the dishwasher. A spike comprising 10 cm3 of 0.262~ by weight CaC12. 6H20 solution was added by pipette to the bottom of each dishwasher. The 65~C wash setting was selected, the wash process comprising main wash and rinse cycles. 20 grams of each composition was employed for each complete wash process. The feed water hardness was 8~ Clark Hardness (114.3 ppm CaC03 equivalent). Each set of three spoons was washed five times in each of the four machines (ie: 20 complete wash + rinse cycles).
At the end of the final wash process the spoons were removed and then graded for silver tarni~hin~. The grading was performed by 4 expert graders and the results averaged for each of the four sets of three spoons.
Grading was through visual inspection according to the following scale:
0 = no tarnish (shiny silver) 1 = very slight tarnish 2 = tarnish 3 = very tarnished 4 = severe tarnish (black coverage) Results were as follows: (average of the 4 gradings from the panellists) Composition A B C D
Tarnish grade 2.0 1.0 0.5 1.0 CA 022424l8 l998-07-07 WO 97/25405 PCT~US97/00471 Comparison of the grade obtained for Composition A with that obtained for Compositions B to D shows that less silver tarni~hin~ is obtained for the compositions in accord with the invention.
Stora~e stability A lkg sample of Composition C, as defined above, was stored in a plastic bottle for t~,vo weeks at 40~C and ambient h~lmiclity. The performance testing protocol as described above was then repeated with the Composition after storage. A tarnish grade of 0.5 was obtained, indicating that the bi~mlltl /HEDP compound does not lose performance capability upon storage under these conditions.
Claims (17)
1. A bismuth diphosphonate compound wherein the molar ratio of bismuth to diphosphonate components is from 1:0.7 to 1:7.
2. A bismuth diphosphonate compound according to Claim 1 wherein said molar ratio is from 1:3 to 1:7.
3. A bismuth diphosphonate compound according to either of Claims 1 or 2 wherein said disphosphonate component is ethane 1-hydroxy-1, 1-diphosphonate.
4. A process for making an alkaline solution containing a bismuth diphosphonate according to any of Claims 1 to 3 comprising the following steps:
(i) formation of an alkaline solution containing a diphosphonate species;
(ii) agitatative addition of a solution containing bismuth ions to said alkaline solution.
(i) formation of an alkaline solution containing a diphosphonate species;
(ii) agitatative addition of a solution containing bismuth ions to said alkaline solution.
5. A process for making a particle containing a bismuth diphosphonate according to any of Claims 1 to 3 by agglomeration of an inorganic salt containing an anion capable of forming a bismuth salt with an alkaline bismuth diphosphonate solution.
6. A process according to Claim 5 wherein said bismuth salt is an insoluble salt.
7. A process according to either of Claims 5 or 6 wherein said inorganic salt is selected from the group consisting of the alkali and alkaline earth metal sulfates, and any mixtures thereof.
8. A process according to any of Claims 5 to 7 wherein said alkaline bismuth diphosphonate solution is made according to the process of Claim 4.
9. A process according to any of Claims 5 to 8 wherein an organic binder is included in the agglomeration step.
10. A bleaching composition comprising (a) an oxygen-releasing bleaching system; and (b) a bismuth diphosphonate compound according to any of Claims 1 to 3.
11. A bleaching composition according to Claim 10 wherein said bismuth diphosphonate compound is present in a particle obtainable by a process according to any of Claims 5 to 9.
12. A detergent composition comprising (a) a detergent component selected from the group consisting of a water soluble builder compound, a low foaming surfactant system and any mixtures thereof; and (b) a bleaching composition according to Claim 10.
13. A solid detergent composition according to Claim 12 obtainable by a process in which an alkaline bismuth diphosphonate solution is sprayed onto one or more of the other component parts of the composition.
14. A solid detergent composition according to Claim 12 containing a bleaching composition according to Claim 11.
15. A detergent composition according to any of Claims 12 to 14 wherein said bismuth diphosphonate compound is present at a level of from 0.005% to 20% by weight of the composition.
16. A detergent composition according to any of Claims 12 to 15 wherein said oxygen-releasing bleaching system comprises a hydrogen peroxide source and a peroxyacid bleach precursor compound.
17. A composition according to Claim 16 wherein said hydrogen peroxide source comprises an inorganic perhydrate salt.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9600553.3 | 1996-01-11 | ||
GB9600553A GB2309032A (en) | 1996-01-11 | 1996-01-11 | Bismuth salts and complexes with nitrogen-free organic diphosphonic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2242418A1 true CA2242418A1 (en) | 1997-07-17 |
Family
ID=10786899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2242418 Abandoned CA2242418A1 (en) | 1996-01-11 | 1997-01-09 | Machine dishwashing compositions |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0948593A1 (en) |
BR (1) | BR9706928A (en) |
CA (1) | CA2242418A1 (en) |
GB (1) | GB2309032A (en) |
WO (1) | WO1997025405A1 (en) |
Families Citing this family (5)
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US20070054825A1 (en) * | 2003-10-17 | 2007-03-08 | Reckitt Benckiser N.V. | Composition for protection of glassware in dishwashers |
GB0625586D0 (en) * | 2006-12-21 | 2007-01-31 | Reckitt Benckiser Nv | Composition |
US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
BR112019016988B1 (en) | 2017-02-17 | 2023-02-23 | Diversey, Inc | PEROXIDE-BASED DISINFECTING SOLUTIONS CONTAINING INORGANIC SALTS, METHOD FOR DISINFECTING OR SANITIZING A SURFACE |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1586067A (en) * | 1976-10-28 | 1981-03-18 | Procter & Gamble | Detergent composition |
EP0070587B2 (en) * | 1981-07-17 | 1988-11-30 | THE PROCTER & GAMBLE COMPANY | Rinse aid composition |
DE3319772A1 (en) * | 1983-05-27 | 1984-11-29 | Schering AG, 1000 Berlin und 4709 Bergkamen | BATH FOR GALVANIC DEPOSITION OF GOLD ALLOYS |
US4856593A (en) * | 1987-09-21 | 1989-08-15 | Conoco Inc. | Inhibition of hydrate formation |
CH673033A5 (en) * | 1987-10-26 | 1990-01-31 | Cosmina Ag | Powder dishwashing agents for dishwashing machines - contg. combination of sodium citrate and sodium salt(s) of hydroxy-ethane di:phosphonic acid with sodium silicate |
GB8813891D0 (en) * | 1988-06-11 | 1988-07-13 | Micro Image Technology Ltd | Solutions of perhalogenated compounds |
GB8813889D0 (en) * | 1988-06-11 | 1988-07-13 | Micro Image Technology Ltd | Solutions of permonosulphuric acid |
GB2297096A (en) * | 1995-01-20 | 1996-07-24 | Procter & Gamble | Bleaching composition. |
US5534180A (en) * | 1995-02-03 | 1996-07-09 | Miracle; Gregory S. | Automatic dishwashing compositions comprising multiperacid-forming bleach activators |
-
1996
- 1996-01-11 GB GB9600553A patent/GB2309032A/en not_active Withdrawn
-
1997
- 1997-01-09 CA CA 2242418 patent/CA2242418A1/en not_active Abandoned
- 1997-01-09 BR BR9706928A patent/BR9706928A/en unknown
- 1997-01-09 EP EP97905571A patent/EP0948593A1/en not_active Withdrawn
- 1997-01-09 WO PCT/US1997/000471 patent/WO1997025405A1/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO1997025405A1 (en) | 1997-07-17 |
GB2309032A (en) | 1997-07-16 |
GB9600553D0 (en) | 1996-03-13 |
BR9706928A (en) | 1999-07-20 |
EP0948593A1 (en) | 1999-10-13 |
EP0948593A4 (en) | 1999-10-13 |
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