CA2235446A1 - Friction modifier comprising metal phenate and lubricating oil composition containing the same - Google Patents
Friction modifier comprising metal phenate and lubricating oil composition containing the same Download PDFInfo
- Publication number
- CA2235446A1 CA2235446A1 CA 2235446 CA2235446A CA2235446A1 CA 2235446 A1 CA2235446 A1 CA 2235446A1 CA 2235446 CA2235446 CA 2235446 CA 2235446 A CA2235446 A CA 2235446A CA 2235446 A1 CA2235446 A1 CA 2235446A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- chain
- lubricating oil
- oil composition
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/86—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
- C10M129/88—Hydroxy compounds
- C10M129/91—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/28—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to a carbon atom of a six-membered aromatic ring
- C10M135/30—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/027—Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/028—Overbased salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/088—Neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention is directed to novel chain-hydrocarbon-group-substituted metal phenates having friction reducing ability and various lubricating oil compositions containing the novel chain-hydrocarbon-group-substituted metal phenates.
A friction modifier comprising a chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group has an alkyl chain linearity of 20% or higher as determined by a carbon nuclear magnetic resonance measurement (13C-NMR measurement); and a lubricating oil composition containing the metal phenate are disclosed.
A friction modifier comprising a chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group has an alkyl chain linearity of 20% or higher as determined by a carbon nuclear magnetic resonance measurement (13C-NMR measurement); and a lubricating oil composition containing the metal phenate are disclosed.
Description
CA 0223~446 1998-0~-22 BACKGROUND OF THE INVENTION
Field of the Invention This invention relates to a friction modifier comprising a chain-hydrocarbon-group-substituted metal phenate and a lubricating oil composition Col-t~il-il-g the same, and more specifically to a friction modifier comprising a specific chain-hydrocarbon-group-substituted metal phenate having excellent friction reducing ability and a lubricating oil composition containing the same.
Description of the Prior Art It is the fundamental theme of lubrication to reduce friction and wear which occur at sliding surfaces of moving parts in machineries, devices, equipments and the like. Technical developments on lubrication technology have conventionally been placed on this theme.
Especially from the need for resource and energy saving, measures for the achievement of low friction and low wear by improvements in the quality of lubricating oils have been investigated from a variety of viewpoints in recent years. As a consequence, it has become an indispensable approach for the production of a lubricating oil excellent in friction characteristics to incorporate additives in base stocks for lubricating oils so that the base stocks can be provided with desired friction characteristics.
Accordingly a number of friction modifiers have been proposed to date, resulting in the use of fatty acids and their metal salts, alcohols, esters, amines and the like - all of which are of the oiliness improver type - and phosphate esters, phosphite esters, zinc dithiophosphate and the like - all of CA 0223'7446 1998-0',-22 which are of the extreme pressure agent type - in automatic transmission fluids,wet brake oils, sliding surface oils, plastic working oils and the like and also in the use of phosphate esters, phosphite esters, acidic phosphite ester amine salts, molybdenum dithiophosphate, molybdenum dithiocarbamate and the like - all of which are of the extreme pressure agent type - in engine oils, gear oils, cutting oils and the like.
Meanwhile, an automatic transmission fluid was disclosed, which had been obtained by adding magnesium sulfonate used as a metallic detergent, especially over-based magnesium sulfonate having a base number of 300 mg-KOH/g or greater in a base stock in order to improve its friction characteristics (see JP Kokai 62-84190). Further, it has also been proposed to use calcium salicylate as a friction coefficient modifiers for automatic trans-mission fluids (see JP Kokai 5-163496).
No matter whether these conventionally-proposed friction modifiers are of the organic type or of the metallic type, their friction reducing effects are however not sufficient depending on the use conditions. All of them are still insufficient in assuring stable friction reducing effects as typified by magnesium sulfonate, calcium salicylate and the like the effects of which vary significantly depending on the kind, use conditions and the like of a lubricating base stock, although they provide friction reducing effects to some extents.
Therefore they are merely adjuvants for friction modifiers such as phosphate esters and molybdenum dithiocarbamate.
In view of the technical developments on friction reducing technology and the circumstances of development of friction modifiers as described above, the present invention has as objects thereof the provision of a CA 0223~446 1998-0~-22 novel friction modifier having friction reducing ability and also the provision of a lubricating oil composition containing the friction modifier.
Present Invention It has been discovered that a metal phenate containing at least one chain hydrocarbon group, which has a specific linear portion determinable by a carbon nuclear magnetic resonance measurement (which may hereinafter be referred to as "13C-NMR measurement" as needed), has excellent friction reduc-ing ability. It has also been found that its addition to a base stock for lubricating oil makes it possible to furnish a lubricating oil composition having improved friction characteristics and utility in many fields. Based on these findings, the present invention has now been completed.
Namely, the present invention relates in a first aspect thereof to a friction modifier comprising at least one chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, characterizedin that said chain hydrocarbon group has an alkyl chain linearity of 20% or higher as dele~ hled by a carbon nuclear magnetic resonance measurement (13C-NMR measurement).
The present invention also relates in a second aspect thereof to a lubricating oil composition characterized in that said lubricating oil composition comprises:
a lubricating base stock; and at least one chain-hydrocarbon-group-substituted metal phenate substituted by a~ least one chain hydrocarbon group, said chain hydrocarbon CA 0223~446 1998-0~-22 group having an alkyl chain linearity of 20% or higher as determined by a carbonnuclear magnehc resonance measurement (13C-NMR measurement), and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on a whole weight of said lubricahng oil composlhon.
The present invenhon will hereinafter be described in detail.
The chain-hydrocarbon-group-substituted metal phenate, which is used as an effective component of the friction modifier according to the presentinvention, is formed basically of a phenol component, which carries at least onechain hydrocarbon group bonded thereto, and a metal component. The above metal phenate may be subjected to sulfurization to contain compounds with two or more aromahc groups bonded together by one or more sulfur atoms, respec-tively, and the above metal phenate may also contain one obtained by subjecting it to an over-basing treatment as needed.
As the chain hydrocarbon group in the chain-hydrocarbon-group-subshtuted metal phenate according to the present invention, those capable of meehng the following requirements are suitable.
As such, the following requirements can be mentioned:
(i) an alkyl group having an average carbon number of 12 or more per hydroxyl group; and (ii) said alkyl group having a linearity of 20% or higher, CA 0223~446 1998-0~-22 both being as determined by a l3C-NMR measurement.
Describing about the above requirement (i), it is important for the exhibition of friction reducing effects that the chain hydrocarbon group of the chain-hydrocarbon-group-substituted metal phenate according to the present invention is an alkyl group having an average carbon number of 12 or more per hydroxyl group. In particular, an alkyl group having an average carbon number of from 12 to 40 is preferred. An average carbon number smaller than 12 involves a potential problem that sufficient friction reducing effects may not be obtained.
Describing further, as chain-hydrocarbon-group-substituted metal phenate according to the present invention, one containing at least one or more alkyl groups having 12 to 30 carbon atoms is particularly preferred.
By the way, the term "hydroxyl group" as used herein means an -OH group existing in a chain-hydrocarbon-group-substituted metal phenate in a form as converted under 13C-NMR measuring conditions.
The term "average carbon number per hydroxyl group" as used herein indicates an average carbon number of an alkyl group as calculated by a 13C-NMR measurement by supposing that an aromatic carbon bonded to a hydroxyl group is 1.
Specific examples of the above-described alkyl group can include dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, triacontyl, pentatriacontyl, and octatriacontyl.
CA 0223~446 1998-0~-22 One of principal features of the present invention resides in that the above alkyl group has a specific linearity as determined by a 13C-NMR measure-ment as indicated above under the requirement (ii), and is a requirement indispensable for the unique chain-hydrocarbon-group-substituted metal phenate according to the present invention.
Namely, the chain-hydrocarbon-group-substituted metal phenate according to the present invention is one having an alkyl chain linearity of 20%or higher, preferably 30% or higher as determined by a 13C-NMR measurement.
Here, the term "alkyl chain linearity" is based on a unique concept established by the present inventors as a result of repetition of numerous experi-ments, and means the ratio of the number of carbon atoms in a linear portion located 5 or more carbon atoms apart from an end of the alkyl group or 4 or more carbon atoms apart from a branched site of the alkyl group to the total number of carbon atoms in the alkyl group. Accordingly, the alkyl chain linearity varies depending on the substituting site of the aromatic group to thealkyl group or the site of branching of the alkyl group. Specifically, the chain linearity is determined specifically by the following formula from a 13C-NMR
measurement.
Alkyl chain linearity (%) =
Integral intensity over a chemical shift range of from 29 ppm to 31 ppm Sum of all integral intensity over a chemical x 100 shift range of from S ppm to 60 ppm CA 0223~446 1998-0~-22 Incidentally, the 13C-NMR measurement was conducted by converting the metal phenate into its corresponding alkyl phenol.
The present inventors were interested in the existence of a correla-tion between the linearity of the alkyl group or groups in the chain-hydrocarbon-group-substituted metal phenate and its friction reducing effects, and have ascertained that the metal phenate exhibits better friction reducing effects as the alkyl chain linearity becomes higher and also that an alkyl chain linearity lower than 20% cannot exhibit the effects fully although an alkyl chain linearity of 20%
or higher, especially of from 30% to 80% shows particularly marked effects.
In the present invention, a chain-hydrocarbon-group-substituted metal phenate excellent in friction reducing effects can still be obtained provided that its alkyl chain linearity as determined by a 13C-NMR measurement is 20%
or higher, even when the chain-hydrocarbon-group-substituted metal phenate contains two or more hydrocarbon groups per hydroxyl group or is a mixture of two or more different compounds (metal phenates). That is, the overall alkyl chain linearity is 20% or higher. In particular, a metal phenate, hydrocarbon groups of which are each a linear alkyl group having 12 or more carbon atoms, ispreferred from the viewpoint that it can substantially improve friction reducingeffects.
The metal component represented by M in the formula (I) of the chain-hydrocarbon-group-substituted metal phenate according to the present invention can be an alkali metal or an alkaline earth metal. Further, a metal of an atomic number in a range of from 12 to 56 is also suited. Specific examples of suitable metals can include sodium, potassium, lithium, calcium, magnesium and barium. In addition, aluminum, zinc, tin, chromium, copper, cobalt and the like CA 0223~446 1998-0~-22 are also effective. Particularly preferred are alkaline earth metals such as calcium, magnesium and barium.
Typical illustrative compounds of the chain-hydrocarbon-group-substituted metal phenate according to the present invention can be represented by the following formulas (I) to (II):
O M O
(Rl)n (R2)n (I) ~ [~/
O M O
(Rl)n (R2)n '~1 sx ~' In each of the above formulas (I) and (II), Rl and R2 are alkyl groups which may be the same or different, the average carbon number of the total carbon number of Rl and the total carbon number of R2, said average total carbon number being equivalent to the number of carbon atoms per hydroxyl group, may preferably be from 12 to 40, and the alkyl chain linearity as deter-mined by a 13C-NMR measurement is 20% or higher. Specific examples of the alkyl group can include dodecyl, tridecyl, tetradecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, and triacontyl.
, CA 0223'7446 1998-0',-22 In each formula, M is appropriately an alkaline earth metal, although it can be other divalent metals described above. n indicates the numberof alkyl groups substituted on the aromatic group and is an integer of from 1 to5, preferably an integer of 1 to 2. In the respective formulas, they can be the same or different. Further, x is an integer of from 1 to 5 in the formula (II).
In the present invention, the chain-hydrocarbon-group-substituted metal phenate can specifically be a metal salt of an alkylphenol or alkylphenol sulfide, which can be a basic salt or over-based salt in addition to a neutral salt.
Its salt type can be chosen as desired depending on its application. The metal salt of the alkylphenol or alkylphenol sulfide can be prepared by a reaction between the alkyl phenol or alkylphenol sulfide and a metal compound, for example, an oxide, hydroxide, alkoxide or the like. The over-based salt can be obtained by a method known per se in the art. On the other hand, the alkyl-phenol sulfide can be produced by reacting the alkylphenol with sulfur or a sulfur-contAining compound such as hydrogen sulfide and is obtained in the form of a mixture that two or more phenol groups are bonded by one or more sulfur atoms, respectively.
A metal phenate mixture with an alkyl chain linearity controlled within the above-described specific range can also be obtained by mixing variousmetal phenates of different alkyl chain linearities.
According to the present invention, a friction modifier comprising such a specific chain-hydrocarbon-group-substituted metal phenate as described above can be provided. This friction modifier is oil-soluble. It can be used by dissolving it in a hydrocarbon or another solvent and diluting the resultant concentrate as needed or as a component of an additive package in combination with other additives.
CA 0223~446 1998-0~-22 A description will next be made about the lubricating oil composi-tion according to the present invention.
The lubricating oil composition according to the present invention contains the lubricating base stock and the chain-hydrocarbon-group-substituted metal phenate.
No particular limitation is imposed on the base stock for use in the lubricating oil composition according to the present invention. The base stock can be any one of mineral base stocks, synthetic base stocks and vegetable base stocks, or can be a blended base stock of two or more of these base stocks.
As a mineral base stock, it is possible to use, for example, a mineral oil obtained by the treatment of a lubricating oil fraction, which is inturn available by vacuum distillation of an atmosphere distillation residue of paraffin-base, neutral or naphthene-base crude oil, through a refining step suchas solvent refining, hydrocracking, hydro-refining, catalytic dewaxing, solvent dewaxing or clay treatment; a mineral oil obtained by subjecting a vacuum distillation residue to solvent deasphalting and then treating the resulting deasphalted oil through the above-described refining step; a mineral oil obtained by isomerizing wax components; or a blended oil thereof. In the above solvent refining, an aromatic extraction solvent such as phenol, furfural or N-methyl-pyrrolidone can be used, whereas as a solvent for the solvent dewaxing, liquefied propane, MEK/toluene, MEK/MIBK, or the like can be used. Among the above-described mineral base stocks, hydro-refined oil is preferred from the standpoint of quality such as oxidation stability, and one containing, for example, 2 wt% or less of aromatic hydrocarbons and 90 wt% or more of saturated hydrocarbons CA 0223~446 1998-0~-22 can be used although the preferred mineral base stock varies depending on the application purpose of the lubricating oil.
Examples of synthetic base stocks, on the other hand, can include poly(a-olefin) oligomers; polybutene; alkylbenzenes; polyol esters such as trimethylolpropane esters and pentaerythritol esters; polyoxyalkylene glycols;
polyoxyalkylene glycol esters; polyoxyalkylene glycol ethers; dibasic acid esters;
phosphate esters; and silicone oils. These base stocks can be used either singlyor in combination.
Further, usable examples of vegetable base stocks can include rape seed oil, palm oil, coconut oil, olive oil and sunflower oil.
As a lubricating base stock such as that described above, it is possible to use a blended base stock obtained by suitably blending plural base stocks so that the blended base stock has a viscosity and other properties desired for the intended application of the lubricating oil composition. For example, it is preferred to control the kinematic viscosity at 1 00~C in a range of from 2 mm2/s to 30 mm2/s, especially from 3 mm2/s to 10 mm2/s for a lubricating oil for internal combustion engines, the kinematic viscosity at 100~C in a range of from2 mm2/s to 30 mm2/s, especially from 3 mm2/s to 15 mm2/s for an automatic transmission fluid, and the kinematic viscosity at 4~C in a range of from 10 mm2/s to 1,000 mm2/s, especially from 20 mm2/s to 500 mm2/s.
The chain-hydrocarbon-group-substituted metal phenate for use in the lubricating oil composition according to the present invention can be added to the lubricating base stock in a proportion of from 0.01 to 10 wt%, preferablyfrom 0.05 to 5 wt% based on the whole weight of the lubricating oil composition or in a proportion of from 1 ppm to 10,000 ppm, preferably from 50 ppm to CA 0223~446 1998-0~-22 5,000 ppm in terms of the metal, although the proportion varies depending on theapplication field of the lubricating oil.
To the lubricating oil composition according to the present inven-tion, it is possible to add selected ones of viscosity index improvers, ashless dispersants, anti-oxidants, extreme pressure agents, wear inhibitors, metal deactivators, pour-point depressants, rust inhibitors, other friction modifiers and other additives as needed.
Illustrative usable examples of the viscosity index improvers can include polymethacrylates, polyisobutylenes, ethylene-propylene copolymers, and hydrogenated styrene-butadiene copolymers. These viscosity index improvers are used generally in a proportion of from 3 wt% to 35 wt%.
Illustrative of the ashless dispersants can be polybutenyl-succinimides, polybutenylsuccinarnides, benzylamines, and succinate esters.
They can be used generally in a proportion of from 0.05 wt% to 7 wt%.
Illustrative examples of the anti-oxidants can include amine-type anti-oxidants such as alkylated diphenylamines, phenyl-a-naphthylamine and alkylated phenyl-a-naphthylamines; phenolic anti-oxidants such as 2,6-di-t-butylphenol and 4,4'-methylene-bis(2,6-di-t-butylphenol); and zinc dithio-phosphate. They can be used generally in a proportion of from 0.05 wt% to 5 wt%.
Illustrative of the extreme pressure agents can be dibenzyl sulfide and dibutyl disulfide. They can be used generally in a propoltion of from 0.05 wP/O to 3 wt%.
CA 0223~446 1998-0~-22 Illustrative examples of the metal deactivators can include benzo-triazole, benzotriazole derivatives, and thiadiazole. They can be used generallyin a proportion of from 0.01 wt% to 3 wt%.
Illustrative of the pour-point depressants can be ethylene-vinyl acetate copolymers, chlorinated paraffin-naphthalene condensation products, polymethacrylates, and polyalkylstyrenes. They can be used generally in a proportion of from 0.1 wt% to 10 wt%.
Illustrative of the wear inhibitors can be phosphate esters, zinc thiophosphate, and sulfur compounds. They can be used generally in a propor-tion of from 0.01 wt% to 5 wt%.
As preferred embodiments of the present invention, it is possible to provide:
(i) a friction modifier for lubricating oils, which comprises chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 20% or higher as determined by a 13C-NMR measure-ment.
(ii) a friction modifier for lubricating oils, which comprises chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 25% or higher as determined by a 13C-NMR measure-ment.
CA 0223~446 1998-0~-22 (iii) A lubricating oil composition comprising:
a lubricating base stock; and chain-hydrocarbon-group-substituted metal phenate, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and a chain linearity of 20% or higher as determined by a 13C-NMR measurement, and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition.
(iv) A lubricating oil composition comprising:
a base stock composed of a hydro-ref1ned oil containing 2 wt% or less of aromatic hydrocarbons and 90% or more of saturated hydrocarbons; and chain-hydrocarbon-group-substituted metal phenate, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 20% or higher as determined by the 13C-NMR measurement, and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition.
(v) A lubricating oil composition comprising:
a lubricating base stock; and CA 0223~446 1998-0~-22 metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 a hydroxyl group and an alkyl chain linearity of 20% or higher as determined by the 13C-NMR measurement, said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition, and at least one of 4 wt% to 30 wt% of a viscosity index improver, 0.1 wt% to 5 wt% of an ashless dispersant, 0.1 wt% to 2.5 wt% of an extreme pressure agent, 0.1 wt% to 3 wt% of an anti-oxidant, 0.1 wt% to 3 wt% of a wear inhibitor, 0.15 wt% to 8 wt% of a pour-point depressant and 0.01 wt% to 2 wt% of a metal deactivator can be added.
As has been described above, the friction modifier according to the present invention, which comprises the chain-hydrocarbon-group-substituted metal phenate, is useful for various fuels and lubricating oils, and the lubricating oil composition according to the present invention, which contains the friction modifier, can be used as hydraulic working oils, wet brake oils, sliding surfaceoils, plastic working oils, cutting oils and the like in addition to automatic trans-mission fluid compositions, lubricating oil compositions for internal combustionengines, and gear oils. It can also be used without limitations in lubricating oils and fuel oils in any fields insofar as the friction reducing effects of the metal phenate can be exhibited.
Examples The present invention will next be described specifically by Examples and Comparative Examples. It is however to be noted that the Examples and the like are to primarily demonstrate the friction reducing effectsof certain chain-hydrocarbon-group-substituted metal phenates (hereinafter may CA 0223~446 1998-0~-22 be referred to as "metal phenates" as needed) according to the present inventionand that the present invention shall not be limited by these Examples and the like.
The alkyl chain linearities of metal phenates employed in the following Examples and the like and, as performance evaluation of lubricating oil compositions, friction coefficients were measured by the following methods.
(i) Measuring method of alkyl chain linearity:
Each metal phenate was converted into its corresponding alkylphenol, and under the following measuring conditions, its 13C-NMR spectrum was measured. Further, its alkyl chain linearity was calculated in accordance with the below-described formula.
Measuring conditions Used instrument EX400 (manufactured by JEOL Ltd.) Observed nucleus 13C
Observing frequency 100.50 MHz Measuring mode Inverse gated lH decoupling Internal standard TMS (= 0 ppm) Relaxation reagent Cr(acac)3 Solvent CDCl3 Quantity of sample 300 mg Temperature 30~C
CA 0223~446 1998-0~-22 Alkyl chain linearity (%) =
Integral intensity over the chemical shift range of form 29 ppm to 31 ppm Sum of all integral intensity over the chemical x 100 shift range of from 5 ppm to 60 ppm (ii) Performance evaluation Friction coefficient measuring method:
Concerning each lubricating oil composition added with its corresponding metal phenate in a predetermined proportion, its friction coefficient was measured under the following conditions by using "LFW- 1 " as a testing machine.
Friction materials: Steel/steel Load: 200 lb Oil temperature: 80~C
Revolution speed: 600 rpm Measuring period: 30 min Example 1 Provided was Calcium Phenate 1 (total base number:
85 mg-KOHlg), which had an average alkyl carbon number of 19 per hydroxyl group and an alkyl chain linearity of 45.3%. A lubricating oil composition was formulated by adding the phenate to a refined mineral oil " 1 00SN" (4.2 mm2/s at 100~C) as a lubricating base stock in a proportion of 140 ppm in terms of calcium based on the whole weight of the lubricating oil composition. The CA 0223~446 1998-0~-22 friction coefficient of the resultant lubricating oil composition was measured by the above-described method. It was found to be 0.10.
Example 2 A lubricating oil composition was formulated in exactly the same manner as in Example I except that the proportion of Calcium Phenate 1 was increased from 140 ppm to 560 ppm in terms of calcium. When subjected to a performance evaluation, its friction coefficient was found to be 0.09.
Example 3 Provided was Calcium Phenate 2 (total base number: 260 mg-KOH/g), which had an average alkyl carbon number of 20 per hydroxyl group and an alkyl chain linearity of 28.2%. A lubricating oil composition was form~ ted by adding the phenate to a lubricating base stock, which was the same as that employed in Example 1, in a proportion of 950 ppm in terms of calcium based on the whole weight of the lubricating oil composition. The resultant lubricating oil composition was subjected to the above-described performance evaluation. Its friction coefficient was found to be 0.09.
Example 4 A lubricating oil composition was formulated in exactly the same manner as in Example 3 except that the proportion of Calcium Phenate 2 was increased from 950 ppm to 1,900 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.09.
. ~ CA 0223~446 1998-0~-22 Example S
A lubricating oil composition was formulated in exactly the same manner as in Example 3 except that the propoltion of Calcium Phenate 2 was increased to 5,700 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.09.
Comparative Example 1 The lubricating base stock, i.e., the purified mineral oil alone was subjected to a performance evaluation. Its friction coefficient was found to be 0.l4.
Comparative Example 2 Provided was Calcium Phenate 3 (total base number: 250 mg-KOH/g), which had an average alkyl carbon number of 20 per hydroxyl group and an alkyl chain linearity of 15.5%. A lubricating oil composition was formulated by adding the phenate to a refined mineral oil, which was the same asthat employed in Example 1, in a proportion of 950 ppm in terms of calcium based on ~e whole weight of the lubricating oil composition. As a result of a performance evaluation, its friction coefficient was found to be 0.14. No advantageous effect was available from the addition of Calcium Phenate 3 the alkyl chain linearity of which is lower than 20%.
~ CA 0223~446 1998-0~-22 Comparative Example 3 A lubricating oil composition was formulated in exactly the same manner as in Comparative Example 2 except that the proportion of Calcium Phenate 3 was increased to 5,700 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.13.
The kinds and properties of the calcium phenate used in the Examples and the like are shown in Table 1, and the results of the performance evaluations of the lubricating oil compositions are summarized in Table 2.
Average Alkyl Carbon Number Per Alkyl Chain Total Base Kind Hydroxyl Group Linearity Number CalciurnPhenate 1 19 45.3% 85 mg-KOH/g Calcium Phenate 2 20 28.2% 260 mg-KOH/g Calcium Phenate 3 20 15.5% 250 mg-KOH/g Example Comparative Example Base stock Refinedmineral oil, lOOSN D
Proportion of additive (Ca conc.. ppm) CalciumPhenate 1 140 560 - - - - - ,~, Calcium Phenate 2 - - 950 1900 5700 - - - ' CalciumPhenate 3 - - - - - 950 5700 ~n Performance evaluation Friction coefficient 0.10 0.09 0.09 0.09 0.09 0.14 0.14 0.13 CA 0223~446 1998-0~-22 From the above Examples and Comparative Examples, it is apparent that a low frictional coefficient can be obtained from a chain-hydrocarbon-group-substituted metal phenate of an alkyl chain linearity of 20%
or higher even if it is added in a small proportion (Example 1), but it is also clear from a comparison among Comparative Examples 1, 2 and 3 that a metal phenate of an alkyl chain linearity lower than 20% cannot bring any significant improve-ment in frictional coefficient even if its proportion is increased. From these results, it has become evident that the alkyl chain linearity is a principal factor governing friction reducing ability.
From this it is seen that a in-hydrocarbon-group-substituted metal phenate having an alkyl chain linearity of 20% or higher has high friction reducing effects, is useful as a friction modifier especially for lubricating oils, and can improve the friction characteristics of lubricating oil compositions.
Field of the Invention This invention relates to a friction modifier comprising a chain-hydrocarbon-group-substituted metal phenate and a lubricating oil composition Col-t~il-il-g the same, and more specifically to a friction modifier comprising a specific chain-hydrocarbon-group-substituted metal phenate having excellent friction reducing ability and a lubricating oil composition containing the same.
Description of the Prior Art It is the fundamental theme of lubrication to reduce friction and wear which occur at sliding surfaces of moving parts in machineries, devices, equipments and the like. Technical developments on lubrication technology have conventionally been placed on this theme.
Especially from the need for resource and energy saving, measures for the achievement of low friction and low wear by improvements in the quality of lubricating oils have been investigated from a variety of viewpoints in recent years. As a consequence, it has become an indispensable approach for the production of a lubricating oil excellent in friction characteristics to incorporate additives in base stocks for lubricating oils so that the base stocks can be provided with desired friction characteristics.
Accordingly a number of friction modifiers have been proposed to date, resulting in the use of fatty acids and their metal salts, alcohols, esters, amines and the like - all of which are of the oiliness improver type - and phosphate esters, phosphite esters, zinc dithiophosphate and the like - all of CA 0223'7446 1998-0',-22 which are of the extreme pressure agent type - in automatic transmission fluids,wet brake oils, sliding surface oils, plastic working oils and the like and also in the use of phosphate esters, phosphite esters, acidic phosphite ester amine salts, molybdenum dithiophosphate, molybdenum dithiocarbamate and the like - all of which are of the extreme pressure agent type - in engine oils, gear oils, cutting oils and the like.
Meanwhile, an automatic transmission fluid was disclosed, which had been obtained by adding magnesium sulfonate used as a metallic detergent, especially over-based magnesium sulfonate having a base number of 300 mg-KOH/g or greater in a base stock in order to improve its friction characteristics (see JP Kokai 62-84190). Further, it has also been proposed to use calcium salicylate as a friction coefficient modifiers for automatic trans-mission fluids (see JP Kokai 5-163496).
No matter whether these conventionally-proposed friction modifiers are of the organic type or of the metallic type, their friction reducing effects are however not sufficient depending on the use conditions. All of them are still insufficient in assuring stable friction reducing effects as typified by magnesium sulfonate, calcium salicylate and the like the effects of which vary significantly depending on the kind, use conditions and the like of a lubricating base stock, although they provide friction reducing effects to some extents.
Therefore they are merely adjuvants for friction modifiers such as phosphate esters and molybdenum dithiocarbamate.
In view of the technical developments on friction reducing technology and the circumstances of development of friction modifiers as described above, the present invention has as objects thereof the provision of a CA 0223~446 1998-0~-22 novel friction modifier having friction reducing ability and also the provision of a lubricating oil composition containing the friction modifier.
Present Invention It has been discovered that a metal phenate containing at least one chain hydrocarbon group, which has a specific linear portion determinable by a carbon nuclear magnetic resonance measurement (which may hereinafter be referred to as "13C-NMR measurement" as needed), has excellent friction reduc-ing ability. It has also been found that its addition to a base stock for lubricating oil makes it possible to furnish a lubricating oil composition having improved friction characteristics and utility in many fields. Based on these findings, the present invention has now been completed.
Namely, the present invention relates in a first aspect thereof to a friction modifier comprising at least one chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, characterizedin that said chain hydrocarbon group has an alkyl chain linearity of 20% or higher as dele~ hled by a carbon nuclear magnetic resonance measurement (13C-NMR measurement).
The present invention also relates in a second aspect thereof to a lubricating oil composition characterized in that said lubricating oil composition comprises:
a lubricating base stock; and at least one chain-hydrocarbon-group-substituted metal phenate substituted by a~ least one chain hydrocarbon group, said chain hydrocarbon CA 0223~446 1998-0~-22 group having an alkyl chain linearity of 20% or higher as determined by a carbonnuclear magnehc resonance measurement (13C-NMR measurement), and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on a whole weight of said lubricahng oil composlhon.
The present invenhon will hereinafter be described in detail.
The chain-hydrocarbon-group-substituted metal phenate, which is used as an effective component of the friction modifier according to the presentinvention, is formed basically of a phenol component, which carries at least onechain hydrocarbon group bonded thereto, and a metal component. The above metal phenate may be subjected to sulfurization to contain compounds with two or more aromahc groups bonded together by one or more sulfur atoms, respec-tively, and the above metal phenate may also contain one obtained by subjecting it to an over-basing treatment as needed.
As the chain hydrocarbon group in the chain-hydrocarbon-group-subshtuted metal phenate according to the present invention, those capable of meehng the following requirements are suitable.
As such, the following requirements can be mentioned:
(i) an alkyl group having an average carbon number of 12 or more per hydroxyl group; and (ii) said alkyl group having a linearity of 20% or higher, CA 0223~446 1998-0~-22 both being as determined by a l3C-NMR measurement.
Describing about the above requirement (i), it is important for the exhibition of friction reducing effects that the chain hydrocarbon group of the chain-hydrocarbon-group-substituted metal phenate according to the present invention is an alkyl group having an average carbon number of 12 or more per hydroxyl group. In particular, an alkyl group having an average carbon number of from 12 to 40 is preferred. An average carbon number smaller than 12 involves a potential problem that sufficient friction reducing effects may not be obtained.
Describing further, as chain-hydrocarbon-group-substituted metal phenate according to the present invention, one containing at least one or more alkyl groups having 12 to 30 carbon atoms is particularly preferred.
By the way, the term "hydroxyl group" as used herein means an -OH group existing in a chain-hydrocarbon-group-substituted metal phenate in a form as converted under 13C-NMR measuring conditions.
The term "average carbon number per hydroxyl group" as used herein indicates an average carbon number of an alkyl group as calculated by a 13C-NMR measurement by supposing that an aromatic carbon bonded to a hydroxyl group is 1.
Specific examples of the above-described alkyl group can include dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, triacontyl, pentatriacontyl, and octatriacontyl.
CA 0223~446 1998-0~-22 One of principal features of the present invention resides in that the above alkyl group has a specific linearity as determined by a 13C-NMR measure-ment as indicated above under the requirement (ii), and is a requirement indispensable for the unique chain-hydrocarbon-group-substituted metal phenate according to the present invention.
Namely, the chain-hydrocarbon-group-substituted metal phenate according to the present invention is one having an alkyl chain linearity of 20%or higher, preferably 30% or higher as determined by a 13C-NMR measurement.
Here, the term "alkyl chain linearity" is based on a unique concept established by the present inventors as a result of repetition of numerous experi-ments, and means the ratio of the number of carbon atoms in a linear portion located 5 or more carbon atoms apart from an end of the alkyl group or 4 or more carbon atoms apart from a branched site of the alkyl group to the total number of carbon atoms in the alkyl group. Accordingly, the alkyl chain linearity varies depending on the substituting site of the aromatic group to thealkyl group or the site of branching of the alkyl group. Specifically, the chain linearity is determined specifically by the following formula from a 13C-NMR
measurement.
Alkyl chain linearity (%) =
Integral intensity over a chemical shift range of from 29 ppm to 31 ppm Sum of all integral intensity over a chemical x 100 shift range of from S ppm to 60 ppm CA 0223~446 1998-0~-22 Incidentally, the 13C-NMR measurement was conducted by converting the metal phenate into its corresponding alkyl phenol.
The present inventors were interested in the existence of a correla-tion between the linearity of the alkyl group or groups in the chain-hydrocarbon-group-substituted metal phenate and its friction reducing effects, and have ascertained that the metal phenate exhibits better friction reducing effects as the alkyl chain linearity becomes higher and also that an alkyl chain linearity lower than 20% cannot exhibit the effects fully although an alkyl chain linearity of 20%
or higher, especially of from 30% to 80% shows particularly marked effects.
In the present invention, a chain-hydrocarbon-group-substituted metal phenate excellent in friction reducing effects can still be obtained provided that its alkyl chain linearity as determined by a 13C-NMR measurement is 20%
or higher, even when the chain-hydrocarbon-group-substituted metal phenate contains two or more hydrocarbon groups per hydroxyl group or is a mixture of two or more different compounds (metal phenates). That is, the overall alkyl chain linearity is 20% or higher. In particular, a metal phenate, hydrocarbon groups of which are each a linear alkyl group having 12 or more carbon atoms, ispreferred from the viewpoint that it can substantially improve friction reducingeffects.
The metal component represented by M in the formula (I) of the chain-hydrocarbon-group-substituted metal phenate according to the present invention can be an alkali metal or an alkaline earth metal. Further, a metal of an atomic number in a range of from 12 to 56 is also suited. Specific examples of suitable metals can include sodium, potassium, lithium, calcium, magnesium and barium. In addition, aluminum, zinc, tin, chromium, copper, cobalt and the like CA 0223~446 1998-0~-22 are also effective. Particularly preferred are alkaline earth metals such as calcium, magnesium and barium.
Typical illustrative compounds of the chain-hydrocarbon-group-substituted metal phenate according to the present invention can be represented by the following formulas (I) to (II):
O M O
(Rl)n (R2)n (I) ~ [~/
O M O
(Rl)n (R2)n '~1 sx ~' In each of the above formulas (I) and (II), Rl and R2 are alkyl groups which may be the same or different, the average carbon number of the total carbon number of Rl and the total carbon number of R2, said average total carbon number being equivalent to the number of carbon atoms per hydroxyl group, may preferably be from 12 to 40, and the alkyl chain linearity as deter-mined by a 13C-NMR measurement is 20% or higher. Specific examples of the alkyl group can include dodecyl, tridecyl, tetradecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, and triacontyl.
, CA 0223'7446 1998-0',-22 In each formula, M is appropriately an alkaline earth metal, although it can be other divalent metals described above. n indicates the numberof alkyl groups substituted on the aromatic group and is an integer of from 1 to5, preferably an integer of 1 to 2. In the respective formulas, they can be the same or different. Further, x is an integer of from 1 to 5 in the formula (II).
In the present invention, the chain-hydrocarbon-group-substituted metal phenate can specifically be a metal salt of an alkylphenol or alkylphenol sulfide, which can be a basic salt or over-based salt in addition to a neutral salt.
Its salt type can be chosen as desired depending on its application. The metal salt of the alkylphenol or alkylphenol sulfide can be prepared by a reaction between the alkyl phenol or alkylphenol sulfide and a metal compound, for example, an oxide, hydroxide, alkoxide or the like. The over-based salt can be obtained by a method known per se in the art. On the other hand, the alkyl-phenol sulfide can be produced by reacting the alkylphenol with sulfur or a sulfur-contAining compound such as hydrogen sulfide and is obtained in the form of a mixture that two or more phenol groups are bonded by one or more sulfur atoms, respectively.
A metal phenate mixture with an alkyl chain linearity controlled within the above-described specific range can also be obtained by mixing variousmetal phenates of different alkyl chain linearities.
According to the present invention, a friction modifier comprising such a specific chain-hydrocarbon-group-substituted metal phenate as described above can be provided. This friction modifier is oil-soluble. It can be used by dissolving it in a hydrocarbon or another solvent and diluting the resultant concentrate as needed or as a component of an additive package in combination with other additives.
CA 0223~446 1998-0~-22 A description will next be made about the lubricating oil composi-tion according to the present invention.
The lubricating oil composition according to the present invention contains the lubricating base stock and the chain-hydrocarbon-group-substituted metal phenate.
No particular limitation is imposed on the base stock for use in the lubricating oil composition according to the present invention. The base stock can be any one of mineral base stocks, synthetic base stocks and vegetable base stocks, or can be a blended base stock of two or more of these base stocks.
As a mineral base stock, it is possible to use, for example, a mineral oil obtained by the treatment of a lubricating oil fraction, which is inturn available by vacuum distillation of an atmosphere distillation residue of paraffin-base, neutral or naphthene-base crude oil, through a refining step suchas solvent refining, hydrocracking, hydro-refining, catalytic dewaxing, solvent dewaxing or clay treatment; a mineral oil obtained by subjecting a vacuum distillation residue to solvent deasphalting and then treating the resulting deasphalted oil through the above-described refining step; a mineral oil obtained by isomerizing wax components; or a blended oil thereof. In the above solvent refining, an aromatic extraction solvent such as phenol, furfural or N-methyl-pyrrolidone can be used, whereas as a solvent for the solvent dewaxing, liquefied propane, MEK/toluene, MEK/MIBK, or the like can be used. Among the above-described mineral base stocks, hydro-refined oil is preferred from the standpoint of quality such as oxidation stability, and one containing, for example, 2 wt% or less of aromatic hydrocarbons and 90 wt% or more of saturated hydrocarbons CA 0223~446 1998-0~-22 can be used although the preferred mineral base stock varies depending on the application purpose of the lubricating oil.
Examples of synthetic base stocks, on the other hand, can include poly(a-olefin) oligomers; polybutene; alkylbenzenes; polyol esters such as trimethylolpropane esters and pentaerythritol esters; polyoxyalkylene glycols;
polyoxyalkylene glycol esters; polyoxyalkylene glycol ethers; dibasic acid esters;
phosphate esters; and silicone oils. These base stocks can be used either singlyor in combination.
Further, usable examples of vegetable base stocks can include rape seed oil, palm oil, coconut oil, olive oil and sunflower oil.
As a lubricating base stock such as that described above, it is possible to use a blended base stock obtained by suitably blending plural base stocks so that the blended base stock has a viscosity and other properties desired for the intended application of the lubricating oil composition. For example, it is preferred to control the kinematic viscosity at 1 00~C in a range of from 2 mm2/s to 30 mm2/s, especially from 3 mm2/s to 10 mm2/s for a lubricating oil for internal combustion engines, the kinematic viscosity at 100~C in a range of from2 mm2/s to 30 mm2/s, especially from 3 mm2/s to 15 mm2/s for an automatic transmission fluid, and the kinematic viscosity at 4~C in a range of from 10 mm2/s to 1,000 mm2/s, especially from 20 mm2/s to 500 mm2/s.
The chain-hydrocarbon-group-substituted metal phenate for use in the lubricating oil composition according to the present invention can be added to the lubricating base stock in a proportion of from 0.01 to 10 wt%, preferablyfrom 0.05 to 5 wt% based on the whole weight of the lubricating oil composition or in a proportion of from 1 ppm to 10,000 ppm, preferably from 50 ppm to CA 0223~446 1998-0~-22 5,000 ppm in terms of the metal, although the proportion varies depending on theapplication field of the lubricating oil.
To the lubricating oil composition according to the present inven-tion, it is possible to add selected ones of viscosity index improvers, ashless dispersants, anti-oxidants, extreme pressure agents, wear inhibitors, metal deactivators, pour-point depressants, rust inhibitors, other friction modifiers and other additives as needed.
Illustrative usable examples of the viscosity index improvers can include polymethacrylates, polyisobutylenes, ethylene-propylene copolymers, and hydrogenated styrene-butadiene copolymers. These viscosity index improvers are used generally in a proportion of from 3 wt% to 35 wt%.
Illustrative of the ashless dispersants can be polybutenyl-succinimides, polybutenylsuccinarnides, benzylamines, and succinate esters.
They can be used generally in a proportion of from 0.05 wt% to 7 wt%.
Illustrative examples of the anti-oxidants can include amine-type anti-oxidants such as alkylated diphenylamines, phenyl-a-naphthylamine and alkylated phenyl-a-naphthylamines; phenolic anti-oxidants such as 2,6-di-t-butylphenol and 4,4'-methylene-bis(2,6-di-t-butylphenol); and zinc dithio-phosphate. They can be used generally in a proportion of from 0.05 wt% to 5 wt%.
Illustrative of the extreme pressure agents can be dibenzyl sulfide and dibutyl disulfide. They can be used generally in a propoltion of from 0.05 wP/O to 3 wt%.
CA 0223~446 1998-0~-22 Illustrative examples of the metal deactivators can include benzo-triazole, benzotriazole derivatives, and thiadiazole. They can be used generallyin a proportion of from 0.01 wt% to 3 wt%.
Illustrative of the pour-point depressants can be ethylene-vinyl acetate copolymers, chlorinated paraffin-naphthalene condensation products, polymethacrylates, and polyalkylstyrenes. They can be used generally in a proportion of from 0.1 wt% to 10 wt%.
Illustrative of the wear inhibitors can be phosphate esters, zinc thiophosphate, and sulfur compounds. They can be used generally in a propor-tion of from 0.01 wt% to 5 wt%.
As preferred embodiments of the present invention, it is possible to provide:
(i) a friction modifier for lubricating oils, which comprises chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 20% or higher as determined by a 13C-NMR measure-ment.
(ii) a friction modifier for lubricating oils, which comprises chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 25% or higher as determined by a 13C-NMR measure-ment.
CA 0223~446 1998-0~-22 (iii) A lubricating oil composition comprising:
a lubricating base stock; and chain-hydrocarbon-group-substituted metal phenate, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and a chain linearity of 20% or higher as determined by a 13C-NMR measurement, and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition.
(iv) A lubricating oil composition comprising:
a base stock composed of a hydro-ref1ned oil containing 2 wt% or less of aromatic hydrocarbons and 90% or more of saturated hydrocarbons; and chain-hydrocarbon-group-substituted metal phenate, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 per hydroxyl group and an alkyl chain linearity of 20% or higher as determined by the 13C-NMR measurement, and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition.
(v) A lubricating oil composition comprising:
a lubricating base stock; and CA 0223~446 1998-0~-22 metal phenate substituted by at least one chain hydrocarbon group, wherein the chain hydrocarbon group is an alkyl group having an average carbon number of from 12 to 40 a hydroxyl group and an alkyl chain linearity of 20% or higher as determined by the 13C-NMR measurement, said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on the whole weight of the lubricating oil composition, and at least one of 4 wt% to 30 wt% of a viscosity index improver, 0.1 wt% to 5 wt% of an ashless dispersant, 0.1 wt% to 2.5 wt% of an extreme pressure agent, 0.1 wt% to 3 wt% of an anti-oxidant, 0.1 wt% to 3 wt% of a wear inhibitor, 0.15 wt% to 8 wt% of a pour-point depressant and 0.01 wt% to 2 wt% of a metal deactivator can be added.
As has been described above, the friction modifier according to the present invention, which comprises the chain-hydrocarbon-group-substituted metal phenate, is useful for various fuels and lubricating oils, and the lubricating oil composition according to the present invention, which contains the friction modifier, can be used as hydraulic working oils, wet brake oils, sliding surfaceoils, plastic working oils, cutting oils and the like in addition to automatic trans-mission fluid compositions, lubricating oil compositions for internal combustionengines, and gear oils. It can also be used without limitations in lubricating oils and fuel oils in any fields insofar as the friction reducing effects of the metal phenate can be exhibited.
Examples The present invention will next be described specifically by Examples and Comparative Examples. It is however to be noted that the Examples and the like are to primarily demonstrate the friction reducing effectsof certain chain-hydrocarbon-group-substituted metal phenates (hereinafter may CA 0223~446 1998-0~-22 be referred to as "metal phenates" as needed) according to the present inventionand that the present invention shall not be limited by these Examples and the like.
The alkyl chain linearities of metal phenates employed in the following Examples and the like and, as performance evaluation of lubricating oil compositions, friction coefficients were measured by the following methods.
(i) Measuring method of alkyl chain linearity:
Each metal phenate was converted into its corresponding alkylphenol, and under the following measuring conditions, its 13C-NMR spectrum was measured. Further, its alkyl chain linearity was calculated in accordance with the below-described formula.
Measuring conditions Used instrument EX400 (manufactured by JEOL Ltd.) Observed nucleus 13C
Observing frequency 100.50 MHz Measuring mode Inverse gated lH decoupling Internal standard TMS (= 0 ppm) Relaxation reagent Cr(acac)3 Solvent CDCl3 Quantity of sample 300 mg Temperature 30~C
CA 0223~446 1998-0~-22 Alkyl chain linearity (%) =
Integral intensity over the chemical shift range of form 29 ppm to 31 ppm Sum of all integral intensity over the chemical x 100 shift range of from 5 ppm to 60 ppm (ii) Performance evaluation Friction coefficient measuring method:
Concerning each lubricating oil composition added with its corresponding metal phenate in a predetermined proportion, its friction coefficient was measured under the following conditions by using "LFW- 1 " as a testing machine.
Friction materials: Steel/steel Load: 200 lb Oil temperature: 80~C
Revolution speed: 600 rpm Measuring period: 30 min Example 1 Provided was Calcium Phenate 1 (total base number:
85 mg-KOHlg), which had an average alkyl carbon number of 19 per hydroxyl group and an alkyl chain linearity of 45.3%. A lubricating oil composition was formulated by adding the phenate to a refined mineral oil " 1 00SN" (4.2 mm2/s at 100~C) as a lubricating base stock in a proportion of 140 ppm in terms of calcium based on the whole weight of the lubricating oil composition. The CA 0223~446 1998-0~-22 friction coefficient of the resultant lubricating oil composition was measured by the above-described method. It was found to be 0.10.
Example 2 A lubricating oil composition was formulated in exactly the same manner as in Example I except that the proportion of Calcium Phenate 1 was increased from 140 ppm to 560 ppm in terms of calcium. When subjected to a performance evaluation, its friction coefficient was found to be 0.09.
Example 3 Provided was Calcium Phenate 2 (total base number: 260 mg-KOH/g), which had an average alkyl carbon number of 20 per hydroxyl group and an alkyl chain linearity of 28.2%. A lubricating oil composition was form~ ted by adding the phenate to a lubricating base stock, which was the same as that employed in Example 1, in a proportion of 950 ppm in terms of calcium based on the whole weight of the lubricating oil composition. The resultant lubricating oil composition was subjected to the above-described performance evaluation. Its friction coefficient was found to be 0.09.
Example 4 A lubricating oil composition was formulated in exactly the same manner as in Example 3 except that the proportion of Calcium Phenate 2 was increased from 950 ppm to 1,900 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.09.
. ~ CA 0223~446 1998-0~-22 Example S
A lubricating oil composition was formulated in exactly the same manner as in Example 3 except that the propoltion of Calcium Phenate 2 was increased to 5,700 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.09.
Comparative Example 1 The lubricating base stock, i.e., the purified mineral oil alone was subjected to a performance evaluation. Its friction coefficient was found to be 0.l4.
Comparative Example 2 Provided was Calcium Phenate 3 (total base number: 250 mg-KOH/g), which had an average alkyl carbon number of 20 per hydroxyl group and an alkyl chain linearity of 15.5%. A lubricating oil composition was formulated by adding the phenate to a refined mineral oil, which was the same asthat employed in Example 1, in a proportion of 950 ppm in terms of calcium based on ~e whole weight of the lubricating oil composition. As a result of a performance evaluation, its friction coefficient was found to be 0.14. No advantageous effect was available from the addition of Calcium Phenate 3 the alkyl chain linearity of which is lower than 20%.
~ CA 0223~446 1998-0~-22 Comparative Example 3 A lubricating oil composition was formulated in exactly the same manner as in Comparative Example 2 except that the proportion of Calcium Phenate 3 was increased to 5,700 ppm in terms of calcium. The resultant lubricating oil composition was subjected to a performance evaluation. Its friction coefficient was found to be 0.13.
The kinds and properties of the calcium phenate used in the Examples and the like are shown in Table 1, and the results of the performance evaluations of the lubricating oil compositions are summarized in Table 2.
Average Alkyl Carbon Number Per Alkyl Chain Total Base Kind Hydroxyl Group Linearity Number CalciurnPhenate 1 19 45.3% 85 mg-KOH/g Calcium Phenate 2 20 28.2% 260 mg-KOH/g Calcium Phenate 3 20 15.5% 250 mg-KOH/g Example Comparative Example Base stock Refinedmineral oil, lOOSN D
Proportion of additive (Ca conc.. ppm) CalciumPhenate 1 140 560 - - - - - ,~, Calcium Phenate 2 - - 950 1900 5700 - - - ' CalciumPhenate 3 - - - - - 950 5700 ~n Performance evaluation Friction coefficient 0.10 0.09 0.09 0.09 0.09 0.14 0.14 0.13 CA 0223~446 1998-0~-22 From the above Examples and Comparative Examples, it is apparent that a low frictional coefficient can be obtained from a chain-hydrocarbon-group-substituted metal phenate of an alkyl chain linearity of 20%
or higher even if it is added in a small proportion (Example 1), but it is also clear from a comparison among Comparative Examples 1, 2 and 3 that a metal phenate of an alkyl chain linearity lower than 20% cannot bring any significant improve-ment in frictional coefficient even if its proportion is increased. From these results, it has become evident that the alkyl chain linearity is a principal factor governing friction reducing ability.
From this it is seen that a in-hydrocarbon-group-substituted metal phenate having an alkyl chain linearity of 20% or higher has high friction reducing effects, is useful as a friction modifier especially for lubricating oils, and can improve the friction characteristics of lubricating oil compositions.
Claims (9)
1. A friction modifier comprising chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, characterized in that said chain hydrocarbon group has an alkyl chain linearity of 20% or higher as determined by a carbon nuclear magnetic resonance measurement (13C-NMR measurement).
2. The friction modifier comprising chain-hydrocarbon-group-substituted metal phenate as defined in claim 1, wherein said chain hydrocarbon group is an alkyl group.
3. The friction modifier of claim 2 wherein the chain hydrocarbon group is one or more alkyl group each of which has 12-40 carbon atoms on average per hydroxyl group as measured by 13C-NMR measurement.
4. The friction modifier of claim 1, 2 or 3 wherein the chain hydrocarbon group has an alkyl chain linearity of 30% or higher as determined by 13C-NMR measurement.
5. A lubricating oil composition characterized in that said lubricating oil composition comprises:
a lubricating base stock; and chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, said chain hydrocarbon group having an alkyl chain linearity of 20% or higher as determined by a carbon nuclear magnetic resonance measurement (13C-NMR measurement), and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on a whole weight of said lubricating oil composition.
a lubricating base stock; and chain-hydrocarbon-group-substituted metal phenate substituted by at least one chain hydrocarbon group, said chain hydrocarbon group having an alkyl chain linearity of 20% or higher as determined by a carbon nuclear magnetic resonance measurement (13C-NMR measurement), and said metal phenate having been added in a proportion of from 1 ppm to 10,000 ppm in terms of the metal thereof based on a whole weight of said lubricating oil composition.
6. The lubricating oil composition of claim 5 wherein the chain hydrocarbon group is an alkyl group.
7. The lubricating oil composition of claim 6 wherein the chain hydrocarbon group is one or more alkyl group each of which has 12-40 carbon atoms on average per hydroxyl group as measured by 13C-NMR measurement.
8. The lubricating oil composition of claim 5, 6 or 7 wherein the chain hydrocarbon group has an alkyl chain linearity of 30% or higher as determined by 13C-NMR measurement.
9. The lubricating oil composition of claim 5, 6 or 7 further containing at least one additive selected from the group consisting of viscosityindex improvers, ashless dispersants, anti-oxidation inhibitors, extreme pressure agents, wear inhibitors, metal deactivators, pour point depressants, rust inhibitors, other friction modifiers.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP171166/97 | 1997-06-12 | ||
| JP17116697 | 1997-06-12 | ||
| JP10409498A JPH1161164A (en) | 1997-06-12 | 1998-03-31 | Friction reducing agent comprising metallic phenate and lubricating oil composition containing the same |
| JP104094/98 | 1998-03-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2235446A1 true CA2235446A1 (en) | 1998-12-12 |
Family
ID=26444637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2235446 Abandoned CA2235446A1 (en) | 1997-06-12 | 1998-05-22 | Friction modifier comprising metal phenate and lubricating oil composition containing the same |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0884379B1 (en) |
| JP (1) | JPH1161164A (en) |
| CA (1) | CA2235446A1 (en) |
| DE (1) | DE69800723T2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4673465B2 (en) * | 2000-05-17 | 2011-04-20 | 東燃ゼネラル石油株式会社 | Lubricating oil composition |
| US9144801B2 (en) | 2010-08-31 | 2015-09-29 | Abbott Laboratories | Sample tube racks having retention bars |
| JP5211126B2 (en) * | 2010-09-30 | 2013-06-12 | 東燃ゼネラル石油株式会社 | Lubricating oil composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1246615A (en) * | 1982-05-22 | 1988-12-13 | Charles Cane | Process for the production of alkaline earth metal alkyl phenates |
| JPH04183792A (en) * | 1990-11-19 | 1992-06-30 | Idemitsu Kosan Co Ltd | Perbasic sulfurized alkaline earth metal phenate and use thereof |
| US5320762A (en) * | 1993-03-12 | 1994-06-14 | Chevron Research And Technology Company | Low viscosity Group II metal overbased sulfurized C12 to C22 alkylphenate compositions |
| GB9305417D0 (en) * | 1993-03-16 | 1993-05-05 | Ethyl Petroleum Additives Ltd | Gear oil lubricants of enhanced friction properties |
| GB9324208D0 (en) * | 1993-11-25 | 1994-01-12 | Bp Chemicals Additives | Lubricating oil additives |
| GB9400415D0 (en) * | 1994-01-11 | 1994-03-09 | Bp Chemicals Additives | Detergent compositions |
| GB9520295D0 (en) * | 1995-10-04 | 1995-12-06 | Ethyl Petroleum Additives Ltd | Friction modification of synthetic gear oils |
-
1998
- 1998-03-31 JP JP10409498A patent/JPH1161164A/en active Pending
- 1998-05-22 CA CA 2235446 patent/CA2235446A1/en not_active Abandoned
- 1998-06-12 EP EP98110773A patent/EP0884379B1/en not_active Expired - Lifetime
- 1998-06-12 DE DE1998600723 patent/DE69800723T2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH1161164A (en) | 1999-03-05 |
| EP0884379B1 (en) | 2001-04-25 |
| EP0884379A1 (en) | 1998-12-16 |
| DE69800723T2 (en) | 2001-08-16 |
| DE69800723D1 (en) | 2001-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2163206C (en) | Lubricating oil composition | |
| EP0768366B1 (en) | Lubricating oil composition | |
| US5696065A (en) | Engine oil composition | |
| CN102317418A (en) | Continuously variable transmission oil composition | |
| WO1996037582A1 (en) | Lubricating oil composition | |
| CN104395446A (en) | Lubricating oil composition | |
| CN101952400A (en) | Cylinder lubricating oil composition for crosshead type diesel engine | |
| RU2659785C2 (en) | Polyglycerol ether based lubricating composition | |
| CA2210974C (en) | Lubricating oil composition | |
| EP0855437A1 (en) | Lubricating oil composition | |
| CA2235701C (en) | Friction modifier comprising metal sulfonate and lubricating oil composition containing the same | |
| JP2016506996A (en) | Lubricant compositions based on amine compounds | |
| EP0418860B1 (en) | Lubricating composition for internal combustion engine | |
| EP0884379B1 (en) | Method for reducing the friction of lubricating oils by the use of metal phenates | |
| CA2235292C (en) | Friction modifier comprising metal salicylate and lubricating oil composition containing the same | |
| US11499115B2 (en) | Lubricant composition | |
| JPH09235579A (en) | Lubricating oil composition | |
| CN113811592A (en) | Use of a lubricating composition for a transmission | |
| JP3746365B2 (en) | Lubricating oil composition | |
| JPH07150173A (en) | Lubricating oil composition | |
| EP0881276A2 (en) | Lubricating oil composition containing a mixture of metal salts of aromatic organic acids | |
| JPH07331269A (en) | Lubricating oil composition | |
| KR20230005366A (en) | Lubricating composition for reducing wear of DLC parts used in internal combustion engines | |
| WO1996037584A1 (en) | Lubricating oil composition | |
| KR20230042293A (en) | Oxidation-stable lubricant composition for automotive transmissions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Dead |