CA2233913A1 - Improvements in and relating to hollow fiber identification - Google Patents

Abstract

Hollow fibers are differentiated by their void being partially filled with a differentiating characteristic that is a protuberance of characterizing polymer material. This material may be the same or different from that of the rest of the fiber. The protuberance is provided by appropriate adjustment of the spinning capillary, i.e., during extrusion to form the fiber.

Description

W O 97/13896 PCTrUS95/12800 TIT~,F, Improvements In and Relating To Hollow Fiber Identification This invention concerns improvements in and relating to fiber identification, and includes a novel method of making a hollow fiber with a characteristic by which it can later be identified, novel hollow fibers so marked as to be identifi~ble, and products and materials including such marked fibers, especially fiberfill filling materials (often referred to shortly as "fiberfill") and products, including batts, fiberballs and other products compri~in~ such marked fibers and m~teri~l~ comprising them, and processes and a~al~lus for obtaining such hollow fibers and their products and m~t~ri~
A fiber m~nllfslcturer's customers t1em~n~1 con~ict~ncy in performance from the fibers provided by the m~nllf~-~tllrer. In other words, the m~nllf~tllrer's customers require that the pl~pcl Lies of any particular fiber not vary ~lcciably from batch to batch of that fiber as the di~ L batches of that fiber are produced over several years. The fiber m~nllf~tllrer, however, has a need to be able to identify fiber from different production batches, while IllA;l~ the consistency and uniformity that the customers require. Much notoriety has been given to fiber identification in criminology, for example, as a way to bring murderers or othercrimin~l~ to justice. Manufacturers also, however, have other more mnnci~ne and practical reasons for needing to identify the production batch of particular fibers.
So it has long been desirable to find a cheap yet effective system for identifying fibers. Previously, for instance, one method has been to add a chemical or nuclear marker to the fiber, but this method has added expense and complications and hashad disadvantages, such as the ease with which some one other than the fiber m~nnf~stllrer can add the same marker, after m~nllf~tllre, and so confuse this system for identification.
In particular, there has long existed a need for an economical way to identify and differentiate resilient hollow fibers (especially polyester hollow fibers) that are crimped and used as fiberfill in products such as batts, fiberballs and other filling m~t~ri~ and filled articles, such as pillows, filled apparel, comforters, cushions and such like bedding and filrni~hin~ material. Such crimped hollow fibers have a single continuous void throughout the fiber length and include those disclosed by Tolliver in U.S. Patent No. 3,772,137, having a void content of about 13 percent to about 25 percent, and a crimp frequency of about 5 to about 12 crimps per inch (about 2 crimps per cm to about 5 crimps per cm), and a crimp index of about 25 to about 35. As indicated, it is important that any identifier system should not change the performance and ~.o~ ies of the fibers.

CA 022339l3 l998-04-02 W O 97/13896 PCTrUS95/12800.

The present invention solves this need to identify and dirr~ielltiate hollow fibers by providing a visual identifying marker in the configuration of the cross-section of the hollow fiber. This marker identifies the hollow fiber only visually, i.e., without significantly affecting performance of the fiber. Fibers with 5 such a visual identifying marker according to the present invention are often referred to herein as "identifier fibers" (or "identifier filarnents").
The terms "fiber" and "fil~ment" are often used herein inclusively, ~,vithout intt?ntling that use of one term should exclude the other.
Accordingly, this invention provides a process for pl~ lg hollow 10 fil~m~nts of a synthetic polymer, comprising the steps of post-co~lecc~nce melt-spinning the synthetic polymer through arc-shaped segmentecl spinning capillary orifices that form a cegmented periphery so the resulting freshly-spun molten strearns coalesce and form continuous hollow fil~ment~ having a continuous inside surface, and qnenching to solidify the hollow fil~mentc, and, if desired,15 drawing the resultant solid hollow filaments, and/or further processing, and/or collv~..Lillg to staple fiber, characterized in that molten polymer is also spun in small amount through a separate small orifice that is located within the said segmented periphery so as to form a small protuberance that is visually iclentifi~ble on the inside surface of the hollow filaments. As indicated hereinafter, the resulting protuberance should desirably be small enough that the degree of irregularity (as defined herein) of the hollow cross-section of the hollow fil~ment is less than 5%.
According to a another aspect, this invention provides, as new articles, hollow fibers that are of a synthetic polymer, and that have a single continuousvoid throughout their fiber length, a void content of up to 30%, and a hollow cross-section that shows characteristic polymer material that protrudes into thesingle continuous void from an inside surface of the single continuous void, said hollow cross-section having a degree of irregularity (as defined herein) of lessthan 5%.
According to a further aspect, this invention provides, as new articles, fiberfill filling m~teri~l comprising resilient crimped hollow filling fibers that are of a synthetic polymer, wherein each of said hollow filling fibers has a single continuous void throughout its fiber length, and a void content of up to 30%, and Whe~hl said fiberfill filling material is identified by all or a predetermined proportion of said fibers having a hollow cross-section that shows characteristic polymer material that protrudes into the single continuous void from an inside surface of the single continuous void, said hollow cross-section having a degree of irregularity (as defined herein) of less than 5%.

W O 97/13896 PCT~US9S112800 A degree of irregularity of a hollow cross-section of a hollow fiber is - defined hereby in the sense that the hollow cross-section has a protruding part that protrudes into the hollow cross-section from an inside surface and the degree ofirregularity is calculated, as a percentage, by dividing the area of the protruding S part by the sum of the area of the protruding part and of the area of the hollow section (and multiplying x 100 to get the percentage); this definition distinguishes between the area of the protruding part, and the area of the hollow section (i.e., the cross-sectional area of the void).
According to other aspects disclosed herein, fiberfill (and including filled articles thereof) is provided wherein said fiberfill comprises resilient crimped hollow filling fibers of synthetic polymer, and wherein, e.g., at least 10 percent by weight of said fibers have a single continuous void throughout the fiber length, and have a cross-section which shows that characteristic polymer m~teri~l protrudes from a wall (i.e., from an inside surface of such void) into such void, whereby said characteristic protruding polymer material dirrclcllLially icl~ntifies said fiber from similar synthetic polymer fibers that do not contain any such protruding polymer m~ten~l but does not significantly differentiate the ~c.r~ .ance properties (as filling material) of said fiber from said similar fibers.
Thus, according to the invention, polymer material protruding from the internal surface of the single void of a (first) fiber of a synthetic material is used to identify said (first) fiber and differentiate it from other hollow fibers of similar cross-section and having similar performance characteristics to those of the first (identified and dirrclcllLiated) fiber, except, of course, that the other fibers do not have the polymer material protruding from the internal surface of the wall of the fiber.
There are also provided hollow synthetic polymer fibers, having a single continuous void throughout their fiber length, wherein the cross-section of the fiber shows that charactèristic polymer material protrudes from a wall into such void, whereby said ~h~r~ct~ristic protruding polymer material differentially identifies said fiber from similar synthetic polymer fibers that do not contain any such protruding polymer material but does not significantly dirr~lcllLiate the performance properties of said fiber from said similar fibers.
Other aspects include methods, d~ lldLUS and products disclosed herein.
Preferred features include using polyester polymer as the material for the synthetic polymer of the fiber and/or the characteristic polymer material, and preferably for both.

W O 97/13896 PCT~US95/12800.

In most respects, the fiberfill filling material and resilient crimped hollow filling fibers of the invention are prepared conventionally by methods known in the art, such as referred to herein. Preferred hollow fibers are prepared from polyester polymers, especially poly(ethylene terephth~l~te), and this preferred embodiment is described herein more particularly, for convenience, it being understood that approl~l;ate modification can be rnade by those skilled in the art for other synthetic polymers, such as polyamides or polypropylene, to take account of their differences, e.g., in melting conditions and properties, such as melt viscosity. One such disclosure in the art is Tolliver U.S. Patent No.
3,772,137, which discloses hollow synthetic fil~mentc and a spinneret capillary for spinning such fil~mentc co..l;~ g a single continuous void from synthetic polymers, including polyesters, in Figures 1, 3 and 5 thereof.
Figures 1-4 are magnified photographs of cross-sections of as-spun filz~mentc according to the invention, as described hereinafter.
Figure 5 is a magnified photograph of cross-sections of conventional hollow as-spun filaments according to the prior art.
Figure 6 is an enlarged view of a spinneret capillary, taken looking at the lower face of the spinneret, for spinning preferred fil~mentc of the invention as in Figs. 1-4.
Figure 7 is a magnified photograph showing preferred fibers of the invention, and not only a cross-section, but also that the fibers are crimped, as described later herein.
Referring to Figure 6 of the accompanying drawings, showing an enlarged view of a spinneret capillary for spinning fil~ment.c of the present invention, the similarity to that of Figure S of Tolliver will be noted. The capillary is formed of four individual segments deci~n~ted generally 11, 12, 13 and 14 in the form of peripheral slots 19, 20, 21, 22 that are curved to form arcs of an incomplete circle. At each end of each peripheral slot, 19, 20, 21 and 22, are "tabs" 23 and 24, 25 and 26, 27 and 28, and 29 and 30, respectively, being enlarged ends of said slot to assist in post-co~lescence of the emerging molten polymer to form the desired hollow solid fil~ment, as is known in the art, such as Tolliver, U. S. Patent No. 3,772,137. An important and novel difference in Figure 6 herein (that differentiates from Figure 5 of Tolliver) is the provision of an orifice 40. Molten polymer extruded through orifice 40 solidifies and coalesces on the internal wall of the hollow fil~mçnt formed by post-coalescence of molten polymer extruded through slots 11, 12, 13 and 14, to form an identifying protuberance protruding into the void on the internal wall of the iAentifiçr fiber.

W O 97/13896 PCTrUS95/12800 .

The relative location of the protuberance may vary along a length of the fil~ment as will be understood.
Cross-sections of such hollow icl~ntifier as-spun fil~ments cont~inin~ a single void with polymer that protrudes from an internal wall into such void, are 5 shown in Figures 1~, in which most of the cross-sections clearly show polymer protruding into the void. Two cross-sections in Figure 1 (at the left end of themiddle horizontal row, and in the horizontal row next below, fourth from the left end) do not clearly show polymer protruding into the void; I believe that those fil~ment cross-sections were actually similar, but that the protruding polymer 10 cannot be seen clearly, perhaps because ofthe way the fil~ment cross-sections were cut and/or because of the angle of the photograph. Other m~gnified photographs of cross-sections of identifier fil~ment~ are shown in Figures 2-4, in which the protuberances can be seen clearly, and in which the m~gnific~tions arein~ te~l Such identifier filaments have performance and properties as filling materials comparable to that of similar conventional art fil~m~-nt~ that do not contain protruding polymer and are shown in Figure 5. Fiberfill fil~m~ntc are sofine that, without magnification, it is doubtful that anyone would be able to see any void in the cross-section, or whether the filament is solid, hollow, or multi-20 void, let alone be able to recognize if any void is partially filled with protruding polymer. In other words, without making n~gnified cross-sections and ç~c~mininp and co~ a~ g them, most people would be unable to determine significant difference between fil~ment~ of the invention and conventional fil~ment~ of the art. So the object of the invention has been achieved economically by use of a 25 different spinneret capillary to give different cross-sectional configurationintern~lly, without affecting the exterior of the fil~ment or its p~lrollllance.The pc~r~ ance of the novel fibers of the present invention is the same as that of similar fibers without any protuberance. The protuberance in a fiber according to the invention does not have any effect on performance (such as 30 bulk properties) but shows up visually when the (magnified) cross-section is esr~min~-l, so the fiber acts as a (visual) identifier without affecting pt:lr,llll~lce.
Although it may prove convenient to refer to a degree of irregularity, we would have preferred to have avoided using an area-based relationship, because we prefer to make a protuberance that is visually like a sudden blip, as a longer wall 35 section with gradual thickening is not as easy to see visually, and so would not be as desirable for the recent invention. We did, however, measure the degree of irregularity for the cross-sections in Figures 1-4 herein, and they are only about 1.5%, i.e., far below 5%.

W O 97113896 PCTrUS95/12800 It will generally be desirable for the protuberance to extend -significantly and ~l~cct~hly into the void, e.g., to an amount of about 5 or 10% of the average wall thickness of the fil~ment, and not more than 35% of the averagewall thickness, bearing in mind the above. A more gentle thiekening of the wall is S not so easy to detect as a sudden significant blip. The important objective is to have a characteristic that is relatively easy to detect visually, especially when using the same polymer material.
Tolliver disclosed void contents of about 13 percent to about 25 percent for his hollow fibers, and such void contents are suitable and useful for 10 hollow fibers according to the invention, also. Hollow fibers with void contents of 15-20 percent are especially useful for fiber~lling purposes, and a wider range of void contents up to 30 percent may also be identified by providing protrudingmaterial according to the invention. The void content is generally at least 10 %, as less may not provide much distinction from solid fibers, but this will likely15 depend on the desired end-use for the fibers, as a thick wall may sometimes be more important than the void content.
It is not necessary to provide every fil~ment (i.e., 100%) with identifier, but a regulated proportion (e.g., at least about 10% by weight) of particularly-identified fil~ment~ may be included, and recorded, for a batch of 20 fiber that is sold. All fil~ment~ may, however, be provided with identifier, if desired.
Furthermore, although it is less costly, so generally preferred, to spin filaments from a single polymer, so the polymer material is the same in the protuberance as in the rest of the fil~ment, dirrclclll polymers may be used, if25 desired, so as to provide better identification for merges or batches of fiber.
As will readily be understood, the invention lends itself to many variations. For instance the number and pattern of protuberance(s) in relation to the void may be varied, to some limited extent, bearing in mind that it is generally desirable to m~imi7~ the void content to take advantage of the presence of the 30 void.
The invention is further illustrated in the following Example, all parts and percentages being by weight, unless otherwise indicated. The levels of coatings (slickeners and finishes) applied to the filaments were OWF (with regard to the weight of the fiber). Relative Viscosity (sometimes referred to as LRV) and 35 void content (by volume, by a flotation method) were determined by the methods referred to in U.S. Patent No. 4,712,988 (Broaddus et al.). Bulk mea~,ure.llents are the way the perform~ln~e of fiberfill is generally ~çs~ed and were dett rminecl by --CA 022339l3 l998-04-02 W O 97/13896 PCT~US95/lZ800 the method referred to in Tolliver U.S . Patent No. 3,772,137. Crimp properties were also measured ~-ssenti~lly as described by Tolliver.

,, ~,X~MPl,F.
Fiberfill was cut from filament~ spun from poly(ethylene terephth~l~te) of relative viscosity of 20.4 at a polymer temperature of 291 to 297~C at 1277 ypm (1167 mpm) through a spinneret with 363 capillaries with a throughput per capillary of 0.278 Ibs./ hr. (0.126 kg./hr.), using orifices as shown in Figure 6.
The fil~ments were assembled to form a rope of 922,000 relaxed drawn denier.
The rope was drawn in a conventional manner, using a draw ratio of 3.5X in a hot, wet spray draw zone m~int~ined at about 95~C. The drawn filaments were crimped in a conventional stuffer box crimper (3.5 in, 8.9 cm, size) to a crimp frequency of about 8.5 crimps per inch (about 3.3 crimps per cm), so as to obtain a Support Bulk (bulk at 0.2 psi) of about 0.6 in. (15 mm), and the crimped rope was relaxed in an oven at 180~C. The fiber had been slickened before relaxing with afinish cont~ining about 1% silicone by weight of fiber to provide an average friction of 0.30. A conventional ~nti~t~tic overlay finish of about 0.07% by weight was applied. The fibers were found to have an average void content of about 18% and a denier per fil~ment of about 6. The outside periphery of the fiber was round and smooth.
The as-spun fil~ment~ of the invention have cross sections as shown in Figures 1-4. The fil~mentc contain single continuous voids. On the inside peripheries of these voids there are protuberances which serve as an identification mark. As will be seen from the following comparison, the performance as filling material (in particular the bulk properties) of these fibers of the invention as filling material was ecs~nti~lly similar to that of conventional fibers that were similar (except for the absence of protruding material acting as a visual identificationmark).

COMPAR~ON
The above fiberfill was compared with current conventional slickened (similarly about 1 %) hollow products of the same denier (about 6) and average void content (about 18%), spun using a conventional capillary (as shown in Figure 6 but without orifice 40, i.e., more or less as shown by Tolliver in Fig. S of U. S.
Patent No. 3,772,137), and crimped similarly to a crimp frequency of about 8.75 - crimps per inch (about 3.4 crimps per cm), to provide a similar Support Bulk level of 0.59 in. (15 mm). These conventional fil~m~ nt~ (as-spun) have a cross section as shown in Figure 5. These cross sections are ~;iiLrc:.c"t from those of the CA 022339l3 l998-04-02 invention, in that they do not contain the fiber identification marker protruding from the internal wall into the void.
In the above co~ e test, where the bnlkinee~ of fiberfill comprising identifier fibers of the invention was colllpa~ed with the bnlkinP~ of 5 fiberfill compri~ing fibers of similar cross-section except that the void was clear (i.e., without identifier), the crimping of each set of fibers that were co...~dled was carried out in the same stuffer-box machine under the same conditions (using thesame velocity, te~lpe~ re profile and pressures). Figure 7 is a m~gnified photograph of crimped hollow fibers according to the invention, showing a hollow10 cross-section that is somewhat similar to the (magnified) photographs in Figs. 1 -4, except that more of the fiber can be seen so this photograph can show that this fiber has indeed been crimped conventionally, using such a stuffer-box.
The hollow fibers of the invention may be processed into products such as batts and fiberballs (sometimes referred to as clusters) and further 15 processed into pillows, filled apparel, comforters, cushions and like bedding and filrni~hing material, as disclosed in the art, including that specifically mentioned herein, and art such as LeVan, U. S. Patent Nos. 3,510,888 and 4,999,232 and various Marcus patents, including U.S. Patent Nos. 4,618,531, 4,783,364, 4,794,038, 4,818,599, 4,940,502, and 5,169,580, and U. S. Patent No. 5,088,140 20 (Belcher et al). Although, hitherto, most fiberfill has comprised cut fiber, such as has been disclosed above, there has been growing commercial interest in using deregistered tows of continuous fil~m~ntc as fiberfill, as disclosed for example by Watson in U. S. Patent Nos. 3,952,134 and 3,328,850. Accordingly, application of the invention to fiberfill in the form of deregistered tows of continuous 25 filaments is also contemplated herein, and the invention is not confined to cut fibers nor to fiberfill comprising such cut fibers. Additionally, as well understood in the art, it has been commonplace to mix or blend fibers for use as filling material. Accordingly, it is colllelllplated that fiberfill according to the invention may consist essçnti~lly entirely of identifier fibers according to the invention, or 30 these identifier fibers may be mixed with other fibers; thus, the fiberfill filling material may be identified by all or a portion of its fibers being such identifier fibers. Fiberfill, as is well understood by those skilled in the art, is shorthand for fiberfill filling material, or more shortly fiberfilling material, and refers to a bulky mass of fibers used to fill articles, such as pillows, cushions and other fi~rni~hing 35 m~t~ri~l~, including other bedding m~t~ri~l~, such as sleeping bags, mattress pads, quilts, comforters, duvets and the like, and in apparel, such as parkas and other in~ t~-cl articles of apparel, whether quilted or not. Crimp is an hllpol ~lt characteristic and provides the bulk that is an ess~nti~l requirement for fiberfill.

CA 022339l3 l998-04-02 W O 97/13896 PCT/US95/12800.

Generally, the fibers are crimped by mechanical means, usually in a stuffer-box - crimper, as described, for exarnple, in Halm et al. in USP 5,112,684. Crimp can also be provided by other means, such as asyrnrnetric qllencllin~ or using bicomponent filarnents as reported, for example, by Marcus in USP 4,618,531 and in USP 4,794,038, and in the liL~ldLul~ referred to therein, so as to provide "spiral crimp". All this is well.understood by those skilled in this art.

Claims (9)

We claim:-

1. Process for preparing hollow filaments of a synthetic polymer, comprising the steps of post-coalescence melt-spinning the synthetic polymer through arc-shaped segmented spinning capillary orifices that form a segmented periphery so the resulting freshly-spun molten streams coalesce and form continuous hollow filaments having a continuous inside surface, and quenching tosolidify the hollow filaments and, if desired, drawing the resultant solid hollow filament, and/or further processing, and/or converting to staple fiber, characterized in that molten polymer is also spun in small amount through a separate small orifice that is located within the said segmented periphery so as to form a small protuberance that is visually identifiable on the inside surface of the hollow filaments.

2. A process according to Claim 1, wherein said synthetic polymer is polyester.

3. A process according to Claim 1 or 2, wherein said synthetic polymer is polyester and said molten polymer is also a polyester.

4. A process according to Claim 3, wherein the polyester of said molten polymer is the same as that of said synthetic polymer.

5. Articles that are hollow fibers of a synthetic polymer and have a single continuous void throughout their fiber length, a void content of up to 30%, and a hollow cross-section that shows characteristic polymer material that protrudes into the single continuous void from an inside surface of the single continuous void, said hollow cross-section having a degree of irregularity (as defined herein) of less than 5%.

6. Articles that comprise fiberfill filling material comprising resilient crimped hollow filling fibers that are of a synthetic polymer, wherein said hollow filling fibers have a single continuous void throughout their fiber length, and a void content of up to 30%, and wherein said fiberfill filling material is identified by all or a predetermined proportion of said fibers having a hollow cross-section that shows characteristic polymer material that protrudes into the single continuous void from an inside surface of the single continuous void, said hollow cross-section having a degree of irregularity (as defined herein) of less than 5%.

7. Articles according to Claim 5 or 6, wherein said synthetic polymer is polyester.

8. Articles according to any of Claims 5, 6 or 7, wherein said synthetic polymer is polyester and said characteristic polymer material is also a polyester.

9. Articles according to Claim 8, wherein the polyester of said characteristic polymer material is the same as that of said synthetic polymer.