CA2225363A1 - Method for predicting chemical or physical properties of complex mixtures - Google Patents
Method for predicting chemical or physical properties of complex mixturesInfo
- Publication number
- CA2225363A1 CA2225363A1 CA002225363A CA2225363A CA2225363A1 CA 2225363 A1 CA2225363 A1 CA 2225363A1 CA 002225363 A CA002225363 A CA 002225363A CA 2225363 A CA2225363 A CA 2225363A CA 2225363 A1 CA2225363 A1 CA 2225363A1
- Authority
- CA
- Canada
- Prior art keywords
- mixture
- chemical
- physical properties
- analysis
- complex mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 239000000126 substance Substances 0.000 title abstract 3
- 230000000704 physical effect Effects 0.000 title abstract 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/0027—Methods for using particle spectrometers
- H01J49/0031—Step by step routines describing the use of the apparatus
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2829—Mixtures of fuels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/04—Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components
- H01J49/0422—Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components for gaseous samples
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/34—Dynamic spectrometers
- H01J49/42—Stability-of-path spectrometers, e.g. monopole, quadrupole, multipole, farvitrons
- H01J49/4205—Device types
- H01J49/421—Mass filters, i.e. deviating unwanted ions without trapping
- H01J49/4215—Quadrupole mass filters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/12—Circuits of general importance; Signal processing
- G01N2201/129—Using chemometrical methods
- G01N2201/1293—Using chemometrical methods resolving multicomponent spectra
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/72—Mass spectrometers
- G01N30/7206—Mass spectrometers interfaced to gas chromatograph
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/86—Signal analysis
- G01N30/8624—Detection of slopes or peaks; baseline correction
- G01N30/8644—Data segmentation, e.g. time windows
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/86—Signal analysis
- G01N30/8675—Evaluation, i.e. decoding of the signal into analytical information
- G01N30/8682—Group type analysis, e.g. of components having structural properties in common
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/86—Signal analysis
- G01N30/8693—Models, e.g. prediction of retention times, method development and validation
-
- G—PHYSICS
- G16—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR SPECIFIC APPLICATION FIELDS
- G16C—COMPUTATIONAL CHEMISTRY; CHEMOINFORMATICS; COMPUTATIONAL MATERIALS SCIENCE
- G16C20/00—Chemoinformatics, i.e. ICT specially adapted for the handling of physicochemical or structural data of chemical particles, elements, compounds or mixtures
- G16C20/30—Prediction of properties of chemical compounds, compositions or mixtures
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A method for predicting the propreties of a complex hydrocarbon mixture which comprises selecting one or more known chemical, perceptual, physical or performance properties of the complex mixture and creating a training set from reference samples which contain characteristic molecular species present in the mixture. The reference samples are subjected to GC/MS analysis wherein the often collinear data generated are treated by multivariate correlation methods. The training set produces coefficients which are multiplied by the matrix generated from a GC/MS analysis of an unknown mixture to produce a predicted value for the chemical, performance or physical property or groups of properties selected.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/494,201 US5602755A (en) | 1995-06-23 | 1995-06-23 | Method for predicting chemical or physical properties of complex mixtures |
US08/494,201 | 1995-06-23 | ||
PCT/US1996/006592 WO1997001142A1 (en) | 1995-06-23 | 1996-05-09 | Method for predicting chemical or physical properties of complex mixtures |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2225363A1 true CA2225363A1 (en) | 1997-01-09 |
CA2225363C CA2225363C (en) | 2008-02-19 |
Family
ID=23963477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002225363A Expired - Fee Related CA2225363C (en) | 1995-06-23 | 1996-05-09 | Method for predicting chemical or physical properties of complex mixtures |
Country Status (8)
Country | Link |
---|---|
US (1) | US5602755A (en) |
EP (1) | EP0871936B1 (en) |
JP (1) | JPH11509313A (en) |
AU (1) | AU709024B2 (en) |
CA (1) | CA2225363C (en) |
DE (1) | DE69620238T2 (en) |
NO (1) | NO319388B1 (en) |
WO (1) | WO1997001142A1 (en) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5463564A (en) | 1994-09-16 | 1995-10-31 | 3-Dimensional Pharmaceuticals, Inc. | System and method of automatically generating chemical compounds with desired properties |
FR2743143B1 (en) * | 1995-12-28 | 1998-02-27 | Elf Antar France | METHOD FOR DETERMINING THE VALUE OF A PHYSICAL QUANTITY |
US5744702A (en) * | 1996-09-12 | 1998-04-28 | Exxon Research And Engineering Company | Method for analyzing total reactive sulfur |
US5808180A (en) * | 1996-09-12 | 1998-09-15 | Exxon Research And Engineering Company | Direct method for determination of true boiling point distillation profiles of crude oils by gas chromatography/mass spectrometry |
AU722336B2 (en) * | 1996-09-12 | 2000-07-27 | Exxon Research And Engineering Company | Method for analyzing total reactive sulfur |
US6453246B1 (en) | 1996-11-04 | 2002-09-17 | 3-Dimensional Pharmaceuticals, Inc. | System, method, and computer program product for representing proximity data in a multi-dimensional space |
US6295514B1 (en) | 1996-11-04 | 2001-09-25 | 3-Dimensional Pharmaceuticals, Inc. | Method, system, and computer program product for representing similarity/dissimilarity between chemical compounds |
US6571227B1 (en) | 1996-11-04 | 2003-05-27 | 3-Dimensional Pharmaceuticals, Inc. | Method, system and computer program product for non-linear mapping of multi-dimensional data |
DE19713194C2 (en) * | 1997-03-27 | 1999-04-01 | Hkr Sensorsysteme Gmbh | Method and arrangement for recognizing properties of a sample on the basis of mass spectroscopy |
US7416524B1 (en) | 2000-02-18 | 2008-08-26 | Johnson & Johnson Pharmaceutical Research & Development, L.L.C. | System, method and computer program product for fast and efficient searching of large chemical libraries |
AU2001241800A1 (en) | 2000-02-29 | 2001-09-12 | 3-Dimensional Pharmaceuticals, Inc. | Method and computer program product for designing combinatorial arrays |
AU4733601A (en) * | 2000-03-10 | 2001-09-24 | Cyrano Sciences Inc | Control for an industrial process using one or more multidimensional variables |
US7039621B2 (en) | 2000-03-22 | 2006-05-02 | Johnson & Johnson Pharmaceutical Research & Development, L.L.C. | System, method, and computer program product for representing object relationships in a multidimensional space |
GB0007063D0 (en) * | 2000-03-23 | 2000-05-10 | Simsci Limited | Mulitvariate statistical process monitors |
WO2001075790A2 (en) | 2000-04-03 | 2001-10-11 | 3-Dimensional Pharmaceuticals, Inc. | Method, system, and computer program product for representing object relationships in a multidimensional space |
GB0016459D0 (en) * | 2000-07-04 | 2000-08-23 | Pattern Recognition Systems As | Method |
US6549861B1 (en) | 2000-08-10 | 2003-04-15 | Euro-Celtique, S.A. | Automated system and method for spectroscopic analysis |
EP1311189A4 (en) | 2000-08-21 | 2005-03-09 | Euro Celtique Sa | Near infrared blood glucose monitoring system |
JP2004507821A (en) * | 2000-08-22 | 2004-03-11 | 3−ディメンショナル ファーマシューティカルズ, インコーポレイテッド | Methods, systems and computer program products for determining characteristics of combinatorial library products from features of library building blocks |
AU2001292740A1 (en) * | 2000-09-20 | 2002-04-02 | Dimitris K. Agrafiotis | Method, system, and computer program product for encoding and building products of a virtual combinatorial library |
WO2002047460A2 (en) * | 2000-12-15 | 2002-06-20 | Exxonmobil Research And Engineering Company | Mass spectrometric multivariate analysis of asphalts |
US6406916B1 (en) | 2001-01-22 | 2002-06-18 | General Electric Company | Method and apparatus for rapid quantitation of a dihydric phenol |
WO2002061419A1 (en) * | 2001-01-29 | 2002-08-08 | 3-Dimensional Pharmaceuticals, Inc. | Method, system, and computer program product for analyzing combinatorial libraries |
WO2004069164A2 (en) * | 2003-01-30 | 2004-08-19 | Euro Celtique Sa | Wireless blood glucose monitoring system |
CN1307419C (en) * | 2003-08-29 | 2007-03-28 | 中国石油化工股份有限公司 | Method of analyzing diesel oil hydrocarbon composition using solid phase extraction and mass chromatogrophy |
GB2410800B (en) * | 2004-02-06 | 2007-12-12 | Statoil Asa | Fingerprinting of hydrocarbon containing mixtures |
WO2005079261A2 (en) * | 2004-02-13 | 2005-09-01 | Waters Investments Limited | System and method for tracking and quatitating chemical entites |
US7187590B2 (en) * | 2004-04-26 | 2007-03-06 | Macronix International Co., Ltd. | Method and system for self-convergent erase in charge trapping memory cells |
US8078402B2 (en) | 2008-07-16 | 2011-12-13 | Schlumberger Technology Corporation | Method of ranking geomarkers and compositional allocation of wellbore effluents |
US8781747B2 (en) * | 2009-06-09 | 2014-07-15 | Schlumberger Technology Corporation | Method of determining parameters of a layered reservoir |
US8360143B2 (en) * | 2009-12-10 | 2013-01-29 | Schlumberger Technology Corporation | Method of determining end member concentrations |
JP5454462B2 (en) * | 2010-12-22 | 2014-03-26 | 株式会社島津製作所 | Chromatograph mass spectrometer |
US11022588B2 (en) | 2011-02-22 | 2021-06-01 | Saudi Arabian Oil Company | Characterization of crude oil by simulated distillation |
US10031121B2 (en) | 2011-02-22 | 2018-07-24 | Saudi Arabian Oil Company | Characterization of an API gravity value of crude oil by ultraviolet visible spectroscopy |
US10684239B2 (en) | 2011-02-22 | 2020-06-16 | Saudi Arabian Oil Company | Characterization of crude oil by NMR spectroscopy |
US10677718B2 (en) | 2011-02-22 | 2020-06-09 | Saudi Arabian Oil Company | Characterization of crude oil by near infrared spectroscopy |
US10571452B2 (en) | 2011-06-28 | 2020-02-25 | Saudi Arabian Oil Company | Characterization of crude oil by high pressure liquid chromatography |
US10725013B2 (en) | 2011-06-29 | 2020-07-28 | Saudi Arabian Oil Company | Characterization of crude oil by Fourier transform ion cyclotron resonance mass spectrometry |
WO2016111988A1 (en) * | 2015-01-05 | 2016-07-14 | Saudi Arabian Oil Company | Charaterization of crude oil by fourier transform ion cyclotron resonance mass spectrometry |
EP2739968A4 (en) * | 2011-08-05 | 2015-04-15 | Smiths Detection Inc | Chemical identification using a chromatography retention index |
US10048194B2 (en) | 2012-02-21 | 2018-08-14 | Saudi Arabian Oil Company | Characterization of crude oil by ultraviolet visible spectroscopy |
US10330653B2 (en) * | 2014-03-03 | 2019-06-25 | Indian Institute Of Technology, Delhi | Optimization free technique for determining unknown concentration of the constituents for a mixture |
JP6836507B2 (en) | 2015-01-05 | 2021-03-03 | サウジ アラビアン オイル カンパニー | Crude oil characterization by UV-visible spectroscopy |
WO2016111997A1 (en) | 2015-01-05 | 2016-07-14 | Saudi Arabian Oil Company | Relative valuation method for naphtha streams |
WO2016112004A1 (en) | 2015-01-05 | 2016-07-14 | Saudi Arabian Oil Company | Characterization of crude oil by near infrared spectroscopy |
US10401344B2 (en) | 2015-01-05 | 2019-09-03 | Saudi Arabian Oil Company | Characterization of crude oil and its fractions by thermogravimetric analysis |
EP3285190A1 (en) | 2016-05-23 | 2018-02-21 | Thermo Finnigan LLC | Systems and methods for sample comparison and classification |
CN109633059B (en) * | 2018-12-14 | 2020-02-21 | 浙江省检验检疫科学技术研究院 | Method for predicting flash point of flammable liquid mixed solution based on headspace gas chromatography-mass spectrometry |
US11913332B2 (en) | 2022-02-28 | 2024-02-27 | Saudi Arabian Oil Company | Method to prepare virtual assay using fourier transform infrared spectroscopy |
US11781988B2 (en) | 2022-02-28 | 2023-10-10 | Saudi Arabian Oil Company | Method to prepare virtual assay using fluorescence spectroscopy |
US11781427B2 (en) | 2022-02-28 | 2023-10-10 | Saudi Arabian Oil Company | Method to prepare virtual assay using ultraviolet spectroscopy |
DE102022110521A1 (en) | 2022-04-29 | 2023-11-02 | Volkswagen Aktiengesellschaft | Method for determining a standardized tendency of a mixture of substances to form soot |
DE102022110522A1 (en) | 2022-04-29 | 2023-11-02 | Volkswagen Aktiengesellschaft | Method for determining a standardized soot formation tendency of a substance mixture and representative indices for calculating an overall soot formation tendency index |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2245815A1 (en) * | 1972-09-19 | 1974-03-28 | Bodenseewerk Perkin Elmer Co | METHOD AND DEVICE FOR IDENTIFYING AND EVALUATING PEAKS IN CHROMATOGRAMS |
US4353242A (en) * | 1980-12-16 | 1982-10-12 | University Of Utah Research Foundation | Multichannel detection and resolution of chromatographic peaks |
US4583183A (en) * | 1983-02-24 | 1986-04-15 | The United States Of America As Represented By The United States Department Of Energy | Masked multichannel analyzer |
US4807148A (en) * | 1987-05-29 | 1989-02-21 | Hewlett-Packard Company | Deconvolving chromatographic peaks |
US4835708A (en) * | 1987-07-06 | 1989-05-30 | Spectra Physics, Inc. | Method and apparatus for analysis of chromatograms using cross-correlation and moment analysis |
US4916645A (en) * | 1988-06-02 | 1990-04-10 | The Perkin-Elmer Corporation | Continuous monochrometer drift compensation of a spectral monochromator |
US5119315A (en) * | 1989-04-28 | 1992-06-02 | Amoco Corporation | Method of correlating a record of sample data with a record of reference data |
JPH0750101B2 (en) * | 1989-09-13 | 1995-05-31 | 株式会社コスモ総合研究所 | Method and apparatus for measuring cetane number or cetane index |
US5121337A (en) * | 1990-10-15 | 1992-06-09 | Exxon Research And Engineering Company | Method for correcting spectral data for data due to the spectral measurement process itself and estimating unknown property and/or composition data of a sample using such method |
FR2672141B1 (en) * | 1991-01-25 | 1993-04-09 | Commissariat Energie Atomique | METHOD FOR RECOGNIZING OBJECTS CODED BY VECTORS. |
-
1995
- 1995-06-23 US US08/494,201 patent/US5602755A/en not_active Expired - Lifetime
-
1996
- 1996-05-09 DE DE69620238T patent/DE69620238T2/en not_active Expired - Fee Related
- 1996-05-09 AU AU56780/96A patent/AU709024B2/en not_active Ceased
- 1996-05-09 JP JP9503829A patent/JPH11509313A/en active Pending
- 1996-05-09 CA CA002225363A patent/CA2225363C/en not_active Expired - Fee Related
- 1996-05-09 EP EP96913971A patent/EP0871936B1/en not_active Expired - Lifetime
- 1996-05-09 WO PCT/US1996/006592 patent/WO1997001142A1/en active IP Right Grant
-
1997
- 1997-12-19 NO NO19976003A patent/NO319388B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP0871936A1 (en) | 1998-10-21 |
EP0871936B1 (en) | 2002-03-27 |
NO976003L (en) | 1998-02-23 |
AU5678096A (en) | 1997-01-22 |
EP0871936A4 (en) | 1999-06-30 |
NO976003D0 (en) | 1997-12-19 |
DE69620238T2 (en) | 2002-09-12 |
DE69620238D1 (en) | 2002-05-02 |
JPH11509313A (en) | 1999-08-17 |
CA2225363C (en) | 2008-02-19 |
US5602755A (en) | 1997-02-11 |
NO319388B1 (en) | 2005-08-08 |
AU709024B2 (en) | 1999-08-19 |
WO1997001142A1 (en) | 1997-01-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |