CA2208588A1 - Elastomer functionalised by carboxylic groupings or graft esters, and use thereof for producing functionalised elastomer/bitumen compositions suitable for making surfacings - Google Patents

Elastomer functionalised by carboxylic groupings or graft esters, and use thereof for producing functionalised elastomer/bitumen compositions suitable for making surfacings

Info

Publication number
CA2208588A1
CA2208588A1 CA002208588A CA2208588A CA2208588A1 CA 2208588 A1 CA2208588 A1 CA 2208588A1 CA 002208588 A CA002208588 A CA 002208588A CA 2208588 A CA2208588 A CA 2208588A CA 2208588 A1 CA2208588 A1 CA 2208588A1
Authority
CA
Canada
Prior art keywords
elastomer
functionalised
surfacings
graft
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002208588A
Other languages
French (fr)
Other versions
CA2208588C (en
Inventor
Pascal Nicol
Jean-Pascal Planche
Laurent Germanaud
Herve Nabet
Patrick Turello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Pascal Nicol
Jean-Pascal Planche
Laurent Germanaud
Herve Nabet
Patrick Turello
Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9512275A external-priority patent/FR2740138B1/en
Application filed by Pascal Nicol, Jean-Pascal Planche, Laurent Germanaud, Herve Nabet, Patrick Turello, Elf Aquitaine filed Critical Pascal Nicol
Publication of CA2208588A1 publication Critical patent/CA2208588A1/en
Application granted granted Critical
Publication of CA2208588C publication Critical patent/CA2208588C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/20Incorporating sulfur atoms into the molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'élastomère fonctionnalisé (EF) est formé d'un substrat élastomère, ayant une masse moléculaire moyenne en poids (a) entre 10000 et 600000 daltons et un indice de polydispersité inférieur à 5, sur lequel sont greffées, en quantité allant de 0,1 % à 10 % en poids du substrat, des séquences (b) où R1 est un radical hydrocarboné (x+z+1)-valent en C1 à C12, X représente H ou un radical hydrocarboné monovalent R en C1 à C12, z est égal à zéro ou 1 et x est un nombre entier allant de 1 à 3, avec x+z 3, la masse moléculaire moyenne en poids (Mw) dudit EF étant telle que le rapport (c) soit inférieur à 20 %. On produit des compositions bitume/EF utilisables pour la réalisation de revêtements en incorporant ledit EF à une composante bitumineuse.The functionalized elastomer (EF) is formed of an elastomeric substrate, having a weight-average molecular mass (a) between 10,000 and 600,000 daltons and a polydispersity index of less than 5, onto which are grafted, in an amount ranging from 0, 1% to 10% by weight of the substrate, of the sequences (b) where R1 is a hydrocarbon radical (x + z + 1) -valent in C1 to C12, X represents H or a monovalent hydrocarbon radical R in C1 to C12, z is zero or 1 and x is an integer ranging from 1 to 3, with x + z 3, the weight average molecular weight (Mw) of said EF being such that the ratio (c) is less than 20%. Bitumen / EF compositions that can be used for the production of coatings are produced by incorporating said EF into a bituminous component.

CA002208588A 1995-10-19 1996-10-16 Elastomer functionalised by carboxylic groupings or graft esters, and use thereof for producing functionalised elastomer/bitumen compositions suitable for making surfacings Expired - Fee Related CA2208588C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9512275A FR2740138B1 (en) 1995-10-19 1995-10-19 ELASTOMER FUNCTIONALIZED BY CARBOXYLIC GROUPS OR GRAFT ESTERS AND ITS APPLICATION TO THE PRODUCTION OF BITUMEN COMPOSITIONS / FUNCTIONALIZED ELASTOMER FOR USE IN THE PRODUCTION OF COATINGS
FR95/12275 1995-10-19
PCT/FR1996/001613 WO1997014726A1 (en) 1995-10-19 1996-10-16 Elastomer functionalised by carboxylic groupings or graft esters, and use thereof for producing functionalised elastomer/bitumen compositions suitable for making surfacings

Publications (2)

Publication Number Publication Date
CA2208588A1 true CA2208588A1 (en) 1997-04-24
CA2208588C CA2208588C (en) 2006-12-12

Family

ID=37561066

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002208588A Expired - Fee Related CA2208588C (en) 1995-10-19 1996-10-16 Elastomer functionalised by carboxylic groupings or graft esters, and use thereof for producing functionalised elastomer/bitumen compositions suitable for making surfacings

Country Status (1)

Country Link
CA (1) CA2208588C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861610A (en) * 2021-08-30 2021-12-31 济南大学 Preparation method and application of novel weather-resistant composite waterproof material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861610A (en) * 2021-08-30 2021-12-31 济南大学 Preparation method and application of novel weather-resistant composite waterproof material

Also Published As

Publication number Publication date
CA2208588C (en) 2006-12-12

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20131016