CA2192232A1 - Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer - Google Patents

Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer

Info

Publication number
CA2192232A1
CA2192232A1 CA002192232A CA2192232A CA2192232A1 CA 2192232 A1 CA2192232 A1 CA 2192232A1 CA 002192232 A CA002192232 A CA 002192232A CA 2192232 A CA2192232 A CA 2192232A CA 2192232 A1 CA2192232 A1 CA 2192232A1
Authority
CA
Canada
Prior art keywords
zeolite
growth enhancing
enhancing layer
colloidal
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002192232A
Other languages
French (fr)
Other versions
CA2192232C (en
Inventor
Wenyih F. Lai
Harry W. Deckman
James A. Mchenry
Johannes P. Verduijn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/272,361 external-priority patent/US5871650A/en
Application filed by Individual filed Critical Individual
Priority claimed from PCT/US1995/008514 external-priority patent/WO1996001687A1/en
Publication of CA2192232A1 publication Critical patent/CA2192232A1/en
Application granted granted Critical
Publication of CA2192232C publication Critical patent/CA2192232C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/028Molecular sieves
    • B01D71/0281Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0083Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1214Chemically bonded layers, e.g. cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/08Specific temperatures applied
    • B01D2323/082Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60Synthesis on support
    • B01J2229/64Synthesis on support in or on refractory materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60Synthesis on support
    • B01J2229/66Synthesis on support on metal supports

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

The present invention is directed toward a new zeo-lite composition having coated thereon a mesoporous growth enhancing layer and a layer of zeolite crystals on said meso-porous growth enhancing layer, and wherein said meso-porous growth enhancing layer comprises nanocrystalline or colloidal sized zeolites, nanocrystalline or colloidal zeolite and metal oxide, or nanocrystalline or colloidal zeolite and colloidal metal, or nanocrystalline or colloidal zeolite col-loidal metal and metal oxide, and wherein said mesoporous growth enhancing layer has interstices of about 20 to about 2000 .ANG., and wherein said zeolite layer s a polycrystalline layer of oriented crystals with similar habit wherein 99,9 %
of said zeolite crystals have at least one point between adja-cent crystals that is 20 .ANG.. The invention is further directed to a process of producing and using the composition.
CA002192232A 1994-07-08 1995-07-10 Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer Expired - Fee Related CA2192232C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US08/272,361 1994-07-08
US08/272,361 US5871650A (en) 1994-07-08 1994-07-08 Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer
US47700795A 1995-06-07 1995-06-07
US08/477,007 1995-06-07
US49972095A 1995-07-07 1995-07-07
US08/499,720 1995-07-07
PCT/US1995/008514 WO1996001687A1 (en) 1994-07-08 1995-07-10 Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer

Publications (2)

Publication Number Publication Date
CA2192232A1 true CA2192232A1 (en) 1996-01-25
CA2192232C CA2192232C (en) 2007-04-03

Family

ID=37951700

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002192232A Expired - Fee Related CA2192232C (en) 1994-07-08 1995-07-10 Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer

Country Status (1)

Country Link
CA (1) CA2192232C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112999890A (en) * 2021-03-03 2021-06-22 大连理工大学 Organic-inorganic hybrid SiO of flat plate2Composite membrane and preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112999890A (en) * 2021-03-03 2021-06-22 大连理工大学 Organic-inorganic hybrid SiO of flat plate2Composite membrane and preparation method and application thereof

Also Published As

Publication number Publication date
CA2192232C (en) 2007-04-03

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Legal Events

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