CA2161516A1 - Thin film pegless permanent orifice plate mandrel - Google Patents

Thin film pegless permanent orifice plate mandrel

Info

Publication number
CA2161516A1
CA2161516A1 CA 2161516 CA2161516A CA2161516A1 CA 2161516 A1 CA2161516 A1 CA 2161516A1 CA 2161516 CA2161516 CA 2161516 CA 2161516 A CA2161516 A CA 2161516A CA 2161516 A1 CA2161516 A1 CA 2161516A1
Authority
CA
Canada
Prior art keywords
mandrel
layer
titanium
photoresist layer
tungsten
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA 2161516
Other languages
French (fr)
Inventor
John W. Wolff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Versamark Inc
Original Assignee
John W. Wolff
Scitex Digital Printing, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by John W. Wolff, Scitex Digital Printing, Inc. filed Critical John W. Wolff
Publication of CA2161516A1 publication Critical patent/CA2161516A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/1626Manufacturing processes etching
    • B41J2/1628Manufacturing processes etching dry etching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/162Manufacturing of the nozzle plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/1631Manufacturing processes photolithography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/1632Manufacturing processes machining
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/164Manufacturing processes thin film formation
    • B41J2/1643Manufacturing processes thin film formation thin film formation by plating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/164Manufacturing processes thin film formation
    • B41J2/1645Manufacturing processes thin film formation thin film formation by spincoating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/164Manufacturing processes thin film formation
    • B41J2/1646Manufacturing processes thin film formation thin film formation by sputtering
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00Electroforming
    • C25D1/10Moulds; Masks; Masterforms

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)

Abstract

A mandrel is used in the manufacture of an ink jet orifice plate. The mandrel comprises a glass substrate and an etched Titanium-Tungsten layer having a thickness of approximately 2000.ANG. to 5000.ANG.
residing on the substrate. The mandrel is manufactured by depositing a 2000.ANG. to 5000.ANG. thick layer of Titanium-Tungsten on a substrate, and then depositing a photoresist layer on the Titanium-Tungsten layer in a spin coater. The photoresist layer is cured, and a patterned photomask is positioned on the photoresist layer. The photoresist layer is exposed to actinic radiation and then developed to produce a photomask pattern on the photoresist layer. The next step is to plasma etch the Titanium-Tungsten layer with a Halogen containing gas to form an etched conducting film mold. Finally, the remaining photoresist layer is stripped to complete construction of the mandrel, so the mandrel is reusable without any additional preparation.

Description

THIN FILM PEGLESS PERMANENT ORIFICE PLATE MANDREL

Technical Field The present invention relates to the field of electroplating and, more particularly, to the field of manufacturing orifice plate mandrels using thin film processes.

Back~round Art In continuous ink jet printing, electrically conductive ink is supplied under pressure to a manifold region that distributes the ink to a plurality of orifices, typically arranged in a linear array(s). The ink discharges from the orifices in filaments which break into droplet streams. Individual droplet streams are selectively charged in the region of the break off from the filaments and charge drops are deflected from their normal trajectories. The deflected drops may be caught and recirculated, and the undeflected drops allowed to proceed to a print receiving medium.
Drops are charged by a charge plate having a plurality of charging electrodes along one edge, and a corresponding plurality of connecting leads along one surface. The edge of the charge plate having the charging electrodes is placed in close proximity to the break off point of the ink jet filaments, and charges applied to the leads to induce charges in the drops as they break off from the filaments.
The prior art method for producing orifice plates utilizes a conductive brass mandrel in which photoresist orifice pegs are applied. Metal mandrels are comparatively poor in quality due to surface scratches and defects inherent in metal substrates. Photoresist thickness variation is another degrading factor in this technique which, combined with the low quality brass substrate, produces an inferior orifice plate. Another disadvantage to this method is the hazardous waste generated from etchants, strippers and dissolved metals into waste streams. Furthermore, the non-reusability of this mandrel makes this process extremely expensive.
U.S. Pat. No. 3,703,450 describes a method for making a precision conductive mesh screen.
First, this method constructs a mandrel. The prior art mandrel is constructed by placing a master plate with the screen pattern on the glass substrate and by vapor depositing a thin film through the interstices of the master plate to form the screen's pattern on the glass. After removing the master plate from the glass substrate, the method deposits photoresist over the entire glass plate. Next, the method exposes and develops the photoresist to produce a layer of thin film in a screen pattern covered with a layer of photoresist in the same screen pattern. Next, the method deposits silicon monoxide on the entire glass substrate and removes the silicon monoxide and photoresist from the thin film pattern. This nonreusable mandrel is now ready for manufacturing the screen. This prior art mandrel has several disadvantages. It cannot manufacture small geometry devices as pointed out in U.S. Pat. No. 4,549,939 discussed below. Also, the complicated prior art process for making this mandrel has low yields.
U.S. Pat. No. 4,549,939 describes another prior art thin film mandrel and the method of making it. This prior art process constructs the prior art mandrel by forming a stained pattern shield on a glass substrate and depositing a conductive and transparent thin film onto the substrate. Next, the prior art method coats the thin film with resist and shines a light through the glass substrate and the transparent thin film to expose the unshielded photoresist. Finally, the photoresist is developed and forms the mold for electroforming. The prior art mandrel formed by this process has several disadvantages. It is non-reusable and of poor quality due to resist broken after the use of a conductive thin film that is transparent; a costly and exotic material.
U.S. Pat. No. 4,528,577 describes another prior art mandrel and the method of making it. This prior art method of manufacturing orifice plates for thermal ink jet printheads electroforms nickel onto a stainless steel mandrel plate that contains either a re-etched orifice pattern or a photoresist orifice pattern. Unfortunately, stainless steel mandrel plates always contain a large number of scratches and defects. These scratches and defects arise from characteristics of the stainless steel material and from the manufacturing process. The scratches and defects, which can not be eliminated, degrade the quality of the orifice plates manufactured from stainless steel mandrels. These inferior orifice plates produce inferior print quality. The method and apparatus in accordance with the present invention obviate these problems with mandrels in the prior art.
In the electroplating process, as in U.S.
Patent No. 4,773,971, the orifices are formed by overplating the voids within the conductive film and onto the underlying smooth glass substrate. Other methods of orifice plate manufacturing processes rely on overplating a photoresist peg that is prone to defects and pinholes, and is dimensionally unstable.
It is seen then that there is a need for an improved mandrel for use in the manufacture of ink jet orifice plates.
s Summary of the Invention This need is met by the improved method of manufacturing ink jet orifice plates using a pegless thin film reusable mandrel.
In accordance with one aspect of the present invention, a mandrel is used in the manufacture of an ink jet orifice plate. The mandrel comprises a glass substrate and an etched Titanium-Tungsten layer having a thickness of approximately 2000A to soooA residing on the substrate.
In accordance with another aspect of the present invention, a method of making a mandrel for an ink jet orifice plate is disclosed. The method comprises the steps of sputter depositing a 2000A to 500 oA thick layer of Titanium-Tungsten on a - substrate, and then depositing a photoresist layer on the Titanium-Tungsten layer in a spin coater, i.e., using a spin coating process. The photoresist layer is cured, and a patterned photomask is positioned on the photoresist layer. The photoresist layer is exposed to actinic radiation and then developed to produce a photomask pattern on the photoresist layer.
The next step is to plasma etch the Titanium-Tungsten layer with a Halogen containing gas to form an etched conducting film mold. Finally, the remaining photoresist layer is stripped to complete construction of the mandrel.
It is an object of the present invention to manufacture orifice plates using a thin film pegless mandrel. Other objects and advantages of the invention will be apparent from the following description and the appended claims.

Brief Description of the Drawings Fig. lA is a top view of a plasma etched thin film permanent mandrel with the orifice patterned, in accordance with the present invention;
Fig. lB is a side view of the plasma etched thin film permanent mandrel, in accordance with one embodiment of the present invention;
Fig. lC is a top view of a nickel plated thin film permanent mandrel, in accordance with another embodiment of the present invention;
Figs. 2A-2H show the steps used to manufacture the thin film pegless orifice plate mandrel of the present invention.

Detailed Description of the Preferred Embodiments The manufacturing of high quality precision orifice plates is highly desirable for ink-jet printheads. One method to accompli~h this is by using a thin film pegless (void in the conductive layer) reusable mandrel. The mandrel is manufactured by sputtering, or sputter etching, or reactive ion etching a conductive thin film metal such as Titanium/Tungsten onto a smooth substrate such as glass. Next, a standard photolithographic process is used to define an appropriate orifice plate pattern in the photoresist. The unprotected thin film Titanium/Tungsten within the photoresist pattern is removed by a plasma etching process. The photoresist is then removed from the conductive thin film and the mandrel can be electroplated to produce orifice plates. This method produces a pegless thin film mandrel that can be manufactured using standard photolithographic and plasma etching techniques that yield a high resolution mandrel in which orifice plates can be produced. The electroformed orifice plates can be reproduced and have the identical high resolution characteristics of the pegless thin film mandrel taking advantage of the dimensional stability.
In the electroplating process, the orifices are formed by overplating the voids within the conductive film and onto the underlying smooth glass substrate. Other methods of orifice plate manufacturing processes rely on overplating a photoresist peg that is prone to defects, pinholes and dimensionally unstable. The pegless mandrel exposes the defect free glass substrate that is not compromised by previous manufacturing processes. The mandrel of the present invention is unique because of the use of Titanium-Tungsten as the conductive layer, and also because the mandrel can be plasma etched to define the conductive film mold. Plasma etching allows for the voids in the conductive layer to be of high resolution.
Referring now to the drawings, Fig. lA is a top view of a plasma etched thin film permanent mandrel 10 with a patterned orifice 12. Fig. lB
illustrates a side view of the plasma etched thin film permanent mandrel 10. Fig. lC is a top view of a nickel plated thin film permanent mandrel 10', with a patterned orifice 12'.
The process for manufacturing the thin film pegless orifice plate mandrel 10 or 10' of the present invention is best illustrated in Figs. 2A-2H.
The process starts with a glass substrate or silicon wafer, or a polished silicon wafer, or a plastic, or any smooth, nonconducting surface 14, as shown in Fig. 2A. As shown in Fig. 2B, a conductive thin film metal 16 is deposited on the glass substrate 14 by a suitable process such as a sputter etching process or reactive ion etching process. The thin film is typically constructed from a Titanium/Tungsten material. However, alternate embodiments could use different conductive materials. Next, as illustrated in Fig. 2C, a photoresist layer 18 is applied atop the Titanium/ Tungsten layer. The photoresist layer 18 is then exposed to actinic radiation and developed to produce the orifice pattern. In Fig. 2E, the Titanium-Tungsten layer is plasma etched to define the orifice mold. In Fig. 2F, the photoresist layer 18 is removed, allowing the thin film permanent mandrel to be nickel plated, with nickel plating layer 20, as shown in Fig. 2G. finally, as illustrated in Fig. 2H, the nickel orifice plate 20 is removed from the thin film permanent mandrel, allowing the mandrel to be reused, with no additional preparation.
Continuing with Figs. lA-lC and 2A-2H, the mandrel comprises a glass substrate 14 with an etched Titanium-Tungsten layer 16 residing on the substrate. The Titanium-Tungsten layer 16 typically has a thickness of approximately 2000A to 5000A. The mandrel is manufactured by sputter depositing the 2000A to 5000A thick layer 16 of Titanium-Tungsten on the substrate 14, and then depositing a photoresist layer 18 on the Titanium-Tungsten layer 16, using a spin coating process. The photoresist layer 18 is cured, and a patterned photomask is positioned on the photoresist layer. The photoresist layer is exposed to actinic radiation and then developed to produce a photomask pattern on the photoresist layer 18. The next step is to plasma etch the Titanium-Tungsten layer 16, such as with a Halogen containing gas, to form an etched conducting film mold. Finally, the rem~;n;ng photoresist layer is stripped to complete construction of the mandrel.

Industrial Applicability and Advantages The present invention is useful in the field of ink jet printing, and has the advantage of providing an improved mandrel. The present invention provides the further advantage of providing a reusable thin film pegless permanent orifice plate mandrel. The advantage of providing a reusable thin film pegless permanent orifice plate mandrel is that from a single mandrel numerous orifice plates can be produced. This has the further advantage of reducing the cost of fabricating orifice plates compared to conventional methods such as metal mandrels with photoresist pegs that are limited to producing a single orifice plate.
Having described the invention in detail and by reference to the preferred embodiment thereof, it will be apparent that other modifications and variations are possible without departing from the scope of the invention defined in the appended claims .

Claims (8)

1. A mandrel for an ink jet orifice plate, the mandrel comprising:
a substrate; and an etched Titanium-Tungsten layer residing on said substrate.
2. A mandrel as claimed in claim 1 wherein the substrate comprises glass.
3. A mandrel as claimed in claim 1 wherein said etched Titanium-Tungsten layer comprises a thickness of approximately 2000.ANG. to 5000.ANG. .
4. A mandrel as claimed in claim 1 wherein the mandrel is reusable.
5. A method of making a mandrel for an ink jet orifice plate, the method comprising the steps of:
providing a substrate;
depositing a layer of Titanium-Tungsten on said substrate;
depositing a photoresist layer on the Titanium-Tungsten layer;
curing said photoresist layer;
positioning a photomask having a pattern on the photoresist layer;
exposing the photoresist layer to actinic radiation;
developing the photoresist layer to produce a photomask pattern on the photoresist layer;
plasma etching the Titanium-Tungsten layer with a Halogen containing gas to form an etched conducting film mold; and stripping the remaining photoresist layer to complete construction of said mandrel.
6. A method of making a mandrel as claimed in claim 5 wherein the step of depositing a layer of Titanium-Tungsten on said substrate further comprises the step of using a sputter etching process.
7. A method of making a mandrel as claimed in claim 5 wherein the step of depositing a photoresist layer on the Titanium-Tungsten layer further comprises the step of using a spin coating process.
8. A method of making a mandrel as claimed in claim 5 wherein the mandrel is reusable.
CA 2161516 1994-10-28 1995-10-26 Thin film pegless permanent orifice plate mandrel Abandoned CA2161516A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33106094A 1994-10-28 1994-10-28
US08/331,060 1994-10-28

Publications (1)

Publication Number Publication Date
CA2161516A1 true CA2161516A1 (en) 1996-04-29

Family

ID=23292467

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2161516 Abandoned CA2161516A1 (en) 1994-10-28 1995-10-26 Thin film pegless permanent orifice plate mandrel

Country Status (3)

Country Link
EP (1) EP0713929B1 (en)
CA (1) CA2161516A1 (en)
DE (1) DE69508705T2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11129483A (en) * 1997-07-03 1999-05-18 Canon Inc Orifice plate for liquid jet head and production thereof, liquid jet head having orifice plate and production thereof
RU2151066C1 (en) * 1998-11-03 2000-06-20 Самсунг Электроникс Ко., Лтд. Microinjector nozzle plate assembly and method for its manufacture
US20030143492A1 (en) 2002-01-31 2003-07-31 Scitex Digital Printing, Inc. Mandrel with controlled release layer for multi-layer electroformed ink jet orifice plates
CN109216405A (en) * 2017-06-30 2019-01-15 苏州苏大维格光电科技股份有限公司 The manufacturing method of AMOLED metal mask plate

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3703450A (en) 1971-04-01 1972-11-21 Dynamics Res Corp Method of making precision conductive mesh patterns
US4528577A (en) 1982-11-23 1985-07-09 Hewlett-Packard Co. Ink jet orifice plate having integral separators
US4549939A (en) 1984-04-30 1985-10-29 Ppg Industries, Inc. Photoelectroforming mandrel and method of electroforming
US4773971A (en) 1986-10-30 1988-09-27 Hewlett-Packard Company Thin film mandrel
US5149419A (en) * 1991-07-18 1992-09-22 Eastman Kodak Company Method for fabricating long array orifice plates

Also Published As

Publication number Publication date
DE69508705D1 (en) 1999-05-06
EP0713929B1 (en) 1999-03-31
EP0713929A1 (en) 1996-05-29
DE69508705T2 (en) 1999-07-29

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