CA2157937A1 - Method and apparatus for manufacturing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols - Google Patents

Method and apparatus for manufacturing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols

Info

Publication number
CA2157937A1
CA2157937A1 CA002157937A CA2157937A CA2157937A1 CA 2157937 A1 CA2157937 A1 CA 2157937A1 CA 002157937 A CA002157937 A CA 002157937A CA 2157937 A CA2157937 A CA 2157937A CA 2157937 A1 CA2157937 A1 CA 2157937A1
Authority
CA
Canada
Prior art keywords
carbohydrates
monocarboxylic acids
primary alcohols
manufacturing
carbohydrate derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002157937A
Other languages
French (fr)
Other versions
CA2157937C (en
Inventor
Markwart Kunz
Hanjo Puke
Carla Recker
Linda Scheiwe
Jorg Kowalczyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suedzucker AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2157937A1 publication Critical patent/CA2157937A1/en
Application granted granted Critical
Publication of CA2157937C publication Critical patent/CA2157937C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H7/00—Compounds containing non-saccharide radicals linked to saccharide radicals by a carbon-to-carbon bond
    • C07H7/02—Acyclic radicals
    • C07H7/033—Uronic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/04—Disaccharides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)

Abstract

In a method for manufacturing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols, carbohydrates, carbohydrate derivatives or primary alcohols are oxidized continuously in aqueous solution and concentrations between 0.1 and 60% with oxygen or oxygen-containing gases on noble metal or mixed metal catalysts. The volume flow of the products so formed is fed to an electrodialysis stage and the monocarboxylic acids are removed and obtained.
CA002157937A 1993-03-10 1994-03-08 Method and apparatus for manufacturing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols Expired - Fee Related CA2157937C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4307388A DE4307388A1 (en) 1993-03-10 1993-03-10 Method and device for producing mono-oxidized products from carbohydrates, carbohydrate derivatives and primary alcohols
DEP4307388.3 1993-03-10
PCT/EP1994/000695 WO1994020448A1 (en) 1993-03-10 1994-03-08 Method and device for producing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols

Publications (2)

Publication Number Publication Date
CA2157937A1 true CA2157937A1 (en) 1994-09-15
CA2157937C CA2157937C (en) 2003-05-06

Family

ID=6482323

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002157937A Expired - Fee Related CA2157937C (en) 1993-03-10 1994-03-08 Method and apparatus for manufacturing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols

Country Status (22)

Country Link
EP (1) EP0651734B1 (en)
JP (1) JPH08509701A (en)
AT (1) ATE137489T1 (en)
AU (1) AU689101B2 (en)
BG (1) BG61999B1 (en)
BR (1) BR9405896A (en)
CA (1) CA2157937C (en)
CZ (1) CZ288628B6 (en)
DE (2) DE4307388A1 (en)
DK (1) DK0651734T3 (en)
ES (1) ES2086999T3 (en)
FI (1) FI110685B (en)
GR (1) GR3019822T3 (en)
HU (1) HU218594B (en)
NO (1) NO303822B1 (en)
NZ (1) NZ262903A (en)
PL (1) PL174620B1 (en)
RO (1) RO114606B1 (en)
RU (1) RU2129541C1 (en)
SK (1) SK281397B6 (en)
UA (1) UA43844C2 (en)
WO (1) WO1994020448A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2004235932B2 (en) * 2003-05-05 2010-08-19 Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt Method for selective carbohydrate oxidation using supported gold catalysts

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19505957A1 (en) * 1995-02-21 1996-08-22 Huels Chemische Werke Ag Process for the preparation of keto compounds
DE19507668C2 (en) * 1995-03-04 2000-01-27 Suedzucker Ag Detergent formulations containing an acylated disaccharide carboxylic acid
DE19542303C2 (en) 1995-11-14 1998-03-26 Suedzucker Ag Acylated sucrose monocarboxylic acids
DE19542287A1 (en) * 1995-11-14 1997-05-15 Suedzucker Ag Process for the preparation of di- and higher-oxidized carboxylic acids of carbohydrates, carbohydrate derivatives or primary alcohols
DE19619016A1 (en) * 1996-05-10 1997-11-13 Suedzucker Ag Method and device for the oxidation of carbohydrates, carbohydrate derivatives or primary alcohols, in which a catalyzed oxidation takes place
DE19748195A1 (en) 1997-10-31 1999-05-06 Suedzucker Ag Disaccharide derivatives for the treatment of hyperglycaemia
US20020038051A1 (en) 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
DE10227432B4 (en) * 2002-06-20 2006-11-30 Südzucker AG Mannheim/Ochsenfurt Process for the separation of carbohydrate carboxylic acids
US8383837B2 (en) * 2007-06-05 2013-02-26 Dsm Ip Assets B.V. Reaction with a gold catalyst
EP3676275B1 (en) * 2017-08-29 2024-05-29 Julius-Maximilians-Universitaet Wuerzburg A new class of sucrose esters and a method for their preparation

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3020104A1 (en) * 1980-05-27 1981-12-03 Merck Patent Gmbh, 6100 Darmstadt METHOD FOR PRODUCING DIACETONE KETOGULONIC ACID
JPS6054338A (en) * 1983-09-05 1985-03-28 Mitsui Toatsu Chem Inc Preparation of 2-keto-l-gulonic acid
DE3446695A1 (en) * 1984-12-21 1986-06-26 Basf Ag, 6700 Ludwigshafen METHOD FOR CONCENTRATING AQUEOUS SOLUTIONS OF ORGANIC COMPOUNDS CONTAINING SALT, WITH A SIMULTANEOUS REDUCTION OF SALT
DE3522032A1 (en) * 1985-06-20 1987-01-02 Hoechst Ag METHOD FOR THE PRODUCTION OF CARBONIC ACIDS
FR2597473B1 (en) * 1986-01-30 1988-08-12 Roquette Freres PROCESS FOR THE OXIDATION OF DI-, TRI-, OLIGO- AND POLYSACCHARIDES TO POLYHYDROXYCARBOXYLIC ACIDS, CATALYST IMPLEMENTED AND PRODUCTS THUS OBTAINED.
DE3803465A1 (en) * 1988-02-05 1989-08-17 Huels Chemische Werke Ag METHOD FOR PRODUCING OXIDIZED SUBSTITUTED SACCHARIDES
DE3916206A1 (en) * 1989-05-18 1990-11-22 Hoechst Ag METHOD FOR PRODUCING 1-FLUOR-GLYCURONIC ACIDS AND THEIR SALTS, AND SUCH NEW 1-FLOUR-GLYCURONIC ACIDS AND THEIR SALTS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2004235932B2 (en) * 2003-05-05 2010-08-19 Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt Method for selective carbohydrate oxidation using supported gold catalysts

Also Published As

Publication number Publication date
AU6283594A (en) 1994-09-26
CZ288628B6 (en) 2001-08-15
EP0651734B1 (en) 1996-05-01
BG100021A (en) 1996-05-31
PL309642A1 (en) 1995-10-30
NO953536D0 (en) 1995-09-08
DE59400253D1 (en) 1996-06-05
HU218594B (en) 2000-10-28
HUT73732A (en) 1996-09-30
EP0651734A1 (en) 1995-05-10
AU689101B2 (en) 1998-03-26
NO303822B1 (en) 1998-09-07
SK281397B6 (en) 2001-03-12
JPH08509701A (en) 1996-10-15
CZ231095A3 (en) 1996-01-17
BR9405896A (en) 1995-12-12
SK109995A3 (en) 1995-12-06
DK0651734T3 (en) 1996-06-10
UA43844C2 (en) 2002-01-15
DE4307388A1 (en) 1994-09-15
RU2129541C1 (en) 1999-04-27
FI953372A0 (en) 1995-07-10
GR3019822T3 (en) 1996-08-31
RO114606B1 (en) 1999-06-30
CA2157937C (en) 2003-05-06
BG61999B1 (en) 1998-12-30
PL174620B1 (en) 1998-08-31
NO953536L (en) 1995-09-08
ATE137489T1 (en) 1996-05-15
WO1994020448A1 (en) 1994-09-15
FI953372A (en) 1995-07-10
FI110685B (en) 2003-03-14
NZ262903A (en) 1996-11-26
ES2086999T3 (en) 1996-07-01
HU9501726D0 (en) 1995-08-28

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