CA2157082A1 - Flame retardant molding compositions having improved flow - Google Patents

Abstract

Thermoplastic molding compositions containing a polycarbonate resin and a phosphorous compound characterized in their improved melt flow are disclosed. Accordingly, the spiral flow and melt flow index of the resin is greatly enhanced upon the incorporation of an additive amount of a phosphorous compound conforming to

Description

Mo-41 65 FLAME RETARDANT MOLDING
COMPOSITIONS HAVING IMPROVED FLOW
Field of the Invention:
The invention concerns thermoplastic molding compositions and, in particular, compositions containing polycarbonate and a phosphorous compound.
SUMMARY OF THE INVENTION
Thermoplastic molding compositions containing a polycarbonate resin and a phosphorous compound characterized in their improved melt flow are disclosed. Accordingly, the spiral flow and melt flow index of the resin is greatly enhanced upon the incorporation of an additive amount of a phosphorous compound conforming to O O
Ar-O- IP [-O-(residue)-O--IP ]n O-Ar O-Ar O-Ar where -(residue)-, n and Ar are defined. An embodiment characterized by its flame retardance is also disclosed.
BACKGROUND OF THE INVENTION
Phosphorous containing compounds have long been recognized for their efficacy as flame retarding agents and thermal stabilizers in thermoplastic molding compositions, including polycarbonate molding compositions. Patents relating to this technology include U.S. Patent 4,111,899 which disclosed compounds having P to P bonds as thermal and oxygen stabilizers of thermoplastic resins. The flame retarding efficacy of triaryl phosphates in the context of a polymeric resin was disclosed in U.S. Patent 4,526,917; the utility of other phosphorous compounds as flame retardant agents for polymers was disclosed in U.S.
ks1\1 021 94 21~7082 Patent 5,130,452. Flame retardant thermoplastic compositions containing a mixture of carbonate polymer, a styrene copolymer and/or a graft rubber polymer, polytetraflouroroethylene and a phosphorous compound were disclosed in U.S. Patents 4,751,260, 4,914,144 and 5,234,979.
5 Also relevant is U.S. Patent 5,204,394 which disclosed a flame retardant blend containing an oligomeric phosphate. A plasticized composition containing a polycarbonate resin and tetra(lower alkaryl)p-phenylene diphosphate was disclosed in U.S. Patent 5,122,556.
DETAILED DESCRIPTION OF THE INVENTION
Spiral flow in the context of the composition is a well recognized term of art. A description of spiral flow molding may be found in Iniection Moldinq TheorY and Practice, A Wiley-lnterscience Publication, John Wiley & Sons by Irvin 1. Rubin, PP. 232-233; also in "Spiral Flow Molding", by L. Griffith in Modem Plastfcs, August, 1957. The spiral flow 15 measurements in the course of the work leading up to the present invention were made by using a variable thickness spiral flow tool (set at 0.100") in a 3 oz. molding machine. Molding conditions were as follows:
Primary Pressure 18,000 psi Secondary Pressure 10,000 psi Back Pressure 800 psi Screw Speed 100 rpm Injection Speed 4 inches/second Cushion 0.250"
Mold Temperature 155F
Melt Temperature 490F
Melt flow rate in the present context is determined in accordance with ASTM D-1238 at 250C with a 5 kg. Ioad.
The invention resides in the enhanced spiral flow and/or melt flow rate of the composition. The composition of the invention exhibits a Mo-4165 considerable improvement, at least about 16% in terms of spiral flow over that of the unmodified resin; alternatively, the improvement in terms of melt flow index is about 60% over the unmodified resin.
The thermoplastic composition of the invention contains 5 (i) polycarbonate resin and (ii) an additive amount preferably about 5 to 30 percent by weight of a phosphorous compound conforming to O O
Il 11 Ar-O-P [--O-(residue)-O--P ]n--O-Ar O-Ar O-Ar 10 where n is about 1 to 7, preferably about 1 to 3, Ar is an aryl group, preferably a phenyl group and -(residue)- denotes the residue of a specific dihydroxydiaryl or a diglycol from which the hydrogen atoms of the OH groups have been removed. Among the suitable dihydroxydiaryl compounds are the ones conforming to formulae (I) and (Il) R5 R5 (I) HO~ OH

R1 R1 (I l) HO~ ( C ) ~ OH, F~2 R3 wherein Mo-41 65 21~7082 A is a single bond, C1-C5-aikylene, C2-C5-alkylidene, C5-C6-cycloalkylidene, -0-, -S- or-S02-, R5 and R6 independently of one another represent hydrogen methyl or halogen, in particular methyl, chlorine or bromine, R1 and R2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C~-C8-alkyl, preferably methyl or ethyl, C5-C6-cycloalkyl, preferably cyclohexyl, C6-C,0-aryl, preferably phenyl, or C7-C12-aralkyl, preferably phenyl-C,-C4-alkyl, in particular benzyl, m is an integer from 4 to 7, preferably 4 or 5, R3 and R4 can be individually selected for each X and independently of one another denote hydrogen or C~-C6-alkyl and X denotes carbon.
The diglycol suitable in the invention has 1 to 30 carbon atoms, 15 preferably 2 to 15 carbon atoms.
Especially suitable phosphorous compounds are bisphenol-A
bisdiphenylphosphate which conform to O
PHO--! _ O~+<~}O--P--OPH

OPH OPH n=1-7 and neopentyl glycol bis(diphenyl phosphate) conforming to Mo41 65 21~7~82 PHO--Pl OCH2 C CH2-- P OPH

The amount of phosphorous compound added to the 5 polycarbonate resin is that amount which imparts to the composition an improved degree of spiral flow and melt flow. More preferably, the amount added is about 1 to 15 percent, more preferably, about 5 to 15 percent of the phosphorous compound relative to the weight of the polycarbonate composition.
Aromatic polycarbonates within the scope of the present invention are homopolycarbonates and copolycarbonates and mixtures thereof.
The polycarbonates generally have a weight average molecular weight of 10,000-200,000, preferably 20,000-80,000 and their melt flow rate, per ASTM D-1238 at 300C, is about 1 to about 65 9/10 min., 15 preferably about 2-15 9/10 min. They may be prepared, for example, by the known diphasic interface process from a carbonic acid derivative such as phosgene and dihydroxy compounds by polycondensation (see German Oflenlegungsschriften 2,063,050; 2,063,052; 1,570,703;
2,211,956; 2,211,957 and 2,248,817; French Patent 1,561,518; and the 20 monograph H. Schnell, "Chemistry and Physics of Polycarbonates", Interscience Publishers, New York, New York, 1964, all incorporated herein by reference).
In the present context, dihydroxy compounds suitable for the preparation of the polycarbonates of the inventor conform to the 25 structural formulae (1) or (2).

Mo-4165 - 21~7082 (1) H0 ~ (A)~9 H0 (Z)d (2) (Z), (Z)f wherein 10 A denotes an alkylene group with 1 to 8 carbon atoms, an alkylidene group with 2 to 8 carbon atoms, a cycloalkylene group with 5 to 15 carbon atoms, a cycloalkylidene group with 5 to 15 carbon atoms, a carbonyl group, an oxygen atom, a sulfur atom, -S0- or -S02- or a radical conforming to CH,~ cCH3 e and g both denote the number 0 to 1; Z denotes F, Cl, Br or C~-C4-20 alkyl and if several Z radicals are substituents in one aryl radical, they Mo~1 65 . 2157082 may be identical or different from one another; d denotes an integer offrom 0 to 4; and f denotes an integer of from 0 to 3.
Among the dihydroxy compounds useful in the practice of the invention are hydroquinone, resorcinol, bis-(hydroxyphenyl)-alkanes, bis-5 (hydroxyphenyl)-ethers, bis-(hydroxyphenyl)-ketones, bis-(hydroxyphenyl)-sulfoxides, bis-(hydroxyphenyl)-sulfides, bis-(hydroxyphenyl)-sulfones, and a,a-bis-(hydroxyphenyl)-diisopropylbenzenes, as well as their nuclear-alkylated compounds. These and further suitable aromatic dihydroxy compounds are described, for example, in U.S. Patents 3,028,356; 2,999,835; 3,148,172; 2,991,273; 3,271,367; and 21999,846, all incorporated herein by reference.
Further examples of suitable bisphenols are 2,2-bis-(4-hydroxy-phenyl)-propane (bisphenol A), 2,4-bis-(4-hydroxyphenyl)-2-methyl-butane, 1,1-bis-(4-hydroxyphenyl)-cyclohexane, a,a'-bis-(4-hydroxy-phenyl)-p-diisopropylbenzene, 2,2-bis-(3-methyl-4-hydroxyphenyl)-propane, 2,2-bis-(3-chloro-4-hydroxyphenyl)-propane, bis-(3,5-dimethyl-4-hydroxyphenyl)-methane, 2,2-bis-(3,5-dimethyl-4-hydroxyphenyl)-propane, bis-(3,5-dimethyl-4-hydroxyphenyl)-sulfide, bis-(3,5-dimethyl-4-hydroxy-phenyl)-sulfoxide, bis-(3,5-dimethyl-4-hydroxyphenyl)-sulfone, dihydroxy-benzophenone, 2,4-bis-(3,5-dimethyl-4-hydroxyphenyl)-cyclohexane, a,a'-bis-(3,5-dimethyl-4-hydroxyphenyl)-p-diisopropylbenzene and 4,4'-sulfonyl diphenol.
Examples of particularly preferred aromatic bisphenols are 2,2,-bis-(4-hydroxyphenyl)-propane, 2,2-bis-(3,5-dimethyl-4-hydroxyphenyl)-propane and 1,1-bis-(4-hydroxyphenyl)-cyclohexane.
The most preferred bisphenol is 2,2-bis-(4-hydroxyphenyl)-propane (bisphenol A).
The polycarbonates of the invention may entail in their structure units derived from one or more of the suitable bisphenols.

Mo-4165 2157~

Among the resins suitable in the practice of the invention are included phenolphthalein-based polycarbonate, copolycarbonates and terpolycarbonates such as are described in U.S. Patents 3,036,036 and 4,210,741, both incorporated by reference herein.
The polycarbonates of the invention may also be branched by condensing therein small quantities, e.g., 0.05-2.0 mol % (relative to the bisphenols) of polyhydroxyl compounds.
Polycarbonates of this type have been described, for example, in German Offenlegungsschriften 1,570,533; 2,116,974 and 2,113,374;
British Patents 885,442 and 1,079,821 and U.S. Patent 3,544,514. The following are some examples of polyhydroxyl compounds which may be used for this purpose: phloroglucinol; 4,6-dimethyl-2,4,6-tri-(4-hydroxy-phenyl)-heptane; 1,3,5-tri-(4-hydroxyphenyl)-benzene; 1,1,1-tri-(4-hydroxy-phenyl)-ethane; tri-(4-hydroxyphenyl)-phenylmethane; 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)]-cyclohexyl-propane; 2,4-bis-(4-hydroxy-1-isopropy-lidine)-phenol; 2,6-bis-(2'-dihydroxy-5'-methylbenzyl)-4-methylphenol; 2,4-dihydroxybenzoic acid; 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4,4'-dihydroxytriphenylmethyl)-benzene. Some of the other polyfunctional compounds are 2,4-dihydroxybenzoic acid, trimesic acid, cyanuric chloride and 3,3-bis-(4-hydroxyphenyl)2-oxo-2,3-dihydroindole.
In addition to the polycondensation process mentioned above, other processes for the preparation of the polycarbonates of the invention are polycondensation in a homogeneous phase and transesterification.
25 The suitable processes are disclosed in the incorporated herein by references, U.S. Patents 3,028,365; 2,999,846; 3,153,008; and 2,991 ,273.
The preferred process for the preparation of polycarbonates is the interfacial polycondensation process.

Mo-41 65 Other methods of synthesis in forming the polycarbonates of the invention such as disclosed in U.S. Patent 3,912,688, incorporated herein by reference, may be used.
Suitable polycarbonate resins are available in commerce, for 5 instance, Makrolon FCR, Makrolon 2600, Makrolon 2800 and Makrolon 3100, all of which are bisphenol based homopolycarbonate resins differing in terms of their respective molecular weights and characterized in that their melt flow indices (MFR) per ASTM D-1238 are about 16.5-24, 13-16, 7.5-13.0 and 3.5-6.5 9/10 min., respectively. These are 10 products of Miles Inc., of Pittsburgh, Pennsylvania.
A polycarbonate resin suitable in the practice of the invention is known and its structure and methods of preparation have been disclosed, for example in U.S. Patents 3,030,331; 3,169,121; 3,395,119; 3,729,447;
4,255,556; 4,260,731; 4,369,303 and 4,714,746 all of which are 15 incorporated by reference herein.
The composition of the invention may include any of the conventional additives fillers and reinforcing agents. These mineral fillers, plasticizers, fluidizing agents, stabilizers against UV light, heat, moisture and the action of oxygen, pigments and flame retardants may be 20 incorporated in the composition in art-recognized amounts by following conventional procedures.
In a preferred embodiment, the composition further contains (iii) about 0 to 30 percent of a graft rubber copolymer (iv) about 0 to 30 percent of an aromatic vinyl copolymer and (v) about 0 to 5 percent 25 polytetraflouroethylene (PTFE). In further preferred embodiments, the composition contains about 3 to 15 percent graft rubber copolymer, 7 to 20 percent aromatic vinyl copolymer, 5 to 30 percent phosphorous compound and 35 to 85 percent polycarbonate resin.

Mo-4165 The graft rubber copolymer useful in the preferred embodiments of the invention is an ABS type polymer, the molecules of which contains two or more polymeric parts of different compositions, namely a rubber base (substrate) and a graft part (the grafted phase), that are bonded chemically. These are prepared by polymerizing a suitable monomer, for instance, butadiene or a conjugated diene, optionally with a comonomer polymerizable therewith such as styrene, to yield the rubber base. After the formation of the rubber base at least one grafting monomer, typically two, are polymerized (grafted phase) in the presence of the rubber base to obtain the graft rubber copolymer. The graft rubber copolymers which are preferably prepared by the known emulsion graft polymerization process are typically obtained by grafting at least one of the following monomers: chloroprene, butadiene-1,3, isoprene, 1,3-heptadiene, methyl-1,3-pentadiene, 2,3-dimethylbutadiene, 2-ethyl-1,3-pentadiene, 1,3- and 2,4-hexadiene as well as chloro and bromo-substituted butadienes, ethylene, propylene, vinyl acetate and C1 ~8 (meth)acrylate esters. Among the more preferred graft bases, mention may be made of butadiene, and butadiene/styrene. Other suitable monomers are described in "Methoden Der Organischen Chemie" (Houben-Weyl), Bd. 14/1, Georg Thieme-Verlag, Stuttgart 1961, pp.393-406 and in C.B. Bucknall, "Toughened Plastics", Appl.Science Publishers, London 1977, the disclosures of which are incorporated herein by reference.
The grafted phase may include styrene and/or acrylonitrile and/or alkyl (meth)acrylate, vinyl acetate, acrylonitrile and/or styrene.
Preferred graft copolymers are partially crosslinked and have gel content above 20 percent, preferably above 60 percent, relative to their weight. These grafts may be obtained by polymerization of 5-90, preferably 30 to 80, parts by weight (pbw) of a mixture of 50-95 pbw of at least one member selected from the group consisting of substituted or Mo-41 65 21~7D~2 unsubstituted styrene, alpha-methyl styrene and methyl methacrylate and 5 to 50 pbw of at least one member selected from the group consisting of acrylonitrile methacrylonitrile, methyl methacrylate, maleic anhydride and maleimide, in the presence of 10-95, preferably 20 to 70, pbw rubber having a glass transition temperature under -10C, as a graft base.
Especially preferred graft copolymers are ABS grafts.
In the preparation of the graft copolymer, the rubber substrate conjugated diolefin polymer or copolymer exemplified by a 1,3-butadiene polymer or copolymer preferably is present at a level of from 15 to 90 percent by weight, and more preferably at from 30 to 70 percent by weight, and most preferably about 50 percent by weight, of the total ABS
graft polymer. The monomers polymerized in the presence of the substrate to form the grafted portion, exemplified by styrene and acrylonitrile, preferably are together present at a combined level of from about 10 to about 85 percent by weight of the total ABS graft polymer, more preferably 30 to 70 weight percent thereof and most preferably about 50 weight percent thereof. It is additionally preferred that the second group of grafting monomers, exemplified by acrylonitrile ethyl acrylate and methyl methacrylate, comprise from about 10 percent to about 40 percent by weight of the grafted portion of the ABS resin while the monovinylaromatic hydrocarbon monomers, exemplified by styrene, comprise from about 60 to about 90 percent by weight of the grafted portion of the ABS resin.
Suitable graft copolymers have been disclosed in U.S. Patents 3,931,356; 3,957,912; 3,991,136; 4,206,293; 4,277,574; 4,559,386;
4,598,124; 5,075,375 and 3,130,177, the disclosures of which are incorporated herein by reference.
The aromatic vinyl copolymer suitable in the present context is the polymerization product of at least one, and preferably two monovinyl Mo-4165 aromatic hydrocarbons. The preferred monovinyl aromatic monomers utilized are generically described by the formula:

R 1~ /R
R C=C\R

wherein R is selected from the group consisting of hydrogen, alkyl groups containing from 1 to 5 carbon atoms, cycloalkyl, aryl, alkaryl, aralkyl, 10 alkoxy, aryloxy chloro and bromo. Examples of the monovinyl aromatic compounds and substituted monovinyl aromatic compounds that may be used are styrene and other vinyl-substituted aromatic compounds including alkyl-, cyclo-, aryl-, alkaryl-, alkoxy-, aralkyl-, aryloxy-, and other substituted vinyl aromatic compounds. Examples of such compounds are 15 3-methylstyrene; 3,5-diethylstyrene and 4-n-propylstyrene, a-methyl-styrene, a-methylvinyl-toluene, a-chlorostyrene, vinyltoluene, a-bromo-styrene, chlorophenyl ethylene, dibromophenyl ethylene, tetrachloro-phenyl ethylene, 1-vinyl-naphthalene, 2-vinylnaphthalene, mixtures thereof and the like. The preferred monovinyl aromatic hydrocarbon 20 used herein is styrene and/or a-methylstyrene.
The second group of monomers polymerized in the preparation of the copolymer of the invention conform to X\ /X
f C Y
X

Mo-41 65 wherein X is hydrogen, C1 5 alkyl, chlorine or bromine and Y is selected from the group consisting of cyano and carbalkoxy groups where the alkoxy group contains 1 to 12 carbon atoms. Examples include acrylo-nitrile, substituted acrylonitrile, ethacrylonitrile, methacrylonitrile, a-5 chloroacrylonitrile, ,B-chloroacrylonitrile, o~-bromoacrylonitrile and ~-bromoacrylonitrile, and/or acrylic acid esters such as methacrylate, methylmethacrylate, ethylacrylate, butylacrylate, propylacrylate, isopropyl-acrylate, isobutylacrylate, mixtures thereof and the like. The preferred acrylic monomer used herein is acrylonitrile and the preferred acrylic acid 10 esters are ethylacrylate and methylmethacrylate. Typically the copolymer contains about 50 to 95 pbw of the monomer(s) of the first group and about 5 to 50 pbw of monomer(s) of the second group. The preferred copolymer is styrene acrylonitrile (SAN) a resin which is well known and available in commerce.
The tetrafluoroethylene polymers suitable in the present context are polymers having a fluorine content of about 65 to 76% by weight, preferably 7 to 76%. Examples are polytetrafluoroethylene, tetrafluoro-ethylene/hexafluoropropylene copolymers and tetrafluoroethylene copolymers with small amounts of chlorine-free copolymerizable 20 ethyleneically unsaturated monomers.
These polymers as well as the methods for their preparation are known - see in this connection U.S. Patents 2,393,697 and 2,534,058;
the disclosures of which are incorporated herein by reference. Suitable polytetrafluoroethylene are available in commerce, for instance, as 25 Hostaflon TF 2026 from Hoechst.
The preparation of the compositions of the invention follows conventional procedures which are well known in the art.

Mo-4165 21~708~

The invention is further illustrated but is not intended to be limited by the following examples in which all parts and percentages are by weight unless otherwise specified.
EXAMPLES
Experimental:
Compositions within the scope of the present invention have been prepared and their properties determined as summarized below. In preparing these compositions and the comparative compositions the following materials were used:
POLYCARBONATE: Makrolon 2600 - a homopolycarbonate based on bisphenol-A, having a melt flow rate of 11 9/10 min. per ASTM
D-1238; (300C, 1.2 kg. Ioad).
COPOLYMER: styrene-acrylonitrile having a weight ratio of S/AN of about 72/28.
ABS: acrylonitrile-butadiene-styrene graft polymer, having a polybutadiene content of about 50 weight and a weight ratio of styrene/acrylonitrile of 72/28.
PTFE: polytetrafluoroethylene was added to the composition as a concentrate of 10% PTFE in ABS. The ABS used in the preparation of the concentrate was characterized in that it contained 55% by weight polybutadiene and the remainder (45%) contained SAN in a weight ratio of styrene/acrylonitrile of 72/28.
The amount of ABS noted in the table includes the ABS derived from the concentrate.
The phosphate compound in composition A: resorcinol diphenyl phosphate conforming to Mo-4165 O O
<~0 10~0 ~jl 0~

n in composition C: neopentyl glycol bis(diphenyl phosphate) conforming to OPH ~ CH3 OPH n n = about 1 in composition B: bisphenol A(diphenylphosphate) conforming to O - O-PHO--P ~ ¦ C~}O P--OPH

OPH OPH n = about 1 in composition D: resorcinol dixylylphosphate conforming to (R)2--P~O --P ) n (~) 2 n = about 1 wherein R =~-CH3 Mo-41 65 The amounts of the components were adjusted so as to obtain a substantially identical phosphorous content in the compositions.
Table 1 A B C D
I ngredient Polycarbonate 68.4 66.9 66.1 66.9 copolymer 10.2 10.0 9.9 10.0 ABS 7.7 7.5 7.4 7.5 phosphate 10.2 12.3 13.2 12.3 PTFE 3.6 3.4 3.4 3.4 approxi" IdL~ P%
in formulation 1.10 1.10 1.18 1.10 MeK Flow Rate' (g/10 min) 20.8 40.5 39.7 32.7 Spiral Flow2, inches 25.25 32 32 29 Tensile Strength, Yield (kpsi) 8.7 9.0 8.8 9-4 Elongabon atYield (%) 3.0 3.2 2.4 2.4 Tensile Strength, @Break (kpsi) 8.6 6.9 7.6 7.5 Elongdlion at Break (%) 118.0 63.0 122.0 95.8 Flexural Strength (kpsi)15.7 15.7 15.1 16.1 Flexural Modulus (psi x 105) 4.2 4.2 4.2 4.3 Vicat, VST B/120C 97.6 92.3 84.7 94.3 Notched Izod Impact .125 in. 73F (ft~lbs) 13.7 12.2 13.1 10.2 Instrumented Impact 23C, 125 mil, Total Energy (ft~lbs) 41.8 39.4 38.0 39 7 Mo-41 65 TABLE 1 (Cont.) A B C D
Fla"""abilil~r UL 94 5V
125 mil 5V 5V Fail Fail Melt Stability @ 5min636 345 409 382 35min 654 364 345 318 ~ 65min 654 364 345 318 Melt Viscosity (Pa~s) at:
8.5 1 218 582 945 709 17.0 1 000 518 700 682 42.6 764 400 491 436 85.1 636 345 409 382 170.2 573 327 373 350 425.5 407 244 273 256 1 5 851.0 298 196 205 204 ' @250C and 50009 load 2 100 mil @ 490F

The results demonstrate the higher melt flow rate and improved 20 spiral flow, which characterize compositions B and C which represent the invention.
Although the invention has been described in detail in the foregoing for the purpose of illustration, it is to be understood that such detail is solely for that purpose and that variations can be made therein 25 by those skilled in the art without departing from the spirit and scope of the invention except as it may be limited by the claims.

Mo-41 65

Claims (9)

1. A thermoplastic molding composition comprising (i) polycarbonate resin and (ii) an additive amount of a phosphorous compound conforming to where n is about 1 to 7 Ar is an aryl group, and -(residue)- denotes the residue of a specific dihydroxydiaryl or a diglycol from which the hydrogen atoms of the OH groups have been removed.

2. The composition of Claim 1 further containing (iii) about 0-30% by weight of graft rubber copolymer (iv) about 0-30% by weight of a vinyl aromatic copolymer and (v) about 0-5% by weight polytetrafluoro-ethylene.

3. The composition of Claim 2 wherein said graft rubber copolymer is the polymerization product of 5-90 pbw of a mixture of 50-95 pbw of at least one member selected from the group consisting of substituted or unsubstituted styrene, .alpha.-methyl styrene and methyl methacrylate and 5 to 50 pbw of at least one member selected from the group consisting of acrylonitrile methacrylonitrile, methyl methacrylate, maleic anhydride and maleimide, in the presence of 10-95 pbw rubber having a glass transition temperature under -10°C, as a graft base.

4. The composition of Claim 3 wherein said graft base is selected from the group consisting of chloroprene, butadiene-1,3-isoprene, 1,3-heptadiene, methyl-1,3-pentadiene, 2,3-dimethylbutadiene, 2-ethyl-1,3-pentadiene, 1,3-hexadiene and 2,4-hexadiene.

5. The composition of Claim 2 wherein said aromatic vinyl copolymer is the polymerization product of (a) at least one member selected from the group consisting of styrene 3-methyl-styrene; 3,5-diethylstyrene, 4-n-propylstyrene, .alpha.-methylstyrene, .alpha.-methylvinyltoluene, .alpha.-chlorostyrene, vinyltoluene, .alpha.-bromostyrene, chlorophenyl ethylene, dibromophenyl ethylene, tetrachlorophenyl ethylene, 1-vinylnaphthalene, 2-vinylnaphthalene, and (b) at least one member selected from the group consisting of acrylonitrile, substituted acrylonitrile, ethacrylonitrile, methacrylonitrile, .alpha.-chloroacrylonitrile, .beta.-chloroacrylonitrile, .alpha.-bromo-acrylonitrile, .beta.-bromoacrylonitrile, and acrylic acid ester.

6. The composition of Claim 5 wherein said (a) is at least one member selected from the group consisting of styrene and .alpha.-methyl-styrene.

7. The composition of Claim 2 wherein said copolymer is styrene acrylonitrile resin.

8. The composition of Claim 2 wherein said graft rubber copolymer is ABS and said aromatic vinyl copolymer is SAN.

9. The composition of Claim 2 wherein said graft rubber copolymer is present in an amount of 3-15%, said aromatic vinyl copolymer is present in amount of 7-20%, said phosphorus compound is present in amount of 5-30% and said polycarbonate is present in an amount of 35-85%.