CA2153312C - Detergent composition and process for producing it - Google Patents
Detergent composition and process for producing it Download PDFInfo
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- CA2153312C CA2153312C CA002153312A CA2153312A CA2153312C CA 2153312 C CA2153312 C CA 2153312C CA 002153312 A CA002153312 A CA 002153312A CA 2153312 A CA2153312 A CA 2153312A CA 2153312 C CA2153312 C CA 2153312C
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A particulate high bulk density detergent composition is provided having improved dissolution characteristics and comprising a surfactant system including one or more anionic and/or nonionic surfactants, at least one detergency builder and a dissolution aid. The dissolution aid is present in an amount from 0.01 to 2 % by weight as calculated on the composition and comprises a nonionic surfactant which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups.
Description
DETERGENT COMPOSITION AND PROCESS FOR PRODUCING IT
The present invention relates to a detergent composition suitable for use in fabric washing applications. The i invention is of especial applicability to particulate detergent compositions, containing no, or low levels of, phosphate builder and to compositions of high bulk density.
The invention also relates to a process for producing this composition.
In recent years there has been a trend to reduce or eliminate phosphate builders in particulate detergent compositions.
The replacement of sodium tripolyphosphate as a builder in detergent powders by a crystalline aluminosilicate (zeolite), has led to a number of difficulties with the structure and physical properties of powders. One such problem that has been encountered, is the tendency of zeolite-built powders to dispense less well in automatic washing machines than do their phosphate-built counter-parts; a higher proportion of the powder dosed into the washing machine is left in the dispenser, in the washing process leading to product wastage and clogging. The problem is especially marked at low water inlet temperatures.
The tendency towards poor dispensing has been exacerbated by the recent trend in the detergent industry towards higher bulk density powders. Detergent powders of high bulk densities from 600 to 1100 kg/m', preferably from 700 to 1100 kg/m', are attractive to the customer. Because the capillary diameter of the high bulk density powder is smaller than in w low bulk density powders, the water penetration into the particle is slower. As a consequence, when the powder is wetted by water flowing through the dispenser the detergent particles may stick together resulting in considerable residues of wetted and adhering powder left behind in the _ 2 _ drawer. Similar problems may be encountered when applying a detergent dosing device as described in EP-A-253,419, for in-c drum dosing of high density detergent powder.
Detergent powders typically comprise anionic and/or nonionic surfactants. Nonionic surfactants are particularly effective in removing hydrophobic soils such as hydrocarbon oils, complex fats and other long-chain unsaturated and saturated glycerides. However, when detergent powders containing nonionic surfactants come into contact with aqueous solutions, the nonionic surfactant may form a viscous phase which may impede dissolution. Nonionic surfactants having a low degree of ethoxylation, generally employed because of their oily soil detergency, are especially problematic in this respect.
It has now surprisingly been found that the problem of poor dissolution and/or dispersion in the wash liquor of such a powder can be overcome by incorporating in the powder a relatively small amount of an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups.
Accordingly, the present invention provides a particulate detergent composition having a bulk density of at least 600 g/1 comprising a surfactant system, at least one detergency builder and a dissolution aid wherein the dissolution aid is present in an amount of 0.01 to 2~ by weight as calculated on the composition and comprises a nonionic material which is an alkoxylated, aliphatic alcohol containing at least 25 alkylene oxide groups.
The invention also provides a process for the production of a particulate detergent composition having a bulk density of at least 600 g/1 comprising a surfactant system, at least one detergency builder and a dissolution aid wherein the ~O 94/16052 3 _ dissolution aid is present in an amount of from 0,01 to 2~ by weight as calculated on the composition and comprises a a nonionic material which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, which process comprises mixing the dissolution aid with the surfactant system and builder sequentially or simultaneously.
The invention further provides the use of an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, as a dissolution aid in a particulate detergent composition having a bulk density of at least 600 g/1.
Suitably a granular detergent composition according to the invention has a bulk density from 600 to 1100 kg/m', preferably from 700 to 1100 kg/m3. Various postdosed ingredients, such as sodium carbonate, bleach material and foam depressing agent, may be added to the composition as desired. The composition may be prepared by spray-drying optionally followed by mixing or by dry-mixing/agglomeration.
For obtaining high bulk densities, the composition is preferably prepared by dry-mixing/agglomeration.
As essential ingredients, the composition contains surfactant system, builder material and a dissolution aid. It is preferred that the dissolution aid is present in the composition of the invention as a separate granular component. Preferably the dissolution aid is substantially pure alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups.
The detergent compositions of the invention are characterised by a dissolution aid comprising a nonionic material which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, preferably at least 50 alkylene oxide groups, more preferably at least 80 alkylene oxide groups.
The present invention relates to a detergent composition suitable for use in fabric washing applications. The i invention is of especial applicability to particulate detergent compositions, containing no, or low levels of, phosphate builder and to compositions of high bulk density.
The invention also relates to a process for producing this composition.
In recent years there has been a trend to reduce or eliminate phosphate builders in particulate detergent compositions.
The replacement of sodium tripolyphosphate as a builder in detergent powders by a crystalline aluminosilicate (zeolite), has led to a number of difficulties with the structure and physical properties of powders. One such problem that has been encountered, is the tendency of zeolite-built powders to dispense less well in automatic washing machines than do their phosphate-built counter-parts; a higher proportion of the powder dosed into the washing machine is left in the dispenser, in the washing process leading to product wastage and clogging. The problem is especially marked at low water inlet temperatures.
The tendency towards poor dispensing has been exacerbated by the recent trend in the detergent industry towards higher bulk density powders. Detergent powders of high bulk densities from 600 to 1100 kg/m', preferably from 700 to 1100 kg/m', are attractive to the customer. Because the capillary diameter of the high bulk density powder is smaller than in w low bulk density powders, the water penetration into the particle is slower. As a consequence, when the powder is wetted by water flowing through the dispenser the detergent particles may stick together resulting in considerable residues of wetted and adhering powder left behind in the _ 2 _ drawer. Similar problems may be encountered when applying a detergent dosing device as described in EP-A-253,419, for in-c drum dosing of high density detergent powder.
Detergent powders typically comprise anionic and/or nonionic surfactants. Nonionic surfactants are particularly effective in removing hydrophobic soils such as hydrocarbon oils, complex fats and other long-chain unsaturated and saturated glycerides. However, when detergent powders containing nonionic surfactants come into contact with aqueous solutions, the nonionic surfactant may form a viscous phase which may impede dissolution. Nonionic surfactants having a low degree of ethoxylation, generally employed because of their oily soil detergency, are especially problematic in this respect.
It has now surprisingly been found that the problem of poor dissolution and/or dispersion in the wash liquor of such a powder can be overcome by incorporating in the powder a relatively small amount of an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups.
Accordingly, the present invention provides a particulate detergent composition having a bulk density of at least 600 g/1 comprising a surfactant system, at least one detergency builder and a dissolution aid wherein the dissolution aid is present in an amount of 0.01 to 2~ by weight as calculated on the composition and comprises a nonionic material which is an alkoxylated, aliphatic alcohol containing at least 25 alkylene oxide groups.
The invention also provides a process for the production of a particulate detergent composition having a bulk density of at least 600 g/1 comprising a surfactant system, at least one detergency builder and a dissolution aid wherein the ~O 94/16052 3 _ dissolution aid is present in an amount of from 0,01 to 2~ by weight as calculated on the composition and comprises a a nonionic material which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, which process comprises mixing the dissolution aid with the surfactant system and builder sequentially or simultaneously.
The invention further provides the use of an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, as a dissolution aid in a particulate detergent composition having a bulk density of at least 600 g/1.
Suitably a granular detergent composition according to the invention has a bulk density from 600 to 1100 kg/m', preferably from 700 to 1100 kg/m3. Various postdosed ingredients, such as sodium carbonate, bleach material and foam depressing agent, may be added to the composition as desired. The composition may be prepared by spray-drying optionally followed by mixing or by dry-mixing/agglomeration.
For obtaining high bulk densities, the composition is preferably prepared by dry-mixing/agglomeration.
As essential ingredients, the composition contains surfactant system, builder material and a dissolution aid. It is preferred that the dissolution aid is present in the composition of the invention as a separate granular component. Preferably the dissolution aid is substantially pure alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups.
The detergent compositions of the invention are characterised by a dissolution aid comprising a nonionic material which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, preferably at least 50 alkylene oxide groups, more preferably at least 80 alkylene oxide groups.
Preferably at least 50~, more preferably at least 80~ and especially substantially all of the alkylene oxide groups are ethylene oxide. The dissolution aid is suitably present at a level of from 0.01 to 2~ by weight, preferably from 0.05 to 0.5~ by weight based on the composition.
The surfactant system present in the detergent composition of the invention suitably contains alkoxylated nonionic surfactants having an average degree of alkoxylation of at most 11. Suitable nonionic surfactants include condensation products of ethylene oxide with an aliphatic alcohol having from 8 to 15 carbon atoms and an average degree of ethoxylation from 2 to 10.
A preferred surfactant system comprises a mixture of two C8_ls nonionic surfactants having an average degree of ethoxylation respectively of 2 to 5, preferably 2.5 to 4 and 6.5 to 10, preferably 6.5 to 8 which, suitably, are present in a weight ratio of 1 to 25:5. In order to obtain particularly beneficial dissolution properties it is especially preferred that the proportion of nonionic surfactant having a branched aliphatic alcohol is in the range from 10 to 60~ by weight for example about 55~ by weight based on the total amount of nonionic surfactant in the composition.
Nonionic detergent-active compounds and the dissolution aid together are suitably present in the compositions of the invention in a total amount of from 2 to 50g by weight, preferably from 5 to 30~ by weight.
In addition to the nonionic surfactants mentioned above, other detergent-active materials may be present in the compositions of the invention. These additional detergent-active materials may be anionic (soap or non-soap), cationic, _ 5 _ zwitterionic, amphoteric surfactants, or any combination of these surfactants.
Anionic detergent-active compounds may be present in an amount of from 0 to 40~ by weight, preferably from 0 to 20~
by weight. It is preferred that the ratio of nonionic surfactant and dissolution aid to anionic surfactant is within the range of 1:2 to 9:1.
Synthetic anionic surfactants are well known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly sodium linear alkylbenzene sulphonates having an alkyl chain length of C8-C15; primary and secondary alkyl sulphates, particularly sodium C12-C15 primary alkyl sulphates, olefin sulphonates; alkane sulphonates; dialkyl sulphosuccinate; and fatty acid ester sulphonates.
It may also be desirable to include one or more soaps of fatty acids. These are preferably sodium soaps derived from naturally occurring fatty acids, for example the fatty acids from coconut oil, beef tallow, sunflower or hardened rapeseed oil.
The total amount of surfactant in the compositions of the invention is suitably from 5 to 50$ by weight. Of particular interest are high-performance compositions containing relatively high levels of surfactant, preferably from 10 to 50g by weight and more preferably from 15 to 50g by weight.
Especially preferred compositions according to the invention include surfactant systems consisting especially of nonionic surfactant as described above in combination with linear alkylbenzene sulphonate (LAS) or primary alcohol sulphate (PAS) or both.
_ 6 _ Surfactant systems of especial interest consist essentially of (i) from 40 to 100 by weight of ethoxylated nonionic surfactant, and (ii) from 0 to 60~ by weight of linear alkylbenzene sulphonate or primary Ce-C18 alcohol sulphate.
The detergent powders of the invention contain one or more detergency builders, suitably in an amount from 5 to 80~ by weight, preferably from 20 to 60~ by weight. The invention is especially applicable to compositions containing alkali metal aluminosilicates as builders. Alkali metal (preferably sodium) aluminosilicates may generally be incorporated in an amount from 5 to 60~ by weight (anhydrous basis) of the composition, preferably from 25 to 55~ by weight, and suitably, in a heavy duty detergent composition, from 25 to 46~ by weight.
The alkali metal aluminosilicate may be either crystalline or amorphous or mixtures thereof, having the general formula:
0.8-1.5 Na20. A12O3. 0.8-6 Si02 These materials contain some bound water and are required to have a calcium ion exchange capacity of at least 50 mg Ca0/g.
The preferred sodium aluminosilicates contain 1.5-3.5 SiOz units (in the formula above).
Suitable crystalline sodium aluminosilicates ion-exchange detergency builders are described, for example, in GB 1,429,143 (Procter & Gamble). The preferred sodium aluminosilicates of this type are the well-known commercially available zeolite A and X, and mixtures thereof. .
94/16052 ~ ~ PCTIEP93I03624 The zeolite may be the commercially available zeolite 4A now widely used in laundry detergent powders. Alternatively, the zeolite builder incorporated in the compositions of the invention is maximum aluminium zeolite P (zeolite MAP) as A
described and claimed in EP-A-384,070 (Unilever). Zeolite MAP is defined as an alkali metal aluminosilicate of the zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, and more preferably within the range of from 0.90 to 1.20.
The calcium binding capacity of zeolite MAP is generally at least 150 mg Cao per g of anhydrous material.
Other builders may also be included in the detergent compositions of the invention if necessary or desired.
Inorganic builders that may be present include sodium carbonate, if desired in combination with a crystallisation seed for calcium carbonate, as disclosed in GB 1,437,950 (Unilever).
Organic builders that may be present include polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di-and trisuccinates, carboxymethyloxysuccinates, hydroxy-ethyliminodiacetates, alkyl- and alkenyl-malonates and succinates; and sulphonated fatty acid salts. This list is not intended to be exhaustive.
Builders, both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
Especially preferred supplementary builders are polycarboxylate polymers, more especially polyacrylates and acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15o by weight, especially from 1 to 10~ by weight; and monomeric polycarboxylates, more especially citric acid and its salts, suitably used in amounts of from 3 to 20~ by weight, more preferably from 5 to 15~ by weight.
The compositions according to the invention may contain alkali metal, preferably sodium, carbonate, to increase detergency and to ease processing. Sodium carbonate may generally be present in amounts ranging from 1 to 60~by weight, preferably from 2 to 40~ by weight, and most preferably from 2 to 13~ by weight. However, compositions free of alkali metal carbonate are also within the scope of the invention.
Preferred compositions of the invention preferably do not contain more than 5~ by weight of inorganic phosphate builders, and are desirably substantially free of phosphate builders.
Fully formulated laundry detergent compositions according to the present invention may additionally contain any suitable ingredients normally employed in detergent compositions, for example, inorganic salts such as sodium silicate or sodium sulphate; organic salts such as sodium citrate; anti-redeposition aids such as cellulose derivatives and acrylate or acrylate/maleate polymers; fluorescers; bleaches, bleach precursors and bleach stabilizers; proteolytic and lipolytic enzymes; dyes; coloured speckles; perfumes; foam controllers;
fabric softening compounds.
A
The particulate detergent compositions of the invention may in principle be prepared by any of the available tower ..
(spray-drying), non-tower (granulation) or combination processes.
~O 94/16052 PCTlEP93103624 Of especial interest are compositions of high bulk density -at least 600 g/1, preferably at least 700 g/1 and most preferably at least 800 g/1 - which may be prepared by processes involving granulation and/or densification in a high-speed mixer/granulator.
One suitable method comprises spray-drying a slurry of compatible heat-insensitive ingredients, including the zeolite MAP, any other builders, and at least part of the detergent-active compounds; densifying the resulting base powder in a mixer/granulator; and then spraying on or post-dosing those ingredients unsuitable for processing via the slurry (for example bleaches and enzymes).
In another method, the spray-drying step can be omitted altogether, a high bulk density base powder being prepared directly from its constituent raw materials, by mixing and granulating in a high speed mixer/granulator, and then post-dosing bleach and other ingredients as in the spray-drying/post-tower densification route.
The high-speed mixer/granulator, also known as a high-speed mixer/densifier, may be a batch machine such as the Fukae (Trade Mark)FS, or a continuous machine such as the Lodige (Trade Mark) Recycler CB30.
Processes using high-speed mixer/granulators are disclosed, for example, in EP-A-340,013, EP-A-367,339, EP-A-390,251 and EP-A-420,317 (Unilever).
The dissolution aid may be included in the base powder but is preferably admixed with the finished base powder.
Nonionic surfactants having a lower degree of alkoxylation, particularly those containing on average less than 11 ethylene oxide groups, may be included in the base powder, post added, or both.
_ _ As mentioned above, detergent compositions according to the present invention have been found to show improved dissolution properties when employed in a washing process in a washing machine. Additional benefits associated with the 5 invention were found to be reduced redeposition characteristics during the washing cycle and improved bleeding behaviour upon storage.
EXAMPLES
The following non-limiting Examples illustrate the invention.
Examples identified by numbers are in accordance with the invention, those identified by letter are comparative. Parts and percentages are by weight unless otherwise stated.
Fxamn'1 as '1 -4 _ ('nmnaraY_iYe EX3IT11?1G A
A particulate detergent composition having a bulk density of 830 kg/m3 was prepared by spray-drying an aqueous slurry to form a base powder (including nonionic surfactants as specified), densifying the base powder in a continuous Lodige high-speed mixer/granulator, spraying-on further nonionic surfactants as specified, and then admixing the remaining ingredients.
The general formulation, in weight percent, is shown in Table 1.
i ~O 94/16052 PCTIEP93/03624 Base powder Linear alkylbenzene sulphonate 8.60 *Nonionic surfactant (i) 1.92 Zeolite 4A1 23.61 Acrylic/maleic copolymerz 3.51 Sodium carbonate 7.49 Minor ingredients' 1.35 Moisture 9.02 55.50 Sprayed-on **Nonionic surfactant (ii) 4.68 '~-'~
Admixed Zeolite 4A 5.00 Sodium Carbonate 4.30 Granular sodium silicate 3.75 Sodium perborate monohydrate 15.00 EDTMPS 0.37 Antifoam granulesb 2.00 Enzyme granules 1.00 Perfume 0.&5 100.00 wherein:
x nonionic ethoxylated alcohol, Synperonic A7 (containing 7 EO groups), ex ICI
** nonionic ethoxylated alcohol, 1:1 mixture of Synperionic A3 and A7 (containing 3 and 7 EO groups), ex ICI
1: wessalith (Trade Mark) P powder ex Degussa: percentage is for anhydrous material, the water of hydration being included in the figure for total moisture.
2: Sokalan (Trade Mark) CP5, ex BASF.
3: Fluorescer, sodium carboxymethylcellulose, salts, etc.
~O 94/16052 , PCT/EP93/03624 4: Tetraacetylethylenediamine, as 83~wt granules.
5: Ethylenediaminetetramethylenephosphonic acid, calcium salt: bequest (Trade Mark) 2047 ex Monsanto (34owt active).
The surfactant system present in the detergent composition of the invention suitably contains alkoxylated nonionic surfactants having an average degree of alkoxylation of at most 11. Suitable nonionic surfactants include condensation products of ethylene oxide with an aliphatic alcohol having from 8 to 15 carbon atoms and an average degree of ethoxylation from 2 to 10.
A preferred surfactant system comprises a mixture of two C8_ls nonionic surfactants having an average degree of ethoxylation respectively of 2 to 5, preferably 2.5 to 4 and 6.5 to 10, preferably 6.5 to 8 which, suitably, are present in a weight ratio of 1 to 25:5. In order to obtain particularly beneficial dissolution properties it is especially preferred that the proportion of nonionic surfactant having a branched aliphatic alcohol is in the range from 10 to 60~ by weight for example about 55~ by weight based on the total amount of nonionic surfactant in the composition.
Nonionic detergent-active compounds and the dissolution aid together are suitably present in the compositions of the invention in a total amount of from 2 to 50g by weight, preferably from 5 to 30~ by weight.
In addition to the nonionic surfactants mentioned above, other detergent-active materials may be present in the compositions of the invention. These additional detergent-active materials may be anionic (soap or non-soap), cationic, _ 5 _ zwitterionic, amphoteric surfactants, or any combination of these surfactants.
Anionic detergent-active compounds may be present in an amount of from 0 to 40~ by weight, preferably from 0 to 20~
by weight. It is preferred that the ratio of nonionic surfactant and dissolution aid to anionic surfactant is within the range of 1:2 to 9:1.
Synthetic anionic surfactants are well known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly sodium linear alkylbenzene sulphonates having an alkyl chain length of C8-C15; primary and secondary alkyl sulphates, particularly sodium C12-C15 primary alkyl sulphates, olefin sulphonates; alkane sulphonates; dialkyl sulphosuccinate; and fatty acid ester sulphonates.
It may also be desirable to include one or more soaps of fatty acids. These are preferably sodium soaps derived from naturally occurring fatty acids, for example the fatty acids from coconut oil, beef tallow, sunflower or hardened rapeseed oil.
The total amount of surfactant in the compositions of the invention is suitably from 5 to 50$ by weight. Of particular interest are high-performance compositions containing relatively high levels of surfactant, preferably from 10 to 50g by weight and more preferably from 15 to 50g by weight.
Especially preferred compositions according to the invention include surfactant systems consisting especially of nonionic surfactant as described above in combination with linear alkylbenzene sulphonate (LAS) or primary alcohol sulphate (PAS) or both.
_ 6 _ Surfactant systems of especial interest consist essentially of (i) from 40 to 100 by weight of ethoxylated nonionic surfactant, and (ii) from 0 to 60~ by weight of linear alkylbenzene sulphonate or primary Ce-C18 alcohol sulphate.
The detergent powders of the invention contain one or more detergency builders, suitably in an amount from 5 to 80~ by weight, preferably from 20 to 60~ by weight. The invention is especially applicable to compositions containing alkali metal aluminosilicates as builders. Alkali metal (preferably sodium) aluminosilicates may generally be incorporated in an amount from 5 to 60~ by weight (anhydrous basis) of the composition, preferably from 25 to 55~ by weight, and suitably, in a heavy duty detergent composition, from 25 to 46~ by weight.
The alkali metal aluminosilicate may be either crystalline or amorphous or mixtures thereof, having the general formula:
0.8-1.5 Na20. A12O3. 0.8-6 Si02 These materials contain some bound water and are required to have a calcium ion exchange capacity of at least 50 mg Ca0/g.
The preferred sodium aluminosilicates contain 1.5-3.5 SiOz units (in the formula above).
Suitable crystalline sodium aluminosilicates ion-exchange detergency builders are described, for example, in GB 1,429,143 (Procter & Gamble). The preferred sodium aluminosilicates of this type are the well-known commercially available zeolite A and X, and mixtures thereof. .
94/16052 ~ ~ PCTIEP93I03624 The zeolite may be the commercially available zeolite 4A now widely used in laundry detergent powders. Alternatively, the zeolite builder incorporated in the compositions of the invention is maximum aluminium zeolite P (zeolite MAP) as A
described and claimed in EP-A-384,070 (Unilever). Zeolite MAP is defined as an alkali metal aluminosilicate of the zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, and more preferably within the range of from 0.90 to 1.20.
The calcium binding capacity of zeolite MAP is generally at least 150 mg Cao per g of anhydrous material.
Other builders may also be included in the detergent compositions of the invention if necessary or desired.
Inorganic builders that may be present include sodium carbonate, if desired in combination with a crystallisation seed for calcium carbonate, as disclosed in GB 1,437,950 (Unilever).
Organic builders that may be present include polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di-and trisuccinates, carboxymethyloxysuccinates, hydroxy-ethyliminodiacetates, alkyl- and alkenyl-malonates and succinates; and sulphonated fatty acid salts. This list is not intended to be exhaustive.
Builders, both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
Especially preferred supplementary builders are polycarboxylate polymers, more especially polyacrylates and acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15o by weight, especially from 1 to 10~ by weight; and monomeric polycarboxylates, more especially citric acid and its salts, suitably used in amounts of from 3 to 20~ by weight, more preferably from 5 to 15~ by weight.
The compositions according to the invention may contain alkali metal, preferably sodium, carbonate, to increase detergency and to ease processing. Sodium carbonate may generally be present in amounts ranging from 1 to 60~by weight, preferably from 2 to 40~ by weight, and most preferably from 2 to 13~ by weight. However, compositions free of alkali metal carbonate are also within the scope of the invention.
Preferred compositions of the invention preferably do not contain more than 5~ by weight of inorganic phosphate builders, and are desirably substantially free of phosphate builders.
Fully formulated laundry detergent compositions according to the present invention may additionally contain any suitable ingredients normally employed in detergent compositions, for example, inorganic salts such as sodium silicate or sodium sulphate; organic salts such as sodium citrate; anti-redeposition aids such as cellulose derivatives and acrylate or acrylate/maleate polymers; fluorescers; bleaches, bleach precursors and bleach stabilizers; proteolytic and lipolytic enzymes; dyes; coloured speckles; perfumes; foam controllers;
fabric softening compounds.
A
The particulate detergent compositions of the invention may in principle be prepared by any of the available tower ..
(spray-drying), non-tower (granulation) or combination processes.
~O 94/16052 PCTlEP93103624 Of especial interest are compositions of high bulk density -at least 600 g/1, preferably at least 700 g/1 and most preferably at least 800 g/1 - which may be prepared by processes involving granulation and/or densification in a high-speed mixer/granulator.
One suitable method comprises spray-drying a slurry of compatible heat-insensitive ingredients, including the zeolite MAP, any other builders, and at least part of the detergent-active compounds; densifying the resulting base powder in a mixer/granulator; and then spraying on or post-dosing those ingredients unsuitable for processing via the slurry (for example bleaches and enzymes).
In another method, the spray-drying step can be omitted altogether, a high bulk density base powder being prepared directly from its constituent raw materials, by mixing and granulating in a high speed mixer/granulator, and then post-dosing bleach and other ingredients as in the spray-drying/post-tower densification route.
The high-speed mixer/granulator, also known as a high-speed mixer/densifier, may be a batch machine such as the Fukae (Trade Mark)FS, or a continuous machine such as the Lodige (Trade Mark) Recycler CB30.
Processes using high-speed mixer/granulators are disclosed, for example, in EP-A-340,013, EP-A-367,339, EP-A-390,251 and EP-A-420,317 (Unilever).
The dissolution aid may be included in the base powder but is preferably admixed with the finished base powder.
Nonionic surfactants having a lower degree of alkoxylation, particularly those containing on average less than 11 ethylene oxide groups, may be included in the base powder, post added, or both.
_ _ As mentioned above, detergent compositions according to the present invention have been found to show improved dissolution properties when employed in a washing process in a washing machine. Additional benefits associated with the 5 invention were found to be reduced redeposition characteristics during the washing cycle and improved bleeding behaviour upon storage.
EXAMPLES
The following non-limiting Examples illustrate the invention.
Examples identified by numbers are in accordance with the invention, those identified by letter are comparative. Parts and percentages are by weight unless otherwise stated.
Fxamn'1 as '1 -4 _ ('nmnaraY_iYe EX3IT11?1G A
A particulate detergent composition having a bulk density of 830 kg/m3 was prepared by spray-drying an aqueous slurry to form a base powder (including nonionic surfactants as specified), densifying the base powder in a continuous Lodige high-speed mixer/granulator, spraying-on further nonionic surfactants as specified, and then admixing the remaining ingredients.
The general formulation, in weight percent, is shown in Table 1.
i ~O 94/16052 PCTIEP93/03624 Base powder Linear alkylbenzene sulphonate 8.60 *Nonionic surfactant (i) 1.92 Zeolite 4A1 23.61 Acrylic/maleic copolymerz 3.51 Sodium carbonate 7.49 Minor ingredients' 1.35 Moisture 9.02 55.50 Sprayed-on **Nonionic surfactant (ii) 4.68 '~-'~
Admixed Zeolite 4A 5.00 Sodium Carbonate 4.30 Granular sodium silicate 3.75 Sodium perborate monohydrate 15.00 EDTMPS 0.37 Antifoam granulesb 2.00 Enzyme granules 1.00 Perfume 0.&5 100.00 wherein:
x nonionic ethoxylated alcohol, Synperonic A7 (containing 7 EO groups), ex ICI
** nonionic ethoxylated alcohol, 1:1 mixture of Synperionic A3 and A7 (containing 3 and 7 EO groups), ex ICI
1: wessalith (Trade Mark) P powder ex Degussa: percentage is for anhydrous material, the water of hydration being included in the figure for total moisture.
2: Sokalan (Trade Mark) CP5, ex BASF.
3: Fluorescer, sodium carboxymethylcellulose, salts, etc.
~O 94/16052 , PCT/EP93/03624 4: Tetraacetylethylenediamine, as 83~wt granules.
5: Ethylenediaminetetramethylenephosphonic acid, calcium salt: bequest (Trade Mark) 2047 ex Monsanto (34owt active).
6: Antifoam granules in accordance with EP-B-266,863 (Unilever).
To the thus prepared particulate detergent composition varying -minor- amounts of several types of ethoxylated alcohol containing at least 25 ethylene oxide (E0) groups, were postdosed, as specified in Table 2. Suitable commercially available nonionic materials containing at least 25 EO groups include the LUTENSOL AT [Trade Mark] series ex BASF and the BRIJ [Trade Mark] series ex ICI.
As can be seen, the type of the postdosed nonionic materials is indicated in this Table by number of EO-groups present therein.
'~ - 14 -Example tdosed high EO nonionic material amount (parts) type A 0.000 --1 0.50 25 EO
2 0.125 25 EO
3 0.50 50 EO
4 0.125 50 EO
5 1.00 80 EO
6 0.50 80 EO
To the thus prepared particulate detergent composition varying -minor- amounts of several types of ethoxylated alcohol containing at least 25 ethylene oxide (E0) groups, were postdosed, as specified in Table 2. Suitable commercially available nonionic materials containing at least 25 EO groups include the LUTENSOL AT [Trade Mark] series ex BASF and the BRIJ [Trade Mark] series ex ICI.
As can be seen, the type of the postdosed nonionic materials is indicated in this Table by number of EO-groups present therein.
'~ - 14 -Example tdosed high EO nonionic material amount (parts) type A 0.000 --1 0.50 25 EO
2 0.125 25 EO
3 0.50 50 EO
4 0.125 50 EO
5 1.00 80 EO
6 0.50 80 EO
7 0.25 80 EO
8 0.125 80 EO
9 0.0625 80 EO
The delivery characteristics of the thus obtained powders were tested using a model system which simulates the delivery of a powder in an automatic washing machine.
For this test a cylindrical vessel having a diameter of 4 cm and a height of 7 cm, made of 600 micron pore size stainless steel mesh, and having a top closure made of teflon and a bottom closure made of the above type of mesh, was used. In this top closure, a 30 cm metal rod was inserted to act as a handle, and this handle was attached in an agitator arm positioned above 1 litre water present in a container and , having a temperature of 20 C. By means of this agitator apparatus the cylindrical vessel held at 45 degrees, could be rotated through a circle with a 10 cm radius during 2 seconds. Subsequently the vessel could be allowed to rest during 2 seconds before the next rotation-rest cycle started.
A 50 grams powder sample was introduced in the cylindrical vessel. This vessel was then closed and attached to the agitator arm which was subsequently moved down to a position wherein the top of the cylindrical vessel was just below the water surface. After a ten second delay, the rotation was started, and the apparatus then allowed to operate for 15 rotation-rest cycles.
Subsequently, the cylindrical vessel and handle were removed from the water and the vessel was detached. Surface water was carefully poured off, and any powder residues transferred to a preweighed container. The container was then dried at 100°C for 24 hours, and the weight of dried residue as a percentage of the initial powder weight calculated.
The results are shown in Table 3.
WO 94/16052 PCTlEP93/03624 Example Postdosed high EO nonionic Residue material amount (parts) type (wt~) A 0.000 -- 34 1 0,50 25 EO 22 2 0.125 25 EO 20 3 0.50 50 EO 24 0.125 50 EO 18 5 1.00 80 EO 25 6 0.5p 80 EO 22 7 0.25 80 EO 16 g 0.125 80 EO 14 g 0.0625 80 EO 21 I i ~
It can be seen from Table 3 that the largest reduction of the powder residue as compared to the residue found in example A, could be obtained when applying a detergent powder composition comprising a minor amount of postdosed ethoxylated alcohol containing 80 ethylene oxide groups.
~,'v'mrW oc ~ n '1 'I C'nmnarai-_iye EX3mT~le B
A particulate detergent composition was prepared in a very similar way and having almost the same formulation as in the above-mentioned Example A, the only difference being that in _ the present Examples the sprayed-on nonionic surfactant material fully consists of Synperionic A3 (containing 3 EO
groups) ex ICI.
~O 94/16052 PCT/EP93/03624 _ 17 _ To this detergent powder, varying amounts of ethoxylated alcohol containing 80 EO groups were postdosed.
The delivery characteristics of the thus obtained powders were tested using the above-described model system and a testing process. The results obtained are shown in Table 4.
Example Postdosed high EO nonionic Residue material amount (parts) type ~ (wt~) B 0.000 -- 68 10 0.50 80 EO 55 11 0.125 80 EO 42 It can be seen that the dissolution properties of the detergent powder of Example B are inferior as compared to the powder of Example A, and that also in this case an improvement of the delivery characteristics could be obtained by post-dosing minor quantities of ethoxylated alcohol containing 80 EO groups.
Comparative Examples C,D
To the detergent powder of Example A, varying -minor- amounts of polyethylene glycol having a molecular weight of 4000 (PEG
4000) were postdosed.
The delivery characteristics of the thus obtained powders were tested using the above-described model system and testing process. The results obtained are shown in Table S.
J
Example Postdosed PEG 4000 Residue amount (parts) (wt~) A 0.000 34 B 0.50 33 C 0.25 35 It can be seen that no improvement of the delivery characteristics of the detergent powder of Example A could be obtained by post-dosing the above-indicated minor amounts of PEG 4000.
example 12 and comparative Example E
A detergent composition having a bulk density of about 900 g/1 was prepared by a mixing/granulation process to produce a base powder to which further components were post-dosed into the base powder as listed below.
~O 94/16052 _ Base Powder Sodium primary alkyl sulphate (PAS) 5.81 J
zeolite MAP 36.04 Sodium carbonate 0.96 :Synperonic A3 ex ICI 7.15 ~Synperonic A7 ex ICI 5.81 Stearic acid 2.04 b'Tallow 80E0 0.20 Sodium carboxymethyl cellulose 0.89 Moisture 4.98 63.88 About 55~ branched.
b Ethoxylated tallow alcohol having an average degree of ethoxylation of 80.
The nonionic materials (*) were mixed and then sprayed onto an adjunct comprising PAS, carbonate and part of the zeolite, and sodium carboxymethyl cellulose and stearic acid in a Lodige CB30 "Recycler" mixer. The stearic acid was neutralised by addition of base. The mixture was then layered with the remaining zeolite and passed to a Lodige KM300 "Ploughshare" mixer and then a fluid bed as described in EP-A-367 339 (Unilever) to produce the base powder.
The following components were then admixed to the base powder (63.88 parts).
WO 94/16052 PCTlEP93/03624 Fluorescer 3.00 Sodium silicate 2.90 ' TAED 4.75 d Manganete catalyst 2.40 Sodium Percarbonate 20.50 DEQUEST 2047 ex Monsanto 0.37 Enzyme 1.75 Perfume 0.45 ' tetraacetyl ethylene diamine as described in EP 458 397 (Unilever) sequestrant A comparative composition E was prepared by the same process and to the same composition as Example 12 save that the Tallow 80E0 in the base was replaced by 0.20 parts SYNPERONIC
A3.
The delivery characterisatics of the two powders were tested using the model system described in Examples 1 to 9. The results are shown in Table 6.
Composition Residue (wt~) 12 45 .
These results demonstrate that compositions containing a dissolution aid have significantly superior delivery a characteristics when compared to a similar composition which does not contain a dissolution aid.
Deteraencv The detergencies of the powders of Examples A,D (comparative) and 7 (according to the invention) were compared by means of a washing machine test. The machine used was a Siemens Siwamat (Trade Mark) Plus 3700 front-loading automatic washer.
3 kg soiled loads containing white cotton interlock test cloth monitors (which monitors have been pre-washed) were washed at 40°C using the half load main wash programme. The powder samples (104 g dose) predissolved in 250 ml water were introduced via the machine's dispenser. Detergency results (reflectance loss after 10 washes at 460 nm of the test cloth monitors) were as follows:
Composition Reflectance loss of after 10 washes Example A 2.1 Example D 1.9 Example 7 1.4 These results demonstrate the additional benefit associated with the invention, of reduced redeposition.
Bleeding _ 22 _ The bleeding characteristics of the powders of Examples A,D
(comparative) and 7 (according to the invention) were compared. To that end, Standard VC2 cardboard packs (having a volume of 1.5 litre) were filled up to 80~ of their total volume with samples of the above mentioned respective powders. Subsequently the filled cardboard packs were stored at a temperature of 37°C and a relative humidity of 70~, for two months. The part of the total cardboard interior surface which was stained and had obtained a darker colour due to nonionic migration (bleeding) during this two months storage period, was recorded as a percentage, as is shown below:
Composition stained part of cardboard of pack interior surface (in ~) Example A 18 Example D 19 Example 7 8 It can be derived from these results that a further benefit associated with the invention, is significantly improved (i.e. reduced) bleeding behaviour of detergent compositions according to the invention.
The delivery characteristics of the thus obtained powders were tested using a model system which simulates the delivery of a powder in an automatic washing machine.
For this test a cylindrical vessel having a diameter of 4 cm and a height of 7 cm, made of 600 micron pore size stainless steel mesh, and having a top closure made of teflon and a bottom closure made of the above type of mesh, was used. In this top closure, a 30 cm metal rod was inserted to act as a handle, and this handle was attached in an agitator arm positioned above 1 litre water present in a container and , having a temperature of 20 C. By means of this agitator apparatus the cylindrical vessel held at 45 degrees, could be rotated through a circle with a 10 cm radius during 2 seconds. Subsequently the vessel could be allowed to rest during 2 seconds before the next rotation-rest cycle started.
A 50 grams powder sample was introduced in the cylindrical vessel. This vessel was then closed and attached to the agitator arm which was subsequently moved down to a position wherein the top of the cylindrical vessel was just below the water surface. After a ten second delay, the rotation was started, and the apparatus then allowed to operate for 15 rotation-rest cycles.
Subsequently, the cylindrical vessel and handle were removed from the water and the vessel was detached. Surface water was carefully poured off, and any powder residues transferred to a preweighed container. The container was then dried at 100°C for 24 hours, and the weight of dried residue as a percentage of the initial powder weight calculated.
The results are shown in Table 3.
WO 94/16052 PCTlEP93/03624 Example Postdosed high EO nonionic Residue material amount (parts) type (wt~) A 0.000 -- 34 1 0,50 25 EO 22 2 0.125 25 EO 20 3 0.50 50 EO 24 0.125 50 EO 18 5 1.00 80 EO 25 6 0.5p 80 EO 22 7 0.25 80 EO 16 g 0.125 80 EO 14 g 0.0625 80 EO 21 I i ~
It can be seen from Table 3 that the largest reduction of the powder residue as compared to the residue found in example A, could be obtained when applying a detergent powder composition comprising a minor amount of postdosed ethoxylated alcohol containing 80 ethylene oxide groups.
~,'v'mrW oc ~ n '1 'I C'nmnarai-_iye EX3mT~le B
A particulate detergent composition was prepared in a very similar way and having almost the same formulation as in the above-mentioned Example A, the only difference being that in _ the present Examples the sprayed-on nonionic surfactant material fully consists of Synperionic A3 (containing 3 EO
groups) ex ICI.
~O 94/16052 PCT/EP93/03624 _ 17 _ To this detergent powder, varying amounts of ethoxylated alcohol containing 80 EO groups were postdosed.
The delivery characteristics of the thus obtained powders were tested using the above-described model system and a testing process. The results obtained are shown in Table 4.
Example Postdosed high EO nonionic Residue material amount (parts) type ~ (wt~) B 0.000 -- 68 10 0.50 80 EO 55 11 0.125 80 EO 42 It can be seen that the dissolution properties of the detergent powder of Example B are inferior as compared to the powder of Example A, and that also in this case an improvement of the delivery characteristics could be obtained by post-dosing minor quantities of ethoxylated alcohol containing 80 EO groups.
Comparative Examples C,D
To the detergent powder of Example A, varying -minor- amounts of polyethylene glycol having a molecular weight of 4000 (PEG
4000) were postdosed.
The delivery characteristics of the thus obtained powders were tested using the above-described model system and testing process. The results obtained are shown in Table S.
J
Example Postdosed PEG 4000 Residue amount (parts) (wt~) A 0.000 34 B 0.50 33 C 0.25 35 It can be seen that no improvement of the delivery characteristics of the detergent powder of Example A could be obtained by post-dosing the above-indicated minor amounts of PEG 4000.
example 12 and comparative Example E
A detergent composition having a bulk density of about 900 g/1 was prepared by a mixing/granulation process to produce a base powder to which further components were post-dosed into the base powder as listed below.
~O 94/16052 _ Base Powder Sodium primary alkyl sulphate (PAS) 5.81 J
zeolite MAP 36.04 Sodium carbonate 0.96 :Synperonic A3 ex ICI 7.15 ~Synperonic A7 ex ICI 5.81 Stearic acid 2.04 b'Tallow 80E0 0.20 Sodium carboxymethyl cellulose 0.89 Moisture 4.98 63.88 About 55~ branched.
b Ethoxylated tallow alcohol having an average degree of ethoxylation of 80.
The nonionic materials (*) were mixed and then sprayed onto an adjunct comprising PAS, carbonate and part of the zeolite, and sodium carboxymethyl cellulose and stearic acid in a Lodige CB30 "Recycler" mixer. The stearic acid was neutralised by addition of base. The mixture was then layered with the remaining zeolite and passed to a Lodige KM300 "Ploughshare" mixer and then a fluid bed as described in EP-A-367 339 (Unilever) to produce the base powder.
The following components were then admixed to the base powder (63.88 parts).
WO 94/16052 PCTlEP93/03624 Fluorescer 3.00 Sodium silicate 2.90 ' TAED 4.75 d Manganete catalyst 2.40 Sodium Percarbonate 20.50 DEQUEST 2047 ex Monsanto 0.37 Enzyme 1.75 Perfume 0.45 ' tetraacetyl ethylene diamine as described in EP 458 397 (Unilever) sequestrant A comparative composition E was prepared by the same process and to the same composition as Example 12 save that the Tallow 80E0 in the base was replaced by 0.20 parts SYNPERONIC
A3.
The delivery characterisatics of the two powders were tested using the model system described in Examples 1 to 9. The results are shown in Table 6.
Composition Residue (wt~) 12 45 .
These results demonstrate that compositions containing a dissolution aid have significantly superior delivery a characteristics when compared to a similar composition which does not contain a dissolution aid.
Deteraencv The detergencies of the powders of Examples A,D (comparative) and 7 (according to the invention) were compared by means of a washing machine test. The machine used was a Siemens Siwamat (Trade Mark) Plus 3700 front-loading automatic washer.
3 kg soiled loads containing white cotton interlock test cloth monitors (which monitors have been pre-washed) were washed at 40°C using the half load main wash programme. The powder samples (104 g dose) predissolved in 250 ml water were introduced via the machine's dispenser. Detergency results (reflectance loss after 10 washes at 460 nm of the test cloth monitors) were as follows:
Composition Reflectance loss of after 10 washes Example A 2.1 Example D 1.9 Example 7 1.4 These results demonstrate the additional benefit associated with the invention, of reduced redeposition.
Bleeding _ 22 _ The bleeding characteristics of the powders of Examples A,D
(comparative) and 7 (according to the invention) were compared. To that end, Standard VC2 cardboard packs (having a volume of 1.5 litre) were filled up to 80~ of their total volume with samples of the above mentioned respective powders. Subsequently the filled cardboard packs were stored at a temperature of 37°C and a relative humidity of 70~, for two months. The part of the total cardboard interior surface which was stained and had obtained a darker colour due to nonionic migration (bleeding) during this two months storage period, was recorded as a percentage, as is shown below:
Composition stained part of cardboard of pack interior surface (in ~) Example A 18 Example D 19 Example 7 8 It can be derived from these results that a further benefit associated with the invention, is significantly improved (i.e. reduced) bleeding behaviour of detergent compositions according to the invention.
Claims (9)
1. A particulate detergent composition having a bulk density of at least 600g/l and comprising a surfactant system including one or more anionic and/or nonionic surfactants, at least one detergency builder and a dissolution aid wherein the dissolution aid is present in an amount from 0.05 to 1% by weight as calculated on the composition and comprises a nonionic material which is alkoxylated aliphatic alcohol containing at feast 25 alkylene oxide groups.
2. A composition according to claim 1 in which at least 50% of the alkylene oxide groups in the nonionic material are ethylene oxide groups.
3. A detergent composition according to any preceding claim, wherein the alkoxylated aliphatic alcohol contains at least 50 ethylene oxide groups.
4. A detergent composition according to any preceding claim, wherein the surfactant system comprises two nonionic surfactants which are condensation products of ethylene oxide with a C8-C15 aliphatic alcohol having respectively an average degree of ethoxylation of 2 to 5 and of 6.5 to 10.
5. A detergent composition according to any preceding claim, wherein the surfactant system consists essentially of (i) from 40 to 100%
by weight of the surfactant system of ethoxylated nonionic surfactant, and (ii) from 0 to 60% by weight of linear alkylbenzene sulphonate of primary C8-C18 alcohol sulphate.
by weight of the surfactant system of ethoxylated nonionic surfactant, and (ii) from 0 to 60% by weight of linear alkylbenzene sulphonate of primary C8-C18 alcohol sulphate.
6. A detergent composition according to any preceding claim in the surfactant system is present in an amount from 10 to 50% by weight of the composition.
7. A detergent composition according to any preceding claim, which is essentially free of phosphates.
8. A process for the production of particulate detergent composition having a bulk density of at least 600g/l comprising a surfactant system, at least one detergency builder and a dissolution aid wherein the dissolution aid is present in an amount of from 0.01 to 2% by weight as calculated on the composition and comprises a nonionic material which is an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, which process comprises mixing the dissolution aid with the surfactant system and builder sequentially or simultaneously.
9. Use of an alkoxylated aliphatic alcohol containing at least 25 alkylene oxide groups, as a dissolution aid in a particulate detergent composition having a bulk density of at least 600g/l.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9300311.9 | 1993-01-08 | ||
| GB939300311A GB9300311D0 (en) | 1993-01-08 | 1993-01-08 | Detergent powders and process for preparing them |
| PCT/EP1993/003624 WO1994016052A1 (en) | 1993-01-08 | 1993-12-17 | Detergent composition and process for producing it |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2153312A1 CA2153312A1 (en) | 1994-07-21 |
| CA2153312C true CA2153312C (en) | 2003-09-16 |
Family
ID=10728467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002153312A Expired - Fee Related CA2153312C (en) | 1993-01-08 | 1993-12-17 | Detergent composition and process for producing it |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0678119B2 (en) |
| JP (1) | JPH08505177A (en) |
| AU (1) | AU5814294A (en) |
| BR (1) | BR9307809A (en) |
| CA (1) | CA2153312C (en) |
| DE (1) | DE69314056T3 (en) |
| ES (1) | ES2107805T5 (en) |
| GB (1) | GB9300311D0 (en) |
| WO (1) | WO1994016052A1 (en) |
| ZA (1) | ZA939731B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19526483A1 (en) * | 1995-07-20 | 1997-01-23 | Henkel Kgaa | Surfactant blends with improved solubility of anionic surfactants based on long-chain alkyl sulfate salts even at low liquor temperatures |
| WO2000077158A1 (en) * | 1999-06-14 | 2000-12-21 | Kao Corporation | Granular base and particulate detergent |
| WO2000077159A1 (en) * | 1999-06-16 | 2000-12-21 | Kao Corporation | Particles for detergent addition |
| EP1186650A4 (en) | 1999-06-16 | 2004-07-21 | Kao Corp | Article for use in washing in sheet form |
| GB0030671D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Detergent compositions |
| GB0030669D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Detergent compositions |
| GB0124308D0 (en) * | 2001-10-10 | 2001-11-28 | Unilever Plc | Detergent compositions |
| GB0124307D0 (en) * | 2001-10-10 | 2001-11-28 | Unilever Plc | Detergent compositions |
| CA2503144C (en) | 2002-11-04 | 2012-02-21 | Unilever Plc | Laundry detergent composition |
| EP1690922A1 (en) * | 2005-02-11 | 2006-08-16 | The Procter & Gamble Company | A solid laundry detergent composition |
| CA2653880C (en) | 2006-05-31 | 2014-08-05 | Basf Se | Amphiphilic graft polymers based on polyalkylene oxides and vinyl esters |
| RU2014133350A (en) | 2012-03-09 | 2016-03-10 | Дзе Проктер Энд Гэмбл Компани | Detergent formulations containing grafted copolymers with a wide range of polar distribution |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH14838A (en) † | 1974-03-21 | 1981-12-16 | Procter & Gamble | Detergent composition |
| US4137197A (en) * | 1977-11-10 | 1979-01-30 | Lever Brothers Company | Powdered detergent compositions containing a calcium salt of an anionic surfactant |
| EP0026013B1 (en) † | 1979-09-21 | 1983-09-07 | THE PROCTER & GAMBLE COMPANY | Washing and softening compositions and methods for their manufacture |
| GB8323131D0 (en) † | 1983-08-27 | 1983-09-28 | Procter & Gamble Ltd | Detergent compositions |
| GB8712285D0 (en) † | 1987-05-23 | 1987-07-01 | Procter & Gamble | Laundry products |
| DK0495345T3 (en) † | 1991-01-16 | 1995-04-24 | Procter & Gamble | Foam-reducing agents in granular form |
| GB9108639D0 (en) † | 1991-04-23 | 1991-06-12 | Procter & Gamble | Particulate detergent compositions |
| DE4124701A1 (en) * | 1991-07-25 | 1993-01-28 | Henkel Kgaa | METHOD FOR THE PRODUCTION OF SOLID DETERGENT AND CLEANING AGENT WITH HIGH SHOCK WEIGHT AND IMPROVED SOLUTION SPEED |
| DE69231555T2 (en) * | 1992-03-17 | 2001-06-07 | Procter & Gamble | Dilutable compositions and methods for cleaning hard surfaces |
| DE69225702T2 (en) * | 1992-07-15 | 1999-01-21 | Procter & Gamble | Process for the production of compact cleaning agents |
-
1993
- 1993-01-08 GB GB939300311A patent/GB9300311D0/en active Pending
- 1993-12-17 CA CA002153312A patent/CA2153312C/en not_active Expired - Fee Related
- 1993-12-17 AU AU58142/94A patent/AU5814294A/en not_active Abandoned
- 1993-12-17 WO PCT/EP1993/003624 patent/WO1994016052A1/en active IP Right Grant
- 1993-12-17 EP EP94903842A patent/EP0678119B2/en not_active Expired - Lifetime
- 1993-12-17 ES ES94903842T patent/ES2107805T5/en not_active Expired - Lifetime
- 1993-12-17 JP JP6515635A patent/JPH08505177A/en active Pending
- 1993-12-17 DE DE69314056T patent/DE69314056T3/en not_active Expired - Lifetime
- 1993-12-17 BR BR9307809A patent/BR9307809A/en not_active IP Right Cessation
- 1993-12-28 ZA ZA939731A patent/ZA939731B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA939731B (en) | 1995-06-28 |
| DE69314056T3 (en) | 2006-02-02 |
| JPH08505177A (en) | 1996-06-04 |
| BR9307809A (en) | 1995-11-14 |
| AU5814294A (en) | 1994-08-15 |
| GB9300311D0 (en) | 1993-03-03 |
| DE69314056T2 (en) | 1998-01-22 |
| WO1994016052A1 (en) | 1994-07-21 |
| EP0678119B1 (en) | 1997-09-17 |
| EP0678119B2 (en) | 2005-05-25 |
| EP0678119A1 (en) | 1995-10-25 |
| DE69314056D1 (en) | 1997-10-23 |
| CA2153312A1 (en) | 1994-07-21 |
| ES2107805T5 (en) | 2005-12-01 |
| ES2107805T3 (en) | 1997-12-01 |
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