CA2145054A1 - A process for the extraction and separation of nickel and/or cobalt - Google Patents

A process for the extraction and separation of nickel and/or cobalt

Info

Publication number
CA2145054A1
CA2145054A1 CA2145054A CA2145054A CA2145054A1 CA 2145054 A1 CA2145054 A1 CA 2145054A1 CA 2145054 A CA2145054 A CA 2145054A CA 2145054 A CA2145054 A CA 2145054A CA 2145054 A1 CA2145054 A1 CA 2145054A1
Authority
CA
Canada
Prior art keywords
metal
feed solution
aqueous feed
organic phase
ions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2145054A
Other languages
French (fr)
Other versions
CA2145054C (en
Inventor
Indje Ognianov Mihaylov
Eberhard Krause
Steven William Laundry
Cuong Van Luong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goro Nickel SA
Original Assignee
Goro Nickel SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/216,258 external-priority patent/US5378262A/en
Application filed by Goro Nickel SA filed Critical Goro Nickel SA
Publication of CA2145054A1 publication Critical patent/CA2145054A1/en
Application granted granted Critical
Publication of CA2145054C publication Critical patent/CA2145054C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/381—Phosphines, e.g. compounds with the formula PRnH3-n, with n = 0-3
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/385—Thiophosphoric acids, or esters thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Abstract

The invention provides a hydrometallurgical process for the recovery of metals. In particular, an aqueous feed solution originating from acid leaching is provided. The aqueous feed solution contains nickel and/or cobalt ions. The pH of the solution is maintained at a level between about 2 and 6. The aqueous feed solution is contacted with a water-immiscible organic phase containing an extractant to load the nickel and/or cobalt metal ions to form a metal-bearing organic phase.
The extractant has at least one organic soluble dithiophosphinic acid, alkali, alkaline earth metal or ammonium salt thereof. The aqueous feed solution has sufficientlylow levels of chromium (VI) ions, iron (III) ions and copper ions to allow repeated use of the extractant. The metal-bearing organic phase is then separated from the metal-containing aqueous feed solution. Finally, after separation from the aqueous feed solution, the metal-bearing organic phase is contacted with an aqueous strip solution to recover the loaded nickel and/or cobalt from the metal-bearing organic phase.
CA002145054A 1994-03-22 1995-03-20 A process for the extraction and separation of nickel and/or cobalt Expired - Lifetime CA2145054C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/216,258 US5378262A (en) 1994-03-22 1994-03-22 Process for the extraction and separation of nickel and/or cobalt
US08/216,258 1994-03-22
US08/337,283 US5447552A (en) 1994-03-22 1994-11-10 Process for the extraction and separation of nickel and/or cobalt
US08/337,283 1994-11-10

Publications (2)

Publication Number Publication Date
CA2145054A1 true CA2145054A1 (en) 1995-09-23
CA2145054C CA2145054C (en) 1999-03-09

Family

ID=26910839

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002145054A Expired - Lifetime CA2145054C (en) 1994-03-22 1995-03-20 A process for the extraction and separation of nickel and/or cobalt

Country Status (8)

Country Link
JP (1) JP2760956B2 (en)
CN (1) CN1046966C (en)
AU (1) AU687981B2 (en)
BR (1) BR9501135A (en)
CA (1) CA2145054C (en)
FR (1) FR2717826B1 (en)
OA (1) OA10135A (en)
PH (1) PH31603A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7128840B2 (en) 2002-03-26 2006-10-31 Idaho Research Foundation, Inc. Ultrasound enhanced process for extracting metal species in supercritical fluids
CN114252653A (en) * 2021-01-06 2022-03-29 中国科学院物理研究所 Ultrafast imaging device and method thereof
CN115058597A (en) * 2022-06-30 2022-09-16 盛隆资源再生（无锡）有限公司 Method for recycling electroplating sludge containing calcium, iron, cobalt and nickel

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1101475C (en) * 1996-01-16 2003-02-12 中国科学院化工冶金研究所 Method for recovering cobalt
US5759512A (en) * 1996-06-04 1998-06-02 Cytec Technology Corp. Regeneration of dithiophosphorus acid metal extractants
CN101343287B (en) * 2008-08-29 2011-05-11 清华大学 Synthesis of sicycle-ring hexyl di-thiophosphinic acid
CN101824550B (en) * 2009-03-02 2012-05-23 姚龚斌 Extracting and purifying technology of high purity nickel
JP5154622B2 (en) * 2010-03-02 2013-02-27 Ｊｘ日鉱日石金属株式会社 Method for recovering cobalt contained in copper-containing aqueous solution
CN102001764B (en) * 2010-10-18 2012-07-04 荆门市格林美新材料有限公司 Method for removing chromium impurities from nickel leach liquor
JP5757425B2 (en) * 2011-11-25 2015-07-29 住友金属鉱山株式会社 Method for producing high-purity nickel sulfate and method for removing impurity element from solution containing nickel
CN104131285B (en) * 2013-05-03 2016-08-31 宁波东盛集成电路元件有限公司 The recovery method of ferric trichloride etching waste liquor
CN103334017A (en) * 2013-07-01 2013-10-02 贵研铂业股份有限公司 Method for preparing high-purity nickel powder from waste high-temperature alloy
JP6176491B2 (en) * 2014-03-26 2017-08-09 住友金属鉱山株式会社 Method for removing copper from aqueous nickel chloride solution
CN104263928B (en) * 2014-09-05 2016-06-08 昆明理工大学 A kind of method of solvent extraction and separation nickel cobalt under super gravity field
CN106148714A (en) * 2015-03-31 2016-11-23 三明学院 A kind of Solid-Phase Extraction reclaims the method for cobalt in zinc hydrometallurgy mine tailings
US10208389B2 (en) * 2015-08-26 2019-02-19 Basf Se Methods and systems for reducing impurity metal from a refinery electrolyte solution
CN106319228B (en) * 2016-08-26 2018-06-19 荆门市格林美新材料有限公司 A kind of method of synchronous recycling nickel cobalt manganese in manganese waste slag from nickel and cobalt containing
CN108517406B (en) * 2018-04-19 2020-01-03 中国人民解放军国防科技大学 Solid phase extracting agent for selectively separating trivalent minor actinide and trivalent lanthanide, and preparation method and application thereof
CN109913668A (en) * 2019-03-20 2019-06-21 金川集团股份有限公司 A method of from containing the organic middle recycling nickel of nickel load
CN112746168A (en) * 2019-10-30 2021-05-04 平顶山德源精细化学品有限公司 Process method for treating laterite-nickel ore leaching solution by using combined extracting agent
BR112022021798A2 (en) * 2020-06-16 2022-12-27 Yara Int Asa PROCESS FOR THE REMOVAL OF HEAVY METALS FROM A COMPOSITION CONTAINING PHOSPHORIC ACID USING A POLYMERIC IONIC SURFACTANT AND THE USE OF SAID SURFACTANT IN THE PRECIPITATION OF HEAVY METALS IN A COMPOSITION CONTAINING PHOSPHORIC ACID
CA3180313A1 (en) * 2020-06-16 2021-12-23 Yara International Asa Process for the removal of heavy metals from a phosphoric acid containing composition using a flocculating agent
CN115427163A (en) * 2020-06-16 2022-12-02 雅苒国际集团 Process for removing heavy metals from phosphoric acid containing compositions
CN112342390A (en) * 2020-10-26 2021-02-09 宁波互邦新材料有限公司 Extraction separation technology of ternary leaching solution and ternary positive electrode material recovery process based on extraction separation technology
CN114317961B (en) * 2021-12-30 2023-06-02 重庆康普化学工业股份有限公司 Co-extraction system for nickel-cobalt co-extraction and co-extraction method thereof
WO2023140198A1 (en) * 2022-01-20 2023-07-27 Ｄｏｗａエコシステム株式会社 Method for recovering valuable substance

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0078051B1 (en) * 1981-10-28 1986-09-17 Hoechst Aktiengesellschaft Process for separating heavy metal values from intermediate products in the manufacture of phosphatic fertilizers
US4721605A (en) * 1985-07-24 1988-01-26 American Cyanamid Company Selective removal of metals from aqueous solutions with dithiophosphinic acids
AT391464B (en) * 1987-07-13 1990-10-10 M & T Nickl Ges M B H METHOD FOR SEPARATING NICKELIONS FROM AQUEOUS SOLUTIONS
IL85751A (en) * 1988-03-16 1991-12-15 Negev Phosphates Ltd Method for the removal of heavy metal ions from phosphoric acid
AT395409B (en) * 1988-07-11 1992-12-28 Rolf Dipl Ing Dr Techn Marr METHOD FOR SEPARATING NICKEL FROM AQUEOUS SOLUTIONS
US5028403A (en) * 1989-05-31 1991-07-02 American Cyanamid Company Metal recovery with monothiophosphinic acids
DE69327486D1 (en) * 1992-06-05 2000-02-10 Avecia Ltd Process for extracting metals
TW218895B (en) * 1993-09-03 1994-01-11 Ind Tech Res Inst An extraction agent composition suitable for separating aluminum,cobalt, and nickle ions in sulfuric aqueous solution and its separation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7128840B2 (en) 2002-03-26 2006-10-31 Idaho Research Foundation, Inc. Ultrasound enhanced process for extracting metal species in supercritical fluids
CN114252653A (en) * 2021-01-06 2022-03-29 中国科学院物理研究所 Ultrafast imaging device and method thereof
CN114252653B (en) * 2021-01-06 2023-12-12 中国科学院物理研究所 Ultrafast imaging device and method thereof
CN115058597A (en) * 2022-06-30 2022-09-16 盛隆资源再生（无锡）有限公司 Method for recycling electroplating sludge containing calcium, iron, cobalt and nickel

Also Published As

Publication number Publication date
BR9501135A (en) 1995-10-24
CN1109913A (en) 1995-10-11
JP2760956B2 (en) 1998-06-04
JPH0835023A (en) 1996-02-06
AU1496695A (en) 1995-09-28
FR2717826B1 (en) 1997-03-14
OA10135A (en) 1996-12-18
AU687981B2 (en) 1998-03-05
CA2145054C (en) 1999-03-09
PH31603A (en) 1998-11-03
FR2717826A1 (en) 1995-09-29
CN1046966C (en) 1999-12-01

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