CA2142637A1 - Investment casting method and apparatus - Google Patents
Investment casting method and apparatusInfo
- Publication number
- CA2142637A1 CA2142637A1 CA 2142637 CA2142637A CA2142637A1 CA 2142637 A1 CA2142637 A1 CA 2142637A1 CA 2142637 CA2142637 CA 2142637 CA 2142637 A CA2142637 A CA 2142637A CA 2142637 A1 CA2142637 A1 CA 2142637A1
- Authority
- CA
- Canada
- Prior art keywords
- riser tube
- shell
- refractory
- solid
- cluster
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 60
- 238000005495 investment casting Methods 0.000 title claims abstract description 24
- 238000005266 casting Methods 0.000 claims abstract description 57
- 239000007787 solid Substances 0.000 claims abstract description 49
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000000919 ceramic Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000010304 firing Methods 0.000 claims description 6
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 4
- 239000012768 molten material Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 210000000988 bone and bone Anatomy 0.000 claims 4
- 244000044283 Toxicodendron succedaneum Species 0.000 abstract description 22
- 238000007711 solidification Methods 0.000 abstract description 3
- 230000008023 solidification Effects 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 210000003127 knee Anatomy 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000007943 implant Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000000399 orthopedic effect Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000005058 metal casting Methods 0.000 description 2
- GWUSZQUVEVMBPI-UHFFFAOYSA-N nimetazepam Chemical compound N=1CC(=O)N(C)C2=CC=C([N+]([O-])=O)C=C2C=1C1=CC=CC=C1 GWUSZQUVEVMBPI-UHFFFAOYSA-N 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- -1 acrylate ester Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 210000000629 knee joint Anatomy 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/02—Sand moulds or like moulds for shaped castings
- B22C9/04—Use of lost patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C7/00—Patterns; Manufacture thereof so far as not provided for in other classes
- B22C7/02—Lost patterns
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Abstract
A modified investment casting process is effective to more safely and efficiently produce cast articles. The casting process utilizes a solid, rigid riser tube, in place of a wax tree, upon which heat disposable, positive models of an article to be cast are joined. This assembly is coated with a refractory and after drying of the refractory the heat disposable positive models are removed. Thereafter the ceramic shell is heated and fired and molten casting material is poured into the assembly. The molten casting material flows from the riser tube to fill the cavities formerly occupied by the positive models. Upon cooling and solidification of the casting material, the refractory is fractured and cast parts are removed.
Description
INVESTMENl CASTING METHOD AND APPARATUS
Back~round of the Inventior~
This invention relates to a metal casting process and to apparatuses utili7.ed in such a process. More particularly, the invention relates to investment casting processes.
Various metal casting processes are well known. Investment casting (or lost wax casting) is commonly used to fabricate metal parts. This process requires several steps, the first of which is to fabricate a pattern that is used to form a master mold. The master mold is then used to form solid wax p~ttern.~ that resemble the part to be manufactured. Typically, several wax patterns are joined together in a wax tree to enable the simultaneous m~nl~f~ctllre of several parts. The wax tree is a solid wax tube that has side walls upon which a stem of the solid patterns are joined. Once all solid patterns are joined to the wax tree, the entire assembly is coated with one or more coats of a refractory. After drying, the assembly is heated and fired and the solid wax patterns and the wax tree are removed, yielding a shel!. Molten metal is then poured into the shell so that it fills each of the cavities formerly occupied by the wax patterns and the wax tree. Upon drying, the refractory is fractured and removed and the metal parts are severed from the metal tree.
Investment casting is advantageous because it facilitates the manufacture of metal parts having complex shapes and accurate dimensions. This type of casting process is particularly useful in manufacturing orthopedic implants.
One of the drawbacks of the investment casting process, as it is currently practiced, is the use of the wax tree which has inherently low structural strength. As a result, the wax tree alone can not adequately support the solid patterns, and several relatively thick coats of refractory are normally required to provide additionalstructural support. In addition, the application of a greater number of refractory coats requires longer drying periods between coating applications. This in turn leads to significant time increases in the overall casting process.
Back~round of the Inventior~
This invention relates to a metal casting process and to apparatuses utili7.ed in such a process. More particularly, the invention relates to investment casting processes.
Various metal casting processes are well known. Investment casting (or lost wax casting) is commonly used to fabricate metal parts. This process requires several steps, the first of which is to fabricate a pattern that is used to form a master mold. The master mold is then used to form solid wax p~ttern.~ that resemble the part to be manufactured. Typically, several wax patterns are joined together in a wax tree to enable the simultaneous m~nl~f~ctllre of several parts. The wax tree is a solid wax tube that has side walls upon which a stem of the solid patterns are joined. Once all solid patterns are joined to the wax tree, the entire assembly is coated with one or more coats of a refractory. After drying, the assembly is heated and fired and the solid wax patterns and the wax tree are removed, yielding a shel!. Molten metal is then poured into the shell so that it fills each of the cavities formerly occupied by the wax patterns and the wax tree. Upon drying, the refractory is fractured and removed and the metal parts are severed from the metal tree.
Investment casting is advantageous because it facilitates the manufacture of metal parts having complex shapes and accurate dimensions. This type of casting process is particularly useful in manufacturing orthopedic implants.
One of the drawbacks of the investment casting process, as it is currently practiced, is the use of the wax tree which has inherently low structural strength. As a result, the wax tree alone can not adequately support the solid patterns, and several relatively thick coats of refractory are normally required to provide additionalstructural support. In addition, the application of a greater number of refractory coats requires longer drying periods between coating applications. This in turn leads to significant time increases in the overall casting process.
.
- Further, a wax tree having a relatively large diameter is often required to provide sufficient structural strength to support the solid patterns. Relatively large volumes of molten metal are thus used in each c~stin~ run to fill the molds and the space formerly occupied by the large diameter wax tree. This substantially increases the cost of the casting process, particularly when articles are to be cast usingexpensive metals or metal alloys.
The use of the wax tree also leads to additional processing delays and safety risks in post-casting procedures. The low structural strength of the wax tree necessitates the use of relatively large gates connecting the wax patterns to the wax tree. Following casting, the metal within the gates solidifies and it is generally of such diameter that the cast part cannot be easily separated from the stem. Rather, the part must be cut from the stem using a specialized cutting process. This cutting stepobviously requires a significant amount of post-processing time and poses a safety risk to the individuals using the cutting equipment.
There is thus a need for an improved investment casting process that can combine the traditional advantages of investment casting while elimin~ting some of its disadvantages. Such an improved process would be particularly applicable to the casting of expensive metals and metal alloys such as those used to manufacture orthopedic implants.
Accordingly, an object of the invention is to provide an improved investment casting process that is more cost effective and that requires less time for the production of metal components. It is also an object of the invention to facilitate the production of metal parts in a more cost effective manner. A further object of the invention is to provide an investment casting process that is well suited to themanufacture of orthopedic implants. It is another object of the invention to provide apparatuses that can improve the efficiency and effectiveness of investment casting processes. These and other objects will be ap~arent from the description that follows.
Summary of the Invention The present invention relates to an improved investment casting process that enables the production of cast parts with more economical use of metal and with fewer post-casting procedures.
.
21~2637 - In one embodiment the invention comprises an investment casting process that elimin~tes the need to use the traditional wax tree. The casting process of the present invention utilizes a hollow, structurally sound riser tube having one or more orifices extending through the wall of the riser tube. The riser tube is typically made from a ceramic material that is able to withstand the temperatures encountered during casting processes.
According to the process of the invention, one or more heat disposable solid patterns of an article to be cast are mounted to the riser tube. The solid patterns are mounted by adhering at least one gate on each solid pattern to a matching orifice on the riser tube to yield a cluster. A refractory is then applied to the cluster in one or more coats to form an investment assembly. The refractory can be applied by a variety of known techniques, including dipping and spraying.
Once the investment assembly is formed, the solid patterns are removed by heating the investment assembly to a temperature sufficient to melt or otherwise destroy of the solid, heat disposable material that forms the solid patterns. In some embodiments, the molten heat disposable material is allowed to flow out of the investment assembly. In other instances the heat disposable material is destroyed by flash firing. After melting or destroying the heat disposable material there remains a shell having one or more cavities that represent negatives of the part to be cast. The shell is then filled with a molten casting material, such as a metal or metal alloy, that is poured through the riser tube. The molten casting material fills the cavities in the shell and, after cooling, forms the desired cast articles.
The present invention also provides a novel investment assembly useful in practicing the method of the invention. The investment assembly comprises a hollow, structurally sound, elongate riser tube, heat disposable patterns mounted by their gates to orifices in the side wall of the riser tube, and a refractory that fully coats the riser tube and the adhered patterns. The riser tube preferably is made of ceramic, and can be of any suitable cross sectional shape. In one preferred embodiment the riser tube has a circular cross section.
Rrief Description of Drawin~
For a fuller understanding ofthe nature and objects ofthe invention, reference should be made to the following detailed description and the accompanying drawings, in which:
!
- . 21426~7 -FIGURES lA - lJ show successive stages in the casting process in accordance with features of the invention;
FIGURE 2 is a perspective view illustrating the formation of a cluster by attaching heat disposable patterns to a riser tube; and FIGURE 3 is a perspective view, partly cut away, of an investment assembly.
Detailed Description of the Invention Referring to Figures 1 through 3, wherein like reference numerals refer to like parts, there is illustrated an investment assembly and successive stages in the casting process in accordance with the features of the invention.
Figures lA through lJ illustrate sequential steps of a process according to the invention for casting desired articles 62.
Figure lA shows a hollow riser tube 10 having one or more orifices 12.
At least one heat disposable solid pattern 14 is mounted to the riser tube 10 byattaching at least one gate 16 of the pattern to a corresponding orifice on the riser tube.
The attachment of patterns to the riser tube forms a cluster assembly 18. Each gate 16 can be secured to the riser tube by inserting it into the orifice 12 where it is held in place by friction between the orifice and stem. More preferably, however, the gate is secured to the orifice by heating the stem until it reaches a molten state and then allowing the gate to solidify and bond to the orifice. It is understood that each pattern may have more than one gate that is used to join the pattern to the riser tube.
Preferably, riser tube 10 has one closed end 22. In one embodiment, shown in Figure lB, a plug 20 can be used to close end 22 of the riser tube.
The refractory can be applied to the cluster assembly 18 by a number of known techniques. Figures lC and lD i11ustrate alternative methods of applying arefractory binder material to the cluster assembly 18. In both methods, the refractory preferably is applied in layers that fully coat the cluster assembly 18, with drying cycles provided between each application of refractory. As understood by those having ordinary skill in the art, primary layers are typically applied before the 21~2637 application of one or more backup layers of refractory. Primary coats of refractory tend to be finer as they must accurately adhere to the contours of the solid patterns 14.
Backup coats of refractory tend to be more coarse as they are primarily intended to impart structural strength. The application of refractory to the cluster assembly 18 forms an investment assembly 30.
In the binder application process illustrated in Figure l C, a dipping apparatus 32 holds cluster 18 over vessel 34 that contains a refractory 36 used in forming primary layers of refractory. The dipping apparatus lowers cluster assembly 18 into vessel 34 until the entire cluster assembly is submerged and fully coated with refractory 36. The apparatus 34 lifts the cluster from the vessel after the coating process is complete and the applied refractory is allowed to dry and form a primary layer 38. These steps are repeated until a desired number of primary layers of adesired thickness form on the cluster assembly. A similar apparatus and process can be used to apply backup refractory layers to the cluster.
Figure lD illustrates an alternative method by which a refractory can be sprayed upon cluster assembly 18 to fully coat the cluster assembly. After spraying, the refractory is allowed to dry and form primary refractory layer 38. Spray applications can be repeated until the desired number of layers and/or the desired thickness of refractory primary coat forms on the cluster assembly. The cluster assembly can then be sprayed with a refractory backup coat and allowed to dry toform backup layer 40. These steps can be repeated until the backup layers are present at a desired number of layers and/or at a desired thickness.
Figure lE illustrates an investment assembly 30 in which a dry refractory 38, 40 fully coats the riser tube 10 and joined patterns 14.
After forming the investment assembly 30, the heat disposable matter 42, which forms patterns 14, can be extracted by a number of known techniques.
Figure lF illustrates the extraction of heat disposable matter 42 by placing theinvestment assembly 30 in a heated, pressurizable chamber or oven 44. According to known techniques, heat and/or pressure are applied to such a degree that the heat disposable matter 42 forming the solid patterns 14 and the stems 16 melts and flows out of the invest~ent assembly 30. One preferred embodiment utilizes a steam autoclave, at a temperature in a range of about 31 5F to 340F and at a ples~uie of about 100 to 150 psi, to extract the heat disposable matter. In some embodimentssolid patterns are made from higher melting polymeric materials that are destroyed by flash finng at temperatures sufficient to rapidly vaporize the solid pattern. In one embodiment, flash firing is conducted at temperatures of about 1900F.
Removal or destruction of the heat disposable matter from investment assembly 30 yields a shell 46 having cavities 48 formerly occupied by the heat disposable patterns. The cavities 48 form the negative image of the desired articles to be manufactured.
Shell 46 can be heated and fired, as illustrated in Figure lG, to impart increased strength to the shell and to remove any residual heat disposable matter. The shell 46 preferably is fired at a temperature typically in the range of about 1,400F to 2,000F for approximately one-half hour or more. The shell 46 is then ready to accept molten casting material 50, which is poured into shell 46, as illustrated in Figure lH, to form solid, cast articles. Preferably, molten casting material 50, such as a metal or metal alloy, is poured from a container 52 into the shell through opening 22 in riser tube 10. The metal fills the riser tube 10 and passes through orifices 12 and gates 16 to fill cavities 48. Once the cavities are filled, the molten metal is allowed to cool and solidify. Thereafter, the refractory shell 46 is fractured and removed, as illustrated in Figure lI, leaving behind riser tube 10 with gates 60 extending from orifices 12 and the desired solid, cast articles 62 attached to the end of the gates opposite the orifices.
As illustrated in Figure lJ, the cast articles 62 can be removed from the gates 60 simply by manually fracturing the stems.
Figure 2 illustrates an exemplary riser tube 10, elongated along a vertical axis 11, that is useful with the casting process of the invention. The riser tube 10 is hollow and has an outer wall 13 that defines an interior space 15. One end of the riser tube, preferably top end 23, remains open to allow communication of molten metal to the riser tube's interior space 15. The other end 22 remains closed. The riser tube 10 contains one or more orifices 12 that extend through the wall 13 to which heat disposable solid patterns 14 are secured. Riser tube 10 can have a variety of suitable cross sectional shapes, including circular, ovoid, triangular, and square.
- Figure 3 illustrates an investment assembly 30 having a ceramic riser tube -10, heat disposable p~ttern~ 14 joined to orifices 12 by gates 16, and refractory binder material 38, 40.
~7~ 2142637 The riser tube is manufactured from virtually any inert, solid, rigid material that is able to withstand contact with molten metal and temperatures in excess of about 3200F. Suitable materials include high purity alumina, magnesium oxide, ceramic refractory, and silica.
The dimensions of riser tube 10 depend upon the identify of articles to be cast and the number of articles to be formed in a single casting operation. The inner diameter or dimensions of riser tube 10 need only be large enough to accommodate the flow of molten material during a casting process. These dimensions can be as small as 0.0625 inch or less. Generally, the range of the inner dimensions (e.g., diameter) of riser tube 10 is approximately 0.0625 inch to 2 inches. Riser tubes with smaller interior dimensions are preferred whenever possible so as to conserve the amount of casting material used in a casting process. The outer diameter or dimension of the riser tube 10 is not critical and it can be varied depending upon the structural strength required of the riser tube.
The use of solid, heat disposable patterns is well known in the art of investment casting. Suitable materials that can be used to form heat disposable patterns are those that are solid at room temperature and melt at elevated temperatures (e.g., about 150F and higher). Suitable heat disposable materials include knowncasting waxes and polymers. Exemplary polymers include polystyrene as well as photocurble polymers such as a blend of epoxy resin and acrylate ester. An exemplary, commercially available photocurable pol~mer is sold by Ciba-Geigy Corporation, Los Angeles, CA, as product name ~ 5170. Casting waxes tend to meltin the range of about 150 - 160F while photocurable polymers have a much highermelting range. Photocurable polymers normally must be extracted by flash firing at tempeldlules of about 1900F to rapidly vaporize the solid polymer.
A variety of refractory materials well lmown for use in investment casting processes can be used with the process of the present invention. Examples of suitable refractory materials include those that utilize colloidal silica binder, alcohol based binder, latex binder additive, and colloidal silica binder with a latex additive. A
preferred primary refractory is a fine stucco with a high percentage of zircon.
Preferred backup coats are generally more coarse than the primary coat and typically use colloidal silica binder with fused silica.
21~2637 By way of example, a ceramic riser tube can be used in a process to cast femoral components of artificial knee joints. A single riser tube can be used to cast from one to as many as about seventy two knee femoral components. Preferably, twelve knee femoral components are cast using a single riser tube. A riser tube suitable for casting twelve knee femoral components typically has a length of about 12 inches, an outside diameter of about 0.75 inch, and an inside diameter of about 0.375 inch. Further, the riser tube preferably has two orifices per article representing a positive model of the article to be cast. Each orifice may be circular in shape having a diameter of about 0.375 inch.
It is understood that riser tubes used according to the present invention, and the components thereof, may have shapes and sizes other than those recited in this exemplary description. For example, the size and shape of the orifices may vary depending upon the requirements of a given casting operation.
The use of the solid, rigid riser tube according to the present casting process has several advantages over the traditional wax trees that these riser tubes replace. The riser tube used according to the invention has sufficient rigidity and structural strength to enable its inside diameter to be substantially smaller than the diameters typically required of a wax tree used for a similar casting operation. This enables a smaller volume of molten metal to be used in casting processes, thus achieving significant cost savings and improved filling of the investment assembly.
Further, the structural strength of the riser tube enables the gates used with the riser tube to be substantially smaller than gates used with wax trees. This provides an important safety advantage as the cast articles can simply be snapped away from the riser tube; they do not have to be mechanically sawed as do the gates that are formed through a casting process that utilizes a wax tree.
~ ` --9- 21~2637 .
The riser tube of the invention is also advantageous because it possesses good thermal insulation properties. An investment assembly formed in a casting process using the riser tube of the present invention derives in~ tion from the riser tube itself as well as from the refractory. When molten material flows into the cavities from the riser tube, the molten material immediately undergoes progressive solidification. The metal first forms a skin corresponding to exterior regions of the article, and solidification progresses thereafter from the exterior regions of the article to interior regions. Due to the insulating properties of the riser tube, casting material (e.g., metal) within the riser tube remains in its molten state longer than the material within the mold cavities. This feature contributes to better mold filling properties during the casting process.
A further unexpected advantage achieved through the use of riser tubes accordingly to the present invention is a significant reduction in material waste.
Investment casting processes that use wax trees tend to have yields of about 36%.
That is, a given casting operation will utilize 36% of the casting material (e.g., metal) to form castings and 64% of the casting material will be waste that forms in the gates and the area once occupied by the wax tree. In contrast, the process of the present invention, lltili7ing a solid riser tube, achieves as much as about a 93% yield. That is, 93% of the casting material forms castings while only 7% of the casting materialrepresents waste components.
The present invention is applicable to the manufacture of virtually any article that can be cast. The cast article can be made from materials that are typically used in casting processes. Such materials include metals, metal alloys, stainless steel, ferrous alloys, and non-ferrous alloys.
EXAMP~ li Metal usage was col~lpa~cd between casting processes using the solid riser tube of the invention and the conventional wax tree system. In both processes thirty-six 10 ounce knee femorals were cast. The actual metal usage for both processes together with the casting yield are illustrated below in Table 1.
,, . 21~2637 Method Actual Metal Metal Usage Casting Usage per Cast Part Yield Casting with Solid Riser Tube 27 Ibs 12 ounces 83%
Casting with Wax Tree 63 lbs 28 ounces 36%
The data illustrated above indicates the improved efficiency of the present casting process. This improved efficiency trAn~lAtes to a substantial cost savings as a great deal of metal can be conserved using the process of this invention.
The foregoing description of methods of manufacture and the illustrative embodiment is presented to indicate the range of constructions to which the invention applies. Variations in the casting process of the invention and the materials to be used in the casting process of the invention will be readily a~arent to those having ordinary skill in the art. Such variations are considered to be within the scope of the invention in which patent rights are asserted, as set forth in the claims appended hereto.
What is claimed is:
- Further, a wax tree having a relatively large diameter is often required to provide sufficient structural strength to support the solid patterns. Relatively large volumes of molten metal are thus used in each c~stin~ run to fill the molds and the space formerly occupied by the large diameter wax tree. This substantially increases the cost of the casting process, particularly when articles are to be cast usingexpensive metals or metal alloys.
The use of the wax tree also leads to additional processing delays and safety risks in post-casting procedures. The low structural strength of the wax tree necessitates the use of relatively large gates connecting the wax patterns to the wax tree. Following casting, the metal within the gates solidifies and it is generally of such diameter that the cast part cannot be easily separated from the stem. Rather, the part must be cut from the stem using a specialized cutting process. This cutting stepobviously requires a significant amount of post-processing time and poses a safety risk to the individuals using the cutting equipment.
There is thus a need for an improved investment casting process that can combine the traditional advantages of investment casting while elimin~ting some of its disadvantages. Such an improved process would be particularly applicable to the casting of expensive metals and metal alloys such as those used to manufacture orthopedic implants.
Accordingly, an object of the invention is to provide an improved investment casting process that is more cost effective and that requires less time for the production of metal components. It is also an object of the invention to facilitate the production of metal parts in a more cost effective manner. A further object of the invention is to provide an investment casting process that is well suited to themanufacture of orthopedic implants. It is another object of the invention to provide apparatuses that can improve the efficiency and effectiveness of investment casting processes. These and other objects will be ap~arent from the description that follows.
Summary of the Invention The present invention relates to an improved investment casting process that enables the production of cast parts with more economical use of metal and with fewer post-casting procedures.
.
21~2637 - In one embodiment the invention comprises an investment casting process that elimin~tes the need to use the traditional wax tree. The casting process of the present invention utilizes a hollow, structurally sound riser tube having one or more orifices extending through the wall of the riser tube. The riser tube is typically made from a ceramic material that is able to withstand the temperatures encountered during casting processes.
According to the process of the invention, one or more heat disposable solid patterns of an article to be cast are mounted to the riser tube. The solid patterns are mounted by adhering at least one gate on each solid pattern to a matching orifice on the riser tube to yield a cluster. A refractory is then applied to the cluster in one or more coats to form an investment assembly. The refractory can be applied by a variety of known techniques, including dipping and spraying.
Once the investment assembly is formed, the solid patterns are removed by heating the investment assembly to a temperature sufficient to melt or otherwise destroy of the solid, heat disposable material that forms the solid patterns. In some embodiments, the molten heat disposable material is allowed to flow out of the investment assembly. In other instances the heat disposable material is destroyed by flash firing. After melting or destroying the heat disposable material there remains a shell having one or more cavities that represent negatives of the part to be cast. The shell is then filled with a molten casting material, such as a metal or metal alloy, that is poured through the riser tube. The molten casting material fills the cavities in the shell and, after cooling, forms the desired cast articles.
The present invention also provides a novel investment assembly useful in practicing the method of the invention. The investment assembly comprises a hollow, structurally sound, elongate riser tube, heat disposable patterns mounted by their gates to orifices in the side wall of the riser tube, and a refractory that fully coats the riser tube and the adhered patterns. The riser tube preferably is made of ceramic, and can be of any suitable cross sectional shape. In one preferred embodiment the riser tube has a circular cross section.
Rrief Description of Drawin~
For a fuller understanding ofthe nature and objects ofthe invention, reference should be made to the following detailed description and the accompanying drawings, in which:
!
- . 21426~7 -FIGURES lA - lJ show successive stages in the casting process in accordance with features of the invention;
FIGURE 2 is a perspective view illustrating the formation of a cluster by attaching heat disposable patterns to a riser tube; and FIGURE 3 is a perspective view, partly cut away, of an investment assembly.
Detailed Description of the Invention Referring to Figures 1 through 3, wherein like reference numerals refer to like parts, there is illustrated an investment assembly and successive stages in the casting process in accordance with the features of the invention.
Figures lA through lJ illustrate sequential steps of a process according to the invention for casting desired articles 62.
Figure lA shows a hollow riser tube 10 having one or more orifices 12.
At least one heat disposable solid pattern 14 is mounted to the riser tube 10 byattaching at least one gate 16 of the pattern to a corresponding orifice on the riser tube.
The attachment of patterns to the riser tube forms a cluster assembly 18. Each gate 16 can be secured to the riser tube by inserting it into the orifice 12 where it is held in place by friction between the orifice and stem. More preferably, however, the gate is secured to the orifice by heating the stem until it reaches a molten state and then allowing the gate to solidify and bond to the orifice. It is understood that each pattern may have more than one gate that is used to join the pattern to the riser tube.
Preferably, riser tube 10 has one closed end 22. In one embodiment, shown in Figure lB, a plug 20 can be used to close end 22 of the riser tube.
The refractory can be applied to the cluster assembly 18 by a number of known techniques. Figures lC and lD i11ustrate alternative methods of applying arefractory binder material to the cluster assembly 18. In both methods, the refractory preferably is applied in layers that fully coat the cluster assembly 18, with drying cycles provided between each application of refractory. As understood by those having ordinary skill in the art, primary layers are typically applied before the 21~2637 application of one or more backup layers of refractory. Primary coats of refractory tend to be finer as they must accurately adhere to the contours of the solid patterns 14.
Backup coats of refractory tend to be more coarse as they are primarily intended to impart structural strength. The application of refractory to the cluster assembly 18 forms an investment assembly 30.
In the binder application process illustrated in Figure l C, a dipping apparatus 32 holds cluster 18 over vessel 34 that contains a refractory 36 used in forming primary layers of refractory. The dipping apparatus lowers cluster assembly 18 into vessel 34 until the entire cluster assembly is submerged and fully coated with refractory 36. The apparatus 34 lifts the cluster from the vessel after the coating process is complete and the applied refractory is allowed to dry and form a primary layer 38. These steps are repeated until a desired number of primary layers of adesired thickness form on the cluster assembly. A similar apparatus and process can be used to apply backup refractory layers to the cluster.
Figure lD illustrates an alternative method by which a refractory can be sprayed upon cluster assembly 18 to fully coat the cluster assembly. After spraying, the refractory is allowed to dry and form primary refractory layer 38. Spray applications can be repeated until the desired number of layers and/or the desired thickness of refractory primary coat forms on the cluster assembly. The cluster assembly can then be sprayed with a refractory backup coat and allowed to dry toform backup layer 40. These steps can be repeated until the backup layers are present at a desired number of layers and/or at a desired thickness.
Figure lE illustrates an investment assembly 30 in which a dry refractory 38, 40 fully coats the riser tube 10 and joined patterns 14.
After forming the investment assembly 30, the heat disposable matter 42, which forms patterns 14, can be extracted by a number of known techniques.
Figure lF illustrates the extraction of heat disposable matter 42 by placing theinvestment assembly 30 in a heated, pressurizable chamber or oven 44. According to known techniques, heat and/or pressure are applied to such a degree that the heat disposable matter 42 forming the solid patterns 14 and the stems 16 melts and flows out of the invest~ent assembly 30. One preferred embodiment utilizes a steam autoclave, at a temperature in a range of about 31 5F to 340F and at a ples~uie of about 100 to 150 psi, to extract the heat disposable matter. In some embodimentssolid patterns are made from higher melting polymeric materials that are destroyed by flash finng at temperatures sufficient to rapidly vaporize the solid pattern. In one embodiment, flash firing is conducted at temperatures of about 1900F.
Removal or destruction of the heat disposable matter from investment assembly 30 yields a shell 46 having cavities 48 formerly occupied by the heat disposable patterns. The cavities 48 form the negative image of the desired articles to be manufactured.
Shell 46 can be heated and fired, as illustrated in Figure lG, to impart increased strength to the shell and to remove any residual heat disposable matter. The shell 46 preferably is fired at a temperature typically in the range of about 1,400F to 2,000F for approximately one-half hour or more. The shell 46 is then ready to accept molten casting material 50, which is poured into shell 46, as illustrated in Figure lH, to form solid, cast articles. Preferably, molten casting material 50, such as a metal or metal alloy, is poured from a container 52 into the shell through opening 22 in riser tube 10. The metal fills the riser tube 10 and passes through orifices 12 and gates 16 to fill cavities 48. Once the cavities are filled, the molten metal is allowed to cool and solidify. Thereafter, the refractory shell 46 is fractured and removed, as illustrated in Figure lI, leaving behind riser tube 10 with gates 60 extending from orifices 12 and the desired solid, cast articles 62 attached to the end of the gates opposite the orifices.
As illustrated in Figure lJ, the cast articles 62 can be removed from the gates 60 simply by manually fracturing the stems.
Figure 2 illustrates an exemplary riser tube 10, elongated along a vertical axis 11, that is useful with the casting process of the invention. The riser tube 10 is hollow and has an outer wall 13 that defines an interior space 15. One end of the riser tube, preferably top end 23, remains open to allow communication of molten metal to the riser tube's interior space 15. The other end 22 remains closed. The riser tube 10 contains one or more orifices 12 that extend through the wall 13 to which heat disposable solid patterns 14 are secured. Riser tube 10 can have a variety of suitable cross sectional shapes, including circular, ovoid, triangular, and square.
- Figure 3 illustrates an investment assembly 30 having a ceramic riser tube -10, heat disposable p~ttern~ 14 joined to orifices 12 by gates 16, and refractory binder material 38, 40.
~7~ 2142637 The riser tube is manufactured from virtually any inert, solid, rigid material that is able to withstand contact with molten metal and temperatures in excess of about 3200F. Suitable materials include high purity alumina, magnesium oxide, ceramic refractory, and silica.
The dimensions of riser tube 10 depend upon the identify of articles to be cast and the number of articles to be formed in a single casting operation. The inner diameter or dimensions of riser tube 10 need only be large enough to accommodate the flow of molten material during a casting process. These dimensions can be as small as 0.0625 inch or less. Generally, the range of the inner dimensions (e.g., diameter) of riser tube 10 is approximately 0.0625 inch to 2 inches. Riser tubes with smaller interior dimensions are preferred whenever possible so as to conserve the amount of casting material used in a casting process. The outer diameter or dimension of the riser tube 10 is not critical and it can be varied depending upon the structural strength required of the riser tube.
The use of solid, heat disposable patterns is well known in the art of investment casting. Suitable materials that can be used to form heat disposable patterns are those that are solid at room temperature and melt at elevated temperatures (e.g., about 150F and higher). Suitable heat disposable materials include knowncasting waxes and polymers. Exemplary polymers include polystyrene as well as photocurble polymers such as a blend of epoxy resin and acrylate ester. An exemplary, commercially available photocurable pol~mer is sold by Ciba-Geigy Corporation, Los Angeles, CA, as product name ~ 5170. Casting waxes tend to meltin the range of about 150 - 160F while photocurable polymers have a much highermelting range. Photocurable polymers normally must be extracted by flash firing at tempeldlules of about 1900F to rapidly vaporize the solid polymer.
A variety of refractory materials well lmown for use in investment casting processes can be used with the process of the present invention. Examples of suitable refractory materials include those that utilize colloidal silica binder, alcohol based binder, latex binder additive, and colloidal silica binder with a latex additive. A
preferred primary refractory is a fine stucco with a high percentage of zircon.
Preferred backup coats are generally more coarse than the primary coat and typically use colloidal silica binder with fused silica.
21~2637 By way of example, a ceramic riser tube can be used in a process to cast femoral components of artificial knee joints. A single riser tube can be used to cast from one to as many as about seventy two knee femoral components. Preferably, twelve knee femoral components are cast using a single riser tube. A riser tube suitable for casting twelve knee femoral components typically has a length of about 12 inches, an outside diameter of about 0.75 inch, and an inside diameter of about 0.375 inch. Further, the riser tube preferably has two orifices per article representing a positive model of the article to be cast. Each orifice may be circular in shape having a diameter of about 0.375 inch.
It is understood that riser tubes used according to the present invention, and the components thereof, may have shapes and sizes other than those recited in this exemplary description. For example, the size and shape of the orifices may vary depending upon the requirements of a given casting operation.
The use of the solid, rigid riser tube according to the present casting process has several advantages over the traditional wax trees that these riser tubes replace. The riser tube used according to the invention has sufficient rigidity and structural strength to enable its inside diameter to be substantially smaller than the diameters typically required of a wax tree used for a similar casting operation. This enables a smaller volume of molten metal to be used in casting processes, thus achieving significant cost savings and improved filling of the investment assembly.
Further, the structural strength of the riser tube enables the gates used with the riser tube to be substantially smaller than gates used with wax trees. This provides an important safety advantage as the cast articles can simply be snapped away from the riser tube; they do not have to be mechanically sawed as do the gates that are formed through a casting process that utilizes a wax tree.
~ ` --9- 21~2637 .
The riser tube of the invention is also advantageous because it possesses good thermal insulation properties. An investment assembly formed in a casting process using the riser tube of the present invention derives in~ tion from the riser tube itself as well as from the refractory. When molten material flows into the cavities from the riser tube, the molten material immediately undergoes progressive solidification. The metal first forms a skin corresponding to exterior regions of the article, and solidification progresses thereafter from the exterior regions of the article to interior regions. Due to the insulating properties of the riser tube, casting material (e.g., metal) within the riser tube remains in its molten state longer than the material within the mold cavities. This feature contributes to better mold filling properties during the casting process.
A further unexpected advantage achieved through the use of riser tubes accordingly to the present invention is a significant reduction in material waste.
Investment casting processes that use wax trees tend to have yields of about 36%.
That is, a given casting operation will utilize 36% of the casting material (e.g., metal) to form castings and 64% of the casting material will be waste that forms in the gates and the area once occupied by the wax tree. In contrast, the process of the present invention, lltili7ing a solid riser tube, achieves as much as about a 93% yield. That is, 93% of the casting material forms castings while only 7% of the casting materialrepresents waste components.
The present invention is applicable to the manufacture of virtually any article that can be cast. The cast article can be made from materials that are typically used in casting processes. Such materials include metals, metal alloys, stainless steel, ferrous alloys, and non-ferrous alloys.
EXAMP~ li Metal usage was col~lpa~cd between casting processes using the solid riser tube of the invention and the conventional wax tree system. In both processes thirty-six 10 ounce knee femorals were cast. The actual metal usage for both processes together with the casting yield are illustrated below in Table 1.
,, . 21~2637 Method Actual Metal Metal Usage Casting Usage per Cast Part Yield Casting with Solid Riser Tube 27 Ibs 12 ounces 83%
Casting with Wax Tree 63 lbs 28 ounces 36%
The data illustrated above indicates the improved efficiency of the present casting process. This improved efficiency trAn~lAtes to a substantial cost savings as a great deal of metal can be conserved using the process of this invention.
The foregoing description of methods of manufacture and the illustrative embodiment is presented to indicate the range of constructions to which the invention applies. Variations in the casting process of the invention and the materials to be used in the casting process of the invention will be readily a~arent to those having ordinary skill in the art. Such variations are considered to be within the scope of the invention in which patent rights are asserted, as set forth in the claims appended hereto.
What is claimed is:
Claims (20)
1. A lost-wax casting process, comprising the steps of:
providing a hollow riser tube that is closed at one end, the riser tube having a plurality of orifices extending through the wall thereof;
mounting one or more, heat disposable solid patterns of an article to be cast directly to the riser tube to form a cluster, the solid patterns being mounted by adhering at least one gate on each solid pattern to at least one orifice of the riser tube;
building a shell around the cluster by applying one or more coatings of a refractory to the cluster to form, upon drying, an investment assembly;
removing the solid patterns from the investment assembly by heating the investment assembly to a temperature sufficient to melt or destroy the solid patterns such that a material from which the solid patterns are made vacates the investment assembly leaving a shell having one or more cavities; and filling the shell, through the riser tube, with a molten casting material such that the molten casting material fills the cavities in the shell to form, upon cooling, solid cast articles.
providing a hollow riser tube that is closed at one end, the riser tube having a plurality of orifices extending through the wall thereof;
mounting one or more, heat disposable solid patterns of an article to be cast directly to the riser tube to form a cluster, the solid patterns being mounted by adhering at least one gate on each solid pattern to at least one orifice of the riser tube;
building a shell around the cluster by applying one or more coatings of a refractory to the cluster to form, upon drying, an investment assembly;
removing the solid patterns from the investment assembly by heating the investment assembly to a temperature sufficient to melt or destroy the solid patterns such that a material from which the solid patterns are made vacates the investment assembly leaving a shell having one or more cavities; and filling the shell, through the riser tube, with a molten casting material such that the molten casting material fills the cavities in the shell to form, upon cooling, solid cast articles.
2. The process of claim 1 further comprising, prior to the step of filling the shell, the step of heating and firing the shell at a temperature and for a duration sufficient to remove any residual material from which the solid patterns are made, and to add fired strength to the shell.
3. The process of claim 1 wherein the patterns are mounted to the riser tube by melting the gates of the solid patterns, adhering the molten gates to the orifices, and allowing the gates to solidify and bond to the orifices.
4. The process of claim 3 wherein the investment assembly is formed by multiple applications to the cluster of a refractory.
5. The process of claim 4 wherein the step of removing the solid patterns is conducted with heat and/or pressure.
6. The process of claim 1 wherein the shell is formed around the cluster by dipping the cluster in the refractory or by spraying the refractory on the cluster.
7. The process of claim 4 wherein one or more applications of the refractory is a primary coat.
8. The process of claim 4 wherein at least one application of the refractory comprises a backup coat.
9. The process of claim 1 wherein the step of removing the solid patterns is conducted in a steam autoclave at a temperature in the range of about 315°F
to 340°F and at a pressure in the range of about 100 to 150 psi.
to 340°F and at a pressure in the range of about 100 to 150 psi.
10. The process of claim 1 wherein the step of removing the solid patterns is conducted by flash firing at a temperature of about 1900°F.
11. The process of claim 2 wherein the step of heating and firing the ceramic shell is conducted at a temperature in the range of about 1400°F to 2000°F for approximately one-half hour or more.
12. The process of claim 1 wherein the casting material is a metal or metal alloy.
13. The process of claim 1 wherein the solid cast articles are implantable bone prostheses.
14. The process of claim 1 further comprising the step of removing the solid cast articles from the shell following completion of the step of filling the shell.
15. A lost wax casting process for forming implantable bone prostheses, comprising the steps of:
providing a hollow riser tube having at least one closed end and having a plurality of orifices extending through the wall of the riser tube;
mounting one or more heat disposable solid patterns of an article to be cast directly to the riser tube by adhering one or more gates of each solid pattern to an orifice of the riser tube to form a cluster;
exposing the cluster to a refractory to fully coat the cluster with one or more layers of the refractory to form, upon drying, an investment assembly;
removing the solid patterns from the investment assembly by heating the investment assembly and extracting from the investment assembly molten material from which the patterns are made to yield a shell having one or more cavities;
heating the shell at a temperature in the range of about 1400°F
and 2000°F for approximately one-half hour or more to harden the ceramic shell;
filling the shell, through the riser tube, with a molten casting material such that the molten casting material fills the cavities formerly occupied by the solid patterns to form, upon cooling, cast implantable bone prostheses encased within the shell; and removing the cast implantable bone prostheses from the riser tube by breaking away the shell to expose the cast prostheses.
providing a hollow riser tube having at least one closed end and having a plurality of orifices extending through the wall of the riser tube;
mounting one or more heat disposable solid patterns of an article to be cast directly to the riser tube by adhering one or more gates of each solid pattern to an orifice of the riser tube to form a cluster;
exposing the cluster to a refractory to fully coat the cluster with one or more layers of the refractory to form, upon drying, an investment assembly;
removing the solid patterns from the investment assembly by heating the investment assembly and extracting from the investment assembly molten material from which the patterns are made to yield a shell having one or more cavities;
heating the shell at a temperature in the range of about 1400°F
and 2000°F for approximately one-half hour or more to harden the ceramic shell;
filling the shell, through the riser tube, with a molten casting material such that the molten casting material fills the cavities formerly occupied by the solid patterns to form, upon cooling, cast implantable bone prostheses encased within the shell; and removing the cast implantable bone prostheses from the riser tube by breaking away the shell to expose the cast prostheses.
16. The lost wax casting process according to claim 15 wherein the inside diameter of the riser tube is in the range of about 0.0625 inch to 2 inches in diameter.
17. The lost wax casting process according to claim 16 wherein said riser tube has a circular cross sectional shape.
18. The lost wax casting process according to claim 15 wherein the riser tube has a square cross sectional shape.
19. The lost wax casting process according to claim 18 wherein the interior dimensions of the riser tube are in the rang of about 0.0625 x 0.0625 inch to 2 inches by 2 inches.
20. An investment assembly, for use in an investment casting process, comprising:
a hollow, vertically extending riser tube having one or more orifices extending through a wall thereof;
one or more heat disposable solid patterns mounted to the orifices within the riser tube; and one or more coats of refractory fully enveloping the riser tube and solid patterns.
a hollow, vertically extending riser tube having one or more orifices extending through a wall thereof;
one or more heat disposable solid patterns mounted to the orifices within the riser tube; and one or more coats of refractory fully enveloping the riser tube and solid patterns.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19846694A | 1994-02-18 | 1994-02-18 | |
US08/198,466 | 1994-02-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2142637A1 true CA2142637A1 (en) | 1995-08-19 |
Family
ID=22733502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2142637 Abandoned CA2142637A1 (en) | 1994-02-18 | 1995-02-16 | Investment casting method and apparatus |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0668117A3 (en) |
JP (1) | JPH07299543A (en) |
CA (1) | CA2142637A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8074420B2 (en) | 2004-05-12 | 2011-12-13 | Quick Fab Products Ltd. | Method of forming joints of non-cylindrical tubing |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1152848B1 (en) * | 1998-11-20 | 2011-08-17 | Rolls-Royce Corporation | Method and apparatus for production of a cast component |
WO2001056722A1 (en) * | 2000-02-02 | 2001-08-09 | Trucast Limited | Investment casting method and apparatus |
US9539638B2 (en) * | 2012-01-06 | 2017-01-10 | Wisys Technology Foundation, Inc. | Modular casting sprue assembly |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS536087B2 (en) * | 1974-10-02 | 1978-03-04 | ||
DE3127700A1 (en) * | 1981-07-14 | 1983-02-03 | Schubert & Salzer Maschinenfabrik Ag, 8070 Ingolstadt | Device for supporting a ceramic investment-casting shell mould during firing |
DE4128425A1 (en) * | 1991-08-27 | 1992-03-19 | Eska Medical Gmbh & Co | Medical implant prodn. with open-structured metallic surfaces - by lost-wax process where open-meshed surface element is reinforced with sprayed-osilicone@ or resin material |
-
1995
- 1995-02-16 CA CA 2142637 patent/CA2142637A1/en not_active Abandoned
- 1995-02-17 EP EP95301016A patent/EP0668117A3/en not_active Withdrawn
- 1995-02-17 JP JP5198195A patent/JPH07299543A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8074420B2 (en) | 2004-05-12 | 2011-12-13 | Quick Fab Products Ltd. | Method of forming joints of non-cylindrical tubing |
Also Published As
Publication number | Publication date |
---|---|
EP0668117A3 (en) | 1996-12-18 |
JPH07299543A (en) | 1995-11-14 |
EP0668117A2 (en) | 1995-08-23 |
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