CA2135955A1 - Shipping container for pairs of water soluble packaging - Google Patents
Shipping container for pairs of water soluble packagingInfo
- Publication number
- CA2135955A1 CA2135955A1 CA002135955A CA2135955A CA2135955A1 CA 2135955 A1 CA2135955 A1 CA 2135955A1 CA 002135955 A CA002135955 A CA 002135955A CA 2135955 A CA2135955 A CA 2135955A CA 2135955 A1 CA2135955 A1 CA 2135955A1
- Authority
- CA
- Canada
- Prior art keywords
- bags
- water soluble
- cell
- pairs
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/82—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for poisons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/02—Wall construction
- B65D90/04—Linings
- B65D90/046—Flexible liners, e.g. loosely positioned in the container
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Packages (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
Abstract
The invention comprises a containerization system for packaging water soluble bags containing a hazardous chemical such as an agrochemical.
The bags are placed in pairs wrapped in an overwrap in a vertical position inside an inner triangular shipping cell of an outer container.
The bags are placed in pairs wrapped in an overwrap in a vertical position inside an inner triangular shipping cell of an outer container.
Description
DOCKET: PH 9~052 213 5 9 ~ 5 Si~lG CONTAINER FOR PAIRS
OF WATER SOLUBLE pAc~A~ G
Inventor: John Forgus Gee FIELD OF T~; INVENTION
The invention relates to a containerization system suitable for containing pairs of packages of hazardous material comprising a rigid container having one or more triangular cells, each cell capable of cont~inin~ two water soluble packages of hazardous material.
BACKGROUND OF ~l~H ~, PRIOR ART
At the present, hazardous materials such as agrochemicals are packaged in water soluble packages for ease and safety of use, see e.g. GB
Patent to Phillips 922,317 and U.S. Patent to Hodakowski 5,080,226, for solid, liquid and gelled contents in a water soluble bag. These bags are tremendous improvements over other packaging such as jugs, drums or the like because of the improvements in prevention of leakage and spillage during transportation, handling, and storage. While these bags represents a maj or step forward in the distribution and use of hazardous chemicals .
~lexible containers are difficult to ship and must be placed in some form of shipping containers. Normally, the containers used for shipping hazardous material must meet certain additional strength requirements. for example.
strength upon dropping the container. U.S. government regulations require.
for example. that the drop and damage resistance of the contents in a shipping container must stop the product from leaving the container. See 213~955 DOCKEr: PH 93052 e.g. Gov. Reg. 49 C.F.R. 178.516, 49 C.F.R. 178.603 and the transfer of dangerous goods 9.7.3.
Normally, rigid containers are used in shippin~ and handling of hazardous materials to allow shipments of multiple units and to further give protection of the contents. For example, corrugated boxes are normally divided on the inside into additional rectangular or square cells for reception of the desired product. The cell being roughly just large enough to contain the product. Where two products are to be placed in the cell, an appropriately larger cell is used. With water soluble packaging, it has been found that when two water soluble units are placed in the same cell, the units will not pass of the desired drop test. The product breaking out of the water soluble packaging and maybe even the sealed overwrap as well.
Current box design then encourages more rather than less breakage when multiple units are placed in a cell. It would be useful to have a design in which two water soluble bags could be placed in a single cell within a rigid container. This would facilitate withdrawals of multiple bags and make construction of the shipping container cheaper and lighter. Normally, however, the design of the cell is just to fit the object and as such the rectangular design is preferred.
SUMMARY OF THE INVENTION
It is a main object of this invention to provide a containerization system for storage and transportation of hazardous chemical products in water soluble bags such as agrochemicals wherein two bags will be placed in each cell which improves the storage and shipping resistance to breaks arld leaks, especially leaks from the shipping container. The present invention is directed to a containerization system comprising:
1 ~135955 -DOCKET: PH 93052 a) one or more pairs of a water soluble or dispersible bag which completely encloses a hazardous chemical or agricultural chemical;
b) one or more protective non water soluble polymeric overwraps enclosing each pair of bags either singlely or together; and c) a rigid outer container for containing the pair or pairs of bags wherein the container has one cell for containing each pair of bags; the cell having a triangular perimeter shape;
wherein each pair of bags is placed vertically in each cell and as a pair is in contact with the surface of the three inner walls of the cell.
In a preferred embodiment of the invention, the container comprises a plurality of cells preferably 4 or 8.
It is a further object of this invention to provide a new containerization system for hazardous chemicals, especially agrochemicals.
Another object is to provide a new system of containing water soluble packages which is easier to use by the end users and minimi7es or diminishes risks of container leakage, pollution and contamination. Another object of the invention is to protect the product inside a water soluble bag from escaping to the environment.
Yet another object of the invention is to provide a means to dissipate the force of a shock away from a water soluble bags when transporting said bags in pairs. A further object is to provide a container which is a cost savings advantage in both shipping and manufacturing. These and-other objects will be clear to those skilled in the art from the description figures.
and example herein.
~1359S5 DOCKET: PH 93052 DESCRIPTION OF THE FIGURES
Figure 1 is a view of a rigid corrugated container having eight cells, each cell containing two water soluble pouches surrounded by a single overwrap.
Figure 2 is a corrugated container of Example 1 unfolded to show dimensions.
Figure 3 is a corrugated divider which is folded to make four cells, two of which are used in the container of Example 1.
Figure 4 is the method of folding the divider of Figure 3 to obtain four triangular cells (top down view~.
Figure 5 is an exploded view of four pairs of bags being inserted into 1/2 of a container of Example with space for another four pairs.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The containerization system of the present invention comprises one or more pairs of water soluble or dispersible bags enclosing a hazardous chemical such as a agrochemical. The pair either singlely or as a pair enclosed within a non-water soluble polymeric outer overwrap bag. Each pair of bags is contained within one cell of a rigid outer container, the cell having a triangular perimeter.
By "water soluble or water dispersible bag enclosing a hazardous chemical" is meant the distribution and containerization system. for example, in U.S. Patent 5,080,226. This type of system comprises a water soluble or dispensable enveloping film preferably soluble in cold water and a hazardous chemical or agricultural chemical or in other embodiments in solid or liquid form.
DOCKET: PH 93052 The chemical nature of the enveloping film constituting the bag can vary quite widely. Suitable materials are water soluble (or possibly water dispersible) materials which are insoluble or compatible with the active ingredients and other contents.
A preferred enveloping film comprises or is made from polyvinylalcohol (PVA). When PVA is used, it is preferably partially or fully alcoholized or hydrolyzed, e.g., 40-100%, preferably 80-99% alcoholized or hydrolyzed, as a polyvinyl acetate (or other ester) film. Copolymers or other derivatives of such polymers can also be used.
Additional preferred materials for constituting the bags in the invention are polyethylene oxide, methylcellulose, and polyvinylalcohol.
A hazardous chemical can be any compound which can easily cause extreme injury to persons exposed to the chemical or which can easily damage the environment. Examples are acids, bases, caustics, poisons, and agrochemicals. An agricultural chemical or agrochemicals are compounds such as pesticides (e.g., herbicides, fungicides, nematocides, insecticides, etc.) and plant protection agents (e.g., plant growth regulators, nutrients, etc.). Agrochemicals also include plant adjuvants such as penetrating agents and the like.
Hack's Chemical Dictionary, 5th Edition, says that Hazardous chemicals are chemicals that may cause loss of life or propertv by improper handling, shipping, or storing.
Those Hazardous chemicals or agricultural chemicals may be in any convenient form, for example, solid, liquid, or gel and are preferablv water soluble or dispersible. Solids are preferred chemicals of the invention.
In practice, the Hazardous chemical used in the invention and is contained in the water soluble bag comprises the active ingredient, which is ~13~955 DOCKET: -PH 93052 the hazardous chemical in association with ingredients that participate in or assist in the formation of the product, for example, surfactants, dispersants, thickeners, solvents and gelled or gelling agents.
It is required that the bag also be enclosed in an additional non-water soluble flexible bag. In the event of severe trauma which does break the bag the outer bag will help contain any leak. The bag may contain each bag separately or contain them both as in the example and Figure 5. Such overwrap bags are normally polymeric such as polyethylene, but one skilled in the art could easily choose others.
By rigid containers, herein is meant those rigid containers normally used to ship product such as water soluble bags. These are normally made of corrugated board but can be made of plastic, metal, wood, or any other .~imil~r rigid material approved for use in the shipping trade.
By triangular perimeter shape is meant that the cell has three sides forming a triangle preferably a right triangle. Since the bag is placed vertically in the cell. the perimeter and dimension should be such that the bag pair is in contact with the cell walls. Thus for a very snug fit, a small ofperimeter is used for a loose fit, a larger perimeter is used. The perimeter should not be so large that one or more cell walls is not in contact with some part of the pair. Likewise a preferred embodiment is that the bag pair fits snugly in the cell making some light pressure required to overcome the friction of insertion.
The following examples are representative of the invention and are not intended to be limiting. Other choices of materials. methods. sizes. and the like will be readily apparent to those skilled in the art on viewing the disclosure and examples.
~135-g~5 - DOCKEI`: F'H 93052 FXAlUI PLE
A corrugated paper box is constructed having the dimensions corresponding to Eigure 2. After inserting two folded dividers of Eigure 3, a box according to Figure 1 is made having a total of eight cells. each cell having 2 bags contained vertically within a single sealed polyethylene bag.
Each bag contained 2 1/2 lbs. of LARVIN(~ brand insecticide/ovicide in a PVOH water soluble bag. This container was subjected to the U.N. packaging group 3, drop tested (31 inches) and compared with pairs of bags in rectangular cells. In the instant invention no damage to the inner bag occurred while several of the pairs in the rectangular cells opened, spilling their contents.
OF WATER SOLUBLE pAc~A~ G
Inventor: John Forgus Gee FIELD OF T~; INVENTION
The invention relates to a containerization system suitable for containing pairs of packages of hazardous material comprising a rigid container having one or more triangular cells, each cell capable of cont~inin~ two water soluble packages of hazardous material.
BACKGROUND OF ~l~H ~, PRIOR ART
At the present, hazardous materials such as agrochemicals are packaged in water soluble packages for ease and safety of use, see e.g. GB
Patent to Phillips 922,317 and U.S. Patent to Hodakowski 5,080,226, for solid, liquid and gelled contents in a water soluble bag. These bags are tremendous improvements over other packaging such as jugs, drums or the like because of the improvements in prevention of leakage and spillage during transportation, handling, and storage. While these bags represents a maj or step forward in the distribution and use of hazardous chemicals .
~lexible containers are difficult to ship and must be placed in some form of shipping containers. Normally, the containers used for shipping hazardous material must meet certain additional strength requirements. for example.
strength upon dropping the container. U.S. government regulations require.
for example. that the drop and damage resistance of the contents in a shipping container must stop the product from leaving the container. See 213~955 DOCKEr: PH 93052 e.g. Gov. Reg. 49 C.F.R. 178.516, 49 C.F.R. 178.603 and the transfer of dangerous goods 9.7.3.
Normally, rigid containers are used in shippin~ and handling of hazardous materials to allow shipments of multiple units and to further give protection of the contents. For example, corrugated boxes are normally divided on the inside into additional rectangular or square cells for reception of the desired product. The cell being roughly just large enough to contain the product. Where two products are to be placed in the cell, an appropriately larger cell is used. With water soluble packaging, it has been found that when two water soluble units are placed in the same cell, the units will not pass of the desired drop test. The product breaking out of the water soluble packaging and maybe even the sealed overwrap as well.
Current box design then encourages more rather than less breakage when multiple units are placed in a cell. It would be useful to have a design in which two water soluble bags could be placed in a single cell within a rigid container. This would facilitate withdrawals of multiple bags and make construction of the shipping container cheaper and lighter. Normally, however, the design of the cell is just to fit the object and as such the rectangular design is preferred.
SUMMARY OF THE INVENTION
It is a main object of this invention to provide a containerization system for storage and transportation of hazardous chemical products in water soluble bags such as agrochemicals wherein two bags will be placed in each cell which improves the storage and shipping resistance to breaks arld leaks, especially leaks from the shipping container. The present invention is directed to a containerization system comprising:
1 ~135955 -DOCKET: PH 93052 a) one or more pairs of a water soluble or dispersible bag which completely encloses a hazardous chemical or agricultural chemical;
b) one or more protective non water soluble polymeric overwraps enclosing each pair of bags either singlely or together; and c) a rigid outer container for containing the pair or pairs of bags wherein the container has one cell for containing each pair of bags; the cell having a triangular perimeter shape;
wherein each pair of bags is placed vertically in each cell and as a pair is in contact with the surface of the three inner walls of the cell.
In a preferred embodiment of the invention, the container comprises a plurality of cells preferably 4 or 8.
It is a further object of this invention to provide a new containerization system for hazardous chemicals, especially agrochemicals.
Another object is to provide a new system of containing water soluble packages which is easier to use by the end users and minimi7es or diminishes risks of container leakage, pollution and contamination. Another object of the invention is to protect the product inside a water soluble bag from escaping to the environment.
Yet another object of the invention is to provide a means to dissipate the force of a shock away from a water soluble bags when transporting said bags in pairs. A further object is to provide a container which is a cost savings advantage in both shipping and manufacturing. These and-other objects will be clear to those skilled in the art from the description figures.
and example herein.
~1359S5 DOCKET: PH 93052 DESCRIPTION OF THE FIGURES
Figure 1 is a view of a rigid corrugated container having eight cells, each cell containing two water soluble pouches surrounded by a single overwrap.
Figure 2 is a corrugated container of Example 1 unfolded to show dimensions.
Figure 3 is a corrugated divider which is folded to make four cells, two of which are used in the container of Example 1.
Figure 4 is the method of folding the divider of Figure 3 to obtain four triangular cells (top down view~.
Figure 5 is an exploded view of four pairs of bags being inserted into 1/2 of a container of Example with space for another four pairs.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The containerization system of the present invention comprises one or more pairs of water soluble or dispersible bags enclosing a hazardous chemical such as a agrochemical. The pair either singlely or as a pair enclosed within a non-water soluble polymeric outer overwrap bag. Each pair of bags is contained within one cell of a rigid outer container, the cell having a triangular perimeter.
By "water soluble or water dispersible bag enclosing a hazardous chemical" is meant the distribution and containerization system. for example, in U.S. Patent 5,080,226. This type of system comprises a water soluble or dispensable enveloping film preferably soluble in cold water and a hazardous chemical or agricultural chemical or in other embodiments in solid or liquid form.
DOCKET: PH 93052 The chemical nature of the enveloping film constituting the bag can vary quite widely. Suitable materials are water soluble (or possibly water dispersible) materials which are insoluble or compatible with the active ingredients and other contents.
A preferred enveloping film comprises or is made from polyvinylalcohol (PVA). When PVA is used, it is preferably partially or fully alcoholized or hydrolyzed, e.g., 40-100%, preferably 80-99% alcoholized or hydrolyzed, as a polyvinyl acetate (or other ester) film. Copolymers or other derivatives of such polymers can also be used.
Additional preferred materials for constituting the bags in the invention are polyethylene oxide, methylcellulose, and polyvinylalcohol.
A hazardous chemical can be any compound which can easily cause extreme injury to persons exposed to the chemical or which can easily damage the environment. Examples are acids, bases, caustics, poisons, and agrochemicals. An agricultural chemical or agrochemicals are compounds such as pesticides (e.g., herbicides, fungicides, nematocides, insecticides, etc.) and plant protection agents (e.g., plant growth regulators, nutrients, etc.). Agrochemicals also include plant adjuvants such as penetrating agents and the like.
Hack's Chemical Dictionary, 5th Edition, says that Hazardous chemicals are chemicals that may cause loss of life or propertv by improper handling, shipping, or storing.
Those Hazardous chemicals or agricultural chemicals may be in any convenient form, for example, solid, liquid, or gel and are preferablv water soluble or dispersible. Solids are preferred chemicals of the invention.
In practice, the Hazardous chemical used in the invention and is contained in the water soluble bag comprises the active ingredient, which is ~13~955 DOCKET: -PH 93052 the hazardous chemical in association with ingredients that participate in or assist in the formation of the product, for example, surfactants, dispersants, thickeners, solvents and gelled or gelling agents.
It is required that the bag also be enclosed in an additional non-water soluble flexible bag. In the event of severe trauma which does break the bag the outer bag will help contain any leak. The bag may contain each bag separately or contain them both as in the example and Figure 5. Such overwrap bags are normally polymeric such as polyethylene, but one skilled in the art could easily choose others.
By rigid containers, herein is meant those rigid containers normally used to ship product such as water soluble bags. These are normally made of corrugated board but can be made of plastic, metal, wood, or any other .~imil~r rigid material approved for use in the shipping trade.
By triangular perimeter shape is meant that the cell has three sides forming a triangle preferably a right triangle. Since the bag is placed vertically in the cell. the perimeter and dimension should be such that the bag pair is in contact with the cell walls. Thus for a very snug fit, a small ofperimeter is used for a loose fit, a larger perimeter is used. The perimeter should not be so large that one or more cell walls is not in contact with some part of the pair. Likewise a preferred embodiment is that the bag pair fits snugly in the cell making some light pressure required to overcome the friction of insertion.
The following examples are representative of the invention and are not intended to be limiting. Other choices of materials. methods. sizes. and the like will be readily apparent to those skilled in the art on viewing the disclosure and examples.
~135-g~5 - DOCKEI`: F'H 93052 FXAlUI PLE
A corrugated paper box is constructed having the dimensions corresponding to Eigure 2. After inserting two folded dividers of Eigure 3, a box according to Figure 1 is made having a total of eight cells. each cell having 2 bags contained vertically within a single sealed polyethylene bag.
Each bag contained 2 1/2 lbs. of LARVIN(~ brand insecticide/ovicide in a PVOH water soluble bag. This container was subjected to the U.N. packaging group 3, drop tested (31 inches) and compared with pairs of bags in rectangular cells. In the instant invention no damage to the inner bag occurred while several of the pairs in the rectangular cells opened, spilling their contents.
Claims (6)
1. A containerization system for shipping hazardous chemicals comprising:
a) one or more pairs of water soluble or dispersible bags which completely encloses the hazardous chemical;
b) one or more protective non-water soluble polymeric overwraps enclosing each pair of bags either individually or together; and c) a rigid outer container for containing the pair or pairs of bags wherein the container has one inner cell for containing each pair of bags; the cell having a triangular perimeter shape;
wherein each pair of bags is placed vertically in each cell and as a pair is in contact with the surface of the three inner walls of the cell.
a) one or more pairs of water soluble or dispersible bags which completely encloses the hazardous chemical;
b) one or more protective non-water soluble polymeric overwraps enclosing each pair of bags either individually or together; and c) a rigid outer container for containing the pair or pairs of bags wherein the container has one inner cell for containing each pair of bags; the cell having a triangular perimeter shape;
wherein each pair of bags is placed vertically in each cell and as a pair is in contact with the surface of the three inner walls of the cell.
2. A containerization system according to Claim 1 wherein the hazardous chemical is an agrochemical.
3. A containerization system according to Claim 2 wherein the agrochemical is in solid form.
4. A containerization system according to Claim 1 wherein the rigid container is of corrugated board.
5. A containerization system according to Claim 1 wherein one overwrap contains two bags.
6. A containerization system according to Claim 1 wherein the container comprises a plurality of pairs of bags.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002135955A CA2135955A1 (en) | 1994-11-16 | 1994-11-16 | Shipping container for pairs of water soluble packaging |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002135955A CA2135955A1 (en) | 1994-11-16 | 1994-11-16 | Shipping container for pairs of water soluble packaging |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2135955A1 true CA2135955A1 (en) | 1996-05-17 |
Family
ID=4154678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002135955A Abandoned CA2135955A1 (en) | 1994-11-16 | 1994-11-16 | Shipping container for pairs of water soluble packaging |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2135955A1 (en) |
-
1994
- 1994-11-16 CA CA002135955A patent/CA2135955A1/en not_active Abandoned
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |